EP2970029A1 - Utilisation d'éthers de polycarboxylates en combinaison avec d'autres additifs pour le broyage de ciment - Google Patents
Utilisation d'éthers de polycarboxylates en combinaison avec d'autres additifs pour le broyage de cimentInfo
- Publication number
- EP2970029A1 EP2970029A1 EP14708058.4A EP14708058A EP2970029A1 EP 2970029 A1 EP2970029 A1 EP 2970029A1 EP 14708058 A EP14708058 A EP 14708058A EP 2970029 A1 EP2970029 A1 EP 2970029A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- independently
- aqueous composition
- salt
- cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004568 cement Substances 0.000 title claims abstract description 100
- 239000000654 additive Substances 0.000 title claims abstract description 67
- 229920005646 polycarboxylate Polymers 0.000 title claims abstract description 56
- 238000003801 milling Methods 0.000 title claims abstract description 10
- 150000002170 ethers Chemical class 0.000 title description 16
- 239000000203 mixture Substances 0.000 claims abstract description 74
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 44
- 230000000996 additive effect Effects 0.000 claims abstract description 25
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 19
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000004327 boric acid Chemical class 0.000 claims abstract description 16
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 13
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 13
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims abstract description 13
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 9
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims abstract description 9
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims abstract description 9
- 229940050410 gluconate Drugs 0.000 claims abstract description 9
- 239000000600 sorbitol Substances 0.000 claims abstract description 9
- 150000001414 amino alcohols Chemical class 0.000 claims abstract description 7
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 claims abstract description 7
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001447 alkali salts Chemical class 0.000 claims abstract description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims abstract description 5
- 238000000227 grinding Methods 0.000 claims description 59
- 229920000642 polymer Polymers 0.000 claims description 28
- 150000001412 amines Chemical class 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 22
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 16
- -1 Acetoxyisopropyl group Chemical group 0.000 claims description 15
- 150000001735 carboxylic acids Chemical class 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 12
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 11
- 150000002334 glycols Chemical class 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 150000003863 ammonium salts Chemical class 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 8
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 150000001462 antimony Chemical class 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical group C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 229920005610 lignin Polymers 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 5
- 239000005569 Iron sulphate Substances 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 125000002636 imidazolinyl group Chemical group 0.000 claims description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021645 metal ion Inorganic materials 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- 235000011054 acetic acid Nutrition 0.000 claims description 3
- 229910001615 alkaline earth metal halide Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- 229920005862 polyol Polymers 0.000 claims description 3
- 150000003077 polyols Chemical class 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001508 alkali metal halide Inorganic materials 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 2
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 claims 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims 2
- 239000011790 ferrous sulphate Substances 0.000 claims 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract description 9
- 229920001732 Lignosulfonate Polymers 0.000 abstract description 5
- 235000011187 glycerol Nutrition 0.000 abstract description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical class [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 abstract 1
- 229910000358 iron sulfate Inorganic materials 0.000 abstract 1
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 26
- 239000004567 concrete Substances 0.000 description 11
- 230000000875 corresponding effect Effects 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000004570 mortar (masonry) Substances 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 235000014633 carbohydrates Nutrition 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229940035437 1,3-propanediol Drugs 0.000 description 2
- BYACHAOCSIPLCM-UHFFFAOYSA-N 2-[2-[bis(2-hydroxyethyl)amino]ethyl-(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CCN(CCO)CCO BYACHAOCSIPLCM-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 2
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 2
- LVTYICIALWPMFW-UHFFFAOYSA-N diisopropanolamine Chemical compound CC(O)CNCC(C)O LVTYICIALWPMFW-UHFFFAOYSA-N 0.000 description 2
- 229940043276 diisopropanolamine Drugs 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000193 polymethacrylate Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000000346 sugar Nutrition 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XKQMKMVTDKYWOX-UHFFFAOYSA-N 1-[2-hydroxypropyl(methyl)amino]propan-2-ol Chemical compound CC(O)CN(C)CC(C)O XKQMKMVTDKYWOX-UHFFFAOYSA-N 0.000 description 1
- LQVVVEHMZPWBOQ-UHFFFAOYSA-N 1-amino-2-(propan-2-ylamino)ethane-1,1,2,2-tetrol Chemical compound OC(C(N)(O)O)(NC(C)C)O LQVVVEHMZPWBOQ-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical group C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000604 Polyethylene Glycol 200 Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 description 1
- 229910001619 alkaline earth metal iodide Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000011400 blast furnace cement Substances 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008032 concrete plasticizer Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 150000002826 nitrites Chemical class 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 150000002482 oligosaccharides Chemical class 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/005—Lignin
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/48—Clinker treatment
- C04B7/52—Grinding ; After-treatment of ground cement
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/52—Grinding aids; Additives added during grinding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
- C08L2555/80—Macromolecular constituents
- C08L2555/82—Macromolecular constituents from natural renewable resources, e.g. starch, cellulose, saw dust, straw, hair or shells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Definitions
- the invention relates to the use of cement grinding aids, the cement grinding aid and a method of producing cement using the cement grinding aid.
- cement is known to be very sensitive to water, regardless of whether it is in liquid or gaseous state, because cement binds hydraulically, that is, it hardens under the influence of water within a short time to a very stable solid.
- a key step in cement production is grinding the clinker. Since clinker are very hard, the crushing is very complex. It is important for the properties of the cement to be present as a fine powder. That is why the fineness of the
- Cement grinding aids are usually selected from the class comprising glycols such as alkylene glycols, amines or amino alcohols.
- glycols such as alkylene glycols, amines or amino alcohols.
- Triisopropanolamine TIPA or N, N-bis (2-hydroxyethyl) -N- (2-hydroxypropyl) amine and tris (2-hydroxybutyl) amine as a grinding aid for clinker.
- water-soluble polycarboxylates are known as grinding aids for the preparation of aqueous suspensions of minerals such as lime or pigments, in particular for use in papermaking from WO 97/10308 or EP 0100947 A1.
- US 2002/0091 177 A1 describes the use of polymers of ethylenically unsaturated monomers as
- a grinding aid for the preparation of aqueous suspensions of ground mineral fillers Furthermore, this document describes that a cement which is mixed with such an aqueous suspension leads to improved early strength. However, none of these documents disclose a cement grinding aid.
- concrete liquefiers have long been known.
- this concrete plasticizer is added to the cement as an additive or added to the cement before grinding, and leads to a strong liquefaction, respectively
- WO 2005/123621 describes the use of special polycarboxylate ethers, also in combination with glycols, organic amines and ammonium salts of organic amines with carboxylic acids, as a cement grinding aid. It has been found that by combining the specific polycarboxylate ethers with glycols, organic amines and ammonium salts of organic amines with carboxylic acids, the disadvantages of the known grinding aids can be eliminated or greatly reduced without losing the advantageous effects of the polycarboxylate ether. To achieve the desired effect can often relatively large amounts of quite expensive glycols, organic amines and
- US 6641661 B1 relates to a method for improving the early strength of cement, comprising adding a water reducer comprising a polyoxyalkylene polymer, a sugar, an alkali or alkaline earth metal chloride and an amine to the cement during milling.
- US 2004/149172 A1 relates to a cement additive comprising a liquid carrier, an alkali or alkaline earth salt as solid particles and another component which may be an amine, alkanolamine, modified polyethyleneamine, glycol, a carbohydrate or a surfactant.
- the liquid carrier can be a polycarboxylate.
- WO 201 1/033124 A1 relates to the use of an additive comprising a lignosulfonate for reducing the floating of soot on mineral binders.
- the additive may contain a polycarboxylate comb polymer.
- EP 1728771 A2 describes a grinding aid for particles, such as cement, comprising a biomass-derived polyol, and may contain a second grinding aid, which i.a. may be selected from triethanolamine, acetic acid, carbohydrates, polycarboxylate ethers, chlorides, nitrites or nitrates.
- the object of the invention therefore relates to the provision of a grinding aid with which the efficiency of the grinding of cement can be optimized. Surprisingly, this could be achieved by a combination of a polycarboxylate ether with special additives.
- the present invention therefore relates to the use of an aqueous composition comprising at least one polycarboxylate ether as a cement grinding aid, wherein the aqueous composition is an or contains a plurality of additives or the aqueous composition is used in combination with one or more additives, and wherein the additive is selected from 1, 3-propanediol, a carboxylic acid, a sulphonated aminoalcohol, boric acid, a salt of boric acid, a salt of phosphoric acid, sorbitol , a saccharide, a gluconate, iron sulphate, tin sulphate, an antimony salt, an alkali metal salt, an alkaline earth metal salt, lignin sulphonate, glycerol, melamine, melamine sulphonate and mixtures thereof.
- the additive is selected from 1, 3-propanediol, a carboxylic acid, a sulphonated aminoalcohol, bo
- polycarboxylate ethers added as improvers for cement grinding are not very good grinding aids. It has been found that the polycarboxylate ethers in admixture with the special additives according to the present invention surprisingly have similar milling properties as the pure substances.
- polycarboxylate ethers have different effects on the processability of fresh concrete or fresh mortar.
- precast polymers give a high initial liquefaction and strong restraining.
- Slunnp-Keeper Polynnere give a good initial liquefaction and low stiffening. It has been found that blends of the polycarboxylate ethers can be prepared with the specific admixtures according to the invention, which show the same tendencies as pure polycarboxylate ethers with regard to the workability of the fresh concrete or fresh mortar. Moreover, it was surprising that blends of the polycarboxylate ethers with the specific admixtures according to the invention can be made, which have little effect on processability, such as e.g. Slump, show.
- these cement additives can be used to adjust the processability of the fresh concrete produced from this cement. Furthermore, it is possible with such blends to increase the grinding efficiency of the cement without the processability of it influenced concrete. Whether or how much the processability is influenced depends, among other things, on the chemical structure of the PCE used. By adding the cement additives according to the invention, the efficiency of the grinding of cement, hydraulic, latent hydraulic, non-hydraulic and / or pozzolanic materials can be increased.
- the present invention thus relates to cement grinding aids of an aqueous composition containing a polycarboxylate ether in
- the aqueous composition contains at least one polycarboxylate ether (PCE). All common polycarboxylate ethers can be used.
- the polycarboxylate ether is in particular a comb polymer which has a polycarboxylate backbone and polyether side chains, the polyether side chains preferably being bound to the polycarboxylate backbone via ester, ether and / or amide groups. If reference is made in the following to the polycarboxylate ether, the statement always applies analogously to the above-mentioned preferred forms and in particular to the comb polymer KP defined below as preferred or particularly preferred embodiments.
- the polycarboxylate ether is preferably a comb polymer KP comprising or consisting of the following partial structural units:
- M independently of one another represents H + , an alkali metal ion, alkaline earth metals, a divalent or trivalent metal ion, an ammonium ion or an organic ammonium group,
- each R u independently of the others for hydrogen or a
- each R v independently of the others is hydrogen or COOM, m is 0, 1 or 2,
- R 1 and R 2 independently of one another are a C 1 - to C 20 -alkyl group, -cycloalkyl group, -alkylaryl group or - [AO] n -R 4 ,
- A is C 2 -C -alkylene
- R 4 is H, C 1 -C 20 -alkyl, -cyclohexyl or -alkylaryl, and n is 2-250,
- R 3 independently of one another are NH 2 , -NR 5 R 6 , -OR 7 NR 8 R 9 ,
- R 5 and R 6 are independently for
- Acetoxyethyl (CH 3 -CO-O-CH 2 -CH 2 -) or a hydroxyisopropyl- (HO-CH (CH 3 ) -CH 2 -) or a
- Acetoxyisopropyl group (CH 3 -CO-O-CH (CH 3 ) -CH 2 -);
- Nitrogen is a part of a morpholine or
- R 7 is a C 2 -C 4 -alkylene group
- R 8 and R 9 are each independently a C 1 to C 20 alkyl group, cycloalkyl group, alkylaryl group,
- a / b / c / d (0.1-0.9) / (0.1-0.9) / (0-0.8) / (0-0.8)
- the sequence of the partial structural units S1, S2, S3 and S4 can be alternating, block-like or random. In principle, it is also possible that, in addition to the partial structural units S1, S2, S3 and S4, further structural units are present.
- the partial structural units S1, S2, S3, and S4 together preferably have a weight fraction of at least 50% by weight, in particular at least 90% by weight, very particularly preferably at least 95% by weight, of the total weight of the comb polymer KP.
- the comb polymer KP is in particular free of aromatic compounds and / or aromatic structural units.
- a weight-average molecular weight (M w ) of the polycarboxylate ether, preferably of the comb polymer KP, is in particular 5 ⁇ 00 - 150 ⁇ 00 g / mol, in particular 10 ⁇ 00 - 100 ⁇ 00 g / mol.
- the weight-average molecular weight (Mw) is determined here and below by gel permeation chromatography (GPC) using polyethylene glycol (PEG) as standard.
- the preparation of comb polymers is known in the art per se and can, for example, by free radical polymerization of the corresponding monomers of the formula (l m), (II m), (lll m) or (IV m) take place, resulting in a Comb polymer KP with the partial structural units S1, S2, S3 and S4 leads.
- the radicals R u , R v , R 1 , R 2 , R 3 , M, m and p are defined as described above.
- the polycarboxylic acid of the formula (V) is esterified or amidated with the corresponding alcohols or amines (eg HO-R 1 , H 2 NR 2 , H-R 3 ) and then at most neutralized or partially neutralized (depending on Type of the residue M, for example with metal hydroxides or ammonia).
- the polymer-analogous reaction Details of the polymer-analogous reaction are disclosed, for example, in EP 1 138 697 B1 on page 7 line 20 to page 8 line 50, as well as in its examples or in EP 1 061 089 B1 on page 4, line 54 to page 5 line 38 and in its the examples.
- the comb polymer can be prepared in a solid state of aggregation.
- the open This patent specification is hereby incorporated by reference in particular. The production by polymer anlog
- Corresponding comb polymers are sold commercially and Sika Switzerland AG under the trade name row ViscoCrete ®.
- radical R u is hydrogen or a methyl group or a mixture of a methyl group and hydrogen.
- a molar ratio of the methyl group to the hydrogen is in particular 25:75 to 75:25, in particular 40:60 to 60:40.
- a molar ratio of the C 2 -alkylene units to the C 3 -alkylene units is in particular 25:75 to 75:25, in particular 40:60 to 60:40.
- R 4 represents a methyl group and / or
- the preparation of the aqueous composition is effected by adding water in the preparation of the polycarboxylate ether or by subsequent mixing of polycarboxylate ether with water.
- the proportion of the polycarboxylate ether in the aqueous composition may vary widely. Typically, the proportion of the polycarboxylate ether is, for example, 5 to 90% by weight, in particular 10 to 50% by weight, based on the weight of the aqueous composition.
- a dispersion or a solution is formed. A solution is preferred.
- WO 2005/123621 discloses the use of aqueous compositions comprising a polycarboxylate ether in combination with at least one further grinding assistant selected from the group consisting of glycols, organic amines and ammonium salts of organic amines with carboxylic acids.
- Suitable glycols, organic amines and ammonium salts of organic amines with carboxylic acids are monoethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, pentaethylene glycol, polyethylene glycol, especially with 6 or more ethylene units, e.g. PEG 200, neopentyl glycol, hexylene glycol, propylene glycol, dipropylene glycol,
- Polypropylene glycol monoethanolamine, diethanolamine, triethanolamine (TEA), diethanolisopropanolamine, ethanol diisopropanolamine, isopropanolamine,
- the aqueous composition containing a polycarboxylate ether together with one or more specific additives is used as a cement grinding aid, wherein the one or more additives are contained in the aqueous composition are used as a separate component together with the aqueous composition.
- an aqueous composition containing at least one polycarboxylate in combination with one or more additives is, in this case, the aqueous composition and the one or more Admixtures are present separately and during or preferably before the grinding of the clinker or cement separately from each other to the clinker or cement are added.
- the additive is selected from 1,3-propanediol, a carboxylic acid, a sulphonated aminoalcohol, boric acid, a salt of boric acid, a salt of phosphoric acid, sorbitol, a saccharide, a gluconate, iron sulphate, tin sulphate, an antimony salt, an alkali salt, an alkaline earth salt .
- the carboxylic acid is preferably selected from formic acid, acetic acid, propionic acid, lactic acid and citric acid.
- lignosulfonate includes the substances sodium lignosulfonate (CAS No. 8061-51-6), magnesium lignosulfonate (CAS No. 8061-54-9), calcium lignosulfonate (CAS No. 8061 -52-7).
- the cation is irrelevant to the efficacy in the present invention.
- the alkali or alkaline earth metal salt is preferably selected from alkali or alkaline earth halide, alkali or alkaline earth nitrate, alkali or Erdalkalinitrit and alkali or alkaline earth thiocyanate.
- alkali metal and alkaline earth metal halides are alkali metal and alkaline earth metal chlorides, alkali metal and alkaline earth fluorides, alkali metals and alkaline earth metal halides Alkaline earth bromides and alkali and alkaline earth metal iodides.
- suitable alkali and alkaline earth metals for these salts are Li, Na, K, Mg and Ca. Specific examples are calcium chloride, sodium chloride, sodium thiocyanate and sodium carbonate.
- Carbohydrates can be polysaccharides and oligosaccharides or sugars.
- An example of a gluconate is sodium gluconate.
- Iron sulphate, tin sulphate and antimony salts are also known as chromate (VI) reducing substances in cements.
- the aqueous composition may contain at least one further grinding aid or the aqueous composition and the additive or additives may be used in combination with at least one further grinding aid, wherein the further grinding aid is selected from the group consisting of glycols, polyols, organic Amines and ammonium salts of organic amines with carboxylic acids.
- suitable glycols organic amines and ammonium salts of organic amines with carboxylic acids have been mentioned above.
- Alkanolamines are particularly preferred as organic amines , especially trialkanolamines, preferably triisopropanolamine (TIPA) or triethanolamine (TEA).
- the aqueous composition preferably contains, in addition to the polycarboxylate ether, the additive (s) and at least one grinding assistant selected from the group consisting of glycols, organic amines and ammonium salts of organic amines with carboxylic acids.
- the additive (s) and the at least one grinding assistant may be present in each case as a separate component
- for the aqueous composition to contain the additive (s) and for the at least one grinding aid to be present as a separate component the aqueous composition contains the at least one grinding assistant and the additive or additives are present as a separate component.
- the aqueous composition contains the at least one grinding assistant and the additive or additives are present as a separate component.
- the further grinding aid is an alkanolamine and the additive is a carboxylic acid or a retarder selected from boric acid, a salt of boric acid, a salt of phosphoric acid, sorbitol, a saccharide and a gluconate, wherein the carboxylic acid or the retarder in the aqueous Composition is used or is used in combination with the aqueous composition, wherein the carboxylic acid or the retarder are preferably contained together with the alkanolamine in the aqueous composition.
- the aqueous composition may contain other ingredients. Examples of these are organic solvents or additives, as described in the
- aqueous composition is used in combination with the one or more
- Add additives and optionally the at least one additional grinding aid the clinker or cement before grinding and then ground to cement or finer cement, the or the additives and / or the optional further grinding aid are contained in the aqueous composition or added separately.
- the addition of the aqueous composition in combination with the additive (s) and optionally the at least one further grinding aid may also be carried out during the milling process. However, it is preferred to add before grinding.
- the addition may be before, during or after the addition of gypsum and optionally other additives, such as lime, blast furnace slag, fly ash or pozzolans.
- the aqueous composition can also be used for grinding cement or producing mixed cements. For the latter, individual cements, each separately prepared by grinding with the aqueous composition, may be mixed or a mixture of several cement clinkers is milled with the aqueous composition to obtain a blended cement.
- the use according to the invention of the aqueous composition in combination with the one or more additives is well suited as a cement grinding aid. It can thus be made of clinker various cements or mowing such cements, such as those classified according to DIN EN 197-1 cements such as CEM I (Portland cement), CEM II, CEM III (blast furnace cement), CEM IV and CEM V. Preferred is CEM II
- the aqueous composition is preferably metered into the clinker or cement in such a way that the proportion of the polycarboxylate ether is 0.001-1.5% by weight, in particular 0.005-0.2% by weight, preferably 0.005-0.1% by weight, based on the clinker to be ground or the cement to be ground.
- the milling process usually takes place in a cement mill. However, it is also possible to use other mills, as are known, for example, in the cement industry. Depending on the grinding time, the cement has different fineness. The fineness of cement is typically given by Blaine in cm 2 / g. On the other hand, the fineness of the particle size distribution is also of practical relevance. Such particle size analyzes are usually determined by laser granulometry or air jet sieves.
- composition in combination with the one or more
- Adjuvants may be added to the meal to achieve the desired fineness, e.g. the Blaine fineness, be reduced. By the thereby reduced
- cement grinding aid is obtained, which combines the advantages of polycarboxylate ethers and additives and reduces their disadvantages or even disappears.
- the cement thus produced can also have a greatly reduced water requirement and excellent early strength, curing properties and a large slump.
- ground cement like any other milled cement, has a wide application, e.g. in concrete, mortar, potting compounds, injections or cleaning.
- polycarboxylate ether If larger amounts of polycarboxylate ether are added to the cement during or before the clinker is ground, then, after it has been mixed with water, the condenser properties known from polycarboxylate ethers are present seen.
- this amount is 0.2 to 1.5% by weight of polycarboxylate ether with respect to the cement.
- the fineness was determined by the air permeability method (Blaine) according to EN 196 by Blaine Automat from Wasag Chemie.
- polycarboxylate ethers As polycarboxylate ethers, commercial polycarboxlate ethers (PCE) have been used, as described, for example, in US Pat. as products for concrete admixtures from Sika
- the cement was ground in a closed laboratory ball mill (so-called batch mill).
- the additives were added to the mill before starting the grinding with the usual dosage for cement additives.
- the cement in the example given here has a composition corresponding to one
- CEM II, CEM III, CEM IV or CEM V can be treated in analogous manner with corresponding results.
- Milling tests were carried out without additive, only with polycarboxylate ether, only with additives and with mixtures of polycarboxylate ether and additives in a weight ratio of 1: 1 according to Table 1 and determines the fineness of the cements obtained.
- the total active ingredient content of all aqueous solutions tested was identical.
- the additives were added to the mill before starting the grinding with the usual dosage for cement additives.
- the cement in the example given here has a composition corresponding to one
- the cement was ground in a closed laboratory ball mill (so-called batch mill).
- the additives were added to the mill before starting the grinding with the usual dosage for cement additives.
- the cement in the example given here has a composition corresponding to one
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- Health & Medical Sciences (AREA)
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Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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EP14708058.4A EP2970029A1 (fr) | 2013-03-13 | 2014-03-06 | Utilisation d'éthers de polycarboxylates en combinaison avec d'autres additifs pour le broyage de ciment |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP13159010 | 2013-03-13 | ||
PCT/EP2014/054354 WO2014139857A1 (fr) | 2013-03-13 | 2014-03-06 | Utilisation d'éthers de polycarboxylates en combinaison avec d'autres additifs pour le broyage de ciment |
EP14708058.4A EP2970029A1 (fr) | 2013-03-13 | 2014-03-06 | Utilisation d'éthers de polycarboxylates en combinaison avec d'autres additifs pour le broyage de ciment |
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EP2970029A1 true EP2970029A1 (fr) | 2016-01-20 |
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EP14708058.4A Withdrawn EP2970029A1 (fr) | 2013-03-13 | 2014-03-06 | Utilisation d'éthers de polycarboxylates en combinaison avec d'autres additifs pour le broyage de ciment |
Country Status (9)
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US (1) | US20160024307A1 (fr) |
EP (1) | EP2970029A1 (fr) |
JP (1) | JP2016516652A (fr) |
CN (1) | CN105189410A (fr) |
BR (1) | BR112015022562A2 (fr) |
CA (1) | CA2904811A1 (fr) |
MX (1) | MX2015012221A (fr) |
RU (1) | RU2690592C2 (fr) |
WO (1) | WO2014139857A1 (fr) |
Families Citing this family (16)
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---|---|---|---|---|
CN104529233A (zh) * | 2014-12-05 | 2015-04-22 | 惠州市富力新技术有限公司 | 一种新型复合水泥助磨剂 |
WO2017067872A1 (fr) | 2015-10-21 | 2017-04-27 | Sika Technology Ag | Additif pour le post-traitement interne de compositions de liant minéral |
CN106810101B (zh) * | 2015-12-01 | 2019-03-01 | 济南大学 | 氧化石墨烯增强型水泥助磨剂的制备方法 |
RU2635420C1 (ru) * | 2016-08-04 | 2017-11-13 | Вячеслав Николаевич Попов | Пластифицирующая добавка для строительных растворов |
KR101773597B1 (ko) * | 2017-04-13 | 2017-08-31 | 주식회사 한화건설 | 고로슬래그 미분말용 액상 혼화제 조성물 |
CN107473616B (zh) * | 2017-09-13 | 2019-12-06 | 江西银杉白水泥股份有限公司 | 一种水泥助磨剂及其制备方法 |
MX2020005910A (es) * | 2017-12-07 | 2020-10-22 | Construction Research & Technology Gmbh | Una composicion dispersante. |
FR3087196B1 (fr) * | 2018-10-10 | 2022-08-05 | Chryso | Procede d'utilisation d'alcanolamine dans un broyeur |
CN109704626B (zh) * | 2019-01-07 | 2021-04-02 | 湖南辰砾新材料有限公司 | 有机氟改性二醇胺取代的聚羧酸水泥助磨剂及其制备方法 |
CN110804167B (zh) * | 2019-11-25 | 2022-06-10 | 江苏金木土科技有限公司 | 一种水泥助磨剂的制备方法 |
CN110790527B (zh) * | 2019-11-25 | 2021-12-31 | 江苏金木土新材料有限公司 | 一种矿渣用助磨剂的制备方法 |
EP3872049A1 (fr) * | 2020-02-25 | 2021-09-01 | Sika Technology AG | Moyen d'aide au processus et son utilisation dans un procédé d'extraction d'agrégats et/ou de matière minérale pulvérulente |
CN112174570B (zh) * | 2020-10-10 | 2022-05-03 | 江苏润天建材有限公司 | 一种环保型水泥助磨剂及制备方法 |
WO2022262985A1 (fr) | 2021-06-17 | 2022-12-22 | Cemex Innovation Holding Ag | Polycarboxylate robuste avec liaison de chaîne latérale sacrificielle à base d'oxyde de polyalkylène en tant qu'auxiliaire de broyage pour des matériaux cimentaires |
CN115057637B (zh) * | 2022-05-26 | 2024-01-09 | 昌德新材科技股份有限公司 | 一种水泥助磨剂及其应用 |
CN116477869A (zh) * | 2023-04-04 | 2023-07-25 | 南京永能新材料有限公司 | 一种水泥立磨助磨剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2298833A1 (fr) * | 2009-09-22 | 2011-03-23 | Sika Technology AG | Complexants de fer (III) pour la stabilisation de polymères en peigne dans des liants minéraux |
WO2011069919A1 (fr) * | 2009-12-08 | 2011-06-16 | Sika Technology Ag | Adjuvant pour liants minéraux à potentiel réduit de coloration en brun |
WO2013092763A1 (fr) * | 2011-12-22 | 2013-06-27 | Sika Technology Ag | Augmentation de l'efficacité de dispositifs de séparation de particules solides par taille |
WO2013150145A1 (fr) * | 2012-04-05 | 2013-10-10 | Chryso | Adjuvant pour compositions hydrauliques |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3615785A (en) * | 1968-02-02 | 1971-10-26 | West Virginia Pulp & Paper Co | Cement grinding aid and pack set inhibitor |
NZ187622A (en) * | 1977-07-01 | 1980-08-26 | Ici Australia Ltd | Asbestos cementitious compositions |
US6258161B1 (en) * | 1998-11-04 | 2001-07-10 | W. R. Grace & Co.-Conn. | Masonry blocks and masonry concrete admixture for improved freeze-thaw durability |
ATE353860T1 (de) * | 1999-06-15 | 2007-03-15 | Grace W R & Co | Früh hochfester zement und additive und verfahren zur herstellung desselben |
US6238448B1 (en) * | 1999-08-16 | 2001-05-29 | R & D Technology, Inc. | Grinding stones |
US6641661B1 (en) * | 2000-05-26 | 2003-11-04 | W. R. Grace & Co.-Conn. | High early strength cement and additives and methods for making the same |
US6800129B2 (en) * | 2003-01-30 | 2004-10-05 | W. R. Grace & Co.-Conn. | High solids pumpable cement additives |
EP2239240A1 (fr) * | 2004-06-21 | 2010-10-13 | Sika Technology AG | Moyen d'aide pour le broyage de ciment |
US7232483B2 (en) * | 2005-02-01 | 2007-06-19 | W. R. Grace & Co.-Conn. | Cement composition having chromium reducer |
WO2006132762A2 (fr) * | 2005-06-02 | 2006-12-14 | W.R. Grace & Co.-Conn. | Agents de mouture derives de la biomasse |
EP1923370A1 (fr) * | 2006-11-02 | 2008-05-21 | Mapei S.p.A. | Additifs et procédés pour la réduction de chrome hexavalent dans le ciment et dans les matériaux à base de ciment |
EP2298710A1 (fr) * | 2009-09-21 | 2011-03-23 | Sika Technology AG | Additif pour liant minéral |
EP2527307A1 (fr) * | 2011-05-26 | 2012-11-28 | Sika Technology AG | Dialkanolamine comme additif pour le broyage de matières solides |
CN102531446B (zh) * | 2011-11-15 | 2013-01-16 | 广东中匠工程建设有限公司 | 一种用于市政工程及高层建筑的水泥添加剂 |
-
2014
- 2014-03-06 CN CN201480013902.7A patent/CN105189410A/zh active Pending
- 2014-03-06 RU RU2015130749A patent/RU2690592C2/ru active
- 2014-03-06 MX MX2015012221A patent/MX2015012221A/es unknown
- 2014-03-06 JP JP2015562029A patent/JP2016516652A/ja active Pending
- 2014-03-06 BR BR112015022562A patent/BR112015022562A2/pt not_active Application Discontinuation
- 2014-03-06 WO PCT/EP2014/054354 patent/WO2014139857A1/fr active Application Filing
- 2014-03-06 US US14/773,446 patent/US20160024307A1/en not_active Abandoned
- 2014-03-06 CA CA2904811A patent/CA2904811A1/fr not_active Abandoned
- 2014-03-06 EP EP14708058.4A patent/EP2970029A1/fr not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2298833A1 (fr) * | 2009-09-22 | 2011-03-23 | Sika Technology AG | Complexants de fer (III) pour la stabilisation de polymères en peigne dans des liants minéraux |
WO2011069919A1 (fr) * | 2009-12-08 | 2011-06-16 | Sika Technology Ag | Adjuvant pour liants minéraux à potentiel réduit de coloration en brun |
WO2013092763A1 (fr) * | 2011-12-22 | 2013-06-27 | Sika Technology Ag | Augmentation de l'efficacité de dispositifs de séparation de particules solides par taille |
WO2013150145A1 (fr) * | 2012-04-05 | 2013-10-10 | Chryso | Adjuvant pour compositions hydrauliques |
Non-Patent Citations (1)
Title |
---|
See also references of WO2014139857A1 * |
Also Published As
Publication number | Publication date |
---|---|
CA2904811A1 (fr) | 2014-09-18 |
WO2014139857A1 (fr) | 2014-09-18 |
US20160024307A1 (en) | 2016-01-28 |
JP2016516652A (ja) | 2016-06-09 |
CN105189410A (zh) | 2015-12-23 |
RU2690592C2 (ru) | 2019-06-04 |
BR112015022562A2 (pt) | 2017-07-18 |
RU2015130749A (ru) | 2017-04-19 |
MX2015012221A (es) | 2016-04-15 |
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