EP2906350A2 - Procédé de regazéification de gaz cryogénique - Google Patents
Procédé de regazéification de gaz cryogéniqueInfo
- Publication number
- EP2906350A2 EP2906350A2 EP13774779.6A EP13774779A EP2906350A2 EP 2906350 A2 EP2906350 A2 EP 2906350A2 EP 13774779 A EP13774779 A EP 13774779A EP 2906350 A2 EP2906350 A2 EP 2906350A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- tank
- gas
- evaporator
- pressure
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/06—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with compressed gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
- F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
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- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0147—Shape complex
- F17C2201/0166—Shape complex divided in several chambers
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0147—Shape complex
- F17C2201/0171—Shape complex comprising a communication hole between chambers
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/03—Orientation
- F17C2201/032—Orientation with substantially vertical main axis
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- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
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- F17C2201/052—Size large (>1000 m3)
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- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
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- F17C2201/054—Size medium (>1 m3)
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- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
- F17C2205/0326—Valves electrically actuated
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- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0341—Filters
- F17C2205/0344—Sinter type
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- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0352—Pipes
- F17C2205/0367—Arrangements in parallel
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- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0169—Liquefied gas, e.g. LPG, GPL subcooled
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/033—Small pressure, e.g. for liquefied gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/04—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
- F17C2223/041—Stratification
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- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/04—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
- F17C2223/042—Localisation of the removal point
- F17C2223/046—Localisation of the removal point in the liquid
- F17C2223/047—Localisation of the removal point in the liquid with a dip tube
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- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
- F17C2225/0107—Single phase
- F17C2225/0123—Single phase gaseous, e.g. CNG, GNC
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
- F17C2225/036—Very high pressure, i.e. above 80 bars
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0107—Propulsion of the fluid by pressurising the ullage
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0121—Propulsion of the fluid by gravity
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- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
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- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
- F17C2227/0306—Heat exchange with the fluid by heating using the same fluid
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
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- F17C2227/0302—Heat exchange with the fluid by heating
- F17C2227/0309—Heat exchange with the fluid by heating using another fluid
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- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
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- F17C2227/0339—Heat exchange with the fluid by cooling using the same fluid
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- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
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- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
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- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
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- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
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- F17C2260/00—Purposes of gas storage and gas handling
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- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/05—Regasification
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- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0134—Applications for fluid transport or storage placed above the ground
- F17C2270/0136—Terminals
Definitions
- the invention relates to a process for the regasification of cryogenic liquefied.
- Gas in which a part of the located in an isolated tank cryogenic liquefied gas is spent by the tank in an insulated Dosier Boulevard, the Dosier1:00 is separated from the tank and a metered amount of cryogenic liquefied gas is then fed by activation of an evaporator circuit an evaporator, whereupon at the same time or subsequently the vaporized gas is filled into a high-pressure gas storage or fed into a mains network, whereupon the evaporator is separated from the metering, the pressure degraded in Dosier Boulevard and the dispenser is filled again with liquefied gas from the tank.
- the invention further relates to a device for regasification of cryogenic liquefied gas comprising an insulated tank, an insulated dosing tank connected to the tank via at least one connecting line, an evaporator connected to the dosing tank via at least one connecting line and a return line and one connected to the evaporator High-pressure accumulator or connected to the evaporator line of a pipeline network, wherein the at least one connecting line between the tank and the Dosier immediately having at least one connecting line and the return line between the Dosier acids and the evaporator each have a shut-off valve.
- WO 2011/009149 AI A method and a device of the type mentioned above, with which a piston-free compression of gases is possible, are known from WO 2011/009149 AI.
- WO 2011/009149 AI are two or more Strands connected in parallel, being pressed with the pressure of one strand of the dosing memory for the filling of the other strand, especially the evaporator, empty.
- the liquid enters the dosing tank downstream air evaporator, ie the liquid must be pressed against the pressure located in the evaporator in this.
- the pressure in the dosing tank must be reduced before refilling the dosing tank with liquefied gas by releasing it through a throttle into the gas space of the tank.
- the present invention aims to avoid the disadvantages of the prior art.
- the method of the type mentioned ge ⁇ called is essentially carried out in such a way that the pressure in the dispenser is reduced by the fact that the gas contained in the dispenser is fed through a heat exchanger in which cooled the gas and / or partially condensed is wherein, preferably, the condensate formed in the heat exchanger and the cooled gas having the remaining gas pressure are forced into the tank, and the cooled gas having the remaining gas pressure is passed into the tank, and the cooled gas is condensed in the part of the tank containing the liquefied gas.
- the gas located in the metering memory is thus cooled in the heat exchanger and, if possible, at least partially condensed, whereby a part of the energy of the pressurized gas is first discharged outside the tank, whereupon the remaining part of the energy can be delivered to the liquid in the tank and released to tank pressure.
- the gas pressure in the heat exchanger is condensed in the liquid phase of the tank. This eliminates the need to blow off the gas in the gas space of the tank from time to time and thereby lose gas.
- the heat exchanger is located outside the tank, the condenser inside the tank.
- the product leaving the condenser mixes in the outlet area of the condenser with the liquefied gas in the tank.
- the condenser it inevitably comes to the condensation of the supplied gas from the heat exchanger, wherein the cooling medium is the liquid of the tank.
- the heat exchanger liquid gas is supplied from the Dosier immediately as a cooling medium and the heated in the heat exchanger or evaporated cooling medium is supplied to the evaporator for the purpose of further energy absorption.
- the heat exchanger has at least one gas-carrying pipe, in which the cooling of the gas takes place, so that a condensation is possible.
- the condenser preferably comprises at least one line extending in the interior of the tank, in particular a cooling coil, through which gas and condensate flow out of the heat exchanger.
- a particularly economical process management is made possible when the liquefied gas is preferably filled under the geodetic pressure in the dosing.
- you can the required pressure difference can also be applied or supported by a circulating pump.
- the filling of the metering reservoir advantageously comprises the production of a pressure equalization between the tank and the metering reservoir.
- the aim is to fill the heat exchanger with - to be evaporated cooling medium, so that this can cool the gas in the dispenser before relaxation in the subsequent process of pressure equalization. If the dosing tank is now connected to the evaporator, the product flow is conducted into the heat exchanger by the geodetic pressure, which is "flooded", the overflowing product passes into the evaporator and is completely transferred to the gas phase, which evaporates through the heat exchange in the heat exchanger Product is replaced by product flowing out of the dosing tank and the excess product flows to the evaporator for evaporation.
- dispenser is separated from the evaporator and its pressure is released into the tank.
- gas of Dosier Itemss is passed through the heat exchanger and the condenser in the tank. There is a pressure equalization and the dispenser can be filled again.
- the procedure is preferably such that the pressure in the tank is kept below the permissible operating pressure of the tank, in particular less than 15 bar, so that it is ensured that the tank can not blow off.
- the cooling and condensation of the supplied from the heat exchanger product in the tank usually has a slight warming of the liquid phase in the tank result, so that it can lead to an increase in pressure in the tank.
- the procedure is preferably such that filling of the dosing tank takes place via one of at least two connecting lines opening out at different levels within the tank, the removal of the cryogenic liquefied gas the tank is via the highest-opening connecting line, which allows the falling level of the tank respectively.
- a preferred procedure provides that the evaporation takes place with the enthalpy of the air.
- a portion of the dispenser connecting the dispenser with the evaporator connecting line forms a coolant line of an insulated heat exchanger, the coming of the Dosier Eat gas whose cooling and / or partial condensation can be flowed through and which is connected to a capacitor arranged in the tank.
- the condenser preferably comprises at least one line running in the interior of the tank, in particular a cooling coil, through which gas can flow from the metering tank.
- the at least one line and its outlet mouth are preferably surrounded by a pipe arranged in the tank.
- the tube serves to separate the liquid phase heated by the condenser from the remaining liquid phase of the tank.
- a preferred development of the device according to the invention provides in this connection that at least two connecting lines connecting the tank to the metering reservoir open into the tank at different heights.
- the connecting lines open inside the tube in the tank.
- the liquid feed is arranged deeper into the metering reservoir than the liquid outlet from the tank. It is also possible to arrange the heat exchanger and the evaporator inlet lower than the dispenser. The feed can also be done by a supporting circulation pump.
- the Dosier immediately is connected via a gas return line to the gas space of the tank, whereby a pressure equalization between the Dosier réelle and the tank is made possible directly.
- the cryogenic part of the system which includes the tank, the dosing tank, the heat exchanger and the lines connecting the tank and the dosing, too minimize, provides a preferred development that the tank, the dosing, the heat exchanger and the tank connecting the dosing memory lines are thermally insulated.
- the evaporator is preferably not thermally insulated so that the ambient entropy can be used to vaporize the gas.
- the non-heat-insulated version of the evaporator has the disadvantage that the evaporator ices up, which isolates the evaporator, i. that the heat supply to the evaporator is reduced from the outside. In this regard, this can be remedied that the evaporator is increased. But this is only a time-delaying measure. Continuously, the next section of the evaporator will freeze, so that the only way is to prevent this icing by switching to another evaporator, which in turn significantly increases the cost of the plant.
- icing is preferably avoided by virtue of the evaporator having on its outside a coating which avoids this icing, e.g. a nanotechnology-based molecular structure.
- the surface of the evaporator can also be kept free from mechanical or chemical treatment steps of ice or other solidification products, wherein the mechanical variant is, for example, a scraping off and the chemical variant is the use of a thawing agent, so that the evaporator is in continuous operation can work.
- the mechanical variant is, for example, a scraping off
- the chemical variant is the use of a thawing agent
- liquefied gases are obtained by cooling and compression. Process
- thermal insulation cold and liquid e.g, liquid oxygen and liquid nitrogen.
- the boiling point of such gases is usually below -160 ° C at atmospheric pressure.
- LNG liquefied natural gas
- Another example is the so-called liquefied natural gas (LNG), which is liquefied natural gas gas by cooling to -164 to -161 ° C (109 K to 112 K) and about one-600th of the volume of natural gas having.
- Refrigerated liquefied gases are stored in heat-insulated tanks, so-called cryogenic containers.
- the reaching within the scope of the invention used tank as well as the dispenser and the heat exchanger are designed for example as a double-walled container, the space between the outer wall and the inner wall is evacuated.
- the inside of the inner wall is preferably provided with a reflective coating. It is also possible to place the dispenser, the valves and the pipes in an insulated container, so that evaporation is excluded or severely limited.
- a metered storage tank is preferably to be understood as meaning a heat-insulated storage tank whose volume is significantly lower than that of the tank.
- the volume of the Dosierurss corresponds to less than half, preferably less than a quarter of the volume of the tank.
- the heat exchanger absorbs the part of the liquid that is required for cooling or condensation of the product, depending on the process design.
- two circuits are connected in series, so that a line is built.
- the dosing circuit the product is stored at a relatively low pressure, for example 15 bar, in a tank.
- the amount of gas to be evaporated is portioned into the dispenser.
- the metering reservoir is preferably filled by the geodetic pressure. For this purpose, a pressure equalization between tank and dispenser can be made. This is done for example via a gas return line.
- the prerequisite is that the pressures in the tank and in the dosing tank are such that the inflow from the tank into the dosing tank is possible - the pressures must be the same in the respective gas phase. If this is not the case - for example, the pressure in the dispenser is always higher after the start of the process than in the tank - this pressure must be reduced. The pressure here is predominantly in the supercritical range.
- the gas returned from the metering reservoir to the tank is passed over the heat exchanger and cooled there.
- the heat exchanger is integrated with its coolant leading circuit in the evaporator circuit.
- the dosing circuit is completely isolated.
- the evaporation of the gas is only possible according to the unintentionally registered heat.
- the insulation is to the evaporation of the gas vermei ⁇ .
- the product is brought from the metering storage in the evaporator.
- the product first passes through the heat exchanger and floods it, so that a product exchange or product mixing takes place between existing, ie "warm” product and fresh, ie "cold” product.
- the evaporator is not insulated and should supply the evaporation and compression energy to the gas.
- the Energy should be removed from the environment or another free heat source. The supplied energy causes the state change.
- the evaporator is in the simplest case, a non-insulated, eg cylindrical container.
- the dispenser To bring the product from the dispenser into the evaporator, the dispenser must be separated from the tank and connected to the evaporator.
- the evaporator inlet is preferably located below the dispenser space. This allows the product to flow through the geodetic pressure into the evaporator. The inflow is made possible by opening or closing valves. This means that the high pressure of the evaporator is everywhere.
- the icing of the evaporator has a limited operating life result.
- the ice layer is removed mechanically in cycles or the preparation of the ice crystals avoided by a suitable coating of the evaporator Oberfizze.
- the tank 1, is stored in the cryogenic liquefied gas is designed as an insulated, preferably vacuum-insulated container.
- the minimum level in the tank 1 is positioned above the maximum level of the dispenser 2 so that the product can flow into the dispenser 2 at the geodetic pressure.
- the Dosier Treat 2 which is also designed as an insulated, preferably vacuum-insulated container is connected via a gas space side connected gas return line 3 with the Gas space of the tank 1 connected. In the gas return line 3, the check valve 4 is arranged.
- the dispenser is further connected via a gas space side connected, equipped with a check valve 29 connecting line 28 with a heat exchanger 14.
- the pressure equalization between the tank 1 and the dispenser 2 takes place.
- the dispenser 2 On the inlet side, the dispenser 2 is connected to the dispenser 2 via the bottom, connecting lines 5, 6 and 1 of different lengths to the tank 1 connected, the stepped in a capacitor 12 ends. If the tank 1 is filled, the longest connection line 5 is opened via the check valve 8. If the level has dropped, so that no supply can take place via the connecting line 5, the dosing storage 2 is filled via the next longer connecting line 6 or 7 by opening the check valves 9 and 10, respectively. This process continues until the tank 1 is emptied. With this cascading removal, the warmest product is always withdrawn first, so that the pressure increase in the tank 1 is slowed down.
- the check valves 8, 9 and 10 are provided for selectively blocking and opening the connecting lines 5, 6 and 7, the check valves 8, 9 and 10 are provided.
- the Dosier immediately 2 is further connected via a line 30 and a check valve 11 with the gas space of the tank 1 connected.
- the heat exchanger 14 has a coolant volume 32 and a volume 31 through which the gas to be cooled can flow.
- the volume 31 via the line 28 and the check valve 29 with the gas chamber side of the metering 2 ver ⁇ connected.
- the volume 31 is connected via the line 15 with a cooling coil 13 of a capacitor 12.
- the Coolant volume 32 of the heat exchanger 14 is connected on the one hand via the check valve 21 to the dispenser 2 and on the other hand to the evaporator 20.
- the condenser 12 is positioned, in the interior of which the cooling coil 13 is located, which is connected via a line 15 with the interposition of the heat exchanger 14 on the head side, ie to the gas space of Dosier Boulevards 2.
- the cooling coil 13 is preferably guided in the tank 1 from top to bottom, so that it is open at the lower end 16, so that there the remaining gas via a mixing nozzle or orifice (not shown) exits.
- a mixing nozzle ends in the "cold" liquid
- the condensation of the gas withdrawn from the metering reservoir 2 takes place in the condenser 12.
- the liquid phase of the tank 1 is used as the coolant, so that the temperature difference necessary for the heat transfer is ensured.
- the gas flows through the cooling coil 13 and it comes in her for further condensation, in which the heat of condensation is delivered to the surrounding liquid.
- the cooling coil 13 is surrounded by a tube 17 and thus forms the condenser 12.
- the condensate collects,
- the remaining gas phase exits via a nozzle and thereby entrains the condensate with it
- the proportion of gas is reduced by the mixed condensation ..
- the resulting "warm" liquid remains in the interior of the tube 17.
- the tube 17 extends up to in the gas space of the tank 1, so that there is no entry of the ext the liquid contained in the tube 17 comes.
- the bottom-side opening of the tube 17 is surrounded by another sieve-like tube 18, which prevents kal ⁇ te liquid flows from outside the tube 17 directly into the tube 17.
- the boundary between the dosing circuit described above and the evaporator circuit described below is indicated by the dashed line 19.
- the evaporator 20 is connected on the bottom side via a supply line 33 and a check valve 21 and at the outlet via a line 22 and a check valve 23 with the Dosiertechnisch 2.
- the feed line 33 of the evaporator 20 may be laid with a slight slope, wherein the evaporator 20 is placed in parts below the dispenser 2. This favors that the product can flow to the evaporator 20.
- the evaporator 20 is followed by the high pressure gas storage 24, which is a finite pressure accumulator, e.g. a pressure vessel store or an infinite pressure store, e.g. a pipeline can be.
- the goal is to fill both with high-pressure gas.
- the connecting line between the evaporator 20 and the high pressure accumulator 24 is denoted by 25 and arranged in this line 25 check valve 26.
- tank 1 has the lowest pressure, e.g. 10 bar.
- pressure between the tank pressure and the evaporator pressure changes.
- the evaporator 20 there is always the maximum possible pressure (for example above 200 bar). This is temporarily above the high-pressure accumulator pressure, which is the prerequisite for a memory filling can be done with it.
- the tank 1 is connected to the dosing tank 2 via the liquid flow and the gas return 30.
- one of the valves 8, 9 or 10, the valve 11 and the Valve 27 opened. It adjusts itself to a pressure equalization and the liquid flows to the desired level in the dispenser 2.
- the valve 8, 9 and 10 and the valve 27 are closed and the valves 21 and 23 are opened.
- the product first flows into the volume 32 of the heat exchanger 14 and thereafter, once the volume 32 has been flooded, into the evaporator 20, where the product is preferably supplied with the vaporization and compression energy from the ambient temperature.
- the valve 26 Upon reaching a pressure which is higher than that of the high-pressure gas reservoir 24, the valve 26 is opened so that pressure equalization takes place between the metering reservoir 2, the evaporator 20 and the high-pressure gas reservoir 24.
- valve 29 is opened, the supercritical product initially cools in the heat exchanger 14 and condenses, if necessary, partially condensed then on the walls of the condenser 12, which is surrounded by the "cold" product (max 18 bar) .
- the process is possible up to the boiling point
- the valve 29 is closed and the rest of the gas is opened by opening the valve 4 relaxed in the gas space of the tank 1.
Abstract
L'invention se rapporte à un procédé de regazéification de gaz cryogénique, consistant à transférer une fraction de gaz cryogénique contenu dans une cuve (1) de cette cuve (1) à un réservoir de dosage (2), à isoler le récipient de dosage (2) de la cuve (1), à amener une portion dosée du gaz cryogénique dans un évaporateur (20), et à introduire ensuite la portion de gaz vaporisé dans un réservoir de gaz à haute pression (24) ou dans un réseau de distribution, puis à isoler l'évaporateur (20) du réservoir de dosage (2), à réduire la pression dans le réservoir de dosage (2), et à remplir à nouveau le réservoir de dosage (2) avec du gaz liquéfié en provenance de la cuve (1). Selon le procédé de l'invention, on réduit la pression dans le réservoir de dosage (2) en faisant circuler le gaz se trouvant dans le réservoir de dosage (2) à travers un échangeur de chaleur (14) dans lequel le gaz est réfrigéré et/ou partiellement condensé, le condensat formé le cas échéant dans l'échangeur de chaleur, et le gaz réfrigéré étant acheminés avec la pression résiduelle dans la cuve (1), et le gaz refroidi est condensé dans la partie de la cuve (1) contenant le gaz liquéfié.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT2432012 | 2012-06-05 | ||
PCT/IB2013/001711 WO2013182907A2 (fr) | 2012-06-05 | 2013-08-05 | Procédé de regazéification de gaz cryogénique |
Publications (1)
Publication Number | Publication Date |
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EP2906350A2 true EP2906350A2 (fr) | 2015-08-19 |
Family
ID=49712763
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13774779.6A Withdrawn EP2906350A2 (fr) | 2012-06-05 | 2013-08-05 | Procédé de regazéification de gaz cryogénique |
Country Status (2)
Country | Link |
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EP (1) | EP2906350A2 (fr) |
WO (1) | WO2013182907A2 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT520662A1 (de) * | 2016-02-18 | 2019-06-15 | Sasu Energiesysteme Gmbh | Verfahren zum Regasifizieren von tiefkalt verflüssigtem Gas |
FR3123643B1 (fr) * | 2021-06-03 | 2024-03-08 | Air Liquide | Installation et procédé de stockage et de distribution de fluide |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL49146C (fr) * | 1935-03-01 | 1900-01-01 | ||
US3260061A (en) * | 1964-12-16 | 1966-07-12 | Lox Equip | Flow system for cryogenic materials |
FR2379018A1 (fr) * | 1976-12-23 | 1978-08-25 | Air Liquide | Procede et installation cryogeniques de distribution de gaz sous pression |
US5954101A (en) * | 1996-06-14 | 1999-09-21 | Mve, Inc. | Mobile delivery and storage system for cryogenic fluids |
US6595048B1 (en) * | 2000-08-04 | 2003-07-22 | Chart Inc. | Accurate cryogenic liquid dispenser |
EP1353112A1 (fr) * | 2002-04-10 | 2003-10-15 | Linde Aktiengesellschaft | Méthode de transfert de fluide cryogénique |
US6732536B1 (en) * | 2003-03-26 | 2004-05-11 | Praxair Technology, Inc. | Method for providing cooling to superconducting cable |
WO2010151107A1 (fr) * | 2009-06-25 | 2010-12-29 | Ballast Nedam International Product Management B.V. | Dispositif et procédé de distribution de gnl |
US20120159969A1 (en) * | 2009-07-22 | 2012-06-28 | Lo Solutions Gmbh | Method for charging evaporators with cryogenically liquefied gases, and a device for carrying out said method |
-
2013
- 2013-08-05 WO PCT/IB2013/001711 patent/WO2013182907A2/fr active Application Filing
- 2013-08-05 EP EP13774779.6A patent/EP2906350A2/fr not_active Withdrawn
Non-Patent Citations (1)
Title |
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See references of WO2013182907A3 * |
Also Published As
Publication number | Publication date |
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WO2013182907A2 (fr) | 2013-12-12 |
WO2013182907A3 (fr) | 2014-12-11 |
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