EP2657466B1 - Centrale alimentée par une énergie fossile avec accumulateur de chaleur - Google Patents

Centrale alimentée par une énergie fossile avec accumulateur de chaleur Download PDF

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Publication number
EP2657466B1
EP2657466B1 EP13164893.3A EP13164893A EP2657466B1 EP 2657466 B1 EP2657466 B1 EP 2657466B1 EP 13164893 A EP13164893 A EP 13164893A EP 2657466 B1 EP2657466 B1 EP 2657466B1
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EP
European Patent Office
Prior art keywords
steam
heat
water
power plant
heat accumulator
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EP13164893.3A
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German (de)
English (en)
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EP2657466A3 (fr
EP2657466A2 (fr
Inventor
Christian Dr.-Ing. Bergins
Friedrich Dr.-Ing. Klauke
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Mitsubishi Power Europe GmbH
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Mitsubishi Hitachi Power Systems Europe GmbH
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Priority to EP17200082.0A priority Critical patent/EP3301266A3/fr
Publication of EP2657466A2 publication Critical patent/EP2657466A2/fr
Publication of EP2657466A3 publication Critical patent/EP2657466A3/fr
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K3/00Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K3/00Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
    • F01K3/18Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters
    • F01K3/186Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters using electric heat
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K13/00General layout or general methods of operation of complete plants
    • F01K13/02Controlling, e.g. stopping or starting
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01KSTEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K3/00Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
    • F01K3/18Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters
    • F01K3/24Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters with heating by separately-fired heaters

Definitions

  • the invention is directed to a power plant comprising a steam generator with connected water / steam circuit and turbine or turbine set integrated therein, the steam generator having a fossil fuel and / or biomass combustible combustion chamber and wherein the water / steam circuit steam side with a thermally coupled to a heat storage heat exchanger conductively connected and / or thermally coupled, wherein the water / steam circuit is connected in line with the heat exchanger such that thermal energy of the steam from the water / steam cycle is thermally coupled into the heat exchanger.
  • the invention is directed to a method for storing generated in a power plant with a steam generator with connected water / steam cycle and integrated turbine or turbo set heat, the steam generator has a fossil fuel and / or biomass combustible combustion chamber and wherein the water / steam cycle on the steam side with a thermally coupled to a heat storage heat exchanger connected in series and / or thermally coupled, wherein in the heat exchanger heat energy from the steam of the water / steam cycle is coupled and coupled into the heat exchanger.
  • the electric power feeding power generation and the electric power taken from the power grid must be balanced. Due to the expansion of renewable energies, there are at times strong overcapacities, but in some cases also undercapacities in the grid.
  • the fluctuating supply of renewable energy and thus the fluctuating feed-in of renewable energies into the power grid must balanced by conventional power plants. This makes it necessary to equip conventional power plants with a quickly controllable power plant capacity, so that they can shut down quickly in case of overcapacity and quickly booted up under sub-capacity, depending on the requirements of the grid.
  • Fossil-fired power plants are now however provided with the disadvantage that they can not be arbitrarily turned on and off and are mobile up and down in relation to their output power.
  • the power of steam power plants especially the coal-fired steam generator, can not be changed arbitrarily strong and fast.
  • minimum operating and minimum downtimes must be observed to avoid excessive system wear. If power plants are to remain on the grid as a so-called "hot reserve" for a direct restart for power generation, then they must be in permanent operation with their own Minimum or minimum load ready.
  • a generic power plant and a generic method with an arrangement for storing energy are from the US 4,164,848 A known.
  • This document discloses a power plant with a coupled in a water / steam cycle heat storage, which in turn is in heat communication with heat exchangers, decouple the heat energy in the water / steam cycle.
  • a coupling of thermal energy of the steam in the heat storage takes place such that from the feed water line of the water / steam cycle preheated water, which is branched off upstream of a steam generator from the water / steam cycle, the heat accumulator is supplied.
  • steam is supplied to the heat storage downstream of the steam generator from the water / steam cycle. In this respect, the heat energy of the steam is coupled into the heat storage.
  • Decoupling occurs in that the water stored in the heat storage is supplied to the heat exchangers and heat energy is released in the heat exchangers to form steam to the water / steam cycle. After passing through the heat exchanger, the water is fed to the feedwater line upstream of the steam generator.
  • the DE 10 2009 060 089 A1 discloses a solar thermal power plant in which a heat storage is integrated into the water / steam cycle. An interaction of this heat storage with an associated heat exchanger is not apparent from this document.
  • the invention has for its object to provide a solution that makes it possible to adapt a power plant to the fluctuating feed demand of the connected power grid and to flexibilize with respect to its Stromeinspeisebaum.
  • this object is achieved in that thermal energy of the steam is transmitted in the heat exchanger to a heat transfer medium and coupled to the heat transfer medium heat energy in the heat storage.
  • this object is achieved in that transferred heat energy of the steam to a heat transfer medium in the heat exchanger and transferred to the heat transfer medium heat energy in the heat storage.
  • heat energy from the steam is indirectly decoupled from the water / steam cycle into a heat store via a heat exchanger and, if appropriate, directly directly into a heat store, wherein both outcoupling paths can possibly also be operated in parallel.
  • This makes it possible to flexibilize power plants insofar as generated steam does not necessarily have to be routed to generate electricity through the turbine set or turbo set, but is passed through at least one heat exchanger and optionally at least one heat storage where the steam (its) gives off energy.
  • the amount of steam used for power generation can thereby be reduced, and thus the amount of electricity or electrical energy fed into the network by the power plant can be regulated so that part of the steam quantity is "stored".
  • the stored energy when the power plant is restarted, the stored energy may be used to achieve a higher rate of power change in percent / minute than the usual 3-5% / minute by the energy stored in the form of thermal energy when starting in the form of steam, for example, to the low-pressure preheaters of the water / steam cycle of the power plant is provided.
  • peak / midload current in addition to the (main) water may be provided by means of a salt / water steam heat exchanger, preferably a once-through steam generator, and any additional turbine circuit / Steam cycle of the power plant are provided and fed into the grid.
  • the invention is thus characterized in design of the power plant by the fact that the water / steam circuit on the steam side connected to the heat storage line connected and / or thermally coupled, the water / steam cycle is so connected to the heat storage line connected, that heat energy of the steam the water / steam cycle is thermally coupled out in the heat storage.
  • the method is characterized by the fact that the Water / steam cycle on the steam side connected to the heat storage line connected and / or thermally coupled, being coupled in the heat storage heat energy from the steam of the water / steam cycle and coupled into the heat storage.
  • heat energy of the steam is transferred in the heat storage to a heat transfer medium and / or a heat storage medium.
  • the invention In order to be able to transfer current overcapacities present in the network from the grid to a storage, the invention also provides that the heat storage is electrically heated, or that the heat storage in the power grid existing overcapacity of electricity and / or operation of the power plant in his Minimum or minimum load range generated, not to be fed into the grid excess current via a with the respective current and / or excess current electrically heated and arranged in the heat storage heater thermal energy is supplied and stored in the heat storage. This makes it possible to store energy, if due to the fluctuating feed-in of renewable energies such as wind or photovoltaic in the grid is too high a feed.
  • the power plant can be restarted relatively quickly, but alternatively, also parallel to the (main) water / steam cycle of the power plant a second water / steam cycle with associated turbine set or turbo set can be operated, which then immediately without the power plant must be started, generates electricity and fed into the network.
  • the invention therefore provides in an embodiment that the heat storage of the power plant in stored heat auskoppelbarer manner is connected to at least one further steam generator, which forms a preheater, superheater or reheater in the or a second water / steam cycle.
  • the invention provides in an embodiment that the heat storage of the power plant in stored heat auskoppelbarer manner is connected to the or a second heat exchanger.
  • the method is characterized in that heat stored in the heat accumulator is decoupled into the or a second steam generator, wherein steam generated in the steam generator is supplied to a turbine as live steam or reheater steam, and / or heat stored in the heat accumulator at least one further heat exchanger is decoupled, which forms a preheater, superheater or reheater in the or a second water / steam cycle.
  • This steam is then fed in each case to a turbine or turbo set with a connected generator.
  • the power plant according to the invention and the method according to the invention can be used to decouple and store the heat energy arising during operation of the power plant in its minimum or minimum load range in the form of steam from the water / steam cycle.
  • the invention therefore further provides, in an embodiment of the method, that the heat energy from heat generated during operation of the power plant in its minimum or minimum load range and not used for power generation excess steam from the water / steam cycle thermally coupled into the heat storage and / or the heat exchanger becomes.
  • This can then in development of the method also be provided that when restarting the power plant from its minimum or minimum load range stored in the heat storage heat in the and / or in the second water / steam cycle, preferably in the range of Niederdruckvor lockerrn coupled.
  • the heat storage can be designed as a steam storage or Ruths storage, salt storage, concrete storage or hot water storage.
  • a particularly suitable heat storage medium is molten salt, in particular a mixture of KNO 3 and NaNO 3 .
  • the heat storage for example, from two reciprocally operated containers (hot / cold) with the storage medium, eg , As molten salts, or a stratified storage tank with molten salt, to use temporarily excess electricity from the power grid and / or temporarily excess steam from the steam power plant (steam power plant with connected water / steam cycle) for heating the storage medium provided in the heat storage use. Since electric heating has an efficiency of nearly 100% and conventional steam power processes in the temperature range 530 ° C have cycle efficiencies of 38-42%, the efficiency of the energy storage is higher than many other alternatives.
  • the inventive measure in power plants to integrate a heat exchanger and an associated heat storage in the steam generation of the power plant or possibly equipped with its own associated steam generation including a turbine or turbo set with attached generator can in the replanning of power plants, especially in a new construction of fossil-fired power plants , planned and provided as additional equipment or additional equipment. But it is also possible to retrofit this additional system in an existing power plant as part of a conversion or upgrade.
  • the single figure shows schematically the water / steam circuit 1 of a fossil-fired power plant.
  • the water / steam cycle is usually equipped and includes in a manner not shown preheater, superheater, reheater, a turbine or turbo set with attached generator and a water treatment.
  • a heat exchanger 2 is thermally coupled, which makes it possible that thermal energy from coupled in the water / steam cycle 1 steam in the heat exchanger 2 circulating heat transfer medium 8 is coupled.
  • the heat exchanger 2 is also thermally coupled to a heat storage 3. In the heat storage 3, the heat transfer medium of the heat exchanger 8 of the second absorbed heat energy to the heat storage 3 decoupled. If desired, the energy transmission path can also be reversed.
  • heat energy is coupled to the heat transfer medium 8 of the heat exchanger 2 and decoupled from this in the heat exchanger 2 to the water / steam cycle 1 of the power plant.
  • a heating device 4 is further arranged, which is in current-conducting connection with a power grid 5. During operation of the heating device 4, for example by means of excess current present in the power grid, heat energy is generated electrically by means of the heating device, which is stored in the heat accumulator 3.
  • the heat storage 3 is thermally coupled to a second heat exchanger 6, which in turn is thermally coupled to a second steam generator 7 or a second water / steam cycle.
  • a second steam generator 7 or a second water / steam cycle is assigned a turbine set or turbo set with a connected generator, so that electricity can also be generated here.
  • this second heat exchanger 6 is then put into operation when undercapacities in the power grid 5 are to be compensated.
  • the heat exchangers 2 and 6 may be preheaters, superheaters or reheaters of the respective water / steam cycle 1, 7 act.
  • the second heat exchanger 6 can be designed as a once-through steam generator (continuous steam generator).

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)
  • Control Of Eletrric Generators (AREA)

Claims (17)

  1. Centrale électrique comprenant un générateur de vapeur avec un circuit eau/vapeur (1) raccordé et un ensemble de turbines ou un groupe turbo-générateur intégré, le générateur de vapeur comprenant une chambre de combustion pouvant être alimentée en carburant fossile et/ou en biomasse et le circuit eau/vapeur (1) étant relié, côté vapeur, par une conduite et/ou couplé thermiquement à un échangeur thermique (2) couplé thermiquement à un accumulateur de chaleur (3),
    le circuit eau/vapeur (1) étant relié par une conduite à l'échangeur thermique (2) de façon à ce que l'énergie thermique de la vapeur puisse être transférée du circuit eau/vapeur (1) thermiquement vers l'échangeur thermique (2),
    caractérisée en ce que
    l'énergie thermique de la vapeur dans l'échangeur thermique (2) est transmise à un fluide caloporteur (8) et l'énergie thermique transmise au fluide caloporteur (8) est transférée à l'accumulateur de chaleur (3).
  2. Centrale électrique selon la revendication 1, caractérisée en ce que le circuit eau/vapeur (1) est relié côté vapeur par une conduite et/ou couplé thermiquement avec l'accumulateur de chaleur (3), le circuit eau/vapeur (1) étant relié par une conduite avec l'accumulateur de chaleur (3) de façon à ce que l'énergie thermique de la vapeur puisse être transférée du circuit eau/vapeur (1) thermiquement vers l'accumulateur de chaleur (3).
  3. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'énergie thermique de la vapeur est transmise, dans l'accumulateur de chaleur (3), à un fluide caloporteur et/ou un fluide d'accumulation thermique.
  4. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'accumulateur de chaleur (3) est conçu de façon à pouvoir être chauffé électriquement.
  5. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que les brûleurs de la chambre de combustion font partie d'un dispositif de combustion indirecte.
  6. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'accumulateur de chaleur (3) est relié avec le ou avec un deuxième générateur de vapeur de façon à pouvoir transférer la chaleur accumulée.
  7. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'accumulateur de chaleur (3) est relié de façon à pouvoir transférer la chaleur accumulée avec au moins un autre échangeur thermique (6) qui est constitué, dans le ou dans un deuxième circuit eau/vapeur (1, 7), d'un dispositif de préchauffage, d'un dispositif de surchauffage ou d'un dispositif de surchauffage intermédiaire.
  8. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'accumulateur de chaleur (3) comprend du sel fondu en tant que fluide d'accumulation de chaleur.
  9. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce qu'elle comprend un accumulateur d'air comprimé comprenant un compresseur et un détendeur, qui est relié avec l'accumulateur de chaleur (3) de façon à pouvoir coupler la chaleur de compression dans l'échangeur thermique (2) ou l'accumulateur de chaleur (3).
  10. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'accumulateur de chaleur (3) est relié avec un dispositif de chauffage d'air de façon à pouvoir transférer la chaleur accumulée.
  11. Centrale électrique selon l'une des revendications précédentes, caractérisée en ce que l'accumulateur de chaleur (3) est conçu comme un accumulateur de vapeur, un accumulateur de sel, un accumulateur de béton ou un accumulateur d'eau chaude.
  12. Procédé de stockage de chaleur générée, dans une centrale électrique, avec un générateur de vapeur avec un circuit eau/vapeur (1) raccordé et un ensemble de turbines ou un groupe turbo-générateur intégré, le générateur de vapeur comprenant une chambre de combustion pouvant être alimentée en carburant fossile et/ou en biomasse et le circuit eau/vapeur (1) étant relié, côté vapeur, par une conduite et/ou couplé thermiquement à un échangeur thermique (2) couplé thermiquement à un accumulateur de chaleur (3),
    de sorte que, dans l'échangeur thermique (2), l'énergie thermique est extraite de la vapeur du circuit eau/vapeur (1) et est introduite dans l'échangeur thermique (2),
    caractérisé en ce que
    dans l'échangeur thermique (2), l'énergie thermique de la vapeur est transmise à un fluide caloporteur (8) et l'énergie thermique transmise au fluide caloporteur (8) est transférée dans l'accumulateur de chaleur (3).
  13. Procédé selon la revendication 12, caractérisé en ce que le circuit eau/vapeur (1) est relié côté vapeur par une conduite et/ou couplé thermiquement avec l'accumulateur de chaleur (3), de façon à ce que, dans l'accumulateur de chaleur (3), l'énergie thermique de la vapeur puisse être extraite du circuit eau/vapeur (1) et introduite dans l'accumulateur de chaleur (3).
  14. Procédé selon la revendication 12 ou 13, caractérisé en ce que la chaleur accumulée dans l'accumulateur de chaleur (3) est transférée vers le ou vers un deuxième générateur de vapeur, de sorte que la vapeur générée dans le générateur de vapeur est introduite dans une turbine en tant que vapeur fraîche ou vapeur du dispositif de surchauffage intermédiaire et/ou en ce que la chaleur accumulée dans l'accumulateur de chaleur (3) est transférée vers au moins un autre échangeur thermique (6), qui constitue, dans le ou dans un deuxième circuit eau/vapeur (1, 7), un dispositif de préchauffage, un dispositif de surchauffage ou un dispositif de surchauffage intermédiaire.
  15. Procédé selon l'une des revendications 12 à 14, caractérisé en ce que l'énergie thermique de la vapeur en excès, générée lors du fonctionnement de la centrale électrique à sa charge minimale et non utilisée pour la production de courant, est transférée thermiquement du circuit eau/vapeur (1) vers l'accumulateur de chaleur (3) et/ou l'échangeur thermique (2).
  16. Procédé selon l'une des revendications 12 à 15, caractérisé en ce que, dans le cas d'un courant en excès qui ne doit pas être introduit dans le réseau, lors d'une surcapacité de courant dans le réseau électrique et/ou lors du fonctionnement de la centrale électrique à sa charge minimale, de l'énergie thermique est introduite dans l'accumulateur de chaleur (3), par l'intermédiaire d'un dispositif de chauffage (4) chauffé électriquement avec un courant correspondant et/ou le courant en excès et disposé dans l'accumulateur de chaleur (3), et est stockée dans l'accumulateur de chaleur (3).
  17. Procédé selon l'une des revendications 12 à 15, caractérisé en ce que, lors d'un redémarrage de la centrale électrique à partir de sa charge minimale, la chaleur stockée dans l'accumulateur de chaleur (3) est transférée vers le et/ou vers un deuxième circuit eau/vapeur (1, 7).
EP13164893.3A 2012-04-25 2013-04-23 Centrale alimentée par une énergie fossile avec accumulateur de chaleur Active EP2657466B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP17200082.0A EP3301266A3 (fr) 2012-04-25 2013-04-23 Centrale électrique à combustible fossile pourvue d'accumulateur thermique couplé directement ou indirectement au cycle de l'eau/de la vapeur

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102012103617.9A DE102012103617B4 (de) 2012-04-25 2012-04-25 Fossilbefeuertes Kraftwerk mit Wärmespeicher

Related Child Applications (2)

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EP17200082.0A Division EP3301266A3 (fr) 2012-04-25 2013-04-23 Centrale électrique à combustible fossile pourvue d'accumulateur thermique couplé directement ou indirectement au cycle de l'eau/de la vapeur
EP17200082.0A Division-Into EP3301266A3 (fr) 2012-04-25 2013-04-23 Centrale électrique à combustible fossile pourvue d'accumulateur thermique couplé directement ou indirectement au cycle de l'eau/de la vapeur

Publications (3)

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EP2657466A2 EP2657466A2 (fr) 2013-10-30
EP2657466A3 EP2657466A3 (fr) 2015-03-11
EP2657466B1 true EP2657466B1 (fr) 2019-06-12

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EP17200082.0A Withdrawn EP3301266A3 (fr) 2012-04-25 2013-04-23 Centrale électrique à combustible fossile pourvue d'accumulateur thermique couplé directement ou indirectement au cycle de l'eau/de la vapeur
EP13164893.3A Active EP2657466B1 (fr) 2012-04-25 2013-04-23 Centrale alimentée par une énergie fossile avec accumulateur de chaleur

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EP17200082.0A Withdrawn EP3301266A3 (fr) 2012-04-25 2013-04-23 Centrale électrique à combustible fossile pourvue d'accumulateur thermique couplé directement ou indirectement au cycle de l'eau/de la vapeur

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US9523285B2 (en) 2013-12-13 2016-12-20 Chromalox, Inc. Energy storage systems with medium voltage electrical heat exchangers
DE102014202277A1 (de) * 2014-02-07 2015-08-13 Siemens Aktiengesellschaft Energiespeicher zur Zwischenspeicherung elektrischer Energie
DE102014104806B4 (de) 2014-04-04 2016-11-10 Mitsubishi Hitachi Power Systems Europe Gmbh Verfahren zum Betrieb eines Kraftwerks mit elektrischer Unterstützung sowie diesbezügliches Kraftwerk
AT518186B1 (de) * 2016-06-10 2017-08-15 Technische Universität Wien Wärmekraftwerk und Verfahren zum Speichern von Wärme
CN107516905B (zh) * 2017-09-30 2023-09-01 北京北方三合能源技术有限公司 一种多元耦合储能系统
EP3746648B1 (fr) * 2018-01-31 2021-12-22 E2S Power Ag Dispositif et système de stockage d'énergie

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US4071079A (en) * 1974-07-31 1978-01-31 Sadao Shimoda Heat-storage unit and system
US4164848A (en) * 1976-12-21 1979-08-21 Paul Viktor Gilli Method and apparatus for peak-load coverage and stop-gap reserve in steam power plants
DE19512466C1 (de) * 1995-04-03 1996-08-22 Siemens Ag Verfahren zum Betreiben eines Abhitzedampferzeugers sowie danach arbeitender Abhitzedampferzeuger
US8261552B2 (en) * 2007-01-25 2012-09-11 Dresser Rand Company Advanced adiabatic compressed air energy storage system
DE102009060089A1 (de) * 2009-12-22 2011-06-30 Siemens Aktiengesellschaft, 80333 Solarthermisches Kraftwerk und Verfahren zum Betrieb eines solarthermischen Kraftwerks
US20120080161A1 (en) * 2010-10-04 2012-04-05 Edmund Joseph Kelly Thermal storage system

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Also Published As

Publication number Publication date
EP3301266A2 (fr) 2018-04-04
DE102012103617B4 (de) 2018-02-08
EP2657466A3 (fr) 2015-03-11
EP3301266A3 (fr) 2018-05-23
EP2657466A2 (fr) 2013-10-30
DE102012103617A1 (de) 2013-10-31

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