EP2794137B1 - Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir - Google Patents
Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir Download PDFInfo
- Publication number
- EP2794137B1 EP2794137B1 EP12808763.2A EP12808763A EP2794137B1 EP 2794137 B1 EP2794137 B1 EP 2794137B1 EP 12808763 A EP12808763 A EP 12808763A EP 2794137 B1 EP2794137 B1 EP 2794137B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning
- roll
- water
- cleaning device
- rolls
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0269—Cleaning
- B21B45/0275—Cleaning devices
- B21B45/0278—Cleaning devices removing liquids
- B21B45/0284—Cleaning devices removing liquids removing lubricants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B28/00—Maintaining rolls or rolling equipment in effective condition
- B21B28/02—Maintaining rolls in effective condition, e.g. reconditioning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
- B21B27/06—Lubricating, cooling or heating rolls
- B21B27/10—Lubricating, cooling or heating rolls externally
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B28/00—Maintaining rolls or rolling equipment in effective condition
- B21B28/02—Maintaining rolls in effective condition, e.g. reconditioning
- B21B28/04—Maintaining rolls in effective condition, e.g. reconditioning while in use, e.g. polishing or grinding while the rolls are in their stands
Definitions
- the invention relates to a cleaning device and a method for removing a lubricant from the rolls of a roll stand See, for example DE 101 48 401 A ,
- Roll stands especially in hot strip mills, typically include nip lubrication equipment, usually mounted to the upstream side of the mill in the area of the work roll.
- a lubricant is applied to the work roll, as a lubricant usually a water-oil emulsion is sprayed.
- the lubricant significantly reduces the coefficient of friction between the respective roller and the rolling stock. This reduces the rolling forces and the surface quality of the rolling stock is improved. As a result, few rolling steps are required and / or the profile and the flatness of the rolling stock can be better influenced by a greater degree of freedom in the rolling force. In addition, energy consumption is reduced and the production spectrum increased.
- the rolls Before tapping the rolling stock, which is for example a rolled strip, however, the rolls, in particular the work rolls, must be free of lubricant in order to increase the coefficient of friction of the roll again, otherwise there is the risk that the rolling stock will not be drawn into the roll stand, which leads to an interruption of the rolling process. For this reason, the roll gap lubrication is switched off just before unloading the rolling stock, thereby burns the lubricant due to the high belt temperature completely in the remaining Walzenumassin. Only after renewed threading of the next rolling stock, the roll gap lubrication is switched on again. The head and foot of the rolling stock are therefore rolled ungeschmiert. This, however, adversely affects the Rolling, since the foot of the rolling stock, which is usually the coldest, requires the highest rolling force.
- WO 2006/089730 A1 a method for cleaning a metal strip is known in which the metal strip is subjected to ultrasonic cleaning in which the metal strip is passed through a container filled with a liquid.
- the invention has for its object to increase the efficiency in the cleaning of the rolls of the mill stand, without increasing the water consumption for cooling the rollers during operation of a roll stand substantially.
- the object is achieved by a cleaning device with the features of claim 1.
- the object is also achieved according to the invention by a method solved with the features of claim 9.
- the invention is based on the finding that the pressure of the cleaning liquid can be reduced, but still there is an intensive surface cleaning with a high efficiency by the cleaning is supplemented by ultrasonic waves, which propagate with the cleaning liquid to the surface of the roller and increase the cleaning effect .
- Ultrasound is known to work even in small wells of the surface and mechanically bring adhering particles or substances into solution. Thanks to the ultrasonic waves, the risk of damage to the surface of the roller is minimized.
- notches on the surface of the roller, such as fire cracks can be cleaned efficiently.
- the cleaning liquid is applied in particular to the roll surface at a pressure of 5 to 15 bar, the pressure being about ten times lower than the required pressure according to FIG JP 2002-178011-A ,
- the at least one ultrasonic generator is integrated in particular in the cleaning device, and surrounded by the cleaning liquid, so that the ultrasonic waves are delivered directly to the cleaning liquid and forwarded with this.
- the result is a fluid bridge between the ultrasonic generator and the roller surface, which transmits the sound waves.
- This type of cleaning can be applied to both the work rolls and the back-up rolls of a rolling stand.
- water is used as the cleaning agent. Since water is chemically neutral, the use of water is gentle on the rollers. In addition, water is anyway a wide application in the rolling process, so that in a rolling mill large amounts of water are available.
- the main advantage of such a cleaning is that the lubrication can be used for the whole band foot and for the essential part of the band head. This reduces the rolling force, resulting in a significant energy saving effect.
- the product range is broadened: with an identical design of the system (drives, hydraulics and stands), harder steel products can be rolled.
- a particularly good synergistic effect which increases the efficiency of cleaning, is achieved by branching off the cleaning water from the cooling water circuit for the rolling mill, the water being supplied via a supply line to the cleaning device and this supply line being a branch of the cooling water circuit for the roll.
- the water consumption for the rolling stand can be kept constant during the cleaning phase, there is only a redistribution of the water by a portion of the cooling water of the cleaning device is supplied. This results in the advantage that the roller temperature increases somewhat, so that the cleaning performance is supported by the higher roller temperature at which the lubricant dissolves better from the roller surface.
- the ultrasonic generator for generating ultrasonic waves having a frequency between 20 kHz and 2 MHz, in particular between 35 kHz and 200 kHz, set.
- This frequency range has proved to be particularly advantageous for the ultrasonic cleaning of fine dirt.
- at least two ultrasonic generators of different frequency are provided, e.g. an ultrasonic generator with 40 kHz and an ultrasonic generator with 80 kHz frequency.
- a sealing element which faces a nip between the rollers is, so that the sealing element seals the roller against an outflowing liquid in the direction of rotation of the roller.
- an opening facing away from the roll gap is provided on the cleaning device, through which the cleaning water is conveyed to the surface of the roller.
- the cleaning device is arranged at least upstream of the respective roller.
- cleaning devices can also be provided on the outlet side. Since the cleaning device is characterized by a manageable number of additional components, it requires a small installation space and can be easily installed in a protected installation position in existing components of the mill stand.
- the cleaning device is integrated in particular in a chock of the work rolls or in a chilled beam for the rolling stand.
- at least one inlet side arranged cleaning device is provided in reversibly operated rolling stands are two cleaning devices per roll useful - an inlet and an outlet side.
- the cleaning water contains an emulsifier.
- the cleaning performance is increased because lubricant particles thrown up during the cleaning process do not settle again so easily on the roll surface can.
- the same emulsifier is used, which is admixed with the lubricant. In this way, it is ensured that no additional resources must be made available, but the cleaning of the roll surface is carried out only with the help of resources that are required and permitted anyway for the operation of the rolling mill.
- the temperature of the cleaning water is between 0 ° C and 70 ° C.
- the temperature of the cleaning water corresponds to an ambient temperature, so that no additional heating effort for the cleaning water is required, or such a heating effort is limited.
- the cleaning device is preferably active only between a tapping of a preceding rolling stock by means of the roll stand and a tapping of a subsequent rolling stock.
- a tapping of a preceding rolling stock by means of the roll stand and a tapping of a subsequent rolling stock.
- the cleaning process is interrupted and normal operation of the rolling mill resumed.
- a rolling stand 2 which comprises two work rolls 4 and two support rollers 6. Between the work rolls, a roll gap 8 is formed, through which rolled goods, run in the embodiment shown rolling belts.
- Fig. 1 is a preceding, already rolled rolled strip 10 with a reduced thickness, shown, the foot part is still in the nip 8, and a subsequent, prepared for rolling rolled strip 12th
- a lubricant is supplied to the work rolls 4 through lubricant nozzles 14.
- the nip 8 must be free of lubricant, so that the rolled strip 12 can be easily drawn into the rolling stand 2.
- a cleaning device 16 per drive roller 4 per a cleaning device 16 is provided with the aid of a cleaning liquid, in the illustrated embodiment, water is applied to the surfaces of the work rolls 4. The cleaning water is applied only to a part of the surface. By rotating the work rolls 4, however, the effective range of the cleaning water shifts around the circumference of the respective work roll 4, so that ultimately the entire surface area of the work rolls 4 is exposed to the cleaning water.
- an ultrasonic generator 18 is integrated, with the aid of which ultrasonic waves are generated, which are conducted by means of the water from the cleaning device 16 to the surface of the work rolls 4.
- the respective cleaning device 16 is installed 16 in the cooling circuit of the work rolls 4 and attached to an inlet-side fender 20 in the illustrated embodiment.
- the function of the mudguard 20 is to prevent cooling water from reaching the rolled strip 10, 12.
- the coolant circuit has per work roll on the inlet and outlet side a coolant supply 22, which opens into a chilled beam 24, which extends substantially over the length of the work rolls perpendicular to the plane of the drawing. From the coolant supply 22, a feed line 26 is also branched off on the inlet side, through which water is introduced into the cleaning device 16.
- the structure of the cleaning device 16 is the FIGS. 2 and 3 refer to.
- the cleaning device 16 has a cavity 28 which is filled with water during operation.
- the ultrasonic generator 18 is arranged, so that the ultrasonic generator 18 is in particular continuously washed by the water during operation, which is conveyed in the direction of the roll surface.
- a sealing element 32 which is formed in the manner of a sealing lip arranged. In particular, by its contact with the roll surface, the sealing element prevents water from the cleaning device 16 during the rotational movement of the work roll 4 down to the rolled strip 10, 12, flows.
- an opening 36 is formed through which the water is passed from the cleaning device 16 in the opposite direction to the direction of rotation of the work roll 4 to the roll surface.
- the lower roller 4 shows the opening 36 down, so that additionally acts gravity and amplifies the flow of cleaning water.
- openings 36 facing away from the roll gap 8 openings which are not shown here in detail can also be provided in the region of the front sides of the work rolls 4. In this case, the lateral Outflow of the cleaning water, for example, collected via lines or baffles and can be recycled.
- baffles 38 are provided in the cleaning device 16, which cause a uniform flow through the cavity 38, so that the formation of dead zones in the cavity 28 is suppressed.
- the water transmits the sound waves from the ultrasonic generator 18 to the roll surface and thereby forms a kind of liquid bridge between the ultrasonic generator 18 and the work roll 4.
- the ultrasonic waves in the water, the lubricant is atomized at the roll surface and removed via the water.
- the water used as cleaning water is conveyed to the work roll 4 at a pressure of about 10 bar and in particular has a temperature which corresponds to the temperature resulting from the process control and / or the plant condition. Thus, in particular, no further heating measures for the removal of the lubricant from the roll surface are required.
- the fluidic connection between the cleaning device 16, the cooling water circuit and a lubricant circuit of the roll stand 2 is in Fig. 4 shown.
- the reference numeral 40 is in Fig. 4 denotes a lubricant tank and the reference numeral 42 an emulsifier tank.
- the lubricant, the emulsifier, and water from a scaffold cooling water supply conduit 48 are brought together in a mixer 44 and supplied via a lubricant conduit 46 to the lubricant nozzle 14, which in the embodiment shown is located below the mudguard 20 in the vicinity of the nip 8.
- Cooling water is introduced from the water supply line 48 into the cooling water line 22, which is sprayed onto the surface of the work roll 4 via the cooling bars 24. A portion of the cooling water is diverted via the supply line 26 before it has reached the chilled beam 24.
- the cooling water flow stands in relation to the cleaning stream between 10: 1 to 2: 1.
- the part of the water in the feed line 26 is mixed in a second mixer 50 with the emulsifier from the emulsifier tank 42 and then introduced into the cleaning device 16.
- an emulsifier line 52 leads directly from the emulsifier tank 42 to the second mixer 50, which likewise is arranged on the protective plate 20 like the cleaning device 16.
- the emulsifier increases the efficiency of the cleaning water.
- the supply line 26 opens into the second mixer 50th
- the cooling water and the cleaning water, which runs off the side of the work rolls 4, is finally collected in a cooling water sump 54 and discharged from the rolling mill 2 for processing.
- Characteristic of the cooling water circuit according to Fig. 4 is that with the aid of the valves 56a and 56b, the water supply in the lines 22 and 26 depending on the rolling process can be controlled dynamically and in a short time.
- the water supply to the cleaning device 16 is interrupted, so that the entire amount of water in the cooling water line 22 is used for cooling purposes.
- the cleaning device 16 is only briefly switched on between a tapping of the preceding rolled strip 10 and a tapping of the following rolled strip 12.
- a portion of the water in the cooling water line 22 is diverted into the supply line 26 and finally enters the cleaning device 16.
- the cleaning device 16 flows at least from the inlet side chilled beam 24 less water to the roll surface.
- this has the positive side effect that the lubricant is easier to solve by heating the roll surface.
- the rolling stand 2 is characterized not only by an efficient operation thanks to the increase in the coefficient of friction when starting the rolling bands 10, 12, but also by a minimized energy requirement and by a potentially constant water requirement.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Metal Rolling (AREA)
Claims (16)
- Dispositif de nettoyage (16) destiné à la suppression d'un lubrifiant à partir des cylindres (4) d'une cage de laminoir (2), comprenant au moins un générateur d'ultrasons (18) destiné à la génération d'ondes ultrasonores, dans lequel les ondes ultrasonores peuvent être dirigées à l'aide d'une eau de nettoyage vers la surface des cylindres (4),
caractérisé en ce qu'
une conduite d'amenée (26) est incluse pour l'eau de nettoyage, la conduite d'amenée (26) étant une déviation d'un circuit d'eau de refroidissement pour la cage de laminoir (2), de sorte qu'une partie de l'eau de refroidissement peut être amenée au dispositif de nettoyage, moyennant quoi la température des cylindres augmente pendant la phase de nettoyage et ainsi la puissance de nettoyage peut être favorisée par le biais de la température plus élevée des cylindres. - Dispositif de nettoyage (16) selon la revendication 1,
dans lequel le générateur d'ultrasons destiné à la génération d'ondes ultrasonores est configuré avec une fréquence comprise entre 20 kHz et 2 MHz, en particulier entre 35 et 200 kHz. - Dispositif de nettoyage (16) selon l'une des revendications précédentes,
comprenant un élément d'étanchéité (32) tourné vers un calibre plat (8) entre les cylindres (4), qui rend étanche au moins un cylindre (4). - Dispositif de nettoyage (16) selon l'une des revendications précédentes,
dans lequel une ouverture (36) opposée à un calibre plat (8) entre les cylindres (4) est prévue pour l'eau de nettoyage. - Dispositif de nettoyage (16) selon l'une des revendications précédentes,
qui est agencé au moins côté entrée du cylindre respectif (4). - Dispositif de nettoyage (16) selon l'une des revendications précédentes,
dans lequel l'eau de nettoyage contient un émulsifiant. - Dispositif de nettoyage (16) selon l'une des revendications précédentes,
dans lequel la température de l'eau de nettoyage se situe entre 0°C et 70°C. - Dispositif de nettoyage (16) selon l'une des revendications précédentes,
qui est actif entre une coulée et une passe initiale consécutive au moyen de la cage de laminoir (2). - Procédé destiné à la suppression d'un lubrifiant à partir des cylindres (4) d'une cage de laminoir (2), dans lequel de l'eau de nettoyage est acheminée vers la surface des cylindres (4) et au moyen de l'eau de nettoyage des ondes ultrasonores sont dirigées vers la surface des cylindres (4),
caractérisé en ce que
l'eau de nettoyage est déviée à partir d'un circuit d'eau de refroidissement pour la cage de laminoir (2), de sorte qu'une partie de l'eau de refroidissement est amenée au dispositif de nettoyage, moyennant quoi la température des cylindres augmente pendant la phase de nettoyage et ainsi la puissance de nettoyage est favorisée par le biais de la température plus élevée des cylindres. - Procédé selon la revendication 9,
dans lequel une fréquence des ondes ultrasonores est réglée pour être comprise entre 20 kHz et 2 MHz, en particulier entre 35 et 200 kHz. - Procédé selon la revendication 9 ou 10,
dans lequel au moins un cylindre (4) est rendu étanche au moyen d'un élément d'étanchéité (32) par rapport à une sortie de l'eau de refroidissement dans la direction de rotation du cylindre (4). - Procédé selon l'une des revendications 9 à 11,
dans lequel l'eau de nettoyage est acheminée par le biais d'une ouverture du dispositif de nettoyage (16), opposée à un calibre plat (8) entre les cylindres (4), vers la surface du cylindre (4) correspondant. - Procédé selon l'une des revendications 9 à 12,
dans lequel les cylindres respectifs (4) sont nettoyés au moins côté entrée. - Procédé selon l'une des revendications 9 à 13,
dans lequel un émulsifiant est incorporé dans l'eau de nettoyage. - Procédé selon l'une des revendications 9 à 14,
dans lequel la température de l'eau de nettoyage est réglée entre 0°C et 70°C. - Procédé selon l'une des revendications 9 à 15,
dans lequel le dispositif de nettoyage (16) est activé entre une coulée et une passe initiale consécutive au moyen de la cage de laminoir (2).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12808763.2A EP2794137B1 (fr) | 2012-02-01 | 2012-12-12 | Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12153475.4A EP2623223A1 (fr) | 2012-02-01 | 2012-02-01 | Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir |
PCT/EP2012/075215 WO2013113441A1 (fr) | 2012-02-01 | 2012-12-12 | Dispositif de nettoyage et procédé permettant d'éliminer un lubrifiant des cylindres d'une cage de laminoir |
EP12808763.2A EP2794137B1 (fr) | 2012-02-01 | 2012-12-12 | Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2794137A1 EP2794137A1 (fr) | 2014-10-29 |
EP2794137B1 true EP2794137B1 (fr) | 2016-03-09 |
Family
ID=47469942
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12153475.4A Withdrawn EP2623223A1 (fr) | 2012-02-01 | 2012-02-01 | Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir |
EP12808763.2A Not-in-force EP2794137B1 (fr) | 2012-02-01 | 2012-12-12 | Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12153475.4A Withdrawn EP2623223A1 (fr) | 2012-02-01 | 2012-02-01 | Dispositif de nettoyage et procédé de suppression d'un lubrifiant à partir des cylindres d'une cage de laminoir |
Country Status (5)
Country | Link |
---|---|
US (1) | US20150020845A1 (fr) |
EP (2) | EP2623223A1 (fr) |
CN (1) | CN104080552B (fr) |
BR (1) | BR112014019035A8 (fr) |
WO (1) | WO2013113441A1 (fr) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10383129B2 (en) * | 2013-10-31 | 2019-08-13 | Sony Corporation | Communication system, communications device, infrastructure equipment and method of allocating resources for performing device-to-device(D2D) communication |
US10374819B2 (en) * | 2014-09-19 | 2019-08-06 | Xiaomi Inc. | Methods and devices of accessing wireless network |
EP3357660A1 (fr) * | 2017-02-06 | 2018-08-08 | R. Faerch Plast A/S | Procédé et système permettant de maintenir la propreté d'un cylindre de calandre |
TWI620905B (zh) * | 2017-06-14 | 2018-04-11 | 住華科技股份有限公司 | 除液裝置 |
BR112020022197A2 (pt) | 2018-06-13 | 2021-02-02 | Novelis Inc. | sistemas e métodos para remoção de materiais viscosos no processamento de artigos de metal |
AU2019287519A1 (en) | 2018-06-13 | 2020-02-27 | Novelis Inc. | System and method for containing viscous materials in roll processing |
DE102018209854A1 (de) * | 2018-06-19 | 2019-12-19 | Sms Group Gmbh | Emulsionsumlaufanlage |
EP4286068A1 (fr) * | 2022-06-02 | 2023-12-06 | Primetals Technologies Austria GmbH | Procédé et dispositif pour fonctionnement d'un cylindre de travail lors du laminage à chaud |
US20240149318A1 (en) * | 2022-11-09 | 2024-05-09 | Primetals Technologies USA LLC | Quick-Change Roll Cooling Header Cartridge with Real-Time Feedback of Operational Data |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6125915A (en) * | 1994-03-30 | 2000-10-03 | Golden Aluminum Company | Method of and apparatus for cleaning a continuous caster |
JP2002178011A (ja) * | 2000-12-06 | 2002-06-25 | Sumitomo Metal Ind Ltd | 鋼板の熱間潤滑圧延方法およびその装置 |
DE10145902A1 (de) * | 2001-09-18 | 2003-04-10 | Andreas H Stranz | Verfahren und Vorrichtung zum Reinigen der Oberfläche eines in Einbau- und Betriebsstellung befindlichen Maschinen- oder Anlagenteils |
DE10148401A1 (de) * | 2001-09-29 | 2003-04-17 | Karl Beis | Einrichtung zum Reinigen von Oberflächen mittels Ultraschall |
CN1938109A (zh) * | 2004-04-05 | 2007-03-28 | Bfivdeh-应用研究院有限公司 | 从带材的表面去除液体的方法和装置 |
DE102005008939A1 (de) * | 2005-02-26 | 2006-09-21 | Sms Demag Ag | Verfahren und Vorrichtung zum Reiningen eines Metallbandes |
EP2143824B1 (fr) * | 2007-05-01 | 2015-04-15 | Nippon Steel & Sumitomo Metal Corporation | Procédé de rinçage d'une tôle d'acier et appareil de rinçage en continu de tôle d'acier |
CN201217016Y (zh) * | 2008-06-23 | 2009-04-08 | 宝山钢铁股份有限公司 | 带钢表面清洗加工的超声波处理装置 |
CN101556267B (zh) * | 2009-05-22 | 2013-07-10 | 东北大学 | 一种模拟铁素体不锈钢热轧粘辊的实验方法及其装置 |
-
2012
- 2012-02-01 EP EP12153475.4A patent/EP2623223A1/fr not_active Withdrawn
- 2012-12-12 BR BR112014019035A patent/BR112014019035A8/pt not_active IP Right Cessation
- 2012-12-12 US US14/376,281 patent/US20150020845A1/en not_active Abandoned
- 2012-12-12 CN CN201280068760.5A patent/CN104080552B/zh not_active Expired - Fee Related
- 2012-12-12 EP EP12808763.2A patent/EP2794137B1/fr not_active Not-in-force
- 2012-12-12 WO PCT/EP2012/075215 patent/WO2013113441A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
BR112014019035A8 (pt) | 2017-07-11 |
WO2013113441A1 (fr) | 2013-08-08 |
US20150020845A1 (en) | 2015-01-22 |
CN104080552A (zh) | 2014-10-01 |
EP2623223A1 (fr) | 2013-08-07 |
BR112014019035A2 (fr) | 2017-06-20 |
EP2794137A1 (fr) | 2014-10-29 |
CN104080552B (zh) | 2016-04-13 |
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