EP2609181A2 - Reinigungsmittel - Google Patents

Reinigungsmittel

Info

Publication number
EP2609181A2
EP2609181A2 EP11748705.8A EP11748705A EP2609181A2 EP 2609181 A2 EP2609181 A2 EP 2609181A2 EP 11748705 A EP11748705 A EP 11748705A EP 2609181 A2 EP2609181 A2 EP 2609181A2
Authority
EP
European Patent Office
Prior art keywords
zone
product
acid
zones
gel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11748705.8A
Other languages
English (en)
French (fr)
Other versions
EP2609181B1 (de
Inventor
Philip Smith
Alexandre Scolan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt and Colman Overseas Ltd
Original Assignee
Reckitt and Colman Overseas Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=45723854&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2609181(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GBGB1014211.5A external-priority patent/GB201014211D0/en
Priority claimed from GBGB1017203.9A external-priority patent/GB201017203D0/en
Priority claimed from GBGB1018095.8A external-priority patent/GB201018095D0/en
Priority claimed from GBGB1108370.6A external-priority patent/GB201108370D0/en
Application filed by Reckitt and Colman Overseas Ltd filed Critical Reckitt and Colman Overseas Ltd
Priority to PL11748705T priority Critical patent/PL2609181T3/pl
Publication of EP2609181A2 publication Critical patent/EP2609181A2/de
Application granted granted Critical
Publication of EP2609181B1 publication Critical patent/EP2609181B1/de
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/045—Multi-compartment
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/20—Water-insoluble oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/268—Carbohydrates or derivatives thereof

Definitions

  • detergents contain a number of active ingredients in order to provide numerous detergent benefits brought about by individual active components.
  • a single gelling aid is employed for a single zone of the product.
  • Polysaccharide gelling aids have been found to be par- ticula.rly beneficial in stabilising gels (especially gels with a high water content such as >30wt%) which are then packaged in a water soluble / dispersible material.
  • a polysaccharide is used as a gelling it is preferably present in an amount of 0.25-4wt% of that zone.
  • An inorganic salt may be used to enhance the gelling ability of the gelling aid.
  • Preferred examples of such salts include magnesium and calcium salts, e.g. the sulphate and / or chloride thereof.
  • Silica gelling aids have been found to be particularly beneficial in stabilising gels containing bleaching agents (i.e. the bleaching agents such as pox-salts have been found to be stable in gels gelled by silica gelling aids) . Additionally / alternatively silica gelling aids have been found to be advantageous since the formation of gels with suitable aesthesis properties such as transparent / translucent gels.
  • the separate zones may be used to house antagonistic components (e.g. bleach in a first zone and enzyme in a second zone) .
  • the zone may be used (since in a preferred arrangement the zones are arranged concentricall ) so that the timing of the release of ac- tives from zones may be delayed relative to a second zone.
  • nonionic surfactants suitable for use include ethylene oxide condensate products of secondary aliphatic alcohols containing 11 to 1 ⁇ carbon atoms in a straight or branched chain configuration condensed with 5 to 30 equivalents of ethylene oxide.
  • examples of commercially available non-ionic detergents of the foregoing type are Cu-is secondary alkanol condensed with ei- ther 9 equivalents of ethylene oxide (Tergitol 15-S-9) or 12 equivalents of ethylene oxide (Tergitol 15-S-12) marketed by Union Carbide, a subsidiary of Dow Chemical.
  • Octylphenoxy polyethoxyethanol type nonionic surfactants for example, Triton X-100, as well as amine ox- ides can also be used as a nonionic surfactant.
  • nonionic surfactants are amine oxides, alkyl amide oxide surfactants.
  • Preferred anionic surfactants are frequently provided as alkali metal salts, ammonium salts, amine salts, ami- noalcohol salts or magnesium salts.
  • surfactants which may be used are alkyl naphthalene sulfonates and oleoy.l sarcosinates and mixtures thereof.
  • Any suitable soil catcher may be employed. Unlike detergents or surfactants, which simply aid in the removal of soils from surfaces, the soil catcher actively binds to the soil allowing it to be removed from the surface of the laundry. Once bound, the soil is less likely to be able to redeposit onto the surface of the laundry.
  • Preferred soil catchers have a high affinity to both oily and water-soluble soil.
  • the soil catcher is a mixture of two or mere, soil catchers, each soil catcher may have a different affinity for different soils.
  • Preferred soil catchers for oily soils have a non polar structure with high absorption capability.
  • Preferred water based soil catchers are generally charged and have a high surface area in order to attract the soil by electrostatic charge and collect it.
  • ethylidene norbene poly- mers ethylidene norbene/ethylene copolymers/ ethylidene norbene/propylene/ethylidene ter-polymers .
  • Inorganic materials may also be employed. Examples include zeolites, talc, bentonites and active carbon. The latter may be used to absorb and/or degrade coloured parts of stain and/or absorb odours. Alginates, carrageneans and chitosan may also be used.
  • the product advantageously additionally comprises cleaning agents selected from the group consisting of,, fillers, builders, chelating agents, activators, fragrances, enzymes or a mixture thereof.
  • cleaning agents selected from the group consisting of,, fillers, builders, chelating agents, activators, fragrances, enzymes or a mixture thereof.
  • These active agents are generally water soluble, so dissolve during the wash. Thus the additional active agents are released over a period of time when exposed to water in the laundry washing machine.
  • Suitable carboxylates containing one carboxy group include the water soluble salts of lactic acid, glycolic acid and ether derivatives thereof.
  • Polycarboxylates containing two carboxy groups include the wa er-soluble salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the s lfinyl carboxylates.
  • Polycarboxylate containing four carboxy groups include oxydisuccinates disclosed in GB-A-1, 261, 829, 1,1,2,2- ethane tetracarboxylates, 1, 1 , , 3-propane tetracarboxy- lates and 1, 1, 2, 3-propane tetracarobyxlates.
  • Polycar- boxylates containing sulfo substituents include the sul- fosucclnate derivatives disclosed in GB-A-1, 398, 21, GB- A-l., 398, 22 and US-A-3, 936448, and the sulfonated pyro- lysed citrates described in GB-A-1, 39,000.
  • the preferred polycarboxylates are hy- droxycarboxylates containing up to three carboxy groups per molecule, more particularly citrates.
  • More preferred polymers are homopolymers, copolymers and multiple polymers of acrylic, f.luorinated acrylic, sulfonated styrene, maleic anhydride, methacrylifc, iso- butylene, styrene and ester monomers.
  • acrylic, f.luorinated acrylic, sulfonated styrene, maleic anhydride, methacrylifc, iso- butylene, styrene and ester monomers are Acusol supplied from Rohm & Haas, Syntran supplied from Interpolymer and the Versa and Alcosperse series supplied from Alco Chemical, a National Starc & Chemical Company.
  • the parent acids of the monomeric or oligomeric polycar- boxylate chelating agents or mixtures thereof with their salts e.g. citric acid or citrate/citric acid mixtures are also contemplated as useful builder components.
  • builders are compounds that sequester metal ions associated with the hardness of water, e.g. calcium and magnesium, whereas chelating agents are compounds that sequester transition metal ions capable of catalysing the degradation of oxygen bleach systems.
  • chelating agents are compounds that sequester transition metal ions capable of catalysing the degradation of oxygen bleach systems.
  • certain compounds may have the ability to do perform both functions.
  • a preferred biodegradable chelating agent for use herein is ethylene diamine ⁇ , ⁇ ' -disuccinic acid, or alkali metal, or alkaline earth, ammonium or substituted ammonium salts thereof or mixtures thereof, Ethylenediafnine N, ' -disuccinic acids, especially the (S,S) isomer have been extensively described in US patent 4, 704, 233, November 3, 1987, to Hartmart and. Perkins. Ethylenediaitiine N f N' -disuccinic acid is, for instance, commercially available under the tradename saEDDS TM from Palmer Re- search Laboratories.
  • Suitable amino carboxylat.es to be used herein include ethylene diamine tetra acetates, diethylene triamine pentaacetates, diethylene triamine pentaacetate (DTPA),N- hydroxyethylethylenediamine triacetates, ni- trilotri-acetates, ethylenediamine tetrapropionates, triethylenetetraaminehexa-acetates, ethanol-diglycines, propylene diamine tetracetic acid (PDTA) and methyl glycine diacetic acid (MGDA) , both in their acid form, or in their alkali metal, ammonium, and substituted ammo- nium sal forms.
  • PDTA propylene diamine tetracetic acid
  • MGDA methyl glycine diacetic acid
  • the product may comprise a solvent.
  • the solvent constituent may include one or more alcohol, glycol, ace- tate, ether acetate, glycerol, polyethylene glycol .i.th molecular weights ranging from 200 to.1000 silicones or glycol ethers.
  • Exemplary useful alcohols include C 2-9 primary and secondary alcohols which may be straight chained or branched, preferably pentanol and hexanol.
  • Preferred solvents . are glycol ethers.
  • examples include those glycol ethers having the general structure R 2 -O- [CH 2 -CH (R) - (CH 2 ) -0] 2 ,-H, wherein R 2 is C 1-20 alky1 or al- kenyl, or a cyclic alkane group of at least 6 carbon at- oms, which may be fully or partially unsaturated or aromatic; n is an integer from 1. to 10, preferably from 1 to 5/ and each R is selected from H or CH 3 .
  • the product may, for example, comprise one enzyme or a combination of them.
  • Enzymes in granular form are preferred. Examples of suitable enzymes are proteases, modified proteases stable in oxidisable conditions, amylases, lipases and cellulases.
  • a method of producing the product of the first aspect of the invention there is provided a method of producing the product of the first aspect of the invention.
  • One preferred method of production is that of extrusion co-extrusion.
  • the materi- als for making up the zone are fed into and then simultaneously extruded through a concentric arrangement of tubes.
  • ah amount of co extruded material is collected (an amount of co extruded .material may be separated from the extrudate, e.g. by cutting) .
  • co- extrusion is used as a production technique the outer zone(s) of the product coalesce over the inner zone(s) of the product forming a product having a concentric arrangement .
  • the extrusion process is carried out with a temperature gradient such that the temperature of the extrudate reduces with its passage through the extruder.
  • th extruder is operated with an input temperature of about 80°C and an exit temperature of about 60°C.
  • the finished product is removed form the second moul .
  • more than two zones may be moulded in this process if more moulding steps are used. Intermediate / final non-moulding steps, such as. spraying and / or dipping are not precluded.
  • the first zone is suspended in the second mould, so that it does not contact a surface of the second mould.
  • the meads used for this suspension comprise a pin / rod.
  • the pin / rod may be inserted into the first zone at or after the removal of the first zone from the first mould.
  • the pin / rod may remain inserted in the first zone throughout any subject moulding steps.
  • the pin / rod may be used as an aid to finished product is removed form the final mould.
  • each zone of the product has a fil (e.g. an outer film) of a packaging material.
  • the finalized product is intended for used in a washing operation, e.g. machine dishwash, automatic laundry. Ideally the product dissolves within 10 minutes when used in an automatic washing process.
  • Example 1 A multi-zone fabric detergent product having the following formulation was prepared in a sequential moulding process.
  • the frozen first zone was dipped into the material of the second zone to be coated. (A pin was inserted into the first zone to retain it during, dipping) .
  • a multi-zone automatic dishwashing detergent product having the following formulation was prepared in a sequential moulding process.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
EP11748705.8A 2010-08-26 2011-08-12 Reinigungsmittel Revoked EP2609181B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL11748705T PL2609181T3 (pl) 2010-08-26 2011-08-12 Produkt detergentowy

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GBGB1014211.5A GB201014211D0 (en) 2010-08-26 2010-08-26 Product
GBGB1017203.9A GB201017203D0 (en) 2010-10-13 2010-10-13 Product
GBGB1018095.8A GB201018095D0 (en) 2010-10-27 2010-10-27 Product
GBGB1108370.6A GB201108370D0 (en) 2011-05-19 2011-05-19 Product
PCT/GB2011/051524 WO2012025736A2 (en) 2010-08-26 2011-08-12 Detergent product

Publications (2)

Publication Number Publication Date
EP2609181A2 true EP2609181A2 (de) 2013-07-03
EP2609181B1 EP2609181B1 (de) 2014-03-19

Family

ID=45723854

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11748705.8A Revoked EP2609181B1 (de) 2010-08-26 2011-08-12 Reinigungsmittel

Country Status (3)

Country Link
EP (1) EP2609181B1 (de)
PL (1) PL2609181T3 (de)
WO (1) WO2012025736A2 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102018221584A1 (de) * 2018-12-13 2020-06-18 Henkel Ag & Co. Kgaa Verfahren zur Herstellung mehrphasiger Wasch- oder Reinigungsmittelformkörper

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE374556B (de) 1968-05-24 1975-03-10 Unilever Nv
US3812044A (en) 1970-12-28 1974-05-21 Procter & Gamble Detergent composition containing a polyfunctionally-substituted aromatic acid sequestering agent
GB1379241A (en) 1971-03-02 1975-01-02 Unilever Ltd Preparation of salts of carboxymethyloxysuccinic acid
CA973771A (en) 1971-04-30 1975-09-02 Unilever Limited Detergent compositions
DE2230073A1 (de) 1971-06-25 1972-12-28 Unilever N.V., Rotterdam (Niederlande) alpha-substituierte beta-Sulfobernsteinsäuren und ihre Verwendung als Builder in Waschmitteln
NL149226B (nl) 1971-06-30 1976-04-15 Monsanto Co Werkwijze voor de bereiding van chelaatvormende polycarbonzuren en werkwijze voor de bereiding van wasmiddelen die ze bevatten.
GB1425343A (en) 1972-02-14 1976-02-18 Unilever Ltd Phthalic acid derivatives
DE2258301B2 (de) 1972-11-29 1980-07-17 Henkel Kgaa, 4000 Duesseldorf Wasch- und Waschhüfsmittel für Textilien
US4704233A (en) 1986-11-10 1987-11-03 The Procter & Gamble Company Detergent compositions containing ethylenediamine-N,N'-disuccinic acid
US5585034A (en) * 1991-11-21 1996-12-17 Colgate-Palmolive Co. Gelled near tricritical point compositions
US20030045441A1 (en) * 2001-08-28 2003-03-06 Unilever Home And Personal Care, Usa, Division Of Conopco, Inc. Water-soluble package with hydrophobic capsules in the film
US20030045411A1 (en) 2001-09-05 2003-03-06 Jong-Yuan Lin Balance training device
DE102008026932A1 (de) * 2008-06-05 2009-12-10 BSH Bosch und Siemens Hausgeräte GmbH Reiniger für Geschirrspülmaschinen, Geschirrspülmaschine und Verfahren zum Reinigen von Geschirrstücken

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2012025736A2 *

Also Published As

Publication number Publication date
EP2609181B1 (de) 2014-03-19
WO2012025736A2 (en) 2012-03-01
WO2012025736A3 (en) 2012-05-03
PL2609181T3 (pl) 2014-08-29

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