EP2897989A4 - Herstellung von vinylterminiertem polyethylen durch verwendung eines gestützten katalysatorsystems - Google Patents

Herstellung von vinylterminiertem polyethylen durch verwendung eines gestützten katalysatorsystems

Info

Publication number
EP2897989A4
EP2897989A4 EP13839330.1A EP13839330A EP2897989A4 EP 2897989 A4 EP2897989 A4 EP 2897989A4 EP 13839330 A EP13839330 A EP 13839330A EP 2897989 A4 EP2897989 A4 EP 2897989A4
Authority
EP
European Patent Office
Prior art keywords
production
catalyst system
supported catalyst
vinyl terminated
terminated polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13839330.1A
Other languages
English (en)
French (fr)
Other versions
EP2897989A1 (de
Inventor
Donna J Crowther
Patrick Brant
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to EP13839330.1A priority Critical patent/EP2897989A4/de
Publication of EP2897989A1 publication Critical patent/EP2897989A1/de
Publication of EP2897989A4 publication Critical patent/EP2897989A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
EP13839330.1A 2012-09-24 2013-09-23 Herstellung von vinylterminiertem polyethylen durch verwendung eines gestützten katalysatorsystems Withdrawn EP2897989A4 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP13839330.1A EP2897989A4 (de) 2012-09-24 2013-09-23 Herstellung von vinylterminiertem polyethylen durch verwendung eines gestützten katalysatorsystems

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201261704606P 2012-09-24 2012-09-24
EP12196838 2012-12-12
EP13839330.1A EP2897989A4 (de) 2012-09-24 2013-09-23 Herstellung von vinylterminiertem polyethylen durch verwendung eines gestützten katalysatorsystems
PCT/US2013/061140 WO2014047538A1 (en) 2012-09-24 2013-09-23 Production of vinyl terminated polyethylene using supported catalyst system

Publications (2)

Publication Number Publication Date
EP2897989A1 EP2897989A1 (de) 2015-07-29
EP2897989A4 true EP2897989A4 (de) 2016-05-04

Family

ID=47325959

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13839330.1A Withdrawn EP2897989A4 (de) 2012-09-24 2013-09-23 Herstellung von vinylterminiertem polyethylen durch verwendung eines gestützten katalysatorsystems

Country Status (3)

Country Link
EP (1) EP2897989A4 (de)
CN (1) CN104640889A (de)
WO (1) WO2014047538A1 (de)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5770664A (en) * 1994-10-13 1998-06-23 Japan Polyolefins Co., Ltd. Catalyst component for producing polyolefin, catalyst for producing polyolefin comprising the catalyst component, and process for producing polyolefin in the presence of the catalyst
US20050032992A1 (en) * 1996-07-16 2005-02-10 Floyd Joseph C. Olefin polymerization process with alkyl-substituted metallocenes
US20120200010A1 (en) * 2007-12-18 2012-08-09 Crowther Donna J Polyethylene and Process for Production Thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69033368T3 (de) * 1990-01-02 2008-07-03 Exxon Chemical Patents, Inc. Ionische Metallocenkatalysatoren auf Träger für Olefinpolymerisation
US6531555B2 (en) * 2000-12-19 2003-03-11 Univation Technologies, Llp Olefin oligomerization catalysts, their production and use
CA2499951C (en) * 2002-10-15 2013-05-28 Peijun Jiang Multiple catalyst system for olefin polymerization and polymers produced therefrom
CN101124235B (zh) * 2004-07-08 2010-12-15 埃克森美孚化学专利公司 烯烃聚合催化剂体系及其使用方法
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
ES2582396T3 (es) * 2009-06-29 2016-09-12 Chevron Phillips Chemical Company Lp Sistemas catalíticos duales de metaloceno para disminuir el índice de fluidez y aumentar la velocidad de producción de polímero

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5770664A (en) * 1994-10-13 1998-06-23 Japan Polyolefins Co., Ltd. Catalyst component for producing polyolefin, catalyst for producing polyolefin comprising the catalyst component, and process for producing polyolefin in the presence of the catalyst
US20050032992A1 (en) * 1996-07-16 2005-02-10 Floyd Joseph C. Olefin polymerization process with alkyl-substituted metallocenes
US20120200010A1 (en) * 2007-12-18 2012-08-09 Crowther Donna J Polyethylene and Process for Production Thereof

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
IMHOFF D W ET AL: "Characterization of methylaluminoxanes and determination of trimethylaluminium using proton NMR", ORGANOMETALLICS, AMERICAN CHEMICAL SOCIETY, US, vol. 17, 11 May 1998 (1998-05-11), pages 1941 - 1945, XP002234016, ISSN: 0276-7333, DOI: 10.1021/OM980046P *
See also references of WO2014047538A1 *
TURUNEN, J. ET AL: "Suppression of metallocene catalyst leaching by the removal of free trimethylaluminium from methylaluminoxane", JOURNAL OF APPLIED POLYMER SCIENCE, vol. 100, 2006, pages 4632 - 4635, XP002696362 *
VINCENZO BUSICO ET AL: "Hafnocenes and MAO: Beware of Trimethylaluminum!", MACROMOLECULES,, vol. 42, no. 6, 24 March 2009 (2009-03-24), pages 1789 - 1791, XP002653530 *

Also Published As

Publication number Publication date
WO2014047538A1 (en) 2014-03-27
CN104640889A (zh) 2015-05-20
EP2897989A1 (de) 2015-07-29

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