EP2704815A1 - Adsorber including parallel passage contactors having built-in insulation - Google Patents
Adsorber including parallel passage contactors having built-in insulationInfo
- Publication number
- EP2704815A1 EP2704815A1 EP12722442.6A EP12722442A EP2704815A1 EP 2704815 A1 EP2704815 A1 EP 2704815A1 EP 12722442 A EP12722442 A EP 12722442A EP 2704815 A1 EP2704815 A1 EP 2704815A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- adsorber
- channels
- parallel
- adsorber according
- insulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0423—Beds in columns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/302—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/404—Nitrogen oxides other than dinitrogen oxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
Definitions
- Adsorber comprising parallel passage contactors with integrated insulation
- the invention relates to the isolation of an adsorber comprising several parallel-passage contactors and to the use of this same adsorber.
- Adsorption is a physical phenomenon that is increasingly used industrially to separate or purify gas flows.
- adsorption is conventionally used to dry various gas streams, in particular air, natural gas, for the production of hydrogen, for the production of oxygen and / or nitrogen from air atmospheric, to capture many components of various effluents before their use in a downstream process or venting such as VOC, nitrogen oxides, mercury ...
- the present invention will particularly relate to TSA.
- the adsorbent used is generally in the form of particles filled with an adsorber. These particles can be in the form of granules, rods, balls, crushed. The characteristic dimensions of these particles generally range from 0.5 mm to 5 mm.
- Axial cylinders of conventional adsorbents in the form of balls use thermal insulation between the beds of balls and the ambient.
- thermal insulation between the beds of balls and the ambient.
- a small bottle typically with a diameter of less than 2 m, it is rather used an external insulation reported on the outer shell of the bottle, type insulation glass wool, or cellular glass or polyurethane foam: this insulation remains inefficient because during the heating phase in regeneration of the bottle, a portion of the thermal energy is used to heat the metal of the bottle, requiring the heat loss to be compensated by over-sizing the regeneration flow rate.
- an internal insulation On a large bottle, typically with a diameter greater than 2m, an internal insulation is used: it must mechanically be able to contain the beds of adsorbent beads, not to favor the creation of preferential gas passage (outside the adsorbent bed) and be able to withstand any compression / decompression cycles between adsorption and regeneration.
- a system of single or double gas blades which serves as an insulating cushion is conventionally used, considering that the air space remains stationary. These blades, relatively efficient in terms of insulation, are difficult to implement and cost relatively expensive.
- a solution of the invention is an adsorber for adsorption of a fluid, comprising a bottle with at least two parallel-passage contactors arranged in series in the direction of the path of the fluid to be adsorbed, and characterized in that each contactor comprises an insulation internal.
- internal insulation is meant an insulation which is specific to each contactor with parallel passages; in other words integrated in each contactor.
- Parallel passage contactor means a device in which the fluid passes through channels whose walls contain adsorbent.
- the fluid circulates in essentially obstacle free channels, these channels allowing the fluid to flow from an input to an output of the contactor.
- These channels can be rectilinear connecting directly the input to the output of the contactor or present changes of direction.
- the fluid is in contact with at least one adsorbent present at said walls.
- the parallel-channel contactors have less pressure losses, which allows loss of equivalent charges to reduce the diameter of the adsorber, possibly increasing its height.
- the contactors with parallel passages of the adsorber according to the invention may comprise one or the other of the following internal isolations.
- the internal insulation of each of the contactors comprises:
- Watertight means that prevents the creation of preferential gas passage outside the contactor with parallel passages.
- Figure 1 shows a contactor with parallel passages with the double environment.
- Figure 2 shows an adsorber according to the invention comprising a series of contactors with parallel passages with the double environment.
- the insulation is preferably chosen from perlite, glass wool, rockwool, cellular glass, vacuum, airgel, multilayer insulation or any other insulation or combination of insulators conventionally used. artwork...
- this first alternative can be supplemented by sealing elements fixed on the outer shell of the double environment facing the inner ferrule of the bottle.
- the sealing elements are preferably selected from brushes, seals, welds or welded elements, glue or glued elements and preferably sized to overcome the possible differential expansion between the shell of the adsorber and the double environment of the parallel passage contactors during regeneration of the adsorber.
- each parallel-channel contactor has channels and the channels are at least partly obstructed over a centripetal radial distance of 20 cm, preferably 10 cm, even more preferably 5 cm starting from the outer perimeter of the parallel-path contactor. .
- This obstruction prevents the creation of preferential gas passage in the channels concerned.
- the parallel passage contactors may optionally have a ferrule. Therefore, the term "outer perimeter" means the edge of the contactor with parallel passages or the edge of the ferrule of the contactor with parallel passages.
- the channels to be partially obstructed are filled, over at least part of their length, with resin, mastic, silicone or any element that can be applied in liquid or pasty form to permanently close the channels concerned; and or
- At least one of the ends of the channels to be partially obstructed is obstructed by a metal plate, or a plastic plate, or a silicone or rubberized seal, or any solid element that can be placed or fixed
- the obstruction may be made at the top, bottom or part of each channel concerned. It can be envisaged to block the entire length of each channel concerned.
- Figure 3 shows a parallel passage contactor with a metal plate at the upper ends of the channels to be clogged.
- Figure 4 shows an adsorber according to the invention comprising a series of parallel passage contactors with a metal plate at the upper ends of the channels to be clogged.
- the obstruction of the channels makes it possible to block the circulation of the fluid in these channels, and to create an insulation in the image of tiny blades of gas.
- the immobile gas cells being much smaller than the conventional gas blades, a much better thermal insulation is obtained.
- equivalent thermal insulation performance can greatly reduce the thickness of the insulation.
- this second alternative may be supplemented by sealing elements fixed on the outer face of the parallel passage contactors facing the inner ferrule of the bottle.
- the sealing elements are preferably chosen from brushes, seals, welds or welded elements, glue or glued elements and preferably dimensioned to overcome the possible differential expansion between the ferrule of the adsorber, and the outer perimeter of the parallel passage contactors during the regeneration of the adsorber.
- the adsorbents that may be used in the parallel-passage contactors are those used in the conventional gas stream separation or purification units. The choice depends on the application. It is possible in the same contactor to use successively several different adsorbents. Mention may be made of silica gels, optionally doped activated alumina, activated carbons, zeolites of various types (3A, 4A, 5A, type X, LSX, Y etc. optionally exchanged, etc.). The zeolites are generally used in the form of microcrystals or even nano-crystals according to the synthetic methods. Other adsorbents, for example activated carbons, can be crushed to obtain micron-sized particles.
- the contactors may be identical or on the contrary, it is possible to use this invention to singularize at least one contactor and adapt it to the operating conditions at this level of the adsorber. Regarding this modification, it may be another type of adsorbent, a change in the thickness of the adsorbent layer, the passage section, etc.
- the device according to the invention can be used in various processes such as TSA, PTSA ... It can also be used to dry, decarbonate or stop secondary impurities of a gas stream, in particular from atmospheric air.
- secondary impurities we mean the traces of hydrocarbons, NOx, SOx ...
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1153756A FR2974735B1 (en) | 2011-05-03 | 2011-05-03 | ADSORBER COMPRISING PARALLEL PASSAGE CONTACTORS WITH INTEGRATED INSULATION |
PCT/FR2012/050859 WO2012172219A1 (en) | 2011-05-03 | 2012-04-20 | Adsorber including parallel passage contactors having built-in insulation |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2704815A1 true EP2704815A1 (en) | 2014-03-12 |
Family
ID=46146938
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12722442.6A Withdrawn EP2704815A1 (en) | 2011-05-03 | 2012-04-20 | Adsorber including parallel passage contactors having built-in insulation |
Country Status (5)
Country | Link |
---|---|
US (1) | US9339754B2 (en) |
EP (1) | EP2704815A1 (en) |
CN (1) | CN103517750B (en) |
FR (1) | FR2974735B1 (en) |
WO (1) | WO2012172219A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1023302B1 (en) | 2015-07-23 | 2017-01-26 | Atlas Copco Airpower Naamloze Vennootschap | Process for the manufacture of an adsorbent for treating compressed gas, adsorbent obtained with such a process and adsorption device provided with such adsorbent |
JP6854808B2 (en) * | 2015-08-31 | 2021-04-07 | アトラス コプコ エアーパワー, ナームローゼ フェンノートシャップATLAS COPCO AIRPOWER, naamloze vennootschap | Adsorption device for compressed gas |
EP3736034A1 (en) * | 2019-05-08 | 2020-11-11 | Linde GmbH | Pressure vessel for with internal insulation |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010096916A1 (en) * | 2009-02-27 | 2010-09-02 | Andre Boulet | Parallel passage fluid contactor structure |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2038071A (en) * | 1932-11-09 | 1936-04-21 | Patent Finance Corp | Fluid treating device |
US2995208A (en) * | 1958-08-15 | 1961-08-08 | Phillips Petroleum Co | Adsorption process and apparatus |
US4386947A (en) * | 1980-04-25 | 1983-06-07 | Nippon Soken, Inc. | Apparatus for adsorbing fuel vapor |
JPS5954682A (en) * | 1982-09-20 | 1984-03-29 | 日本碍子株式会社 | Open end sealing method for ceramic honeycomb structure |
JPS60131620U (en) * | 1984-02-14 | 1985-09-03 | 本田技研工業株式会社 | catalytic converter |
DE8812817U1 (en) * | 1988-10-10 | 1988-12-29 | HWT Gesellschaft für Hydrid- und Wasserstofftechnik mbH, 4330 Mülheim | Device for cleaning gas |
US5260035A (en) * | 1992-08-05 | 1993-11-09 | Corning Incorporated | Apparatus and method for modifying gaseous mixtures |
EP0745416B1 (en) * | 1995-06-02 | 2003-09-17 | Corning Incorporated | Device for removal of contaminants from fluid streams |
FR2757427B1 (en) * | 1996-12-24 | 1999-02-05 | Air Liquide | THERMALLY INSULATED REACTOR |
DE19814132A1 (en) * | 1998-03-30 | 1999-10-14 | Emitec Emissionstechnologie | Honeycomb body with adsorber material, especially for a hydrocarbon trap |
DE60018794T2 (en) | 1999-12-09 | 2006-03-30 | Eminox Ltd., Gainsborough | DEVICE FOR TREATING GASSTROM |
EP1829596A1 (en) * | 2002-03-29 | 2007-09-05 | Ibiden Co., Ltd. | Ceramic filter and exhaust gas decontamination unit |
US7160361B2 (en) * | 2003-10-15 | 2007-01-09 | Delphi Technologies, Inc. | Evaporative emission treatment device |
JP2005270755A (en) | 2004-03-24 | 2005-10-06 | Ngk Insulators Ltd | Honeycomb structure and its production method |
US7722705B2 (en) * | 2006-05-11 | 2010-05-25 | Corning Incorporated | Activated carbon honeycomb catalyst beds and methods for the use thereof |
EA017307B1 (en) * | 2007-05-18 | 2012-11-30 | Эксонмобил Рисерч Энд Инджиниринг Компани | Temperature swing adsorption of cofrom flue gas using a parallel channel contactor |
US7806956B2 (en) * | 2007-08-09 | 2010-10-05 | Cummins Filtration Ip, Inc. | Tuning particulate filter performance through selective plugging and use of multiple particulate filters to reduce emissions and improve thermal robustness |
DE102008016236A1 (en) * | 2008-03-27 | 2009-10-01 | J. Eberspächer GmbH & Co. KG | Exhaust gas treatment device |
EP3144050B1 (en) * | 2008-04-30 | 2018-12-05 | Exxonmobil Upstream Research Company | Method for removal of oil from utility gas stream |
US20110296871A1 (en) * | 2009-01-15 | 2011-12-08 | Esther Lucia Johanna Van Soest-Vercammen | Method and apparatus for separating nitrogen from a mixed stream comprising nitrogen and methane |
WO2011030461A1 (en) * | 2009-09-14 | 2011-03-17 | イビデン株式会社 | Method for manufacturing honeycomb structure |
-
2011
- 2011-05-03 FR FR1153756A patent/FR2974735B1/en active Active
-
2012
- 2012-04-20 WO PCT/FR2012/050859 patent/WO2012172219A1/en active Application Filing
- 2012-04-20 EP EP12722442.6A patent/EP2704815A1/en not_active Withdrawn
- 2012-04-20 US US14/114,806 patent/US9339754B2/en not_active Expired - Fee Related
- 2012-04-20 CN CN201280021469.2A patent/CN103517750B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010096916A1 (en) * | 2009-02-27 | 2010-09-02 | Andre Boulet | Parallel passage fluid contactor structure |
Also Published As
Publication number | Publication date |
---|---|
CN103517750B (en) | 2016-12-14 |
WO2012172219A1 (en) | 2012-12-20 |
FR2974735B1 (en) | 2015-11-20 |
US20140083293A1 (en) | 2014-03-27 |
WO2012172219A8 (en) | 2013-01-24 |
US9339754B2 (en) | 2016-05-17 |
FR2974735A1 (en) | 2012-11-09 |
CN103517750A (en) | 2014-01-15 |
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