EP2621026A1 - Sealed plug method for sealing a plug - Google Patents
Sealed plug method for sealing a plug Download PDFInfo
- Publication number
- EP2621026A1 EP2621026A1 EP13152448.0A EP13152448A EP2621026A1 EP 2621026 A1 EP2621026 A1 EP 2621026A1 EP 13152448 A EP13152448 A EP 13152448A EP 2621026 A1 EP2621026 A1 EP 2621026A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- plug
- adhesive
- passage
- silicone
- sealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007789 sealing Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims abstract description 77
- 230000001070 adhesive effect Effects 0.000 claims abstract description 77
- 238000004804 winding Methods 0.000 claims abstract description 14
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 claims abstract description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 24
- 238000009413 insulation Methods 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000001723 curing Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000004033 plastic Substances 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000000565 sealant Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 125000006850 spacer group Chemical group 0.000 description 5
- 238000005382 thermal cycling Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004593 Epoxy Chemical class 0.000 description 2
- 240000005702 Galium aparine Species 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000012945 sealing adhesive Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229920001971 elastomer Chemical class 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000012812 sealant material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000013464 silicone adhesive Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/46—Bases; Cases
- H01R13/52—Dustproof, splashproof, drip-proof, waterproof, or flameproof cases
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/40—Securing contact members in or to a base or case; Insulating of contact members
- H01R13/405—Securing in non-demountable manner, e.g. moulding, riveting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R13/00—Details of coupling devices of the kinds covered by groups H01R12/70 or H01R24/00 - H01R33/00
- H01R13/46—Bases; Cases
- H01R13/52—Dustproof, splashproof, drip-proof, waterproof, or flameproof cases
- H01R13/5216—Dustproof, splashproof, drip-proof, waterproof, or flameproof cases characterised by the sealing material, e.g. gels or resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R43/00—Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors
- H01R43/005—Apparatus or processes specially adapted for manufacturing, assembling, maintaining, or repairing of line connectors or current collectors or for joining electric conductors for making dustproof, splashproof, drip-proof, waterproof, or flameproof connection, coupling, or casing
Definitions
- the invention relates to a sealed plug according to the preamble of patent claim 1 and a method for sealing a plug according to the preamble of patent claim 13.
- Control elements of the hydraulic system can be actuated electromagnetically.
- the valve has an encapsulated electromagnet with a coil, via the energization of which an armature is moved, which carries a valve piston.
- a position of the valve piston can be precisely adjusted.
- a housing passing through the plug is provided on the housing of the electromagnet, which preferably consists of plastic and molded onto the housing.
- the design text DE 1 148 613 from 1963 recommends as sealing compound for the plug to be cast silicone, which should have the tendency to adhere to the touched materials.
- sticky petroleum compounds or rubber or epoxy compounds are suggested.
- a disadvantage of the proposed solutions is that the substances proposed as sealant materials are not specified.
- a disadvantage of the proposed epoxy compounds is that they are subject to shrinkage, in particular during thermal cycling, which can lead to a separation and thus to leakage at a boundary layer between pin and sealant.
- a disadvantage of the solution without sealant is that the plastic surrounding the pins is subject to shrinkage over its lifetime.
- the plastic is only slightly elastic, so that it can come in this solution for recurring mechanical stress or thermal cycling to the leakage of the passage.
- the invention has the object to provide a plug with an improved tightness against ingress of moisture.
- the plug according to the invention for the electrical supply of an aggregate of the hydraulic system can be arranged on a housing of this unit.
- a plug base of the plug is penetrated by at least one current path.
- This passage of the at least one flow path through the plug base is sealed with a silicone-containing compound.
- this mass is an adhesive, and has a high adhesion. This strong adhesion can ensure that under adverse operating conditions in which the current path is moved, the sealing mass still adheres to the current path. A detachment from the flow path, i. a gap formation between the flow path and the sealant is thus prevented. This allows the unit to be permanently sealed against moisture. In connection with the high adhesiveness of the mass or the adhesive is preferred when the adhesive has a high flexibility.
- Another advantage of the adhesive used is that at a thermal cycling of the connector, which leads to stresses in the boundary layer between Stormbahn and adhesive due to different thermal expansion coefficients of the sealant or the adhesive and the current path, the tightness of the plug is still maintained.
- Plug base is understood to be a region of a housing of the plug through which a current path passes.
- the unit is preferably connected via the plug with a power source or an electrical control unit.
- the unit is a coil of an electromagnet or a control cabinet. It is preferred if via the solenoid, a valve, in particular a pilot valve of the mobile hydraulics, can be actuated.
- the plug base of the plug is filled with the adhesive at least in a region of the passage of the at least one flow path.
- the pouring is manufacturing technology little expensive, so that the seal is inexpensive to produce.
- the silicone-containing adhesive proves to be very advantageous, since due to its low surface energy in a very narrow Gap penetrates, so that it is sealingly filled with the adhesive or filled.
- the adhesive is one-component, which represents a reduction of the expense compared to a use of two- or multi-component adhesives or adhesives with catalyst.
- acetoxy adhesive which, at least in the uncured state, has an acetoxy group.
- the adhesive it is light-cured, in particular UV-light-cured.
- the adhesive may be moisture cured.
- the adhesive is primarily light-cured or UV-light-cured and secondarily moisture-cured.
- the adhesive is in a region near the plug bottom, i. near the passage of the current path through the plug base or the plug housing, tough or viscous.
- the sealing adhesive has a higher elasticity and is also more adhesive. These properties can be achieved, for example, by the adhesive in this area is not fully cured.
- an insulation resistance via the sealed passage of the at least one current path at an applied voltage of 500 volts has a value greater than 0.5 MIO (megohms). This value is particularly preferably about 1 M ⁇ .
- a coil winding is arranged on this, so that a device-particularly compact and space-saving arrangement of a coil of an electromagnet is possible.
- the plug according to the invention is arranged, in particular molded, on a housing of an aggregate of the hydraulic system for the electrical supply of the unit.
- the unit is preferably a coil of an electromagnet or a control cabinet, wherein via the solenoid preferably a valve, in particular a pilot valve of the mobile hydraulics can be actuated.
- a valve in particular a pilot valve of the mobile hydraulics
- the housing in the mobile hydraulics, when the housing is exposed to changing operating conditions over water and especially under water. This applies, for example, to mobile working machines that are used in flood protection to rescue people. It may happen that electrically or electrohydraulically actuated valves or their electromagnets get under water. The tightness of their plugs for power supply is crucial.
- a method according to the invention for sealing a plug bottom of a plug which is penetrated by at least one current path, or for sealing a passage of the at least one current path through the plug base, wherein an aggregate of the hydraulics can be supplied electrically via the plug comprises the step of: sealing the passage with a plug silicone-containing adhesive.
- the sealing is preferably carried out by filling a gap formed in a region of the passage between the at least one flow path and the plug base. This gap may be formed in particular as a gap or as an annular gap.
- the sealing or the filling can be done in particular by pouring the plug base with the silicone-containing adhesive in the region of the passage of the at least one current path through the plug base.
- the adhesive Due to the strong adhesion of the adhesive, in particular to the flow path and a surface of the plug base or of the passage, it can be ensured that under disadvantageous operating conditions in which the flow path is moved, the sealing mass of the adhesive still adheres to the flow path. A detachment of the adhesive from the flow path, or a gap formation between the flow path and the sealant, is thus prevented. As a result, the unit can be permanently sealed in the area of the current path against ingress of moisture. In conjunction with the high adhesiveness of the adhesive, it is preferred if the adhesive has high flexibility or elasticity. In this way, the adhesion of the adhesive to the current path is further improved. Another advantage of the adhesive used is that at a thermal cycling of the plug, which leads to stresses in the region of the boundary layer between the current path and adhesive due to different thermal expansion coefficients of the sealant or the adhesive and the current path, the tightness of the plug is still maintained.
- silicones are advantageous to use as an adhesive, since they have a low surface energy in the liquid state and can therefore very well wet the plug base to be sealed and the current path to be sealed.
- the casting of the plug base of the plug is a procedurally well controllable step. However, it must be ensured that the components to be glued or sealed the current path and the plug base are clean.
- the silicone-containing adhesive is preferably one-component in order to keep the procedural effort low. In this case, the adhesive preferably has an acetoxy group.
- the silicone-containing adhesive is cured by light, in particular by ultraviolet light.
- the method according to the invention after or during the step of curing the silicone-containing adhesive by light as a further step, a curing of the silicone-containing adhesive by moisture, in particular by humidity or water vapor, on. This ensures that areas that are not accessible or accessible during curing with light, harden by the naturally occurring in the ambient air humidity.
- FIG. 1 shows a plug 1 for powering a coil of an electromagnet (not shown), via which a pilot valve of the mobile hydraulics can be controlled in a front view.
- the plug 1 is made of plastic as an injection molded part. It has a substantially circular cylindrical plug housing 2, which is provided for arrangement in a corresponding outbreak of a housing of the electromagnet (not shown).
- the connector housing 2 has an end face 4, from which, the viewer of the FIG. 1 opposite, a connector device 6 extends.
- the connector device 6 has an approximately rectangular connector collar 8 with rounded corners.
- two current paths 12 configured as pins and four smaller spacers 14 are symmetrical to a vertical axis 16 of the plug 1 arranged.
- a Verrastungslic 20 is arranged on the plug collar 8.
- the Verrastungslic 20 has at its in FIG. 1 lower, open side on a guide groove 22, which on both sides to the vertical axis 16 in the direction of a FIG. 1 upper side of the plug 1 is further recessed, and in this way forms a Verrastungsnut 24.
- the plug base 10 of the plug 1 is in this case filled with an adhesive 26, that the spacers 14 and the current paths 12 are each connected to its radially outer surface cohesively with the adhesive 26.
- FIG. 2 shows the embodiment of the plug according to FIG. 1 in a longitudinal section.
- the plug 1 extends in FIG. 2 from the plug collar 8 right to the left-side connector housing 2. Approximately in the middle between the plug base 10 is arranged. Radially circumferentially on the plug base 10, an O-ring groove 28 is formed, which is provided for receiving an O-ring or sealing ring (not shown).
- the plug 1 is in a built-in state, ie when it is attached to a housing of the coil or the electromagnet (not shown), arranged at the level of the plug base 10 or at the level of the O-ring groove 28 on the housing.
- the housing with the connector 1 waterproof or moisture-proof sealed.
- the two current paths 12 pass through the plug 1 or its plug base 10 in FIG FIG. 2 from right to left. With a in FIG. 2 not shown left end portion of the current paths 12 dip this in a winding body 30 a.
- This winding body 30 has a winding groove 32 which opens radially outwards and into which a coil winding 34 is accommodated.
- This coil winding 34 is connected to the end portions of the current paths 12, which are pressed into the plastic of the winding body 30, or contacted by these. Via the current paths 12, a power supply of the coil winding 37 is thus produced.
- a pole plate 36 is arranged, which serves as a magnetic return plate for closing the magnetic circuit.
- FIG. 2 right above is the Verrastungs phenomenon 20, via which a plug of the power source (not shown) with the plug 1 and the connector device 6 is detachably connected, arranged.
- the plug of the power source must be approximately coaxially inserted into a framed by the plug collar 8 connector receptacle 44. This takes place until one end of the plug, not shown, comes into abutment with the spacers 14 of the plug 1.
- the spacers 14 of the plug 1 are elastically deformable in the axial direction, so that the plug, not shown, can continue to penetrate further or deeper into the plug receptacle 44 by the application of a certain force.
- the latching takes place when the Verrastungsnase engages behind a Verrastungskante 38 Verrastungsaus Principleung 40 of Verrastungslvess 20.
- the plug not shown, with a certain bias in the connector receptacle 44 can be fixed.
- the plug base 10 of the plug 1 is in FIG. 2 extended to the right by a base rib 42. This has the task to clamp the penetrating current paths 12.
- a movement of the current paths 12 is prevented to a certain extent.
- the plug-in collar 8 encompassed plug base 10 is filled with a silicone-containing adhesive 26.
- a silicone-containing adhesive 26 This is a single-component acetoxy silicone adhesive LOCTITE ® 5091 TM (Technical Data Sheet December 2007).
- the one-component mold proves to be advantageous during the filling of the plug base 10, since no mixing with a second Component or with a catalyst is required.
- a curing of the adhesive 26 takes place during the manufacturing process or after filling by UV light. Already under normal processing conditions, the adhesive 26 is exposed to sufficient UV radiation to completely cure at least on the surface.
- the adhesive 26 has a further positive and advantageous property, since it cures by surface or atmospheric moisture even in shadow areas into which no UV radiation can get. A complete cure of the adhesive is achieved after about 72 hours at ambient temperature.
- the adhesive used 26 is highly flexible, whereby the splice has a shock-absorbing property and a good load capacity. A transverse movement of the current paths 12 can be well compensated not only because of the adhesion of the adhesive 26, but also due to the elasticity of the adhesive 26. At the interfaces between the current paths 12 and the adhesive 26 so a gap formation is effectively prevented.
- FIGS. 3 and 4 schematically a preferably designed as dosing tip dosing device 50 for the metered and precisely placed introduction of the liquid adhesive 26 in the passage region of the current paths 12 in the region of the plug base 10 is shown.
- the metering device 50 is thereby introduced with respect to their position in the region of the connector receptacle 44, that due to the amount and the flow properties of the adhesive 26 is a uniform filling of the gap in the passage region of the current paths 12 and to the outside a homogeneous smooth surface of the adhesive 26th formed.
- FIG. 2 schematically illustrates a curing device 51, preferably designed as a UV light source, for curing the liquid adhesive 26.
- a curing device 51 preferably designed as a UV light source, for curing the liquid adhesive 26.
- the adhesive used 26 has advantageous and positive properties. This is shown by stress tests, which have the task of investigating the tightness of the passage of the current paths 12 through the plug base 10.
- the heated by a two-hour storage in a climatic chamber at 140 ° C plug 1 are suddenly immersed in 20 ° cold water. There they remained at one meter depth for a period of one hour.
- In a subsequent storage of the specimens in a climatic chamber and at 20 ° was examined to what extent water has come from the plug receptacle 44 to the other side of the plug 1 in the region of the winding body 30. Even after 20 cycles, no leaks occurred.
- An insulation resistance of the sealing adhesive 26 was greater than 1 M ⁇ in each case.
- a leakage current was less than 10 ⁇ A at an applied voltage of 500 volts.
- the plug 1 for a coil of an electromagnet of a pilot valve of the mobile hydraulics plug 1 according to the invention can be used with advantage everywhere where a watertight implementation of electrical current paths or pins is required.
- the plug according to the invention proves to be particularly advantageous when used on pilot valves for mobile control blocks.
- the plug according to the invention has significantly better properties of the seal with temperature changes and mechanical stress.
- a plug for the electrical supply of an aggregate of the hydraulic which can be arranged or arranged on a housing of such an aggregate.
- a plug base of the plug is penetrated by a current path and sealed in a region of this passage with a silicone-containing compound against moisture penetration.
- this composition is an adhesive with high adhesion forces.
- a method for sealing a plug-in base of a plug which is penetrated by a current path and via which an aggregate of the hydraulics can be supplied electrically.
- the method has a step "sealing a passage of the current path through the plug base with a silicone-containing adhesive" on.
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Connector Housings Or Holding Contact Members (AREA)
- Magnetically Actuated Valves (AREA)
- Electromagnets (AREA)
Abstract
Description
Die Erfindung betrifft einen abgedichteten Stecker gemäß dem Oberbegriff des Patentanspruchs 1 und ein Verfahren zur Abdichtung eines Steckers gemäß dem Oberbegriff des Patentanspruchs 13.The invention relates to a sealed plug according to the preamble of
Steuerungselemente der Hydraulik, beispielsweise Ventile, können elektromagnetisch betätigt werden. Hierzu weist das Ventil einen gekapselten Elektromagneten mit einer Spule auf, über deren Bestromung ein Anker bewegt wird, der einen Ventilkolben mitnimmt. Auf diese Weise ist eine Stellung des Ventilkolbens präzise einstellbar. Zur Stromversorgung der Spule ist am Gehäuse des Elektromagneten ein das Gehäuse durchsetzender Stecker vorgesehen, der bevorzugt aus Kunststoff besteht und am Gehäuse angespritzt ist. Mit einer Stromquelle verbindbare Strombahnen beziehungsweise Pins des Steckers durchgreifen einen Steckerboden des Steckers von einer Außenseite hin zu einer Innenseite des Gehäuses, wo sie mit der Spule verbunden sind.Control elements of the hydraulic system, such as valves, can be actuated electromagnetically. For this purpose, the valve has an encapsulated electromagnet with a coil, via the energization of which an armature is moved, which carries a valve piston. In this way, a position of the valve piston can be precisely adjusted. To power the coil, a housing passing through the plug is provided on the housing of the electromagnet, which preferably consists of plastic and molded onto the housing. With a current source connectable current paths or pins of the plug pass through a plug bottom of the plug from an outside to an inside of the housing, where they are connected to the coil.
Es ist bekannt, den Steckerboden des Steckers mit einer dielektrischen Dichtmasse auszugießen, um den Durchtritt der Strombahnen gegen eindringende Feuchtigkeit abzudichten. Hierbei kommen herkömmlicher Weise Kunststoffe, Epoxydharz oder Silikonkautschuk zum Einsatz.It is known to pour the plug bottom of the plug with a dielectric sealant to seal the passage of the current paths against moisture penetration. Here conventionally plastics, epoxy resin or silicone rubber are used.
Die Auslegungsschrift
Nachteilig an der vorgeschlagenen Lösungen ist, dass die als Dichtmasse vorgeschlagenen Stoffe nicht spezifiziert sind. Nachteilig an den vorgeschlagenen Epoxy-Verbindungen ist, dass sie insbesondere bei einer Temperaturwechselbeanspruchung einer Schwindung unterliegen, die an einer Grenzschicht zwischen Pin und Dichtmasse zu einer Ablösung und damit zur Undichtigkeit führen kann.A disadvantage of the proposed solutions is that the substances proposed as sealant materials are not specified. A disadvantage of the proposed epoxy compounds is that they are subject to shrinkage, in particular during thermal cycling, which can lead to a separation and thus to leakage at a boundary layer between pin and sealant.
Die Patentschrift
Nachteilig an der Lösung ohne Dichtmasse ist, dass der die Pins umgebende Kunststoff über seine Lebensdauer einer Schwindung unterliegt. Zudem ist der Kunststoff nur wenig elastisch, so dass es auch bei dieser Lösung bei wiederkehrenden mechanischen Belastungen oder bei einer Temperaturwechselbeanspruchung zur Undichtigkeit des Durchtritts kommen kann.A disadvantage of the solution without sealant is that the plastic surrounding the pins is subject to shrinkage over its lifetime. In addition, the plastic is only slightly elastic, so that it can come in this solution for recurring mechanical stress or thermal cycling to the leakage of the passage.
Dem gegenüber liegt der Erfindung die Aufgabe zugrunde, einen Stecker mit einer verbesserten Dichtheit gegen Eindringen von Feuchtigkeit zu schaffen.In contrast, the invention has the object to provide a plug with an improved tightness against ingress of moisture.
Diese Aufgabe wird gelöst durch einen abgedichteten Stecker mit den Merkmalen des Patentanspruchs 1, sowie durch ein Verfahren zur Abdichtung eines Steckers mit den Merkmalen des Patentanspruchs 13.This object is achieved by a sealed plug with the features of
Vorteilhafte Weiterbildungen der Erfindung sind in den abhängigen Patentansprüchen beschrieben.Advantageous developments of the invention are described in the dependent claims.
Der erfindungsgemäße Stecker zur elektrischen Versorgung eines Aggregates der Hydraulik ist an einem Gehäuse dieses Aggregates anordbar. Dabei ist ein Steckerboden des Steckers von wenigstens einer Strombahn durchgriffen. Dieser Durchtritt der wenigstens einen Strombahn durch den Steckerboden ist mit einer silikonhaltigen Masse abgedichtet. Erfindungsgemäß ist diese Masse ein Klebstoff, und weist eine hohe Haftfähigkeit auf. Durch diese starke Anhaftung kann sichergestellt werden, dass unter nachteiligen Betriebsbedingungen, in denen die Strombahn bewegt wird, die dichtende Masse nach wie vor an der Strombahn haftet. Eine Ablösung von der Strombahn, d.h. eine Spaltbildung zwischen der Strombahn und der Dichtmasse, wird so verhindert. Dadurch kann das Aggregat nachhaltig gegen Feuchtigkeit abgedichtet werden. In Verbindung mit der großen Haftfähigkeit der Masse beziehungsweise des Klebstoffs wird bevorzugt, wenn der Klebstoff eine hohe Flexibilität aufweist. Auf diese Weise ist die Anhaftung des Klebstoffes an der Strombahn weiter verbessert. Ein weiterer Vorteil des verwendeten Klebstoffes ist, dass bei einer Temperaturwechselbeanspruchung des Steckers, die aufgrund verschiedener Temperaturausdehnungskoeffizienten der Dichtmasse beziehungsweise des Klebstoffes und der Strombahn zu Spannungen im Bereich der Grenzschicht zwischen Stormbahn und Klebstoff führt, die Dichtheit des Steckers weiterhin erhalten bleibt.The plug according to the invention for the electrical supply of an aggregate of the hydraulic system can be arranged on a housing of this unit. In this case, a plug base of the plug is penetrated by at least one current path. This passage of the at least one flow path through the plug base is sealed with a silicone-containing compound. According to the invention, this mass is an adhesive, and has a high adhesion. This strong adhesion can ensure that under adverse operating conditions in which the current path is moved, the sealing mass still adheres to the current path. A detachment from the flow path, i. a gap formation between the flow path and the sealant is thus prevented. This allows the unit to be permanently sealed against moisture. In connection with the high adhesiveness of the mass or the adhesive is preferred when the adhesive has a high flexibility. In this way, the adhesion of the adhesive to the current path is further improved. Another advantage of the adhesive used is that at a thermal cycling of the connector, which leads to stresses in the boundary layer between Stormbahn and adhesive due to different thermal expansion coefficients of the sealant or the adhesive and the current path, the tightness of the plug is still maintained.
Als Steckerboden wird ein Bereich eines Gehäuses des Steckers verstanden, durch den eine Strombahn durchtritt.Plug base is understood to be a region of a housing of the plug through which a current path passes.
Das Aggregat ist über den Stecker bevorzugt mit einer Stromquelle oder einer elektrischen Steuereinheit verbindbar. Besonders bevorzugt ist das Aggregat eine Spule eines Elektromagneten oder ein Schaltschrank. Dabei ist es bevorzugt, wenn über den Elektromagnet ein Ventil, insbesondere ein Pilotventil der Mobilhydraulik, betätigbar ist.The unit is preferably connected via the plug with a power source or an electrical control unit. Particularly preferably, the unit is a coil of an electromagnet or a control cabinet. It is preferred if via the solenoid, a valve, in particular a pilot valve of the mobile hydraulics, can be actuated.
In einer vorteilhaften Weiterbildung des Steckers ist der Steckerboden des Steckers zumindest in einem Bereich des Durchtritts der wenigstens einen Strombahn mit dem Klebstoff ausgegossen. Das Ausgießen ist dabei fertigungstechnisch wenig aufwendig, wodurch die Abdichtung kostengünstig herstellbar ist.In an advantageous development of the plug, the plug base of the plug is filled with the adhesive at least in a region of the passage of the at least one flow path. The pouring is manufacturing technology little expensive, so that the seal is inexpensive to produce.
Bei Steckern, die gröbere Fertigungstoleranzen aufweisen und daher einen zwischen der wenigstens einen Strombahn und dem Steckerboden angeordneten Spalt, insbesondere einen Ringspalt oder einen Zwischenraum, aufweisen, erweist sich der silikonhaltige Klebstoff als sehr vorteilhaft, da er aufgrund seiner geringen Oberflächenenergie auch in einen sehr engen Spalt eindringt, so dass dieser dichtend mit dem Klebstoff ausgegossen beziehungsweise aufgefüllt ist.For plugs that have coarse manufacturing tolerances and therefore have a gap arranged between the at least one flow path and the plug bottom, in particular an annular gap or a gap, the silicone-containing adhesive proves to be very advantageous, since due to its low surface energy in a very narrow Gap penetrates, so that it is sealingly filled with the adhesive or filled.
In einer besonders bevorzugten Weiterbildung des Steckers ist der Klebstoff einkomponentig, was gegenüber einer Verwendung von zwei- oder mehrkomponentigen Klebstoffen oder Klebstoffen mit Katalysator eine Verringerung des Aufwandes darstellt.In a particularly preferred embodiment of the plug, the adhesive is one-component, which represents a reduction of the expense compared to a use of two- or multi-component adhesives or adhesives with catalyst.
Besonders geeignet ist hierfür ein Acetoxy-Klebstoff, der zumindest in unausgehärtetem Zustand eine Acetoxygruppe aufweist.Particularly suitable for this purpose is an acetoxy adhesive which, at least in the uncured state, has an acetoxy group.
In einer besonders bevorzugten Variante des Klebstoffes ist dieser licht-, insbesondere UV-lichtgehärtet. Alternativ oder ergänzend dazu kann der Klebstoff feuchtigkeitsgehärtet sein. Besonders bevorzugt ist der Klebstoff dabei primär lichtbeziehungsweise UV-lichtgehärtet und sekundär feuchtigkeitsgehärtet.In a particularly preferred variant of the adhesive, it is light-cured, in particular UV-light-cured. Alternatively or additionally, the adhesive may be moisture cured. Particularly preferably, the adhesive is primarily light-cured or UV-light-cured and secondarily moisture-cured.
In einer bevorzugten Variante des Steckers ist der Klebstoff in einem Bereich nahe dem Steckerboden, d.h. nahe dem Durchtritt der Strombahn durch den Steckerboden beziehungsweise das Steckergehäuse, zäh oder zähflüssig. Dadurch weist der dichtende Klebstoff dort eine höhere Elastizität auf und ist zudem adhäsiver. Diese Eigenschaften können beispielsweise erreicht werden, indem der Klebstoff in diesem Bereich nicht ganz ausgehärtet ist.In a preferred variant of the plug, the adhesive is in a region near the plug bottom, i. near the passage of the current path through the plug base or the plug housing, tough or viscous. As a result, the sealing adhesive has a higher elasticity and is also more adhesive. These properties can be achieved, for example, by the adhesive in this area is not fully cured.
In einer besonders vorteilhaften Weiterbildung des Steckers weist ein Isolationswiderstand über den abgedichteten Durchtritt der wenigstens einen Strombahn bei einer angelegten Spannung von 500 Volt einen Wert größer als 0,5 MIO (Megaohm) auf. Besonders bevorzugt ist dieser Wert etwa 1 MΩ.In a particularly advantageous development of the plug, an insulation resistance via the sealed passage of the at least one current path at an applied voltage of 500 volts has a value greater than 0.5 MIO (megohms). This value is particularly preferably about 1 MΩ.
In einer besonders vorteilhaften Weiterbildung des Steckers ist an diesem eine Spulenwicklung angeordnet, so dass eine vorrichtungstechnisch besonders kompakte und bauraumsparende Anordnung einer Spule eines Elektromagneten ermöglicht ist.In a particularly advantageous embodiment of the plug, a coil winding is arranged on this, so that a device-particularly compact and space-saving arrangement of a coil of an electromagnet is possible.
Besonders vorteilhaft erweist es sich, wenn der erfindungsgemäße Stecker an einem Gehäuse eines Aggregates der Hydraulik zur elektrischen Versorgung des Aggregates angeordnet, insbesondere angespritzt ist.It proves to be particularly advantageous when the plug according to the invention is arranged, in particular molded, on a housing of an aggregate of the hydraulic system for the electrical supply of the unit.
Dabei ist das Aggregat bevorzugt eine Spule eines Elektromagneten oder ein Schaltschrank, wobei über den Elektromagnet bevorzugt ein Ventil, insbesondere ein Pilotventil der Mobilhydraulik betätigbar ist. Besonders vorteilhaft ist dabei die Verwendung des Gehäuses in der Mobilhydraulik, wenn das Gehäuse wechselnden Betriebszuständen über Wasser und insbesondere unter Wasser ausgesetzt ist. Dies betrifft beispielsweise mobile Arbeitsmaschinen, die im Hochwasserschutz zur Bergung von Personen eingesetzt werden. Dabei kann es vorkommen, dass elektrisch oder elektrohydraulisch betätigte Ventile beziehungsweise deren Elektromagneten unter Wasser geraten. Dabei kommt der Dichtheit von deren Steckern zur Stromversorgung eine entscheidende Bedeutung zu.In this case, the unit is preferably a coil of an electromagnet or a control cabinet, wherein via the solenoid preferably a valve, in particular a pilot valve of the mobile hydraulics can be actuated. Particularly advantageous is the use of the housing in the mobile hydraulics, when the housing is exposed to changing operating conditions over water and especially under water. This applies, for example, to mobile working machines that are used in flood protection to rescue people. It may happen that electrically or electrohydraulically actuated valves or their electromagnets get under water. The tightness of their plugs for power supply is crucial.
Ein erfindungsgemäßes Verfahren zur Abdichtung eines von wenigstens einer Strombahn durchgriffenen Steckerbodens eines Steckers, beziehungsweise zur Abdichtung eines Durchtritts der wenigstens einen Strombahn durch den Steckerboden, wobei über den Stecker ein Aggregat der Hydraulik elektrisch versorgbar ist, weist den Schritt auf: Abdichtung des Durchtritts mit einem silikonhaltigen Klebstoff. Dabei erfolgt die Abdichtung bevorzugt durch eine Auffüllung eines in einem Bereich des Durchtritts zwischen der wenigstens einen Strombahn und dem Steckerboden ausgebildeten Spalts. Dieser Spalt kann insbesondere als Zwischenraum oder als Ringspalt ausgebildet sein. Die Abdichtung oder die Auffüllung kann insbesondere über ein Vergießen des Steckerbodens mit dem silikonhaltigen Klebstoff im Bereich des Durchtritts der wenigstens einen Strombahn durch den Steckerboden erfolgen.A method according to the invention for sealing a plug bottom of a plug which is penetrated by at least one current path, or for sealing a passage of the at least one current path through the plug base, wherein an aggregate of the hydraulics can be supplied electrically via the plug, comprises the step of: sealing the passage with a plug silicone-containing adhesive. In this case, the sealing is preferably carried out by filling a gap formed in a region of the passage between the at least one flow path and the plug base. This gap may be formed in particular as a gap or as an annular gap. The sealing or the filling can be done in particular by pouring the plug base with the silicone-containing adhesive in the region of the passage of the at least one current path through the plug base.
Durch die starke Anhaftung des Klebstoffes insbesondere an der Strombahn und einer Oberfläche des Steckerbodens beziehungsweise des Durchtritts kann sichergestellt werden, dass unter nachteiligen Betriebsbedingungen, in denen die Strombahn bewegt wird, die dichtende Masse des Klebstoffs nach wie vor an der Strombahn haftet. Eine Ablösung des Klebstoffs von der Strombahn, beziehungsweise eine Spaltbildung zwischen der Strombahn und der Dichtmasse, wird so verhindert. Dadurch kann das Aggregat im Bereich der Strombahn nachhaltig gegen ein Eindringen von Feuchtigkeit abgedichtet werden. In Verbindung mit der großen Haftfähigkeit des Klebstoffs ist es bevorzugt, wenn der Klebstoff eine hohe Flexibilität beziehungsweise Elastizität aufweist. Auf diese Weise ist die Anhaftung des Klebstoffes an der Strombahn weiter verbessert. Ein weiterer Vorteil des verwendeten Klebstoffes ist, dass bei einer Temperaturwechselbeanspruchung des Steckers, die aufgrund verschiedener Temperaturausdehnungskoeffizienten der Dichtmasse beziehungsweise des Klebstoffes und der Strombahn zu Spannungen im Bereich der Grenzschicht zwischen Strombahn und Klebstoff führt, die Dichtheit des Steckers weiterhin erhalten bleibt.Due to the strong adhesion of the adhesive, in particular to the flow path and a surface of the plug base or of the passage, it can be ensured that under disadvantageous operating conditions in which the flow path is moved, the sealing mass of the adhesive still adheres to the flow path. A detachment of the adhesive from the flow path, or a gap formation between the flow path and the sealant, is thus prevented. As a result, the unit can be permanently sealed in the area of the current path against ingress of moisture. In conjunction with the high adhesiveness of the adhesive, it is preferred if the adhesive has high flexibility or elasticity. In this way, the adhesion of the adhesive to the current path is further improved. Another advantage of the adhesive used is that at a thermal cycling of the plug, which leads to stresses in the region of the boundary layer between the current path and adhesive due to different thermal expansion coefficients of the sealant or the adhesive and the current path, the tightness of the plug is still maintained.
Mit Vorteil werden Silikone als Klebstoff eingesetzt, da sie im flüssigen Zustand eine geringe Oberflächenenergie aufweisen, und daher den abzudichtenden Steckerboden und die abzudichtende Strombahn sehr gut benetzen können. Das Vergießen des Steckerbodens des Steckers stellt einen verfahrenstechnisch gut beherrschbaren Schritt dar. Dabei muss jedoch sichergestellt werden, dass die zu verklebenden beziehungsweise abzudichtenden Komponenten der Strombahn und des Steckerbodens sauber sind. Der silikonhaltige Klebstoff ist dabei bevorzugt einkomponentig, um den verfahrenstechnischen Aufwand gering zu halten. Dabei weist der Klebstoff bevorzugt eine Acetoxygruppe auf.It is advantageous to use silicones as an adhesive, since they have a low surface energy in the liquid state and can therefore very well wet the plug base to be sealed and the current path to be sealed. The casting of the plug base of the plug is a procedurally well controllable step. However, it must be ensured that the components to be glued or sealed the current path and the plug base are clean. The silicone-containing adhesive is preferably one-component in order to keep the procedural effort low. In this case, the adhesive preferably has an acetoxy group.
Besonders vorteilhaft ist es, wenn nach der Abdichtung des Durchtritts der wenigstens einen Strombahn durch den Steckerboden mit dem silikonhaltigen Klebstoff als weiterer Schritt ein Aushärten des silikonhaltigen Klebstoffes durch Licht, insbesondere durch ultraviolettes Licht, erfolgt.It is particularly advantageous if after sealing the passage of the at least one current path through the plug base with the silicone-containing adhesive as a further step, the silicone-containing adhesive is cured by light, in particular by ultraviolet light.
Alternativ oder ergänzend dazu weist das erfindungsgemäße Verfahren nach oder während dem Schritt des Aushärtens des silikonhaltigen Klebstoffs durch Licht als weiteren Schritt ein Aushärten des silikonhaltigen Klebstoffs durch Feuchtigkeit, insbesondere durch Luftfeuchtigkeit beziehungsweise Wasserdampf, auf. Dadurch ist gewährleistet, dass Bereiche, die während des Aushärtens mit Licht nicht erreichbar sind oder erreichbar waren, durch die in der Umgebungsluft natürlich vorkommende Luftfeuchtigkeit aushärten.Alternatively or additionally, the method according to the invention, after or during the step of curing the silicone-containing adhesive by light as a further step, a curing of the silicone-containing adhesive by moisture, in particular by humidity or water vapor, on. This ensures that areas that are not accessible or accessible during curing with light, harden by the naturally occurring in the ambient air humidity.
Im Folgenden wird ein Ausführungsbeispiel eines erfindungsgemäßen Steckers anhand der Figuren näher erläutert. Es zeigt:
-
Fig. 1 einen Stecker in einer Vorderansicht; -
den Stecker gemäßFigur 2 in einem Längsschnitt;Figur 1 -
Figur 3 u. 4 den Stecker gemäß mit einer Vorrichtung zum Einbringen des Klebers; undFigur 1 und 2 -
Figur 5 u. 6 den Stecker gemäß mit einer Vorrichtung zum Aushärten des Klebers.Figur 1 und 2
-
Fig. 1 a plug in a front view; -
FIG. 2 according to the plugFIG. 1 in a longitudinal section; -
FIG. 3 u. 4 the plug according toFIGS. 1 and 2 with a device for introducing the adhesive; and -
FIG. 5 u. 6 the plug according toFIGS. 1 and 2 with a device for curing the adhesive.
Der Stecker 1 erstreckt sich in
Die beiden Strombahnen 12 durchsetzen den Stecker 1 beziehungsweise dessen Steckerboden 10 in
Radial innen am Steckergehäuse 2 ist eine Polscheibe 36 angeordnet, die als magnetisches Rückführungsblech zum Schließen des magnetischen Kreises dient.Radially inside the
In
Um zu verhindern, dass von außen (in
In den
In den
Nicht nur bei den besprochenen mechanischen Belastungen sondern auch bei einer Temperaturwechselbeanspruchung des Steckers 1 hat der verwendete Klebstoff 26 vorteilhafte und positive Eigenschaften. Dies zeigen Belastungstests, die zur Aufgabe haben, die Dichtheit des Durchtritts der Strombahnen 12 durch den Steckerboden 10 zu untersuchen. Dabei werden die durch eine zweistündige Lagerung in einer Klimakammer auf 140 °C erhitzten Stecker 1 schlagartig in 20° kaltes Wasser getaucht. Dort verblieben sie in einem Meter Tiefe für eine Zeitdauer von einer Stunde. Bei einer anschließenden Lagerung der Prüflinge in einer Klimakammer und bei 20° wurde untersucht, inwiefern Wasser von der Steckeraufnahme 44 auf die andere Seite des Steckers 1 im Bereich des Wicklungskörpers 30 gelangt ist. Auch nach 20 Zyklen traten dabei keine Undichtigkeiten auf. Ein Isolationswiderstand des abdichtenden Klebstoffs 26 war dabei in jedem Fall größer 1 MΩ. Ein Leckstrom war kleiner als 10 µA bei einer angelegten Spannung von 500 Volt.Not only in the discussed mechanical loads but also in a thermal cycling of the
Abweichend von der Verwendung des Steckers 1 für eine Spule eines Elektromagneten eines Pilotventils der Mobilhydraulik kann der erfindungsgemäße Stecker 1 mit Vorteil überall dort verwendet werden, wo eine wasserdichte Durchführung von elektrischen Strombahnen beziehungsweise Pins erforderlich ist. Ganz besonders vorteilhaft erweist sich der erfindungsgemäße Stecker bei einer Verwendung an Pilotventilen für Mobilsteuerblöcke. Im Gegensatz zu herkömmlich vergossenen Böden von Steckern, die mit Epoxydharz oder Siloprenmasse abgedichtet sind, weist der erfindungsgemäße Stecker bedeutend bessere Eigenschaften der Abdichtung bei Temperaturwechsel und bei mechanischer Beanspruchung auf.Notwithstanding the use of the
Offenbart ist ein Stecker zur elektrischen Versorgung eines Aggregates der Hydraulik, der an einem Gehäuse eines derartigen Aggregates anordbar ist oder angeordnet ist. Ein Steckerboden des Steckers ist dabei von einer Strombahn durchgriffen und in einem Bereich dieses Durchtritts mit einer silikonhaltigen Masse gegen eindringende Feuchtigkeit abgedichtet. Erfindungsgemäß ist diese Masse ein Klebstoff mit hohen Adhäsionskräften.Disclosed is a plug for the electrical supply of an aggregate of the hydraulic, which can be arranged or arranged on a housing of such an aggregate. A plug base of the plug is penetrated by a current path and sealed in a region of this passage with a silicone-containing compound against moisture penetration. According to the invention, this composition is an adhesive with high adhesion forces.
Weiterhin ist offenbart ein Gehäuse eines Aggregates der Hydraulik mit einem derartigen Stecker.Furthermore, a housing of an aggregate of the hydraulic system with such a plug is disclosed.
Weiterhin ist offenbart ein Verfahren zur Abdichtung eines von einer Strombahn durchgriffenen Steckerbodens eines Steckers, über den ein Aggregat der Hydraulik elektrisch versorgbar ist. Erfindungsgemäß weist das Verfahren dabei einen Schritt "Abdichtung eines Durchtritts der Strombahn durch den Steckerboden mit einem silikonhaltigen Klebstoff" auf.Furthermore, a method is disclosed for sealing a plug-in base of a plug which is penetrated by a current path and via which an aggregate of the hydraulics can be supplied electrically. According to the invention, the method has a step "sealing a passage of the current path through the plug base with a silicone-containing adhesive" on.
- 11
- Steckerplug
- 22
- Steckergehäuseplug housing
- 44
- Stirnflächeface
- 66
- Steckervorrichtungplug device
- 88th
- Steckerkragenplug collar
- 1010
- Steckerbodenplug ground
- 1212
- Strombahncurrent path
- 1414
- Abstandhalterspacer
- 1616
- Hochachsevertical axis
- 1818
- Querachsetransverse axis
- 2020
- VerrastungsträgerVerrastungsträger
- 2222
- Führungsnutguide
- 2424
- Verrastungsnutlocking groove
- 2626
- Klebstoffadhesive
- 2828
- O-RingnutO-ring groove
- 3030
- Wickelkörperbobbin
- 3232
- Wicklungsnutwinding groove
- 3434
- Spulenwicklungcoil winding
- 3636
- Polscheibepole disk
- 3838
- Verrastungskantelatching edge
- 4040
- Verrastunglatching
- 4242
- Sockelrippebase rib
- 4444
- Steckeraufnahmeplug receptacle
- 5050
- Dosiervorrichtungmetering
- 5151
- Aushärtevorrichtungcuring
Claims (15)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13152448T PL2621026T3 (en) | 2012-01-25 | 2013-01-24 | Sealed plug method for sealing a plug |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102012100598A DE102012100598A1 (en) | 2012-01-25 | 2012-01-25 | Sealed plug and method for sealing a plug |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2621026A1 true EP2621026A1 (en) | 2013-07-31 |
EP2621026B1 EP2621026B1 (en) | 2017-07-19 |
Family
ID=47603435
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13152448.0A Not-in-force EP2621026B1 (en) | 2012-01-25 | 2013-01-24 | Sealed plug method for sealing a plug |
Country Status (7)
Country | Link |
---|---|
US (1) | US9437955B2 (en) |
EP (1) | EP2621026B1 (en) |
CN (1) | CN103227381B (en) |
DE (1) | DE102012100598A1 (en) |
ES (1) | ES2644222T3 (en) |
HU (1) | HUE035014T2 (en) |
PL (1) | PL2621026T3 (en) |
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CN103904475A (en) * | 2014-03-12 | 2014-07-02 | 中航光电科技股份有限公司 | Underwater electromagnetic separation device |
WO2016011474A1 (en) * | 2014-07-24 | 2016-01-28 | Connec Limited | An electrical connector |
EP3172744B1 (en) | 2014-07-24 | 2019-11-06 | Connec Limited | Electrical connection component for a machine cable |
WO2016031740A1 (en) * | 2014-08-26 | 2016-03-03 | 京セラ株式会社 | Thermal head and thermal printer |
DE102015004486B3 (en) * | 2015-04-07 | 2016-06-30 | Rosenberger Hochfrequenztechnik Gmbh & Co. Kg | Method of making a connector and connector |
US10168371B2 (en) * | 2017-04-04 | 2019-01-01 | Pa&E, Hermetic Solutions Group, Llc | System and methods for determining the impact of moisture on dielectric sealing material of downhole electrical feedthrough packages |
US11081684B2 (en) | 2017-05-24 | 2021-08-03 | Honda Motor Co., Ltd. | Production of carbon nanotube modified battery electrode powders via single step dispersion |
CN112421302B (en) * | 2020-11-16 | 2022-07-01 | 合肥吉顺新能源科技有限公司 | Anti-drop formula new energy automobile is with rifle that charges |
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- 2013-01-24 EP EP13152448.0A patent/EP2621026B1/en not_active Not-in-force
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Also Published As
Publication number | Publication date |
---|---|
CN103227381B (en) | 2018-07-03 |
US9437955B2 (en) | 2016-09-06 |
ES2644222T3 (en) | 2017-11-28 |
PL2621026T3 (en) | 2017-12-29 |
HUE035014T2 (en) | 2018-03-28 |
DE102012100598A1 (en) | 2013-07-25 |
CN103227381A (en) | 2013-07-31 |
US20130189865A1 (en) | 2013-07-25 |
EP2621026B1 (en) | 2017-07-19 |
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