EP2817114A1 - Ensemble de noyau de fonderie pour la fabrication d'une aube de turbomachine, procédé de fabrication d'une aube et aube associés - Google Patents
Ensemble de noyau de fonderie pour la fabrication d'une aube de turbomachine, procédé de fabrication d'une aube et aube associésInfo
- Publication number
- EP2817114A1 EP2817114A1 EP13704418.6A EP13704418A EP2817114A1 EP 2817114 A1 EP2817114 A1 EP 2817114A1 EP 13704418 A EP13704418 A EP 13704418A EP 2817114 A1 EP2817114 A1 EP 2817114A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cavity
- core
- blade
- leading edge
- trailing edge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/147—Construction, i.e. structural features, e.g. of weight-saving hollow blades
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C21/00—Flasks; Accessories therefor
- B22C21/12—Accessories
- B22C21/14—Accessories for reinforcing or securing moulding materials or cores, e.g. gaggers, chaplets, pins, bars
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C7/00—Patterns; Manufacture thereof so far as not provided for in other classes
- B22C7/02—Lost patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/02—Sand moulds or like moulds for shaped castings
- B22C9/04—Use of lost patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/10—Cores; Manufacture or installation of cores
- B22C9/103—Multipart cores
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/18—Hollow blades, i.e. blades with cooling or heating channels or cavities; Heating, heat-insulating or cooling means on blades
- F01D5/187—Convection cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/10—Cores; Manufacture or installation of cores
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/20—Manufacture essentially without removing material
- F05D2230/21—Manufacture essentially without removing material by casting
- F05D2230/211—Manufacture essentially without removing material by casting by precision casting, e.g. microfusing or investment casting
Definitions
- Foundry core assembly for the manufacture of a turbomachine blade, method of manufacturing a blade and associated blades
- the invention relates generally to the field of turbomachines, and more particularly to the turbine blades of these turbomachines and their manufacture.
- the turbine blades are subjected to high thermal stresses due to the heat of the gases in which they are immersed at the outlet of the combustion chamber, and need to be cooled to withstand these temperatures. They are therefore hollow and traversed by internal cavities in which circulates a cooling gas taken from the output of a stage of a compressor.
- a turbine blade of a turbomachine comprises an aerodynamic surface (or blade) extending between a blade root and a blade head.
- the blade has a leading edge disposed opposite the flow of the hot gases from the combustion chamber of the turbomachine, and a trailing edge opposite the leading edge and side walls intrados and extrados which connect the leading edge at the trailing edge.
- the internal cavities extend over the height of the blade, and comprise, upstream to downstream in the flow direction of the combustion chamber gases, a leading edge cavity and an edge cavity. leak, adjacent to the leading edge and the trailing edge of the blade respectively, and at least one central cavity, extending between the leading edge cavity and the trailing edge cavity. These cavities are supplied with cooling gas by pipes connecting them to the foot of the dawn.
- the dawn further comprises, at the level of its head, a hollow form or bathtub, which is defined by the extension of the intrados and extrados walls, as well as by a bottom wall which closes the internal cavities.
- the blades are conventionally produced by a technique known as lost wax foundry.
- This technique schematically consists of making a wax dawn blank in which are drowned ceramic cores which reproduce the cavities to come. The dawn wax is then embedded in a shell, for example refractory material, then the cores are removed chemically, leaving in their place the desired internal and bathtub cavities. Implementations of this method are in particular described in documents FR 2 875 425, FR 2 874 186, or FR 2 957 828 in the name of the Applicant,
- the cores for these modern turbine blades are constituted by cavity internal cores, conventionally having the form of columns, which are positioned side by side and held together by conventional means.
- a core generally comprises a first core member for forming the cavities and a second core member for forming the tub, the second core member being connected to the first core member by alumina or quartz connecting rods.
- These rods are intended to maintain the parts of the core between them and to stiffen the assembly thus formed, as well as to participate in the realization of dusting holes in the upper part of the blade, These rods are stuck in the holes that they are intended to generate in the bottom of the bath.
- the dedusting holes allow the circulation of the cooling gas in the cavities and the evacuation of various particles entering the turbomachine.
- Such turbine blades are adapted to minimize energy losses. They include a blade that can be broken down into stacked blade sections in a stacking direction along the blade. In the case of the blade head with offset head sections, the stack of sections at the head of the blade is shifted towards the intrados wall, preferably progressively.
- the blade may comprise a cavity at its head, open towards its free end and delimited by the bottom wall and a flange which s' extends between the leading edge and the trailing edge.
- the stacking of blade sections of the blade at this rim then has an offset in the direction of the underside, this offset being more and more important when approaching the free end of the head of the blade. 'dawn. The dawn also includes cooling channels, inclined relative to the intrados, and connecting the internal cavities to the intrados wall.
- the intrados wall of the blade may further have a projecting portion, the outer face is inclined relative to the remainder of the intrados of the blade and has at its end, facing the rim, an end face.
- the bottom wall is then connected to the intrados wall at the end face of the projecting portion, and the cooling channels can be arranged in the projecting portion of the intrados wall so that they open out. on the end face of the protruding portion, the distance between the axis of the cooling channels and the outer limit of the free end of the intrados side edge being greater than zero.
- the invention proposes a core assembly for the manufacture of a turbomachine blade cooled by circulation of fluid in internal cavities, comprising a first elongate core element for the formation of different internal cavities and a second element core for forming a bath cavity, the second core member being adapted to be disposed in the extension of the first core member.
- the first core element comprises an internal leading edge cavity core, at least one central cavity inner core and an internal trailing edge cavity core for respectively forming, upstream to downstream in the direction of a gas flow in the turbine, a leading edge cavity, at least one central cavity and a trailing edge cavity of the blade.
- the core of the central internal cavity adjacent to the inner core of the trailing edge cavity has, in the immediate vicinity of the second core member, a bulge extending in the direction of the core of the leading edge cavity.
- Such a solution makes it possible to anchor at least one connecting rod at an enlarged zone of the first core element (at the level of the bulge), and consequently to make turbine blades for turbomachines having a slice offset. head in a reliable process with a low kernel scrap rate.
- the invention also relates to a blade obtained by means of such a foundry core assembly, and a manufacturing method using such a set.
- FIG. 1 is a general view in section and in semi-perspective of an example of turbine blade with offset of the head sections according to the invention
- FIG. 2 is a perspective representation illustrating a foundry core according to one embodiment of the invention
- FIG. 3 is a representation of a detail of the upper part of the foundry core of FIG. 2 and connecting rods between the different core elements.
- FIG. 4a is a side view of an example of a blade with an offset in head cups according to the prior art
- FIG. 4b is a top view of the blade of FIG. 4a, on which are visible the cavities along planes X1 and X2,
- FIG. 5a is a side view of an example of blade with an offset in head sections according to the invention.
- FIGS. 1 and 5a there is seen a turbine engine turbine blade 1 comprising a blade 10 extending between a blade root 1 1 and a blade head 12, and having a leading edge 13, a trailing edge 14 opposite to the leading edge, lateral surfaces intrados and extrados 15, and internal cavities 19a-19e separated by inter-cavity walls 20, which extend along the height of the blade 1.
- the dawn may for example have an advanced blade tip of the type "offsets cuts at the head" in accordance with the French patent application filed November 17, 201 1 in the name of the Applicant No. FR 1 1 60465.
- the blade 1 comprises a leading edge cavity 19a, one or more central cavities 19b, 19c, 19d, (in this case three in the case of dawn 1 shown in the figure, namely a first upstanding central cavity 19b, a downward central cavity 19c, and a second upstanding central cavity 19d, which together form an internal cavity "trombone"), and a trailing edge cavity 19th.
- the blade 1 further comprises, at its head 1 1, a bath 18, whose bottom wall 17 closes the internal cavities 19a-19e cooling.
- the inter-cavity wall 20 separating the central cavity 19d adjacent to the trailing edge cavity 19e and the subsequent cavity towards the leading edge 13 is shaped, in the vicinity of the bottom wall 17 of the bath 18, with an offset 16 in the direction of the leading edge 13.
- the blade 1 when the blade 1 comprises only one central cavity 19d, it is then the inter-cavity wall 20 which separates this single central cavity 19d from the leading edge cavity 19a which can be shaped, at near the bottom wall 17 of the bath, with an offset 16 towards the leading edge 13. Because of this offset 16 relative to the remainder of the intercavity wall 20, the central cavity 19d which is adjacent to the trailing edge cavity 19e has a bulge 34 in the vicinity of the bottom wall 17, said cavity 19d being wider. at the level of the blade head 12 only at the level of the blade root 1 1. The particular shape of this central cavity 19d simplifies the manufacture of the blade 1.
- the intercavity wall 20 is offset at the offset 16 to the bottom wall 17, to widen the entire upper part of the central cavity 19d.
- the foundry core assembly 30 for the manufacture of such a turbomachine blade has a suitable complementary shape and comprises a first core element 31, taking the shape of the cavities 19a-19e, as well as a second core element 32, taking again the shape of the bath 18.
- the two core elements 31 and 32 are for example ceramic.
- the second core element 32 is connected to the first core element 31 by connecting rods 40 which may for example be made of alumina or quartz.
- the first core element 31 is of generally elongated shape according to the height of the blade 1 and comprises a series of internal cores 31a, 31b, 31c, 31d and 31e intended to form respectively the leading edge cavities 19a, the central cavity (s) 19b, 19c and 19d, and the trailing edge cavity 19e, respectively.
- the second core member 32 is disposed above the first core member 31, and is separated therefrom by connecting rods 40 positioned to provide dust holes 35 in the inner cores 31a through 31c. .
- the inner core 19d defining the central cavity 31 d adjacent to the core 31 e of the trailing edge cavity has, at least in an area in the immediate vicinity of the second core member 32, a bulge 34 towards the inner core 31 a of the leading edge cavity.
- the core internal 31 c of the corresponding central cavity is therefore wider at this level, for example from 30% to 60% wider, as visible in Figures 4a to 5b.
- the maximum width d x of the core of the internal cavity 31 d adjacent to the core of the trailing edge cavity 31 e at the plane X 2 is of the order 3.4 mm.
- the maximum width d y of the core of the inner cavity 31 d which is adjacent to the trailing edge internal cavity core 31 e at the plane Y 2 , for a similar blade with offset head section but including a bulge 34 according to the invention, can be of the order of 5 mm (or about 50% wider).
- the space available for implanting a connecting rod 40 in this cavity core 31 d is therefore much greater than in the vanes of the prior art, which makes it possible to increase the depth of anchoring and the thickness of the cores around the connecting rods 40 and avoids the formation of cracks in the core elements 31, 32, and thus significantly reduce the scrap rate of the blades in the manufacture.
- the inner core 31c of central cavity immediately adjacent towards the leading edge cavity 31a is in turn shaped with a counter-form 33 complementary so that the inter-cavity wall 20 made between these two internal cores 31c and 31d present the offset 16 described above in the direction of the leading edge 13 of the blade 1.
- the first core 31 when the blade 1 comprises only one central cavity 19d, the first core 31 then comprises only one inner core 31c of central cavity, and it is then the inner core 31a of the cavity leading edge which is immediately adjacent to this inner core 31 d of central core. It is therefore the leading edge inner core 31a which is shaped with the complementary counterform so that the inter-cavity wall 20 formed between these two inner cores 31a and 31d has the offset 16 described below. above in the direction of the leading edge 13 of the dawn 1.
- the bulge 34 and the counter-form 33 are local, and extend only at the level of the upper part of the internal nuclei 31 b-31 d (respectively 31 a, in the case of a blade comprising a single central cavity), the core 31 d adjacent to the core 31 e of the trailing edge cavity being wider at this bulge 34 than at its level. lower part.
- the height of the bulge 34 is sufficient to allow anchoring of the connecting rods 40 at the bulge 34, and the realization of dust holes 35 in the wall 17 forming the bottom of the bath 18 without formation of cracks in the inner cores 31 b-31 d. Furthermore, the bulge 34 extends to the upper wall of the inner core 31 e of central cavity.
- the diameter of the holding rods 40 may be chosen to be equal to the desired diameter for the dusting holes 35 in the final piece, in order to avoid an additional step of finishing the blade 10 (plugging the holes). after the lost wax casting step.
- the dedusting holes 35 are oblique and may, for example, be oriented towards the leading edge 13 of the blade 1. This orientation is however not limiting, only the respect of the diameter of the holding rods 40 is important to ensure the evacuation of dust in the blade 1.
- the connecting rods 40 are thus oriented obliquely with respect to the general direction in which the second core element 32 extends through which they pass to form the dedusting holes 35 of the second core element 32.
- the second core element 32 may further comprise bosses 36 (FIG. 2) in the upper part in order to improve the anchoring of the connecting rods 40.
- the foundry core assembly 30 as illustrated in Figures 2 and 3 is then used to make a wax blank, which is then embedded in a shell, and then the cores are removed to form the various cavities 19a. -19th and the bathtub 18.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Architecture (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1251620A FR2986982B1 (fr) | 2012-02-22 | 2012-02-22 | Ensemble de noyau de fonderie pour la fabrication d'une aube de turbomachine, procede de fabrication d'une aube et aube associes |
| PCT/EP2013/052785 WO2013124189A1 (fr) | 2012-02-22 | 2013-02-12 | Ensemble de noyau de fonderie pour la fabrication d'une aube de turbomachine, procédé de fabrication d'une aube et aube associés |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2817114A1 true EP2817114A1 (fr) | 2014-12-31 |
| EP2817114B1 EP2817114B1 (fr) | 2019-04-03 |
Family
ID=47716029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13704418.6A Active EP2817114B1 (fr) | 2012-02-22 | 2013-02-12 | Ensemble de noyau de fonderie pour la fabrication d'une aube de turbomachine, procédé de fabrication d'une aube et aube associés |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9890644B2 (fr) |
| EP (1) | EP2817114B1 (fr) |
| JP (1) | JP6170510B2 (fr) |
| CN (1) | CN104144757B (fr) |
| BR (1) | BR112014020620B1 (fr) |
| CA (1) | CA2864576C (fr) |
| FR (1) | FR2986982B1 (fr) |
| RU (1) | RU2616700C2 (fr) |
| WO (1) | WO2013124189A1 (fr) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10370980B2 (en) * | 2013-12-23 | 2019-08-06 | United Technologies Corporation | Lost core structural frame |
| FR3025444B1 (fr) | 2014-09-04 | 2016-09-23 | Snecma | Procede de production d'un noyau ceramique |
| CN104550735A (zh) * | 2015-02-08 | 2015-04-29 | 哈尔滨鑫润工业有限公司 | 百万千瓦核电机组末级超长导叶片精铸方法 |
| FR3034128B1 (fr) * | 2015-03-23 | 2017-04-14 | Snecma | Noyau ceramique pour aube de turbine multi-cavites |
| FR3037829B1 (fr) * | 2015-06-29 | 2017-07-21 | Snecma | Noyau pour le moulage d'une aube ayant des cavites superposees et comprenant un trou de depoussierage traversant une cavite de part en part |
| FR3047767B1 (fr) * | 2016-02-12 | 2019-05-31 | Safran | Procede de formation de trous de depoussierage pour aube de turbine et noyau ceramique associe |
| FR3048374B1 (fr) * | 2016-03-01 | 2018-04-06 | Snecma | Noyau pour le moulage d'une aube ayant des cavites superposees et comprenant un conduit de depoussierage traversant une cavite de part en part |
| FR3058917B1 (fr) * | 2016-11-18 | 2020-06-12 | Safran Aircraft Engines | Noyau complexe de fonderie pour une aube multi-cavites |
| FR3072415B1 (fr) * | 2017-10-17 | 2020-11-06 | Safran Aircraft Engines | Aube de turbine creuse a prelevement d'air de refroidissement reduit |
| US11566527B2 (en) | 2018-12-18 | 2023-01-31 | General Electric Company | Turbine engine airfoil and method of cooling |
| US11499433B2 (en) | 2018-12-18 | 2022-11-15 | General Electric Company | Turbine engine component and method of cooling |
| US11174736B2 (en) | 2018-12-18 | 2021-11-16 | General Electric Company | Method of forming an additively manufactured component |
| US10767492B2 (en) | 2018-12-18 | 2020-09-08 | General Electric Company | Turbine engine airfoil |
| US11352889B2 (en) | 2018-12-18 | 2022-06-07 | General Electric Company | Airfoil tip rail and method of cooling |
| US10844728B2 (en) | 2019-04-17 | 2020-11-24 | General Electric Company | Turbine engine airfoil with a trailing edge |
| US11053803B2 (en) | 2019-06-26 | 2021-07-06 | Raytheon Technologies Corporation | Airfoils and core assemblies for gas turbine engines and methods of manufacture |
| US11041395B2 (en) | 2019-06-26 | 2021-06-22 | Raytheon Technologies Corporation | Airfoils and core assemblies for gas turbine engines and methods of manufacture |
| FR3100143B1 (fr) * | 2019-08-30 | 2021-11-12 | Safran | Procédé amélioré de fabrication d’un noyau céramique pour la fabrication d’aubes de turbomachine |
| US11773726B2 (en) | 2019-10-16 | 2023-10-03 | Rtx Corporation | Angled tip rods |
| US11143035B2 (en) * | 2019-10-16 | 2021-10-12 | Raytheon Technologies Corporation | Angled tip rods |
| US12006836B2 (en) | 2021-07-02 | 2024-06-11 | Rtx Corporation | Cooling arrangement for gas turbine engine component |
| US11913353B2 (en) | 2021-08-06 | 2024-02-27 | Rtx Corporation | Airfoil tip arrangement for gas turbine engine |
| US11905847B1 (en) | 2022-10-21 | 2024-02-20 | Rtx Corporation | Airfoil with venturi tube |
| KR102831611B1 (ko) * | 2023-11-16 | 2025-07-08 | 에이치디현대마린엔진 주식회사 | 세라믹 코어를 이용한 터빈 블레이드 제조방법 |
| KR102900031B1 (ko) * | 2023-11-16 | 2025-12-15 | 에이치디현대마린엔진 주식회사 | 터빈 블레이드 제조용 세라믹 코어의 용접 지그 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1160465A (fr) | 1956-11-02 | 1958-07-16 | Fleurs, plantes artificielles, etc., pour aquariums | |
| US4770608A (en) * | 1985-12-23 | 1988-09-13 | United Technologies Corporation | Film cooled vanes and turbines |
| US5296308A (en) | 1992-08-10 | 1994-03-22 | Howmet Corporation | Investment casting using core with integral wall thickness control means |
| US6974308B2 (en) * | 2001-11-14 | 2005-12-13 | Honeywell International, Inc. | High effectiveness cooled turbine vane or blade |
| US7014424B2 (en) * | 2003-04-08 | 2006-03-21 | United Technologies Corporation | Turbine element |
| US7175391B2 (en) * | 2004-07-08 | 2007-02-13 | United Technologies Corporation | Turbine blade |
| FR2874186B1 (fr) | 2004-08-12 | 2008-01-25 | Snecma Moteurs Sa | Procede de fabrication par moulage a cire perdue de pieces comportant au moins une cavite. |
| FR2875425B1 (fr) | 2004-09-21 | 2007-03-30 | Snecma Moteurs Sa | Procede de fabrication d'une aube de turbomachine, assemblage de noyaux pour la mise en oeuvre du procede. |
| FR2889088B1 (fr) * | 2005-07-29 | 2008-08-22 | Snecma | Noyau pour aubes de turbomachine |
| US8105031B2 (en) * | 2008-01-10 | 2012-01-31 | United Technologies Corporation | Cooling arrangement for turbine components |
| US8172533B2 (en) * | 2008-05-14 | 2012-05-08 | United Technologies Corporation | Turbine blade internal cooling configuration |
| US8092178B2 (en) * | 2008-11-28 | 2012-01-10 | Pratt & Whitney Canada Corp. | Turbine blade for a gas turbine engine |
| FR2957828B1 (fr) * | 2010-03-26 | 2012-10-05 | Snecma | Extraction des tiges d'alumine utilisees pour le maintien du noyau lors de la fabrication d'aubes de turbine. |
| FR2961552B1 (fr) * | 2010-06-21 | 2014-01-31 | Snecma | Aube de turbine a cavite de bord d'attaque refroidie par impact |
| FR2982903B1 (fr) * | 2011-11-17 | 2014-02-21 | Snecma | Aube de turbine a gaz a decalage vers l'intrados des sections de tete et a canaux de refroidissement |
-
2012
- 2012-02-22 FR FR1251620A patent/FR2986982B1/fr active Active
-
2013
- 2013-02-12 BR BR112014020620-1A patent/BR112014020620B1/pt active IP Right Grant
- 2013-02-12 CN CN201380010550.5A patent/CN104144757B/zh active Active
- 2013-02-12 EP EP13704418.6A patent/EP2817114B1/fr active Active
- 2013-02-12 WO PCT/EP2013/052785 patent/WO2013124189A1/fr not_active Ceased
- 2013-02-12 US US14/380,459 patent/US9890644B2/en active Active
- 2013-02-12 RU RU2014138091A patent/RU2616700C2/ru active
- 2013-02-12 JP JP2014558064A patent/JP6170510B2/ja active Active
- 2013-02-12 CA CA2864576A patent/CA2864576C/fr active Active
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2013124189A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2864576A1 (fr) | 2013-08-29 |
| EP2817114B1 (fr) | 2019-04-03 |
| CN104144757B (zh) | 2017-05-10 |
| CN104144757A (zh) | 2014-11-12 |
| US20150132139A1 (en) | 2015-05-14 |
| RU2616700C2 (ru) | 2017-04-18 |
| CA2864576C (fr) | 2019-12-31 |
| JP2015508025A (ja) | 2015-03-16 |
| RU2014138091A (ru) | 2016-04-10 |
| FR2986982A1 (fr) | 2013-08-23 |
| BR112014020620B1 (pt) | 2019-05-14 |
| US9890644B2 (en) | 2018-02-13 |
| WO2013124189A1 (fr) | 2013-08-29 |
| JP6170510B2 (ja) | 2017-07-26 |
| FR2986982B1 (fr) | 2024-07-05 |
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