EP2881179A1 - Dispositif de pulvérisation électrostatique - Google Patents

Dispositif de pulvérisation électrostatique Download PDF

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Publication number
EP2881179A1
EP2881179A1 EP13826305.8A EP13826305A EP2881179A1 EP 2881179 A1 EP2881179 A1 EP 2881179A1 EP 13826305 A EP13826305 A EP 13826305A EP 2881179 A1 EP2881179 A1 EP 2881179A1
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EP
European Patent Office
Prior art keywords
opening
electrode
electrostatic atomizing
atomizing device
spray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP13826305.8A
Other languages
German (de)
English (en)
Other versions
EP2881179A4 (fr
Inventor
Van Thanh DAU
Tibor TEREBESSY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of EP2881179A1 publication Critical patent/EP2881179A1/fr
Publication of EP2881179A4 publication Critical patent/EP2881179A4/fr
Withdrawn legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
    • B05B5/03—Discharge apparatus, e.g. electrostatic spray guns characterised by the use of gas, e.g. electrostatically assisted pneumatic spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
    • B05B5/053—Arrangements for supplying power, e.g. charging power
    • B05B5/0533—Electrodes specially adapted therefor; Arrangements of electrodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • B05B15/50—Arrangements for cleaning; Arrangements for preventing deposits, drying-out or blockage; Arrangements for detecting improper discharge caused by the presence of foreign matter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/16—Arrangements for supplying liquids or other fluent material
    • B05B5/1691—Apparatus to be carried on or by a person or with a container fixed to the discharge device

Definitions

  • the present invention relates to an electrostatic atomizing device which allows a reduction in ratio in which an atomized substance adheres to a device surface of the electrostatic atomizing device.
  • An atomizing device which sprays a liquid in a container via a nozzle has been widely used in various fields.
  • a known example of such an atomizing device is an electrostatic atomizing device which atomizes and sprays a liquid by Electro Hydrodynamics (EHD).
  • the electrostatic atomizing device forms an electric field near a tip of a nozzle and uses the electric field to atomize and spray the liquid at the tip of the nozzle.
  • Patent Literature 1 is known as a document which discloses such an electrostatic atomizing device.
  • Patent Literature 1 Japanese Translation of PCT International Application, Tokuhyo, No. 2004-530552 (Publication Date: October 7, 2004 )
  • an electrostatic atomizing device is configured such that an electric field is formed between two electrodes (a pin and a capillary) by application of a voltage across the electrodes.
  • the electric field is oriented in a direction in which a pin extends, and thus an atomized substance is easily atomized in the direction in which the pin extends, i.e., in a direction to the electrostatic atomizing device (hereinafter, this phenomenon is referred to as a spray-back).
  • the electrostatic atomizing device whose device surface is wet by the spray-back causes a hand of a user with which hand the electrostatic atomizing device is being held to be wet.
  • the electrostatic atomizing device is sometimes used for, for example, atomization of aromatic oil, a chemical substance for an agricultural product, a medicine, an agricultural chemical, a pesticide, and an air cleaning agent.
  • the spray-back to the device surface is preferably smaller.
  • Patent Literature 1 does not refer to prevention of the spray-back to the device surface.
  • the present invention has been made in view of the problem, and an object of the present invention is to provide an electrostatic atomizing device which allows a reduction in ratio in which an atomized substance adheres to a device surface of the electrostatic atomizing device.
  • an electrostatic atomizing device of the present invention includes: a first electrode and a second electrode across which and the first electrode a voltage is applied, the first electrode for atomizing a substance from a tip thereof, the second electrode being provided near the first electrode, the first electrode and the second electrode being provided in a first opening and a second opening which are provided on a first device surface of device surfaces of the electrostatic atomizing device, respectively, and the second opening being provided so as to reduce a ratio in which the atomized substance adheres to the first device surface.
  • the first electrode is provided near the second electrode.
  • the first electrode and the second electrode are provided in the first opening and the second opening, respectively, which are provided on the device surface.
  • the voltage is applied across the first electrode and the second electrode, so that an electric field is formed between the first and second electrodes.
  • the first electrode atomizes a positively charged (or negatively charged) droplet.
  • the second electrode ionizes and negatively charges (or positively charges) air near the second electrode.
  • the negatively charged air moves so as to be away from the second electrode due to the electric field formed between the first and second electrodes and a repulsive force among particles of the negatively charged air.
  • the movement causes a flow of air (hereinafter, the flow may be referred to as an ion stream), and the positively charged droplet is atomized by the ion stream in a direction in which the droplet is away from the electrostatic atomizing device.
  • the electric field is oriented in a direction in which the second electrode extends. Therefore, a substance normally is atomized in the direction in which the second electrode extends, i.e., in a direction to the electrostatic atomizing device, so that the atomized substance easily adheres to the device surface (hereinafter, this phenomenon may be referred to as a spray-back).
  • the second opening is provided so that a ratio in which the atomized substance adheres to the device surface may be reduced.
  • a shape and a size and the like of the second opening are appropriately adjusted, so that the ratio in which the atomized substance adheres to the device surface is reduced.
  • an electric charge amount of the droplet and a size of the droplet are controllable by use of a change in strength of the ion stream by a change in shape and size of the second opening.
  • the electric charge amount of the droplet and the size of the droplet serve as important factors in determination of an effect of the atomized substance which effect is yielded in use of the electrostatic atomizing device.
  • the electrostatic atomizing device of the present invention yields an effect of preventing the spray-back and realizing atomization suitable for a purpose of use by controlling the electric charge amount of the droplet and the size of the droplet.
  • the electrostatic atomizing device of the present invention is configured such that the first electrode and the second electrode are provided in a first opening and a second opening, respectively, which are provided on a first device surface of device surfaces of the electrostatic atomizing device, and the second opening is provided so as to reduce a ratio in which the atomized substance adheres to the first device surface.
  • the electrostatic atomizing device of the present invention yields an effect of reducing the ratio in which the atomized substance adheres to the device surface.
  • Fig. 2 illustrates the configuration of the main part of the electrostatic atomizing device 100.
  • the electrostatic atomizing device 100 is used for, for example, atomization of aromatic oil, a chemical substance for an agricultural product, a medicine, an agricultural chemical, a pesticide, and an air cleaning agent and the like.
  • the electrostatic atomizing device 100 includes at least a spray electrode 1 (a first electrode), a reference electrode 2 (a second electrode), a power supply device 3, and a dielectric 10.
  • the electrostatic atomizing device 100 may be configured such that the power supply device 3 is provided on an outside of the electrostatic atomizing device 100 and the electrostatic atomizing device 100 is connected with the power supply device 3.
  • the spray electrode 1 includes a conductive conduit such as a metallic capillary (e.g., type 304 stainless steel) and a spray part which is a tip of the spray electrode 1.
  • the spray electrode 1 is connected with the reference electrode 2 via the power supply device 3 and its spray part atomizes a substance to be atomized. Note that the following description simply refers to the substance to be atomized as a "liquid.”
  • the reference electrode 2 is made of a conductive rod such as a metal pin (e.g., type 304 steel pin).
  • the spray electrode 1 and the reference electrode 2 are provided in parallel with each other with a prescribed distance therebetween.
  • the spray electrode 1 and the reference electrode 2 are provided with a distance of, for example, 8 mm therebetween.
  • the power supply device 3 applies a high voltage across the spray electrode 1 and the reference electrode 2.
  • the power supply device 3 applies a high voltage of 1 kV to 30 kV (e.g., 3-7 kV) across the spray electrode 1 and the reference electrode 2.
  • the application of a high voltage forms an electric field between the electrodes. This causes an electric dipole inside the dielectric 10.
  • the spray electrode 1 is positively charged, and the reference electrode 2 is negatively charged (alternatively, the spray electrode 1 may be negatively charged, and the reference electrode 2 may be positively charged).
  • a negative dipole occurs on a surface of the dielectric 10 which surface is closest to the positively-charged spray electrode 1
  • a positive dipole occurs on a surface of the dielectric 10 which surface is closest to the negatively-charged reference electrode 2, so that a charged gas and a charged substance species are released by the spray electrode 1 and the reference electrode 2.
  • the dielectric 10 is made of a dielectric material such as nylon 6, nylon 11, nylon 12, polypropylene, nylon 66, or a polyacetyl-polytetrafluoroethylene mixture.
  • the dielectric 10 supports the spray electrode 1 at a spray electrode fixing part 6 and supports the reference electrode 2 at a spray electrode fixing part 7.
  • Fig. 3 illustrates the appearance of the electrostatic atomizing device 100.
  • the electrostatic atomizing device 100 is rectangular (or may have another shape).
  • the spray electrode 1 and the reference electrode 2 are provided on a surface of the electrostatic atomizing device 100.
  • the spray electrode 1 is provided near the reference electrode 2.
  • a circular opening 11 and a circular opening 12 are provided so as to surround the spray electrode 1 and the reference electrode 2, respectively.
  • a voltage is applied across the spray electrode 1 and the reference electrode 2, so that an electric field is formed.
  • the spray electrode 1 atomizes a positively charged droplet.
  • the reference electrode 2 ionizes and negatively charges air near the reference electrode 2.
  • the negatively charged air moves so as to be away from the reference electrode 2 due to the electric field formed between the spray electrode 1 and the reference electrode 2 and a repulsive force among particles of the negatively charged air.
  • the movement causes a flow of air (hereinafter, the flow may be referred to as an ion stream), and the positively charged droplet is atomized by the ion stream in a direction in which the droplet is away from the electrostatic atomizing device 100.
  • the electrostatic atomizing device 100 is configured such that an electric field is formed between the spray electrode 1 and the reference electrode 2 by application of a voltage across the electrodes.
  • the electric field is oriented in a direction in which a pin extends. Therefore, an atomized liquid is easily atomized in the direction in which the pin extends, i.e., in a direction to the electrostatic atomizing device 100, so that the atomized liquid adheres to a device surface of the electrostatic atomizing device 100 (hereinafter, this phenomenon is referred to as a spray-back).
  • An ion stream is generated from the reference electrode 2 by application of a voltage across the spray electrode 1 and the reference electrode 2.
  • the generation of the ion stream causes a reduction in air pressure around the reference electrode 2.
  • the ion stream and inflow air are mixed to cause the ion stream to be a turbulent flow.
  • This turbulent flow may be a cause of the spray-back.
  • inventors of the present application consider that the spray-back can be prevented by changing a diameter and a shape of the opening 12 around the reference electrode 2.
  • the reference electrode 2 having a tip with a diameter of less than 0.1 mm and a body with a diameter of 0.5 mm is used.
  • the tip of the reference electrode 2 is preferably sharp, so that negatively charged air easily occurs.
  • Fig. 4 is a front view of the electrostatic atomizing device 100 having the opening 12 with the increased diameter.
  • the ion stream is weakened in a case where the opening 12 has the increased diameter.
  • a droplet is less likely to be atomized from the electrostatic atomizing device 100, so that the spray-back easily occurs.
  • the diameter of the opening 12 can be increased.
  • the confirmation reveals that the ion stream is weakened in a case where the opening 12 has a diameter which is 25 times or more the diameter of the body of the reference electrode 2, or 150 times or more the diameter of the tip of the reference electrode 2, so that inflow air easily flows into the opening 12 via an end of the opening 12. Flow of air into the opening 12 easily causes the ion stream be a turbulent flow. This makes it possible to say that the spray-back is highly likely to occur.
  • the spray-back can be less likely to occur by causing the diameter of the opening 12 to be smaller than at least either one of 25 times the diameter of the body of the reference electrode 2 and 150 times the diameter of the tip of the reference electrode 2.
  • Fig. 5 is a front view of the electrostatic atomizing device 100 in a case where the opening 12 has a decreased diameter.
  • a decrease in diameter of the opening 12 causes the ion stream to be strong. However, a part of droplets atomized from the spray electrode 1 in a vertical direction may insufficiently ride the ion stream generated from the reference electrode 2, so that the spray-back may occur.
  • the opening 12 preferably has a diameter of 1.5 mm to 12.5 mm, i.e., a diameter which is 15 times to 125 times the diameter of the tip of the reference electrode 2, or which is 3 times to 25 times the diameter of the body of the reference electrode 2.
  • the opening 12 preferably has a diameter of 2.5 mm to 4.5 mm, i.e., a diameter which is 25 times to 45 times the diameter of the tip of the reference electrode 2, or which is 5 times to 9 times the diameter of the body of the reference electrode 2.
  • the opening 12 having a diameter falling within an above-described numerical value range allows most of the droplets atomized from the spray electrode 1 to ride the ion stream, so that the spray-back can be prevented.
  • Fig. 6 is a front view of the electrostatic atomizing device 100 in a case where the opening 12 is shaped to have an ellipse. Note that the ellipse of the opening 12 has a long axis which is positioned so as to substantially align with a line segment connecting the reference electrode 2 and the spray electrode 1.
  • the ion stream is weak, and additionally, a part of droplets atomized from the spray electrode 1 in a vertical direction insufficiently rides the ion stream, so that the spray-back easily occurs to a right side of Fig. 6 (the reference electrode 2 side).
  • the opening 12 which is elliptic as illustrated in Fig. 6 preferably has a width in a short axis direction of 1.5 mm to 12.5 mm. Further, the opening 12 preferably has a width in the short axis direction of 2.5 mm to 4.5 mm, i.e., the width being 25 times to 45 times the diameter of the tip of the reference electrode 2, or being 5 times to 9 times the diameter of the body of the reference electrode 2. Still further, the opening 12 preferably has a width in a long axis direction of 1.5 times to 3.5 times the width in the short axis direction. This allows most of the droplets atomized from the spray electrode 1 to ride the ion stream, so that the spray-back can be prevented.
  • Fig. 7 is a front view of the electrostatic atomizing device 100 in a case where the opening 12 is shaped to have an ellipse. Note that the ellipse of the opening 12 has a short axis which is positioned so as to substantially align with a line segment connecting the reference electrode 2 and the spray electrode 1.
  • the ion stream is slow in speed. However, most of the droplets atomized from the spray electrode 1 ride the ion stream, so that the spray-back can be prevented. Strength of the ion stream is optimized by changing the width of the short axis of the ellipse.
  • the ellipse of Fig. 7 and the ellipse described with reference to Fig. 6 may be identical in size of the long axis and the short axis.
  • Fig. 8 is a front view of the electrostatic atomizing device 100 in a case where the opening 12 is shaped to have an ellipse. Note that the ellipse of the opening 12 has a long axis and a short axis each of which forms an angle with a line segment connecting the spray electrode 1 and the reference electrode 2.
  • the elliptic opening 12 may be positioned to form an angle with the line segment connecting the spray electrode 1 and the reference electrode 2, and the angle can be changed appropriately.
  • lengths of the long axis and the short axis can be appropriately optimized so that the droplet can be atomized in a direction in which the droplet is away from the electrostatic atomizing device 100.
  • the opening 12 does not need to be elliptic.
  • the opening 12 may be appropriately designed to have a shape and a size which allow the droplet to ride the ion stream and then be atomized in a direction in which the droplet is away from the electrostatic atomizing device 100.
  • the openings 12, which are elliptic as illustrated in Figs. 6 to 8 are merely an example.
  • the openings may have another shape.
  • the electrostatic atomizing device 100 may be configured as below so that the spray-back may be prevented.
  • the electrostatic atomizing device 100 which is upright may be configured such that the spray electrode 1 and the reference electrode 2 are arranged in a vertical direction or two reference electrodes 2 are arranged on both sides of the spray electrode 1.
  • the electrostatic atomizing device 100 may be configured such that a shape(s) of the spray electrode 1 and/or the reference electrode 2 are/is changed or positive and negative electric charges of the spray electrode 1 and the reference electrode 2 are reversed.
  • the electrostatic atomizing device 100 may also be configured such that magnetic field generation means is used to atomize the droplet in a direction in which the droplet is away from the electrostatic atomizing device 100.
  • Fig. 9 illustrates flowing in/out of air via the opening 12 around the reference electrode 2.
  • An arrow in Fig. 9 indicates a flow of the air.
  • Occurrence of the ion stream reduces an air pressure in the vicinity of the opening 12 around the reference electrode 2, so that air flows into a region in which the air pressure has been reduced.
  • the supply of the air only to the region in the vicinity of the opening 12 causes the ion stream to be a turbulent flow. This may trigger the spray-back.
  • Fig. 1 illustrates a configuration in which an electrostatic atomizing device 110 having an opening 15 (air supply opening) for air supply.
  • An arrow in Fig. 1 indicates a flow of air. Note that a description of what has been described with reference to, for example, Fig. 3 is omitted.
  • the electrostatic atomizing device 110 has the opening 15.
  • the opening 15 is provided on a surface 31 which is adjacent to a surface 30 to which the spray electrode 1 and the reference electrode 2 are provided and which is the reference electrode 2 side surface of the electrostatic atomizing device 110 which is upright.
  • the opening 15 is in communication with the opening 12 in the electrostatic atomizing device 110.
  • the electrostatic atomizing device 110 Since the electrostatic atomizing device 110 has the opening 15, it has a path through which air is supplied from the opening 15 to the opening 12. Accordingly, air flowing into the electrostatic atomizing device 110 via the opening 15 is naturally supplied to the region in the vicinity of the opening 12 around the reference electrode 2, in which region the air pressure has been reduced by the occurrence of the ion stream. The air flowing into the electrostatic atomizing device 110 via the opening 15 causes the ion stream to be the laminar flow and consequently prevents the spray-back to the electrostatic atomizing device 110.
  • the opening 15 which is too small is unfavorable as being highly resistant to an air flow.
  • the opening 15 desirably has a larger area than the opening 12.
  • the opening 15 which is circular preferably has a diameter of 0.6 mm or more, and the opening which is elliptic preferably has a short axis with a diameter of 0.6 mm or more. This more preferably prevents the spray-back.
  • the opening 15 does not need to be provided on the surface 31 illustrated in Fig. 1 . Assuming that the electrostatic atomizing device 110 is upright, the opening 15 may be provided on an upper surface or a back surface of the electrostatic atomizing device 110, or a surface of the electrostatic atomizing device 110 which surface faces the surface 31. Further, the opening 15 is not particularly limited in shape and may be circular, rectangular, or the like.
  • Fig. 10 illustrates how a droplet flows when the elliptic opening 12 illustrated in Fig. 7 is used.
  • Fig. 11 illustrates how a droplet flows when the opening 12 with the increased diameter illustrated in Fig. 4 is used.
  • Figs. 10 and 11 illustrate pictures taken with a high-speed camera from above of the electrostatic atomizing device which is upright and is in operation.
  • a broken line is drawn in a direction in which a droplet is atomized.
  • a larger angle formed between the broken line and the surface 30 shows that the ion stream is stronger, and a smaller angle formed between the broken line and the surface 30 shows that the ion stream is weaker.
  • Fig. 12 described later discusses, with reference to Fig. 12 described later.
  • FIG. 12 illustrates how a droplet flows when the circular opening 12 illustrated in Fig. 5 is used.
  • Fig. 13 illustrates how a droplet flows when the circular opening 12 illustrated in Fig. 5 and the opening 15 illustrated in Fig. 1 are used.
  • Fig. 13 illustrating the electrostatic atomizing device 110 having the opening 15
  • the ion stream is strong because the opening 12 has a small area
  • the ion stream continues to be the laminar flow by the air supplied from the opening 15. This allows a greater effect of preventing the spray-back.
  • Fig. 14 illustrates a state immediately after the start of supply of the smoke to the opening 15 for air supply.
  • Fig. 15 illustrates a state after a time elapsed from the start of supply of the smoke to the opening 15 for air supply.
  • Fig. 14 illustrates the state immediately after the start of supply of the smoke to the opening 15 for air supply, and the smoke begins to appear from the opening 12 around the reference electrode 2.
  • the opening 12 is a circle having a diameter of 4 mm and the opening 15 is a 7.5 mm square.
  • Fig. 15 illustrates the state after a time elapsed from the start of supply of the smoke to the opening 15 for air supply and a state in which the smoke captures a positively charged droplet.
  • supply of air from the opening 15 to the opening 12 causes the ion stream to be the laminar flow. This yields an effect of preventing the spray-back to the electrostatic atomizing device 110.
  • Fig. 16 illustrates a state of the spray-back when the elliptic opening 12 illustrated in Fig. 6 is used.
  • the elliptic opening 12 has a length in a long axis direction of 10 mm and a length in a short axis direction of 4 mm.
  • the reference electrode 2 is connected with an electric conductor 13 and receives a voltage from a power supply device (not shown) via the electric conductor 13.
  • Fig. 17 is shown to compare an effect of preventing the spray-back with the effect described with reference to Fig. 16.
  • Fig. 17 illustrates a state of the spray-back when the opening 12 with the increased diameter illustrated in Fig. 4 is used.
  • the opening 12 is not a circle, but is a 12.5 mm x 15 mm rectangle.
  • one-day atomizing experiments were carried out so as to compare amounts of droplets adhering to the electric conductor 13 exposed to outside air.
  • various methods can be used to prevent the spray-back.
  • the spray-back can be prevented by various methods such as a method of changing the size and the shape of the opening 12 around the reference electrode 2, a method of supplying air from the opening 15 to the opening 12, and an appropriate combination of the methods. These methods yield an effect of realizing a device body without a great change in design of the device body and at low cost.
  • Fig. 18 illustrates a first method for controlling the electric charge amount of the droplet and the size of the droplet.
  • the first method is a method for controlling the electric charge amount of the droplet and the size of the droplet in accordance with the strength of the ion stream, which strength changes depending on the size of the opening 12 around the reference electrode 2.
  • An effect of the first method is verified by carrying out verification tests by use of two types of electrostatic atomizing devices: an electrostatic atomizing device 100a and an electrostatic atomizing device 100b.
  • the opening 12 around the reference electrode 2 has a diameter which is set to be 125 times the diameter (0.1 mm) of the tip of the reference electrode 2.
  • the opening 12 around the reference electrode 2 has a diameter which is set to be 40 times the diameter (0.1 mm) of the tip of the reference electrode 2. That is, the diameter of the opening 12 is set to be larger in the electrostatic atomizing device 100a than in the electrostatic atomizing device 100b.
  • Electric charge amounts of droplets and sizes of the droplets were compared in the two types of electrostatic atomizing devices. Figs. 19 and 20 illustrate results of the comparison.
  • Fig. 19 is a graph showing a particle size when the diameter of the opening 12 around the reference electrode 2 varies.
  • a horizontal axis indicates a diameter ( ⁇ m) of the droplet and a vertical axis indicates the number of droplets.
  • Fig. 20 is a graph showing the electric charge amount when the diameter of the opening 12 around the reference electrode 2 varies.
  • a horizontal axis indicates a sampling time (second) and a vertical axis indicates a current value (fA).
  • the opening 12 with a smaller diameter (a small opening) was higher than the opening 12 with a larger diameter (a large opening) in ratio of droplets with a small diameter. Further, as shown in Fig. 20 , the opening 12 with a smaller diameter (a small opening) was higher than the opening with a larger diameter (a large opening) in electric charge amount. A result of this may be brought about for the following reason.
  • a droplet is charged, and an electric charge amount per volume of a liquid increases as the charged droplet is evaporated.
  • the charging is intensified, the droplet is divided into a plurality of droplets by the Coulomb force. In other words, a droplet which is large in electric charge amount is readily made small.
  • the electrostatic atomizing device 100a is larger in the diameter of the opening 12 than the electrostatic atomizing device 100b.
  • the electrostatic atomizing device 100a the ion stream generated from the opening 12 around the reference electrode 2 is weak, and a residence time of the droplet is long. Accordingly, neutralization of a positively charged droplet and negatively charged air more easily proceeds in the electrostatic atomizing device 100a than in the electrostatic atomizing device 100b.
  • the electrostatic atomizing device 100a is smaller in electric charge amount of the droplet than the electrostatic atomizing device 100b ( Fig. 20 ), so that the droplet is highly likely to be large in the electrostatic atomizing device 100a ( Fig. 19 ).
  • gray regions are illustrated in an upper part and a lower part of each of solid lines of Fig. 20 .
  • the gray regions indicate displacement of current values for each sampling time and each of the solid lines indicates an average value of the current values. This also applies to Fig. 23 described later.
  • Fig. 21 illustrates a second method for controlling the electric charge amount of the droplet and the size of the droplet.
  • the second method is a method for controlling the electric charge amount of the droplet and the size of the droplet in accordance with a property of the ion stream (the turbulent flow, the laminar flow), which property changes depending on presence or absence of the opening 15.
  • An effect of the second method is verified by use of two types of electrostatic atomizing devices: the electrostatic atomizing device 100a and an electrostatic atomizing device 110a.
  • the electrostatic atomizing device 100a is identical with the electrostatic atomizing device 100a illustrated in Fig 18 .
  • the electrostatic atomizing device 110a is obtained by causing the electrostatic atomizing device 110 illustrated in Fig. 1 to have two openings 15 which are provided so as to face each other. Reference numbers 15a and 15b are given to the respective two openings in Fig. 21 . Note that the two openings each have a size of 10 mm x 10 mm.
  • the ion stream generated from the opening 12 around the reference electrode 2 is highly likely to be the turbulent flow as illustrated with reference to Fig. 4 .
  • the electrostatic atomizing device 110a the ion stream is highly likely to be the laminar flow by air supplied from each of the two openings 15a and 15b. Electric charge amounts of droplets and sizes of the droplets were compared in the two electrostatic atomizing devices. Figs. 22 and 23 illustrate results of the comparison.
  • Fig. 22 is a graph showing a particle size for each of presence and absence of the opening 15.
  • a horizontal axis indicates a diameter ( ⁇ m) of the droplet and a vertical axis indicates the number of droplets.
  • Fig. 23 is a graph showing the electric charge amount for each of presence and absence of the opening.
  • a horizontal axis indicates a sampling time (second) and a vertical axis indicates a current value (fA).
  • the electrostatic atomizing device 110a (with the opening) has a smaller droplet than the electrostatic atomizing device 100a (with no opening). Further, as illustrated in Fig. 23 , the electrostatic atomizing device 100a (with no opening) has a smaller electric charge amount. This may occur for the following reason.
  • a droplet is charged, and an electric charge amount per volume of a liquid increases as the droplet is evaporated.
  • the charging is intensified, the droplet is divided into a plurality of droplets by the Coulomb force. In other words, a droplet which is large in electric charge amount is readily made small.
  • the ion stream is highly likely to be the turbulent flow.
  • neutralization of a positively charged droplet and negatively charged air more easily proceeds in the electrostatic atomizing device 100a than in the electrostatic atomizing device 110a, in which the ion stream becomes the laminar flow.
  • the electrostatic atomizing device 100a is smaller in electric charge amount of the droplet than the electrostatic atomizing device 110a ( Fig. 23 ), so that the droplet is highly likely to be large in the electrostatic atomizing device 100a ( Fig. 22 ).
  • the electrostatic atomizing device which has the opening 15, causes the ion stream to be the laminar flow, and a particle size distribution of the droplet shifts to a left side (a small diameter side) as shown in Fig. 22 .
  • the electrostatic atomizing device 110a is three times larger in number of droplets with a small diameter than the electrostatic atomizing device 100a. Further, an average particle size is 1.2 ⁇ m in the electrostatic atomizing device 100a, whereas an average particle size is 0.77 ⁇ m in the electrostatic atomizing device 110a. Still further, the electrostatic atomizing device 110a greatly increases in electric charge amount of the droplet. As illustrated in Fig. 23 , the electrostatic atomizing device 110a is three times larger in current value than the electrostatic atomizing device 100a.
  • the size of the droplet and the electric charge amount of the droplet are controllable by adjusting the size of the opening 12 around the reference electrode 2 or depending on whether the electrostatic atomizing device has the opening 15. This allows suitable atomization in accordance with a purpose of use such as fragrance or insect-killing. Additionally, the spray-back can be prevented by adjusting the size of the opening 12 around the reference electrode 2 and providing the electrostatic atomizing device with the opening 15. This makes it possible to prevent the spray-back while controlling the size of the droplet and the electric charge amount of the droplet.
  • the electrostatic atomizing device of the present invention may be configured such that a first device surface or a second device surface of the device surfaces which differs from the first device surface is provided with an air supply opening for the second electrode which air supply opening is in communication with the second opening in the electrostatic atomizing device and supplies air to the second opening while the electrostatic atomizing device is driven.
  • An ion stream is generated from the second electrode by application of a voltage across the first electrode and the second electrode.
  • the generation of the ion stream causes a reduction in air pressure around the second electrode.
  • air flows in around the second electrode.
  • the ion stream and inflow air are mixed to cause the ion stream to be a turbulent flow.
  • This turbulent flow may be a cause of the spray-back.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, allows air to be supplied from the air supply opening for the second electrode to the second opening while the electrostatic atomizing device is being driven, so that the ion stream can be a laminar flow. Accordingly, the electrostatic atomizing device of the present invention allows the atomized substance to be less likely to adhere to the device surface, so that the spray-back can be prevented.
  • the electrostatic atomizing device of the present invention may be configured such that the air supply opening for the second electrode is provided on the second device surface, and the first electrode and the second electrode are provided on the first device surface.
  • the air supply opening for the second electrode and (ii) the first electrode and the second electrode are provided on an identical surface.
  • the second opening at which the ion stream is generated and the air supply opening for the second electrode which air supply opening supplies air to the second opening are provided on an identical surface. Accordingly, the ion stream and inflow air are mixed to cause the ion stream to be a turbulent flow. This turbulent flow may be a cause of the spray-back.
  • the electrostatic atomizing device of the present invention allows the ion stream to be the laminar flow by causing a surface on which the ion stream is generated and a surface to which air is supplied to be separate. Therefore, the electrostatic atomizing device of the present invention allows the atomized substance to be less likely to adhere to the device surface.
  • the electrostatic atomizing device of the present invention may be configured such that the air supply opening for the second electrode has a larger area than the second opening.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, reduces a resistance to air supplied from the air supply opening for the second electrode to the second opening, and facilitates a flow of the air to the second opening. Accordingly, the electrostatic atomizing device of the present invention allows the ion stream to be the laminar flow and allows the atomized substance to be less likely to adhere to the device surface.
  • the electrostatic atomizing device of the present invention may be configured such that the first device surface, the second device surface, or a third device surface of the device surfaces which differs from each of the first device surface and the second device surface, is provided with an air supply opening for the first electrode which air supply opening is in communication with the first opening in the electrostatic atomizing device and supplies air to the first opening while the electrostatic atomizing device is driven.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, allows air to be supplied via the air supply opening for the first electrode to the first opening around the first electrode from which first opening a substance is atomized.
  • the electrostatic atomizing device of the present invention allows the substance atomized from the first electrode to ride a flow of the air, so that the atomized substance can be atomized to a distant place. Accordingly, the electrostatic atomizing device of the present invention allows the atomized substance to be less likely to adhere to the device surface.
  • the electrostatic atomizing device may be configured such that the air supply opening for the first electrode is provided on the second device surface or the third device surface, and the first electrode and the second electrode are provided on the first device surface.
  • the air supply opening for the first electrode and (ii) the first electrode and the second electrode are provided on an identical surface.
  • the first electrode from which the substance is atomized and the air supply opening for the first electrode which air supply opening supplies air to the first opening are provided on an identical surface, so that the turbulent flow occurs around the first opening. This turbulent flow may be a cause of the spray-back.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, allows prevention of the occurrence of the turbulent flow and allows the atomized substance to be less likely to adhere to the device surface.
  • the electrostatic atomizing device of the present invention may be configured such that the air supply opening for the first electrode has a larger area than the first opening.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, reduces a resistance to air supplied from the air supply opening for the first electrode to the first opening and facilitates a flow of the air to the first opening. Accordingly, the electrostatic atomizing device of the present invention allows prevention of the occurrence of the turbulent flow in a region in which the substance is atomized, and allows the atomized substance to be less likely to adhere to the device surface.
  • the electrostatic atomizing device of the present invention may be configured such that: the second electrode is needle-shaped, and the second opening is circular; and the second opening has a diameter which is smaller than at least either one of 25 times a diameter of a body of the second electrode and 150 times a diameter of a tip of the second electrode.
  • the electrostatic atomizing device of the present invention may be configured such that: the second electrode is needle-shaped, and the second opening is circular; and the second opening has a diameter which is 5 times to 9 times a diameter of a body of the second electrode or a diameter which is 25 times to 45 times a diameter of a tip of the second electrode.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, allows most of the droplet atomized from the first electrode to ride the ion stream and allows the atomized substance to be less likely to adhere to the device surface.
  • the electrostatic atomizing device of the present invention may be configured such that: the second opening is shaped to have an ellipse; and the ellipse has a short axis which is positioned so as to substantially align with a line segment connecting the first electrode and the second electrode.
  • the electrostatic atomizing device of the present invention which electrostatic atomizing device has the configuration, allows most of the droplet atomized from the first electrode to ride the ion stream and allows the atomized substance to be less likely to adhere to the device surface. Note that strength of the ion stream can be optimized by changing a width of the short axis of the ellipse.
  • the present invention is suitably applicable to an electrostatic atomizing device.

Landscapes

  • Electrostatic Spraying Apparatus (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
EP13826305.8A 2012-08-01 2013-07-25 Dispositif de pulvérisation électrostatique Withdrawn EP2881179A4 (fr)

Applications Claiming Priority (2)

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JP2012171411A JP5968716B2 (ja) 2012-08-01 2012-08-01 静電噴霧装置
PCT/JP2013/070204 WO2014021191A1 (fr) 2012-08-01 2013-07-25 Dispositif de pulvérisation électrostatique

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EP2881179A1 true EP2881179A1 (fr) 2015-06-10
EP2881179A4 EP2881179A4 (fr) 2016-03-30

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US (1) US10173229B2 (fr)
EP (1) EP2881179A4 (fr)
JP (1) JP5968716B2 (fr)
CN (1) CN104487172B (fr)
AU (1) AU2013297692B2 (fr)
WO (1) WO2014021191A1 (fr)

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Publication number Priority date Publication date Assignee Title
EP3508277A4 (fr) * 2016-09-05 2020-05-06 Sumitomo Chemical Company, Limited Dispositif de pulvérisation électrostatique

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JP6212504B2 (ja) * 2013-01-15 2017-10-11 住友化学株式会社 静電噴霧装置
CN108247135B (zh) * 2018-03-16 2023-07-21 浙江工业大学 荷电气雾u型喷嘴
CN110200800B (zh) * 2019-06-13 2023-08-04 东华理工大学 一种静电雾化智能熏蒸仪及其熏蒸方法

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DE4312262A1 (de) 1993-04-15 1994-10-20 Gema Volstatic Ag Elektrostatische Sprühvorrichtung
WO2000064590A1 (fr) * 1999-04-23 2000-11-02 Battelle Memorial Institute Pulverisateur aerosol electrohydrodynamique (ehd) a commande directionnelle
GB0115355D0 (en) * 2001-06-22 2001-08-15 Pirrie Alastair Vaporization system
GB0308021D0 (en) 2003-04-07 2003-05-14 Aerstream Technology Ltd Spray electrode
JP4232542B2 (ja) * 2003-06-04 2009-03-04 パナソニック電工株式会社 静電霧化装置及びこれを備えた加湿装置
GB0501015D0 (en) * 2005-01-18 2005-02-23 Aerstream Technology Ltd Rigid dispenser system
WO2007077424A1 (fr) * 2006-01-05 2007-07-12 Aerstream Technology Limited Dispositif de pulverisation electrostatique
JP4816275B2 (ja) * 2006-06-13 2011-11-16 パナソニック電工株式会社 静電霧化装置
BR112013018746B1 (pt) 2010-12-28 2019-03-19 Sumitomo Chemical Company, Limited Método de tratamento do espaço-alvo
JP5762872B2 (ja) 2011-07-29 2015-08-12 住友化学株式会社 静電噴霧装置

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3508277A4 (fr) * 2016-09-05 2020-05-06 Sumitomo Chemical Company, Limited Dispositif de pulvérisation électrostatique
US10994292B2 (en) 2016-09-05 2021-05-04 Sumitomo Chemical Company, Limited Electrostatic spraying device

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WO2014021191A1 (fr) 2014-02-06
CN104487172A (zh) 2015-04-01
AU2013297692A1 (en) 2015-03-12
JP2014030782A (ja) 2014-02-20
AU2013297692B2 (en) 2017-05-25
EP2881179A4 (fr) 2016-03-30
JP5968716B2 (ja) 2016-08-10
US10173229B2 (en) 2019-01-08
US20150182978A1 (en) 2015-07-02
CN104487172B (zh) 2017-04-26

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