EP2731742A1 - Vertikales semikontinuierliches giessverfahren für mehrere legierungen - Google Patents
Vertikales semikontinuierliches giessverfahren für mehrere legierungenInfo
- Publication number
- EP2731742A1 EP2731742A1 EP12748724.7A EP12748724A EP2731742A1 EP 2731742 A1 EP2731742 A1 EP 2731742A1 EP 12748724 A EP12748724 A EP 12748724A EP 2731742 A1 EP2731742 A1 EP 2731742A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- separator
- casting
- alloy
- alloys
- plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 98
- 239000000956 alloy Substances 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000009749 continuous casting Methods 0.000 title claims abstract description 14
- 238000005266 casting Methods 0.000 claims abstract description 46
- 238000007711 solidification Methods 0.000 claims abstract description 31
- 230000008023 solidification Effects 0.000 claims abstract description 31
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims abstract description 9
- 229910001338 liquidmetal Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 239000011819 refractory material Substances 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 238000009987 spinning Methods 0.000 claims description 7
- 239000003365 glass fiber Substances 0.000 claims description 6
- 239000007769 metal material Substances 0.000 claims description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- 239000003870 refractory metal Substances 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 239000011226 reinforced ceramic Substances 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 2
- 239000002436 steel type Substances 0.000 claims 2
- 238000005520 cutting process Methods 0.000 claims 1
- 239000002131 composite material Substances 0.000 abstract description 4
- 239000000047 product Substances 0.000 description 9
- 229910001152 Bi alloy Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 239000011701 zinc Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000007747 plating Methods 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005275 alloying Methods 0.000 description 3
- 238000005219 brazing Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000005098 hot rolling Methods 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000004611 spectroscopical analysis Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 210000000887 face Anatomy 0.000 description 2
- 210000001061 forehead Anatomy 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003351 stiffener Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010301 surface-oxidation reaction Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/14—Plants for continuous casting
- B22D11/141—Plants for continuous casting for vertical casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/007—Continuous casting of metals, i.e. casting in indefinite lengths of composite ingots, i.e. two or more molten metals of different compositions being used to integrally cast the ingots
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
Definitions
- the invention relates to the field of the manufacture of semi-finished products such as rolling plates and spinning billets of aluminum alloys by vertical semi-continuous casting.
- the invention relates to a method of vertical semi-continuous casting of plates or billets comprising at least two aluminum alloys, by simultaneous casting and using at least one separator.
- the invention also relates to the device for implementing said method and the manufacture of said plates or billets.
- Aluminum is increasingly used in the fields of aeronautic and automobile construction, as regards fuselage sheets, longitudinal members and wing stiffeners, as well as body panels and brazed heat exchangers for automobiles, for reasons of weight limitation, but also for optical reflectors or shielding sheets, molds for thermoplastics, forging parts, machining parts.
- All aluminum alloys referred to in the following are designated, unless otherwise indicated, in accordance with the designations defined by "Aluminum Association” in the “Registration Record Series” which it publishes regularly.
- the use of homogeneous alloys makes it possible to fulfill certain requirements, but substantial improvements could be obtained if it were possible, for example, to control a variation in composition between the surface and the core of a sheet or between the surface and the heart of an extrusion, forging or machining plot, and thus to differentiate the surface properties of the properties at heart.
- Veneered products made by hot co-rolling two plates of different alloys exist for certain applications, such as for example:
- the plating is then an alloy with a lower melting point than the core, and will become the filler metal which will ensure the connection between the parts to be assembled during the brazing process.
- bilayer products including optical reflectors, with any inexpensive alloy coated with a high-purity aluminum alloy or the bilayer products for shielding in the military field.
- this hot-rolling method can not be applied to all families of alloys, especially alloys containing magnesium and / or zinc in a significant amount (products intended in particular for the automotive, aeronautical or other industry). ) because of the surface oxidation of Mg and / or Zn-rich alloys. It also very often requires a double hot rolling, which is not favorable from the point of view of productivity, nor from the economic point of view.
- No. 4,567,936 of Kaiser Aluminum & Chemical Corporation claims, for its part, a bi-alloy casting in which the core is fully encapsulated in the cover alloy layer.
- This outer layer is previously solidified and the core alloy is cast inside this shell.
- the outer alloy must have a significantly higher liquidus than the core alloy.
- the inner surface of the outer layer is necessarily oxidized and it is again difficult to ensure a metallurgical bond between the two layers.
- the main claim of the patent is also to protect the inner alloy, type Al-Li, direct cooling water.
- the invention aims to solve these difficulties by allowing the introduction of a separator in direct contact with the solidification front without it being taken by the metal which solidifies and entrained by the solid; in this way, it is a question of ensuring the seal between the two alloys by limiting the possible mixture, via the semi-solid zone even if there is a difference in level on either side of the separator.
- the subject of the invention is a method for direct cooling vertical semi-continuous casting of rolling plates or spinning billets in which a separator and two means for supplying liquid metal, typically nozzles or chutes, arranged on both sides. other of said separator are used, comprising the following steps: a) Casting a first aluminum alloy in the vertical semi-continuous casting mold using the first nozzle,
- said separator is raised slightly before stopping the casting, allowing mixing between the alloys in an area corresponding to said end of casting, and this area is then trimmed.
- the separator may be a substantially flat plate whose cutout in the lower part matches a vertical section of the solidification front through the mold from one side to the casting of plates or billets having layers of different alloys superimposed.
- It may also be a hollow cylindrical body generally, but not necessarily, respecting the geometric symmetry of the product for the casting of composite billets, but also a hollow body with a substantially rectangular section for casting so-called internally lined plates with an alloy other than the outer alloy.
- the substantially rectangular section of the separator may be rounded corners, so as to marry a horizontal section of the solidification front of the cast plate, or perfectly rectangular section.
- said separator is then delimited in the lower part by a flat surface with angles rolled up so as to follow the shape of the solidification front in said corners.
- said separator may be of metal material of the steel or refractory metal type such as in particular molybdenum or tungsten, but this is not limiting.
- It can also be made of refractory material based on ceramic or glass fiber reinforced ceramic.
- the vibration of said separator is of low amplitude, typically of the order of one hundred ⁇ at frequencies of the order of one hundred Hz up to ultrasonic frequencies.
- This vibration is produced by a vibrator chosen from the group of pneumatic, electric or ultrasonic vibrators, without limitation.
- the vibration frequency is 100 to 20000 Hz and, advantageously, the vibration amplitude is 100 to 200 ⁇ .
- said first and second alloys are of identical compositions. Indeed, the Applicant has found that the vibration had the positive effect of reducing meso-segregations dendritic.
- the method can be applied to the casting of more than two alloys then implementing more than one separator.
- the subject of the invention is also the means for implementing said method, namely a vertical direct-slab casting device for plates or billets comprising a cylindrical or rectangular tubular vertical semi-continuous casting mold with open ends. , with the exception of the lower end closed at the beginning of casting by a false bottom which moves downwards thanks to a descender during the casting of the plate or billet, the upper end being intended for feeding metal, the lower end at the outlet of the plate or billet, said upper end being provided with two liquid metal supply means, typically nozzles or chutes, and a separator adapted to be introduced into the mold, in the liquid metal swamp in contact with the solidification front, thereby dividing the swamp into two distinct zones, characterized in that said separator ur is connected to a vibrator allowing to animate it with a typically multidirectional vibration movement, at least during the entire duration of its contact with the solidification front, the vibration being of the low amplitude type, typically of the order of one hundred ⁇ , preferably 100 at 200 ⁇ , at frequencies of the order of one hundred Hz
- the separator may be a substantially flat plate or a hollow cylindrical body associated with a tubular mold of substantially circular section, or a hollow body of substantially rectangular section associated with a tubular mold of substantially rectangular section.
- the substantially rectangular section of said separator may be rounded corners.
- Said section may also be perfectly rectangular and said separator is then delimited in the lower part by a flat surface with rolled angles to match the shape of the solidification front in said corners.
- said separator may be of metal material of the steel or refractory metal type such as in particular molybdenum or tungsten, but this is not limiting.
- It can also be made of refractory material based on ceramic or glass fiber reinforced ceramic.
- the vibration it is produced by a vibrator chosen from the group of pneumatic, electric or ultrasonic vibrators.
- said device may comprise more than one separator, more than two liquid metal supply means, for casting plates or billets comprising more than two aluminum alloys.
- FIG. 1 represents in section the first casting phase of the first alloy 1, in the mold 6 provided with a riser made of refractory material 7, on the "seat” or “casting” 8, also called false bottom, the front solidification bearing the mark 2, the separator 3, here of the rectangle or cylinder type, being fixed to the plate 4 which is itself fixed the vibrator (not shown) connected to the mounting 5 by flexible springs, said assembly moving up and down through guides 9.
- FIG. 2 represents the second phase during which the separator 3 is brought into contact with the solidification front and the vibration 10 is engaged.
- FIG. 3 represents the third phase during which the feed nozzle 11 of second alloy 12 is put in place and the second cast alloy.
- Figure 4 corresponds to the steady state, the second alloy 12 being at the heart of the plate or billet and the first 1 in the lower part to crop, mixed with the second alloy, and periphery.
- FIG. 5 represents the Zn% of a cross-section of the bi-alloy plate of Example 2 with AA5083 alloy exterior and AA7449 alloy core as a function of the distance d in mm from an external face of the plate. in the direction of the thickness, obtained by spark spectrometry.
- FIG. 6 represents the Zn% of a cross-section of the bi-alloy plate of Example 2 with AA6016 alloy exterior and AA7021 alloy core as a function of the distance d in mm from an external face of the plate. in the direction of the thickness, obtained by spark spectrometry. Description of the invention
- the invention consists in animating the separator with a low amplitude vibratory movement, typically from 100 to 200 ⁇ , which, breaking the dendrites that form on contact, locally repels the dendritic coherence towards higher solidified fractions and thus ensures that the separator is not driven by the solid metal.
- a low amplitude vibratory movement typically from 100 to 200 ⁇
- the separator can be a hollow cylindrical body, preferably delimited at the bottom by a plane horizontal, and whose section then marries a horizontal section of the solidification front, so as to obtain a good seal.
- the cross section of the separator is, for rectangular plates, calculated by 3D thermal modeling of the solidification front and takes the form of a rectangle with rounded corners according to a specific law. It is possible, if it is desired that the separation of the alloys occurs at a constant distance from the surfaces of the plate, including near the edges, to design a separator of perfectly rectangular section; in the lower part it is no longer delimited by a plane, but by a flat surface whose angles are rolled up to match the shape of the front in the corners, and which can also be calculated by 3D thermal modeling of the front.
- the section of the separator is of course circular.
- separators can be used: nonmetallic refractory material, or metal material (steel, refractory metals such as Mo or W) with, depending on the case, a protective coating against attack by liquid aluminum.
- This configuration makes it possible to respect, if necessary, the geometric and thermal symmetry of the plate or the bi-alloy billet.
- This concept of "filled" plate or billet, in which a core of a first alloy is totally included in a second alloy also offers new possibilities compared to existing processes. Indeed, thanks to the presence of the outer alloy on the sides of the plate (which is not the case for the Fusion TM process, nor for the co-rolling processes), it is possible to envisage the transformation by rolling.
- magnesium-rich core alloys (more than 5% or even 7%) in Zn (up to 15% or more) in Cu (up to 5% or more), in Li (up to 2% or more), Si (including hypereutectic content), or a combination of these elements, while avoiding a phenomenon of cracking from the edges, encountered today during hot rolling attempts of this type of multilayer .
- compositions lead to a good compromise between mechanical strength / formability and the coating can also make it possible to improve in particular their resistance to corrosion and / or their formability.
- the manufacture of filled billets can have the additional advantage of allowing the very fast extrusion of hard alloys protected by a less hard alloy sheath, in order to be able to dissolve the hard alloy on simple heat of spinning: indeed the Spinning speeds required are impractical on hard alloys because of their poor spinnability. Since the hard alloy is surrounded by a "soft" alloy layer, the assembly becomes easier to spin and at a higher speed, which makes it possible to precisely dissolve the hard alloy on simple spinning heat. This specificity is particularly interesting, especially in the case of reverse spinning.
- the separator may also consist of a flat plate cut so that it matches a vertical section of the solidification front parallel to one of the faces of the plate, or to one of the generatrices in the case of billets .
- a filled plate or billet is no longer obtained, but two-layer or even three-layer products if two flat separators are used, or even more.
- the separator may not respect the geometric and thermal symmetry of the plate or billet to obtain different layer thicknesses on the different faces.
- the casting of the filled plates or billets is started with the only peripheral alloy. Then the separator is introduced into the liquid metal, vibrated, lowered in contact with the front while the supply channel of the core alloy is lowered canned, so as to feed the interior of the separator with the soul alloy. As long as the vibration is activated, it prevents the capture of the separator by the forehead. Experience shows that it is possible to obtain level differences between the two sides of the separator, in one direction or another, which is proof of a good seal. At the end of casting, the separator is raised: there is thus mixing between the two alloys. This zone must be trimmed unless it is deliberately desired to obtain a variation of composition in the length of the cast billet or billet, the alloys having been chosen accordingly. It's a additional degree of freedom offered by the casting process with vibrating separator.
- the casting is started with a single alloy. Then the plate separator is introduced into the liquid metal, vibrated, lowered in contact with the front while the supply chute of the other alloy is lowered in order to feed the other side of the separator with the other alloy. The rest of the casting is carried out as in the previous case.
- the invention can also be applied for the production of ingots, plates, or billets, comprising more than two layers of aluminum alloys, while using more than one separator.
- EXAMPLE 1 This first test is not in accordance with the invention because the separator, of the plate type, does not pass through the mold from one side and a single casting of a single alloy has been implemented, but it was intended to demonstrate the effectiveness of the vibration to prevent the drive of the plate by the solidified metal.
- a one-piece refractory composite / glass fiber plate was introduced and vibrated in the swamp of an AA1050 alloy rolling plate casting with a 1,100x300mm cross section.
- the refractory plate was 200mm wide. It was introduced parallel to the large rolling face, 65mm from the wall of the mold.
- the vibration of the refractory plate was provided by a pneumatic vibrator of the "Netter NTC" type such as those used for the emptying of the grain silos and other hoppers. This is a multidirectional vibration of small amplitude.
- the vibrated plate was brought into contact with the solidification front. Drills using a stick have made sure of the effectiveness of this contact. Different pressures of the pneumatic vibrator (between 2 bars and 4 bars) have been tested, so that, taking into account the natural vibration frequencies of the assembly, a vibration amplitude of the order of 100 to 200 ⁇ m is obtained at a frequency of the order of 100Hz.
- the plate was immediately taken by the forehead.
- the dimensions of the total cross section of the plates were 1100 x 300mm.
- a one-piece refractory composite / glass fiber separator whose cross-section, substantially rectangular, conformed to the solidification front in a horizontal plane, was manufactured and used to obtain an outer alloy layer of 75 mm thick. thickness at the periphery of the plate. At bends near the corners, dictated by the shape of the solidification front in these areas, the core was homothetic to the total section, with typical dimensions of 950x150mm.
- the thickness of the separator was 12mm over its entire height and gradually increased to 4mm at the bottom end, to a height of 15mm.
- the separator was introduced into the marsh, lowered into contact with the solidification front, while vibrating under the same conditions as those of Example 1, so that that it is not carried away by the solid metal.
- the vibration was obtained thanks to the same pneumatic vibrator screwed on the metal support frame of the separator.
- This support slid on vertical guide rods and was motorized using a worm system.
- the chute leading the core alloy was then lowered and the internal cavity of the separator fed.
- a spark spectrometry measurement of the zinc content of a cross-section for the two types of plate as a function of the distance d in mm of an outer face of the plate in the direction of the thickness was carried out.
- composition profiles are represented in FIGS. 5 and 6 and confirm the quite effective separation of the alloys.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Metal Rolling (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1102197A FR2977817B1 (fr) | 2011-07-12 | 2011-07-12 | Procede de coulee semi-continue verticale multi-alliages |
PCT/FR2012/000280 WO2013007891A1 (fr) | 2011-07-12 | 2012-07-10 | Procede de coulee semi-continue verticale multi-alliages |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2731742A1 true EP2731742A1 (de) | 2014-05-21 |
EP2731742B1 EP2731742B1 (de) | 2015-04-08 |
Family
ID=46717872
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12748724.7A Active EP2731742B1 (de) | 2011-07-12 | 2012-07-10 | Vertikales semikontinuierliches giessverfahren für mehrere legierungen |
Country Status (9)
Country | Link |
---|---|
US (1) | US8985190B2 (de) |
EP (1) | EP2731742B1 (de) |
JP (1) | JP6014663B2 (de) |
CN (1) | CN103648683B (de) |
AU (1) | AU2012282371B2 (de) |
CA (1) | CA2841291C (de) |
ES (1) | ES2541678T3 (de) |
FR (1) | FR2977817B1 (de) |
WO (1) | WO2013007891A1 (de) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2452763A1 (de) | 2008-03-05 | 2012-05-16 | Southwire Company | Grafitdruckgiessteil mit Niobium-Schutzschicht und entspreches Druckgiessverfahren |
US8652397B2 (en) | 2010-04-09 | 2014-02-18 | Southwire Company | Ultrasonic device with integrated gas delivery system |
PT2556176T (pt) | 2010-04-09 | 2020-05-12 | Southwire Co | Dispositivo ultrassónico com sistema integrado de entrega de gás |
EP3071718B1 (de) | 2013-11-18 | 2019-06-05 | Southwire Company, LLC | Ultraschallsonden mit gasauslässen zum entgasen von metallschmelze |
PL3256275T3 (pl) | 2015-02-09 | 2020-10-05 | Hans Tech, Llc | Ultradźwiękowa rafinacja ziarna |
CN104827005A (zh) * | 2015-05-29 | 2015-08-12 | 内蒙古汇豪镁业有限公司 | 合金连铸结晶区超声波搅拌装置 |
US10233515B1 (en) | 2015-08-14 | 2019-03-19 | Southwire Company, Llc | Metal treatment station for use with ultrasonic degassing system |
CN114871418A (zh) | 2015-09-10 | 2022-08-09 | 南线有限责任公司 | 用于金属铸造的超声晶粒细化和脱气程序及系统 |
CN106735002B (zh) * | 2016-12-29 | 2018-10-09 | 重庆大学 | 一种自抑控流式双水口电磁复合浇铸装置 |
CN108526425B (zh) * | 2018-03-30 | 2020-09-01 | 鞍钢股份有限公司 | 一种复合金属连铸装置及连铸方法 |
WO2020117950A1 (en) * | 2018-12-04 | 2020-06-11 | Kozicki Michael N | Dendritic tags |
CN109773145B (zh) * | 2018-12-27 | 2021-05-07 | 北京科技大学 | 一种贵金属层状复合材料高真空连铸成形设备和工艺 |
CN110508764B (zh) * | 2019-09-20 | 2021-01-15 | 哈尔滨工业大学 | 一种等外径薄壁合金铸件行波磁场/超声波协同优化的半连铸设备及其半连铸方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3206808A (en) * | 1962-08-14 | 1965-09-21 | Reynolds Metals Co | Composite-ingot casting system |
US4567936A (en) | 1984-08-20 | 1986-02-04 | Kaiser Aluminum & Chemical Corporation | Composite ingot casting |
JPH05253651A (ja) * | 1992-03-12 | 1993-10-05 | Nippon Steel Corp | 双ロール式連続鋳造によるクラッド鋼板の鋳造方法 |
DE4420697C2 (de) | 1994-06-14 | 1997-02-27 | Inst Verformungskunde Und Huet | Stranggießkokille zum Gießen eines Verbundmetallstranges mit einem Trennkörper zum Trennen der eingegossenen Schmelzen der Teilstränge |
ATE250476T1 (de) * | 1996-12-03 | 2003-10-15 | Corus Aluminium Walzprod Gmbh | Mehrschichtige metallverbundwerkstoffe hergestellt durch stranggiessen von metallverbundsträngen |
US6705384B2 (en) | 2001-10-23 | 2004-03-16 | Alcoa Inc. | Simultaneous multi-alloy casting |
PT1638715E (pt) | 2003-06-24 | 2008-03-17 | Novelis Inc | Processo para moldagem de uma lingote compósito |
BRPI0602943B1 (pt) | 2006-06-30 | 2017-05-23 | Brudden Equip | sinalizador de desalinhamento de correia de esteira ergométrica |
JP2010519055A (ja) * | 2007-02-28 | 2010-06-03 | ノベリス・インコーポレイテッド | ダイレクトチル鋳造法による金属の同時鋳造 |
WO2009024601A1 (en) | 2007-08-23 | 2009-02-26 | Aleris Aluminum Koblenz Gmbh | Method for casting a composite aluminium alloy ingot or billet |
WO2010012099A1 (en) | 2008-07-31 | 2010-02-04 | Novelis Inc. | Sequential casting of metals having similar freezing ranges |
-
2011
- 2011-07-12 FR FR1102197A patent/FR2977817B1/fr active Active
-
2012
- 2012-07-10 CA CA2841291A patent/CA2841291C/fr not_active Expired - Fee Related
- 2012-07-10 CN CN201280034764.1A patent/CN103648683B/zh not_active Expired - Fee Related
- 2012-07-10 AU AU2012282371A patent/AU2012282371B2/en not_active Ceased
- 2012-07-10 US US14/131,421 patent/US8985190B2/en not_active Expired - Fee Related
- 2012-07-10 EP EP12748724.7A patent/EP2731742B1/de active Active
- 2012-07-10 WO PCT/FR2012/000280 patent/WO2013007891A1/fr active Application Filing
- 2012-07-10 ES ES12748724.7T patent/ES2541678T3/es active Active
- 2012-07-10 JP JP2014519595A patent/JP6014663B2/ja not_active Expired - Fee Related
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Also Published As
Publication number | Publication date |
---|---|
CN103648683A (zh) | 2014-03-19 |
JP6014663B2 (ja) | 2016-10-25 |
US8985190B2 (en) | 2015-03-24 |
AU2012282371B2 (en) | 2016-05-12 |
AU2012282371A1 (en) | 2014-01-30 |
JP2014520674A (ja) | 2014-08-25 |
FR2977817B1 (fr) | 2013-07-19 |
CA2841291A1 (fr) | 2013-01-17 |
US20140138041A1 (en) | 2014-05-22 |
CA2841291C (fr) | 2019-03-05 |
WO2013007891A1 (fr) | 2013-01-17 |
EP2731742B1 (de) | 2015-04-08 |
ES2541678T3 (es) | 2015-07-23 |
FR2977817A1 (fr) | 2013-01-18 |
CN103648683B (zh) | 2015-07-29 |
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