EP2787811A1 - Concentré émulsionnable comprenant un pesticide, du diméthylsulfoxyde, de l'alcool benzylique et un lactate d'alkyle - Google Patents
Concentré émulsionnable comprenant un pesticide, du diméthylsulfoxyde, de l'alcool benzylique et un lactate d'alkyleInfo
- Publication number
- EP2787811A1 EP2787811A1 EP12787703.3A EP12787703A EP2787811A1 EP 2787811 A1 EP2787811 A1 EP 2787811A1 EP 12787703 A EP12787703 A EP 12787703A EP 2787811 A1 EP2787811 A1 EP 2787811A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- emulsifiable concentrate
- concentrate according
- pesticide
- concentrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Definitions
- Emulsifiable concentrate comprising pesticide, dimethyl sulfoxide, benzyl alcohol, alkyl lactate
- Subject matter of the present invention is an emulsifiable concentrate comprising a water- insoluble pesticide, benzyl alcohol, alkyl lactate and not more than 40% by weight of dimethyl sulfoxide.
- a further subject matter is an emulsion obtainable by mixing water with the emulsifiable concentrate; a process for the preparation of the emulsifiable concentrate; and a method for controlling phytopathogenic fungi and/or undesired vegetation and/or undesired attack by insects or mites and/or for regulating the growth of plants, where the concentrate or the emulsion is allowed to act on the respective pests, their environment or on the crop plants to be protected from the respective pests, on the soil and/or on undesired plants and/or on the crop plants and/or their environment.
- the present invention comprises combinations of preferred features with other preferred features.
- Emulsifiable concentrates are widely used formulations in crop protection.
- the disadvantage of the known emulsion concentrates is the poor cold stability, the pronounced tendency to crystallize and the low pesticide concentration. It was an object of the present invention to provide an emulsion concentrate which overcomes these disadvantages.
- the object was achieved by an emulsifiable concentrate comprising a water-insoluble pesticide, benzyl alcohol, alkyl lactate and not more than 40% by weight of dimethyl sulfoxide.
- an emulsifiable concentrate is taken to mean compositions which form an oil-in-water emulsion upon mixing with water (e.g. in a weight ratio of 1 part concentrate to 99 parts water).
- the emulsion usually arises spontaneously.
- the resulting emulsion may have an average droplet size of more than 0.1 pm, preferably more than 0.5 pm, in particular more than 0.8 pm, and most preferred more than 1.1 pm.
- the resulting emulsion may have an average droplet size of up to 30 pm, preferably up to 10 pm, in particular up to 5 pm.
- the average droplet size may be determined by laser diffraction, e.g. with a Malvern Mastersizer 2000.
- the resulting emulsion is not a miniemulsion, and not a microemulsion.
- the concentrate is preferably present as a homogeneous solution. It is usually virtually free from dispersed particles.
- Suitable alkyl lactates are aliphatic Ci-Cie-alkyl lactates (in particular C6-Cio-alkyl lactates), which may be linear or branched. Examples are cyclohexyl lactate, 2-ethylhexyl lactate, 2- methylcyclohexyl lactate, heptyl lactate, octyl lactate, or mixtures of these. Especially preferred is 2-ethylhexyl lactate.
- the alkyl lactates can be present in the form of D- and/or L-lactates, with the L-lactates being preferred.
- the concentrate can comprise not less than 10% by weight, preferably not less than 15% by weight, more preferably not less than 20% by weight and in particular not less than 30% by weight of alkyl lactate (such as 2-ethylhexyl lactate).
- the concentrate can comprise not more than 80% by weight, preferably not more than 65% by weight and in particular not more than 50% by weight of alkyl lactate (such as 2-ethylhexyl lactate).
- the concentrate can comprise not more than 30% by weight, preferably not more than 20% by weight, more preferably not more than 15% by weight and in particular not more than 10% by weight of dimethyl sulfoxide (DMSO).
- DMSO dimethyl sulfoxide
- the concentrate can comprise not more than 50% by weight, preferably not more than 35% by weight and in particular not more than 28% by weight of benzyl alcohol.
- the concentrate can comprise not less than 3% by weight, preferably not less than 8% by weight and in particular not less than 15% by weight of benzyl alcohol.
- the concentrate can comprise from 0.5 to 20% by weight of DMSO, from 5 to 50% by weight of benzyl alcohol and from 10 to 60% by weight of alkyl lactate (such as 2-ethylhexyl lactate).
- the concentrate can comprise from 1 to 10% by weight of DMSO, from 15 to 30% by weight of benzyl alcohol and from 15 to 50% by weight of alkyl lactate (such as 2-ethylhexyl lactate).
- the concentrate is free from water.
- the concentrate is essentially free from water. It can comprise not more than 3% by weight, preferably not more than 1 % by weight and in particular not more than 0.5% by weight of water. In special form, the concentrate may comprise not more than 0.3% by weight and in particular not more than 0.1 % by weight of water.
- pesticides refers to at least one active substance selected from the group of the fungicides, insecticides, nematicides, herbicides, safeners and/or growth regulators.
- Preferred pesticides are fungicides, insecticides, herbicides and growth regulators.
- Especially preferred pesticides are fungicides.
- Mixtures of pesticides from two or more of the abovementioned classes may also be used.
- the skilled worker is familiar with such pesticides, which can be found, for example, in Pesticide Manual, 15th Ed. (2009), The British Crop Protection Council, London.
- the following pesticides are suitable, by way of example (pesticides A) to K) are fungicides):
- coumethoxystrobin coumoxystrobin, dimoxystrobin, enestroburin, fenaminstrobin, fenoxy- strobin/flufenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, trifloxystrobin, methyl 2-[2-
- - complex-ll-inhibitors for example carboxamides: benodanil, bixafen, boscalid, carboxin, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, isopyrazam, mepronil, oxycarboxin, penflufen, penthiopyrad, sedaxane, tecloftalam, thifluzamide, N-(4'-trifluoromethylthio- biphenyl-2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, N-(2-(1 ,3,3- trimethylbutyl)phenyl)-1 ,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxamide and N-[9- (dichloromethylene)-l ,2,3,4-tetrahydro-1 ,4-methanonaphthalen-5-yl]-3-(
- respiration inhibitors for example complex I, decouplers: diflumetorim; nitrophenyl derivatives: binapacryl, dinobuton, dinocap, fluazinam; ferimzone; organometal compounds: fentin salts such as fentin acetate, fentin chloride or fentine hydroxide; ametoctradin; and silthiofam;
- DMI fungicides triazoles: azaconazole, bitertanol,
- epoxiconazole fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, oxpoconazole, paclobutrazole, penconazole, propiconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triticonazole, uniconazole; imidazoles: imazalil, pefurazoate, prochloraz, triflumizole; pyrimidines, pyridines and piperazines: fenarimol, nuarimol, pyrifenox, triforine;
- - delta 14-reductase inhibitors aldimorph, dodemorph, dodemorph acetate, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamine;
- phenylamides or acylamino acid fungicides benalaxyl, benalaxyl-M, kiralaxyl, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl;
- - tubulin inhibitors such as benzimidazoles, thiophanates: benomyl, carbendazim,
- cell division inhibitors diethofencarb, ethaboxam, pencycuron, fluopicolid, zoxamid, metrafenon, pyriofenon;
- - methionine synthesis inhibitors anilinopyrimidines: cyprodinil, mepanipyrim, pyrimethanil;
- MAP/histidine kinase inhibitors fluoroimide, iprodione, procymidone, vinclozolin, fenpiclonil, fludioxonil;
- phospholipid biosynthesis inhibitors edifenphos, iprobenfos, pyrazophos, isoprothiolane;
- lipid peroxidation dicloran, quintozene, tecnazene, tolclofos-methyl, biphenyl, chloroneb, etridiazole;
- organochlorine compounds for example phthalimides, sulfamides, chloronitriles: anilazine, chlorothalonil, captafol, captan, folpet, dichlofluanid, dichlorophen, flusulfamide,
- guanidine dithianon
- - glucan synthesis inhibitors validamycin, polyoxin B; melanin synthesis inhibitors: pyroquilon, tricyclazole, carpropamid, dicyclomet, fenoxanil;
- chlormequat chlormequat chloride
- choline chloride cyclanilid, daminozide, dikegulac, dimethipin, 2,6-dimethylpuridine, ethephon, flumetralin, flurprimidol, fluthiacet, forchlorfenuron, gibberellic acid, inabenfid, indole-3-acetic acid, maleic hydrazide, mefluidid, mepiquat (mepiquat chloride), metconazole, naphthaleneacetic acid, N-6-benzyladenine,
- paclobutrazole prohexadione (prohexadione-calcium), prohydrojasmone, thidiazuron, triapenthenol, tributylphosphorotrithioate, 2,3,5-triiodobenzoic acid, trinexapac-ethyl and uniconazole;
- acetochlor alachlor, butachlor, dimethachlor, dimethenamid, flufenacet,
- mefenacet metolachlor, metazachlor, napropamid, naproanilid, pethoxamid, pretilachlor, propachlor, thenylchlor;
- - aryloxyphenoxypropionates clodinafop, cyhalofop-butyl, fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefuryl;
- acifluorfen acifluorfen, aclonifen, bifenox, diclofop, ethoxyfen, fomesafen, lactofen, oxyfluorfen;
- - imidazolinones imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, imazethapyr;
- - phenoxyacetic acids clomeprop, 2,4-dichlorophenoxyacetic acid (2,4-D), 2,4-DB, dichlorprop,
- MCPA MCPA-thioethyl
- MCPB mecoprop
- - pyridines aminopyralid, clopyralid, diflufenican, dithiopyr, fluridone, fluroxypyr, picloram, picolinafen, thiazopyr;
- - sulfonylureas amidosulfuron, azimsulfuron, bensulfuron, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron, foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron, mesosulfuron, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron, prosulfuron, pyrazosulfuron, rimsulfuron,
- sulfometuron sulfosulfuron, thifensulfuron, triasulfuron, tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron, 1 -((2-chloro-6-propylimidazo[1 ,2-b]pyridazin-3-yl)sulfonyl)-3-(4,6- dimethoxypyrimidin-2-yl)urea;
- - triazines ametryne, atrazine, cyanazine, dimethametryne, ethiozine, hexazinone, metamitron, metribuzine, prometryne, simazine, terbuthylazine, terbutryne, triaziflam;
- - ureas chlortoluron, daimuron, diuron, fluometuron, isoproturon, linuron, methabenzthiazuron, tebuthiuron;
- acetolactate synthase inhibitors bispyribac-sodium, cloransulam-methyl, diclosulam, florasulam, flucarbazone, flumetsulam, metosulam, orthosulfamuron, penoxsulam, propoxycarbazone, pyribambenz-propyl, pyribenzoxim, pyriftalide, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyroxasulfon, pyroxsulam;
- pyrazoxyfen pyrazolynate, quinoclamin, saflufenacil, sulcotrione, sulfentrazone, terbacil, tefuryltrione, tembotrione, thiencarbazone, topramezone, 4-hydroxy-3-[2-(2-methoxyethoxy- methyl)-6-trifluoromethylpyridin-3-carbonyl]bicyclo[3.2.1]oct-3-en-2-one, ethyl (3-[2-chloro-4- fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-2H-pyrimidin-1-yl)phenoxy]pyridin- 2-yloxy)acetate, methyl 6-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylate, 6-chloro- 3-(2-cyclopropyl-6-methylphenoxy)pyridazin-4-o
- organo(thio)phosphates acephate, azamethiphos, azinphos-methyl, chlorpyrifos,
- chlorpyrifos-methyl chlorfenvinphos, diazinon, dichlorvos, dicrotophos, dimethoate, disulfoton, ethion, fenitrothion, fenthion, isoxathion, malathion, methamidophos,
- methidathion methidathion, methyl-parathion, mevinphos, monocrotophos, oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone, phosmet, phosphamidon, phorate, phoxim, pirimiphos- methyl, profenofos, prothiofos, sulprophos, tetrachlorvinphos, terbufos, triazophos, trichlorfon;
- - pyrethroids allethrin, bifenthrin, cyfluthrin, cyhalothrin, cyphenothrin, cypermethrin, alpha- cypermethrin, beta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, imiprothrin, lambda-cyhalothrin, permethrin, prallethrin, pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate, tefluthrin, tetramethrin, tralomethrin, transfluthrin, profluthrin, dimefluthrin,
- - insect growth inhibitors a) chitin synthesis inhibitors: benzoylureas: chlorfluazuron,
- cyramazin diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, teflubenzuron, triflumuron; buprofezin, diofenolan, hexythiazox, etoxazole, clofentazin; b) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide, azadirachtin; c) juvenoids: pyriproxyfen, methoprene, fenoxycarb; d) lipid biosynthesis inhibitors:
- - nicotine receptor agonists/antagonists clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, acetamiprid, thiacloprid, 1 -(2-chlorothiazol-5-ylmethyl)-2-nitrimino-3,5-dimethyl- [1 ,3,5]triazinane;
- - GABA antagonists endosulfan, ethiprole, fipronil, vaniliprole, pyrafluprole, pyriprole,
- acaricides fenazaquin, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim;
- - inhibitors of oxidative phosphorylation cyhexatin, diafenthiuron, fenbutatin oxide, propargite; - insect ecdysis inhibitors: cryomazine;
- the pesticide is water-insoluble. Usually, it is soluble in water to not more than 1 g/l, preferably to not more than 200 mg/l and in particular to not more than 50 mg/l at 25°C. Examples of water-insoluble pesticides are fluxapyroxad. Using simple preliminary experiments, the skilled worker can select a pesticide with a suitable water-solubility from the above pesticide list.
- the pesticide can have a melting point of more than 40°C, preferably more than 70°C and in particular more than 90°C.
- the pesticide is preferably present in the concentrate in dissolved form. Using simple preliminary experiments, the skilled worker can select, from the above pesticide list, a pesticide with a suitable solubility.
- the concentrate can comprise one or more further pesticides.
- the further pesticide is preferably water-insoluble. Usually, it is soluble in water to not more than 1 g/l, preferably to not more than 200 mg/l and in particular to not more than 50 mg/l at 25°C. Using simple preliminary experiments, the skilled worker can select a pesticide with a suitable water-solubility from the above pesticide list.
- the concentrate does not comprise any further pesticide.
- the further pesticide is epoxiconazol.
- the concentrate comprises the water insoluble pesticide fluxapyroxad and optionally a further pesticide, which is water insoluble (e.g. epoxiconazol).
- the concentrate may comprise from 0.1 to 60% by weight, preferably from 1 to 25% by weight, in particular from 5 to 15% by weight, of pesticide, the basis being the total of all the pesticides present in the concentrate.
- the emulsifiable concentrate can furthermore comprise auxiliaries conventionally used for crop protection products.
- auxiliaries are solvents, liquid carriers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetrants, protective colloids, stickers, thickeners, bactericides, antifreeze agents, antifoam agents, colorants, adhesives and binders.
- Suitable solvents and liquid carriers are organic solvents such as mineral oil fractions with medium to high boiling point, for example kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, for example toluene, paraffin, tetrahydro- naphthalene, alkylated naphthalenes; alcohols, for example ethanol, propanol, butanol, cyclohexanol; glycols; ketones, for example cyclohexanone; esters, for example lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, for example N-methylpyrrolidone, fatty acid dimethyl amides; and their mixtures.
- organic solvents such as mineral oil fractions with medium to high boiling point, for example kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic
- Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emusifier, dispersant, solubilizer, wetter, penetrant, protective colloid, or auxiliary. Examples of surfactants are listed in McCutcheon's, Vol.1 : Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
- Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
- sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates.
- sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters.
- phosphates are phosphate esters.
- carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.
- Preferred anionic surfactants are sulfates and sulfonates.
- Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
- alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
- Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
- N-subsititued fatty acid amides are fatty acid glucamides or fatty acid
- esters are fatty acid esters, glycerol esters or monoglycerides.
- sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose g
- esters or alkylpolyglucosides examples include polymeric surfactants are homo- or copolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.
- Preferred nonionic surfactants are alkoxylates.
- Nonionic surfactants such as alkoxylates may also be employed as adjuvants.
- Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
- Suitable amphoteric surfactants are alkylbetains and imidazolines.
- Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
- Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.
- Suitable adjuvants are compounds which have negligible or even no pesticidal activity themselves, and which improve the biological performance of the compound I on the target. Examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and Additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
- Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones, chloroisothiazolinones and benzisothiazolinones.
- Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerol.
- Suitable antifoam agents are silicones, long-chain alcohols, and salts of fatty acids.
- Suitable colorants e.g. in red, blue, or green
- Suitable colorants are pigments which are sparingly soluble in water, and water-soluble dyes. Examples are inorganic colorants (e.g. iron oxide, titanium oxide, iron hexacyanoferrate) and organic colorants (e.g. alizarin, azo and phthalocyanine colorants).
- the concentrate preferably comprises at least one anionic surfactant.
- the concentrate usually comprises not less than 0.5% by weight of anionic surfactants, preferably not less than 2% by weight and in particular not less than 3% by weight.
- the composition can comprise not more than 30% by weight of anionic surfactants, preferably not more than 15% by weight and in particular not more than 10% by weight.
- the concentrate preferably comprises at least one nonionic surfactant (such as alkoxylates, especially alkoxylated alcohols).
- the concentrate usually comprises not less than 1 % by weight of nonionic surfactants, preferably not less than 5% by weight and in particular not less than 10% by weight.
- the composition can comprise not more than 65% by weight of nonionic surfactants, preferably not more than 45% by weight and in particular not more than 35% by weight.
- the concentrate preferably comprises at least one alkoxylate, in particular an alkoxylated C6-C22-alcohol.
- the concentrate usually comprises not less than 2% by weight of alkoxylates (in particular an alkoxylated C6-C22-alcohol), preferably not less than 7% by weight and in particular not less than 10% by weight.
- the concentrate comprises a nonionic surfactant (such as alkoxylates) and an anionic surfactant (such as sulfates or sulfonates).
- a nonionic surfactant such as alkoxylates
- an anionic surfactant such as sulfates or sulfonates
- the invention furthermore relates to a process for the preparation of the emulsifiable
- the concentrate according to the invention by mixing the water-insoluble pesticide, not more than 40% by weight of dimethyl sulfoxide, benzyl alcohol and alkyl lactate. In most cases, the pesticide will be dissolved in the solvent upon mixing.
- the invention furthermore relates to an emulsion obtainable (preferably obtained) by mixing water with the emulsifiable concentrate according to the invention.
- the emulsion normally arises spontaneously upon mixing.
- the emulsion is an oil-in-water emulsion.
- the mixing ratio of water to concentrate can be in the range of from 1000 to 1 up to 1 to 1 , preferably 200 to 1 up to 3 to 1.
- the invention furthermore relates to a method for controlling phytopathogenic fungi and/or undesired vegetation and/or undesired attack by insects or mites and/or for regulating the growth of plants, where the concentrate according to the invention or the emulsion according to the invention is allowed to act on the respective pests, their environment or on the crop plants to be protected from the respective pests, on the soil and/or on undesired plants and/or on the crop plants and/or their environment.
- the therapeutic treatment of humans and animals is excluded from the method for controlling phytopathogenic fungi and/or undesired vegetation and/or undesired attack by insects or mites and/or for regulating the growth of plants.
- the application rates of the pesticides amount to from 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha and in particular from 0.1 to 0.75 kg per ha, depending on the nature of the desired effect.
- amounts of active substance of from 0.1 to 1000 g, preferably from 1 to 1000 g, more preferably from 1 to 100 g and in particular from 5 to 100 g, per 100 kg of plant propagation material (preferably seed) are generally required.
- the amount of active substance applied depends on the kind of application area and on the desired effect. Amounts customarily applied in the protection of materials are 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.
- oils, wetters, adjuvants, fertilizers or micronutrients and further pesticides may be added to the emulsion in the form of a premix or optionally only shortly before use (tank mix).
- pesticides for example herbicides, insecticides, fungicides, growth regulators, safeners
- These agents can be admixed to the compositions according to the invention at a weight ratio of from 1 :100 to 100:1 , preferably from 1 :10 to 10:1.
- the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
- the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an
- agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
- 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
- the concentrate is highly stable to low temperatures (e.g. even below 0°C); that the pesticide does not precipitate, cream or crystallize in the concentrate at low temperatures (e.g. even below 0°C); that high pesticide concentrations in the concentrate can be employed; that an emulsion forms spontaneously upon dilution of the concentrate with water; that the concentrate is capable of being stored over prolonged periods; that the concentrate does not require the presence of water (e.g.
- the concentrate forms a stable emulsion upon dilution with water; that the concentrate ; or that adjuvants (such as alcohol alkoxylates) can be included in the concentrate formulations.
- AI2 epoxiconazole
- AI3 pyraclostrobin
- NS1 nonionic surfactant, liquid ethoxylated polyalkylarylphenol, HLB 12-13.
- NS2 nonionic surfactant, liquid alkoxylated fatty alcohol, surface tension (1 g/l, 23°C)
- AS1 calcium tetrapropylenebenzenesulfonate, 40% by weight in aromatic solvent.
- Example 1 - 1 1 Preparation of emulsion concentrates
- the emulsifiable concentrates of fluxapyroxad (in each case 62.5 g/l) were prepared by the components and making up to 1.0 I with (S)-2 -ethyl hexyl lactate.
- Table 1 Composition of examples 1 -1 1 (all data in g/l)
- Example 12-25 Preparation of emulsion concentrates
- the emulsifiable concentrates in Table 2 were prepared by mixing the components and making up to 1.0 I with (S)-2-ethylhexyl lactate.
- Table 2 Composition of examples 12-16 (all data in g/l)
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
La présente invention a pour objet un concentré émulsionnable comprenant un pesticide insoluble dans l'eau, de l'alcool benzylique, un lactate d'alkyle et pas plus de 40 % en poids de diméthylsulfoxyde. La présente invention a pour autre objet une émulsion pouvant être obtenue par mélange d'eau avec le concentré émulsionnable; un procédé pour la préparation du concentré émulsionnable; et un procédé pour la lutte contre des champignons phytopathogènes et/ou de la végétation parasite et/ou une attaque indésirable par des insectes ou des acariens et/ou pour la régulation de la croissance de plantes, consistant à laisser le concentré ou l'émulsion agir sur les animaux nuisibles respectifs, leur environnement ou sur les plantes cultivées devant être protégées des animaux nuisibles respectifs, sur le sol et/ou sur les plantes parasites et/ou sur les plantes cultivées et/ou leur environnement.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12787703.3A EP2787811A1 (fr) | 2011-12-05 | 2012-11-14 | Concentré émulsionnable comprenant un pesticide, du diméthylsulfoxyde, de l'alcool benzylique et un lactate d'alkyle |
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161566739P | 2011-12-05 | 2011-12-05 | |
US201261608130P | 2012-03-08 | 2012-03-08 | |
EP12158596 | 2012-03-08 | ||
EP12787703.3A EP2787811A1 (fr) | 2011-12-05 | 2012-11-14 | Concentré émulsionnable comprenant un pesticide, du diméthylsulfoxyde, de l'alcool benzylique et un lactate d'alkyle |
PCT/EP2012/072565 WO2013083372A1 (fr) | 2011-12-05 | 2012-11-14 | Concentré émulsionnable comprenant un pesticide, du diméthylsulfoxyde, de l'alcool benzylique et un lactate d'alkyle |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2787811A1 true EP2787811A1 (fr) | 2014-10-15 |
Family
ID=48573577
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12787703.3A Withdrawn EP2787811A1 (fr) | 2011-12-05 | 2012-11-14 | Concentré émulsionnable comprenant un pesticide, du diméthylsulfoxyde, de l'alcool benzylique et un lactate d'alkyle |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP2787811A1 (fr) |
KR (1) | KR20140099926A (fr) |
AR (1) | AR089659A1 (fr) |
AU (1) | AU2012348730A1 (fr) |
BR (1) | BR112014013029A2 (fr) |
CA (1) | CA2854845A1 (fr) |
CR (1) | CR20140241A (fr) |
EA (1) | EA201400650A1 (fr) |
WO (1) | WO2013083372A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103687514A (zh) | 2011-05-03 | 2014-03-26 | 罗德里克·威廉·菲利普斯 | 家具装置及套件及系统及其用途 |
KR20180096604A (ko) * | 2015-12-22 | 2018-08-29 | 바이엘 크롭사이언스 악티엔게젤샤프트 | 친유성 화합물의 유제 농축물 |
EP4145995A4 (fr) * | 2020-05-08 | 2024-05-22 | CJB Applied Technologies, LLC | Compositions pesticides et procédés associés |
AU2021301088A1 (en) * | 2020-06-29 | 2023-02-02 | Basf Se | Biocide compositions |
EP4346404A1 (fr) * | 2021-05-26 | 2024-04-10 | Basf Se | Nouveau procédé de lutte contre les nuisibles |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101196233B1 (ko) * | 2004-02-06 | 2012-11-05 | 메리얼 리미티드 | 식물 보호 조성물 및 그 용도 |
EP1886560A1 (fr) * | 2006-08-05 | 2008-02-13 | Bayer CropScience AG | nouveaux concentrés micro-émulsionables |
TW201018400A (en) * | 2008-10-10 | 2010-05-16 | Basf Se | Liquid aqueous plant protection formulations |
-
2012
- 2012-11-14 EP EP12787703.3A patent/EP2787811A1/fr not_active Withdrawn
- 2012-11-14 CA CA2854845A patent/CA2854845A1/fr not_active Abandoned
- 2012-11-14 EA EA201400650A patent/EA201400650A1/ru unknown
- 2012-11-14 BR BR112014013029A patent/BR112014013029A2/pt not_active Application Discontinuation
- 2012-11-14 WO PCT/EP2012/072565 patent/WO2013083372A1/fr active Application Filing
- 2012-11-14 AU AU2012348730A patent/AU2012348730A1/en not_active Abandoned
- 2012-11-14 KR KR1020147017911A patent/KR20140099926A/ko not_active Application Discontinuation
- 2012-12-14 AR ARP120104750A patent/AR089659A1/es unknown
-
2014
- 2014-05-22 CR CR20140241A patent/CR20140241A/es unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2013083372A1 * |
Also Published As
Publication number | Publication date |
---|---|
CR20140241A (es) | 2014-06-20 |
AR089659A1 (es) | 2014-09-10 |
KR20140099926A (ko) | 2014-08-13 |
BR112014013029A2 (pt) | 2017-06-13 |
EA201400650A1 (ru) | 2014-11-28 |
CA2854845A1 (fr) | 2013-06-13 |
AU2012348730A1 (en) | 2014-07-03 |
WO2013083372A1 (fr) | 2013-06-13 |
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