EP2788197A1 - Sicherheitspapier, daraus erhältliches wertdokument und verfahren zum herstellen derselben - Google Patents
Sicherheitspapier, daraus erhältliches wertdokument und verfahren zum herstellen derselbenInfo
- Publication number
- EP2788197A1 EP2788197A1 EP12797714.8A EP12797714A EP2788197A1 EP 2788197 A1 EP2788197 A1 EP 2788197A1 EP 12797714 A EP12797714 A EP 12797714A EP 2788197 A1 EP2788197 A1 EP 2788197A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- substrate
- lacquer
- security
- repellent
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/324—Reliefs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/328—Diffraction gratings; Holograms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/355—Security threads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0036—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers dried without curing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0045—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or film forming compositions cured by mechanical wave energy, e.g. ultrasonics, cured by electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams, or cured by magnetic or electric fields, e.g. electric discharge, plasma
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- B42D2033/04—
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- B42D2033/18—
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- B42D2033/24—
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- B42D2033/30—
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- B42D2033/32—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
Definitions
- the invention relates to a security paper for the production of value documents, such as banknotes, passports, identity documents or the like, having a planar substrate which is provided on at least one surface with at least one counterfeit protection means, wherein the counterfeiting means for extending the life and the ability to run provided with a paint.
- the invention further relates to a value document with such a security paper and method for producing the security paper and the value document.
- Security documents such as banknotes, stocks, bonds, certificates, vouchers, checks, high-quality admission tickets, as well as other papers that are prone to forgery, such as passports or other identification documents, are often provided with counterfeit securities as a safeguard, verifying the authenticity of the value document and at the same time serve as protection against unauthorized reproduction.
- the tamper-evident means may, for example, be present in the form of a security thread wholly or partly embedded in a banknote or in the form of a security strip or patch applied to the banknote.
- Optically variable security features give the viewer a different image impression under different viewing angles.
- the security features may be in the form of diffraction-optically effective microstructures or nanostructures, such as in the case of conventional embossing holograms or others Hologram-like diffraction structures (see, for example, the publications EP 0 330 733 AI or EP 0 064 067 AI).
- EP 0 238 043 A2 and DE 36 09 090 A1 describe a security thread made of a transparent material, on the surface of which a grid of several parallel cylindrical lenses is embossed. The thickness of the security thread is chosen so that it corresponds approximately to the focal length of the cylindrical lenses.
- a printed image is applied register-accurate, wherein the printed image is designed taking into account the optical properties of the cylindrical lenses.
- Moire magnification arrangements have also been used as security features.
- Such a moire magnification arrangement is disclosed in document WO 2006/087138 A1 or in DE 10 2005 028 162 A1.
- the counterfeit protection means disclosed in WO 2006/087138 A1 has at least one first and one second security feature.
- the first authenticity feature comprises a first arrangement with a plurality of focusing elements, which are present in a first grid, and a second arrangement with a multiplicity of microscopic structures, which are present in a second grid.
- the first and second arrays are arranged one another such that the microscopic structures of the second array are magnified as viewed through the focussing elements of the first array.
- Such a magnification effect is also referred to as Moire magnification.
- moiré magnification thereafter denotes a phenomenon which, when viewing a grid of identical image objects, is represented by a lenticular grid of approximately ben grid occurs. As with any pair of similar rasters, this results in a moire pattern, in which case each of the moiré fringes appears in the form of an enlarged and rotated image of the repeated elements of the image raster.
- EP 0 256 170 B2 proposes to provide printed bills with a protective layer which contains cellulose ester or cellulose ether to a greater extent and, to a lesser extent, micro-sized wax, and which is applied over the entire surface to the bills.
- the micronized wax is thereby dispersed by kneading or mixing with oil, a colorant or a mixture thereof.
- the sheets freshly printed with the protective layer can be stacked without difficulty, without black color rubbing off from a sheet to the underlying sheet.
- Optically variable counterfeit protection means in particular security elements with a microoptical representation arrangement with microstructures and microimage elements for enlarged imaging of the microstructures, eg microlens or micro hollow mirror arrays, can not be provided with a dirt-repellent protective layer due to a possible impairment of the optical effect.
- the partial application of a dirt-repellent protective layer to a banknote equipped with an optically variable counterfeit security device stalt that the protective layer has a recess in the area of the anti-counterfeiting agent, circulating leads to disturbing dirt spots in the region of the recess (in particular in the case of a window thread).
- the object of the invention is to avoid the disadvantages of the prior art and, in particular, to provide a security paper which has improved soil repellency in the region of the optically variable counterfeiting device and at the same time ensures an attractive visual appearance of the counterfeiting device.
- a first aspect of the invention relates to a security paper for producing value documents, such as banknotes, passports, identity documents or the like, having a planar substrate which is provided on at least one surface with at least one counterfeit protection means, wherein the counterfeiting means on a carrier film with opposing first and second main surfaces based and the at least partially visually recognizable, at least partially visually recognizable, the substrate lying opposite the first main surface of the carrier film has an optically variable security feature, and
- the first lacquer may contain an additional feature substance, in particular luminescent substance, which does not substantially influence the perceptibility of the optically variable security feature.
- Suitable luminescent substances are, for example, nanoscale luminescent substances.
- the luminescent substance can be detectable, for example, in the UV range.
- the first lacquer provided with a luminescent substance may at least partially have a special design or pattern at least at its edges.
- the tamper-evident means may in particular be in the form of a security strip, a security thread (for example a window thread) or a patch.
- the radiation-curing first lacquer is preferably a UV-curable lacquer which is high-gloss after crosslinking, i. has only a very low scattering and thus only a very slight matting.
- a crosslinked UV varnish can be obtained from a UV-crosslinking varnish which contains no dulling agents and, as a result of its varnish composition, has only a very slight scattering after drying and thus only a very slight dulling.
- the substrate may be provided with a water-based primer layer on its surface lying outside the counterfeiting protection means, said dirt layer having said dirt, which does not substantially influence the perceptibility of the optically variable security feature. may optionally partially overlaps in the region of the partial surface of the substrate surrounding the counterfeiting protection means.
- the primer layer may according to an alternative in
- the primer layer can be present all over and the counterfeit protection means (for example a patch or a strip) can be arranged above the primer layer.
- the primer layer can be provided with a UV-crosslinking lacquer forming a cover layer which protects the substrate from physical and chemical influences.
- the substrate may be provided on its surface lying outside the counterfeiting protection means with a dirt-repellent second lacquer which
- the perceptibility of the optically variable security feature substantially non-influencing, soil-repellent radiation-curing first lacquer in the region of the anti-counterfeiting surrounding partial surface of the substrate optionally partially overlaps
- Dispersion varnish is based, which may optionally contain crosslinking agent, and having a matt impression after drying, in particular a gloss of less than 20 gloss units, preferably less than 15 gloss units at 60 °, measured by means of gloss meters according to DIN 67530 has,
- the soil-repellent second paint is based on a physically drying, water-based dispersion paint which cures by removal of the dispersion medium and is an aqueous dispersion of a polyacrylic resin and / or a polyurethane resin.
- a second aspect of the invention relates to a document of value, such as a banknote, a passport, a document of identification or the like, with a security paper according to the first aspect of the invention, wherein the substrate is located on its surface outside the counterfeiting device, in particular in the case of the presence of the optionally existing dirt-repellent second paint or the optionally present water-based primer layer on the surface of the same or the same, is printed with signs or patterns.
- the substrate is provided with a water-based primer layer on its surface lying outside the counterfeiting protection means, which comprises the said dirt-repellent radiation-curing first varnish, which does not substantially influence the perceptibility of the optically variable security feature, in the area surrounding the counterfeiting means
- the substrate may be partially overlapped (or the primer layer is spaced from the first resist, or the primer layer is over the entire area and the counterfeit protection agent is disposed on the primer layer), wherein the primer layer is printed with indicia and the primer layer is coated with a UV- capping layer.
- crosslinking third paint is provided, which protects the substrate from physical and chemical influences.
- the UV-crosslinked third varnish may also contain characters or patterns are printed (eg, a citation can be printed).
- a third aspect of the invention relates to a method for producing a security paper, in particular for a value document, such as a banknote, a passport, a passport document or the like, comprising
- a planar substrate which is provided on at least one surface with at least one counterfeit protection means, wherein the counterfeit protection means is based on a carrier film with opposing first and second major surfaces and the at least partially visually recognizable, the substrate opposite first major surface of the carrier film a having optically variable security feature;
- the tamper-evident means be in the form of a security strip, a security thread or a patch.
- the radiation-curing first lacquer is a UV-curable lacquer which is high-gloss after crosslinking.
- the method preferably comprises the additional step of applying a water-based primer layer to the surface of the substrate lying outside the counterfeiting protection means in such a way that the mentioned, the perceptibility of the optically variable security feature substantially not influencing, dirt-repellent radiation-curing first coat in the area surrounding the counterfeit security part surface of the substrate may be partially overlapped layer of the water-based primer layer.
- the primer layer may, according to an alternative, be arranged spaced apart from the tamper-evident means (so that there is no overlapping arrangement with respect to the first lacquer). According to a further alternative, the primer layer can be applied over the whole area in a first step and the counterfeiting agent (eg a patch or a strip) can be arranged in a second step above the primer layer.
- the method may comprise the additional step of applying a soil-repellent second paint to the surface of the substrate external to the anti-counterfeiting agent, such that said, the perceptibility of the optically variable security feature in Substantially non-influencing, dirt-repellent, radiation-curing first lacquer in the region of the partial surface of the substrate surrounding the counterfeit protection agent is optionally partially overlapped by the de-staining second lacquer, wherein the dirt-repellent second lacquer
- the soil-repellent second paint is based on a physically drying, water-based dispersion paint which cures by removal of the dispersant and which is an aqueous dispersion of a polyacrylic resin and / or a polyurethane resin.
- a fourth aspect of the invention relates to a method of manufacturing a value document, such as a banknote, a passport, a passport document or the like
- the printing of the surface of the substrate lying outside the counterfeiting protection means in particular in the case of the presence of the optionally present dirt-repelling second varnish or the possibly present water-based primer layer, the printing of the surface of the same or the same, with signs or patterns.
- the method preferably comprises
- the invention is based on the finding that the contamination resistance of an optically variable counterfeit protection agent can be substantially improved by application of a radiation-curing, high-gloss finish after crosslinking in a small layer thickness of 0.7 to 2 ⁇ m, preferably 0.7 to 1.5 ⁇ m, without noticeably deteriorating the optical effect of the counterfeiting agent, in particular the light / dark contrast, the image sharpness and the magnification and movement effect.
- a varnish can be obtained from a UV-crosslinking varnish which contains no dulling agents and, as a result of its varnish composition, has only a very slight scattering after drying and thus only a very slight dulling.
- matting agent refers to substances which influence the surface of a coating in such a way that its degree of gloss decreases Matting agents may be of inorganic or organic origin.
- the first class includes amorphous preparations on silicic acid or silicate basis, to the latter, inter alia, Al, Zn, Ca or Mg stearates and similarly built compounds and finally products of waxy type, eg
- micronized polypropylene waxes Inorganic matting agents usually have a mean particle size of 0.5 to 20 ⁇ . Organic matting agents usually have a mean grain size of 0.04 to 10 microns.
- the measurement of the degree of gloss for example using devices of the reflectometer type, is known to the person skilled in the art (see, for example, the gloss measurement according to DIN 67530 at a measuring angle of 60 °).
- the radiation-curing "first" lacquer may in particular be a UV-crosslinking lacquer, which may be free-radically or cationically crosslinking UV lacquers
- the UV-crosslinking lacquer preferably has at least one monomeric acrylate (mono-, di-, tri-and or optionally tetrameric acrylate) and optionally additives or processing aids, such as defoamers, dispersing agents, UV curing accelerators, viscosity modifiers, leveling agents and stabilizers preference is given to an acrylate mixture which is prepared by reacting at least one prepolymeric acrylate of average molecular weight of, for example, 500 to 2000 with the monomeric acrylate (mono-, di-, tri- and / or tetrameric acrylate), the paint comprising 100 parts by weight of the Acrylate paint (calculated without additive or processing aid) and 1 to 10 parts by weight of a UV Initia or UV initiator mixture contains or consists of these components.
- the radiation-curing "first" coating may in particular be based on mixtures of mono- and / or difunctional monomeric acrylates, prepolymeric acrylates, and tri- and / or tetrafunctional monomeric acrylates.
- An example of the composition of the radiation-curing first coating is listed below:
- Composition 1 is a composition of Composition 1:
- polyester acrylate prepolymer (“Laromer PE 55 F” from BASF) 10% by weight of trimethylolpropane triacrylate (“Laromer TMPTA” from BASF) 20% by weight of hexanediol diacrylate (“Laromer HDDA "of BASF)
- the radiation-curing first coating can be applied as a spot coating in the flexo, offset or high-pressure process.
- the application can be made in the paper mill or in the printing house.
- the anti-fouling agent based on a carrier film can be in the form of a security strip, a security thread or in the form of a label or patch, for example.
- the optically variable security feature with which the anti-counterfeiting agent is provided can be present, for example, in the form of diffraction-optically active microstructures or nanostructures, such as for example in the case of conventional embossed holograms or other hologram-like diffraction structures (see, for example, the publications EP 0 330 733 A1 or EP 0 064 067 A1).
- the security feature can be based, in particular, on lens systems (see, for example, the publications EP 0 238 043 A2 and DE 36 09 090 A1) or on hollow micromirror arrays (see, for example, DE 10 2009 035 361 A1).
- the forgery-proofing means can be visually recognizable to the observer completely or only partially.
- An example of an only partially visually recognizable counterfeit security device is a window security thread (eg a microlens thread) which protrudes in window areas on the surface of a banknote, while it is embedded in the intervening web areas inside the banknote (see, eg, FIG WO 2004/097112 AI).
- the dirt-repellent radiation-curing first lacquer is not applied in register over the anti-counterfeiting agent, but the lacquer also covers a part of the security paper substrate which surrounds the anti-counterfeiting agent and forms, as it were, an edge area for the counterfeit protection means (the phrase "surrounding the anti-counterfeiting agent
- the tamper-evident means may be circumferentially surrounded by the first lacquer, such as in the case of a patch-shaped tamper-evident means, in the case of a security thread or tuft extending from one edge of the note to the other
- the anti-counterfeiting agent is surrounded on two sides by the first varnish, ie the anti-counterfeiting means and two elongated, adjacent to the anti-counterfeiting means surfaces of the substrate are mi t the first paint provided.
- the partial surface of the substrate surrounding the anti-counterfeiting means ie the edge region, can in particular have a width of 0.3 to 10 mm, preferably 1 to 5 mm, measured from the outer edge of the counterfeiting protection means to the outer edge of the adjacent partial surface of the substrate ,
- the security paper substrate on its surface lying outside the counterfeit protection means with a conventional dirt-repellent second paint
- the dirt-repellent radiation-curing first paint in the partially overlaps the anti-counterfeiting agent surrounding partial surface of the substrate. If there is no overlap, there is a risk of uncoated areas, which lead to visible dirt edges in circulation.
- the second varnish may be based on a physically drying, water-based dispersion varnish, which may optionally contain crosslinking agent and has a matt impression after drying, in particular a gloss of less than 20 gloss units, preferably less than 15 gloss units at 60 °, measured by means of gloss meters DIN 67530, (see, for example, the publications WO
- a UV-crosslinking lacquer which has a matt impression after crosslinking, in particular a gloss of less than 20 gloss units, preferably less than 15 gloss units at 60 °, measured by gloss meters according to DIN 67530, has.
- the paint may in particular contain matting agents. The presence of a matting agent improves the printability of the substrate.
- the lacquer components described above with reference to the first lacquer are suitable.
- aqueous dispersions based on a polyacrylic resin and / or a polyurethane resin are preferred.
- the paint can be based in particular on a one-component polyurethane system or one-component polyacrylate system with pre-crosslinked polyurethane or polyacrylate. But it can also be used blocked polyurethane having chemically bonded to the polymer chains isocyanate groups. The isocyanate groups can be regenerated at elevated temperatures, which are generally used in the security printing process. Two-component polyurethane systems or polyacrylate systems crosslinkable by using multifunctional reagents such as melamine / formaldehyde precondensates may also be used.
- the polyurethane may in particular be of the aliphatic polyester type and / or of the aliphatic polyether type. It is also possible to use aliphatic polycarbonate polyurethane.
- the polyacrylate may generally be, for example, of the aromatic type, such as a styrene / acrylic copolymer. Gemi- see of a polyurethane and a polyacrylate can be used for example in a weight ratio of 90:10 to 10:90, preferably 75:25 to 25:75.
- the physically drying aqueous dispersions may contain additional ingredients such as catalysts, cosolvents, dispersing aids, defoamers, viscosity modifiers, extenders, fluorescent and / or iridescent additives and / or surfactants.
- a typical physically drying aqueous dispersion comprises, for example, a polyurethane of the aliphatic polyester or an aliphatic polyether type having a polyurethane content of from 2 to 70% by weight, preferably from 5 to 30% by weight.
- the second lacquer may preferably be applied to the security paper by means of the flexographic printing process.
- the coating layer is expediently applied in a coating amount of 1 to 8 g / m 2 . Examples of physically drying compositions of the second paint are listed below, wherein additionally matting agents are present (for example in a proportion of 1 to 20 wt .-% based on the aqueous dispersion): Composition 2:
- Composition 4 is a composition having Composition 4:
- the security paper is printed with characters or patterns on the surface of the substrate which is located outside the counterfeiting means.
- a printed image can be printed on the second lacquer.
- the security paper substrate may be provided on its surface outside the anti-counterfeiting agent with a water-based primer layer containing the dirt-repellent radiation-curing first lacquer in the area optionally partially overlapping the partial surface of the substrate surrounding the counterfeit security device.
- the primer layer may, according to an alternative, be arranged at a distance from the counterfeit protection means (so that there is no overlapping arrangement with respect to the first varnish).
- the primer layer can be present over the entire surface and the counterfeit protection means (for example a patch or a strip) can be arranged above the primer layer.
- the primer layer serves as an adhesion promoter between the substrate and one or more layers or layers arranged above the primer layer.
- the primer layer has a barrier effect against liquids.
- the water-based primer layer may be provided with a UV-crosslinking varnish (the "third" varnish) which forms a top-layer coating printed by characters and / or patterns.
- Suitable water-based primer layers are known in the art (see, for example, EP 1 595 029 Bl). It is in particular a physically drying lacquer layer which makes contact with the underlying substrate and closes its pores.
- the primer layer can be formed, for example, by a water-based dispersion lacquer layer.
- the lacquer layer is elastic, so that cracking in the lacquer layer by mechanical movements or sources of the fiber, for example by moisture absorption, are avoided.
- the haptic typical for banknotes ie the bending stiffness and the sound, is retained longer under stress.
- the elastic paints comprise polyurethane systems which give the paint its elasticity.
- aqueous primer layer may optionally contain crosslinking agents, eg aziridine.
- Suitable UV-crosslinking lacquer layers with high physical and chemical resistance are known in the art (see, for example, US Pat EP 1 595 029 B1).
- the paint may contain, in particular matting agents (eg 10 to 15 wt .-%).
- matting agents eg 10 to 15 wt .-%).
- the paint components of the UV-crosslinking third paint for example, the paint components described above with respect to the first paint are suitable. It is preferred that the UV-crosslinking third lacquer has silicones and / or waxes for improving the soil-repelling properties.
- cationic crosslinking lacquer systems are also suitable.
- the third lacquer may be present in particular on the substrate in a coating weight of 0.5 to 3 g / m 2 , preferably of 1 to 2 g / m 2 . This corresponds to about 1 to 2 g / m 2 of the preferred range in the uncrosslinked state because UV systems are so-called "100% systems" (ie, 100% solids).
- UV crosslinking third varnish may be e.g. based on the above-described "Composition 1", wherein matting agents are mixed in a proportion of 10 to 15 wt .-%.
- Banknote papers are typically made from fibers of annual plants, especially cotton fibers or pulp fibers, but papers which are at least partially made of plastic fibers, preferably polyamide fibers or polyester fibers, may also be used. More preferably, a cotton paper is used as a security paper substrate.
- the basis weight of the substrate varies depending on the application form. Typical basis weights are in the range of 50 g / m 2 to 100 g / m 2 , preferably in the range of 60 g / m 2 to 90 g / m 2 , more preferably about 70 g / m 2 .
- the individual paper layers may consist of the same or different types of paper.
- a paper layer may be a pure cotton paper, while another paper layer may comprise plastic fibers.
- multi-layered Paper / foil composites are used, such as a paper / foil / paper composite or a foil / paper / foil composite.
- the production preferably takes place by means of a rotary screening machine.
- FIG. 1 shows a schematic representation of a security paper with embedded window security thread and glued, patch-shaped security element
- Fig. 2a shows the enlarged area II in plan view, wherein schematically the Wobbeizone of the thread is illustrated;
- Fig. 2c shows the enlarged area II in plan view, wherein the expansion of the second lacquer layer is schematically illustrated.
- Fig. 1 shows a schematic representation of a security paper 1, which is provided with an embedded window security thread 2 and a glued patch-shaped security element 3.
- the security paper 1 also has the denomination "100" in the form of a watermark
- the window security thread 2 in the present case a microlens thread
- the security element 3 in the present case, a micro-optical representation arrangement with microstructures and micro-cavity arrays for enlarged reproduction of the microstructures
- the window security thread 2 shown in dashed lines protrudes at the window areas 4 on the surface of the security paper 1, while it is embedded in the interior of the security paper 1 at the intervening web areas.
- Shaped security element 3 and the window security thread 2 are each provided with a dirt-repellent radiation-curing first lacquer which does not substantially influence the perceptibility of the optically variable effect
- the first varnish is a UV varnish based on the above-described Composition 1, and is applied to the security paper in the flexographic printing or offset printing processes in the ranges 5 and II.
- the first lacquer is not applied in register above the anti-counterfeiting means 2 and 3, but the lacquer also covers adjacent parts of the security paper substrate, which surround the counterfeit protection means 2 and 3 and, as it were, form edge regions for the counterfeit protection means 2 and 3.
- the layer thickness of the first coating is 1.5 ⁇ m in the present example.
- the security paper 1 is on its surface lying outside the counterfeiting protection means 2 and 3 over its entire surface with a dirt provided second repellent paint, which partially overlaps the first UV varnish in the area surrounding the anti-counterfeiting means 2 and 3 partial surfaces of the substrate.
- the soil-repellent second paint is based on a preferably by means of flexographic applied, physically drying aqueous dispersion paint according to the composition 2 described above.
- Fig. 2a shows the enlarged section II of Fig. 1 in plan view.
- the window security thread 2 protrudes at the window areas 4 on the surface of the security paper while being embedded at the intermediate land areas inside the security paper.
- the security thread is introduced into the paper during papermaking by means of the wobble technique known in the prior art.
- wobble here denotes a periodic variation of the security thread when embedding in the paper of several millimeters perpendicular to the thread direction, so that certain Wöbbel zones 6 are formed, within which the security thread comes to rest.
- the window security thread 2 and the window security thread 2 surrounding part surface of the substrate are to extend the life and the fitness for circulation with the above-described, the perceptibility of the optically variable security feature substantially not influencing, dirt-repellent radiation-curing first lacquer 7 is provided (see Fig. 2b).
- the security paper 1 has on its outside of the window security thread 2 lying surface on the above-described dirt-repellent second lacquer 8, which partially overlaps the first lacquer 7 in the area surrounding the window security thread 2 partial surface of the substrate.
- the overlapping areas are designated by reference numeral 9 (see Fig. 2c).
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Credit Cards Or The Like (AREA)
- Printing Methods (AREA)
- Paper (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102011120850A DE102011120850A1 (de) | 2011-12-09 | 2011-12-09 | Sicherheitspapier, daraus erhältliches Wertdokument und Verfahren zum Herstellen derselben |
| PCT/EP2012/004938 WO2013083253A1 (de) | 2011-12-09 | 2012-11-29 | Sicherheitspapier, daraus erhältliches wertdokument und verfahren zum herstellen derselben |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2788197A1 true EP2788197A1 (de) | 2014-10-15 |
| EP2788197B1 EP2788197B1 (de) | 2016-02-03 |
Family
ID=47297099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP12797714.8A Active EP2788197B1 (de) | 2011-12-09 | 2012-11-29 | Sicherheitspapier, daraus erhältliches wertdokument und verfahren zum herstellen derselben |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US9827803B2 (de) |
| EP (1) | EP2788197B1 (de) |
| CL (1) | CL2014001476A1 (de) |
| DE (1) | DE102011120850A1 (de) |
| MX (1) | MX337085B (de) |
| WO (1) | WO2013083253A1 (de) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180209099A1 (en) * | 2014-07-03 | 2018-07-26 | Basf Se | Aqueous surface-coating agent for paper and paperboard |
| TW201619917A (zh) * | 2014-09-09 | 2016-06-01 | 西克帕控股有限公司 | 具有相互關聯的特徵的鈔票 |
| GB2535985B (en) | 2015-02-24 | 2019-11-06 | Portals De La Rue Ltd | Improvements in security documents |
| DE102017004039B4 (de) * | 2017-04-26 | 2019-06-06 | Mühlbauer Gmbh & Co. Kg | Sicherheitseinlage für ein Ausweisdokument und Verfahren zur Herstellung einer Sicherheitseinlage für ein Ausweisdokument |
| DE102017004037B4 (de) * | 2017-04-26 | 2019-06-27 | Mühlbauer Gmbh & Co. Kg | Sicherheitseinlage mit einer Vertiefung für ein Ausweisdokument und Verfahren zur Herstellung einer Sicherheitseinlage mit einer Vertiefung für ein Ausweisdokument |
| EP3939803B1 (de) * | 2020-09-29 | 2024-05-08 | Hueck Folien Gesellschaft m.b.H. | Polymersubstrat zur herstellung von polymer-wertpapieren oder polymer-sicherheitspapieren |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0338596B2 (de) | 1980-11-05 | 1991-06-11 | Suchiibun Hooru Matsuguruu | |
| DE3609090A1 (de) | 1986-03-18 | 1987-09-24 | Gao Ges Automation Org | Wertpapier mit darin eingelagertem sicherheitsfaden und verfahren zur herstellung derselben |
| ATE49376T1 (de) | 1986-08-19 | 1990-01-15 | Enschede & Zonen Grafisch | Mit tinte bedruckter und mit einer schutzschicht beschichteter papiergegenstand und dessen herstellungsverfahren. |
| KR930003329B1 (ko) | 1988-03-04 | 1993-04-26 | 게아오 게젤샤프트 퓌어 오토마찌온 운트 오가니쟈찌온 엠베하 | 보안서류내에 삽입되기 위한 세선 및 세편형태의 보안소자와 그 제조방법 |
| ATE186345T1 (de) | 1995-03-13 | 1999-11-15 | Rue De Int Ltd | Sicherheitspapier |
| CH690067A5 (de) | 1995-08-10 | 2000-04-14 | Ovd Kinegram Ag | Verfahren zur Herstellung teilmetallisierter Gitterstrukturen. |
| DE19829004A1 (de) | 1998-06-30 | 2000-01-05 | Giesecke & Devrient Gmbh | Sicherheitspapier |
| US6562755B1 (en) * | 2000-10-31 | 2003-05-13 | Ncr Corporation | Thermal paper with security features |
| DE10124630A1 (de) | 2001-05-18 | 2002-11-21 | Giesecke & Devrient Gmbh | Wertpapier und Verfahren zu seiner Herstellung |
| GB2385298B (en) | 2002-02-19 | 2004-04-28 | Rue De Int Ltd | Method of preparing a security document |
| DE10327083A1 (de) | 2003-02-11 | 2004-08-19 | Giesecke & Devrient Gmbh | Sicherheitspapier und Verfahren zur Herstellung desselben |
| DE10319232A1 (de) | 2003-04-28 | 2004-11-18 | Giesecke & Devrient Gmbh | Flächiges Sicherheitselement und Herstellungsverfahren für dasselbe |
| AU2005238699B2 (en) * | 2004-04-30 | 2008-11-20 | De La Rue International Limited | Arrays of microlenses and arrays of microimages on transparent security substrates |
| DE102004044459B4 (de) * | 2004-09-15 | 2009-07-09 | Ovd Kinegram Ag | Sicherheitsdokument mit transparenten Fenstern |
| FR2877609B1 (fr) * | 2004-11-08 | 2007-03-09 | Arjowiggins Security Soc Par A | Structure de securite et article incorporant une telle structure |
| DE102005028162A1 (de) | 2005-02-18 | 2006-12-28 | Giesecke & Devrient Gmbh | Sicherheitselement und Verfahren zu seiner Herstellung |
| DE102009035361A1 (de) | 2009-07-30 | 2011-02-03 | Giesecke & Devrient Gmbh | Sicherheitselement für einen zu schützenden Gegenstand sowie zu schützender Gegenstand mit einem solchen Sicherheitselement |
| DE102010047250A1 (de) | 2009-12-04 | 2011-06-09 | Giesecke & Devrient Gmbh | Sicherheitselement, Wertdokument mit einem solchen Sicherheitselement sowie Herstellungsverfahren eines Sicherheitselementes |
-
2011
- 2011-12-09 DE DE102011120850A patent/DE102011120850A1/de not_active Withdrawn
-
2012
- 2012-11-29 MX MX2014006708A patent/MX337085B/es active IP Right Grant
- 2012-11-29 WO PCT/EP2012/004938 patent/WO2013083253A1/de not_active Ceased
- 2012-11-29 EP EP12797714.8A patent/EP2788197B1/de active Active
- 2012-11-29 US US14/361,380 patent/US9827803B2/en not_active Expired - Fee Related
-
2014
- 2014-06-05 CL CL2014001476A patent/CL2014001476A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| MX2014006708A (es) | 2014-07-09 |
| CL2014001476A1 (es) | 2014-11-07 |
| WO2013083253A1 (de) | 2013-06-13 |
| DE102011120850A1 (de) | 2013-06-13 |
| US20140319816A1 (en) | 2014-10-30 |
| EP2788197B1 (de) | 2016-02-03 |
| US9827803B2 (en) | 2017-11-28 |
| MX337085B (es) | 2016-02-11 |
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