EP2657633A1 - Tubing module for air separation unit - Google Patents
Tubing module for air separation unit Download PDFInfo
- Publication number
- EP2657633A1 EP2657633A1 EP13001829.4A EP13001829A EP2657633A1 EP 2657633 A1 EP2657633 A1 EP 2657633A1 EP 13001829 A EP13001829 A EP 13001829A EP 2657633 A1 EP2657633 A1 EP 2657633A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- main heat
- fluid
- casing module
- air separation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000926 separation method Methods 0.000 title claims abstract description 82
- 239000012530 fluid Substances 0.000 claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 claims abstract description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 44
- 229910052757 nitrogen Inorganic materials 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 238000009826 distribution Methods 0.000 claims description 7
- 238000012546 transfer Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 abstract 1
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 238000007906 compression Methods 0.000 description 9
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- 239000000047 product Substances 0.000 description 9
- 229910052786 argon Inorganic materials 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 229910052756 noble gas Inorganic materials 0.000 description 5
- 150000002835 noble gases Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
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- 238000000746 purification Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
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- 229910052754 neon Inorganic materials 0.000 description 3
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 3
- 238000009417 prefabrication Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
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- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 229910052743 krypton Inorganic materials 0.000 description 2
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
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- 238000011144 upstream manufacturing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- VVTSZOCINPYFDP-UHFFFAOYSA-N [O].[Ar] Chemical compound [O].[Ar] VVTSZOCINPYFDP-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
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- 238000011010 flushing procedure Methods 0.000 description 1
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- 230000017525 heat dissipation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
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- 238000009834 vaporization Methods 0.000 description 1
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Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
- F25J3/0489—Modularity and arrangement of parts of the air fractionation unit, in particular of the cold box, e.g. pre-fabrication, assembling and erection, dimensions, horizontal layout "plot"
Definitions
- the invention relates to a casing module for at least one main heat exchanger of an air separation plant, an air separation plant with such a casing module and a method for producing an air separation plant.
- Atmospheric air is a gas mixture consisting essentially of nitrogen (78%), oxygen (21%) and argon (0.9%).
- the remaining 0.1% comprise mainly carbon dioxide and, as further components, the noble gases neon, helium, krypton and xenon.
- Air separation plants Facilities for rectificatory air separation (hereinafter referred to as "air separation plants") are known. They are used for the production of gaseous oxygen and nitrogen and possibly of liquid oxygen, liquid nitrogen and the said noble gases.
- the air separation includes as essential steps the compression, precooling, purification, cooling and rectification.
- the compression takes place, for example, in multi-stage turbocompressors with intermediate and after-cooling to a pressure of about 6 bar or more. Before compaction dust particles can be removed in so-called intensive filters.
- water-operated direct contact cooler for subsequent pre-cooling can be used with water-operated direct contact cooler, in which also a partial leaching of water-soluble impurities can be done.
- the water used can, for example, be recooled in trickle evaporation coolers against nitrogen residual gas from the rectification (also referred to below as "cooling nitrogen").
- the purification of the precooled air is usually carried out in molecular sieve adsorbers. In these, moisture, carbon dioxide and hydrocarbons are removed.
- the thus purified air is cooled in one or more main heat exchangers to about -175 ° C.
- the cooling takes place by internal heat exchange in countercurrent to cold gas streams generated in the system. Again, i.d.R. at least nitrogen residual gas from the rectification used.
- the air continues to cool by the Joule-Thomson effect and liquefies.
- the actual decomposition (rectification) of the air takes place in separation columns (rectification columns) of a separation column system, wherein first an oxygen-rich bottom fraction and a nitrogen-rich top fraction are produced.
- separation columns rectification columns
- different column configurations can be used for the separation column system.
- two separation columns in the form of so-called medium-pressure and low-pressure columns can be used as double columns.
- Noble gases such as argon and / or neon can be generated by downstream separation columns and process steps.
- the rectification can also include, for example, the liquefaction of pure nitrogen against evaporating oxygen and its return to the separation column system.
- Corresponding systems may also include other devices such as e.g. Complementary or final compressor, expansion turbines, high-pressure heat exchanger, internal compression pumps and / or liquid separator have.
- Air separation plants are thus made up of a so-called warm part, which contains the components for compression, precooling and purification, and a so-called cold part with the main heat exchanger (s) and possibly other heat exchangers, for example a supercooling countercurrent, and the separation column system.
- the components in the cold part can be arranged in one or more so-called cold boxes. These are clad steel frames filled with insulating material such as perlite to reduce heat input from the environment. Ideally, the inside of a coldbox is maintenance-free. Maintenance-requiring components can be isolated for this purpose from the insulating material and arranged accessible from the outside. Valves can be led to the outside, so that, for example, their drives are accessible. Ingress of moisture can be prevented by flushing with nitrogen.
- argon boxes in plants for argon production
- Gaseous oxygen and nitrogen produced in an air separation plant can be fed into a pipeline network and sent directly to the consumer.
- oxygen, nitrogen and argon in liquid form are temporarily stored in storage tanks and transported to tank trucks.
- Corresponding air separation plants should preferably be present at the place of use for the respective gases, e.g. in the vicinity of refineries or oil reservoirs, in order to keep the transport routes for the said fluids as short as possible.
- the present invention proposes a casing module for at least one main heat exchanger of an air separation plant, an air separation plant with such a casing module and a method for producing an air separation plant with the features of the independent claims.
- Preferred embodiments are the subject of the dependent claims and the following description.
- the invention proposes a casing module by means of which at least two fluid connections of at least one main heat exchanger designed for use in an air separation plant can be connected to at least two fluid lines in a warm part of the air separation plant.
- the casing module has at least two main compressor side ports connectable to the at least two fluid conduits in the warm part of the air separation plant and at least two main heat exchanger side ports coupleable to the at least two fluid ports of the at least one main heat exchanger and at least two of the at least two main compressor side ports and the at least two main heat exchanger side ports connecting fluid lines.
- the casing module proposed according to the invention makes it possible to replace the so-called header piping which is usually required for the main heat exchangers in air separation plants.
- the header piping is usually used to connect the main heat exchanger or to the explained warm part of the system and is arranged on top of the main heat exchanger or the.
- the main heat exchanger (s) of an air separation plant serve at least for cooling the feed air intended for decomposition in the separation columns of the air separation plant in countercurrent to at least one air product produced from the feed air.
- the main heat exchanger (s) are thus arranged for cooling air in indirect heat exchange with return streams from the separation column system and have correspondingly equipped means which comprise, for example, suitably designed lines.
- Air separation plants can also be designed for so-called internal compression, in which one or more separation columns are taken off a liquid stream, brought to liquid pressure and vaporized in the main heat exchanger (s) against a heat transfer medium, usually a compressed air stream, to a gaseous product. If a corresponding liquid stream is present at supercritical pressure, no evaporation takes place, but a pseudo-vaporization.
- the one for the Evaporation or pseudo-evaporation used heat transfer medium so for example a corresponding compressed air flow is compressed for thermodynamic reasons to a pressure which is usually well above a pressure which is used in the separation column system as the operating pressure. It is liquefied in the main heat exchanger or heat exchangers (or possibly pseudo-liquefied if supercritical pressure prevails). Main heat exchangers are thus also used to provide a corresponding gaseous print product.
- main heat exchangers are used in particular for reasons of space or constructive considerations, for example, when the required for an air separation plant main heat exchanger can not be arranged in a single cold box and / or a production and / or transport otherwise constitute an insurmountable effort.
- the main heat exchanger (s) of an air separation plant may each be formed from one or more main heat exchanger blocks or main heat exchanger sections connected in parallel and / or in series, for example from one or more plate heat exchanger blocks.
- main heat exchangers including several separate units understood, but in each case basically fulfill the same functions.
- all main heat exchangers are traversed by the same number of fluid conduits and cool or heat them to substantially the same temperatures. It is therefore a matter of several units that can be connected in parallel and thus fulfill the function of a larger main heat exchanger.
- main heat exchanger blocks these are to be understood as meaning a plurality of separate units which, however, fulfill different functions.
- these may be a plurality of mutually separate plate heat exchanger blocks, each of which can be flowed through by different fluids.
- the heat transfer medium to be liquefied (or pseudo-liquefied) and the internally compressed stream (or streams) to be vaporized (or pseudo-evaporated) in a separate plate heat exchanger block in the indirect Heat exchange are conducted against each other.
- separate plate heat exchanger blocks may be used, which must be designed for lower pressures.
- main heat exchanger blocks together fulfill the function of a main heat exchanger.
- a plurality of main heat exchangers may each have an identical set of main heat exchanger blocks.
- the individual main heat exchanger blocks can be arranged in different cold boxes.
- the main heat exchanger (s) are themselves part of the so-called cold part of an air separation plant explained in the introduction, but designed for connection to their warm part.
- the main heat exchanger (s) are fundamentally different from the heat exchangers or coolers (for example an aftercooler of one or more compressors) arranged in the warm part of the air separation plant in that at least one fluid cooled to cryogenic temperatures is supplied to and / or removed from them.
- a cryogenic temperature is for example below -50 ° C, in particular below -100 ° C before.
- the main heat exchanger (s) are therefore adapted to operate at correspondingly low temperatures, for example by having materials which are stable at or produced by the cryogenic temperatures. They are thus structurally, manufacturing and functional at least for cooling the intended for decomposition in the separation columns of the air separation plant feed air countercurrent to at least one air product produced from the feed set.
- the main heat exchanger Upstream of or the main heat exchanger, ie in the warm part of the system, however, usually only heat exchangers or coolers are used, which are fed or removed higher-temperature fluids. These usually have a temperature of at least 0 ° C.
- the compressed air in a main compressor is usually cooled by means of at least one cooler, such as a water cooler, to dissipate the heat of compression.
- the cooling takes place completely at temperatures above 0 ° C., ie not at cryogenic temperatures and / or not in countercurrent to at least one air product produced from the feed air.
- the main compressor is the compressor or the compressor arrangement, which is driven as a single machine with external energy and, for example, as a single-stage or multi-stage compressor whose stages are all connected to the same drive. All stages can be housed in a housing or connected to a gearbox. Reciprocators are often not among the driven by external energy machines because they are driven by each associated relaxation machines.
- the "warm part" of the air separation plant to whose connection to the main heat exchanger or the casing module according to the invention is used, comprises as a central component of this main heat exchanger, but can other facilities such as booster and / or Aufalisms Huaweien and / or product compressor (for the external compression of air products) include.
- the preparation of the header piping proves to be particularly complicated if, for an air separation plant, a plurality of main heat exchangers and / or a main heat exchanger are provided with a plurality of main heat exchanger blocks, as explained above.
- the pipelines on respective main heat exchangers and / or main heat exchanger blocks or their enclosing cold boxes must be merged at the site of the air separation plant, each to establish a connection to common fluid lines.
- a prefabrication of the header piping per se is difficult, since the tolerances are often too large in practice.
- a main heat exchanger and / or main heat exchanger block can hardly be created in the precision that allows a direct adaptation of one or more prefabricated header lines.
- the directly into the main heat exchanger and / or main heat exchanger blocks pipes, corresponding collector and the transfer lines for connecting other components, such as the upstream compression and cleaning devices as explained above, must therefore be made very expensive on the site.
- the invention proposes to move the said pipes from the roof of the main heat exchanger and / or main heat exchanger blocks or the corresponding cold boxes into the casing module in the form of a so-called piping skid.
- the casing module can be arranged vertically next to the main heat exchanger (s) and / or main heat exchanger blocks. At the Then only the connection connections between the main heat exchanger (s) and / or main heat exchanger blocks and the casing module have to be made in order to establish a connection with the respective fluid lines. This usually proves to be uncritical in comparison to the previously described individual production.
- the casing module provided according to the invention is characterized by the fact that it has predominantly, in particular exclusively, lines (fluid lines) designed for the forwarding of fluids.
- a casing module is formed with main compressor side connections for connection to a warm part of the air separation plant and with main heat exchanger side connections for connection to the cold part, more precisely to the main heat exchanger and / or main heat exchanger blocks or their connections.
- a casing module has, for example, n main compressor side connections and n x m main heat exchanger side connections, where m is the number of main heat exchangers respectively connectable to the casing module and, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10.
- the main compressor side ports and the main heat exchanger side ports are connected to each other via the fluid lines. If n> 1, in each case a plurality of main heat exchanger-side connections can be connected via a fluid distributor to a main compressor-side connection.
- a casing module optionally comprises shut-off means for shutting off individual fluid lines and / or adjusting means for adjusting a fluid flow, in particular for evenly distributing fluid of a main compressor side connection to main heat exchanger side connections, but not active pressure and / or temperature-influencing means, ie compressors, expansion valves or Relaxation machines, heaters, coolers, heat exchangers and the like.
- a casing module according to the invention is thus structurally designed such that one, in particular one, each leaves the fluid flow guided through the casing module at an outlet pressure and / or an outlet temperature which substantially corresponds to the inlet pressure or inlet temperature.
- a fluid flow which is fed to the casing module either via a main compressor side port and via a main heat exchanger side port (or m main heat exchanger side ports), or vice versa, has substantially the same pressure and temperature at discharge as at the feed.
- a "substantially” equal pressure and a “substantially” the same temperature may, for example, minor pressure increases or pressure losses and / or slight increases in temperature or temperature decreases, for example, less than 1 bar, 0.5 bar or 0.1 bar or less than 10 ° C, 5 ° C or 1 ° C and may, for example, by line losses and / or heat input from or heat dissipation into the environment may arise.
- the "main compressor side” connections are characterized by, they are set up for connection to a warm part of the air separation plant.
- the “main heat exchanger side” connections for connection to the main heat exchanger and / or main heat exchanger blocks or their connections are set up.
- the connections are arranged, in particular, by having a respectively suitable spatial arrangement and / or position.
- the casing module according to the invention is used in particular for header piping (or its partial replacement).
- the main heat exchanger-side connections are therefore preferably arranged above the casing module.
- the arrangement “above” or “below” is defined, for example, by a support structure which supports the casing module and has corresponding feet or structures on its underside.
- the piping module allows three-dimensionally adapting the connecting piping between the respective ports of the main heat exchanger (s) and / or main heat exchanger blocks and the piping module.
- the casing module in this case has connections of at least one of the main heat exchanger and / or main heat exchanger blocks corresponding and coupled with these connections on its upper side, namely the mentioned main heat exchanger side connections, on.
- a casing module according to the invention can be completely prefabricated, e.g. be painted, pressure tested, isolated, instrumented and wired. I.d.R. appropriate testing and monitoring facilities available that allow a safety inspection at the production site. In this way it can be avoided that, for example, damage or manufacturing defects are only discovered at the place of construction of the air separation plant, which necessitates expensive repairs or, in extreme cases, return transport.
- the casing module according to the invention structures the layout of a corresponding system and provides a clear concept. This allows a large-scale creation of standardized modules with correspondingly matching connections in the sense of an arbitrarily expandable modular principle.
- the main heat exchangers for plants of such size or corresponding main heat exchanger blocks can be produced in the required capacity only at a few specialized production sites. This is also due to the manufacturing technique for such devices. Particularly advantageous for the said systems are in particular vacuum-brazed aluminum plate heat exchangers. The production of such heat exchangers takes place in vacuum furnaces without the use of fluxes. This technique requires a high degree of Production quality, since the solder, which is used here for joining, deviates only slightly in its melting point from that of the materials to be joined.
- the casing module according to the invention significantly simplifies the piping of such main heat exchangers, so that the personnel employed need not be qualified to the extent that is conventionally required, or else highly qualified personnel only have to be employed for a shorter period of time.
- a casing module according to the invention is advantageously designed for connecting at least two main heat exchangers and / or main heat exchanger blocks. This allows a particularly flexible creation of air separation plants, which can be adapted to the respective existing performance requirements.
- the piping modules according to the invention equipped with at least one fluid distributor.
- a "fluid distributor” is understood to mean a tube arrangement which permits the connection of connections of a plurality of main heat exchangers and / or main heat exchanger blocks or a plurality of connections of a main heat exchanger to a common line.
- a fluid distributor helps to provide a plurality of sets of ports corresponding to the respective main heat exchangers to be connected, wherein, as explained, for example, n main compressor side ports and n ⁇ m main heat exchanger side ports are provided.
- a casing module can therefore be assembled, for example, at the production site from a basic module and a corresponding fluid distribution module.
- the basic module also makes sense to include components that are conventionally mounted in the field on the construction site. This allows a large-scale production and prefabrication of appropriate modules, which then only need to be mounted as needed. This allows efficient and timely creation of casing modules.
- a separate main heat exchanger side connection set is provided for each main heat exchanger and / or main heat exchanger block, which comprises at least one supply line for compressed, pre-cleaned and pre-cooled air and a discharge line for cooling nitrogen.
- the main heat exchangers or main heat exchanger blocks used in the illustrated air separation plants have a series of lines which conduct fluid flows in both directions through the main heat exchanger or main heat exchanger blocks.
- the lines end at the top of the main heat exchanger or main heat exchanger blocks in one or more connecting pieces.
- a main heat exchanger side connection set also include other discharge lines, for example, for oxygen, product nitrogen and / or noble gases. If an additional high-pressure heat exchanger is provided in the air separation plant (which is to be connected to a corresponding after-circulation or cycle compressor), corresponding lines can also be provided in a line set for this purpose.
- connection sets are advantageously arranged spatially so that the simplest possible and direct connection of the main heat exchanger is ensured.
- a similar spatial arrangement can be normalized such that a variety of different modules - in the sense of the above-mentioned modular principle - can be connected to each other without costly adjustments.
- the spatial arrangement allows three-dimensional adaptation of corresponding connection lines, at least to a certain extent, in order, e.g. Compensate tolerances of modules and foundations.
- connection pipes For the connection of the casing module with the main heat exchanger (s), it is therefore possible in turn to use prefabricated connection pipes, if appropriate with correspondingly standardized flanges. This reduces the required assembly steps. However, these are still at least to some extent customizable.
- a casing module according to the invention advantageously also comprises fire-protected oxygen transfer valves.
- Correspondingly required Brandabschottungs Vintageen can also be prefabricated together with the other components of the casing module and thus spent in prefabricated and possibly suitably tested form to the site of the air separation plant. The usual foreclosure with a concrete wall is eliminated.
- an illustrated casing module possibly with an integrated and / or modular previously explained Fluid distributor, formed for vertical arrangement next to the at least one main heat exchanger or a corresponding main heat exchanger block.
- this enables space-saving piping of one or more main heat exchangers and, on the other hand, simple prefabrication and unproblematic transport.
- Vertically locatable casing modules can be formed flat in a horizontal direction and therefore prefabricated lying. The required mounting space is therefore considerably reduced compared to conventional arrangements.
- the present invention also provided air separation plant benefits from the advantages explained above, to which therefore can be explicitly referenced.
- An inventive method for producing an air separation plant comprises a provision of at least one main heat exchanger and a casing module according to the invention and the connection of the at least one main heat exchanger to the casing module.
- said components are prefabricated. This also results in the mentioned advantages.
- FIG. 1 shows an air separation plant according to the prior art in a highly simplified, schematic representation. This is designated 100 in total.
- the present invention relates in particular to the connection of a main heat exchanger in such an air separation plant 100.
- the main heat exchanger is provided in the form of a main heat exchanger module 1.
- an air separation plant 100 typically comprises a plurality of adsorbers 3, which operated alternately and can be regenerated accordingly.
- the supplied, compressed and purified air is cooled countercurrently with cold, gaseous nitrogen GAN from the head of a separation column 5 explained below.
- the cooled to near liquefaction temperature air stream is subsequently expanded in an expansion valve 4 and fed in partially liquid form in a central region of the separation column 5.
- a corresponding system may additionally comprise a recompression of a (partial) air flow and a cooling in a high-pressure heat exchanger. Again, this is not shown for clarity.
- a separation column 5 instead of a single separation column 5, as in FIG. 1 represented, also several successive separation columns, double columns and the like can be used as a separation column system.
- the different boiling points of its components are used.
- the liquid air trickles over a Number of highly simplified sieve trays countercurrent to non-liquefied ascending air downwards.
- the liquid is thereby stowed on the ground and flows through ascending vapor bubbles.
- the higher-boiling oxygen liquefies from the gas stream, while the lower-boiling nitrogen preferably evaporates from the liquid drops.
- gaseous nitrogen GAN collects at the cold head of the separation column 5 and liquid oxygen LOX at the warmer bottom.
- the liquid oxygen LOX is vaporized from the bottom of the separation column 5 in an evaporator 6, the gaseous nitrogen is liquefied in a so-called top condenser 7.
- the vaporized gaseous oxygen GOX and the liquified nitrogen LIN are returned to the separation column 5, where the rectification is repeated until the desired purity is achieved.
- the separation column 5 can also be taken, for example, an oxygen-argon mixture O / Ar, from which in a separate process in a further column high-purity argon can be obtained. Separate columns are also needed for the extraction of the noble gases xenon, krypton, helium and / or neon.
- FIG. 2 shows a casing module with two main heat exchangers 1 a and 1 b according to an embodiment of the invention in a schematic representation.
- the casing module is indicated generally at 10, a main heat exchanger module containing the two main heat exchangers 1a and 1b is designated 1.
- a main heat exchanger module containing the two main heat exchangers 1a and 1b is designated 1.
- the main heat exchanger module 1 can be designed, for example, in the form of a cold box, as explained above.
- the casing module 10 may be constructed from a base module 11 and a fluid distribution module 12, which are interconnected via a suitable connection 13.
- central components such as corresponding valves 14 may be arranged.
- FIG. 2 Here, only one line is shown in the basic module 11, which is divided into two lines in the fluid distribution module 12.
- a main heat exchanger module 1 or the main heat exchangers 1 a and 1 b arranged therein are in practice flowed through by a plurality of different fluid streams in countercurrent to one another, so that the said lines are also present in a plurality.
- a set of connections in the fluid distribution module 12 is provided for each main heat exchanger 1 a or 1 b to be connected.
- the piping module 10 may further comprise - in the main module 11 and / or the fluid distribution module 12 - at least one pressure, temperature and / or Druchmannregler 15. Not shown are, for example, fire-protected oxygen valves.
- the fluid distribution module 12 has a set of connections 12a and 12b, respectively, for the main heat exchangers 1 a and 1 b to be connected. These can be very easily connected with corresponding terminals 12a 'and 12b' to be connected to the main heat exchanger 1 a and 1 b.
Abstract
Description
Die Erfindung betrifft ein Verrohrungsmodul für wenigstens einen Hauptwärmetauscher einer Luftzerlegungsanlage, eine Luftzerlegungsanlage mit einem derartigen Verrohrungsmodul sowie ein Verfahren zur Erstellung einer Luftzerlegungsanlage.The invention relates to a casing module for at least one main heat exchanger of an air separation plant, an air separation plant with such a casing module and a method for producing an air separation plant.
Bei atmosphärischer Luft handelt es sich um ein Gasgemisch, das sich im Wesentlichen aus Stickstoff (78%), Sauerstoff (21 %) und Argon (0,9%) zusammensetzt. Die verbleibenden 0, 1 % umfassen hauptsächlich Kohlendioxid sowie als weitere Komponenten die Edelgase Neon, Helium, Krypton und Xenon.Atmospheric air is a gas mixture consisting essentially of nitrogen (78%), oxygen (21%) and argon (0.9%). The remaining 0.1% comprise mainly carbon dioxide and, as further components, the noble gases neon, helium, krypton and xenon.
Anlagen zur rektifikatorischen Luftzerlegung (nachfolgend kurz "Luftzerlegungsanlagen") sind bekannt. Sie werden zur Herstellung von gasförmigem Sauerstoff und Stickstoff sowie ggf. von Flüssigsauerstoff, Flüssigstickstoff und der genannten Edelgase eingesetzt. Die Luftzerlegung umfasst als wesentliche Schritte die Verdichtung, Vorkühlung, Aufreinigung, Abkühlung und Rektifikation.Facilities for rectificatory air separation (hereinafter referred to as "air separation plants") are known. They are used for the production of gaseous oxygen and nitrogen and possibly of liquid oxygen, liquid nitrogen and the said noble gases. The air separation includes as essential steps the compression, precooling, purification, cooling and rectification.
Die Verdichtung erfolgt beispielsweise in mehrstufigen Turbokompressoren mit Zwischen- und Nachkühlung auf einen Druck von ca. 6 bar oder mehr. Vor der Verdichtung können Staubpartikel in sogenannten Intensivfiltern entfernt werden.The compression takes place, for example, in multi-stage turbocompressors with intermediate and after-cooling to a pressure of about 6 bar or more. Before compaction dust particles can be removed in so-called intensive filters.
Zur anschließenden Vorkühlung können mit Wasser betriebene Direktkontaktkühler eingesetzt werden, in denen zudem eine teilweise Auswaschung wasserlöslicher Verunreinigungen erfolgen kann. Das verwendete Wasser kann beispielsweise in Rieselverdunstungskühlern gegen Stickstoffrestgas aus der Rektifikation (nachfolgend auch als "Kühlstickstoff" bezeichnet) rückgekühlt werden.For subsequent pre-cooling can be used with water-operated direct contact cooler, in which also a partial leaching of water-soluble impurities can be done. The water used can, for example, be recooled in trickle evaporation coolers against nitrogen residual gas from the rectification (also referred to below as "cooling nitrogen").
Die Aufreinigung der vorgekühlten Luft erfolgt i.d.R. in Molekularsiebadsorbern. In diesen werden Feuchtigkeit, Kohlendioxid und Kohlenwasserstoffe entfernt.The purification of the precooled air is usually carried out in molecular sieve adsorbers. In these, moisture, carbon dioxide and hydrocarbons are removed.
Zur Verflüssigung wird die derart aufgereinigte Luft in einem oder mehreren Hauptwärmetauschern auf ca. -175 °C abgekühlt. Die Abkühlung erfolgt durch internen Wärmeaustausch im Gegenstrom zu in der Anlage erzeugten kalten Gasströmen. Auch hier wird i.d.R. zumindest Stickstoffrestgas aus der Rektifikation verwendet. Bei einer anschließenden Expansion kühlt sich die Luft durch den Joule-Thomson-Effekt weiter ab und verflüssigt sich.For liquefaction, the thus purified air is cooled in one or more main heat exchangers to about -175 ° C. The cooling takes place by internal heat exchange in countercurrent to cold gas streams generated in the system. Again, i.d.R. at least nitrogen residual gas from the rectification used. In a subsequent expansion, the air continues to cool by the Joule-Thomson effect and liquefies.
Die eigentliche Zerlegung (Rektifikation) der Luft erfolgt in Trennsäulen (Rektifikationskolonnen) eines Trennsäulensystems, wobei zunächst eine sauerstoffreiche Sumpffraktion und eine stickstoffreiche Kopffraktion erzeugt werden. Je nach der erforderlichen Reinheit der Endprodukte und/oder den zu erzeugenden Gasen können für das Trennsäulensystem unterschiedliche Säulenkonfigurationen verwendet werden. Beispielsweise können zwei Trennsäulen in Form sogenannter Mitteldruck- und Niederdrucksäulen als Doppelsäulen zum Einsatz kommen. Edelgase wie Argon und/oder Neon können durch nachgeschaltete Trennsäulen und Verfahrensschritte erzeugt werden. Die Rektifikation kann auch beispielsweise die Verflüssigung von Reinstickstoff gegen verdampfenden Sauerstoff und dessen Rückführung in das Trennsäulensystem umfassen. Entsprechende Anlagen können auch weitere Vorrichtungen wie z.B. Zusatz- bzw. Nachverdichter, Expansionsturbinen, Hochdruckwärmetauscher, Innenverdichtungspumpen und/oder Flüssigkeitsabscheider aufweisen.The actual decomposition (rectification) of the air takes place in separation columns (rectification columns) of a separation column system, wherein first an oxygen-rich bottom fraction and a nitrogen-rich top fraction are produced. Depending on the required purity of the end products and / or the gases to be generated, different column configurations can be used for the separation column system. For example, two separation columns in the form of so-called medium-pressure and low-pressure columns can be used as double columns. Noble gases such as argon and / or neon can be generated by downstream separation columns and process steps. The rectification can also include, for example, the liquefaction of pure nitrogen against evaporating oxygen and its return to the separation column system. Corresponding systems may also include other devices such as e.g. Complementary or final compressor, expansion turbines, high-pressure heat exchanger, internal compression pumps and / or liquid separator have.
Luftzerlegungsanlagen setzen sich damit aus einem sogenannten warmen Teil, der die Komponenten für die Verdichtung, die Vorkühlung und die Aufreinigung enthält, sowie einem sogenannten kalten Teil mit dem oder den Hauptwärmetauschern und ggf. weiteren Wärmetauschern, beispielsweise einem Unterkühlungsgegenströmer, und dem Trennsäulensystem zusammen. Die Komponenten im kalten Teil können in einer oder in mehreren sogenannten Coldboxen angeordnet sein. Hierbei handelt es sich um verkleidete Stahlrahmen, die mit Isoliermaterial wie Perlit gefüllt sind, um einen Wärmeeintrag aus der Umgebung zu reduzieren. Idealerweise ist das Innere einer Coldbox wartungsfrei. Wartungsbedürftige Komponenten können zu diesem Zweck vom Isoliermaterial abgeschottet und von außen zugänglich angeordnet werden. Ventile können nach außen geführt werden, damit beispielsweise deren Antriebe zugänglich sind. Ein Eindringen von Feuchtigkeit kann durch eine Spülung mit Stickstoff verhindert werden.Air separation plants are thus made up of a so-called warm part, which contains the components for compression, precooling and purification, and a so-called cold part with the main heat exchanger (s) and possibly other heat exchangers, for example a supercooling countercurrent, and the separation column system. The components in the cold part can be arranged in one or more so-called cold boxes. These are clad steel frames filled with insulating material such as perlite to reduce heat input from the environment. Ideally, the inside of a coldbox is maintenance-free. Maintenance-requiring components can be isolated for this purpose from the insulating material and arranged accessible from the outside. Valves can be led to the outside, so that, for example, their drives are accessible. Ingress of moisture can be prevented by flushing with nitrogen.
Je nach Größe der Anlage können mehrere Komponenten in einer gemeinsamen Coldbox integriert sein. Bei kleineren Anlagen werden dabei beispielsweise der oder die Hauptwärmetauscher und das Trennsäulensystem in einer Coldbox zusammengefasst, in größeren Anlagen werden diese auf mehrere Coldboxen verteilt. Große Anlagen können auch mehrere Hauptwärmetauscher, die in separaten Coldboxen untergebracht sind, umfassen. Auch weitere Coldboxen, beispielsweise mehrere Säulenboxen und/oder sogenannte Argonboxen (in Anlagen zur Argongewinnung) können vorgesehen sein.Depending on the size of the system, several components can be integrated in a common coldbox. In smaller systems, for example, the main heat exchanger or the separation column system are combined in a cold box, in larger systems these are distributed over several cold boxes. Large systems may also include several main heat exchangers housed in separate cold boxes. Other cold boxes, for example, several column boxes and / or so-called argon boxes (in plants for argon production) can be provided.
In einer Luftzerlegungsanlage gewonnener gasförmiger Sauerstoff und Stickstoff kann in ein Rohrleitungsnetz eingespeist und direkt zum Verbraucher geleitet werden. Sauerstoff, Stickstoff und Argon in flüssiger Form werden beispielsweise in Speichertanks zwischengelagert und in Tankwagen zum Einsatzort transportiert.Gaseous oxygen and nitrogen produced in an air separation plant can be fed into a pipeline network and sent directly to the consumer. For example, oxygen, nitrogen and argon in liquid form are temporarily stored in storage tanks and transported to tank trucks.
Entsprechende Luftzerlegungsanlagen sollten vorzugsweise am Verwendungsort für die jeweiligen Gase vorhanden sein, also z.B. in der Nähe von Raffinerien oder Erdöllagerstätten, um die Transportwege für die genannten Fluide möglichst kurz zu halten.Corresponding air separation plants should preferably be present at the place of use for the respective gases, e.g. in the vicinity of refineries or oil reservoirs, in order to keep the transport routes for the said fluids as short as possible.
Die Montage von Luftzerlegungsanlagen erfolgt dabei i.d.R. aus vorgefertigten Bauteilen. Dies ist jedoch häufig problematisch, da ausreichend qualifiziertes Personal zur Montage entweder nicht verfügbar oder teuer ist. Insbesondere betrifft dies die Anbindung der Hauptwärmetauscher. Daher besteht der Bedarf nach Verbesserungen, die eine zuverlässigere und einfachere Erstellung von Luftzerlegungsanlagen ermöglichen.The installation of air separation plants takes place i.d.R. from prefabricated components. However, this is often problematic because sufficient qualified personnel for assembly is either unavailable or expensive. In particular, this relates to the connection of the main heat exchanger. Therefore, there is a need for improvements that allow more reliable and easier construction of air separation plants.
Vor diesem Hintergrund schlägt die vorliegende Erfindung ein Verrohrungsmodul für wenigstens einen Hauptwärmetauscher einer Luftzerlegungsanlage, eine Luftzerlegungsanlage mit einem derartigen Verrohrungsmodul sowie ein Verfahren zur Erstellung einer Luftzerlegungsanlage mit den Merkmalen der unabhängigen Patentansprüche vor. Bevorzugte Ausgestaltungen sind jeweils Gegenstand der Unteransprüche sowie der nachfolgenden Beschreibung.Against this background, the present invention proposes a casing module for at least one main heat exchanger of an air separation plant, an air separation plant with such a casing module and a method for producing an air separation plant with the features of the independent claims. Preferred embodiments are the subject of the dependent claims and the following description.
Die Erfindung schlägt ein Verrohrungsmodul vor, mittels dessen wenigstens zwei Fluidanschlüsse wenigstens eines zur Verwendung in einer Luftzerlegungsanlage ausgebildeten Hauptwärmetauschers an wenigstens zwei Fluidleitungen in einem warmen Teil der Luftzerlegungsanlage anbindbar sind. Das Verrohrungsmodul weist wenigstens zwei hauptverdichterseitige Anschlüsse, die mit den wenigstens zwei Fluidleitungen in dem warmen Teil der Luftzerlegungsanlage koppelbar sind, und wenigstens zwei hauptwärmetauscherseitige Anschlüsse, die mit den wenigstens zwei Fluidanschlüssen des wenigstens einen Hauptwärmetauschers koppelbar sind, und wenigstens zwei die wenigstens zwei hauptverdichterseitigen Anschlüsse und die wenigstens zwei hauptwärmetauscherseitigen Anschlüsse verbindende Fluidleitungen auf.The invention proposes a casing module by means of which at least two fluid connections of at least one main heat exchanger designed for use in an air separation plant can be connected to at least two fluid lines in a warm part of the air separation plant. The casing module has at least two main compressor side ports connectable to the at least two fluid conduits in the warm part of the air separation plant and at least two main heat exchanger side ports coupleable to the at least two fluid ports of the at least one main heat exchanger and at least two of the at least two main compressor side ports and the at least two main heat exchanger side ports connecting fluid lines.
Das erfindungsgemäß vorgeschlagene Verrohrungsmodul ermöglicht den Ersatz der üblicherweise für die Hauptwärmetauscher in Luftzerlegungsanlagen erforderlichen sogenannten Headerverrohrung. Die Headerverrohrung dient üblicherweise zur Anbindung des oder der Hauptwärmetauscher an den erläuterten warmen Teil der Anlage und ist auf der Oberseite des oder der Hauptwärmetauscher angeordnet.The casing module proposed according to the invention makes it possible to replace the so-called header piping which is usually required for the main heat exchangers in air separation plants. The header piping is usually used to connect the main heat exchanger or to the explained warm part of the system and is arranged on top of the main heat exchanger or the.
Der oder die Hauptwärmetauscher einer Luftzerlegungsanlage dienen zumindest zur Abkühlung der zur Zerlegung in den Trennsäulen der Luftzerlegungsanlage vorgesehenen Einsatzluft im Gegenstrom zu zumindest einem aus der Einsatzluft hergestellten Luftprodukt. Der oder die Hauptwärmetauscher sind also zur Abkühlung von Luft im indirekten Wärmetausch mit Rückströmen aus dem Trennsäulensystem eingerichtet und verfügen über entsprechend eingerichtete Mittel, die beispielsweise geeignet ausgebildete Leitungen umfassen.The main heat exchanger (s) of an air separation plant serve at least for cooling the feed air intended for decomposition in the separation columns of the air separation plant in countercurrent to at least one air product produced from the feed air. The main heat exchanger (s) are thus arranged for cooling air in indirect heat exchange with return streams from the separation column system and have correspondingly equipped means which comprise, for example, suitably designed lines.
Luftzerlegungsanlagen können auch zur sogenannten Innenverdichtung eingerichtet sein, bei der einer oder mehreren Trennsäulen ein flüssiger Strom entnommen, flüssig auf Druck gebracht, und in dem oder den Hauptwärmetauschern gegen einen Wärmeträger, i.d.R. einen verdichteten Luftstrom, zu einem gasförmigen Druckprodukt verdampft wird. Liegt ein entsprechender flüssiger Strom bei überkritischem Druck vor, erfolgt keine Verdampfung sondern eine Pseudoverdampfung. Der für die Verdampfung bzw. Pseudoverdampfung verwendete Wärmeträger, also beispielsweise ein entsprechender verdichteter Luftstrom, wird aus thermodynamischen Gründen auf einen Druck verdichtet, der i.d.R. deutlich oberhalb eines Drucks liegt, der in dem Trennsäulensystem als Betriebsdruck verwendet wird. Er wird in dem oder den Hauptwärmetauschern verflüssigt (oder ggf. pseudoverflüssigt, falls ein überkritischer Druck herrscht). Hauptwärmetauscher werden also auch zur Bereitstellung eines entsprechenden gasförmigen Druckprodukts verwendet.Air separation plants can also be designed for so-called internal compression, in which one or more separation columns are taken off a liquid stream, brought to liquid pressure and vaporized in the main heat exchanger (s) against a heat transfer medium, usually a compressed air stream, to a gaseous product. If a corresponding liquid stream is present at supercritical pressure, no evaporation takes place, but a pseudo-vaporization. The one for the Evaporation or pseudo-evaporation used heat transfer medium, so for example a corresponding compressed air flow is compressed for thermodynamic reasons to a pressure which is usually well above a pressure which is used in the separation column system as the operating pressure. It is liquefied in the main heat exchanger or heat exchangers (or possibly pseudo-liquefied if supercritical pressure prevails). Main heat exchangers are thus also used to provide a corresponding gaseous print product.
Mehrere Hauptwärmetauscher werden insbesondere aus Platzgründen oder aufgrund konstruktiver Erwägungen verwendet, beispielsweise dann, wenn der für eine Luftzerlegungsanlage erforderliche Hauptwärmetauscher nicht in einer einzelnen Coldbox angeordnet werden kann und/oder eine Fertigung und/oder ein Transport anderenfalls einen unüberwindlichen Aufwand darstellen.Several main heat exchangers are used in particular for reasons of space or constructive considerations, for example, when the required for an air separation plant main heat exchanger can not be arranged in a single cold box and / or a production and / or transport otherwise constitute an insurmountable effort.
Der oder die Hauptwärmetauscher einer Luftzerlegungsanlage können jeweils aus einem oder mehreren parallel und/oder seriell verbundenen Hauptwärmetauscherblöcken bzw. Hauptwärmetauscherabschnitten gebildet sein, beispielsweise aus einem oder mehreren Plattenwärmetauscherblöcken.The main heat exchanger (s) of an air separation plant may each be formed from one or more main heat exchanger blocks or main heat exchanger sections connected in parallel and / or in series, for example from one or more plate heat exchanger blocks.
Ist nachfolgend davon die Rede, dass mehrere Hauptwärmetauscher vorgesehen sind, seien darunter mehrere getrennte Einheiten verstanden, die jedoch jeweils grundsätzlich dieselben Funktionen erfüllen. Alle Hauptwärmetauscher werden beispielsweise von derselben Anzahl an Fluidleitungen durchzogen und kühlen bzw. erwärmen diese im Wesentlichen auf dieselben Temperaturen. Es handelt sich also um mehrere Einheiten, die parallel geschaltet werden können und dadurch die Funktion eines größeren Hauptwärmetauschers erfüllen können.If the following is the speech that several main heat exchangers are provided, including several separate units understood, but in each case basically fulfill the same functions. For example, all main heat exchangers are traversed by the same number of fluid conduits and cool or heat them to substantially the same temperatures. It is therefore a matter of several units that can be connected in parallel and thus fulfill the function of a larger main heat exchanger.
Ist nachfolgend hingegen von mehreren Hauptwärmetauscherblöcken die Rede, seien hierunter mehrere getrennte Einheiten verstanden, die jedoch unterschiedliche Funktionen erfüllen. Beispielsweise kann es sich hierbei um mehrere voneinander getrennte Plattenwärmetauscherblöcke handeln, die jeweils von unterschiedlichen Fluiden durchströmt werden können. Beispielsweise können für die erläuterte Innenverdichtung der zu verflüssigende (bzw. pseudozuverflüssigende) Wärmeträger und der zu verdampfende (bzw. pseudozuverdampfende) innenverdichtete Strom (oder mehrere Ströme) in einem separaten Plattenwärmetauscherblock im indirekten Wärmetausch gegeneinander geführt werden. Für die verbleibenden abzukühlenden und zu erwärmenden Ströme können separate Plattenwärmetauscherblöcke verwendet werden, die für geringere Drücke ausgelegt werden müssen. Mehrere Hauptwärmetauscherblöcke zusammen erfüllen die Funktion eines Hauptwärmetauschers. Mehrere Hauptwärmetauscher können jeweils einen identischen Satz an Hauptwärmetauscherblöcken aufweisen. Auch die einzelnen Hauptwärmetauscherblöcke können in unterschiedlichen Coldboxen angeordnet sein.If, in the following, however, reference is made to a plurality of main heat exchanger blocks, these are to be understood as meaning a plurality of separate units which, however, fulfill different functions. For example, these may be a plurality of mutually separate plate heat exchanger blocks, each of which can be flowed through by different fluids. For example, for the illustrated internal compression, the heat transfer medium to be liquefied (or pseudo-liquefied) and the internally compressed stream (or streams) to be vaporized (or pseudo-evaporated) in a separate plate heat exchanger block in the indirect Heat exchange are conducted against each other. For the remaining streams to be cooled and heated, separate plate heat exchanger blocks may be used, which must be designed for lower pressures. Several main heat exchanger blocks together fulfill the function of a main heat exchanger. A plurality of main heat exchangers may each have an identical set of main heat exchanger blocks. The individual main heat exchanger blocks can be arranged in different cold boxes.
Der oder die Hauptwärmetauscher sind (ggf. mit ihren separaten Hauptwärmetauscherblöcken) selbst Teil des eingangs erläuterten sogenannten kalten Teils einer Luftzerlegungsanlage, jedoch zur Anbindung an ihren warmen Teil ausgebildet. Der oder die Hauptwärmetauscher unterscheiden sich jedenfalls dadurch von den im warmen Teil der Luftzerlegungsanlage angeordneten Wärmetauschern bzw. Kühlern (z.B. einem Nachkühler eines oder mehrerer Verdichter) grundlegend dadurch, dass ihnen wenigstens ein auf kryogene Temperaturen abgekühltes Fluid zugeführt und/oder entnommen wird. Eine kryogene Temperatur liegt beispielsweise unterhalb von -50 °C, insbesondere unterhalb von -100 °C vor. Der oder die Hauptwärmetauscher sind daher zum Betrieb bei entsprechenden niedrigen Temperaturen eingerichtet, indem sie beispielsweise Materialien aufweisen, die bei den kryogenen Temperaturen beständig sind, bzw. aus diesen hergestellt sind. Sie sind damit baulich, fertigungstechnisch und funktionell zumindest zur Abkühlung der zur Zerlegung in den Trennsäulen der Luftzerlegungsanlage vorgesehenen Einsatzluft im Gegenstrom zu zumindest einem aus der Einsatzluft hergestellten Luftprodukt eingerichtet.The main heat exchanger (s) (possibly with their separate main heat exchanger blocks) are themselves part of the so-called cold part of an air separation plant explained in the introduction, but designed for connection to their warm part. In any case, the main heat exchanger (s) are fundamentally different from the heat exchangers or coolers (for example an aftercooler of one or more compressors) arranged in the warm part of the air separation plant in that at least one fluid cooled to cryogenic temperatures is supplied to and / or removed from them. A cryogenic temperature is for example below -50 ° C, in particular below -100 ° C before. The main heat exchanger (s) are therefore adapted to operate at correspondingly low temperatures, for example by having materials which are stable at or produced by the cryogenic temperatures. They are thus structurally, manufacturing and functional at least for cooling the intended for decomposition in the separation columns of the air separation plant feed air countercurrent to at least one air product produced from the feed set.
Stromauf des oder der Hauptwärmetauscher, d.h. im warmen Teil der Anlage, werden hingegen i.d.R. ausschließlich Wärmetauscher bzw. Kühler verwendet, denen höher temperierte Fluide zugeführt bzw. entnommen werden. Diese weisen i.d.R. eine Temperatur von wenigstens 0 °C auf. So wird die in einem Hauptverdichter verdichtete Luft üblicherweise mittels wenigstens eines Kühlers, beispielsweise eines Wasserkühlers, abgekühlt, um die Kompressionswärme abzuführen. Die Abkühlung erfolgt jedoch hierbei vollständig bei Temperaturen oberhalb von 0° C, also nicht bei kryogenen Temperaturen und/oder nicht im Gegenstrom zu zumindest einem aus der Einsatzluft hergestellten Luftprodukt.Upstream of or the main heat exchanger, ie in the warm part of the system, however, usually only heat exchangers or coolers are used, which are fed or removed higher-temperature fluids. These usually have a temperature of at least 0 ° C. Thus, the compressed air in a main compressor is usually cooled by means of at least one cooler, such as a water cooler, to dissipate the heat of compression. However, the cooling takes place completely at temperatures above 0 ° C., ie not at cryogenic temperatures and / or not in countercurrent to at least one air product produced from the feed air.
Als Hauptverdichter wird im Rahmen der vorliegenden Anmeldung der Verdichter oder die Verdichteranordnung bezeichnet, die als einzige Maschine mit externer Energie angetrieben wird und beispielsweise als ein einstufiger oder mehrstufiger Verdichter, dessen Stufen alle mit dem gleichen Antrieb verbunden sind ausgebildet ist. Alle Stufen können in einem Gehäuse untergebracht oder mit einem Getriebe verbunden sein. Nachverdichter zählen häufig nicht zu den mit externer Energie angetriebenen Maschinen da sie durch ihnen jeweils zugeordnete Entspannungsmaschinen angetrieben werden. Der "warme Teil" der Luftzerlegungsanlage, zu dessen Anbindung an den oder die Hauptwärmetauscher das erfindungsgemäße Verrohrungsmodul eingesetzt wird, umfasst als zentrale Komponente diesen Hauptwärmetauscher, kann jedoch weitere Einrichtungen wie Nachverdichter und/oder Aufreinigungseinrichtungen und/oder Produktverdichter (zur externen Verdichtung von Luftprodukten) umfassen.In the context of the present application, the main compressor is the compressor or the compressor arrangement, which is driven as a single machine with external energy and, for example, as a single-stage or multi-stage compressor whose stages are all connected to the same drive. All stages can be housed in a housing or connected to a gearbox. Reciprocators are often not among the driven by external energy machines because they are driven by each associated relaxation machines. The "warm part" of the air separation plant to whose connection to the main heat exchanger or the casing module according to the invention is used, comprises as a central component of this main heat exchanger, but can other facilities such as booster and / or Aufreinigungseinrichtungen and / or product compressor (for the external compression of air products) include.
Die Erstellung der Headerverrohrung erweist sich insbesondere dann als aufwendig, wenn für eine Luftzerlegungsanlage mehrere Hauptwärmetauscher und/oder ein Hauptwärmetauscher mit mehreren Hauptwärmetauscherblöcken vorgesehen sind, wie oben erläutert. In diesem Fall müssen die Rohrleitungen auf entsprechenden Hauptwärmetauschern und/oder Hauptwärmetauscherblöcken bzw. der sie einschließenden Coldboxen am Erstellungsort der Luftzerlegungsanlage zusammengeführt werden, um jeweils eine Anbindung an gemeinsame Fluidleitungen herzustellen. Eine Vorfertigung der Headerverrohrung an sich ist nur schwer möglich, da die Toleranzen in der Praxis häufig zu groß sind. Mit anderen Worten kann beispielsweise ein Hauptwärmetauscher und/oder Hauptwärmetauscherblock kaum in der Präzision erstellt werden, die eine direkte Anpassung einer oder mehrerer vorgefertigter Headerleitungen erlaubt. Die direkt in die Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke mündenden Rohrleitungen, entsprechende Sammler sowie die Übergabeleitungen zur Anbindung weiterer Komponenten, beispielsweise der vorgeschalteten Komprimierungs- und Reinigungseinrichtungen wie oben erläutert, müssen daher sehr aufwendig auf der Baustelle gefertigt werden.The preparation of the header piping proves to be particularly complicated if, for an air separation plant, a plurality of main heat exchangers and / or a main heat exchanger are provided with a plurality of main heat exchanger blocks, as explained above. In this case, the pipelines on respective main heat exchangers and / or main heat exchanger blocks or their enclosing cold boxes must be merged at the site of the air separation plant, each to establish a connection to common fluid lines. A prefabrication of the header piping per se is difficult, since the tolerances are often too large in practice. In other words, for example, a main heat exchanger and / or main heat exchanger block can hardly be created in the precision that allows a direct adaptation of one or more prefabricated header lines. The directly into the main heat exchanger and / or main heat exchanger blocks pipes, corresponding collector and the transfer lines for connecting other components, such as the upstream compression and cleaning devices as explained above, must therefore be made very expensive on the site.
Im Gegensatz dazu schlägt die Erfindung vor, die genannten Rohrleitungen vom Dach des oder der Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke bzw. der entsprechenden Coldboxen in das Verrohrungsmodul in Form eines sogenannten Piping Skids zu verlegen. Das Verrohrungsmodul kann senkrecht neben dem oder den Hauptwärmetauschern und/oder Hauptwärmetauscherblöcken angeordnet werden. Am Erstellungsort der Luftzerlegungsanlage müssen dann nur noch Anschlussverbindungen zwischen dem oder den Hauptwärmetauschern und/oder Hauptwärmetauscherblöcken und dem Verrohrungsmodul gefertigt werden, um eine Verbindung mit den jeweiligen Fluidleitungen herzustellen. Dies erweist sich i.d.R. als unkritisch im Vergleich zu der zuvor erläuterten Individualfertigung.In contrast, the invention proposes to move the said pipes from the roof of the main heat exchanger and / or main heat exchanger blocks or the corresponding cold boxes into the casing module in the form of a so-called piping skid. The casing module can be arranged vertically next to the main heat exchanger (s) and / or main heat exchanger blocks. At the Then only the connection connections between the main heat exchanger (s) and / or main heat exchanger blocks and the casing module have to be made in order to establish a connection with the respective fluid lines. This usually proves to be uncritical in comparison to the previously described individual production.
Das erfindungsgemäß vorgesehene Verrohrungsmodul zeichnet sich dadurch aus, dass es vornehmlich, insbesondere ausschließlich, zur Weiterleitung von Fluiden ausgebildete Leitungen (Fluidleitungen) aufweist. Ein Verrohrungsmodul ist mit hauptverdichterseitigen Anschlüssen zur Anbindung an einen warmen Teil der Luftzerlegungsanlage und mit hauptwärmetauscherseitigen Anschlüssen zur Anbindung an deren kalten Teil, genauer an den oder die Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke bzw. deren Anschlüsse ausgebildet.The casing module provided according to the invention is characterized by the fact that it has predominantly, in particular exclusively, lines (fluid lines) designed for the forwarding of fluids. A casing module is formed with main compressor side connections for connection to a warm part of the air separation plant and with main heat exchanger side connections for connection to the cold part, more precisely to the main heat exchanger and / or main heat exchanger blocks or their connections.
Ein Verrohrungsmodul weist hierzu beispielsweise n hauptverdichterseitige Anschlüsse und n x m hauptwärmetauscherseitige Anschlüsse auf, wobei m die Anzahl der jeweils an das Verrohrungsmodul anbindbaren Hauptwärmetauscher darstellt und beispielsweise 1, 2, 3, 4, 5, 6, 7, 8, 9 oder 10 beträgt. Die hauptverdichterseitigen Anschlüsse und die hauptwärmetauscherseitigen Anschlüsse sind über die genannten Fluidleitungen miteinander verbunden. Ist n > 1, können jeweils mehrere hauptwärmetauscherseitige Anschlüsse über einen Fluidverteiler mit einem hauptverdichterseitigen Anschluss verbunden sein. Ein Verrohrungsmodul umfasst ggf. Absperrmittel zum Absperren einzelner Fluidleitungen und/oder Einstellmittel zum Einstellen eines Fluidstroms, insbesondere zur gleichmäßigen Aufteilung von Fluid eines hauptverdichterseitigen Anschlusses auf m hauptwärmetauscherseitige Anschlüsse, jedoch keine aktiv druck- und/oder temperaturbeeinflussenden Mittel, also Verdichter, Entspannungsventile bzw. Entspannungsmaschinen, Heizeinrichtungen, Kühler, Wärmetauscher und dergleichen.For this purpose, a casing module has, for example, n main compressor side connections and n x m main heat exchanger side connections, where m is the number of main heat exchangers respectively connectable to the casing module and, for example, 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10. The main compressor side ports and the main heat exchanger side ports are connected to each other via the fluid lines. If n> 1, in each case a plurality of main heat exchanger-side connections can be connected via a fluid distributor to a main compressor-side connection. A casing module optionally comprises shut-off means for shutting off individual fluid lines and / or adjusting means for adjusting a fluid flow, in particular for evenly distributing fluid of a main compressor side connection to main heat exchanger side connections, but not active pressure and / or temperature-influencing means, ie compressors, expansion valves or Relaxation machines, heaters, coolers, heat exchangers and the like.
Ein erfindungsgemäßes Verrohrungsmodul ist also baulich derart ausgebildet, däss ein, insbesondere ein jeder, durch das Verrohrungsmodul geführte Fluidstrom bei einem Austrittsdruck und/oder einer Austrittstemperatur verlässt, der bzw. die im Wesentlichen dem Eintrittsdruck bzw. der Eintrittstemperatur entspricht.A casing module according to the invention is thus structurally designed such that one, in particular one, each leaves the fluid flow guided through the casing module at an outlet pressure and / or an outlet temperature which substantially corresponds to the inlet pressure or inlet temperature.
Ein Fluidstrom, der dem Verrohrungsmodul entweder über einen hauptverdichterseitigen Anschluss eingespeist und über einen hauptwärmetauscherseitigen Anschluss (oder m hauptwärmetauscherseitige Anschlüsse) entnommen wird oder umgekehrt, weist bei der Entnahme den im Wesentlichen gleichen Druck und die im Wesentlichen gleiche Temperatur auf wie bei der Einspeisung. Ein "im Wesentlichen" gleicher Druck und eine "im Wesentlichen" gleiche Temperatur kann beispielsweise geringfügige Drucksteigerungen oder Druckverluste und/oder geringfügige Temperaturzunahmen oder Temperaturabnahmen umfassen, die beispielsweise weniger als 1 bar, 0,5 bar oder 0,1 bar bzw. weniger als 10 °C, 5 °C oder 1 °C betragen können und beispielsweise durch Leitungsverluste und/oder Wärmeeintrag aus der bzw. Wärmeabfuhr in die Umgebung entstehen können.A fluid flow, which is fed to the casing module either via a main compressor side port and via a main heat exchanger side port (or m main heat exchanger side ports), or vice versa, has substantially the same pressure and temperature at discharge as at the feed. A "substantially" equal pressure and a "substantially" the same temperature may, for example, minor pressure increases or pressure losses and / or slight increases in temperature or temperature decreases, for example, less than 1 bar, 0.5 bar or 0.1 bar or less than 10 ° C, 5 ° C or 1 ° C and may, for example, by line losses and / or heat input from or heat dissipation into the environment may arise.
Die "hauptverdichterseitigen" Anschlüsse zeichnen sich dadurch aus, sie zur Anbindung an einen warmen Teil der Luftzerlegungsanlage eingerichtet sind. Hingegen sind die "hauptwärmetauscherseitigen" Anschlüsse zur Anbindung an den oder die Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke bzw. deren Anschlüsse eingerichtet. Sind, wie erläutert, m Hauptwärmetauscher vorgesehen, unterscheidet sich die Anzahl der hauptverdichterseitigen Anschlüsse und der hauptwärmetauscherseitigen Anschlüsse. Zur Anbindung an den oder die Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke sind die Anschlüsse insbesondere dadurch eingerichtet, dass sie eine jeweils geeignete räumliche Anordnung und/oder Lage aufweisen. Wie erläutert, wird das erfindungsgemäße Verrohrungsmodul insbesondere für eine Headerverrohrung (bzw. deren teilweisen Ersatz) verwendet. Die hauptwärmetauscherseitigen Anschlüsse sind daher vorzugsweise oberhalb des Verrohrungsmoduls angeordnet. Die Anordnung "oberhalb" bzw. "unterhalb" definiert sich beispielsweise über eine Haltestruktur, die das Verrohrungsmodul trägt und entsprechende Standfüße bzw. -strukturen an ihrer Unterseite aufweist.The "main compressor side" connections are characterized by, they are set up for connection to a warm part of the air separation plant. By contrast, the "main heat exchanger side" connections for connection to the main heat exchanger and / or main heat exchanger blocks or their connections are set up. As explained, when the main heat exchanger is provided, the number of the main compressor side ports and the main heat exchanger side ports differs. For connection to the main heat exchanger (s) and / or main heat exchanger blocks, the connections are arranged, in particular, by having a respectively suitable spatial arrangement and / or position. As explained, the casing module according to the invention is used in particular for header piping (or its partial replacement). The main heat exchanger-side connections are therefore preferably arranged above the casing module. The arrangement "above" or "below" is defined, for example, by a support structure which supports the casing module and has corresponding feet or structures on its underside.
Im Gegensatz zu einer wie oben erwähnten vorgefertigten Headerverrohrung erlaubt das Verrohrungsmodul, die verbindenden Rohrleitungen zwischen den jeweiligen Anschlüssen (Anschlussstutzen) des oder der Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke und dem Verrohrungsmodul dreidimensional anzupassen. Vorteilhafterweise weist das Verrohrungsmodul dabei mit Anschlüssen des wenigstens einen des oder der Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke korrespondierende und mit diesen koppelbare Anschlüsse an seiner Oberseite, nämlich die erwähnten hauptwärmetauscherseitigen Anschlüsse, auf.In contrast to prefabricated header piping as mentioned above, the piping module allows three-dimensionally adapting the connecting piping between the respective ports of the main heat exchanger (s) and / or main heat exchanger blocks and the piping module. Advantageously, the casing module in this case has connections of at least one of the main heat exchanger and / or main heat exchanger blocks corresponding and coupled with these connections on its upper side, namely the mentioned main heat exchanger side connections, on.
Ein erfindungsgemäßes Verrohrungsmodul kann vollständig vorgefertigt, also z.B. gestrichen, druckgetestet, isoliert, instrumentiert und verkabelt werden. Am Fertigungsort stehen auch i.d.R. entsprechende Prüf- und Überwachungseinrichtungen zur Verfügung, die eine Sicherheitsabnahme am Fertigungsort erlauben. Hierdurch kann vermieden werden, dass beispielsweise Schäden oder Fertigungsfehler erst am Erstellungsort der Luftzerlegungsanlage entdeckt werden, was aufwendige Reparaturen oder, im Extremfall, Rücktransporte erforderlich macht.A casing module according to the invention can be completely prefabricated, e.g. be painted, pressure tested, isolated, instrumented and wired. I.d.R. appropriate testing and monitoring facilities available that allow a safety inspection at the production site. In this way it can be avoided that, for example, damage or manufacturing defects are only discovered at the place of construction of the air separation plant, which necessitates expensive repairs or, in extreme cases, return transport.
Durch die Verwendung eines erfindungsgemäßen Verrohrungsmoduls kann auch die Planung und Konzeption einer Luftzerlegungsanlage signifikant verbessert werden. Das erfindungsgemäße Verrohrungsmodul strukturiert das Layout einer entsprechenden Anlage und gibt ein eindeutiges Konzept vor. Dies ermöglicht eine weitgehende Erstellung aus standardisierten Modulen mit entsprechend zueinander passenden Anschlüssen im Sinne eines beliebig erweiterbaren Baukastenprinzips.By using a casing module according to the invention, the planning and design of an air separation plant can be significantly improved. The casing module according to the invention structures the layout of a corresponding system and provides a clear concept. This allows a large-scale creation of standardized modules with correspondingly matching connections in the sense of an arbitrarily expandable modular principle.
Insbesondere für Raffinerien, die Erdöltertiärförderung (Enhanced Oil Recovery) und Stahlwerke werden beträchtliche Mengen von Reingasen benötigt. Der Luftdurchsatz der größten Anlagen zur Erzeugung von Stickstoff für die Enhanced Oil Recovery beträgt ca. 500.000 Normkubikmeter Luft pro Stunde, für Raffinerien sind Anlagen mit Produktionsvolumina von ca. 860.000 Normkubikmetern Sauerstoff pro Stunde im Bau. Für Anlagen mit einem Luftdurchsatz von zumindest 200.000 Normkubikmetern Luft pro Stunde sind erfindungsgemäße Verrohrungsmodule problemlos transportierbar.In particular, refineries, enhanced oil recovery and steel mills require significant quantities of clean gases. The air throughput of the largest plants for the production of nitrogen for the Enhanced Oil Recovery amounts to approx. 500,000 standard cubic meters of air per hour, for refineries plants with production volumes of approx. 860,000 standard cubic meters of oxygen per hour are under construction. For systems with an air flow rate of at least 200,000 standard cubic meters of air per hour, casing modules according to the invention can be transported without difficulty.
Die Hauptwärmetauscher für Anlagen derartiger Größe bzw. entsprechende Hauptwärmetauscherblöcke können in der erforderlichen Leistungsfähigkeit nur an wenigen spezialisierten Fertigungsorten hergestellt werden. Dies ist auch durch die Herstellungstechnik für derartige Vorrichtungen bedingt. Besonders vorteilhaft für die genannten Anlagen sind insbesondere vakuumgelötete Aluminiumplatten-Wärmetauscher. Die Herstellung derartiger Wärmetauscher erfolgt in Vakuumöfen ohne den Einsatz von Flussmitteln. Diese Technik erfordert einen hohen Grad an Fertigungsqualität, da das Lot, das hierbei zum Fügen verwendet wird, in seinem Schmelzpunkt nur gering von jenem der zu fügenden Materialien abweicht.The main heat exchangers for plants of such size or corresponding main heat exchanger blocks can be produced in the required capacity only at a few specialized production sites. This is also due to the manufacturing technique for such devices. Particularly advantageous for the said systems are in particular vacuum-brazed aluminum plate heat exchangers. The production of such heat exchangers takes place in vacuum furnaces without the use of fluxes. This technique requires a high degree of Production quality, since the solder, which is used here for joining, deviates only slightly in its melting point from that of the materials to be joined.
Um eine maximale Leistungsfähigkeit zu erzielen, sind jedoch auch bei der Verrohrung entsprechend hohe Anforderungen an die Montagequalität einzuhalten. Insbesondere eine unsachgemäße Verschweißung kann die Leistungsfähigkeit der Hauptwärmetauscher, und damit der gesamten Luftzerlegungsanlage, signifikant beeinträchtigen. Insbesondere die erforderliche spannungsfreie Montage der Rohre bereitet Schwierigkeiten. Im Extremfall können beträchtliche Schäden auftreten.In order to achieve maximum performance, however, high demands must also be placed on the assembly quality in the piping. In particular, improper welding can significantly affect the performance of the main heat exchangers, and thus the entire air separation plant. In particular, the required stress-free assembly of the pipes is difficult. In extreme cases, considerable damage can occur.
Das erfindungsgemäße Verrohrungsmodul vereinfacht die Verrohrung derartiger Hauptwärmetauscher signifikant, so dass das eingesetzte Personal nicht in dem Umfang qualifiziert sein muss, wie dies herkömmlicherweise erforderlich ist, oder aber hochqualifiziertes Personal nur für einen kürzeren Zeitraum eingesetzt werden muss.The casing module according to the invention significantly simplifies the piping of such main heat exchangers, so that the personnel employed need not be qualified to the extent that is conventionally required, or else highly qualified personnel only have to be employed for a shorter period of time.
Wie bereits teilweise angesprochen, ist ein erfindungsgemäßes Verrohrungsmodul vorteilhafterweise zur Anbindung wenigstens zweier Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke ausgebildet. Dies ermöglicht eine besonders flexible Erstellung von Luftzerlegungsanlagen, die an die jeweils bestehenden Leistungsanforderungen angepasst werden können.As already partially addressed, a casing module according to the invention is advantageously designed for connecting at least two main heat exchangers and / or main heat exchanger blocks. This allows a particularly flexible creation of air separation plants, which can be adapted to the respective existing performance requirements.
Für jede Gasanwendung existiert eine optimale Wirtschaftlichkeit der Gasversorgung, die von zahlreichen Randbedingungen abhängig ist. Die rektifikatorische Luftzerlegung ist i.d.R. bereits ab einem Bedarf von 200 Normkubikmetern Stickstoff bzw. 1.000 Normkubikmetern Sauerstoff pro Stunde sinnvoll. Von diesen Werten bis hin zu den zuvor erwähnten Maximalleistungen ergibt sich eine sehr große Bandbreite an Produktionsvolumina, die von Luftzerlegungsanlagen abgedeckt werden muss. Insbesondere die verwendeten Hauptwärmetauscher können jedoch bisher nicht in beliebiger Größe erstellt werden. Auch unterhalb der durch mechanische Grenzen definierten Maximalgröße erweist sich die Herstellung sehr großer Hauptwärmetauscher häufig als wirtschaftlich nicht sinnvoll. In diesen Fällen ist es, wie erwähnt, erforderlich, mehrere Hauptwärmetauscher oder Hauptwärmetauscherblöcke (z.B. angeordnet in entsprechenden Coldboxen) zu verwenden und gemeinsam mit Luft aus dem warmen Bereich der Anlage zu versorgen. Gerade in derartigen Fällen ist ein Verrohrungsmodul mit einer entsprechenden Anschlussmöglichkeit für mehrere Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke sinnvoll.For every gas application there is an optimal economy of the gas supply, which depends on numerous boundary conditions. The rectificatory air separation is usually sensible from a requirement of 200 standard cubic meters of nitrogen or 1,000 standard cubic meters of oxygen per hour. From these values to the aforementioned maximum performance results in a very wide range of production volumes, which must be covered by air separation plants. In particular, the main heat exchangers used can not be created in any size yet. Also below the maximum size defined by mechanical limits, the production of very large main heat exchanger often proves to be economically not useful. In these cases, as mentioned, it is necessary to use several main heat exchangers or main heat exchanger blocks (eg arranged in corresponding cold boxes) and to supply them together with air from the warm area of the plant. Especially in such cases a casing module with a corresponding connection option for several main heat exchanger and / or main heat exchanger blocks makes sense.
Vorteilhafterweise sind hierzu die erfindungsgemäßen Verrohrungsmodule, wie erläutert, mit wenigstens einem Fluidverteiler ausgestattet. Unter einem "Fluidverteiler" sei dabei eine Rohranordnung verstanden, die die Anbindung von Anschlüssen mehrerer Hauptwärmetauscher und/oder Hauptwärmetauscherblöcke oder mehrerer Anschlüsse eines Hauptwärmetauschers an eine gemeinsame Leitung erlaubt. Ein Fluidverteiler trägt dabei dazu bei, mehrere Sätze von Anschlüssen entsprechend den jeweils anzubindenden Hauptwärmetauschern bereitzustellen, wobei, wie erläutert, beispielsweise n hauptverdichterseitige Anschlüsse und n × m hauptwärmetauscherseitige Anschlüsse vorgesehen sind.Advantageously, for this purpose, the piping modules according to the invention, as explained, equipped with at least one fluid distributor. A "fluid distributor" is understood to mean a tube arrangement which permits the connection of connections of a plurality of main heat exchangers and / or main heat exchanger blocks or a plurality of connections of a main heat exchanger to a common line. A fluid distributor helps to provide a plurality of sets of ports corresponding to the respective main heat exchangers to be connected, wherein, as explained, for example, n main compressor side ports and n × m main heat exchanger side ports are provided.
Auch ein derartiger Fluidverteiler kann vorteilhafterweise als Modul ausgebildet sein. Ein Verrohrungsmodul kann daher beispielsweise am Fertigungsort aus einem Grundmodul und einem entsprechenden Fluidverteilermodul zusammengesetzt werden. Das Grundmodul beinhaltet sinnvollerweise auch noch Bauteile, die herkömmlicherweise im Feld auf der Baustelle montiert werden. Dies ermöglicht eine weitgehende Serien- und Vorfertigung entsprechender Module, die dann lediglich noch nach Bedarf montiert werden müssen. Hierdurch wird eine effiziente und zeitnahe Erstellung von Verrohrungsmodulen ermöglicht.Also, such a fluid distributor can be advantageously designed as a module. A casing module can therefore be assembled, for example, at the production site from a basic module and a corresponding fluid distribution module. The basic module also makes sense to include components that are conventionally mounted in the field on the construction site. This allows a large-scale production and prefabrication of appropriate modules, which then only need to be mounted as needed. This allows efficient and timely creation of casing modules.
Vorteilhafterweise ist für jeden Hauptwärmetauscher und/oder Hauptwärmetauscherblock ein separater hauptwärmetauscherseitiger Anschlusssatz vorgesehen, der zumindest eine Zuleitung für komprimierte, vorgereinigte und vorgekühlte Luft und eine Abführleitung für Kühlstickstoff umfasst. Die in den erläuterten Luftzerlegungsanlagen verwendeten Hauptwärmetauscher bzw. Hauptwärmetauscherblöcke weisen eine Reihe von Leitungen auf, die Fluidströme in beiden Richtungen durch die Hauptwärmetauscher bzw. Hauptwärmetauscherblöcke führen. Die Leitungen enden an der Oberseite der Hauptwärmetauscher bzw. Hauptwärmetauscherblöcke in einem oder in mehreren Anschlussstutzen. Mehrere Anschlussstutzen werden in dem erläuterten Fluidverteiler, der erfindungsgemäß einen Teil des Verrohrungsmoduls darstellt, zusammengefasst. Hierzu sind die genannten Zu- und Abführleitungen vorgesehen.Advantageously, a separate main heat exchanger side connection set is provided for each main heat exchanger and / or main heat exchanger block, which comprises at least one supply line for compressed, pre-cleaned and pre-cooled air and a discharge line for cooling nitrogen. The main heat exchangers or main heat exchanger blocks used in the illustrated air separation plants have a series of lines which conduct fluid flows in both directions through the main heat exchanger or main heat exchanger blocks. The lines end at the top of the main heat exchanger or main heat exchanger blocks in one or more connecting pieces. Several connecting pieces are summarized in the illustrated fluid distributor, which is part of the casing module according to the invention. For this purpose, the aforementioned supply and discharge lines are provided.
Den Hauptwärmetauscher durchlaufen in Luftzerlegungsanlagen der eingangs erläuterten Art üblicherweise auch entsprechende Produktströme, die im Gegenstrom zu der aus dem warmen Teil der Anlage eingespeisten Luft durch den Hauptwärmetauscher geführt werden. Somit kann ein hauptwärmetauscherseitiger Anschlusssatz auch weitere Abführleitungen, beispielsweise für Sauerstoff, Produktstickstoff und/oder Edelgase umfassen. Ist in der Luftzerlegungsanlage ein zusätzlicher Hochdruckwärmetauscher vorgesehen (der an einen entsprechenden Nach- bzw. Kreislaufverdichter anzubinden ist), können auch hierfür entsprechende Leitungen in einem Leitungssatz vorgesehen sein.The main heat exchangers in air separation plants of the type described at the beginning usually also pass through corresponding product streams which are passed through the main heat exchanger in countercurrent to the air fed from the warm part of the plant. Thus, a main heat exchanger side connection set also include other discharge lines, for example, for oxygen, product nitrogen and / or noble gases. If an additional high-pressure heat exchanger is provided in the air separation plant (which is to be connected to a corresponding after-circulation or cycle compressor), corresponding lines can also be provided in a line set for this purpose.
In entsprechenden Anschlusssätzen sind vorteilhafterweise die entsprechenden Anschlüsse räumlich so angeordnet, dass eine möglichst einfache und direkte Anbindung des oder der Hauptwärmetauscher gewährleistet ist. Eine derartige gleichartige räumliche Anordnung kann dabei derart normiert werden, dass eine Vielzahl von unterschiedlichen Modulen - im Sinne des oben erwähnten Baukastenprinzips - ohne aufwendige Anpassungen miteinander verbunden werden kann. Die räumliche Anordnung erlaubt jedoch eine dreidimensionale Anpassung entsprechender Verbindungsleitungen zumindest in gewissem Umfang, um z.B. Toleranzen von Modulen und Fundamenten ausgleichen zu können.In corresponding connection sets, the corresponding connections are advantageously arranged spatially so that the simplest possible and direct connection of the main heat exchanger is ensured. Such a similar spatial arrangement can be normalized such that a variety of different modules - in the sense of the above-mentioned modular principle - can be connected to each other without costly adjustments. However, the spatial arrangement allows three-dimensional adaptation of corresponding connection lines, at least to a certain extent, in order, e.g. Compensate tolerances of modules and foundations.
Zur Verbindung des Verrohrungsmoduls mit dem oder den Hauptwärmetauscher(n) können daher ihrerseits vorgefertigte Anschlussrohre, ggf. mit entsprechend normierten Flanschen, verwendet werden. Dies reduziert die erforderlichen Montageschritte. Auch diese sind jedoch noch zumindest in gewissem Umfang anpassbar.For the connection of the casing module with the main heat exchanger (s), it is therefore possible in turn to use prefabricated connection pipes, if appropriate with correspondingly standardized flanges. This reduces the required assembly steps. However, these are still at least to some extent customizable.
Ein erfindungsgemäßes Verrohrungsmodul umfasst vorteilhafterweise auch brandgeschützte Sauerstoffübergabeventile. Entsprechend erforderliche Brandabschottungseinrichtungen können ebenfalls zusammen mit den übrigen Komponenten des Verrohrungsmoduls vorgefertigt und damit in vorgefertigter und ggf. entsprechend geprüfter Form an den Erstellungsort der Luftzerlegungsanlage verbracht werden. Die übliche Abschottung mit einer Betonmauer entfällt.A casing module according to the invention advantageously also comprises fire-protected oxygen transfer valves. Correspondingly required Brandabschottungseinrichtungen can also be prefabricated together with the other components of the casing module and thus spent in prefabricated and possibly suitably tested form to the site of the air separation plant. The usual foreclosure with a concrete wall is eliminated.
In einer besonders bevorzugten Ausgestaltung ist ein erläutertes Verrohrungsmodul, ggf. mit einem zuvor erläuterten integrierten und/oder modular ausgebildeten Fluidverteiler, zur senkrechten Anordnung neben dem wenigstens einen Hauptwärmetauscher bzw. einem entsprechenden Hauptwärmetauscherblock ausgebildet. Dies ermöglicht einerseits eine platzsparende Verrohrung eines oder mehrerer Hauptwärmetauscher und andererseits eine einfache Vorfertigung und einen unproblematischen Transport. Senkrecht anordenbare Verrohrungsmodule können in einer Horizontalrichtung flach ausgebildet und daher liegend vorgefertigt werden. Der erforderliche Montageraum ist daher gegenüber herkömmlichen Anordnungen beträchtlich reduziert.In a particularly preferred embodiment is an illustrated casing module, possibly with an integrated and / or modular previously explained Fluid distributor, formed for vertical arrangement next to the at least one main heat exchanger or a corresponding main heat exchanger block. On the one hand, this enables space-saving piping of one or more main heat exchangers and, on the other hand, simple prefabrication and unproblematic transport. Vertically locatable casing modules can be formed flat in a horizontal direction and therefore prefabricated lying. The required mounting space is therefore considerably reduced compared to conventional arrangements.
Die erfindungsgemäß ebenfalls vorgesehene Luftzerlegungsanlage profitiert von den zuvor erläuterten Vorteilen, auf die daher ausdrücklich verwiesen werden kann.The present invention also provided air separation plant benefits from the advantages explained above, to which therefore can be explicitly referenced.
Ein erfindungsgemäßes Verfahren zur Erstellung einer Luftzerlegungsanlage umfasst eine Bereitstellung wenigstens eines Hauptwärmetauschers und eines erfindungsgemäßen Verrohrungsmoduls sowie die Anbindung des wenigstens einen Hauptwärmetauschers an das Verrohrungsmodul. Vorzugsweise sind die genannten Komponenten vorgefertigt. Hieraus ergeben sich ebenfalls die erwähnten Vorteile.An inventive method for producing an air separation plant comprises a provision of at least one main heat exchanger and a casing module according to the invention and the connection of the at least one main heat exchanger to the casing module. Preferably, said components are prefabricated. This also results in the mentioned advantages.
Es versteht sich, dass die vorstehend genannten und die nachstehend noch zu erläuternden Merkmale nicht nur in der jeweils angegebenen Kombination, sondern auch in anderen Kombinationen oder in Alleinstellung verwendbar sind, ohne den Rahmen der vorliegenden Erfindung zu verlassen.It is understood that the features mentioned above and those yet to be explained below can be used not only in the particular combination given, but also in other combinations or in isolation, without departing from the scope of the present invention.
Die Erfindung ist anhand eines Ausführungsbeispiels in der beigefügten Zeichnung schematisch dargestellt und wird im Folgenden unter Bezugnahme auf die Zeichnung ausführlich beschrieben.The invention is illustrated schematically with reference to an embodiment in the accompanying drawing and will be described in detail below with reference to the drawing.
- Figur 1FIG. 1
- zeigt eine Luftzerlegungsanlage gemäß dem Stand der Technik in stark vereinfachter, schematischer Darstellung.shows an air separation plant according to the prior art in a highly simplified, schematic representation.
- Figur 2FIG. 2
- zeigt ein Verrohrungsmodul mit zwei Hauptwärmetauschern gemäß einer Ausführungsform der Erfindung in schematischer Darstellung.shows a casing module with two main heat exchangers according to an embodiment of the invention in a schematic representation.
In den Figuren tragen gleiche oder gleichwirkende Elemente ggf. identische Bezugszeichen und werden der Übersichtlichkeit halber nicht wiederholt erläutert.In the figures, the same or equivalent elements may carry identical reference numerals and will not be explained repeatedly for the sake of clarity.
Dem Hauptwärmetauscher in dem Hauptwärmetauschermodul 1, der einen oder mehrere Hauptwärmetauscherblöcke in einer entsprechenden Coldbox umfassen kann, wird ein gestrichelt dargestellter Luftstrom zugeführt, der zuvor in einem Verdichter 2 verdichtet und in einem Adsorber 3 aufgereinigt wurde. Zusätzliche Einrichtungen wie Filter und dergleichen sind nicht dargestellt. Wenngleich in
In dem Hauptwärmetauscher in dem Hauptwärmetauschermodul 1 wird die zugeführte, komprimierte und aufgereinigte Luft im Gegenstrom mit kaltem, gasförmigem Stickstoff GAN vom Kopf einer nachfolgend erläuterten Trennsäule 5 gekühlt.In the main heat exchanger in the main
Der bis nahe Verflüssigungstemperatur abgekühlte Luftstrom wird nachfolgend in einem Expansionsventil 4 entspannt und in teilweise flüssiger Form in einen mittleren Bereich der Trennsäule 5 eingespeist. Eine entsprechende Anlage kann zusätzlich eine Nachverdichtung eines (Teil-)Luftstroms und eine Abkühlung in einem Hochdruckwärmetauscher umfassen. Auch dies ist der Übersicht halber nicht dargestellt. Wie bereits erläutert, können anstatt einer einzigen Trennsäule 5, wie in
Für die Zerlegung der verflüssigten Luft werden die unterschiedlichen Siedepunkte ihrer Bestandteile genutzt. In der Trennsäule 5 rieselt die flüssige Luft hierzu über eine Anzahl von stark vereinfacht dargestellten Siebböden im Gegenstrom zu nicht verflüssigter, aufsteigender Luft nach unten. Die Flüssigkeit wird hierbei auf den Böden gestaut und von aufsteigenden Dampfblasen durchströmt. Aus dem Gasstrom verflüssigt sich dabei vor allem der höher siedende Sauerstoff, während aus den Flüssigkeitstropfen bevorzugt der tiefer siedende Stickstoff verdampft. Am kalten Kopf der Trennsäule 5 sammelt sich aus diesem Grund gasförmiger Stickstoff GAN und am wärmeren Boden flüssiger Sauerstoff LOX.For the decomposition of the liquefied air, the different boiling points of its components are used. In the separation column 5, the liquid air trickles over a Number of highly simplified sieve trays countercurrent to non-liquefied ascending air downwards. The liquid is thereby stowed on the ground and flows through ascending vapor bubbles. Above all, the higher-boiling oxygen liquefies from the gas stream, while the lower-boiling nitrogen preferably evaporates from the liquid drops. For this reason, gaseous nitrogen GAN collects at the cold head of the separation column 5 and liquid oxygen LOX at the warmer bottom.
Zur weiteren Aufreinigung der Fraktionen wird der flüssige Sauerstoff LOX vom Boden der Trennsäule 5 in einem Verdampfer 6 verdampft, der gasförmige Stickstoff wird in einem sogenannten Kopfkondensator 7 verflüssigt. Der verdampfte, gasförmige Sauerstoff GOX und der verflüssigte Stickstoff LIN werden wieder der Trennsäule 5 zugeführt, wo die Rektifikation wiederholt wird, bis die gewünschte Reinheit erreicht ist.For further purification of the fractions, the liquid oxygen LOX is vaporized from the bottom of the separation column 5 in an evaporator 6, the gaseous nitrogen is liquefied in a so-called
Entsprechend reine Fluide können vom Boden bzw. Kopf der Trennsäule 5 entnommen und zur Weiterverwendung in Flüssigtanks 8, 9 gelagert werden.Correspondingly pure fluids can be removed from the bottom or head of the separation column 5 and stored for further use in
Der Trennsäule 5 kann ferner beispielsweise eine Sauerstoff-Argon-Mischung O/Ar entnommen werden, aus der in einem separaten Verfahren in einer weiteren Säule hochreines Argon gewonnen werden kann. Auch für die Gewinnung der Edelgase Xenon, Krypton, Helium und/oder Neon werden separate Säulen benötigt.The separation column 5 can also be taken, for example, an oxygen-argon mixture O / Ar, from which in a separate process in a further column high-purity argon can be obtained. Separate columns are also needed for the extraction of the noble gases xenon, krypton, helium and / or neon.
Zur Kühlung von neu angesaugter Luft (siehe oben) wird ein Teil des gewonnenen Stickstoffs GAN entnommen und zum Hauptwärmetauscher in dem Hauptwärmetauschermodul 1 zurückgeführt.For cooling of newly aspirated air (see above), a portion of the recovered nitrogen GAN is removed and returned to the main heat exchanger in the main
Das Verrohrungsmodul 10 kann aus einem Grundmodul 11 und einem Fluidverteilermodul 12 aufgebaut sein, die über eine geeignete Verbindung 13 miteinander verbunden sind. In dem Grundmodul 11 können zentrale Komponenten wie entsprechende Ventile 14 angeordnet sein. In der
Das Verrohrungsmodul 10 kann ferner - in dem Hauptmodul 11 und/oder dem Fluidverteilermodul 12 - wenigstens einen Druck-, Temperatur- und/oder Druchflussregler 15 aufweisen. Nicht dargestellt sind beispielsweise brandgeschützte Sauerstoffventile.The
Das Fluidverteilermodul 12 weist, wie erwähnt, einen Satz Anschlüsse 12a bzw. 12b für die anzuschließenden Hauptwärmetauscher 1 a bzw. 1 b auf. Diese können sehr einfach mit korrespondierenden Anschlüssen 12a' bzw. 12b' an den anzuschließenden Hauptwärmetauscher 1 a bzw. 1 b verbunden werden.As mentioned, the
Claims (11)
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PL13001829T PL2657633T3 (en) | 2012-04-27 | 2013-04-09 | Tubing module for air separation unit |
EP13001829.4A EP2657633B1 (en) | 2012-04-27 | 2013-04-09 | Tubing module for air separation unit |
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DE102012008416A DE102012008416A1 (en) | 2012-04-27 | 2012-04-27 | Casing module for air separation plant |
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EP13001829.4A EP2657633B1 (en) | 2012-04-27 | 2013-04-09 | Tubing module for air separation unit |
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FR3052242A1 (en) * | 2016-06-06 | 2017-12-08 | L'air Liquide Sa Pour L'etude Et L'exploitation Des Procedes Georges Claude | CONSTRUCTION ELEMENT OF MASS AND / OR HEAT EXCHANGE APPARATUS, ASSEMBLY OF TWO ELEMENTS AND EXCHANGE METHOD USING ASSEMBLY |
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CN109348726A (en) * | 2016-06-06 | 2019-02-15 | 乔治洛德方法研究和开发液化空气有限公司 | Method for constructing or modifying substance and/or heat-exchange device |
US11215395B2 (en) | 2016-06-06 | 2022-01-04 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude | Element for construction of a mass- and/or heat-exchange device, assembly of two elements and exchange method using an assembly |
WO2019015806A1 (en) * | 2017-07-20 | 2019-01-24 | Linde Aktiengesellschaft | Device for disassembling the product stream of an alkane dhydrogenation |
CN107588667A (en) * | 2017-10-12 | 2018-01-16 | 开封空分集团有限公司 | Star multilayer condenser/evaporator |
CN107588667B (en) * | 2017-10-12 | 2023-10-03 | 开封空分集团有限公司 | Star-shaped multi-layer condensation evaporator |
CN109916137A (en) * | 2019-04-09 | 2019-06-21 | 中国海洋石油集团有限公司 | A kind of ice chest shunting means |
FR3116892A1 (en) | 2020-12-02 | 2022-06-03 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Apparatus for air separation by cryogenic distillation |
WO2022117741A1 (en) | 2020-12-02 | 2022-06-09 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Device for separating air by cryogenic distillation |
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EP2657633B1 (en) | 2019-10-02 |
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