EP2737543A2 - Procédé de fabrication d'une cellule photovoltaïque et cellule photovoltaïque - Google Patents
Procédé de fabrication d'une cellule photovoltaïque et cellule photovoltaïqueInfo
- Publication number
- EP2737543A2 EP2737543A2 EP12740153.7A EP12740153A EP2737543A2 EP 2737543 A2 EP2737543 A2 EP 2737543A2 EP 12740153 A EP12740153 A EP 12740153A EP 2737543 A2 EP2737543 A2 EP 2737543A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dielectric layer
- substrate
- layer
- solar cell
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 35
- 239000000758 substrate Substances 0.000 claims abstract description 33
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 27
- 239000010703 silicon Substances 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 15
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 11
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000151 deposition Methods 0.000 claims description 24
- 230000008021 deposition Effects 0.000 claims description 16
- 238000005530 etching Methods 0.000 claims description 15
- 238000009792 diffusion process Methods 0.000 claims description 10
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 230000005855 radiation Effects 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 104
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 17
- 235000012431 wafers Nutrition 0.000 description 14
- 238000005215 recombination Methods 0.000 description 10
- 230000006798 recombination Effects 0.000 description 10
- 230000003071 parasitic effect Effects 0.000 description 9
- 238000002161 passivation Methods 0.000 description 9
- 239000002019 doping agent Substances 0.000 description 6
- 239000004065 semiconductor Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000007650 screen-printing Methods 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 230000005669 field effect Effects 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000002146 bilateral effect Effects 0.000 description 2
- 239000002800 charge carrier Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003989 dielectric material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000000873 masking effect Effects 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000007788 roughening Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910004205 SiNX Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0216—Coatings
- H01L31/02161—Coatings for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/02167—Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0236—Special surface textures
- H01L31/02363—Special surface textures of the semiconductor body itself, e.g. textured active layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
- H01L31/056—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means the light-reflecting means being of the back surface reflector [BSR] type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
- H01L31/068—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN homojunction type, e.g. bulk silicon PN homojunction solar cells or thin film polycrystalline silicon PN homojunction solar cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/547—Monocrystalline silicon PV cells
Definitions
- the invention relates to a solar cell, comprising a silicon substrate with the radiation-facing front, which is textured and has an n-doped region, a back having a p-doped region, along the back extending first dielectric layer, a substrate along facing away Side of the first dielectric layer extending second dielectric layer consisting of or containing a material selected from the group consisting of silicon nitride, silicon oxide, silicon oxynitride and a side facing away from the substrate side of the second dielectric layer extending metal layer.
- WO 2009/071561 A discloses a MWT (Metal Wrap-Through) PERC (Passivated Emitter Rear Cell), in which a first layer of an oxide such as aluminum oxide is applied to the rear side and a SiNx: H layer as the second layer.
- MWT Metal Wrap-Through
- PERC Passivated Emitter Rear Cell
- DE 10 2010 017 155 A provides at least one dielectric layer on the back side of the substrate of the solar cell, which consists of aluminum oxide, aluminum nitride or aluminum oxynitride and a further element.
- EP 1489667 A2 and EP 1763086 AI one obtains knowledge about the possibility of increasing the time until the recombination of the free charge carriers and thus the recombination rate and thus again the efficiency, in the side facing away from the light, a dielectric layer between the silicon substrate and the metallization is applied.
- EP 1763086 A1 describes the use of a dielectric layer system consisting of Si0 2 and an SiN layer deposited thereon for electrical passivation of the solar cell rear side.
- EP 1489667 A2 uses a compound comprising Al 2 O 3 and SiO 2 for the dielectric passivation of the solar cell backside.
- DE 3815 512 A 1 discloses a solar cell comprising a doped semiconductor body containing an n + p junction, which is covered over its entire surface with a contact layer on the rear side. On the back of the semiconductor body, an oxide layer is additionally applied over the entire surface.
- the concentration of a charge carrier type on the surface can also be greatly reduced due to their field effect. This also suppresses recombination (field effect passivation).
- various dielectrics in contact with silicon form a surface charge, particularly silicon oxide (weak positive), silicon nitride (positive), and aluminum oxide (negative). Depending on the chosen deposition process, this charge may be formed after an annealing step.
- the wafer surface In order to be able to passivate the surface, it is first necessary to remove the surface damage resulting from the production process of the wafer.
- the wafer surface can be etched in an acidic or alkaline solution.
- the etching solution can be adjusted to be polishing or roughening.
- a particularly smoothly etched surface offers the advantage of a lower recombination, rough surfaces, however, prove to be advantageous for the solar cell front side, since the reflection is reduced.
- the wafer backside can be provided with a protective layer before doping.
- a layer is removed from the wafer backside, the thickness of which is slightly larger than the penetration depth of the dopant, ie typically between 0.5 and a few ⁇ .
- A10 x is a good alternative, but it can not be economically deposited in layer thicknesses that would ensure a sufficient temperature stability. Due to the difficulties described, combinations of these materials appear to be very advantageous, often using SiO x or A10 x as the first layer and SiO x or SiN as the second layer.
- WO 2006/097303 A1 describes that a sufficient quality of the surface passivation is achieved only when using very thick layers; Further, the formation of contacts by locally introducing holes into the layers and applying a conductive material to the back surface will be described. Only the front side of the wafer is textured.
- DE 100 46 170 A describes a method for contact formation between the back metal layer and silicon, after the application of the metal layer and, if necessary, sintering with metal paste, wherein the designated contact region is locally e.g. is heated by laser radiation, so that the metal penetrates the dielectric layer and connects to the silicon.
- the parasitic contacts are formed on sintering of a layer of metal on the back of the cell deposited on the passivi.
- the avoidance of these loss mechanisms takes place according to the classical teaching by the following measures:
- Polishing or blank etching the wafer backside by subjecting the wafer to a one-sided etch after a texture step or by masking the back side after a two-sided smooth etch and texturing only the front side,
- the opening of the layer for forming local contacts can be done by the following techniques:
- the present invention has the object, a method for producing a solar cell and a solar cell in such a way that the solar cells with consistently high efficiency can be reproducibly made with fewer process steps.
- the back side of the substrate has a gloss value at 60 ° irradiation angle less than 80 GU (gloss units), in particular between 2 GU and 80 GU, preferably in the range between 20 GU and 80 GU and that the first dielectric layer contains fixed negative charges.
- 80 GU gloss units
- a combination of bilateral (substantially) symmetrical texture is provided (characteristic: roughness on the back remains) with deposition of the following layer sequence: ⁇ therm. Si0 2 (optional) ⁇ , Al 2 0 3 , SiN x or SiO x .
- AlO does not avoid parasitic contact (unopened cells).
- AlO improves rough surface efficiency compared to SiO x .
- A10 x must be designed in such a way that no "blistering" occurs in combination with the subsequent processing.
- the process is carried out in such a way that substantially no increased recombination occurs despite the increased surface area.
- Roughness reducing etching of the entire back surface occurs exclusively after diffusion, regardless of whether the diffusion is performed on one or both sides.
- the removal is as high as necessary to remove the diffused layer, so typically greater than 0.5 ⁇ , but less than, for example, 5 ⁇ . Due to the contained negative charges, the losses are minimized by parasitic contacts.
- the layer structure also helps ensure that even on a rough surface as possible no parasitic contacts are formed.
- Preferred process sequences are the following, where appropriate, process steps can be omitted, replaced or changed in order.
- step D preferably removal of the phosphorus glass before or after step E.
- a dielectric layer preferably silicon nitride
- the first dielectric layer consists of a material or contains one of the group of aluminum oxide, doped silicon oxide.
- the invention provides that the first dielectric layer has a layer thickness D 1 with 5 nm ⁇ Dl ⁇ 100 nm.
- the second dielectric layer should preferably have a layer thickness D2 with 40 nm ⁇ D2 ⁇ 400 nm.
- the invention proposes that between the first dielectric layer and the substrate extends a silicon oxide or silicon oxide containing layer having a thickness D3 preferably 1 nm ⁇ D3 ⁇ 10 nm.
- the invention is in particular characterized by a method for producing a solar cell, comprising the method steps
- a second dielectric layer of a material or a material comprising the group of silicon nitride, silicon oxide, silicon oxynitride along the first dielectric layer Depositing a metal layer along the second dielectric layer.
- the negatively charged layer is A10 x
- ALD Atomic Laser Deposition
- PECVD Plasma Enhanced Chemical Vapor Deposition
- Substrate temperature at SiN deposition preferably> 320 ° C.
- the rear side of the substrate is textured.
- a silicon oxide or silicon oxide containing layer having a thickness D3 of preferably 1 nm ⁇ D3 ⁇ 10 nm. In this layer thickness region, the formation of the negative charges in the first dielectric layer does not become with special needs.
- the layer having the thickness D3 may be e.g. be generated by thermal oxidation.
- the single FIGURE shows an embodiment of a solar cell whose rear side RS is passivated by means of an at least double-layered dielectric layer 23, 24 in such a way that parasitic contact losses are substantially avoided.
- This is achieved by the combination of bilateral (substantially) symmetrical texture T, wherein the roughness is retained on the back RS and with deposition of the following layer sequence: ⁇ therm. Si0 2 (optional) ⁇ , Al 2 O 3, SiN x or SiO x , viewed from the back RS.
- the first dielectric layer 23, which contains stationary negative charges after deposition, is first applied to the rear side RS after optionally depositing a silicon oxide layer having a thickness of preferably between 1 m and 10 nm.
- a fluorine doped silicon oxide layer is applied to the second dielectric layer 24, which may be silicon nitride, silicon oxide or silicon oxynitride.
- a backside metal layer 25, in particular an aluminum layer, is then applied to the second dielectric layer 24 and contacted with the silicon substrate 21 at desired locations through the first and second dielectric layers 23, 24.
- a front side contact 27 is applied in the usual way.
- the rear side RS is not smoothly etched, but rather can be termed textured, since during etching of the front or top side OS, which faces the incident radiation, the rear side RS is also etched.
- the ⁇ -layer 23 is designed so that no "blistering" occurs in combination with the subsequent processing.
- the process control is carried out in such a way that substantially no increased recombination occurs despite the increased surface area of the rear side RS.
- Roughness-reducing etching of the entire backside surface occurs exclusively after the diffusion of the dopant to form a pn junction in the silicon substrate 21, regardless of whether the diffusion is performed on one or both sides.
- the removal is as high as necessary to remove the layer formed by diffusion of the dopant layer, so typically greater than 0.5 ⁇ , but less than. 5 ⁇ . Due to the contained negative charges in the first dielectric layer 23, the losses due to parasitic contacts are minimized.
- the layer structure also helps ensure that even on a rough surface as possible no parasitic contacts are formed.
- the sole FIGURE shows a solar cell produced by the method previously described as method II., which has a non-brightly etched reverse side RS.
- the solar cell has a silicon wafer 21 with p-doping, in which a multi- or monocrystalline formation can be present.
- the surfaces, ie the front side OS and back RS are etched in order to remove sawing damage or to form a texture T.
- An otherwise performed according to the prior art separate Glanzlegien the back RS omitted.
- an n-doping substance such as phosphorus is diffused (layer 22).
- a silicon oxide layer may be previously applied directly to the back RS, with a thickness between 1 nm and 10 nm being preferred.
- a second dielectric layer 24 is then deposited from a material such as silicon nitride, silicon oxide or silicon oxynitride, wherein the thickness is preferably between 40 nm and 400 nm.
- the second dielectric layer 24 may also be referred to as a capping layer.
- a metal layer, in particular an aluminum layer 25 is applied to the free outer side of the second dielectric layer 24. This can be done by vapor deposition or screen printing. Then, a preferably punctiform contacting takes place between the metal layer 25 and the substrate 21.
- local metal-semiconductor contacts 26 can be produced by local heating of the backside metal by means of laser radiation such that the metal penetrates the dielectric layers 23, 24 and connects to the silicon.
- the front side OS has a front side contact 27 in the usual way.
- the inventive method allows the production of an improved Si solar cell with as few manufacturing steps, in particular in addition to the standard process (1 diffusion step, screen printing contacts).
Landscapes
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Sustainable Energy (AREA)
- Photovoltaic Devices (AREA)
Abstract
L'invention concerne un procédé de fabrication d'une cellule photovoltaïque et une cellule photovoltaïque ainsi fabriquée. La cellule photovoltaïque comprend un substrat en silicium avec une face avant dirigée vers le rayonnement et une face arrière, une première couche diélectrique s'étendant le long de la face arrière, une deuxième couche diélectrique s'étendant le long de la face opposée au substrat de la première couche diélectrique et constituée d'un matériau choisi dans le groupe constitué par le nitrure de silicium, l'oxyde de silicium et l'oxynitrure de silicium, ainsi qu'une couche métallique s'étendant le long de la face opposée au substrat de la deuxième couche diélectrique. L'objet de la présente invention est de fabriquer une cellule photovoltaïque de manière reproductible avec un rendement particulièrement élevé et un petit nombre d'étapes de procédé. A cet effet, la face arrière du substrat présente une brillance inférieure à 80 UB sous un angle d'incidence de 60° et la première couche diélectrique contient des charges négatives immobiles.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011052310 | 2011-07-29 | ||
DE201210102745 DE102012102745A1 (de) | 2011-07-29 | 2012-03-29 | Verfahren zur Herstellung einer Solarzelle sowie Solarzelle |
PCT/EP2012/064715 WO2013017526A2 (fr) | 2011-07-29 | 2012-07-26 | Procédé de fabrication d'une cellule photovoltaïque et cellule photovoltaïque |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2737543A2 true EP2737543A2 (fr) | 2014-06-04 |
Family
ID=47503223
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12740153.7A Withdrawn EP2737543A2 (fr) | 2011-07-29 | 2012-07-26 | Procédé de fabrication d'une cellule photovoltaïque et cellule photovoltaïque |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP2737543A2 (fr) |
CN (1) | CN103718311A (fr) |
DE (1) | DE102012102745A1 (fr) |
TW (1) | TW201312779A (fr) |
WO (1) | WO2013017526A2 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI492400B (zh) * | 2013-02-21 | 2015-07-11 | 茂迪股份有限公司 | 太陽能電池及其製造方法與太陽能電池模組 |
CN104241410B (zh) * | 2014-09-24 | 2017-07-14 | 中国科学院宁波材料技术与工程研究所 | 复合硅基材料及其制法和应用 |
US9559245B2 (en) * | 2015-03-23 | 2017-01-31 | Sunpower Corporation | Blister-free polycrystalline silicon for solar cells |
TWI539613B (zh) * | 2015-07-16 | 2016-06-21 | 有成精密股份有限公司 | 高功率太陽能電池模組 |
CN110120431A (zh) * | 2019-05-28 | 2019-08-13 | 中国科学院物理研究所 | 具有v型槽绒面的硅片及其应用 |
DE102019114498A1 (de) * | 2019-05-29 | 2020-12-03 | Hanwha Q Cells Gmbh | Wafer-Solarzelle, Solarmodul und Verfahren zur Herstellung der Wafer-Solarzelle |
CN110289333B (zh) * | 2019-07-10 | 2022-02-08 | 江苏隆基乐叶光伏科技有限公司 | 一种太阳电池、生产方法及光伏组件 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3815512C2 (de) | 1988-05-06 | 1994-07-28 | Deutsche Aerospace | Solarzelle und Verfahren zu ihrer Herstellung |
US6600557B1 (en) * | 1999-05-21 | 2003-07-29 | Memc Electronic Materials, Inc. | Method for the detection of processing-induced defects in a silicon wafer |
DE10046170A1 (de) | 2000-09-19 | 2002-04-04 | Fraunhofer Ges Forschung | Verfahren zur Herstellung eines Halbleiter-Metallkontaktes durch eine dielektrische Schicht |
US7659475B2 (en) | 2003-06-20 | 2010-02-09 | Imec | Method for backside surface passivation of solar cells and solar cells with such passivation |
EP1763086A1 (fr) | 2005-09-09 | 2007-03-14 | Interuniversitair Micro-Elektronica Centrum | Cellule solaire avec une couche épaisse de passivation d'oxyde de silicium et de nitrure de silicium et son procédé de fabrication |
EP2068369A1 (fr) * | 2007-12-03 | 2009-06-10 | Interuniversitair Microelektronica Centrum (IMEC) | Cellules photovoltaïques ayant un circuit métallique et une passivation améliorée |
TW200929575A (en) * | 2007-12-28 | 2009-07-01 | Ind Tech Res Inst | A passivation layer structure of the solar cell and the method of the fabricating |
US8338220B2 (en) * | 2009-02-06 | 2012-12-25 | Applied Materials, Inc. | Negatively charged passivation layer in a photovoltaic cell |
US20110132444A1 (en) * | 2010-01-08 | 2011-06-09 | Meier Daniel L | Solar cell including sputtered reflective layer and method of manufacture thereof |
DE102010017155B4 (de) * | 2010-05-31 | 2012-01-26 | Q-Cells Se | Solarzelle |
-
2012
- 2012-03-29 DE DE201210102745 patent/DE102012102745A1/de not_active Withdrawn
- 2012-07-26 WO PCT/EP2012/064715 patent/WO2013017526A2/fr active Application Filing
- 2012-07-26 CN CN201280037938.XA patent/CN103718311A/zh active Pending
- 2012-07-26 EP EP12740153.7A patent/EP2737543A2/fr not_active Withdrawn
- 2012-07-27 TW TW101127174A patent/TW201312779A/zh unknown
Non-Patent Citations (1)
Title |
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See references of WO2013017526A2 * |
Also Published As
Publication number | Publication date |
---|---|
CN103718311A (zh) | 2014-04-09 |
TW201312779A (zh) | 2013-03-16 |
WO2013017526A2 (fr) | 2013-02-07 |
WO2013017526A3 (fr) | 2013-11-07 |
DE102012102745A1 (de) | 2013-01-31 |
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