EP2836089B9 - Zigarettenpapier, das einer zigarette ein gleichmässiges zugprofil verleiht - Google Patents
Zigarettenpapier, das einer zigarette ein gleichmässiges zugprofil verleiht Download PDFInfo
- Publication number
- EP2836089B9 EP2836089B9 EP14725200.1A EP14725200A EP2836089B9 EP 2836089 B9 EP2836089 B9 EP 2836089B9 EP 14725200 A EP14725200 A EP 14725200A EP 2836089 B9 EP2836089 B9 EP 2836089B9
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- cigarette
- paper
- cigarette paper
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 235000019504 cigarettes Nutrition 0.000 title claims description 216
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 50
- 239000000203 mixture Substances 0.000 claims description 49
- 238000000034 method Methods 0.000 claims description 26
- 238000007639 printing Methods 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 19
- 238000001035 drying Methods 0.000 claims description 17
- 230000001419 dependent effect Effects 0.000 claims description 12
- 230000035699 permeability Effects 0.000 claims description 9
- 239000001509 sodium citrate Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 7
- 238000007646 gravure printing Methods 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 6
- 239000001508 potassium citrate Substances 0.000 claims description 6
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 235000015870 tripotassium citrate Nutrition 0.000 claims description 6
- 238000009499 grossing Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 4
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 4
- 238000005470 impregnation Methods 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 4
- 235000021317 phosphate Nutrition 0.000 claims description 4
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 4
- 229940038773 trisodium citrate Drugs 0.000 claims description 4
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 3
- -1 oxylates Chemical class 0.000 claims description 3
- 230000002441 reversible effect Effects 0.000 claims description 3
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 244000025254 Cannabis sativa Species 0.000 claims description 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 claims description 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 claims description 2
- 244000303965 Cyamopsis psoralioides Species 0.000 claims description 2
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 240000006240 Linum usitatissimum Species 0.000 claims description 2
- 235000004431 Linum usitatissimum Nutrition 0.000 claims description 2
- 241001148717 Lygeum spartum Species 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 235000010443 alginic acid Nutrition 0.000 claims description 2
- 229920000615 alginic acid Polymers 0.000 claims description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 2
- 235000009120 camo Nutrition 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 235000005607 chanvre indien Nutrition 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-L fumarate(2-) Chemical class [O-]C(=O)\C=C\C([O-])=O VZCYOOQTPOCHFL-OWOJBTEDSA-L 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 239000011487 hemp Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 150000003893 lactate salts Chemical class 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- 150000004701 malic acid derivatives Chemical class 0.000 claims description 2
- 239000012764 mineral filler Substances 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 150000003873 salicylate salts Chemical class 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 150000003890 succinate salts Chemical class 0.000 claims description 2
- 150000003892 tartrate salts Chemical class 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 13
- 230000000996 additive effect Effects 0.000 claims 12
- 238000012885 constant function Methods 0.000 claims 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims 1
- 244000061176 Nicotiana tabacum Species 0.000 claims 1
- 229940072056 alginate Drugs 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- 229940105329 carboxymethylcellulose Drugs 0.000 claims 1
- 235000019263 trisodium citrate Nutrition 0.000 claims 1
- 241000208125 Nicotiana Species 0.000 description 49
- 150000003839 salts Chemical class 0.000 description 44
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 25
- 229960002715 nicotine Drugs 0.000 description 25
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 25
- 230000007423 decrease Effects 0.000 description 14
- 239000000779 smoke Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000009423 ventilation Methods 0.000 description 9
- 230000000391 smoking effect Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000008859 change Effects 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 4
- 235000011941 Tilia x europaea Nutrition 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 239000004571 lime Substances 0.000 description 4
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 4
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 230000006399 behavior Effects 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- JKRDADVRIYVCCY-UHFFFAOYSA-N 2-hydroxyoctanoic acid Chemical class CCCCCCC(O)C(O)=O JKRDADVRIYVCCY-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000032900 absorption of visible light Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
- A24D1/025—Cigars; Cigarettes with special covers the covers having material applied to defined areas, e.g. bands for reducing the ignition propensity
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/005—Treatment of cigarette paper
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Definitions
- the present invention relates to a cigarette paper which imparts a uniform tensile profile to a cigarette made therefrom. It further relates to a method for producing such a cigarette paper, a cigarette and the use of a location-dependent concentration of a fire salt in a cigarette.
- a typical cigarette is made of tobacco, which is wrapped by the cigarette paper and together with it forms a typically cylindrical tobacco rod.
- the tobacco rod is followed by the filter, which typically consists of cellulose acetate fibers.
- the filter and tobacco rod are wrapped by the tipping paper.
- the tipping paper connects the filter to the tobacco rod.
- the cigarette paper has in addition to the function of wrapping the tobacco, among other things, the task of the cigarette to give an attractive appearance in the smoked and not hacked state and to influence the smoldering speed of the cigarette. It also serves to control the composition of the smoke, especially the content of tar, nicotine and carbon monoxide.
- the smoker When smoking, the smoker creates a negative pressure at the mouth end of the smoldering cigarette, is sucked through the air on the one hand by the cone of embers on the cigarette holder, but on the other hand also flows through the air-permeable cigarette paper into the tobacco rod and so diluted the smoke.
- the stream of air flowing through the air-permeable cigarette paper into the tobacco rod during smoking is called strand ventilation.
- the total dilution of the smoke is composed of the strand ventilation and the filter ventilation.
- the tobacco cord burns, so that its length decreases.
- the available area for the strand ventilation cigarette paper decreases, so that less and less air can flow through the cigarette paper in the tobacco rod and thus the strand ventilation decreases from train to train.
- the smoke is less dilute from train to train, and the concentration of the smoke-forming aerosols and gases in the smoke flowing from the mouth end increases.
- the tobacco rod has a certain filtration effect on the smoke, which is also decreasing with decreasing length of the tobacco rod. This gives the smoker the impression that the cigarette is getting "stronger" from train to train.
- the cigarette paper may be perforated with the portion of the cigarette paper close to the filter being more perforated and thus having a higher air permeability than the rest of the cigarette paper.
- the strand ventilation does not decrease as much as with cigarette paper with an approximately constant air permeability along the tobacco rod.
- this method sometimes has the disadvantage that such cigarettes are difficult to ignite because much air flows through the more perforated part of the cigarette paper and the air flow through the tip of the cigarette is too low to start the glowing process when lighting.
- a cigarette paper which comprises a water-soluble salt which has lost more than 15% of its initial mass after heating to 230 ° C, the heating starting from a starting temperature of 30 ° C at a heating rate of 5 ° C / min under a Nitrogen flow of 25 ml / min takes place.
- the water-soluble salt may be contained in discrete strip-shaped portions.
- the cigarette paper is equipped with burn salts and designed so that the content of one or more Brandsalze in the cigarette paper from the filter end to the tobacco end changed on a cigarette made from it, in particular, that it changes monotonously within normal production and measurement tolerances, ie either monotonous increases or decreases monotonically.
- the change need not be strictly monotone, so there may be portions of constant content of the one or more Brandsalzes.
- the variable content or the variable concentration of Brandsalzen is chosen so that the cigarette paper gives a cigarette, in particular a filter cigarette, a more uniform tensile profile than would be the case for an otherwise similar cigarette with a constant Brandsalzkonzentration along the longitudinal direction of the cigarette.
- the burn salts are substances, for example salts, which can increase or decrease the smoldering speed of the cigarette paper.
- Very commonly used are trisodium and tripotassium citrate and mixtures thereof.
- Trisodium and tripotassium citrate are examples according to the invention of the flame accelerating, ie fire-promoting, Brandsalze, while phosphates can serve as the inventive example of the glow slowing, so fire retardant, Brandsalze.
- a fire salt is fire-promoting or fire-retardant is generally known to those skilled in the art, or it can be easily determined by measuring the smoldering speed of a cigarette paper containing the fire salt in question in sufficient quantity.
- the direction x of the cigarette papers may or may not necessarily be in accordance with the machine direction.
- the length L corresponds to the length of the visible tobacco rod on the cigarette for which the cigarette paper is intended, ie the length from the point where the tobacco rod emerges under the tipping paper to the tip of the cigarette to be lit. This length L may be different for different types of cigarette but will be ⁇ 11 cm and ⁇ 3 cm in the bars.
- the function f (x) is monotone over the interval [0, L], but does not necessarily have to be strictly monotone. On the contrary, some of the presently preferred embodiments have near-end and near-tip portions having a uniform or substantially uniform concentration c (x) of the burnt salt. In any case, the function f (x) is not constant over the entire interval.
- the actual concentration c (x) of the fire salt may deviate from the monotone function f (x) by a value of ⁇ c .
- This value ⁇ c takes into account the usual production and measurement tolerances of Brandsalzgehaltes.
- ⁇ c defines a certain corridor about an idealized curve f (x), which still allows an improvement over a constant Br of salt concentration, but possibly deviates locally to a moderate extent from the ideal monotonous course.
- the minimum for tar and nicotine is typically at a fire salt content between 1.5% and 5.0% by weight, for.
- Trisodium citrate typically at a Brandsalzgehalt of 1.5 wt .-% to 3.0 wt .-% and for tripotassium citrate at 3.5 wt .-% to 5.0 wt .-%, each based on the mass of the cigarette paper, so as it is used on the cigarette.
- the levels of smoke are beginning to rise again.
- a first possibility is to choose the content of the Brandsalzes at the filter end of the cigarette near the value at which - with an otherwise equal cigarette but with constant Brandsalzgehalt - a minimum tar and nicotine would be achieved and the content of the Brandsalzes then in the direction of to be lit end of the cigarette monotonically or at least approximately monotonically.
- a second possibility is to choose the content of the Brandsalzes at the filter end of the cigarette again close to the value at which a minimum tar and nicotine is achieved, but then to increase the content of the Brandsalzes in the direction of the end of the cigarette to be ignited.
- the Brandsalzgehalt which - with a constant Brandsalzgehalt - to minimal tar and nicotine values leads near the filter end of the tobacco rod, ie in a range of the cigarette, which produces the "strongest” features when smoking, while those Brandsalzgehalte, the - At constant Brandsalzgehalt - lead to higher levels of smoke in the vicinity of the lit end of the cigarette, ie where the trains are rather "weak".
- a “strong” or “weak” train is understood to mean that the levels of exhaustion of tar and nicotine are higher or lower this turn relative to the other strokes on the same cigarette.
- the total content of Brandsalzen in cigarette paper be constant, but is preferably, depending on which Brands salt outweighed in its effect on the Glasprofil, decrease or increase from the filter end to the tobacco end.
- L corresponds to the length of tobacco rod visible on the associated cigarette, ie, the length from the point where the tobacco rod emerges from under the tipping paper to the tip of the cigarette to be lit.
- a preferred course of the content of at least one Brandsalzes starting from the filter end of the visible tobacco rod, x 0, in the direction of the end of the cigarette to be lit, first an optional range in which the content of the Brandsalzes is constant, then followed by a linear increase or decrease of the content, and finally again an optional range with constant Brandsalzgehalt.
- the values L 1 and L 2 should be set so that the rise or fall is neither too steep nor too late to begin or end.
- the upper limit for L 1 is 2L / 3, preferably L / 2 and more preferably L / 3 has proven.
- the lower limit for L 1 is 0, and preferably L / 6.
- the upper limit for L 2 can usually be set at L, preferably at 5 L / 6. In general, however, it must always be true that L 1 is less than or equal to L 2 .
- L 1 L 2
- the invention can be realized in principle, this embodiment is not preferred. It is better to choose the length of the increase or decrease of Brandsalzgehalts, L 2 -L 1 , greater than L / 6, preferably greater than L / 3 and more preferably greater than L / 2.
- the length of the rise or fall, L 2 -L 1 , on the cigarette can not be greater than the length of the visible tobacco strand, so that L defines an upper limit for the difference L 2 -L 1 .
- L 2 -L 1 is therefore 9L / 10, and more preferably 4L / 5, and most preferably 2L / 3.
- c 0 or c L should be greater than or equal to 0% by weight, preferably greater than 0.2% by weight and particularly preferably greater than 0.5% by weight. With regard to the upper limits for c 0 and c L , 15% by weight is a possible choice, but 10% by weight and more preferably 7% by weight are preferred. If the at least one fire salt, the content of which changes on the cigarette paper, is a citrate, 5% by weight has also proved to be a very particularly preferred upper limit. These ranges apply to c 0 and c L independently of each other.
- c 0 is different from c L , ie that there is actually a change in the fire salt content, and preferably the amount of the difference c 0 -c L is greater than 2 ⁇ c.
- the value for ⁇ c again preferably corresponds to the abovementioned values.
- the cigarette paper is designed so that it can produce cigarettes, which have within the production and measurement tolerances the nominally same course of the content of at least one Brandsalzes along the visible tobacco rod.
- the cigarette paper is provided with one or more markings which allow the cut of the tobacco rod to be synchronized with the course of the fire salt content, whose positions are thus in a predetermined local relation to the curve c (x) of the fire salt content.
- the markings are preferably detectable by their action on electromagnetic waves, that is, for example, transmission, reflection, refraction or absorption of visible light, ultraviolet light or infrared radiation, and more preferably by an optical sensor, in particular an optical sensor which responds to reflected visible light to be detected.
- these markers are mounted on the cigarette paper so that they come to lie on the finished cigarette under the tipping paper and thus are not visible to the smoker.
- One possible method is to slightly color the composition with the one or more branding salts applied to the paper and to apply a fine but easily detectable line or other mark at the location where the tipping paper overlaps with the cigarette paper , Preferably, one will imprint the line or marking on the later side facing away from the tobacco, so that after production of the tobacco rod, the line or mark remains detectable for an optical sensor. Generally that's the top of the cigarette paper. It is also possible to place the line or mark on the tobacco-facing side of the cigarette paper, but then it is advisable to detect the line or mark on the cigarette paper before the tobacco rod is formed on the cigarette machine.
- This may mean that the course of the fire salt content c (x) along the running direction of the cigarette paper is periodically alternately applied, optionally with suitable spacing, in the normal and in the reverse direction, so that after cutting the double cigarette the Brandsalzprofil on the visible part of the tobacco strand at nominally equal to all cigarettes.
- the invention can also be applied to cigarettes which contain no filter.
- Base cigarette papers preferred for the invention consist of pulp fibers derived from wood, flax, hemp, esparto grass or other materials. Mixtures of pulp fibers of various origins can also be used. Preferred base cigarette papers have a basis weight of 10 g / m 2 to 60 g / m 2 , with the range of 20 g / m 2 to 35 g / m 2 being particularly preferred.
- the preferred base cigarette paper also contains inorganic mineral fillers which are added to the paper in a mass fraction of 10% to 45%.
- a particularly preferred filler is lime (calcium carbonate), but other oxides such as magnesium oxide and aluminum hydroxide and carbonates and mixtures thereof can also be used.
- Precipitated lime is preferred over geologically degraded lime for its purity and more uniform particle size.
- Cigarette papers without filler or with less than 10% filler are also common and conceivable for the invention, especially for non-machine-made cigarettes ("roll-your-own", "make-your-own”).
- Cigarette papers with more than 45% filler known, however, decreases with increasing filler content, the strength of the paper, and the paper tends to release dust during further processing, which is why this design is not preferred for use in machine-made cigarettes.
- the preferred base cigarette papers in the context of the invention have a natural air permeability, ie without further perforation, from 0 cm.sup.- 1 kPa.sup.- 1 to 350 cm.sup.- 1 kPa.sup.- 1 , preferably between 20 cm.sup.- 1 kPa.sup.- 1 and 200 cm min -1 kPa -1 and more preferably between 30 cm min -1 kPa -1 and 120 cm min -1 kPa -1 .
- the air permeability can be significantly increased, for example, over 300 cm min -1 kPa -1 or even over 1000 cm min -1 kPa -1 .
- Cigarette papers are typically made in rolls of, for example, between 0.3m and 5m widths and cut into reels having a cigarette circumference derived width, typically 9mm to 35mm, or an integer multiple of that width.
- the known from the prior art treatment of the cigarette paper with Brandsalzen comprises impregnation of the paper on the paper machine in the size or film press with a water-based solution of the Brandsalzes and subsequent drying. Also a soaking of the paper on a separate downstream of the paper machine device is conceivable.
- aqueous composition with a particularly high Brandsalzkonzentration is applied over the entire surface and uniformly on the overdried paper by means of a flexographic printing unit integrated in the paper machines and the paper is then rolled directly without further drying.
- the at least one fire salt is applied to the base cigarette paper in the form of a liquid composition, especially a solution, suspension or other form of mixture in a solvent.
- a liquid composition especially a solution, suspension or other form of mixture in a solvent.
- This order can preferably be achieved by a printing process or by spraying.
- the single-layer application is preferred over a multilayer.
- the printing process can be formed by gravure printing or flexographic printing.
- a gravure cylinder is preferably provided with wells, from which the composition to be printed is transferred to the base cigarette paper, wherein the volume of the wells and / or the density of the wells on the gravure cylinder, which is also referred to as "grid size of the wells" can, is or is chosen so that the desired location-dependent concentration c (x) of the Brandsalzes results.
- this process is used to modify a possibly even constant course of the content of at least one fire salt which is already present in the cigarette paper.
- processing steps such as printing on self-extinguishing tapes known in the art, may be carried out before, after or simultaneously with such treatment of the paper to create or modify a history of fire salt content.
- the composition used to prepare the history of the fire salt content comprises at least one fire salt and a solvent.
- solvent should not be considered as limited to solutions in the chemical sense.
- the fire salt may also be in suspension in a suspension or other form of the mixture in the solvent.
- water is preferred as a solvent over organic solvents because it leaves no trace of the taste of the cigarette in the paper and is safe in terms of fire hazard.
- the content of the Brandsalzes in the composition is at least 0.1 wt .-%, preferably at least 1 wt .-% and particularly preferably at least 2 wt .-%, and at most 15 wt .-%, preferably at most 10 wt .-% and particularly preferably 7% by weight, where the statements are to be understood as the mass of the anhydrous Brandsalzes based on the mass of the finished composition.
- the composition for example, for adjusting the viscosity, other substances, in particular polymers individually or in any mixture, included.
- polymers are cellulose derivatives, such as carboxymethyl cellulose, polysaccharides, such as starch or starch derivatives, or in particular also alginates, dextrins, guar or gum arabic.
- Such substances may be required, for example, for chromium-plated steel printing cylinders for intaglio printing in order to produce a film on the printing cylinder by the adapted viscosity so that the doctor applied to the printing cylinder does not scratch the printing cylinder.
- such substances may possibly be omitted in the composition.
- the viscosity of the composition can be characterized by the flow time, and it will, for example, for the gravure between 10 s and 40 s, preferably choose between 12 s and 35 s, measured as flow time from a cup with an opening of 4 mm according to ⁇ NORM EN ISO 2431: 2011.
- the measurement of the flow time should be done at the temperature at which the composition is used in the application process.
- the applied amount of the composition on the initial basis weight of the cigarette paper ie on the basis weight before the application of the composition must be coordinated.
- the applied amount of the composition should be at most 100% of the starting surface weight, preferably at most 80%, and more preferably at most 60%.
- the upper limits result from the amount of composition which can be applied to a cigarette paper without significantly impairing its processability, for example due to the reduced strength in the wet state.
- a lower limit results from the possibilities of the application method and is at least 0% of the starting surface weight, preferably at least 0.5% and particularly preferably at least 1%. Surfaces to which no order of the composition is made, of course, can also be provided.
- any type of dryer can be used, for example hot air dryer, infrared dryer, tunnel dryer, heated drying cylinder or even a drying by microwaves.
- the drying of the cigarette paper after the application of a water-based composition is preferably carried out by contact with one or more heatedeauzylindem. Treating the paper with waterborne compositions often results in the formation of wrinkles in the paper that can be efficiently reduced by drying with drying cylinders.
- one or more spreader rollers or smoothing devices can be provided which pull wrinkles from the paper during drying and are preferably arranged so that the paper passes over one or more spreader rollers or the smoothing devices prior to contact with the first drying cylinder.
- the spreader rollers or smoothing devices may also be arranged after one or more drying cylinders.
- these technologies can also be used, but the problem of wrinkling does not occur there or only to a considerably lesser extent.
- the subject invention depends in the circumferential direction only on the average content of the at least one Brandsalzes, which is why preferably the content of the at least one Brandsalzes in the cigarette paper in the transverse direction, i. is substantially constant in the circumferential direction on a cigarette made from the paper according to the invention. This prevents the cigarette from smoldering unevenly around its circumference, and ash or tobacco falling out or the ash image being deteriorated.
- an aqueous solution was prepared from the brine salt, as prepared for the prior art infusion of the paper.
- the content of Brandsalz in the solution resulted from the desired course of the content in the cigarette paper and the specifications of the application process.
- the application of the burn salts was carried out by gravure printing with an engraving of the gravure cylinder corresponding to the geometry of the desired course.
- the content of tar and nicotine in each train was calculated as the mean (M) in mg over all trains, the coefficient of variation (CoV) in% across all trains and the ratio V of the content between last and first train.
- the coefficient of variation is the standard deviation of the respective smoking value over all the traits of a cigarette divided by its mean and expressed as a percentage.
- the course of the Brandsalzgehalts according to the function f (x) are characterized by the parameters c 0 , c L , L 1 and L 2 and shown together with the results in Table 1.
- the course no. 1 corresponds to a constant Brandsalzgehalt of 1.4% and served as a comparison.
- V On the basis of the ratio V, a clear increase in the tar content of 62% and in the nicotine content of 41% can be seen.
- the coefficients of variation of tar and nicotine are 16.1% and 11.6%.
- the courses 2 to 6 show a sinking from the mouth end to the cigarette tip content of fire salt, while the courses 7 to 13 correspond to an increasing content of fire salt.
- the courses 12 and 13 is still in addition to a length of 10 mm and 5 mm respectively at the mouth end and the cigarette holder, the content of Brandsalz constant and in between linearly increasing.
- the lowest coefficient of variation of the tar content of gradients 2-6 is obtained at 12.5% on the course 3, ie a drop of 1.4% to 0% Brandsalzgehalt, while the same parameter for all courses 7-11 is already below this value, and for course 9, an increase from 1.4% to 3.5% Bratsalzgehalt, a minimum of 6.2% achieved.
- the fire salt content in the region of the filter end can be selected at least approximately so that it leads to a minimization of a specific smoke value, in particular nicotine or tar, and starting from this value in the direction of the Cigarette tip monotonically or approximately monotonically increases or decreases.
- the term "approximately chosen so” should also allow deviations from the ideal value of the Brandsalzkonzentration that less than 50%, preferably less than 30%, more preferably less than 15% of the ideal amount with the "per se same cigarette” is also a Cigarette made of the same base cigarette paper or of a similar base cigarette paper in which the grammage does not differ by more than 20% and the mean air permeability according to ISO 2965 by more than 15% from the same base cigarette paper.
- An exemplary cigarette 100 consists of a filter 101 encased in a tipping paper 102 which partially overlaps the tobacco rod 103, which in turn is enveloped by a cigarette paper 104. On the cigarette 100, the tipping paper 102 is then in the overlap zone over the cigarette paper 104.
- Diagram 110 arranged above the cigarette 100 shows an exemplary profile of the content of the at least one fire salt.
- On the y-axis 112 is the content of the at least one Brands salt applied.
- this is an idealized course of the deviations in reality, for example, by the usual production tolerances and Inhomogeneities of the paper are possible.
- an endless tobacco rod is formed which is cut into pieces having the length of the tobacco rod on the cigarette. Between each pair of such pieces, a double-length filter plug is inserted and glued to a doubly wide mouthpiece covering paper to form a double cigarette connected to the filter end. In a final cut, the double cigarette is divided into two cigarettes and turned over one of the two cigarettes, so that all running out of the cigarette machine cigarettes are the same orientation. This results in the need to choose the course of the content of at least one Brandsalzes along the cigarette paper web accordingly. Such an exemplary course is in FIG. 2 shown.
- the main direction of the cigarette paper is indicated by the arrow 201.
- the content of the at least one Brandsalzes is plotted and its course in the direction 201 is represented by the line 203.
- a piece of tobacco rod is made by cutting at each of the positions indicated by lines 204 and 205.
- the demarcated by the dashed lines 206 area 207 comes to rest on the double cigarette under the tipping paper and is thus not visible in normal use. In this area 207, the course of the content of at least one Brandsalzes plays no role, because this area is not usually smoked.
- brine salts according to the invention also leads to changes in the total tar and nicotine content even compared to the comparative cigarette with the constant course from Example 1. However, these changes can be compensated simply by adapting the filter ventilation or the filter without impairing the effect according to the invention ,
- the skilled person will be able to find a course of the invention content of at least one Brandsalzes with little experimental effort for a large class of Brandsalzen, so that the invention can be easily transferred to a variety of Brandsalze. Likewise, he will be able to find a desired course of the content of at least one Brandsalzes for different cigarette papers and cigarette designs.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Paper (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL14725200T PL2836089T3 (pl) | 2013-06-21 | 2014-05-21 | Papier papierosowy, który nadaje papierosowi równomierny profil zaciągania |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013106516.3A DE102013106516B3 (de) | 2013-06-21 | 2013-06-21 | Zigarettenpapier, das einer zigarette ein gleichmässiges zugprofil verleiht |
PCT/EP2014/060445 WO2014202319A1 (de) | 2013-06-21 | 2014-05-21 | Zigarettenpapier, das einer zigarette ein gleichmässiges zugprofil verleiht |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2836089A1 EP2836089A1 (de) | 2015-02-18 |
EP2836089B1 EP2836089B1 (de) | 2017-09-27 |
EP2836089B9 true EP2836089B9 (de) | 2017-12-27 |
Family
ID=50736110
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP14725200.1A Active EP2836089B9 (de) | 2013-06-21 | 2014-05-21 | Zigarettenpapier, das einer zigarette ein gleichmässiges zugprofil verleiht |
Country Status (11)
Country | Link |
---|---|
US (1) | US10154687B2 (ko) |
EP (1) | EP2836089B9 (ko) |
KR (1) | KR102228926B1 (ko) |
CN (1) | CN105324042B (ko) |
BR (1) | BR112015030114B1 (ko) |
DE (1) | DE102013106516B3 (ko) |
ES (1) | ES2647834T3 (ko) |
MY (1) | MY168057A (ko) |
PH (1) | PH12015502644B1 (ko) |
PL (1) | PL2836089T3 (ko) |
WO (1) | WO2014202319A1 (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106820257A (zh) * | 2016-12-13 | 2017-06-13 | 云南中烟工业有限责任公司 | 一种具有定位标识的分区涂布卷烟纸及涂布方法 |
CN106906698A (zh) * | 2016-12-13 | 2017-06-30 | 云南中烟工业有限责任公司 | 一种具有定位标识的渐变式涂布卷烟纸及涂布方法 |
CN107087812A (zh) * | 2017-05-28 | 2017-08-25 | 中国烟草总公司郑州烟草研究院 | 一种两段式新型卷烟 |
US20180343919A1 (en) * | 2017-06-06 | 2018-12-06 | Larry Gitman | Cigars with filters, and method of making the same |
DE102017119819A1 (de) | 2017-08-29 | 2019-02-28 | Delfortgroup Ag | Verfahren zum Aufbringen von Registermarken auf Umhüllungspapier für Rauchartikel |
KR102598360B1 (ko) * | 2018-07-02 | 2023-11-06 | 니뽄 다바코 산교 가부시키가이샤 | 비연소 가열형 흡연 물품용 권지, 비연소 가열형 흡연 물품 및 전기 가열형 흡연 시스템 |
CN109100264B (zh) * | 2018-10-22 | 2020-11-17 | 云南中烟工业有限责任公司 | 一种快速预测细支卷烟抽吸均匀性的方法 |
DE102019112777B3 (de) * | 2019-05-15 | 2020-08-06 | Delfortgroup Ag | Umhüllungspapier mit gebrauchsindikator für aerosolerzeugende artikel |
DE102020129301A1 (de) | 2020-07-01 | 2022-01-05 | Delfortgroup Ag | Umhüllungspapier mit verbesserter brandhemmung |
CN116172232B (zh) * | 2022-12-28 | 2024-09-06 | 浙江中烟工业有限责任公司 | 一种用于红外加热烟具的气溶胶生成制品 |
CN116289333B (zh) * | 2023-03-24 | 2024-08-13 | 浙江中烟工业有限责任公司 | 具有非线性模块化分布试剂的卷烟纸、制备方法及卷烟 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1605085A (en) * | 1926-03-26 | 1926-11-02 | Unger Louis | Cigarette paper |
US3667479A (en) * | 1970-01-19 | 1972-06-06 | Brown & Williamson Tobacco | Cigarette with modified paper wrapper |
BE791758A (fr) * | 1971-11-24 | 1973-05-22 | Olin Corp | Enveloppe chargee de carbone pour article a fumer et article a fumer presentant une telle enveloppe |
US3805799A (en) * | 1972-07-17 | 1974-04-23 | Philip Morris Inc | Cigarette ventilation achieved with coated wrapper |
US3911932A (en) * | 1974-07-31 | 1975-10-14 | Philip Morris Inc | Control of smoking delivery through cigarette paper porosity |
IE48028B1 (en) * | 1977-09-16 | 1984-09-05 | Gallaher Ltd | Smoking rod wrapper |
US4187862A (en) * | 1978-07-17 | 1980-02-12 | Cohn Charles C | Treatment of cigarette paper |
GB8302594D0 (en) * | 1983-01-31 | 1983-03-02 | Gallaher Ltd | Smoking rod wrapper |
US4726385A (en) * | 1986-05-09 | 1988-02-23 | The American Tobacco Company | Method of fabricating an all-tobacco cigarette controlling tar delivery and an all-tobacco cigarette |
US4730628A (en) * | 1986-07-21 | 1988-03-15 | R. J. Reynolds Tobacco Company | Cigarette rods having segmented sections |
US5168884A (en) * | 1991-04-12 | 1992-12-08 | Philip Morris Incorporated | Smoking articles using novel paper wrapper |
US5878754A (en) * | 1997-03-10 | 1999-03-09 | Schweitzer-Mauduit International, Inc. | Smoking article wrapper for controlling ignition proclivity of a smoking article |
JP4166365B2 (ja) * | 1999-04-09 | 2008-10-15 | 秀希 青木 | タバコ及び紙巻タバコ |
US20020179105A1 (en) * | 2001-02-26 | 2002-12-05 | Zawadzki Michael A. | Reduced ignition propensity smoking article |
US6929013B2 (en) * | 2001-08-14 | 2005-08-16 | R. J. Reynolds Tobacco Company | Wrapping materials for smoking articles |
US20080216852A1 (en) * | 2006-12-29 | 2008-09-11 | Philip Morris Usa Inc. | Banded cigarette paper with reduced ignition propensity |
RU2009147306A (ru) * | 2007-07-03 | 2011-08-10 | Швайцер-Маудит Интернешнл, Инк. (Us) | Курительные изделия, имеющие пониженную способность к поджиганию |
MX2010009078A (es) * | 2008-02-22 | 2010-09-10 | Schweitzer Mauduit Int Inc | Areas tratadas en una envoltura para reducir las caracteristicas de susceptibilidad a ignicion de un articulo para fumar. |
CN101983270B (zh) * | 2008-05-16 | 2012-11-21 | 日本烟草产业株式会社 | 低着火倾向的卷烟用卷纸的制造方法 |
DE102009030546B3 (de) * | 2009-06-25 | 2011-01-20 | Delfortgroup Ag | Filmbildende Zusammensetzung zum Aufbringen auf Zigarettenpapier, Zigarettenpapier, Zigarette sowie Verfahren zum Herstellen eines Zigarettenpapiers |
DE102010032814B4 (de) * | 2010-07-30 | 2013-12-05 | Delfortgroup Ag | Zigarettenpapier mit hoher Diffusionskapazität während des thermischen Zerfalls, Zigarette, Verfahren zur Herstellung eines Zigarettenpapiers sowie Verwendung eines wasserlöslichen Salzes |
CN102094364A (zh) * | 2010-11-24 | 2011-06-15 | 云南烟草科学研究院 | 一种低引燃倾向的卷烟纸及其制备方法 |
AU2013329037B2 (en) * | 2012-10-11 | 2016-10-13 | Schweitzer-Mauduit International, Inc. | Wrapper having reduced ignition proclivity characteristics |
-
2013
- 2013-06-21 DE DE102013106516.3A patent/DE102013106516B3/de active Active
-
2014
- 2014-05-21 EP EP14725200.1A patent/EP2836089B9/de active Active
- 2014-05-21 WO PCT/EP2014/060445 patent/WO2014202319A1/de active Application Filing
- 2014-05-21 ES ES14725200.1T patent/ES2647834T3/es active Active
- 2014-05-21 CN CN201480033915.0A patent/CN105324042B/zh active Active
- 2014-05-21 MY MYPI2015002771A patent/MY168057A/en unknown
- 2014-05-21 PL PL14725200T patent/PL2836089T3/pl unknown
- 2014-05-21 US US14/895,339 patent/US10154687B2/en active Active
- 2014-05-21 BR BR112015030114-2A patent/BR112015030114B1/pt active IP Right Grant
- 2014-05-21 KR KR1020157035581A patent/KR102228926B1/ko active IP Right Grant
-
2015
- 2015-11-26 PH PH12015502644A patent/PH12015502644B1/en unknown
Also Published As
Publication number | Publication date |
---|---|
MY168057A (en) | 2018-10-11 |
CN105324042A (zh) | 2016-02-10 |
EP2836089B1 (de) | 2017-09-27 |
PH12015502644A1 (en) | 2016-03-07 |
DE102013106516B3 (de) | 2014-10-09 |
EP2836089A1 (de) | 2015-02-18 |
ES2647834T3 (es) | 2017-12-26 |
BR112015030114A2 (pt) | 2017-07-25 |
CN105324042B (zh) | 2019-05-10 |
KR102228926B1 (ko) | 2021-03-17 |
WO2014202319A1 (de) | 2014-12-24 |
KR20160021124A (ko) | 2016-02-24 |
US20160120214A1 (en) | 2016-05-05 |
BR112015030114B1 (pt) | 2022-02-15 |
US10154687B2 (en) | 2018-12-18 |
PL2836089T3 (pl) | 2018-02-28 |
PH12015502644B1 (en) | 2016-03-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2836089B9 (de) | Zigarettenpapier, das einer zigarette ein gleichmässiges zugprofil verleiht | |
EP2552253B1 (de) | Perforiertes zigarettenpapier | |
EP3283686B1 (de) | Zigarettenpapier mit hohem kurzfaseranteil | |
DE102012108255B4 (de) | Zigarettenpapier mit homogenem optischen Eindruck, Verfahren zu seiner Herstellung sowie Zigarette | |
DE69806286T2 (de) | Rauchwarenumhüllung und Verfahren zu ihrer Herstellung zur Steuerung der Zündungneigung einer Rauchware | |
AT518224B1 (de) | Zigarettenpapier mit verbesserter Luftdurchlässigkeit | |
EP3298198B1 (de) | Umhüllungspapier mit durchscheinenden bereichen | |
EP0325920A1 (de) | Schnell oder von selbst erlöschende Cigarette | |
DE102017119819A1 (de) | Verfahren zum Aufbringen von Registermarken auf Umhüllungspapier für Rauchartikel | |
WO2010149380A1 (de) | Filmbildende zusammensetzung zum aufbringen auf zigarettenpapier | |
EP2597975B1 (de) | Zigarettenpapier mit hoher diffusionskapazität während des thermischen zerfalls | |
EP0716816B1 (de) | Segment-Filtercigarette | |
DE102013109386B3 (de) | Effizient herstellbares Zigarettenpapier für selbstverlöschende Zigaretten, Verfahren zu seiner Herstellung sowie eine Zigarette | |
WO2014082796A1 (de) | Verbessertes zigarettenpapier für selbstverlöschende zigaretten | |
EP0325921A1 (de) | Cigarette | |
DE69326368T2 (de) | Zigarette | |
EP2761086A1 (de) | Zigarettenpapier mit plättchenförmigem füllstoff | |
DE102021104011B4 (de) | Strukturiertes filtermaterial für nikotinabgabeprodukte |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20141013 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: BACHMANN, STEFAN Inventor name: VOLGGER, DIETMAR |
|
DAX | Request for extension of the european patent (deleted) | ||
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20170224 |
|
GRAJ | Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR1 |
|
GRAL | Information related to payment of fee for publishing/printing deleted |
Free format text: ORIGINAL CODE: EPIDOSDIGR3 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R108 |
|
INTC | Intention to grant announced (deleted) | ||
GRAR | Information related to intention to grant a patent recorded |
Free format text: ORIGINAL CODE: EPIDOSNIGR71 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
INTG | Intention to grant announced |
Effective date: 20170818 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 931155 Country of ref document: AT Kind code of ref document: T Effective date: 20171015 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2647834 Country of ref document: ES Kind code of ref document: T3 Effective date: 20171226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171227 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20170927 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171227 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20171228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180127 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 5 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20180628 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20180531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180531 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180521 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180521 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180531 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20140521 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 Ref country code: MK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20170927 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20170927 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230313 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20240521 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20240610 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 20240521 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: RO Payment date: 20240520 Year of fee payment: 11 Ref country code: FR Payment date: 20240527 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20240424 Year of fee payment: 11 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20240502 Year of fee payment: 11 |