EP2863123B1 - Procédé pour incinérer des gaz pauvres contenant des composants azotés, comme par exemple NH3, HCN, C5H5N, dans les chambres de combustion d'une installation énergétique industrielle, et système pour mettre en oeuvre le procédé - Google Patents
Procédé pour incinérer des gaz pauvres contenant des composants azotés, comme par exemple NH3, HCN, C5H5N, dans les chambres de combustion d'une installation énergétique industrielle, et système pour mettre en oeuvre le procédé Download PDFInfo
- Publication number
- EP2863123B1 EP2863123B1 EP14003568.4A EP14003568A EP2863123B1 EP 2863123 B1 EP2863123 B1 EP 2863123B1 EP 14003568 A EP14003568 A EP 14003568A EP 2863123 B1 EP2863123 B1 EP 2863123B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- combustion
- calorific value
- section
- air
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000002485 combustion reaction Methods 0.000 title claims description 171
- 239000007789 gas Substances 0.000 title claims description 80
- 238000000034 method Methods 0.000 title claims description 24
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 title description 2
- 239000003546 flue gas Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 230000001154 acute effect Effects 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims description 2
- 239000000446 fuel Substances 0.000 description 29
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 18
- 239000003345 natural gas Substances 0.000 description 9
- 239000002912 waste gas Substances 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910017464 nitrogen compound Inorganic materials 0.000 description 4
- 150000002830 nitrogen compounds Chemical class 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000013618 particulate matter Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 230000001535 kindling effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002894 chemical waste Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/061—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating
- F23G7/065—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases with supplementary heating using gaseous or liquid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/30—Cyclonic combustion furnace
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2209/00—Specific waste
- F23G2209/14—Gaseous waste or fumes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/12—Heat utilisation in combustion or incineration of waste
Definitions
- the invention relates to a method of a low-emission incineration of low and medium calorific value gaseous containing NH 3 , HCN, C 5 H 5 N and other nitrogen-containing compounds in the combustion chambers of industrial power equipment, such as the power and heating boilers, and the metallurgical furnaces, characterized by low NO x emissions. Additionally, the subject of the invention includes a system for use this method.
- Patent No. P. 391715 describes a method of incineration of low calorific value waste gases, which involves the gradual co-incineration of waste gas together with high calorific value gaseous fuel, where the high calorific value gas is supplied tangentially to the walls of the first combustion section and where it creates together with the axially supplied air, a mixture, which is ignited by one of the pilot burners; the flame heats the system interior, next after reaching the adequate temperature in the combustion section waste gas is fed onto the resulting flame which ignites and heats the first and subsequent sections of the system, upon reaching a specific temperature, the waste gas is also supplied into the second combustion section, which is located in the burner, tangentially to the walls of this section, after exceeding another temperature threshold the waste gas is supplied to the third combustion section, which is located directly in the combustion chamber at an angle of 0 to 90° with respect to the direction of the combustion chamber axis, the amount of air supplied to the system by the first and similarly by the subsequent second combustion section approximates the stoichio
- the technical issue to the solved is the low-emission method of incineration of low and mean calorific value gases containing considerable amounts of nitrogen compounds, such as NH 3 , HCN, C 5 H 5 N, contributing to intensive production of nitrogen oxides, additionally containing particulate matter and liquid phase containing high hydrocarbons, with a minimum demand for high calorific value fuel as kindling fuel for heating the system to a temperature of 750°C and in special cases as fuel for stabilizing the process temperature.
- nitrogen compounds such as NH 3 , HCN, C 5 H 5 N
- a method according to the invention is provided in claim 1.
- low or mean calorific value gas into the combustion system in the second combustion section via at least one nozzle located at an acute angle of 0 to 90° to the longitudinal axis of the combustion system depending on the physicochemical properties of the gas.
- the low and mean calorific value gas stream and the stream of air with flue gases are parallel to each other, the direction and rate with which the gas and air with flue gases are supplied to the second combustion section causes the production of a strong internal recirculation of flue gases within the second combustion section.
- a system according to the invention is provided in claim 3.
- each low or mean calorific value gas nozzle in the second combustion section of the combustion system is connected to the low or mean calorific value gas feeder via a shut-off valve.
- the system further comprises a temperature sensor at the exit of the combustion system, the control element is connected to said temperature sensor, to the shut-off valve of the low or mean calorific value gas nozzle, to the control dampers of the air nozzles supplying air to the third section of the combustion system.
- the system has at least one branch where the first section of the combustion system is connected with the common second section of the combustion system and in series with the third combustion section of the combustion system.
- the invention provides for the incineration of low or mean calorific value gases containing considerable amounts of nitrogen compounds, such as NH 3 , HCN, C 5 H 5 N (which contribute to the intensive production of nitrogen oxides), during a safe and stable combustion process whilst maintaining high efficiency of the system and extremely low emissions of CO and NOx.
- nitrogen compounds such as NH 3 , HCN, C 5 H 5 N (which contribute to the intensive production of nitrogen oxides)
- the combustion system facilitates:
- combustion takes place in accordance with the objectives of volumetric combustion technology, and flame stabilisation is based on the aerodynamic properties of the process conducted according to set velocities and directions for supplying air, high calorific value fuel and low or mean calorific value gases in particular combustion zones and on temperature stabilisation. Gradually supply of air to different combustion sections and the aerodynamic shaping and separation of individual combustion zones results in low CO and NO X emissions.
- An essential part of the incineration process is carried out in a semi-adiabatic combustion chamber above the mixture's self-ignition point.
- the system comprises a supply air chamber 1 , combustion system 2 with sections 3 , 4 , 5 connected in series, ignition burner 6 , high calorific value fuel nozzles 7 and 8, low and mean calorific value gas nozzles 9 , air nozzles 10, air heater 11 , high calorific value fuel feeder 12 , low and mean calorific value gas feeder 13 , control dampers 14 and 19 , high calorific value fuel shut-off valves 15, low and mean calorific value gas shut-off valves 20 , temperature sensors 16 and 21 flame detector 17, is characterised in that the first section 3 of the combustion system 2 has a form of a cylindrical cylinder containing at least one pilot burner 6 and at least one high calorific value fuel nozzle 7 placed parallel to the tangent of the cylindrical cylinder's cross-section, where at one side the first section 3 of the combustion system 2 is connected to the supply air chamber 1 , and at the other side it couples, through a narrowing, with the entrance of the second section 4 of the combustion system 2 , one cylinder contains the
- the supply air chamber 1 is connected to the air heater 11 via a control damper 19 .
- each high calorific value fuel nozzle 7 is connected to a high calorific value fuel feeder 12 via a shut-off valve 15 .
- each high calorific value fuel nozzle 8 is connected to a high calorific value fuel feeder 12 via a shut-off valve 15 .
- each low or mean calorific value gas nozzle 9 is connected to a low or mean calorific value gas feeder 13 via a shut-off valve 20.
- each air nozzle 10 is connected to an air heater 11 via a control damper 14 .
- the control element 18 is connected to temperature sensors 16 and 21 and shut-off valves 15 of high calorific value fuel nozzles 7 , 8 , shut-off valves 20, of low or mean calorific value gas nozzles 9 , control dampers 14 of air nozzles 10 supplying air to the third combustion section 5 and control damper 19 of the pipe supplying air to the air chamber 1 .
- the system has at least one branch where the first section 3 , is connected in series with a common second section 4 of the combustion system 2 , and third section 5 of the combustion system 2.
- the synthesized gas combustion process is conducted on four dual-fuel burners.
- a schematic diagram of the combustion process is presented in Fig. 1 .
- air for the first combustion stage is fed through the air chamber 1 .
- Natural gas is fed via the nozzles 7 perpendicularly to the air stream and tangentially to the walls of the first combustion section 3 .
- the resulting mixture is ignited by means of an pilot burner 6 .
- the pilot burner 6 In order to deliver a natural gas stream to the combustion system 2 via nozzle 7 , the pilot burner 6 must be operative. After activating pilot burner 6 it is recommended to wait a few minutes before introducing natural gas from the feeder 12 . A few seconds after initiating the supply of natural gas to nozzles 7 flame control is performed by means of a flame detector 17 mounted on the back wall of the burner.
- the flame detector 17 fails to confirm the presence of a flame when the system temperature is below 750°C, the supply of natural gas to the nozzles 7 is cut off.
- the pilot burner 6 must function properly or the flame detector 17 must confirm the presence of a flame.
- the role of the flame control is to measure the temperature on the walls of the combustion chamber, and at the same time the flame detectors located in the first combustion section and pilot burner are relieved of this role. This procedure results in an enhanced reliability of the system's performance.
- the system must be heated gradually, in line with the relevant heating curve, and cooled down in accordance with the cooling curve. If the combustion system 2 starts operation when the temperature measured on the walls of the second combustion section 4 is lower than the nominal temperature, the system must be heated gradually in accordance with the heating curve, and operation at maximum output is not possible from the very start.
- the temperature of the system exceeds 850°C measured by a temperature sensor 16 on the walls of the second combustion section 4 of the combustion system 2 the supply of natural gas to nozzles 7 and 8 is cut off and pilot burner 6 is turned off, and synthetic gas is delivered to the second combustion section 4 via nozzles 9 .
- the amount of air delivered to the first and second sections 3 and 4 of the combustion system 2 approximates 70% of the stoichiometric value. Such amount of air allows to achieve a optimum, relatively low temperature in the second section 4 of the combustion system 2 , required for the process of synthesized gas treatment. The generation of the said temperature allows to achieve an adequate quality of the combustion process and ensure low intensity of NOx production. In the third section 5 of the combustion system 2 the remaining portion of air is delivered, which allows to achieve the set excess air ratio at the system outlet.
- the air stream is supplied via nozzles 10 distributed on two levels on the walls of the combustion chamber and directed at an angle to the combustion chamber walls in order to enhance the inner vortex which guarantees intensification of the gas mixing process, longer residence time of gas in the chamber, afterburning of underburnt compounds from previous sections 3 and 4 of the combustion system 2 the aim of which is to maximise the quality of the combustion process.
- the solution according to the invention does not require the use of mechanical parts, such as paddles or plates for swirling the stream and stabilising the flame.
- mechanical parts such as paddles or plates for swirling the stream and stabilising the flame.
- the description presents one technical embodiment of the method and system for synthetic gas combustion, in the form of co-combustion of gas from the gasification of selected municipal waste and natural gas as a high caloric value fuel used for initial heating of the system, using the heat energy generated in the course of this process in the form of flue gases.
- Synthetic gas is generated in the process of gasification of selected municipal waste, biomass, coal and etc.. Owing to its composition, namely a high content of nitrogen compounds, such as NH 3 , HCN, C 5 H 5 N, synthetic gas requires a special combustion process.
- the process involves volumetric, high-temperature combustion while maintaining precise control over the fuel/air and air/fuel ratios in specific combustion sections (air stratification), whilst minimising the consumption of natural gas as kindling/high calorific value fuel and in special cases as fuel for stabilizing the process.
- the installation has been prepared for use with synthetic gas which is characterised by the following parameters that change in real time: heat value, content of main gas components, including particulate matter and liquids containing high hydrocarbons, amount and type of pollutants, moisture content and pressure.
- the combustion of synthesized gas takes place in a non-cooled (semi-adiabatic) combustion chamber in the shape of a cylinder in the bottom part and a truncated cone in the upper part.
- the inclination of the combustion chamber walls in its upper part has a favourable effect on lowering the temperatures in this area, that is, in the second combustion section (making use of the radiation mechanism).
- the dimensions of the combustion chamber have been selected to meet the requirements of the minimum residence time of flue gas in the system, amounting to a few seconds, and the maximum flue gas flow rate in the combustion system, which is not more than a few meters per second.
- the minimum operating temperature of the combustion system has been determined at 850°C, this temperature ensures the combustion of low and mean calorific value gases. Temperature in the system exceeding 850°C is controlled by the amount of synthetic gas and air delivered. A drop in the system temperature below 850°C triggers the delivery of high calorific value gas directly to the second combustion section, when the temperature exceeds 850°C once again, the supply of high calorific value gas is cut off.
- the combustion system is equipped with two-stage, dual fuel burners fed by independent media supplying systems, which ensures independent operation of individual burners.
- the amount of synthetic gas supplied is controlled, so as to maintain the set temperature and flue gas stream at the combustion system outlet.
- the amount of synthetic gas supplied to the combustion system is controlled by a control damper, which is shared by all four burners.
- the required synthetic gas pressure in the pipe feeding the combustion system is 10.0 kPa, nominal pressure 5.0 kPa, for a nominal rate of 750.0 Nm 3 /h per burner, which in the case of four installed burners totals 3000.0 Nm 3 /h, and a negative pressure in the combustion chamber reaching even 3 kPa.
- the air heated in the recuperator to a temperature of 800°C separates into two streams: the first stream feeds the first, and then indirectly the second and third combustion section and the second stream feeds directly the third combustion section.
- the first air stream for combustion is selected so that the excess air ratio in the second combustion stage achieves approximately 0.7.
- the required air pressure ensuring proper functioning of the burners ranges to 10 kPa, nominal pressure 5.0 kPa, and the flow rate for each burner approximates 850 Nm 3 /h, for the burner's nominal operating conditions.
- the second air stream is delivered directly to the combustion system, to the third combustion section, via 2 to 8 nozzles located on two levels of the lateral walls of the combustion chamber, where the first level of nozzles is inclined towards the flue gas outlet from the combustion chamber at 20° to the plane perpendicular to the longitudinal axis of the combustion chamber, compliant with the flue gas flow direction, which results in reduced flue gas recirculation from the third combustion section to the second combustion section and the creation of two zones in the combustion chamber with markedly different oxygen content, the second level of nozzles is positioned parallel to this plane, additionally the axles of nozzles distributed on both levels pass the longitudinal axis of the combustion chamber, thanks to which the exiting air forms a strong vortex inside the combustion chamber, whose rotation axis overlaps longitudinal axi
- the required air pressure for the third combustion section to function properly is up to 10.0 kPa, nominal pressure 5 kPa, and the flow rate for this combustion section is 20,000.0 Nm 3 /h. Thanks to such a division of air streams and the inclined walls of the combustion chamber, we achieve a reduction atmosphere in the second combustion section and we reduce the process temperature in this area, this operation is essential for minimizing and reducing the production of NOx compounds.
- the second air stream supplied to the third combustion section increases the excess air ratio to 1.0 or even 5.0.
- the volume of air supplied to the third combustion section is controlled by control dampers valves according to the measurements performed. In the case of a smaller demand for air in the third combustion section or due to a lower power output of the system, air is delivered only to selected nozzles, which ensures maintaining relevant velocities within a wide scope of changes in the system's operation.
Claims (7)
- Un procédé de combustion à faible émission des gaz à bas ou moyen pouvoir calorifique, en particulier des gaz de synthèse, dans une chambre de combustion du système de combustion (2) des équipements électriques industriels, caractérisée en ce que la combustion est effectuée selon les étapes suivantes:- alimenter en air par un courant d'air constant à une vitesse de 20 m / s et à une température de 0 à 800° C, de préférence supérieure à 300° C,- transporter de l'air d'une chambre d'alimentation en air (1) vers la première section (3) du système de combustion (2) où la vitesse de l'air augmente jusqu'à environ 80 m / s et où il est mélangé avec un gaz à haut pouvoir calorifique qui est fourni à une vitesse maximale de 25 m / s, de préférence de 15 m / s, par au moins une buse à gaz à haut pouvoir calorifique (7),- allumer le mélange obtenu à l'aide d'au moins un brûleur d'allumage (6) qui allume et entretient la flamme,- chauffer consécutivement les deuxième et troisième sections (4, 5) du système de combustion (2) par le biais des gaz de combustion chauds générés,- alimenter la deuxième section de combustion (4) en gaz à haut pouvoir calorifique après que la température sur ses parois dépasse 750°C, de préférence parallèlement au flux d'air contenant les gaz de combustion par le biais d'au moins une buse de gaz à haut pouvoir calorifique (8) tout en chauffant la chambre de combustion avec la flamme résultante jusqu'à ce que la température mesurée sur les parois de la deuxième section de combustion (4) atteigne 850° C,- alimenter la deuxième section de combustion (4) en gaz à bas ou moyen pouvoir calorifique par le biais d'au moins une buse (9) à un débit allant jusqu'à 120 m / s, de préférence 70 m / s et à une température de 0 à 600° C, en quantité allant jusqu'à 100% du flux total à incinérer,- couper le gaz à haut pouvoir calorifique au moment où le gaz à bas ou moyen pouvoir calorifique commence à être fourni,- reprendre l'alimentation en gaz de haut pouvoir calorifique de la deuxième section de combustion (4) lorsque la température à la sortie du système tombe en dessous de la température définie et / ou lorsque la température mesurée sur la paroi de la chambre de combustion tombe en dessous de la température définie et la continuation de l'augmentation du flux de gaz à moyen ou bas pouvoir calorifique est impossible ou le pouvoir calorifique du gaz est si bas que l'augmentation du flux de gaz provoque une nouvelle baisse de température dans la chambre de combustion, et la quantité d'air fournie par la première section de combustion (3) à la deuxième section de combustion (4) située dans la chambre de combustion est inférieure à la quantité stoechiométrique, le rapport du volume d'excès d'air s'élève d'habitude de 0,4 à 0,99, de préférence égal à 0,7,- alimenter en air à niveaux multiples la troisième section de combustion (5) située dans la chambre de combustion, de préférence sur deux niveaux équipés d'au moins deux buses à injection d'air (10) chacun, où les buses d'air (10) étant situées à chaque niveau sont inclinées dans le sens du flux dans la chambre de combustion, où l'inclinaison est comprise entre 0° et 45° du plan perpendiculaire à l'axe longitudinal de la chambre de combustion et peut différer pour chaque niveau, de plus, les buses à injection d'air (10) sont positionnées dans tous les niveaux d'une manière qui, dans la chambre de combustion, provoque un tourbillon puissant dont l'axe de rotation chevauche celui de la chambre de combustion, dans laquelle de l'air introduit dans la troisième section de combustion (5) à une température de 0 à 800° C, de préférence supérieure à 300° C, est diffusé jusqu'à 200 m / s, de préférence 100 m / s, en quantité suffisante pour créer une zone contenant une proportion élevée d'oxygène, le rapport du volume d'excès d'air variant de 1,0 à 5,0.
- Un procédé selon la revendication 1, caractérisée en ce que dans la deuxième section de combustion (4), un courant de gaz à bas ou moyen pouvoir calorifique est introduit dans le système de combustion (2) par ladite au moins une buse (9) fixée à un angle aigu de 0 à 90° par rapport à l'axe longitudinal de la chambre de combustion en fonction des propriétés physico-chimiques du gaz.
- Le système de combustion à faible émission des gaz à bas ou moyen pouvoir calorifique, en particulier des gaz de synthèse, comprenant : un système de combustion (2) avec une chambre de combustion, une chambre d'alimentation en air (1), une première section (3) du système de combustion (2) reliée par un rétrécissement à une deuxième section (4) du système de combustion (2) et en série avec une troisième section (5) du système de combustion (2), au moins une buse à injection de gaz à bas ou moyen pouvoir calorifique (9), des buses de gaz à haut pouvoir calorifique (7, 8), au moins un brûleur d'allumage (6), un réchauffeur d'air (11), un dispositif d'alimentation en gaz à bas ou moyen pouvoir calorifique (13), un dispositif d'alimentation en gaz à haut pouvoir calorifique (12), des vannes d'arrêt (15) pour le gaz à haut pouvoir calorifique, un régulateur de gaz (19), au moins deux buses d'air (10), au moins un capteur de température (16) et un élément de contrôle (18) relié à des vannes d'arrêt (15) pour le gaz à haut pouvoir calorifique, au régulateur de gaz (19) et à au moins un capteur de température (16), caractérisée en ce que la première section (3) du système de combustion a la forme d'un cylindre cylindrique dans lequel est placé au moins un brûleur d'allumage (6) et au moins une buse de gaz à haut pouvoir calorifique (7) situé à l'axe parallèle à la tangente de la section transversale du cylindre cylindrique, où d'un côté la première section (3) du système de combustion est reliée à la chambre d'alimentation en air (1) qui est reliée à un réchauffeur d'air (11) par le biais d'un régulateur (19) et de l'autre côté, elle est reliée - par un rétrécissement - à l'entrée de la deuxième section (4) du système de combustion (2), dans lequel un cylindre contient les deuxième (4) et troisième sections (5) du système de combustion (2), où une partie du cylindre constitue la deuxième section (4) du système de combustion (2) comprenant au moins une buse de gaz à haut pouvoir calorifique (8), au moins une buse de gaz à bas ou moyen pouvoir calorifique (9) et au moins un capteur de température (16) du système de combustion, par contre, la deuxième partie du cylindre comprend la troisième section (5) du système de combustion (2) comprenant au moins deux buses d'air (10) et où, dans la première section (3) du système de combustion (2), la buse de gaz à haut pouvoir calorifique (7) est raccordée au dispositif d'alimentation en gaz à haut pouvoir calorifique (12) par le biais d'une vanne d'arrêt (15) tandis que dans la deuxième section (4) du système de combustion (2), chaque buse de gaz à haut pouvoir calorifique (8) est reliée à un distributeur de gaz à haut pouvoir calorifique (12) par le biais d'une vanne d'arrêt (15).
- Le système selon la revendication 3, caractérisé en ce que dans la seconde section (4) du système de combustion (2), chaque buse de gaz à bas et moyen pouvoir calorifique (9) est reliée au dispositif d'alimentation en gaz à bas et moyen pouvoir calorifique (13) par une vanne d'arrêt (20).
- Le système selon la revendication 3 ou 4, caractérisé en ce que dans la troisième section (5) du système de combustion (2), chaque buse d'air (10) est reliée à un réchauffeur d'air (11) par le biais d'une vanne de régulation (14).
- Le système selon la revendication précédente, comprenant ce qui suit : un capteur de température (21) à la sortie de la troisième section de combustion (5), caractérisé en ce que l'élément de contrôle (18) est relié à un capteur de température (21), à une vanne d'arrêt (20) de la buse de gaz à bas et moyen pouvoir calorifique (9) et à des vannes de régulation (14) des buses d'air (10) alimentant en air la troisième section (5) du système de combustion (2).
- Le système selon les revendications 3 à 6 précédentes, caractérisé en ce que ledit système comporte au moins une branche où la première section (3) du système de combustion (2) est reliée à la deuxième section commune (4) du système de combustion (2) et en série à la troisième section de combustion (5) du système de combustion (2).
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL405710A PL227902B1 (pl) | 2013-10-21 | 2013-10-21 | Sposób niskoemisyjnego spalania gazów nisko i średniokalorycznych, zwłaszcza gazów syntezowanych, w komorach spalania przemysłowych urządzeń energetycznych i układ do niskoemisyjnego spalania gazów nisko i średniokalorycznych, zwłaszcza gazów syntezowanych, w komorach spalania przemysłowych urządzeń energetycznych |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2863123A1 EP2863123A1 (fr) | 2015-04-22 |
EP2863123B1 true EP2863123B1 (fr) | 2019-08-21 |
Family
ID=51865964
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14003568.4A Active EP2863123B1 (fr) | 2013-10-21 | 2014-10-20 | Procédé pour incinérer des gaz pauvres contenant des composants azotés, comme par exemple NH3, HCN, C5H5N, dans les chambres de combustion d'une installation énergétique industrielle, et système pour mettre en oeuvre le procédé |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2863123B1 (fr) |
PL (1) | PL227902B1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117570455A (zh) * | 2023-12-23 | 2024-02-20 | 山东瀚圣新能源科技股份有限公司 | 一种甲醛生产蒸发尾气热量回收装置 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5269235A (en) * | 1988-10-03 | 1993-12-14 | Koch Engineering Company, Inc. | Three stage combustion apparatus |
US5707596A (en) * | 1995-11-08 | 1998-01-13 | Process Combustion Corporation | Method to minimize chemically bound nox in a combustion process |
PL217183B1 (pl) | 2010-07-02 | 2014-06-30 | Ics Ind Comb Systems Spółka Z Ograniczoną Odpowiedzialnością | Sposób niskoemisyjnego spalania gazów odpadowych, zwłaszcza niskokalorycznych w komorach spalania przemysłowych urządzeń energetycznych i układ do niskoemisyjnego spalania gazów odpadowych, zwłaszcza niskokalorycznych w komorach spalania przemysłowych urządzeń energetycznych |
PL217825B1 (pl) * | 2010-07-02 | 2014-08-29 | Ics Ind Comb Systems Spółka Z Ograniczoną Odpowiedzialnością | Sposób spalania paliwa w komorach spalania pieców hutniczych i stalowniczych oraz kotłów grzewczych i energetycznych oraz układ do stosowania tego sposobu |
-
2013
- 2013-10-21 PL PL405710A patent/PL227902B1/pl unknown
-
2014
- 2014-10-20 EP EP14003568.4A patent/EP2863123B1/fr active Active
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
EP2863123A1 (fr) | 2015-04-22 |
PL405710A1 (pl) | 2015-04-27 |
PL227902B1 (pl) | 2018-01-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4969015B2 (ja) | 固体燃料バーナと固体燃料バーナを用いた燃焼方法 | |
CA2733121C (fr) | Systeme de combustion a gaz oxygene equipe d'un refoulement de gaz combustible reduit | |
US6843185B1 (en) | Burner with oxygen and fuel mixing apparatus | |
US8485813B2 (en) | Three stage low NOx burner system with controlled stage air separation | |
CA2653890C (fr) | Procede et dispositif pour combustion etagee d'air et de combustible | |
US20100077944A1 (en) | Combustion system with precombustor | |
ZA200709079B (en) | Pulverized solid fuel burner | |
MX2007010342A (es) | Sistema y metodo de combustion. | |
US6244200B1 (en) | Low NOx pulverized solid fuel combustion process and apparatus | |
JP6653862B2 (ja) | 発火装置における燃焼管理のための方法および発火装置 | |
EP2588809B1 (fr) | Procédé et système pour l'incinération, à faible émission, de gaz résiduels faiblement calorifiques | |
CN101142447B (zh) | 燃烧方法和系统 | |
EP2751484B1 (fr) | Appareil de combustion avec combustion indirecte | |
US20130255551A1 (en) | Biomass Combustion | |
EP2863123B1 (fr) | Procédé pour incinérer des gaz pauvres contenant des composants azotés, comme par exemple NH3, HCN, C5H5N, dans les chambres de combustion d'une installation énergétique industrielle, et système pour mettre en oeuvre le procédé | |
CN210688167U (zh) | 一种基于现有燃气锅炉改造的可燃烧生物质燃料的锅炉 | |
KR101854568B1 (ko) | 고체 연료 연소 시스템 | |
RU2339878C2 (ru) | Способ плазменно-угольной безмазутной растопки котла и устройство для его реализации | |
CN102032591A (zh) | 一种煤粉点火系统及其控制方法 | |
RU2055268C1 (ru) | Прямоточная горелка с низким выходом окислов азота (варианты) и способ сжигания топлива | |
RU2407948C1 (ru) | Способ трехступенчатого сжигания угля с применением плазменной термохимической подготовки | |
Kirzhner et al. | Combustion of Sewage Sludge and Coal Powder |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20141020 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
R17P | Request for examination filed (corrected) |
Effective date: 20151012 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20190220 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAL | Information related to payment of fee for publishing/printing deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR3 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
INTG | Intention to grant announced |
Effective date: 20190705 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602014052015 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1170185 Country of ref document: AT Kind code of ref document: T Effective date: 20190915 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191121 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191121 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191223 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191122 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20191221 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1170185 Country of ref document: AT Kind code of ref document: T Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20200224 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602014052015 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG2D | Information on lapse in contracting state deleted |
Ref country code: IS |
|
26N | No opposition filed |
Effective date: 20200603 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20141020 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190821 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20221017 Year of fee payment: 9 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 20231023 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20231019 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IE Payment date: 20231019 Year of fee payment: 10 Ref country code: FR Payment date: 20231023 Year of fee payment: 10 Ref country code: DE Payment date: 20231020 Year of fee payment: 10 Ref country code: CH Payment date: 20231102 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20231020 Year of fee payment: 10 |