EP2711501A2

EP2711501A2 - Nickel-based alloy and turbine component having nickel-based alloy

Info

Publication number: EP2711501A2
Application number: EP13177491.1A
Authority: EP
Inventors: Ganjiang Feng; Michael Douglas Arnett; Yan Cui; Shan Liu; Matthew Laylock
Original assignee: General Electric Co
Current assignee: General Electric Co
Priority date: 2012-07-31
Filing date: 2013-07-22
Publication date: 2014-03-26
Also published as: US20140205490A1; JP2014111822A

Abstract

A nickel-based alloy and a turbine component including a nickel-based alloy are disclosed. The nickel-based alloy includes, by weight, between about 8% and about 11% cobalt, up to about 3% niobium, up to about 3% titanium, up to about 2.3% aluminum, up to about 3% tungsten, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel, or the nickel-based alloy includes, by weight, between about 1% and about 3% niobium, between about 1% and about 3% titanium, between about 2.1% and about 2.5% aluminum, up to about 3% tungsten, up to about 11% cobalt, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel. The turbine component includes the nickel-based alloy.

Description

FIELD OF THE INVENTION

The present invention is directed to alloys and turbine components containing alloys. More specifically, the present invention is directed to nickel-based alloys.

BACKGROUND OF THE INVENTION

Gas turbine components are subjected to both thermally, mechanically, and chemically hostile environments. For example, in the compressor portion of a gas turbine, atmospheric air is compressed, for example, to 10-25 times atmospheric pressure, and adiabatically heated, for example, to 800° - 1250° F (427° C - 677° C), in the process. This heated and compressed air is directed into a combustor, where it is mixed with fuel. The fuel is ignited, and the combustion process heats the gases to very high temperatures, for example, in excess of 3000° F (1650° C). These hot gases pass through the turbine, where airfoils fixed to rotating turbine disks extract energy to drive the fan and compressor of the turbine, and the exhaust system, where the gases provide sufficient energy to rotate a generator rotor to produce electricity. To improve the efficiency of operation of the turbine, combustion temperatures have been raised. To handle such higher temperatures, it is desirable to improve the properties of materials within such components.
Many alloys used in these environments include cobalt. One known alloy having cobalt at a relatively high concentration has a composition, by weight, of between about 15% and about 20% cobalt, between about 10% and 19% chromium, between about 2.5% and 3.4% aluminum, less than about 0.5% tantalum, less than about 1.0% molybdenum, less than about 0.06% zirconium, less than about 0.04% boron, between about 1.1% and about 1.5% niobium, between about 3.0% and 3.9% titanium, up to about 3% tungsten, between about 0.03% and 0.07% carbon, and a balance of nickel. Another known alloy having cobalt at relatively high concentration has a composition, by weight, of about between about 0.08% and 0.12% carbon, between about 22.2% and 22.8% chromium, about 0.10% manganese, about 0.25% silicon, between about 18.5% and 19.5% cobalt, between about 1.8% and 2.2% tungsten, about 2.3% titanium, about 1.2% aluminum, about 1.0% tantalum, about 0.8% niobium, about 0.05% zirconium, about 0.008% boron, and a balance of nickel. Another known alloy has a composition, by weight, of about 22.5% chromium, about 19% cobalt, about 2% tungsten, about 1.35% niobium, about 2.3% titanium, about 1.2% aluminum, about 0.1% carbon, about 0.01% zirconium, about 0.01% boron, and a balance of nickel. Another alloy has a composition, by weight, of about 22.5% chromium, about 19% cobalt, about 2% tungsten, about 1.35% niobium, about 2.3% titanium, about 1.7% aluminum, about 0.1% carbon, about 0.01% zirconium, about 0.01% boron and a balance of nickel.
In general, the above alloys have desirable mechanical properties, oxidation-resistance properties, and hot corrosion properties. However, using cobalt at these high concentrations can be undesirable because cobalt has been subject to substantial price fluctuations, limited availability, and often comes from regions having geopolitical instability. Prior attempts to reduce cobalt have been unsuccessful in maintaining these properties, especially creep strength.
A nickel-based alloy and a turbine component containing a nickel-based alloy that do not suffer from one or more of the above drawbacks would be desirable in the art.

BRIEF DESCRIPTION OF THE INVENTION

In an exemplary embodiment, a nickel-based alloy includes, by weight, between about 8% and about 11% cobalt, up to about 3% niobium, up to about 3% titanium, up to about 2.3% aluminum, up to about 3% tungsten, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel.
In another exemplary embodiment, a nickel-based alloy includes, by weight, between about 1% and about 3% niobium, between about 1% and about 3% titanium, between about 2.1% and about 2.5% aluminum, up to about 3% tungsten, up to about 11% cobalt, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel.
In another exemplary embodiment, a turbine component includes one or both of a first nickel-based alloy comprising between about 8% and about 11% cobalt, up to about 3% niobium, up to about 3% titanium, up to about 2.3% aluminum, up to about 3% tungsten, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel and a second nickel-based alloy comprising between about 1% and about 3% niobium, between about 1% and about 3% titanium, between about 2.1% and about 2.5% aluminum, up to about 3% tungsten, up to about 11% cobalt, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel.
Other features and advantages of the present invention will be apparent from the following more detailed description of the preferred embodiment, which illustrates, by way of example, the principles of the invention.

DETAILED DESCRIPTION OF THE INVENTION

Provided is an exemplary nickel-based alloy and a turbine component containing a nickel-based alloy. Embodiments of the present disclosure have desirable mechanical properties, oxidation-resistance properties, hot corrosion properties, creep strength, and permit resistance to price fluctuations of cobalt and/or limited availability of cobalt, or combinations thereof. In some embodiments, in comparison to the known higher cobalt alloys, the exemplary nickel-based alloy includes substantially equivalent or increased weldability, castability, structural stability, high temperature strength, hot corrosion resistance, creep strength, yield strength, ductility, phase stability, gamma prime (volume, fraction, size, and/or distribution), or combinations thereof.
The exemplary nickel-based alloy includes cobalt, chromium, tungsten, niobium, titanium, aluminum, carbon, boron, and nickel. In one embodiment, the nickel-based alloy is all or a portion of a turbine component, such as, a turbine nozzle casting, a turbine blade, a turbine bucket, a turbine dovetail, and/or any other suitable component.
The cobalt is at a concentration, by weight, of between about 8% and about 11%. In further embodiments, the cobalt is at a concentration, by weight, of between about 8% and about 10%, between about 8% and about 9.5%, at about 8%, at about 9%, at about 9.5%, at about 10%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the chromium is at a concentration, by weight, of up to about 25%, up to about 23%, up to about 22.5%, between about 20% and about 25%, between about 21% and about 23%, between about 22% and about 23%, at about 20%, at about 21%, at about 22%, at about 22.5%, at about 23%, at about 25%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the tungsten is at a concentration, by weight, between about 1% and about 3%, at about 1%, at about 2%, at about 2.5%, at about 3%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the niobium is at a concentration, by weight, between about 1% and about 3%, at about 2%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the titanium is at a concentration, by weight, between about 2% and about 3%, between about 2% and about 2.3%, between about 2.3% and about 2.5%, between about 2% and about 2.5%, at about 2.3%, at about 2.5%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the aluminum is at a concentration, by weight, of between about 2% and about 2.3%, at about 2.1%, at about 2.2%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the carbon is at a concentration, by weight, of up to about 0.1%, up to about 0.08%, between about 0.05% and about 0.15%, between about 0.05% and about 0.1%, between about 0.05% and about 0.08%, between about 0.08% and about 0.1%, at about 0.05%, at about 0.08%, at about 0.1%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the boron is at a concentration, by weight, of up to about 0.01%, up to about 0.008%, between about 0.005% and about 0.015%, between about 0.005% and about 0.01%, at about 0.005%, at about 0.008%, at about 0.01%, or any suitable combination, sub-combination, range, or sub-range thereof.
In one embodiment, the nickel-based alloy includes a balance of nickel.
In one embodiment, the nickel-based alloy includes or consists of, by weight, about 22.5% chromium, about 9.5%, cobalt, about 2% tungsten, about 2% niobium, about 2.3% titanium, about 2.3% aluminum, about 0.08% carbon, about 0.008% boron, incidental impurities, and a balance nickel.
In other embodiments, the nickel-based alloy is devoid or substantially devoid of tantalum, molybdenum, zirconium, or a combination thereof.
In one embodiment, the nickel-based alloy includes tensile strength at 1200°F for 0.2% yield strength of at about 90 ksi.
In one embodiment, the nickel-based alloy includes tensile ductility at 1200°F of greater than about 20%.
In one embodiment, the nickel-based alloy includes low-cycle fatigue properties (creep strength) at 1600°F with 0.7% strain for 2 minutes of greater than about 3,500 cycles prior to crack initiation.
In one embodiment, the nickel-based alloy exhibits 2% creep under 18 ksi at 1600°F after about 1,900 hours.
In one embodiment, the nickel-based alloy exhibits oxidation, after about 2,000 hours, at about 127 microns.
In one embodiment, the nickel-based alloy includes corrosion-resistance, under conditions of 1,700°F in 5 ppm salt with 0.4% sulfur. For example, in one embodiment, at about 600 hours, maximum penetration into the nickel-based alloy is at about 1.85 mils. In one embodiment, at about 1,000 hours, maximum penetration into the nickel-based alloy is at about 4.56 mils. In one embodiment, at about 1,400 hours, maximum penetration into the nickel-based alloy is at about 7.46 mils.
The terms "comprise", "comprising" and "include" are to be interpreted to also cover the terms "consist of" and "consisting of".
While the invention has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.

Claims

A nickel-based alloy, comprising, by weight:
between about 8% and about 11% cobalt, up to about 3% niobium, up to about 3% titanium, up to about 2.3% aluminum, up to about 3% tungsten, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and balance nickel.
The nickel-based alloy of claim 1, wherein the nickel-based alloy is a portion of a turbine component.
The nickel-based alloy of claim 2, wherein the turbine component is a turbine nozzle casing.
The nickel-based alloy of any preceding claim, wherein the cobalt is at a concentration, by weight, of about 9.5%.
The nickel-based alloy of any preceding claim, wherein the chromium is at a concentration, by weight, of about 22.5%.
The nickel-based alloy of any preceding claim, wherein the tungsten is at a concentration, by weight, of about 2%.
The nickel-based alloy of any preceding claim, wherein the niobium is at a concentration, by weight, of about 2%.
The nickel-based alloy of any preceding claim, wherein the titanium is at a concentration, by weight, of about 2.3%.
The nickel-based alloy of any preceding claim, wherein the aluminum is at a concentration, by weight, of about 2.3%.
The nickel-based alloy of any preceding claim, wherein the carbon is at a concentration, by weight, of about 0.08%.
The nickel-based alloy of any preceding claim, wherein the boron is at a concentration, by weight, of about 0.008%.
The nickel-based alloy of any preceding claim, wherein the nickel-based alloy includes one or more of :
(a) tensile strength at 1200°F for 0.2%, yield strength of about 90 ksi;

(b) tensile ductility at 1200°F of about 27%;

(c) low-cycle fatigue properties at 1600°F with 0.7% strain for 2 minutes of about 3,600 cycles prior to crack initiation;

(d) creep properties of 2% creep under 18 ksi at 1600°F at about 1,980 hours;

(e) oxidation, after about 2,000 hours, of about 127 microns;

(f) corrosion-resistance, under conditions of 1,700°F in 5 ppm salt with 0.4% sulfur, of about 47 microns after 600 hours, of about 116 microns after 1,000 hours, and 189 microns after 1,400 hours.
The nickel-based alloy of any preceding claim, wherein the nickel-based alloy includes substantially equivalent or increased weldability, castability, structural stability, high temperature strength, hot corrosion resistance, creep strength, yield strength, ductility, and phase stability in comparison to each of the following:
a first comparative alloy having a composition, by weight, of between about 15% and

about 20% cobalt, between about 10% and 19% chromium, between about 2.5% and 3.4% aluminum, less than about 0.5% tantalum, less than about 1.0% molybdenum, less than about 0.06% zirconium, less than about 0.04% boron, between about 1.1% and about 1.5% niobium, between about 3.0% and 3.9% titanium, up to about 3% tungsten, between about 0.03% and 0.07% carbon, and a balance of nickel;

a second comparative alloy having a composition, by weight, of about between about 0.08% and 0.12% carbon, between about 22.2% and 22.8% chromium, about 0.10% manganese, about 0.25% silicon, between about 18.5% and 19.5% cobalt, between about 1.8% and 2.2% tungsten, about 2.3% titanium, about 1.2% aluminum, about 1.0% tantalum, about 0.8% niobium, about 0.05% zirconium, about 0.008% boron, and a balance of nickel;

a third comparative alloy having a composition, by weight, of about 22.5% chromium, about 19% cobalt, about 2% tungsten, about 1.35% niobium, about 2.3% titanium, about 1.2% aluminum, about 0.1% carbon, about 0.01% zirconium, about 0.01% boron, and a balance of nickel; and

a fourth comparative alloy having a composition, by weight, of about 22.5% chromium, about 19% cobalt, about 2% tungsten, about 1.35% niobium, about 2.3% titanium, about 1.7% aluminum, about 0.1% carbon, about 0.01% zirconium, about 0.01% boron and a balance of nickel.
A nickel-based alloy, comprising, by weight:
between about 1% and about 3% niobium, between about 1% and about 3% titanium,

between about 2.1% and about 2.5% aluminum, up to about 3% tungsten, up to about 11% cobalt, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel.
A turbine component, comprising one or both of:
a first nickel-based alloy comprising between about 8% and about 11% cobalt, up to about 3% niobium, up to about 3% titanium, up to about 2.3% aluminum, up to about 3% tungsten, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel; and

a second nickel-based alloy comprising between about 1% and about 3% niobium,

between about 1% and about 3% titanium, between about 2.1% and about 2.5% aluminum, up to about 3% tungsten, up to about 11% cobalt, up to about 25% chromium, up to about 0.1% carbon, up to about 0.01% boron, and a balance nickel.