EP2590511A2 - Anthranilamides in combination with fungicides - Google Patents

Anthranilamides in combination with fungicides

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Publication number
EP2590511A2
EP2590511A2 EP11731306.4A EP11731306A EP2590511A2 EP 2590511 A2 EP2590511 A2 EP 2590511A2 EP 11731306 A EP11731306 A EP 11731306A EP 2590511 A2 EP2590511 A2 EP 2590511A2
Authority
EP
European Patent Office
Prior art keywords
methyl
alkyl
carboxamide
phenyl
spp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11731306.4A
Other languages
German (de)
French (fr)
Inventor
Christian Funke
Heike Hungenberg
Rüdiger Fischer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Intellectual Property GmbH
Original Assignee
Bayer Intellectual Property GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Intellectual Property GmbH filed Critical Bayer Intellectual Property GmbH
Priority to EP11731306.4A priority Critical patent/EP2590511A2/en
Publication of EP2590511A2 publication Critical patent/EP2590511A2/en
Withdrawn legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/713—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with four or more nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
    • A01N47/14—Di-thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/32—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals

Definitions

  • the present invention relates to new active compound combinations which consist of the insecticidally active compounds of the formula (I) in combination with fungicidal active compounds (II) and are very suitable for controlling undesired animal pests such as insects, acaricides and / or nematodes and undesired phytopathogenic fungi ,
  • the anthranilic acid amides of the formula (I) are known in part from WO 2007/144100 and describe their insecticidal activity.
  • the active ingredients mentioned in this specification with their "common name” are known, for example, from "The Pesticide Manual” 14th Ed., British Crop Protection Council 2006, and the website http://www.alanwood.net/pesticides.
  • insecticidal or fungicidal activity and / or range of action and / or the plant tolerance of the known compounds, in particular to crops is not always sufficient.
  • Ci-C 6 alkyl represents hydrogen, amino, hydroxy, or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl or C 3 -C 6 -cycloalkyl, where the substituents may be independently selected from halogen, cyano, nitro, hydroxy, CC 4 -alkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, C r C 4 -Alkylsul- fonyl, (CC 4 -alkoxy) carbonyl, C -C 4 alkylamino, di- (Ci-C 4 alkyl) amino, C 3 -C 6 cycloalkyl, amino or (Ci-C 4 alkyl) C 3 -C 6 cycloalkylamino, hydrogen, CC 6 alkyl, C
  • R 3 is C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkylaminocarbonyl or di (C 1 -C 6) -alkylaminocarbonyl, or
  • R 3 furthermore represents a singly or multiply, identically or differently substituted 5- or 6-membered aromatic or heteroaromatic ring, a 4, 5 or 6-membered partially saturated ring or saturated heterocyclic ring, or a saturated, partially saturated or aromatic heteroaromatic ring; bicyclic ring, which may optionally contain one to three heteroatoms from the series O, S or N, wherein the substituents are independently selected from SF 5; Halogen, cyano, nitro, hydroxy, amino, carboxy, carbamoyl, Ci-C 6 alkyl, C 3 -C 6 cycloalkyl, CC 4 -alkoxy, Coe-haloalkyl, Ci-C4-haloalkoxy, CC 4 - alkylthio, C 1 -C 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, C 1 -C 4 -Alkylsulfimino, CC 4 - Alkyls
  • R 2 and R 3 may be connected to each other via two to six carbon atoms and form a ring which optionally additionally contains a further nitrogen, sulfur or oxygen atom and optionally monosubstituted to fourfold with C 1 -C 2 -alkyl, C 1 -C 2 - Haloalkyl, halogen, cyano, amino Ci-C 2 alkoxy or dC 2 haloalkoxy may be substituted,
  • R 4 is hydrogen, halogen, cyano, nitro CC 4 alkyl, CC 4 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, CC 4 alkoxy, CC 4 haloalkoxy, SF 5, CC 4 alkylthio, CC 4 - Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 -halo-alkyl-sulfmyl, CC 4 - haloalkylsulfonyl, Ci-C 4 alkylamino, di- (Ci-C 4 alkyl) amino, C 3 -C 6 cycloalkylamino, (C 1 -C4- alkoxy) imino, (Ci-C 4 alkyl) (Ci-C 4 alkoxy) imino, (CC 4
  • n is 0 to 3
  • QY is a 5- or 6-membered, partially saturated or saturated heterocyclic or heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system, wherein the ring or the ring system, optionally mono- or polysubstituted, identical or different is substituted, said substituents may be independently selected from hydrogen, Ci-COE-alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Ci-C 6 haloalkyl , C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, CC 4 -alkoxy, CC 4 -
  • R 9 independently of one another represent hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkyl, halogen, cyano, nitro, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkoxy, C 1 -C 4 -alkyl 4- alkylthio or C 1 -C 4 -haloalkylthio, p is 0 to 4,
  • Z is N, CH, CF, CC1, CBr or Cl, the compounds of the general formula (I) furthermore comprise N-oxides and salts, and one or more fungicides of the group (II):
  • Fungicides (1) inhibitors of ergosterol biosynthesis, such as Al dimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fenhexamide, fenpropidin, Fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole cis, hexaconazole, imazalil, imazalil sulfate, imibenconazole, ipconazole, metconazole, myclobutanil, naftifine, nuarimol, oxpoconazole, paclobutrazo
  • inhibitors of respiration such as bixafen, boscalid, carboxin, diflumetorim, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, furmecyclox, isopyrazam mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti- more highly enriched racemates 1RS, 4SR, 9SR, isopyrazam (anti-epimeric racemate), isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), isopyrazam (syn-epimeric racemate 1RS , 4SR, 9RS) Isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), isopyrazam (syn-epimeric enantiomer (syn-ep
  • inhibitors of respiration at the complex III of the respiratory chain, such as ametoctradine, amisulbrom, azoxystrobin, cyazofamide, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, famoxadone, fenamidone, fenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin , Picoxystrobin, Pyraclostrobin, Pyrametostrobin, Pyraoxystrobin, Pyribencarb, Triclopyricarb, Trifloxystrobin, (2E) -2- (2 - ⁇ [6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] oxy ⁇ phenyl) -2- (methoxyimino) -N-methylethaneamide, (2E) -2- (methoxyimino) -N
  • Mitosis and cell division inhibitors such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fluopicolide, fuberidazole, pencycuron, thiabendazole, thiophanate-methyl, thiophanate, zoxamide, 5-chloro-7- (4-methylpiperidine-1) yl) -6- (2,4,6-trifluorophenyl) [l, 2,4] triazolo [l, 5-ajpyrimidine and 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4 - (2,4,6-trifluorophenyl) pyridazine.
  • Compounds with multisite activity such as Bordeaux mixture, captafol, captan, chlorothalonil, copper preparations such as copper hydroxide, copper naphthenate, copper oxide, copper oxychloride, copper sulfate, dichlofluanid, dithianone, dodine, dodine free base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatin acetate , Iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram.
  • copper preparations such as copper hydroxide, copper naphthenate, copper oxide, copper oxychloride, copper sulfate, dichlofluanid,
  • resistance inducers such as acibenzolar-S-methyl, isotianil, probenazole and tiadinil.
  • inhibitors of amino acid and protein biosynthesis such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim, pyrimethanil and 3-
  • Inhibitors of ATP production such as, for example, acetate acetate, fentin chloride, fentin hydroxide and silthiofam.
  • inhibitors of cell wall synthesis such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A, and valifenalate.
  • lipid and membrane synthesis inhibitors such as biphenyl, chloroneb, diclorane, edifenphos, etndiazole, iodocarb, ipamplesfos, isoprothiolane, propamocarb, propamocarb hydrochloride, prothiocarb, pyrazophos, quintozene, tecnazene and tolclofos-methyl.
  • inhibitors of melanin biosynthesis such as carpropamide, diclocymet, fenoxanil, phthalide, pyroquilone, tricyclazole and 2,2,2-trifluoroethyl ⁇ 3-methyl-1 - [(4-methylbenzoyl) amino] butane
  • inhibitors of nucleic acid synthesis such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacon, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl and oxolic acid.
  • Signal transduction inhibitors such as cholzolinate, fenpiclonil, fludioxonil, iprodione, procymidone, quinoxyfen and vinclozoline.
  • Decouplers such as binapacryl, dinocap, ferimzone, fluazinam and meptyldinocap.
  • the insecticidal, acaricidal, nematicidal and fungicidal activity of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unpredictable true synergistic effect and not just an effect supplement.
  • R 1 is preferably hydrogen, CC 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, cyano (CC 6 -alkyl), CC 6 -alkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C r C 4 -alkoxy-Ci- C4-alkyl, Ci-C4-alkylthio-Ci-C 4 alkyl, CC 4 alkylsulfinyl-C 4- alkyl or CC 4 -alkylsulfonyl-CC 4 -alkyl,
  • R 1 particularly preferably represents hydrogen, methyl, ethyl, cyclopropyl, cyanomethyl, methoxymethyl, methylthiomethyl, methylsulfinylmethyl or methylsulfonylmethyl,
  • R 1 very particularly preferably represents hydrogen
  • R 2 is preferably hydrogen or C 1 -C 6 -alkyl.
  • R 2 particularly preferably represents hydrogen or methyl.
  • R 2 very particularly preferably represents hydrogen.
  • R 3 preferably represents hydrogen or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents, Ci-C 4 alkyl, Ci-C 4 alkoxy, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl, C 3 - C 6 - is cycloalkyl, where the substituents can be independently selected from halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, CC 4 alkyl, CC 4 haloalkyl, C 3 -C 6 cycloalkyl, CC 4 alkoxy , CC 4 haloalkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 - membered 6-alkylsulfonyl, Ci-C 4 alkoxycarbonyl, Ci-C4-alkylcarbonyl or a phenyl or a 4, 5 or, aromatic partially saturated or
  • R 3 is preferably C 2 -C 4 alkoxycarbonyl, C 2 -C 4 alkylcarbonyl, C 2 -C 4 alkylaminocarbonyl or C 2 - C 4 .Dialkylaminocarbonyl; or
  • R 3 preferably represents a phenyl ring, a 5- or 6-membered aromatic heterocyclic ring or a 4-, 5- or 6-membered partially saturated or saturated heterocyclic ring which may contain 1-3 heteroatoms from the series N, S, O.
  • the phenyl ring or heterocyclic ring is optionally mono- or polysubstituted by identical or different substituents, and where the substituents can be selected independently of one another from hydrogen, CC 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 - Alkynyl, C 3 -C 6 cycloalkyl, CC 4 haloalkyl, C 2 -C 4 haloalkenyl, C 2 -C 4 haloalkynyl, C 3 -C 6 halocycloalkyl, halo, cyano, carboxy, carbamoyl, NO 2 , hydroxy , CC 4 -alkoxy, CC 4 haloalkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 - alkylsulfonyl, CC 4 haloalkylthio, Ci-C 4 -
  • R 3 particularly preferably represents hydrogen or represents in each case optionally mono- or polysubstituted, identically or differently substituted C 1 -C 4 -alkyl or C 3 -C 6 -cycloalkyl, where the substituents can be selected independently of one another from halogen, cyano, carboxy, hydroxy, CC 4 alkyl, CC 4 haloalkyl, C 3 -C 6 cycloalkyl, CC 4 alkoxy, CC 4 haloalkoxy, CC 4 alkylthio, CC 4 alkylsulfmyl, CC 4 alkylsulfonyl, C 2 -C 4 alkoxycarbonyl , C 2 -C 6 - alkylcarbonyl or a phenyl ring or a 4-, 5- or 6-membered aromatic, partially saturated or saturated heterocyclic ring, wherein the phenyl ring or heterocyclic ring optionally monosubstituted or polysubstituted
  • R 3 particularly preferably represents a phenyl ring, a 5- or 6-membered aromatic heterocyclic ring or a 4-, 5- or 6-membered, partially saturated or saturated heterocyclic ring which contains 1 -3 heteroatoms from the series N, S, O where the phenyl ring or heterocyclic ring is optionally mono- or polysubstituted by identical or different substituents, and where the substituents can be selected independently of one another from hydrogen, CC 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 3 -C 6 - cycloalkyl, C r C 4 haloalkyl, C 2 -C 4 haloalkenyl, C 2 -C 4 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, carbamoyl, N0 2, Hydroxy, CC 4 alkoxy, Ci-C 4
  • R 3 particularly preferably represents hydrogen, methyl, isopropyl, cyclopropyl or tert-butyl.
  • R 4 particularly preferably represents chlorine, fluorine or bromine
  • R 4 furthermore particularly preferably represents iodine or cyano.
  • R 5 is preferably CC 4 alkyl, C 3 -C 6 cycloalkyl, CC 4 haloalkyl, dC 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl , C 2 -C 4 haloalkynyl, C r C 4 alkoxy, Ci-C4 haloalkoxy, alkylthio CC 4, CC 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC -Halo- 4 alkylsulfinyl, C 1 -C 4 -haloalkylsulfonyl, halogen, cyano, nitro or C 3 -C 6 -trialkylsilyl,
  • R 5 particularly preferred for CC 4 alkyl, C 3 -C 6 cycloalkyl, Ci-C 4 haloalkyl, Ci-C 6 -Halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 4 haloalkenyl, C 2 C 4 alkynyl, C 2 -C 4 haloalkynyl, CC 4 alkoxy, CC 4 haloalkoxy, fluoro, chloro, bromo, iodo, cyano, nitro or C 3 -C 6 trialkylsilyl,
  • R 5 very particularly preferably represents methyl, fluorine, chlorine, bromine or iodine
  • R 5 particularly preferably represents methyl or chlorine
  • Qx preferably represents an optionally mono- or polysubstituted by identical or different substituent R 7 substituted 5-6 membered heteroaromatic ring, which may contain 1-3 heteroatoms from the series N, O, S, or represents phenyl,
  • Qx particularly preferably represents an optionally mono- or polysubstituted by identical or different substituents represented by R 7, 5- or 6-membered ring selected from the group consisting of furan, thiophene, triazole, imidazole, thiazole, oxazole, isoxazole, isothiazole, thiadiazole , Oxadiazole, pyrrole, pyridine, pyrimidine, pyridazine, pyrazine, phenyl or pyrazole,
  • Qx very particularly preferably represents thiazole, oxazole, pyrrole, imidazole, triazole, pyrimidine, phenyl or pyrazole, which is represented by the group R 7
  • a particularly preferably represents CH 2 , CH (CH 3 ), -CH 2 O- or -C ( O) -CH 2 -,
  • Qz preferably represents a 3- to 4-membered, partially saturated or saturated, or for a 5- to 6-membered, partially saturated, saturated or aromatic ring, wherein the ring is optionally 1 -3 heteroatoms from the series N, S, 0 may contain, where the ring is optionally mono- or polysubstituted by identical or different substituents, and wherein the substituents may be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 - Alkynyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, hydroxy, CC 4 - alkoxy, Ci-C4-haloalkoxy, CC 4 - alkylthio,
  • Q.sup.2 is particularly preferably a 3- to 4-membered, partially saturated or saturated, or a 5-membered, partially saturated, saturated or aromatic ring, the ring optionally containing 1 -2 heteroatoms from the series N, S, O. where the ring is optionally mono- or polysubstituted by identical or different substituents, and where the substituents can be selected independently of one another from hydrogen, C 1 -C 6 -alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Ci-C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 - haloalkynyl, C 3 - C 6 halocycloalkyl, halogen, cyano, hydroxy, CC 4 -alkoxy, CC 4 haloalkoxy, CC 4 - alkylthio, Ci-C 4
  • R 9 independently of one another are preferably hydrogen, halogen, cyano, CC 4 alkyl, CC 4 -alkoxy, C 1 -C 4 -haloalkyl, CC 4 -haloalkoxy, CC 4 -haloalkylsulfonyl or (C 1 -C 4 -alkyl) C 1 -C 4 -alkyl 4- alkoxyimino stands,
  • R 9 independently of one another particularly preferably represents hydrogen, halogen, cyano or CC 4 -haloalkyl
  • R 9 independently of one another very particularly preferably represents fluorine, chlorine or bromine, R 9 particularly preferably represents chlorine, p is preferably 1, 2 or 3, p is more preferably 1 or 2, p is very particularly preferably 1,
  • Z is preferably N, CH, CF, CC1, CBr or CI
  • Z particularly preferably represents N, CH, CF, CC1 or CBr,
  • Z very particularly preferably represents N, CC1 or CH
  • R 8 preferably represents linear or branched - (C 1 -C 4 -alkylene) or represents a direct bond
  • R 8 particularly preferably represents methyl, ethyl, propyl, iso-propyl, n-butyl, sec-butyl or iso-butyl or a direct bond
  • R 8 very particularly preferably represents methyl or ethyl or a direct bond
  • Q Y preferably represents a 5- or 6-membered, partially saturated or saturated heterocyclic or heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system, where the heteroatoms can be selected from the series N, S, O, wherein the ring or the ring system is optionally mono- or polysubstituted by identical or different substituents, and wherein the substituents may be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 - cycloalkyl, Ci-C6-haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, Ci-C 4 alkoxy, dC 4 hal
  • Q Y particularly preferably represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q1 to Q-53 and Q-58 to Q-59, Q62 to Q63, a 9-membered aromatic heterobicyclic ring system Q-54 to Q-56 and to a 5-membered heterocyclic ring Q-60 to Q-61, wherein the substituents can be independently selected from C r C 3 alkyl, dC 3 haloalkyl, Ci-C 2 - alkoxy, halogen, cyano, hydroxy, nitro or CC 2 haloalkoxy, or wherein the substituents can be independently selected from phenyl or a 5- or 6-membered heteroaromatic ring, wherein phenyl or the ring is optionally mono- or polysubstituted, identically or differently, with Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl
  • Q Y most preferably represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q-36 to Q-40, Q43, Q-58 to Q-59, Q62, Q63, an aromatic 9-membered fused heterobicyclic ring system Q-54 to Q-56 and also a 5-membered heterocyclic ring Q-60 to Q-61, where the substituents can be selected independently of one another from CC 3 -alkyl, C 1 -C 3 -haloalkyl, CC 2 - Alkoxy, halogen, cyano, hydroxy, nitro or Ci-C 2 haloalkoxy, or wherein the substituents can be independently selected from phenyl or a 5- or 6-membered heteroaromatic ring, wherein phenyl or the ring optionally mono- or polysubstituted, identical or differently, with Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -
  • Q Y particularly preferred for an optionally mono- or polysubstituted or differently substituted heteroaromatic ring of the series Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 and Q63, as well as for a 5-membered heterocyclic ring Q-60, where the substituents can be selected independently of one another from methyl, ethyl, cyclopropyl, tert-butyl, chlorine, fluorine, iodine, bromine, cyano, nitro, difluoromethyl, trifluoromethyl, pentafluoroethyl, n-heptafluoropropyl and isoheptafluoropropyl or where the substituents can be selected independently of one another from phenyl or a 5- or 6-membered heteroaromatic ring, where the substituents can be selected independently of one another from methyl, ethyl, cyclopropyl, tert-
  • the oxo group as a substituent on a ring C atom then means, for example, a carbonyl group in the heterocyclic ring.
  • lactones and lactams are preferably also included.
  • the oxo group can also occur on the hetero ring atoms, which can exist in different oxidation states, for example at N and S, and then form, for example, the divalent groups -N (O) -, -S (O) - (also short SO) and -S (0) 2 - (also short S0 2 ) in the heterocyclic ring.
  • - N (O) and -S (0) groups both enantiomers are included.
  • Substituents other than the oxo group may also be bonded to a heteroatom on a heterocyclic ring, for example a nitrogen atom, if a hydrogen atom on the nitrogen atom of the main body is replaced. In the case of the nitrogen atom and other heteroatoms such.
  • the sulfur atom is also a further substitution to form quaternary ammonium compounds or sulfonium compounds in question.
  • the compounds of formulas (I) may be in the form of various regioisomers. For example in the form of mixtures of compounds with the definition Q62 or Q63 or in the form of mixtures of Q58 and Q59.
  • the invention also includes active compound combinations comprising mixtures of compounds of the formulas (I), where Q Y has the meanings Q62 and Q63, and Q58 and Q59 and the compounds can be present in different mixing ratios, and one or more active compounds from the group (II) , While mixing ratios of from compounds of formula (I) wherein the radical Q Y is Q62 or Q58 are preferred to compounds of formula (I) wherein the radical Qy represents Q63 or Q59, from 60:40 to 99: 1, more preferably from 70:30 to 97: 3, most preferably from 80:20 to 95: 5.
  • R 3 is hydrogen or each optionally mono- or polysubstituted by identical or different substituents CC 6 alkyl, CC 6 alkoxy, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 2 cycloalkyl, C 3 - Ci 2 cycloalkyl-Ci-C6-alkyl, wherein the substituents may be independently selected from halogen, amino, cyano, nitro, hydroxy, Ci-C 6 alkyl, C 3 -C 6 cycloalkyl, C 1 -C4- alkoxy, Ci-C4-haloalkoxy, CC 4 -alkylthio, C 2 -C 6 alkoxycarbonyl, Ci-C6-alkylcarbonyl, C3 -C6- cycloalkylamino or a 5- or 6-membered heteroaromatic ring,
  • R 4 is halogen, cyano or methyl
  • R 5 is methyl or chlorine
  • Z is N, CC1 or CH
  • Qy represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q-36 to Q-40, Q43, Q-58 to Q-59, Q62, Q63, a 9-membered aromatic heterobicyclic ring system Q- 54 to Q-56 and also a 5-membered heterocyclic ring Q-60 to Q-61, where the substituents can be selected independently of one another from C 1 -C 3 -alkyl, C 1 -C 3 -haloalkyl, C 1 -C 2 -alkoxy, Halogen, cyano, hydroxy, nitro or CC 2 -haloalkoxy, where the compounds of the formula (1-1) may be present in the form of salts, and one or more active substances selected from the group (II),
  • the compounds of formula (1 1) preferably represents hydrogen or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents, Ci-C 6 alkyl, CC 6 alkoxy, C 2 -C 6 alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 - cycloalkyl, C 3 -C cycloalkyl-Ci-C stands 6 6 alkyl, wherein the substituents may be independently selected from halogen, cyano, amino, hydroxy, Ci-C 6 alkyl , C 1 -C4- alkoxy, Ci-C4-haloalkoxy, Ci-C4 alkylthio, Cj-C b cycloalkyl, a 5 or 6-membered heteroaromatic ring containing 1 -2 heteroatoms from the series N, 0, S in which two oxygen atoms are not adjacent in the ring, more preferably one
  • R 4 is preferably halogen, cyano or methyl
  • R 4 particularly preferably represents chlorine and cyano
  • R 4 is also particularly preferably bromine, fluorine, iodine or methyl
  • R 5 is preferably and more preferably methyl, Z is preferably N or CH,
  • QY is preferably an optionally mono- or polysubstituted or differently substituted heteroaromatic ring of the series Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 and Q63, as well as a 5 -member heterocyclic ring Q-60, wherein the substituents can be independently selected from methyl, ethyl, cyclo-propyl, tert-butyl, chlorine, fluorine, iodine, bromine, cyano, nitro, difluoromethyl, trifluoromethyl, pentafluoroethyl, n Heptafuoropropyl and isoheptafluoropropyl.
  • QY particularly preferably represents an optionally mono- or polysubstituted or different substituted heteroaromatic ring of the series Q-58 and Q-59, wherein the substituents can be independently selected from methyl, ethyl, cyclo-propyl, tert-butyl, difluoromethyl, trifluoromethyl, pentafluoroethyl, n-heptafluoropropyl and iso-heptafluoropropyl.
  • the compounds of formulas (1-1) may be in the form of various regioisomers.
  • the compounds of formulas (1-1) may be in the form of various regioisomers.
  • the compounds of formulas (1-1) may be in the form of mixtures of compounds with the definition Q62 or Q63 or in the form of mixtures of Q58 and Q59. Therefore, according to the invention also includes combinations of active substances containing mixtures of compounds of formulas (1-1), wherein Q Y has the meanings Q62 and Q63, and Q58 and Q59 and the compounds may be present in different mixing ratios, and one or more active compounds from the group ( II).
  • active ingredients containing at least one active substance of the general formula (I) or (1-1) and an active compound of the group (II) selected from
  • active ingredient combinations comprising the mixtures of active compounds of the formula (I-I-1) to (I-1-60) given below and one or more active compounds of the group (II).
  • mixtures are preferably present in a mixing ratio of 80:20 to 99: 1.
  • Be ⁇ playfully mentioned is the mixture Il -1 / 1-1-7, wherein the compound of formula III to the compound of formula 1-1-7 in a mixing ratio of 80:20 to 99: 1 is present.
  • mixture 1-1-2 / 1-1-8 mentions the mixture 1-1-2 / 1-1-8 wherein the compound of the formula 1-1-2 to the compound of the formula 1-1-8 in a mixing ratio of 80:20 to 99: 1 is present.
  • -1-1- / 1-1-7
  • the active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond.
  • the combinations according to the invention contain active compounds of the formula (I) to the mixing partner of the group (II) in the ratio of 625: 1 to 1: 625; preferably in the preferred and particularly preferred mixing ratios given in Table 1 below: • the mixing ratios are based on weight ratios.
  • the ratio is to be understood as the active ingredient of the formula (I): Mixture partner to formula (I): Mischpartner
  • the application rates can be varied within a relatively wide range, depending on the mode of administration.
  • the application rate of the active compound combinations according to the invention is in the treatment of parts of plants, e.g.
  • Leaves from 0.1 to 1000 g / ha preferably from 10 to 500 g / ha, more preferably from 50 to 300 g / ha (when applied by pouring or drop, the application rate can even be reduced, especially if inert substrates such as rock wool or perlite are used); in the seed treatment from 1 to 2000 g per 100 kg of seed, preferably from 2 to 1000 g per 100 kg of seed, more preferably from 3 to 750 g per 100 kg of seed, most preferably from 5 to 500 g per 100 kg of seed; in the soil treatment from 0.1 to 5000 g / ha, preferably from 1 to 1000 g / ha.
  • the active compound combinations according to the invention can be used to protect plants within a certain period of time after the treatment against attack by phytopathogenic fungi and / or animal pests.
  • the period of time within which protection is afforded generally ranges from 1 to 28 days, preferably from 1 to 14 days, more preferably from 1 to 10 days, most preferably from 1 to 7 days after treatment of the plants with the active - up to 200 days after seed treatment.
  • the active compound combinations according to the invention are suitable for plant tolerance, favorable warm-blooded toxicity and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling phytopathogenic fungi such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc. and of animal pests, in particular insects, arachnids, helminths, nematodes and mollusks, used in agriculture, horticulture, livestock, forestry, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector occurrence. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the active compound combinations according to the invention have very good fungicidal properties and can be used for controlling phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
  • the active compound combinations according to the invention are particularly suitable for controlling Phytophthora infestans, Plasmopara viticola and Botrytis cinerea.
  • Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
  • pathogens of fungal and bacterial diseases which fall under the generic names enumerated above, are named: Diseases caused by powdery mildews such as e.g.
  • Blumeria species such as Blumeria graminis
  • Podosphaera species such as Podosphaera leucotricha
  • Sphaerotheca species such as Sphaerotheca fuliginea
  • Uncinula species such as Uncinula necator
  • Gymnosporangium species such as Gymnosporangium sabinae Hemileia species, such as Hemileia vastatrix;
  • Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae
  • Puccinia species such as Puccinia recondita
  • Uromyces species such as Uromyces appendiculatus
  • Bremia species such as Bremia lactucae
  • Peronospora species such as Peronospora pisi or P. brassicae;
  • Phytophthora species such as Phytophthora infestans
  • Plasmopara species such as Plasmopara viticola
  • Pseudoperonospora species such as Pseudoperonospora humuli or
  • Pythium species such as Pythium ultimum
  • Alternaria species such as Alternaria solani;
  • Cercospora species such as Cercospora beticola
  • Cladiosporum species such as Cladiosporium cucumerinum
  • Cochliobolus species such as Cochliobolus sativus
  • Colletotrichum species such as Colletotrichum lindemuthanium
  • Cycloconium species such as cycloconium oleaginum
  • Diaporthe types such as Diaporthe citri;
  • Elsinoe species such as Elsinoe fawcettii
  • Gloeosporium species such as, for example, Gloeosporium laeticolor
  • Glomerella species such as Glomerella cingulata
  • Guignardia species such as Guignardia bidwelli;
  • Leptosphaeria species such as Leptosphaeria maculans
  • Magnaporthe species such as Magnaporthe grisea
  • Mycosphaerella species such as Mycosphaerelle graminicola
  • Phaeosphaeria species such as Phaeosphaeria nodorum
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramularia species such as Ramularia collo-cygni
  • Rhynchosporium species such as Rhynchosporium secalis
  • Septoria species such as Septoria apii
  • Typhula species such as Typhula incarnata
  • Venturia species such as Venturia inaequalis
  • Root and stem diseases caused by eg Corticium species, such as Corticium graminearum;
  • Fusarium species such as Fusarium oxysporum
  • Gaeumannomyces species such as Gaeumannomyces graminis
  • Rhizoctonia species such as Rhizoctonia solani
  • Tapesia species such as Tapesia acuformis
  • Thielaviopsis species such as Thielaviopsis basicola
  • Ear and panicle diseases caused by e.g.
  • Alternaria species such as Alternaria spp .
  • Aspergillus species such as Aspergillus flavus
  • Cladosporium species such as Cladosporium spp .
  • Claviceps species such as Claviceps purpurea
  • Fusarium species such as Fusarium culmorum
  • Gibberella species such as Gibberella zeae
  • Monographella species such as Monographella nivalis
  • Sphacelotheca species such as Sphacelotheca reiliana
  • Tilletia species such as Tilletia caries
  • Urocystis species such as Urocystis occulta
  • Ustilago species such as Ustilago nuda
  • Aspergillus species such as Aspergillus flavus
  • Botrytis species such as Botrytis cinerea
  • Penicillium species such as Penicillium expansum
  • Sclerotinia species such as Sclerotinia sclerotiorum
  • Verticilium species such as Verticilium alboatrum
  • Fusarium species such as Fusarium culmorum
  • Phytophthora species such as Phytophthora cactorum
  • Pythium species such as Pythium ultimum
  • Rhizoctonia species such as Rhizoctonia solani
  • Sclerotium species such as Sclerotium rolfsii
  • Nectria species such as Nectria galligena
  • Monilinia species such as Monilinia laxa
  • Esca species such as Phaemoniella clamydospora
  • Botrytis species such as Botrytis cinerea
  • Rhizoctonia species such as Rhizoctonia solani
  • Xanthomonas species such as Xanthomonas campestris pv. Oryzae;
  • Pseudomonas species such as Pseudomonas syringae pv. Lachrymans;
  • Erwinia species such as Erwinia amylovora
  • the following diseases of soybean beans can be controlled: fungal diseases on leaves, stems, pods and seeds caused by e.g.
  • Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Powdery Mildew (Phyllosticta sojaecola) Micros
  • Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var.
  • Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregular, Pythium Debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).
  • the active compound combinations according to the invention can be used with particular success for the purpose of combating cereal diseases, such as against Puccinia species and diseases in wine, fruit and vegetable crops, such as against Botrytis, Venturia or Alternaria species use.
  • the active compound combinations according to the invention also have very good antifungal effects. They have a very broad antimycotic spectrum of activity, in particular against dermatophytes and yeasts, mold and diphasic fungi (eg against Candida species such as Candida albicans, Candida glabrata) and Epidermophyton floccosum, Aspergillus species such as Aspergillus niger and Aspergillus fumigatus, Trichophyton species such as Trichophyton mentagrophytes, Microsporon species such as Microsporon canis and audouinii. The list of these fungi is by no means a limitation of the detectable mycotic spectrum, but has only an explanatory character.
  • the active compound combinations according to the invention also have very good insecticidal effects. They have a very broad insecticidal activity spectrum, in particular against the following animal pests:
  • Anoplura e.g. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp .. From the class of the arachnids e.g.
  • Acarus spp. Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri , Eutetranychus spp., Eriophyes spp., Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Nuphersa spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phylloc
  • Anthrenus spp. Anthrenus spp., Apion spp., Apogonia spp., Atomaria spp., Attagenus spp., Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp.
  • Lucilla spp. Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia spp., Phorbia spp., Prodiplosis spp., Psila rosae, Rhagoletis spp., Stomoxys spp , Tabanus spp., Tannia spp., Tetanops spp., Tipula spp.
  • Gastropoda From the class of Gastropoda, for example Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.
  • helminths e.g. Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp, Dictyocaulus filaria, Diphyllobothrium latum , Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Ne
  • protozoa such as Eimeria
  • Lepidoptera From the order of Lepidoptera, for example, Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Barathra brassicae, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius , Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocerus spp., Cnephasia spp., Conopomorph
  • Copitarsia spp. Cydia spp., Dalaca noctuides, Diaphania spp., Diatraea saccharalis, Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Etiella spp., Eulia spp.
  • Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Dichroplus spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
  • siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.
  • Thysanoptera e.g. Anaphothrips obscurus, Baliothrips biformis, Drepanothris reuteri, Enneothrips hevens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp. From the order of Thysanura e.g. Lepisma saccharina.
  • the plant parasitic nematodes include, for example, Aphelenchoides spp., Bursaphelenchus spp., Ditylenchus spp., Globodera spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Trichodorus spp., Tylenchulus semipenetrans, Xiphinema spp ..
  • the active compound combinations according to the invention can be used to protect industrial materials against infestation and destruction by undesired microorganisms.
  • engineering materials to be protected from microbial alteration or destruction by the active compounds of the present invention may be adhesives, glues, paper and board, textiles, leather, wood, paints and plastics, coolants, and other materials that infiltrate or decompose microorganisms can be.
  • materials to be protected are also parts of production plants, such as cooling water circuits, called, which can be affected by the proliferation of microorganisms.
  • technical materials which may be mentioned are preferably adhesives, glues, papers and cartons, leather, wood, paints, cooling lubricants and heat transfer fluids, particularly preferably wood.
  • microorganisms that can cause degradation or a change in the technical materials, for example, bacteria, fungi, yeasts, algae and mucus organisms may be mentioned.
  • the active compound combinations according to the invention preferably act against fungi, in particular molds, wood-discolouring and wood-destroying fungi (Basidiomycetes) and against slime organisms and algae.
  • microorganisms of the following genera There may be mentioned, for example, microorganisms of the following genera:
  • Alternaria such as Alternaria tenuis
  • Aspergillus such as Aspergillus niger
  • Chaetomium such as Chaetomium globosum
  • Coniophora like Coniophora puetana,
  • Lentinus like Lentinus tigrinus
  • Penicillium such as Penicillium glaucum
  • Polyporus such as Polyporus versicolor
  • Aureobasidium such as Aureobasidium pullulans
  • Sclerophoma such as Sclerophoma pityophila
  • Trichoderma like Trichoderma viride
  • Escherichia like Escherichia coli
  • Pseudomonas such as Pseudomonas aeruginosa
  • Staphylococcus such as Staphylococcus aureus.
  • insects By way of example and preferably without limiting however, the following insects are mentioned: Beetles such as Hylotrupes b Camillus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
  • Hymenoptera such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.
  • Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
  • Bristle tails like Lepisma saccharina.
  • Non-living materials such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.
  • the material to be protected from insect attack is wood and woodworking products.
  • wood and wood products which can be protected by the active compound combinations according to the invention, is to be understood by way of example: timber, wooden beams, railway sleepers, bridge parts, boat jetties, wooden vehicles, crates, pallets, containers, telephone poles, wood cladding, wooden windows and doors, plywood, chipboard, Carpentry or wood products commonly used in home construction or joinery.
  • the active compound combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
  • the formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments, and further processing aids.
  • the insecticidal active ingredient combinations or concentrates used for the protection of wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60 wt .-%.
  • the amount of active ingredient combinations or concentrates used depends on the nature and occurrence of the insects and on the medium. The optimal amount used can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the material to be protected.
  • insects in particular insects, arachnids and mites, which are used in enclosed spaces such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
  • Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
  • Araneae e.g. Aviculariidae, Araneidae.
  • Opiliones e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
  • Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
  • Anthrenus spp. From the order of Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
  • Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
  • Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
  • Ctenocephalides canis Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
  • Hymenoptera e.g. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
  • Anoplura e.g. Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis.
  • Heteroptera e.g. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.
  • Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprayers, fog machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-less or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in straw baits or bait stations.
  • Pump and atomizer sprayers fog machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-less or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in straw baits or bait stations.
  • the active compound combinations of the invention not only against plant, hygiene and storage pests, but also in the veterinary sector against animal parasites (ectoparasites) such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, Featherlings and fleas.
  • animal parasites ectoparasites
  • ticks leather ticks, mange mites, mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, Featherlings and fleas.
  • Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
  • Nematocerina and Brachycerina eg Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp.
  • Atylotus spp. Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilla spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
  • siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
  • heteropterid e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
  • Actinedida Prostigmata
  • Acaridida Acaridida
  • Acarapis spp. Cheyletiella spp., Omithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp , Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.
  • the active compound combinations according to the invention are also suitable for controlling arthropods, the livestock, such as cattle, sheep, goats, horses, pigs, donkeys, camels, buffalos, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs , Cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested.
  • livestock such as cattle, sheep, goats, horses, pigs, donkeys, camels, buffalos, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs , Cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested.
  • the application of the active compound combinations according to the invention takes place in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boluses, the feed-through process, suppositories, by parenteral Administration, for example by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, dipping or bathing (dipping), spraying, pouring (pour-on and spot -on), washing, powdering and with the aid of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.
  • enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boluses, the feed-through process, suppositories
  • parenteral Administration for example by injection
  • the active ingredient combinations When used for livestock, poultry, pets, etc., the active ingredient combinations may be used as formulations (for example, powders, emulsions, flowables) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath.
  • the active compound combinations according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as anti-MLO agents ( Mycoplasma-like-organism) and RLO (Rickettsia-like-organism).
  • the present invention further relates to formulations and application forms prepared therefrom as crop protection agents and / or pesticides such.
  • B. drench, drip and spray comprising at least one of the active compound combinations according to the invention.
  • the use forms contain other crop protection agents and / or pesticides and / or the effect of improving adjuvants such as penetration enhancers, eg.
  • vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetal fatty acids such as rapeseed oil or soybean oil methyl ester or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts, e.g.
  • organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such.
  • Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ;
  • SL water-soluble liquids
  • EC emulsion concentrates
  • EW emulsions in water
  • SC suspension concentrates
  • SC SE, SE, FS, OD
  • WG water-dispersible granules
  • GR granules
  • capsule concentrates CS
  • the formulations contain in addition to one or more active substances according to the invention further agrochemical active substances.
  • auxiliaries such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, for example adjuvants.
  • An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect.
  • Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.
  • formulations are prepared in a known manner, e.g. by mixing the active ingredients with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants.
  • the preparation of the formulations is carried out either in suitable systems or before or during use.
  • excipients there may be used those substances which are suitable for conferring special properties, such as certain physical, technical and / or biological properties, to the formulation of the active substance or to the forms of use prepared from these formulations (for example usable plant protection agents such as spray or seed dressing).
  • polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes
  • alcohols and polyols which may also be substituted, etherified and / or esterified
  • ketones such as
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • alcohols such as butanol or glycol and their ethers and esters
  • ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Suitable solvents are, for example, aromatic hydrocarbons, such as, for example, xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, such as chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, such as methanol, ethanol, iso-propanol, butanol or glycol and their ethers and Esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide, and water.
  • aromatic hydrocarbons such as, for example, xylene, toluene or alkylnaphthalenes
  • chlorinated aromatic or aliphatic hydrocarbons such as chlorobenzene, chloroethylene,
  • Suitable carriers are, in particular: Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used.
  • Suitable carriers for granules are: e.g.
  • liquefied gaseous diluents or solvents can be used.
  • Particularly suitable are those diluents or carriers which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
  • Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyltaurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, for example alkylarylpolyglycol ethers, alkyl- sulfonates, alkyl sulfates, arylsulfonates, protein
  • a surfactant is advantageous when one of the active ingredients and / or one of the inert carriers is not soluble in water and when applied in water.
  • dyes such as inorganic pigments, eg iron oxide, titanium oxide, ferrocyan blue and organic dyes, such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients, such as salts of iron, manganese, boron, in the formulations and the applications derived therefrom, can be used. Copper, cobalt, molybdenum and zinc may be present.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers.
  • formulations and applications derived therefrom may also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins, and synthetic phospholipids.
  • additional auxiliaries may be mineral and vegetable oils.
  • auxiliaries may be present in the formulations and in the use forms derived therefrom.
  • additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents.
  • the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.
  • retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.
  • Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants.
  • Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle.
  • the method described in the literature can be used to determine this property.
  • Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12)
  • fatty acid esters such as rapeseed oil or soybean oil
  • fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms is in the range of 0.00000001 to 97 wt .-% of active ingredient, preferably in the range of 0.0000001 to 97 wt .-%, particularly preferably in the range of 0.000001 to 83 wt .-% or 0, 000001 to 5 wt .-% and most preferably in the range of 0.0001 to 1 wt .-%.
  • the active compound combinations according to the invention can be present in their commercially available formulations and in the formulations prepared from these formulations in admixture with other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals.
  • active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals.
  • a mixture with other known active ingredients, such as herbicides, fertilizers, growth regulators, safeners, semiochemicals, or with agents for improving the plant properties is possible.
  • the active compound combinations according to the invention can furthermore be present in mixtures with synergists when used as fungicides and / or insecticides in their commercial formulations and in the forms of use prepared from these formulations.
  • synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.
  • the active compound combinations according to the invention can also be present in their commercial formulations and in the forms of use prepared from these formulations in mixtures with inhibitors which inhibit degradation of the active substance after application in the environment of the plant, on the surface of plant parts or in plant tissues.
  • the application is done in a custom forms adapted to the application forms.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including plant varieties that can be protected or not protected by plant variety protection rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes.
  • the plant parts also include crops and vegetative and generative propagation material, for example fruits, seeds, cuttings, tubers, rhizomes, offshoots, seeds, bulbs, sinkers and shoots.
  • the treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, eg by dipping, spraying, evaporating, atomizing, spreading, spreading painting, injecting and propagating material, in particular seed, by single or multi-layer coating.
  • the active substance combinations can be prepared before the treatment by mixing the individual active ingredients. Or the treatment is carried out successively by using first a compound of formula (I) or (1-1) followed by treatment with a group II active ingredient. However, it is also possible to first treat the plants or plant parts with a group II active ingredient and to join the treatment with a compound of formula I or (1-1).
  • plants which can be treated according to the invention mention may be made of the following: cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (for example, pome fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp.
  • Rosaceae sp. for example, pome fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries
  • Rosaceae sp. for example, pome fruits such as apple and pear
  • Rubiaceae sp. for example, coffee
  • Theaceae sp. Sterculiceae sp.
  • Rutaceae sp. for example, lemons, organs and grapefruit
  • Solanaceae sp. for example tomatoes
  • Liliaceae sp. Asteraceae sp.
  • Umbelliferae sp. for example, Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (for example cucumber), Alliaceae sp. leek, onion), Papilionaceae sp.
  • Main crops such as Gramineae sp. (for example corn, turf, cereals such as wheat, rye, rice, barley, oats, millet and triticale), Asteraceae sp. (for example sunflower), Brassicaceae sp. (for example, white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radishes and rapeseed, mustard, horseradish and cress), Fabacae sp. (for example, bean, peanuts), Papilionaceae sp. (for example, soybean), Solanaceae sp. (for example potatoes), Chenopodiaceae sp. (for example, sugar beet, fodder beet, Swiss chard, beet); Crops and ornamental plants in the garden and forest.
  • Gramineae sp. for example corn, turf, cereals such as wheat, rye, rice, barley, oats, mille
  • the treatment according to the invention can also lead to superadditive (“synergistic”) effects.
  • the following effects are possible, which go beyond the expected effects: reduced application rates and / or extended spectrum of action and / or increased efficacy of the active ingredients and compositions that can be used according to the invention, better plant growth, increased tolerance to high or low Temperatures, increased tolerance to drought or water or soil salinity, increased flowering, harvest relief, ripening, higher yields, larger fruits, greater plant height, intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, better storage and / or processability of the harvested products.
  • the active compound combinations according to the invention can also exert a strengthening effect on plants. They are therefore suitable for mobilizing the plant defense system against attack by undesirable phytopathogenic fungi and / or microorganisms and / or viruses. This may optionally be one of the reasons for the increased effectiveness of the combinations according to the invention, for example against fungi.
  • Plant-strengthening (resistance-inducing) substances in the present context should also mean those substances or combinations of substances which are able to stimulate the plant defense system so that the treated plants, when subsequently inocculated with undesirable phytopathogenic fungi and / or microorganisms and / or viruses a considerable degree of resistance to these unwanted phytopathogenic fungi and / or microorganisms and / or viruses.
  • phytopathogenic fungi, bacteria and viruses are understood to be undesirable phytopathogenic fungi and / or microorganisms and / or viruses.
  • the substances according to the invention can therefore be employed for the protection of plants against attack by the mentioned pathogens within a certain period of time after the treatment.
  • the period of time over which a protective effect is achieved generally extends from 1 to 10 days, preferably 1 to 7 days, after the treatment of the plants with the active substances.
  • Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology). Plants and plant varieties which are also preferably treated according to the invention are resistant to one or more biotic stressors, i. H. These plants have an improved defense against animal and microbial pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids.
  • Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties.
  • An increased yield can in these plants z. B. based on improved plant physiology, improved plant growth and improved plant development, such as water efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination and accelerated Abreife.
  • Yield can be further influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for hybrid seed production, seedling vigor, plant size, internode count and spacing, root growth, seed size, fruit size, Pod size, pod or ear number, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed drop, reduced pod popping and stability.
  • Other yield-related traits include seed composition such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction of nontoxic compounds, improved processability, and improved shelf life.
  • Plants which can be treated according to the invention are hybrid plants which already express the properties of heterosis or hybrid effect, which generally leads to higher yield, higher vigor, better health and better resistance to biotic and abiotic stress factors.
  • Such plants are typically produced by crossing an inbred male sterile parental line (the female crossover partner) with another inbred male fertile parent line (the male crossbred partner).
  • the hybrid seed is typically harvested from the male sterile plants and sold to propagators.
  • Pollen sterile plants can sometimes be produced (eg in maize) by delaving (ie mechanical removal of the male reproductive organs or the male flowers); however, it is more common for male sterility to be due to genetic determinants in the plant genome.
  • cytoplasmic male sterility have been described, for example, for Brassica species (WO 1992/005251, WO 1995/009910, WO 1998/27806, WO 2005/002324, WO 2006/021972 and US 6,229,072).
  • pollen sterile plants can also be obtained using plant biotechnology methods such as genetic engineering.
  • a particularly convenient means of producing male-sterile plants is described in WO 89/10396, wherein, for example, a ribonuclease such as a barnase is selectively expressed in the tapetum cells in the stamens. The fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells (eg WO 1991/002069).
  • Plants or plant varieties which can be treated according to the invention are herbicidally tolerant plants, ie plants made tolerant to one or more given herbicides. Such plants can be obtained by selection of plants containing a mutation conferring such herbicide tolerance.
  • the active compound combinations according to the invention are suitable for the treatment of seed. Preference is given to mention the combinations according to the invention mentioned above as being preferred or particularly preferred.
  • a large part of the damage to crops caused by phytopathogenic fungi and / or animal pests already occurs through the infestation of the seed during storage and after introduction of the seed into the soil and during and immediately after germination of the plants.
  • This phase is particularly critical, as the roots and shoots of the growing plant are particularly sensitive and even minor damage can lead to the death of the entire plant.
  • the control of phytopathogenic fungi and / or animal pests by the treatment of the seed of plants has long been known and is the subject of constant improvement. Nevertheless, there are a number of problems in the treatment of seeds that can not always be satisfactorily resolved. Thus, it is desirable to develop methods of protecting the seed and the germinating plant, which eliminate the need for additional crop protection after sowing or after emergence of the plants.
  • methods for treating seed should also include the intrinsic fungicidal and / or insecticidal properties of transgenic plants in order to achieve optimum protection of the seed and also the germinating plant with a minimum of pesticides.
  • the present invention therefore also relates, in particular, to a method for protecting seed and germinating plants from infestation by phytopathogenic fungi and / or animal pests by treating the seed with a combination of active substances according to the invention.
  • the method according to the invention for protecting seed and germinating plants from infestation by phytopathogenic fungi and / or animal pests comprises a method in which the seed is at the same time treated with a compound of the formula (I) and an active compound from the above-mentioned group (II ) is treated. It also comprises a process in which the seed is treated at different times with a compound of formula (I) and an active ingredient from the group (II) listed above.
  • the invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the germinating plant from phytopathogenic fungi and / or by phytopathogenic fungi and / or animal pests. Furthermore, the invention relates to seed which has been treated with a combination of active substances according to the invention for protection against phytopathogenic fungi and / or animal pests. The invention also relates to seed treated at the same time with a compound of formula (I) and a group II active ingredient. The invention further relates to seed which has been treated at different times with a compound of formula (I) and a group II active ingredient.
  • the individual active compounds of the active ingredient combination according to the invention may be present in different layers on the seed.
  • the layers which comprise a compound of the formula (I) and an active compound from group II may optionally be separated by an intermediate layer.
  • the invention also relates to seed in which a compound of formula (I) and an active compound from group II are applied as part of a coating or as a further layer or further layers in addition to a coating.
  • An advantage of the present invention is the synergistic increase in the insecticidal activity of the active compound combinations according to the invention over the insecticidal single active substance, which goes beyond the expected efficacy of the two individually applied active ingredients. Also advantageous is the synergistic increase in the fungicidal activity of the active compound combinations according to the invention compared with the fungicidal single active substance, which goes beyond the expected effectiveness of the individually applied active ingredient. This allows optimization of the amount of active ingredients used. Likewise, it is considered to be advantageous that the active compound combinations according to the invention can be used in particular also in transgenic seed.
  • the active compound combinations according to the invention are suitable for the protection of seed of any plant variety as already mentioned above, which is used in agriculture, in the greenhouse, in forests or in horticulture.
  • these are corn, peanut, canola, rapeseed, poppy, soybean, cotton, turnip (eg sugarbeet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower, tobacco, potatoes or vegetables ( eg tomatoes, cabbages, Salad, etc.).
  • the active compound combinations according to the invention are likewise suitable for the treatment of the seed of fruit plants and vegetables as already mentioned above.
  • the active ingredient combination according to the invention is applied to the seed alone or in a suitable formulation.
  • the seed is treated in a state where it is so stable that no damage occurs during the treatment.
  • the treatment of the seed can be done at any time between harvesting and sowing.
  • seed is used which has been separated from the plant and freed from flasks, shells, stems, hull, wool or pulp.
  • seed may be used which has been harvested, cleaned and dried to a moisture content below 15% by weight.
  • seed can also be used, which after drying, for example, treated with water and then dried again.
  • the amount of the active ingredient combination and / or other additives applied to the seed is chosen so that germination of the seed is not impaired or the resulting plant is not damaged. This is especially important for active ingredients, which can show phytotoxic effects in certain application rates.
  • the agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to those skilled in the art and are described e.g. in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 AI, WO 2002/080675 AI, WO 2002/028186 A2.
  • the active compounds which can be used according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.
  • formulations are prepared in a known manner by mixing the active ingredients with conventional additives, such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and water.
  • conventional additives such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and water.
  • Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. There are both in Water sparingly soluble pigments as well as water-soluble dyes usable. Examples which may be mentioned are the dyes known under the names Rhodamine B, CI Pigment Red 112 and CI Solvent Red 1.
  • Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds. Preference is given to using alkylnaphthalene sulfonates, such as diisopropyl or diisobutylnaphthalene sulfonates.
  • Suitable dispersants and / or emulsifiers which may be present in the seed dressing formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active compounds.
  • Preferably usable are nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants.
  • Particularly suitable nonionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
  • Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.
  • Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds.
  • Defoamers which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Examples include dichlorophen and Benzylalkoholhemiformal.
  • Suitable secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica.
  • Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents.
  • polyvinylpyrrolidone polyvinyl acetate, polyvinyl alcohol and Tylose.
  • the gibberellins are known (see R. Wegler "Chemie der convinced- und Swdlingsbekungsstoff", Vol. 2, Springer Verlag, 1970, p. 401-412).
  • the seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds, including seed of transgenic plants. In this case, additional synergistic effects may occur in interaction with the substances formed by expression.
  • the seed dressing formulations which can be used according to the invention or the preparations prepared therefrom by the addition of water
  • all mixing devices customarily usable for the dressing can be considered.
  • the seed is placed in a mixer which adds either desired amount of seed dressing formulations either as such or after prior dilution with water and mixes until evenly distributed the formulation on the seed.
  • a drying process follows.
  • the active compound combinations according to the invention are also suitable for increasing crop yield. They are also low toxicity and have good plant tolerance.
  • the active compound combinations according to the invention also have a strong tonic effect in plants. They are therefore suitable for mobilizing plant-own defenses against attack by unwanted microorganisms.
  • plant-strengthening (resistance-inducing) substances are to be understood as meaning those substances which are capable of stimulating the defense system of plants in such a way that the treated plants exhibit extensive resistance to these microorganisms with subsequent inoculation with undesired microorganisms.
  • Undesirable microorganisms in the present case are phytopathogenic fungi, bacteria and viruses.
  • the substances according to the invention can therefore be used to protect plants within a certain period of time after the treatment against the infestation by the said pathogens.
  • the period within which protection is provided generally extends from 1 to 10 days, preferably 1 to 7 days after the treatment of the plants with the active ingredients.
  • the listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention.
  • the preferred ranges given above for the active substance combinations also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the active ingredient combinations specifically mentioned in the present text.
  • the good insecticidal and fungicidal action of the active compound combinations according to the invention is evident from the examples below. While the individual active ingredients have weaknesses in their effect, the combinations show an effect that goes beyond a simple sum of effects. A synergistic effect is always present in the case of insecticides and fungicides whenever the insecticidal or fungicidal action of the active substance combinations is greater than the sum of the effects of the individually applied active substances.
  • X means the degree of killing or efficiency, expressed in% of the untreated control, when using the active substance A in an application rate of m ppm or g / ha,
  • Y means the degree of killing or efficiency, expressed in% of the untreated control, when using the active ingredient B at an application rate of n ppm or g / ha, and
  • E means the degree of killing or efficiency, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and nppm or g / ha,
  • the degree of kill or efficiency is determined in%. It means 0% a degree of kill or efficiency equal to that of the control, while a kill rate of 100% means that all animals are dead and an efficiency of 100% means that no infestation is observed.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica oleracea) which are heavily infested with the green peach aphid (Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and with larvae of the horseradish beetle (Phaedon cochleariae) as long as the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Table B 1 Phaedon cochleariae larval test
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • Cabbage leaves (Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm (Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cotton leaves which are heavily infested with the cotton aphid (Aphis gossypii) are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica oleracea) which are heavily infested with the green peach aphid (Myzus persicae) are treated by dripping wet spray with the preparation of active compound in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula.

Abstract

The present invention relates to novel active substance combinations which are composed of the insecticidally active compounds of the formula (I) in combination with fungicidal active substances (II) and which are highly suitable for controlling undesirable animal pests such as insects and undesirable phytopathogenic fungi.

Description

Anthranilsäureamide in Kombination mit Fungiziden  Anthranilic acid amides in combination with fungicides
Die vorliegende Erfindung betrifft neue Wirkstoffkombinationen, die aus den insektizid wirksamen Verbindungen der Formel (I) in Kombination mit funigiziden Wirkstoffen (II) bestehen und sehr gut zur Bekämpfung von unerwünschten tierischen Schädlingen wie Insekten, Akariziden und/oder Nematoden sowie unerwünschten phytopathogenen Pilzen geeignet sind. The present invention relates to new active compound combinations which consist of the insecticidally active compounds of the formula (I) in combination with fungicidal active compounds (II) and are very suitable for controlling undesired animal pests such as insects, acaricides and / or nematodes and undesired phytopathogenic fungi ,
Die Anthranilsäureamide der Formel (I) sind teils aus WO 2007/144100 bekannt und ihre Insektizide Wirkung beschrieben. Die in dieser Beschreibung mit ihrem„common name" genannten Wirkstoffe sind beispielsweise aus„The Pesticide Manual" 14th Ed., British Crop Protection Council 2006, und der Webseite http://www.alanwood.net/pesticides bekannt. Die Insektizide oder fungizide Wirksamkeit und / oder Wirkungsbreite und / oder die Pflanzenverträglichkeit der bekannten Verbindungen, insbesondere gegenüber Kulturpflanzen, ist jedoch nicht immer ausreichend. The anthranilic acid amides of the formula (I) are known in part from WO 2007/144100 and describe their insecticidal activity. The active ingredients mentioned in this specification with their "common name" are known, for example, from "The Pesticide Manual" 14th Ed., British Crop Protection Council 2006, and the website http://www.alanwood.net/pesticides. However, the insecticidal or fungicidal activity and / or range of action and / or the plant tolerance of the known compounds, in particular to crops, is not always sufficient.
Es wurde nun gefunden, dass Wirkstoffkombinationen enthaltend die Verbindungen der allgemeinen Formel (I), It has now been found that active ingredient combinations comprising the compounds of the general formula (I)
für Wasserstoff, Amino, Hydroxy oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl oder C3-C6-Cycloalkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Nitro, Hydroxy, C C4-Alkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, CrC4-Alkylsul- fonyl, (C C4-Alkoxy)carbonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6-Cycloalkyl- amino oder (Ci-C4-Alkyl)C3-C6-cycloalkylamino, für Wasserstoff, C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C4-Alkoxy, C C4-Alkylamino, Di-(C C4-alkyl)amino, C3-C6-Cycloalkylamino, Ci-C6-Alkoxycarbonyl oder Ci-Cö-Alkylcarbonyl steht, für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes C C6-Alkyl, C C6-Alkoxy, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-Ci2-Cycloalkyl, C3- Ci2-Cycloalkyl-Ci-C6-Alkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Amino, C3-C6-Cycloalkyl-amino, Halogen, Cyano, Carboxy, Carbamoyl Nitro, Hydroxy, C C6-Alkyl, C C6-Haloalkyl, C3-C6-Cycloalkyl, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C6-Alkoxycarbonyl, C C6- Alkylcarbonyl , C3-C6-Trialkylsilyl oder einem gesättigten oder teilgesättigten heterocyclischen Ring, einem aromatischen oder heteroaromatischen Ring oder einem gesättigten, teilgesättigten oder aromatischen hetero-bizyklischen Ring, wobei der Ring oder das Ringsystem gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist mit SF5, Halogen, Cyano, Nitro, Hydroxy, Amino, Carboxy, Carbamoyl, Aminosulfonyl, Ci-C6-Alkyl, C3-C6-Cycloalkyl, C C4- Alkoxy, Ci-C6-Haloalkyl, C C4-Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4- Alkylsulfonyl, C C4-Alkylsulfimino, Ci-C4-Alkylsulfimino-Ci-C4-alkyl, Ci-C4-Alkylsulfimino- C2-C5-alkylcarbonyl, Ci-C4-Alkylsulfoximino, Ci-C4-Alkylsulfoximino-Ci-C4-alkyl, C1-C4- Alkylsulfoximino-C2-C5-alkylcarbonyl, Ci-C6-Alkoxycarbonyl, Ci-C6-Alkylcarbonyl, C3-C6-Tri- alkylsilyl, Benzyl C2-C6-Alkenyl, C2-C6-Alkinyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6- Halocycloalkyl, Ci-C4-Haloalkylthio, Ci-C4-Haloalkylsulfinyl, Ci-C4-Haloalkylsulfonyl, C1-C4- Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6-Cycloalkylamino, oder einem 3- bis 6-gliedrigen Ring, wobei der Ring gegebenenfalls substituiert sein kann durch Ci-C6-Alkyl, Halogen, Cyano, Nitro, Halogen(C C6)-Alkyl, C C6-Alkoxy oder Halogen(C C6)-Alkoxy, oder represents hydrogen, amino, hydroxy, or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl or C 3 -C 6 -cycloalkyl, where the substituents may be independently selected from halogen, cyano, nitro, hydroxy, CC 4 -alkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, C r C 4 -Alkylsul- fonyl, (CC 4 -alkoxy) carbonyl, C -C 4 alkylamino, di- (Ci-C 4 alkyl) amino, C 3 -C 6 cycloalkyl, amino or (Ci-C 4 alkyl) C 3 -C 6 cycloalkylamino, hydrogen, CC 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, CC 4 alkoxy, CC 4 alkylamino, di- (CC 4 alkyl) amino, C 3 -C 6 cycloalkylamino , Ci-C6-alkoxycarbonyl or Ci-COE-alkylcarbonyl, represents hydrogen or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents CC 6 alkyl, CC 6 alkoxy, C 2 -C 6 alkenyl, C 2 -C 6 -alkynyl, C 3 -C 2 cycloalkyl, C 3 - Ci 2 -cycloalkyl-Ci-C6-alkyl, wherein the substituents may be independently selected from amino, C 3 -C 6 -cycloalkyl-amino, halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, CC 6 alkyl, CC 6 haloalkyl, C 3 -C 6 cycloalkyl, CC 4 alkoxy, CC 4 haloalkoxy, CC 4 alkylthio, C 1 -C 4 alkylsulfmyl, CC 4 alkylsulfonyl, CC 6 alkoxycarbonyl, CC 6 alkylcarbonyl, C C 3 -C 6 -trialkylsilyl or a saturated or partially saturated heterocyclic ring, an aromatic or heteroaromatic ring or a saturated, partially saturated or aromatic heterocyclic ring, where the ring or the ring system is optionally monosubstituted or polysubstituted, identically or differently, by SF 5 , halogen, cyano, nitro, hydroxy, amino, carboxy, carbamoyl, aminosulfonyl, Ci-C 6 alkyl, C 3 -C 6 cycloalkyl, CC 4 - alkoxy, Ci-C 6 haloalkyl, haloalkoxy CC 4, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 - alkylsulfonyl, CC 4 -Alkylsulfimino, Ci-C 4 -Alkylsul fimino-Ci-C4-alkyl, Ci-C 4 -Alkylsulfimino- C 2 -C 5 alkylcarbonyl, Ci-C 4 -Alkylsulfoximino, Ci-C 4 -Alkylsulfoximino-C 4 alkyl, C 1 -C 4 Alkylsulfoximino-C 2 -C 5 -alkylcarbonyl, C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylcarbonyl, C 3 -C 6 -trialkylsilyl, benzyl C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 - halocycloalkyl, Ci-C4-haloalkylthio, Ci-C4-haloalkylsulfinyl, Ci-C4-haloalkylsulfonyl, C 1 -C 4 - Alkylamino, di- (C 1 -C 4 -alkyl) amino, C 3 -C 6 -cycloalkylamino, or a 3 to 6-membered ring, where the ring may optionally be substituted by C 1 -C 6 -alkyl, halogen, cyano, Nitro, halo (CC 6 ) alkyl, CC 6 alkoxy or halo (CC 6 ) alkoxy, or
R3 für Ci-Cö-Alkoxycarbonyl, Ci-C6-Alkylcarbonyl, Ci-Cö-Alkylaminocarbonyl oder Di(d- C6)alkylaminocarbonyl steht, oder R 3 is C 1 -C 6 -alkoxycarbonyl, C 1 -C 6 -alkylcarbonyl, C 1 -C 6 -alkylaminocarbonyl or di (C 1 -C 6) -alkylaminocarbonyl, or
R3 weiterhin für einen einfach oder mehrfach, gleich oder verschieden substituierten 5- oder 6- gliedrigen aromatischen oder heteroaromatischen Ring, einen 4, 5- oder 6-gliedrigen teilweise gesättigten Ring oder gesättigten heterozyklischen Ring, oder einen gesättigten, teilgesättigten oder aromatischen hetero-bizyklischen Ring steht, welcher gegebenenfalls ein bis drei Heteroatome aus der Reihe O, S oder N enthalten kann, wobei die Substituenten unabhängig voneinander ausgewählt sind aus SF5; Halogen, Cyano, Nitro, Hydroxy, Amino, Carboxy, Carbamoyl, Ci-C6-Alkyl, C3-C6-Cycloalkyl, C C4-Alkoxy, Ci-Cö-Haloalkyl, Ci-C4-Haloalkoxy, C C4-Alkylthio, C1-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C1-C4-Alkylsulfimino, C C4- Alkylsulfimino-Ci -C4-alkyl, Ci -C4-Alkylsulfimino-C 1 -C5-alkylcarbonyl, C 1 -C4-Alkylsulfoximino, C i-C4-Alkylsulfoximino-Ci -C4-alkyl, Ci -C4-Alkylsulfoximino-C2-C5-alkylcarbonyl, C 1 -C - Alkoxycarbonyl, Ci-C6-Alkylcarbonyl, C3-C6-Trialkylsilyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C2-C6- Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Ci-C4-Haloalkylthio, C1-C4- Haloalkylsulfinyl, C C4-Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6- Cycloalkylamino, oder einem 3- bis 6-gliedrigen Ring, wobei der Ring geben enfalls substituiert sein kann durch Ci-C6-Alkyl, Halogen, Cyano Nitro, Halogen(C C6)-Alkyl, Ci-C6-Alkoxy oder Halogen(C C6)-Alkoxy, R 3 furthermore represents a singly or multiply, identically or differently substituted 5- or 6-membered aromatic or heteroaromatic ring, a 4, 5 or 6-membered partially saturated ring or saturated heterocyclic ring, or a saturated, partially saturated or aromatic heteroaromatic ring; bicyclic ring, which may optionally contain one to three heteroatoms from the series O, S or N, wherein the substituents are independently selected from SF 5; Halogen, cyano, nitro, hydroxy, amino, carboxy, carbamoyl, Ci-C 6 alkyl, C 3 -C 6 cycloalkyl, CC 4 -alkoxy, Coe-haloalkyl, Ci-C4-haloalkoxy, CC 4 - alkylthio, C 1 -C 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, C 1 -C 4 -Alkylsulfimino, CC 4 - Alkylsulfimino-Ci-C4-alkyl, Ci-C4 -Alkylsulfimino-C 1 -C 5 alkylcarbonyl, C 1 -C 4 -Alkylsulfoximino, C iC 4 -Alkylsulfoximino-Ci-C4-alkyl, Ci-C4 -Alkylsulfoximino-C 2 -C 5 alkylcarbonyl, C 1 -C - alkoxycarbonyl, Ci-C 6 alkylcarbonyl, C 3 -C 6 trialkylsilyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 2 -C 6 - haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, C 4 haloalkylthio, C 1 -C 4 - haloalkylsulfinyl, CC 4 haloalkylsulfonyl, Ci-C 4 alkylamino, di- (Ci-C 4 alkyl) amino, C 3 -C 6 - cycloalkylamino, or a 3- to 6- the ring may optionally be substituted by Ci-C 6 alkyl, halogen, cyano nitro, halogen (C C6) alkyl, Ci-C 6 alkoxy or Halogen (CC 6 ) -alkoxy,
R2 und R3 miteinander über zwei bis sechs Kohlenstoffatome verbunden sein können und einen Ring ausbilden, der gegebenenfalls zusätzlich ein weiteres Stickstoff-, Schwefel- oder Sauerstoffatom enthält und gegebenenfalls einfach bis vierfach mit Ci-C2-Alkyl, Ci-C2-Haloalkyl, Halogen, Cyano, Amino Ci-C2-Alkoxy oder d-C2-Haloalkoxy substituiert sein kann, R 2 and R 3 may be connected to each other via two to six carbon atoms and form a ring which optionally additionally contains a further nitrogen, sulfur or oxygen atom and optionally monosubstituted to fourfold with C 1 -C 2 -alkyl, C 1 -C 2 - Haloalkyl, halogen, cyano, amino Ci-C 2 alkoxy or dC 2 haloalkoxy may be substituted,
R2, R3 weiterhin gemeinsam für =S(C C4-Alkyl)2, =S(0)(C C4-Alkyl)2, stehen, R 2 , R 3 furthermore together stand for = S (CC 4 -alkyl) 2 , = S (O) (CC 4 -alkyl) 2 ,
R4 für Wasserstoff, Halogen, Cyano, Nitro C C4-Alkyl, C C4-Haloalkyl, C2-C6-Alkenyl, C2-C6- Haloalkenyl, C2-C6-Alkinyl, C C4-Alkoxy, C C4-Haloalkoxy, SF5, C C4-Alkylthio, C C4- Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Halo-alkyl-sulfmyl, C C4- Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6-Cycloalkylamino, (C1 -C4- Alkoxy)imino, (Ci-C4-Alkyl)(Ci-C4-Alkoxy)imino, (C C4-Haloalkyl)(Ci-C4-Alkoxy)imino oder C3-C6-Trialkylsilyl steht, oder zwei R4 über benachbarte Kohlenstoffatome einen Ring ausbilden, der für -(CH2)3-, -(CH2)4-, -(CH2)5-, - (CH=CH-)2-, -OCH20-, -0(CH2)20-, -OCF20-, -(CF2)20-, -0(CF2)20-, -(CH=CH-CH=N)- oder - (CH=CH-N=CH)- steht, zwei R4 weiterhin über benachbarte Kohlenstoffatome die folgenden anellierten Ringe ausbilden, die gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert sind, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-Cö-Alkyl, C3-C6- Cycloalkyl, C C6-Haloalkyl, C3-C6-Halocycloalkyl, Halogen, C C6-Alkoxy, Ci-C4-Alkylthio(Ci-C6- alkyl), Ci-C4-Alkylsulfmyl(Ci-C6-alkyl), C C4-Alkylsulfonyl(Ci-C6-alkyl), Ci-C4-Alkylamino, Di-(C C4-alkyl)amino oder C3-C6-Cycloalkylamino, R 4 is hydrogen, halogen, cyano, nitro CC 4 alkyl, CC 4 haloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, C 2 -C 6 alkynyl, CC 4 alkoxy, CC 4 haloalkoxy, SF 5, CC 4 alkylthio, CC 4 - Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 -halo-alkyl-sulfmyl, CC 4 - haloalkylsulfonyl, Ci-C 4 alkylamino, di- (Ci-C 4 alkyl) amino, C 3 -C 6 cycloalkylamino, (C 1 -C4- alkoxy) imino, (Ci-C 4 alkyl) (Ci-C 4 alkoxy) imino, (CC 4 -haloalkyl ) (Ci-C 4 -alkoxy) imino or C 3 -C 6 -trialkylsilyl, or two R 4 form a ring via adjacent carbon atoms, which is - (CH 2 ) 3 -, - (CH 2 ) 4 -, - (CH 2 ) 5 -, - (CH = CH-) 2 -, -OCH 2 O-, -O (CH 2 ) 2 O-, -OCF 2 O-, - (CF 2 ) 2 O-, -O (CF 2 ) 2 0-, - (CH = CH-CH = N) - or - (CH = CH-N = CH) -, two R 4 continue to form the following fused rings via adjacent carbon atoms, optionally simple or repeatedly, the same or different substituted, wherein the substituents independently selected ählt may be selected from hydrogen, Ci-C ö alkyl, C3-C6 cycloalkyl, CC 6 haloalkyl, C 3 -C 6 halocycloalkyl, halogen, CC 6 alkoxy, Ci-C 4 alkylthio (Ci-C 6 - alkyl), Ci-C 4 -Alkylsulfmyl (Ci-C 6 alkyl), CC 4 alkylsulfonyl (Ci-C 6 alkyl), Ci-C 4 alkylamino, di- (CC 4 alkyl) amino or C 3 -C 6 -cycloalkylamino,
n für 0 bis 3 steht, für C C6-Alkyl, C3-C6-Cycloalkyl, C C6-Haloalkyl, C C6-Halocycloalkyl, C2-C6-Alkenyl, C2- Cö-Haloalkenyl, C2-C6-Alkinyl, C2-C6-Haloalkinyl, d-C4-Alkoxy, d-C4-Haloalkoxy, C1 -C4- Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkyl- sulfinyl, Ci-C4-Haloalkylsulfonyl, Halogen, Cyano, Nitro oder C3-C6-Trialkylsilyl steht, für einen gegebenenfalls einfach oder mehrfach, gleich oder verschieden durch R7 substituierten, aromatischen oder heteroaromatischen 5-bis 6-gliedrigen Ring steht, welcher 1-3 Heteroatome aus der Reihe N, S, O enthalten kann, für gegebenenfalls, einfach oder mehrfach, substituiertes -(Ci-C6-alkylen)-, -(C2-C6-alkenylen)-, - (C2-C6-alkinylen)-, -R8-(C3-C6-Cycloalkyl)-R8-, -R8-0-R8-, -R8-S-R8-, -R8-S(=0)-R8-, -R8-S(=0)2- R8-, -R8-N(C C6-Alkyl)-R8-, -R8-C=NO(C C6-Alkyl)- R8, -CH[C02(C C6-Alkyl)-, -R8-C(=0)- R8, -R8-C(=0)NH-R8, R8-C(=0)N(C C6-Alkyl)-R8, -R8-C(=0)NHNH-R8-, -R8-C(=0)N(C C6- Alkyl)-NH-R8-, -R8-C(=0)NHN(C C6-Alkyl)-R8, -R8-0(C=0)-R8, -R8-0(C=0)NH-R8, -R8- 0(C=0)N(C C6-Alkyl)-R8, -R8-S(=0)2NH-R8, -R8-S(=0)2N(C C6-Alkyl)-R8, -R8-S(C=0)-R8, - R8-S(C=0)NH-R8, -R8-S(C=0)N(C C6-Alkyl)-R8, -R8-NHNH-R8, -R8-NHN(C C6-Alkyl)-R8, - R8-N(C C6-Alkyl)-NH-R8, -R8-N(Ci-C6-Alkyl)-N(C C6-Alkyl)-R8, -R8-N=CH-0-R8, -R8- NH(C=0)0-R8, -R8-N(C C6-Alkyl)-(C=0)0-R8, -R8-NH(C=0)NH-R8, -R8-NH(C=S)NH-R8, -R8- NHS(=0)2-R8, R8-NH-R8, R8-C(=0)-C(=0)-R8, R8-C(OH)-R8 , R8-NH(C=0)-R8, R8-Qz-R8 , R8- C(=N-NR'2)-R8 , R8-C(=C-R'2)-R8 oder -R8-N(C C6-Alkyl)S(=0)2-R8 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Nitro, Hydroxy, C C6-Alkyl, C C6-Alkyoxy, Halogen-Ci-C6-Alkyl, Amino, (Ci-C6-Alkyl)amino, Di(C C6- Alkyl)amino, C3-C6-Cycloalkyl wobei -(C3-C6-Cycloalkyl)- im Ring gegebenenfalls 1 bis 2 Heteroatome ausgewählt aus der Reihe N,S,0 enthalten kann, R8 für linear oder verzweigtes -(Ci-Cö-alkylen)- steht oder für eine direkte Bindung steht, wobei mehrere R8 unabhängig voneinander für linear oder verzweigtes-(Ci-C6-alkylen)- oder für eine direkte Bindung stehen, beispielsweise steht R8-0-R8- für -(Ci-C6-alkylen)-0-(Ci-C6-alkylen)-, -(C C6-alkylen)-0-, -0-(C C6- alkylen)-, oder -O-, wobei R' für Alkyl, Alkylcarbonyl, Alkenyl, Alkinyl, welche gegebenenfalls ein- oder mehrfach durch Halogen substituiert sein können, steht, Qz für einen 3- bis 4-gliedrigen, teilweise gesättigten oder gesättigten, oder für einen 5 bis 6- gliedrigen, teilweise gesättigten, gesättigten oder aromatischen Ring steht oder für ein 6 bis 10- gliedriges bizyklisches Ringsystem steht, wobei der Ring oder das bizyklische Ringsystem gegebenenfalls 1 -3 Heteroatome aus der Reihe N, S, O enthalten kann, wobei der Ring oder das bizyklische Ringsystem gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6- Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carbamoyl, Nitro, Hydroxy, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4- Alkylsulfonyl, Ci-C4-Haloalkylthio, Ci-C4-Haloalkylsulfinyl, C C4-Haloalkylsulfonyl, C1 -C4- Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6-Cycloalkylamino, (C C6-Alkyl)carbonyl, (Ci-C6- Alkoxy)carbonyl, (Ci-C6-Alkyl)aminocarbonyl, Di-(Ci-C4-alkyl)aminocarbonyl, n is 0 to 3, CC for 6 alkyl, C 3 -C 6 cycloalkyl, CC 6 haloalkyl, CC 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 - Coe-haloalkenyl, C2-C6 alkynyl, C 2 -C 6 haloalkynyl, dC 4 alkoxy, dC 4 -haloalkoxy, C 1 -C4- alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 haloalkyl sulfinyl , C 1 -C 4 -haloalkylsulfonyl, halogen, cyano, nitro or C 3 -C 6 -trialkylsilyl, represents an optionally mono- or polysubstituted by identical or different substituents by R 7 , aromatic or heteroaromatic 5- to 6-membered ring, which 1-3 heteroatoms from the series N, S, O may contain, for optionally, singly or multiply, substituted - (Ci-C 6 -alkylene) -, - (C 2 -C 6 -alkenylene) -, - (C 2 -C 6 -alkynylene), -R 8 - (C 3 -C 6 -cycloalkyl) -R 8 -, -R 8 -O-R 8 -, -R 8 -SR 8 -, -R 8 -S ( = 0) -R 8 -, -R 8 -S (= O) 2 - R 8 -, -R 8 -N (CC 6 -alkyl) -R 8 -, -R 8 -C = NO (CC 6 - Alkyl) - R 8 , -CH [CO 2 (CC 6 alkyl) -, R 8 -C (= O) - R 8 , -R 8 -C (= O) NH-R 8 , R 8 -C (= 0) N (CC 6 alkyl) -R 8, -R 8 -C (= 0) NHNH-R 8 -, -R 8 -C (= 0) N (CC 6 - alkyl) -NH -R 8 -, -R 8 -C (= 0) NHN (CC 6 alkyl) -R 8, -R 8 -0 (C = 0) -R 8, -R 8 -0 (C = 0) NH -R 8 , -R 8 - 0 (C = O) N (CC 6 alkyl) -R 8 , -R 8 -S (= O) 2 NH-R 8 , -R 8 -S (= O) 2 N (CC 6 alkyl) -R 8, -R 8 -S (C = 0) -R 8, - R 8 -S (C = 0) NH-R 8, -R 8 -S (C = 0) N (CC 6 -alkyl) -R 8 , -R 8 -NHNH-R 8 , -R 8 -NHN (CC 6 -alkyl) -R 8 , - R 8 -N (CC 6 -alkyl) -NH-R 8 , -R 8 -N (C 1 -C 6 -alkyl) -N (CC 6 -alkyl) -R 8 , -R 8 -N = CH-O-R 8 , -R 8 - NH (C = 0) 0-R 8 , -R 8 -N (CC 6 alkyl) - (C = O) O-R 8 , -R 8 -NH (C = O) NH-R 8 , -R 8 -NH (C = S) NH-R 8 , -R 8 - NHS (= O) 2 -R 8 , R 8 -NH-R 8 , R 8 -C (= O) -C (= O) -R 8 , R 8 - C (OH) -R 8, R 8 NH (C = 0) -R 8, R 8 -QZ-R 8, R 8 - C (= N-NR '2) -R 8, R 8 -C ( = CR ' 2 ) -R 8 or -R 8 -N (CC 6 alkyl) S (= O) 2 -R 8 where the substituents can be independently selected from halogen, cyano, nitro, hydroxy, CC 6 Alkyl, CC 6 -alkoxy, halo-C 1 -C 6 -alkyl, amino, (C 1 -C 6 -alkyl) -amino, di (CC 6 -alkyl) -amino, C 3 -C 6 -cycloalkyl where - (C 3 -C 6 -cycloalkyl) - may contain in the ring optionally 1 to 2 heteroatoms selected from the series N, S, 0, R 8 is linear or branched - (Ci-Cö-alkylene) - or a direct Binding is where several R 8 are independently of one another linear or branched (Ci-C6-alkylene) - or for a direct bond, for example, R 8 -0-R 8 - is - (Ci-C 6 -alkylene) - 0- (C 1 -C 6 -alkylene) -, - (CC 6 -alkylene) -O-, -O- (CC 6 -alkylene) -, or -O-, where R 'is alkyl, alkylcarbonyl, alkenyl, alkynyl which may optionally be monosubstituted or polysubstituted by halogen, Qz is a 3- to 4-membered, partially saturated or saturated, or for a 5- to 6-membered, partially saturated, saturated or aromatic ring or is a 6- to 10-membered bicyclic ring system, wherein the ring or the bicyclic Ring system optionally contain 1 -3 heteroatoms from the series N, S, O, wherein the ring or the bicyclic ring system optionally monosubstituted or polysubstituted by identical or different substituents, and wherein the substituents can be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, C 6 - haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 - C6 halocycloalkyl, halogen, cyano, carbamoyl, nitro, hydroxy, CC 4 -alkoxy, CC 4 haloalkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 - alkylsulfonyl, Ci-C4-haloalkylthio, Ci- C 4 haloalkylsulfinyl, C 4 -haloalkylsulfonyl, C 1 -C 4 -alkylamino, di- (C 1 -C 4 -alkyl) amino, C 3 -C 6 cycloalkylamino, (CC 6 alkyl) carbonyl, (Ci-C 6 - alkoxy) carbonyl, (Ci-C6 alkyl) aminocarbonyl, di- (Ci-C 4 alkyl) aminocarbonyl,
QY für einen 5-oder 6-gliedrigen, teilweise gesättigten oder gesättigten heterozyklischen oder heteroaromatischen Ring oder ein aromatisches 8-, 9- oder 10-gliedriges annelliertes heterobicyclisches Ringsystem steht, wobei der Ring oder das Ringsystem, gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-Cö-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6- Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, Nitro, Hydroxy, C C4-Alkoxy, C C4-QY is a 5- or 6-membered, partially saturated or saturated heterocyclic or heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system, wherein the ring or the ring system, optionally mono- or polysubstituted, identical or different is substituted, said substituents may be independently selected from hydrogen, Ci-COE-alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Ci-C 6 haloalkyl , C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, CC 4 -alkoxy, CC 4 -
Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkylsulfinyl, C C4-Haloalkylsulfonyl, C C4-Alkylamino, Di-(C C4-alkyl)amino, C3-CÖ- Cycloalkylamino, (C C6-Alkyl)carbonyl, (Ci-C6-Alkoxy)carbonyl, (C C6-Alkyl)aminocarbonyl, Di-(Ci-C4-alkyl)aminocarbonyl, Tri-(Ci-C2)alkylsilyl, (Ci-C4-Alkyl)(Ci-C4-Alkoxy)imino, oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei Phenyl oder der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden mit Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-Cö-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Nitro, Hydroxy, Ci-C4-Alkoxy, C C4-Haloalkoxy substituiert sein können, R7 für Wasserstoff, C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C3-C6-Cycloalkoxy oder steht, Haloalkoxy, CC 4 alkylthio, C 1 -C 4 alkylsulfmyl, CC 4 alkylsulfonyl, CC 4 haloalkylthio, CC 4 haloalkylsulfinyl, CC 4 haloalkylsulfonyl, CC 4 alkylamino, di (CC 4 alkyl) amino, C 3 -C Ö - cycloalkylamino, (C-C6 alkyl) carbonyl, (Ci-C 6 alkoxy) carbonyl, (C-C6 alkyl) aminocarbonyl, di- (Ci-C 4 alkyl) aminocarbonyl, tri (Ci- C 2 ) alkylsilyl, (C 1 -C 4 -alkyl) (C 1 -C 4 -alkoxy) imino, or where the substituents can be selected independently of one another from phenyl or a 5- or 6-membered heteroaromatic ring, where phenyl or the ring optionally mono- or polysubstituted, identically or differently, with Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Ci-COE-haloalkyl, C 2 -C 6 Haloalkenyl, C 2 -C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, nitro, hydroxy, C 1 -C 4 -alkoxy, C -C 4 -haloalkoxy may be substituted, R 7 is hydrogen, CC 6 -alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Ci-C 6 haloalkyl, C 2 -C 6 -Ha loalkenyl, C 3 -C 6 cycloalkoxy or stands,
R9 unabhängig voneinander für Wasserstoff, Ci-C6-Alkyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, Halogen, Cyano, Nitro, Ci-C4-Alkoxy, Ci-C4-Haloalkoxy, Ci-C4-Alkylthio oder Ci-C4-Haloalkylthio steht, p für 0 bis 4 steht, R 9 independently of one another represent hydrogen, C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkyl, halogen, cyano, nitro, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkoxy, C 1 -C 4 -alkyl 4- alkylthio or C 1 -C 4 -haloalkylthio, p is 0 to 4,
Z für N, CH, CF, CC1, CBr oder CI steht, die Verbindungen der allgemeinen Formel (I) außerdem N-Oxide und Salze umfassen, und ein oder mehrere Fungizide der Gruppe (II): Z is N, CH, CF, CC1, CBr or Cl, the compounds of the general formula (I) furthermore comprise N-oxides and salts, and one or more fungicides of the group (II):
Fungizide (1) Inhibitoren der Ergosterol-Biosynthese, wie beispielsweise AI dimorph, Azaconazol, Bitertanol, Bromuconazol, Cyproconazol, Diclobutrazol, Difenoconazol, Diniconazol, Diniconazol-M, Dodemorph, Dodemorph Acetat, Epoxiconazol, Etaconazol, Fenarimol, Fenbuconazol, Fenhexamid, Fenpropidin, Fenpropimorph, Fluquinconazol, Flurprimidol, Flusilazol, Flutriafol, Furconazol, Furconazol-Cis, Hexaconazol, Imazalil, Imazalil Sulfat, Imibenconazol, Ipconazol, Metconazol, Myclobutanil, Naftifin, Nuarimol, Oxpoconazol, Paclobutrazol, Pefurazoat, Penconazol, Piperalin, Prochloraz, Propiconazol, Prothioconazol, Pyributicarb, Pyrifenox, Quinconazol, Simeconazol, Spiroxamin, Tebuconazol, Terbinafin, Tetraconazol, Triadimefon, Triadimenol, Tridemorph, Triflumizol, Triforin, Triticonazol, Uniconazol, Uniconazol-p, Viniconazol, Voriconazol, l -(4- Chlorphenyl)-2-( 1 H- 1 ,2,4-triazol- 1 -yl)cycloheptanol, Methyl-1 -(2,2-dimethyl-2,3 -dihydro- 1 H-inden- 1 - yl)-lH-imidazol-5-carboxylat, N'-{5-(Difluormethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl} -N- ethyl-N-methylimidoformamid, N-Ethyl-N-methyl-N'-{2-methyl-5-(trifluormethyl)-4-[3- (trimethylsilyl)propoxy]phenyl}imidoformamid und 0-[l-(4-Methoxyphenoxy)-3,3-dimethylbutan-2- yl] - 1 H-imidazol- 1 -carbothioat. Fungicides (1) inhibitors of ergosterol biosynthesis, such as Al dimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fenhexamide, fenpropidin, Fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole cis, hexaconazole, imazalil, imazalil sulfate, imibenconazole, ipconazole, metconazole, myclobutanil, naftifine, nuarimol, oxpoconazole, paclobutrazole, pefurazoate, penconazole, piperaline, prochloraz, propiconazole, prothioconazole , Pyributicarb, Pyrifenox, Quinconazole, Simeconazole, Spiroxamine, Tebuconazole, Terbinafine, Tetraconazole, Triadimefon, Triadimenol, Tridemorph, Triflumizole, Triforin, Triticonazole, Uniconazole, Uniconazole-p, Viniconazole, Voriconazole, 1- (4-Chlorophenyl) -2- ( 1 H -1, 2,4-triazol-1-yl) cycloheptanol, methyl 1 - (2,2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5 carboxylate, N '- {5- (D. ifluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, N-ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) - 4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide and 0- [1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl] -1H-imidazole-1-carbothioate.
(2) Inhibitoren der Respiration (Atmungsketten-Inhibitoren), wie beispielsweise Bixafen, Boscalid, Carboxin, Diflumetorim, Fenfuram, Fluopyram, Flutolanil, Fluxapyroxad, Furametpyr, Furmecyclox, Isopyrazam Mischung des syn-epimeren Razemates 1RS,4SR,9RS und des anti-empimeren Razemates 1RS,4SR,9SR, Isopyrazam (anti-epimeres Razemat ), Isopyrazam (anti-epimeres Enantiomer 1R,4S,9S), Isopyrazam (anti-epimeres Enantiomer 1 S,4R,9R), Isopyrazam (syn-epimeres Razemat 1RS,4SR,9RS), Isopyrazam (syn-epimeres Enantiomer 1R,4S,9R), Isopyrazam (syn-epimeres Enantiomer 1S,4R,9S), Mepronil, Oxycarboxin, Penflufen, Penthiopyrad, Sedaxane, Thifluzamid, l-Methyl-N-[2-(l,l,2,2- te1rafluorethoxy)phenyl]-3-(lTifluormethyl)-lH-pyrazol-4-carboxarriid, 3-(Difluormethyl)-l-methyl-N- [2-( 1 , 1 ,2,2-tetrafluorethoxy)phenyl]-l H-pyrazol-4-carboxamid, 3-(Difluormethyl)-N-[4-fluor-2- (1,1 ,2,3 ,3 ,3 -hexafluorpropoxy)phenyl]- 1 -methyl-1 H-pyrazol-4-carboxamid, N-[ 1 -(2,4-Dichlorphenyl)- l-methoxypropan-2-yl]-3-(difluormethyl)-l-methyl-lH-pyrazol-4-carboxamid, 5,8-Difluor-N-[2-(2- fluor-4-{[4-(lTifluormethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-^ N-[9-(Dichlormethylen)- 1 ,2,3 ,4-tetrahydro- 1 ,4-methanonaphthalen-5-yl]-3 -(difluormethyl)- 1 -methyl-1 H-pyrazol-4-carboxamid, N-[(l S,4R)-9-(Dichlormethylen)-l,2,3,4-te^ (2) inhibitors of respiration (respiratory chain inhibitors), such as bixafen, boscalid, carboxin, diflumetorim, fenfuram, fluopyram, flutolanil, fluxapyroxad, furametpyr, furmecyclox, isopyrazam mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti- more highly enriched racemates 1RS, 4SR, 9SR, isopyrazam (anti-epimeric racemate), isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), isopyrazam (syn-epimeric racemate 1RS , 4SR, 9RS) Isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), mepronil, oxycarboxine, penflufen, penthiopyrad, sedaxanes, thifluzamide, l-methyl-N- [2- (l, 1, 2,2-tetrafluoroethoxy) phenyl] -3- (1-trifluoromethyl) -1H-pyrazole-4-carboxuridine, 3- (difluoromethyl) -1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy ) phenyl] -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,3,3,3,3,3-hexafluoropropoxy) phenyl] -1-methyl- 1 H -pyrazole-4-carboxamide, N- [1- (2,4-dichlorophenyl) -1-methoxy-propan-2-yl] -3- (difluoromethyl) -l-methyl-1H-pyrazole-4-carboxamide, 5 , 8-Difluoro-N- [2- (2-fluoro-4 - {[4- (1-trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazoline ^ N- [9- (dichloromethylene) -1] 2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, N - [(1S, 4R) -9- (dichloromethylene) -l, 2,3,4-te ^
methyl-1 H-pyrazol-4-carboxamid und N-[(lR,4S)-9-(Dichlormethylen)-l,2,3,4-tetrahydro-l,4- methanonaphthalen-5-yl] -3-(difluormethyl)- 1 -methyl- 1 H-pyrazol-4-carboxamid. methyl-1H-pyrazole-4-carboxamide and N - [(IR, 4S) -9- (dichloromethylene) -l, 2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl] -3- ( difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide.
(3) Inhibitoren der Respiration (Atmungsketten-Inhibitoren) am Komplex III der Atmungskette, wie beispielsweise Ametoctradin, Amisulbrom, Azoxystrobin, Cyazofamid, Coumethoxystrobin, Coumoxystrobin, Dimoxystrobin, Enestroburin, Famoxadon, Fenamidon, Fenoxystrobin, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyrametostrobin, Pyraoxystrobin, Pyribencarb, Triclopyricarb, Trifloxystrobin, (2E)-2-(2-{[6-(3-Chlor-2- methylphenoxy)-5-fluorpyrimidin-4-yl]oxy}phenyl)-2-(methoxyimino)-N-methylethanamid, (2E)-2- (Methoxyimino)-N-methyl-2-(2- { [( {( 1 E)- 1 -[3-(3) inhibitors of respiration (respiratory chain inhibitors) at the complex III of the respiratory chain, such as ametoctradine, amisulbrom, azoxystrobin, cyazofamide, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, famoxadone, fenamidone, fenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin , Picoxystrobin, Pyraclostrobin, Pyrametostrobin, Pyraoxystrobin, Pyribencarb, Triclopyricarb, Trifloxystrobin, (2E) -2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylethaneamide, (2E) -2- (methoxyimino) -N-methyl-2- (2- {[({(1 E) -1 - [3-
(trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)ethanamid, (2E)-2-(Methoxyimino)-N- methyl-2-{2-[(E)-({l-[3-(trifluormethyl)phenyl]ethoxy}imino)methyl]phenyl}ethanamid, (2E)-2-{2- [( { [( 1 E)-l -(3 - { [(E)- 1 -Fluor-2-phenylethenyl] oxy } phenyl)ethyliden] amino } oxy)methyl]phenyl} -2- (methoxyimino)-N-methylethanamid, (2E)-2-{2-[({[(2E,3E)-4-(2,6-Dichlorphenyl)but-3-en-2- yliden]amino}oxy)methyl]phenyl}-2-(methoxyimino)-N-methylethanamid, 2-Chlor-N-(l,l,3-trimethyl- 2,3-dihydro-lH-inden-4-yl)pyridin-3-carboxamid, 5-Methoxy-2-methyl-4-(2-{[({(lE)-l-[3- (1rifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)-2,4-dihydro-3H-l,2,4-triazol-3-on, Methyl-(2E)-2- {2-[( {cyclopropyl[(4-methoxyphenyl)imino]methyl} sulfanyl)methyl]phenyl} -3- methoxyprop-2-enoat, N-(3-Ethyl-3,5,5-trimethylcyclohexyl)-3-(formylamino)-2-hydroxybenzamid, 2- {2-[(2,5-Dimethylphenoxy)methyl]phenyl} -2-methoxy-N-methylacetamid und (2R)-2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl } -2-methoxy-N-methylacetamid. (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) ethanamide, (2E) -2- (methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl ) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2E) -2- {2- [({[(1E) -1- (3 - {[(E) -1-fluoro-2-phenylethenyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethaneamide, (2E) -2- {2 - [({[(2E, 3E) -4- (2,6 -Dichlorophenyl) but-3-en-2-ylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethaneamide, 2-chloro-N- (1, l, 3-trimethyl-2,3 -dihydro-1H-inden-4-yl) pyridine-3-carboxamide, 5-methoxy-2-methyl-4- (2 - {[({(1E) -l- [3- (1-trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-l, 2,4-triazol-3-one, methyl (2E) -2- {2 - [({cyclopropyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] phenyl} -3-methoxyprop-2-enoate, N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide, 2- {2- [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide and (2R) -2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide id.
(4) Inhibitoren der Mitose und Zellteilung, wie beispielsweise Benomyl, Carbendazim, Chlorfenazol, Diethofencarb, Ethaboxam, Fluopicolid, Fuberidazol, Pencycuron, Thiabendazol, Thiophanat-Methyl, Thiophanat, Zoxamid, 5-Chlor-7-(4-methylpiperidin-l-yl)-6-(2,4,6-trifluorphenyl)[l,2,4]triazolo[l,5- ajpyrimidin und 3-Chlor-5-(6-chlorpyridin-3-yl)-6-methyl-4-(2,4,6-trifluorphenyl)pyridazin. (5) Verbindungen mit Multisite -Aktivität, wie beispielsweise Bordeauxmischung, Captafol, Captan, Chlorothalonil, Kupferzubereitungen wie Kupferhydroxid, Kupfernaphthenat, Kupferoxid, Kupferoxychlorid, Kupfersulfat, Dichlofluanid, Dithianon, Dodine, Dodine freie Base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatinacetat, Iminoctadin, Iminoctadinalbesilat, Iminoctadintriacetat, Mankupfer, Mancozeb, Maneb, Metiram, Zinkmetiram, Kupfer-Oxin, Propamidin, Propineb, Schwefel und Schwefelzubereitungen wie beispielsweise Calciumpolysulfid, Thiram, Tolylfluanid, Zineb und Ziram. (4) Mitosis and cell division inhibitors such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fluopicolide, fuberidazole, pencycuron, thiabendazole, thiophanate-methyl, thiophanate, zoxamide, 5-chloro-7- (4-methylpiperidine-1) yl) -6- (2,4,6-trifluorophenyl) [l, 2,4] triazolo [l, 5-ajpyrimidine and 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4 - (2,4,6-trifluorophenyl) pyridazine. (5) Compounds with multisite activity such as Bordeaux mixture, captafol, captan, chlorothalonil, copper preparations such as copper hydroxide, copper naphthenate, copper oxide, copper oxychloride, copper sulfate, dichlofluanid, dithianone, dodine, dodine free base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatin acetate , Iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram.
(6) Resistenzinduktoren, wie beispielsweise Acibenzolar-S-Methyl, Isotianil, Probenazol und Tiadinil. (6) resistance inducers such as acibenzolar-S-methyl, isotianil, probenazole and tiadinil.
(7) Inhibitoren der Aminosäure- und Protein-Biosynthese, wie beispielsweise Andoprim, Blasticidin-S, Cyprodinil, Kasugamycin, Kasugamycin Hydrochlorid Hydrat, Mepanipyrim, Pyrimethanil und 3-(5-(7) inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim, pyrimethanil and 3- (5-
Fluor-3,3 ,4,4-tetramethyl-3 ,4-dihydroisoquinolin- 1 -yl)quinolin. Fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline.
(8) Inhibitoren der ATP Produktion, wie beispielsweiseFentin Acetat, Fentin Chlorid, Fentin Hydroxid und Silthiofam. (8) Inhibitors of ATP production, such as, for example, acetate acetate, fentin chloride, fentin hydroxide and silthiofam.
(9) Inhibitoren der Zellwandsynthese, wie beispielsweise Benthiavalicarb, Dimethomorph, Flumorph, Iprovalicarb, Mandipropamid, Polyoxins, Polyoxorim, Validamycin A und Valifenalat. (9) inhibitors of cell wall synthesis, such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A, and valifenalate.
(10) Inhibitoren der Lipid- und Membran-Synthese, wie beispielsweise Biphenyl, Chloroneb, Dicloran, Edifenphos, Etndiazol, lodocarb, Iprobenfos, Isoprothiolan, Propamocarb, Propamocarb Hydrochlorid, Prothiocarb, Pyrazophos, Quintozen, Tecnazene und Tolclofos-Methyl. (10) lipid and membrane synthesis inhibitors such as biphenyl, chloroneb, diclorane, edifenphos, etndiazole, iodocarb, ipamplesfos, isoprothiolane, propamocarb, propamocarb hydrochloride, prothiocarb, pyrazophos, quintozene, tecnazene and tolclofos-methyl.
(11) Inhibitoren der Melanin-Biosynthese, wie beispielsweiseCarpropamid, Diclocymet, Fenoxanil, Phthalid, Pyroquilon, Tricyclazol und 2,2,2-Trifluorethyl {3-methyl-l-[(4-methylbenzoyl)amino]butan-(11) inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, phthalide, pyroquilone, tricyclazole and 2,2,2-trifluoroethyl {3-methyl-1 - [(4-methylbenzoyl) amino] butane
2-yl}carbamat. 2-yl} carbamate.
(12) Inhibitoren der Nukleinsäuresynthese, wie beispielsweise Benalaxyl, Benalaxyl-M (Kiralaxyl), Bupirimat, Clozylacon, Dimethirimol, Ethirimol, Furalaxyl, Hymexazol, Metalaxyl, Metalaxyl-M (Mefenoxam), Ofurace, Oxadixyl und Oxolinsäure. (13) Inhibitoren der Signaltransduktion, wie beispielsweiseChlozolinat, Fenpiclonil, Fludioxonil, Iprodion, Procymidon, Quinoxyfen und Vinclozolin. (12) inhibitors of nucleic acid synthesis, such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacon, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl and oxolic acid. (13) Signal transduction inhibitors, such as cholzolinate, fenpiclonil, fludioxonil, iprodione, procymidone, quinoxyfen and vinclozoline.
(14) Entkoppler, wie beispielsweise Binapacryl, Dinocap, Ferimzon, Fluazinam und Meptyldinocap. (14) Decouplers such as binapacryl, dinocap, ferimzone, fluazinam and meptyldinocap.
(15) Weitere Verbindungen, wie beispielsweise Benthiazol, Bethoxazin, Capsimycin, Carvon, Chinomethionat, Pyriofenon (Chlazafenon), Cufraneb, Cyflufenamid, Cymoxanil, Cyprosulfamide, Dazomet, Debacarb, Dichlorophen, Diclomezin, Difenzoquat, Difenzoquat Methylsulphat, Diphenylamin, Ecomat, Fenpyrazamin, Flumetover, Fluoromid, Flusulfamid, Flutianil, Fosetyl- Aluminium, Fosetyl-Calcium, Fosetyl-Natrium, Hexachlorbenzol, Irumamycin, Methasulfocarb, Methylisothiocyanat, Metrafenon, Mildiomycin, Natamycin, Nickel Dimethyldithiocarbamat, Nitrothal- Isopropyl, Octhilinone, Oxamocarb, Oxyfenthiin, Pentachlorphenol und dessen Salze, Phenothrin, Phosphorsäure und deren Salze, Propamocarb-Fosetylat, Propanosin-Natrium, Proquinazid, Pyrimorph, Pyrrolnitrin, Tebufloquin, Tecloftalam, Tolnifanid, Triazoxid, Trichlamid, Zarilamid, (3S,6S,7R,8R)-8- Benzyl-3-[({3-[(isobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino]-6-methyl-4,9-dioxo- 1 ,5-dioxonan-7-yl 2-methylpropanoat, 1 -(4- {4-[(5R)-5-(2,6-Difluorphenyl)-4,5-dihydro-l ,2-oxazol-3- yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(1rifluormethyl)-lH-pyrazol-l-yl]ethanon, l-(4-{4- [(5S)-5-(2,6-Difluoφhenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl- 3-(trifluormethyl)-lH-pyrazol-l-yl]ethanon, l-(4-{4-[5-(2,6-Difluorphenyl)-4,5-dihydro-l,2-oxazol-3- yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(1rifluormethyl)-lH-pyrazol-l-yl]ethanon, l-(4- Methoxyphenoxy)-3,3-dimethylbutan-2-yl-lH-imidazol-l-carboxylat, 2,3,5,6-Tetrachlor-4- (methylsulfonyl)pyridin, 2,3-Dibutyl-6-chlorthieno[2,3-d]pyrimidin-4(3H)-on, 2,6-Dimethyl-lH,5H- [l,4]dithiino[2,3-c:5,6-c']dipyrrol-l,3,5,7(2H,6H)-tetron, 2-[5-Methyl-3-(trifluormethyl)-lH-pyrazol-l- yl]-l-(4-{4-[(5R)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanon, 2-[5- Methyl-3-(trifluormethyl)-lH-pyrazol-l^ (15) Other compounds such as benthiazole, bethoxazine, capsimycin, carvone, quinomethionate, pyriofenone (Chlazafenone), Cufraneb, cyflufenamid, cymoxanil, cyprosulfamide, dazomet, debacarb, dichlorophen, diclomethine, difenzoquat, difenzoquat methylsulphate, Diphenylamine, ecomat, fenpyrazine, flumetover, fluoromide, flusulfamide, flutianil, fosetyl-aluminum, fosetyl-calcium, fosetyl-sodium, hexachlorobenzene, irumamycin, methasulfocarb, methylisothiocyanate, metrafenone, mildiomycin, natamycin, nickel dimethyldithiocarbamate, nitrothal-isopropyl, octhilinone, oxamocarb , Oxyfenthiine, pentachlorophenol and its salts, phenothrin, phosphoric acid and its salts, propamocarb-fosetylate, propanosine sodium, proquinazide, pyrimorph, pyrrolnitrin, tebufloquine, tecloftalam, tolnifanide, triazoxide, trichlamide, zarilamide, (3S, 6S, 7R, 8R) Benzyl-3 - [({3 - [(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-1, 5-dioxonan-7- yl 2-methylpropanoate, 1- (4- {4 - [(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazole -2-yl} piperidin-1-yl) -2- [5-methyl-3- (1-trifluoromethyl) -1H-pyrazol-1-yl] ethanone, 1- (4- {4- [(5S) -5- (2,6-Difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3 - (trifluoromethyl ) -LH-pyrazol-1-yl] ethanone, 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -l, 3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (1-trifluoromethyl) -1H-pyrazol-1-yl] ethanone, 1- (4-methoxyphenoxy) -3,3- dimethylbutan-2-yl-1H-imidazole-1-carboxylate, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidine-4 (3H) -one, 2,6-dimethyl-1H, 5H- [l, 4] dithiino [2,3-c: 5,6-c'] dipyrrole-1, 3,5,7 (2H, 6H) tetron, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4 - [(5R) -5-phenyl-4,5-dihydro-1, 2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazole-1: 1
thiazol-2-yl}piperidin-l-yl)ethanon, 2-[5-Methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]-l-{4-[4-(5-phenyl- 4,5-dihydro-l,2-oxazol-3-yl)-l,3-thiazol-2-yl]piperidin-l-yl}ethanon, 2-Butoxy-6-iod-3-propyl-4H- chromen-4-οη, 2-Chlor-5-[2-chlor-l-(2,6-difluor-4-methoxyphenyl)-4-methyl-lH-imidazol-5-yl]pyridin,thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- {4- [4- (5-phenyl-4 , 5-dihydro-l, 2-oxazol-3-yl) -1,3-thiazol-2-yl] -piperidin-1-yl} -ethanone, 2-butoxy-6-iodo-3-propyl-4H-chromen- 4-o, 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4-methyl-1H-imidazol-5-yl] pyridine,
2- Phenylphenol und dessen Salze, 3-(4,4,5-Trifluor-3,3-dimethyl-3,4-dihydroisoquinolin-l-yl)quinolin, 3,4,5-Trichlorpyridin-2,6-dicarbonitril, 3-[5-(4-Chlorphenyl)-2,3-dimethyl-l,2-oxazolidin-3-yl]pyridin,2- phenylphenol and its salts, 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3- pyridine [5- (4-chlorophenyl) -2,3-dimethyl-l, 2-oxazolidin-3-yl],
3- Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6-methylpyridazin, 4-(4-Chlorphenyl)-5-(2,6- difluorphenyl)-3,6-dimethylpyridazin, 5-Amino-l,3,4-thiadiazol-2-thiol, 5-Chlor-N'-phenyl-N'-(prop-2- in-l-yl)thiophen-2-sulfonohydrazid, 5-Fluor-2-[(4-fluorbenzyl)oxy]pyrimidin-4-amin, 5-Fluor-2-[(4- methylbenzyl)oxy]pyrimidin-4-amin, 5-Methyl-6-octyl[l,2,4]triazolo[l,5-a]pyrimidin-7-amin, Ethyl- (2Z)-3-amino-2-cyan-3-phenylprop-2-enoat, N'-(4-{[3-(4-Chlorbenzyl)-l,2,4-thiadiazol-5-yl]oxy}-2,5- dimethylphenyl)-N-ethyl-N-methylimidoformamid, N-(4-Chlorbenzyl)-3-[3-methoxy-4-(prop-2-in-l- yloxy)phenyl]propanamid, N-[(4-Chlorphenyl)(cyan)methyl]-3-[3-methoxy-4-(prop-2-in-l- yloxy)phenyl]propanamid, N-[(5-Brom-3-chlorpyridin-2-yl)methyl]-2,4-dichlorpyridin-3-carboxamid, N-[l -(5-Brom-3-chlorpyridin-2-yl)ethyl]-2,4-dichlorpyridin-3-carboxamid, N-[l -(5-Brom-3- chlorpyridin-2-yl)ethyl]-2-fluor-4-iodpyridin-3-carboxamid, N-{(E)-[(Cyclopropylmethoxy)imino][6- (difluormethoxy)-2,3 -difluorphenyljmethyl } -2-phenylacetamid, N- {(Z)- [(Cyclopropylmethoxy)imino][6-(difluormethoxy)-2,3-difluorphenyl]methyl}-2-phenylacetamid, N'-{4- [(3-Tert-butyl-4-cyano-l,2-thiazol-5-yl)oxy]-2-chlor-5-methylphenyl}-N-ethyl-N- methylimidoformamid, N-Methyl-2-( 1 - { [5 -methyl-3 -(trifluormethyl)- 1 H-pyrazol- 1 -yl] acetyl } piperidin- 4-yl)-N-( 1 ,2,3 ,4-tetrahydronaphthalen-l -yl)- 1 ,3 -thiazol-4-carboxamid, N-Methyl-2-( 1 - { [5-methyl-3 - (trifluormethyl)- 1 H-pyrazol-1 -yl] acetyl} piperidin-4-yl)-N-[( 1 R)- 1 ,2,3,4-tetrahydronaphthalen- 1 -yl] -1,3- thiazol-4-carboxamid, N-Methyl-2-( 1 - { [5-methyl-3 -(trifluormethyl)- 1 H-pyrazol- 1 -yl] acetyl }piperidin-4- yl)-N-[(lS)-l,2,3,4-tetrahydronaphthalen-l-yl]-l,3-thiazol-4-carboxamid, Pentyl-{6-[({[(l-methyl-lH- tetrazol-5-yl)(phenyl)methyliden]amino}oxy)methyl]pyridin-2-yl}carbamat, Phenazin-1 -carbonsäure, Chinolin-8-ol, Chinolin-8-olsulfat(2: l) und Tert-butyl {6-[({[(l-methyl-lH-tetrazol-5- yl)(phenyl)methylen]amino}oxy)methyl]pyridin-2-yl}carbamat. 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, 5-amino-l, 3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N '- (prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, 5-fluoro-2 - [(4-fluorobenzyl) oxy] pyrimidin-4-amine, 5-fluoro-2 - [(4-methylbenzyl) oxy] pyrimidin-4-amine, 5-methyl-6-octyl [l, 2,4] triazolo [l, 5-a] pyrimidin-7-amine, ethyl (2Z) -3-amino-2-cyano-3-phenylprop-2-enoate, N '- (4 - {[3- (4-chlorobenzyl) -l, 2,4-thiadiazol-5-yl] oxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop -2-yn-1-yloxy) phenyl] propanamide, N - [(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide , N - [(5-Bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloro-pyridin-2-yl) -ethyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodopyridine-3-carboxamide, N - {(E) - [(Cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl l} -2-phenylacetamide, N- {(Z) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N '- {4- [(3- Tert -butyl-4-cyano-1,2-thiazol-5-yl) oxy] -2-chloro-5-methylphenyl} -N-ethyl-N-methylimidoformamide, N-methyl-2- (1 - {[5 -methyl-3 - (trifluoromethyl) -1 H -pyrazol-1-yl] acetyl} piperidine 4-yl) - N - (1,2,3,4-tetrahydronaphthalen-1-yl) -1,3-thiazole-4-carboxamide, N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl) -1 H -pyrazol-1-yl] acetyl} piperidin-4-yl) - N - [(1 R) -1,2,3,4-tetrahydronaphthalen-1-yl] -1,3-thiazole 4-carboxamide, N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] -acetyl} -piperidin-4-yl) -N - [(IS) -l, 2,3,4-tetrahydronaphthalene-1-yl] -l, 3-thiazole-4-carboxamide, pentyl {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl ) methylidene] amino} oxy) methyl] pyridin-2-yl} carbamate, phenazine-1-carboxylic acid, quinolin-8-ol, quinoline-8-olsulfate (2: 1) and tert-butyl {6 - [({ (1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate.
(16) Weitere Verbindungen, wie beispielsweise l-Methyl-3-(trifluormethyl)-N-[2'- (trifluormethyl)biphenyl-2-yl]-lH-pyrazol-4-carboxamid, N-(4'-Chlorbiphenyl-2-yl)-3-(difluormethyl)- 1 -methyl-1 H-pyrazol-4-carboxamid, N-(2',4'-Dichlorbiphenyl-2-yl)-3 -(difluormethyl)- 1 -methyl- 1 H- pyrazol-4-carboxamid, 3-(Difluormethyl)-l-methyl-N-[4'-(trifluormethyl)biphenyl-2-yl]-lH-pyrazol-4- carboxamid, N-(2',5'-Difluorbiphenyl-2-yl)-l-methyl-3-(trifluormethyl)-l H-pyrazol -4-carboxamid, 3- (Difluormethyl)-l-methyl-N-[4'-(prop-l-in-l-yl)biphenyl-2-yl]-l H-pyrazol -4-carboxamid, 5-Fluor-l,3- dimethyl-N-[4'-(prop-l -in-1 -yl)biphenyl-2-yl]-lH-pyrazol-4-carboxamid, 2-Chlor-N-[4'-(prop-l -in-1 - yl)biphenyl-2-yl]pyridin-3 -carboxamid, 3 -(Difluormethyl)-N-[4'-(3,3 -dimethylbut- 1 -in- 1 -yl)biphenyl-2- yl]-l -methyl-1 H-pyrazol -4-carboxamid, N-[4'-(3,3-Dimethylbut-l-in-l-yl)biphenyl-2-yl]-5-fluor-l,3- dimethyl- 1 H-pyrazol -4-carboxamid, 3 -(Difluormethyl)-N-(4'-ethinylbiphenyl-2-yl)- 1 -methyl- 1 H- pyrazol-4-carboxamid, N-(4'-Ethinylbiphenyl-2-yl)-5-fluor-l,3-dimethyl-lH-pyrazol-4-carboxamid, 2- Chlor-N-(4'-ethinylbiphenyl-2-yl)pyridin-3-carboxamid, 2-Chlor-N-[4'-(3,3-dimethylbut-l -in-1 - yl)biphenyl-2-yl]pyridin-3-carboxamid, 4-(Difluormethyl)-2-methyl-N-[4'-(trifluormethyl)biphenyl-2- yl]-l,3-thiazol-5-carboxamid, 5-Fluor-N-[4'-(3-hydroxy-3-methylbut-l-in-l-yl)biphenyl-2-yl]-l,3- dimethyl- 1 H-pyrazol -4-carboxamid, 2-Chlor-N-[4'-(3-hydroxy-3 -methylbut- 1 -in- 1 -yl)biphenyl-2- yl]pyridin-3-carboxamid, 3-(Difluormethyl)-N-[4'-(3-methoxy-3-methylbut-l-in-l-yl)biphenyl-2-yl]-l- methyl-lH-pyrazol-4-carboxamid, 5-Fluor-N-[4'-(3-methoxy-3-methylbut-l-in-l-yl)biphenyl-2-yl]-l,3- dimethyl- 1 H-pyrazol -4-carboxamid, 2-Chlor-N-[4'-(3-methoxy-3 -methylbut- 1 -in- 1 -yl)biphenyl-2- yl]pyridin-3-carboxamid, (5-Brom-2-methoxy-4-methylpyridin-3-yl)(2,3,4-trimethoxy-6- methylphenyl)methanon und N-[2-(4-{[3-(4-Chlorphenyl)prop-2-in-l-yl]oxy}-3-methoxyphenyl)ethyl]- N2-(methylsulfonyl)valinamid, 4-Oxo-4-[(2-phenylethyl)amino]butansäure und But-3-yn-l-yl {6- [( { [(Z)-( 1 -methyl-1 H-tetrazol-5-yl)(phenyl)methylen]amino} oxy)methyl]pyridin-2-yl} carbamat sehr gut zur Bekämpfung von unerwünschten tierischen Schädlingen wie Insekten, Akariziden und/oder Nematoden sowie unerwünschten phytopathogenen Pilzen geeignet sind. (16) Further compounds such as, for example, 1-methyl-3- (trifluoromethyl) -N- [2'- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, N- (4'-chlorobiphenyl) 2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, N- (2 ', 4'-dichlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl- 1 H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [4 '- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, N- (2', 5 '-Difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole -4-carboxamide, 3- (difluoromethyl) -l-methyl-N- [4' - (prop-1-in -l-yl) biphenyl-2-yl] -1H-pyrazole -4-carboxamide, 5-fluoro-1,3-dimethyl-N- [4 '- (prop-1-yn-1-yl) biphenyl] 2-yl] -1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (prop-1-yn-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 3 - (difluoromethyl ) -N- [4 '- (3,3-dimethylbut-1 -in-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole -4-carboxamide, N- [4' - ( 3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] -5-fluoro-1, 3-dimethyl-1H-pyrazole -4-carboxamide, 3 - (difluoromethyl) -N- (4 '-ethynyl-biphenyl-2-yl) -1-methyl-1 H-pyrazole-4-carboxamide, N- (4'-ethynyl-biphenyl-2-yl) -5-fluoro-1, 3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- (4'-ethynyl-biphenyl -2-yl) pyridine-3-carboxamide, 2-chloro-N- [4 '- (3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 4- (Difluoromethyl) -2-methyl-N- [4 '- (trifluoromethyl) biphenyl-2-yl] -1,3-thiazole-5-carboxamide, 5-fluoro-N- [4' - (3-hydroxy-3 -methylbut-1-yn-1-yl) biphenyl-2-yl] -l, 3-dimethyl-1H-pyrazole -4-carboxamide, 2-chloro-N- [4 '- (3-hydroxy-3 - methylbut-1-yn-1-yl) biphenyl-2-yl] pyridine-3-carboxamide, 3- (difluoromethyl) -N- [4 '- (3-methoxy-3-methylbut-1-yn-1-yl ) biphenyl-2-yl] -l-methyl-1H-pyrazole-4-carboxamide, 5-fluoro-N- [4 '- (3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2 -yl] -1,3-dimethyl-1H-pyrazole -4-carboxamide, 2-chloro-N- [4 '- (3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2- yl] pyridine-3-carboxamide, (5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone and N- [2- (4 - { 3- (4-chlorophenyl) prop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] - N 2 - (methylsulfonyl) val inamide, 4-oxo-4 - [(2-phenylethyl) amino] butanoic acid and but-3-yn-1-yl {6- [({[(Z) - (1-methyl-1H-tetrazole-5-yl] yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate are very well suited for controlling undesired animal pests such as insects, acaricides and / or nematodes as well as unwanted phytopathogenic fungi.
Wenn im Rahmen dieser Beschreibung die Kurzform des„common name" eines Wirkstoffes verwendet wird, so sind damit jeweils alle gängigen Derivate, wie die Ester und Salze, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Wird mit dem„common name" ein Ester oder Salz bezeichnet, so sind damit auch jeweils alle anderen gängigen Derivate wie andere Ester und Salze, die freien Säuren und Neutralverbindungen, und Isomere, insbesondere optische Isomere umfasst, insbesondere die handelsübliche Form bzw. Formen. Die angegebenen chemischen Verbindungsnamen bezeichnen zumindest ein der von dem„common name" umfassten Verbindungen, häufig eine bevorzugte Verbindung. If the abbreviated form of the "common name" of an active ingredient is used in the context of this description, then all common derivatives, such as the esters and salts, and isomers, in particular optical isomers, are included, in particular the commercially available form or forms "Common name" an ester or salt, so are all other common derivatives such as other esters and salts comprising free acids and neutral compounds, and isomers, in particular optical isomers, in particular the commercial form or forms. The chemical link names given refer to at least one of the "common name" compounds, often a preferred compound.
Überraschenderweise ist die Insektizide, akarizide, nematizide und fungizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen wesentlich höher als die Summe der Wirkungen der einzelnen Wirkstoffe. Es liegt ein nicht vorhersehbarer echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung. Surprisingly, the insecticidal, acaricidal, nematicidal and fungicidal activity of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unpredictable true synergistic effect and not just an effect supplement.
Bevorzugt sind Kombinationen enthaltend mindestens einen der als bevorzugt, besonders bevorzugt, ganz besonders bevorzugt oder insbesondere bevorzugt angegebenen Wirkstoffe der Formel (I) und einen oder mehrere Wirkstoffe ausgewählt aus der Gruppe (II). Preference is given to combinations containing at least one of the active compounds of the formula (I) given as preferred, particularly preferred, very particularly preferred or particularly preferred, and one or more active substances selected from group (II).
Bevorzugt, besonders bevorzugt, ganz besonders bevorzugt oder insbesondere bevorzugt sind Wirkstoffe der Formel (I), wobei Preferred, particularly preferred, very particularly preferred or particularly preferred are active compounds of the formula (I), where
R1 bevorzugt für Wasserstoff, C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Cyano(C C6-alkyl), C C6-FIaloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, CrC4-Alkoxy-Ci- C4-alkyl, Ci-C4-Alkylthio-Ci-C4-alkyl, C C4-Alkylsulfinyl-Ci-C4-alkyl oder C C4-Alkylsulfonyl- C C4-alkyl steht, R 1 is preferably hydrogen, CC 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, cyano (CC 6 -alkyl), CC 6 -alkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C r C 4 -alkoxy-Ci- C4-alkyl, Ci-C4-alkylthio-Ci-C 4 alkyl, CC 4 alkylsulfinyl-C 4- alkyl or CC 4 -alkylsulfonyl-CC 4 -alkyl,
R1 besonders bevorzugt für Wasserstoff, Methyl, Ethyl, Cyclopropyl, Cyanomethyl, Methoxymethyl, Methylthiomethyl, Methylsulfinylmethyl oder Methylsulfonylmethyl steht, R 1 particularly preferably represents hydrogen, methyl, ethyl, cyclopropyl, cyanomethyl, methoxymethyl, methylthiomethyl, methylsulfinylmethyl or methylsulfonylmethyl,
R1 ganz besonders bevorzugt für Wasserstoff steht, R 1 very particularly preferably represents hydrogen,
R2 bevorzugt für Wasserstoff oder Ci-C6-Alkyl steht. R 2 is preferably hydrogen or C 1 -C 6 -alkyl.
R2 besonders bevorzugt für Wasserstoff oder Methyl steht. R 2 particularly preferably represents hydrogen or methyl.
R2 ganz besonders bevorzugt für Wasserstoff steht. R 2 very particularly preferably represents hydrogen.
R3 bevorzugt für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C4-Alkyl, Ci-C4-Alkoxy, C2-C4-Alkenyl, C2-C4-Alkinyl, C3-C6- Cycloalkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Carboxy, Carbamoyl,, Nitro, Hydroxy, C C4-Alkyl, C C4-Haloalkyl, C3-C6- Cycloalkyl, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4- Alkylsulfonyl, Ci-C4-Alkoxycarbonyl, Ci-C4-Alkylcarbonyl oder einem Phenylring oder einem 4, 5- oder 6-gliedrigen, aromatischen teilgesättigten oder gesättigten heterozyklischen Ring stehen, wobei der Phenylring bzw. heterozyklische Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6- Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, N02, Hydroxy, Ci-C4-Alkoxy, Ci-C4-Haloalkoxy, C C4- Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4- Haloalkylsulfinyl, C C4-Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6- Cycloalkylamino, (C C6-Alkyl)carbonyl, (Ci-C6-Alkoxy)carbonyl oder R 3 preferably represents hydrogen or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents, Ci-C 4 alkyl, Ci-C 4 alkoxy, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl, C 3 - C 6 - is cycloalkyl, where the substituents can be independently selected from halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, CC 4 alkyl, CC 4 haloalkyl, C 3 -C 6 cycloalkyl, CC 4 alkoxy , CC 4 haloalkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 - membered 6-alkylsulfonyl, Ci-C 4 alkoxycarbonyl, Ci-C4-alkylcarbonyl or a phenyl or a 4, 5 or, aromatic partially saturated or saturated heterocyclic ring, wherein the phenyl or heterocyclic ring is optionally mono- or polysubstituted by identical or different substituents, and wherein the substituents may be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl , C 3 -C 6 - cycloalkyl, Ci-C6-haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, carboxy, carbamoyl, N0 2, hydroxy, C -C 4 alkoxy, Ci-C4-haloalkoxy, CC 4 - alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 - haloalkylsulfinyl, CC 4 haloalkylsulfonyl, Ci-C 4 - alkylamino, di- (Ci-C 4 alkyl) amino, C 3 -C 6 - cycloalkylamino, (C-C6 alkyl) carbonyl, (Ci-C 6 alkoxy) carbonyl, or
R3 bevorzugt für C2-C4-Alkoxycarbonyl, C2-C4-Alkylcarbonyl, C2-C4-Alkylaminocarbonyl oder C2- C4.Dialkylaminocarbonyl steht, oder R 3 is preferably C 2 -C 4 alkoxycarbonyl, C 2 -C 4 alkylcarbonyl, C 2 -C 4 alkylaminocarbonyl or C 2 - C 4 .Dialkylaminocarbonyl; or
R3 bevorzugt für einen Phenylring, einen 5- oder 6-gliedrigen aromatischen heterozyklischen Ring oder einen 4-, 5- oder 6-gliedrigen teilgesättigten oder gesättigten heterozyklischen Ring steht, welcher 1-3 Heteroatome aus der Reihe N, S, O enthalten kann, wobei der Phenylring bzw. heterozyklische Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, C C4-Alkyl, C2-C4-Alkenyl, C2-C4-Alkinyl, C3-C6-Cycloalkyl, C C4-Haloalkyl, C2- C4-Haloalkenyl, C2-C4-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, N02, Hydroxy, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4- Alkylsulfonyl, C C4-Haloalkylthio, Ci-C4-Haloalkylsulfmyl, Ci-C4-Haloalkylsulfonyl, C1 -C4- Alkylamino, Di-( Ci-C4-alkyl)amino, C3-C6-Cycloalkylamino, (Ci-C4-Alkyl)carbonyl, (C1 -C4- Alkoxy)carbonyl, R 3 preferably represents a phenyl ring, a 5- or 6-membered aromatic heterocyclic ring or a 4-, 5- or 6-membered partially saturated or saturated heterocyclic ring which may contain 1-3 heteroatoms from the series N, S, O. in which the phenyl ring or heterocyclic ring is optionally mono- or polysubstituted by identical or different substituents, and where the substituents can be selected independently of one another from hydrogen, CC 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 - Alkynyl, C 3 -C 6 cycloalkyl, CC 4 haloalkyl, C 2 -C 4 haloalkenyl, C 2 -C 4 haloalkynyl, C 3 -C 6 halocycloalkyl, halo, cyano, carboxy, carbamoyl, NO 2 , hydroxy , CC 4 -alkoxy, CC 4 haloalkoxy, CC 4 alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 - alkylsulfonyl, CC 4 haloalkylthio, Ci-C 4 -Haloalkylsulfmyl, Ci-C4-haloalkylsulfonyl, C 1 - C 1-4 -alkylamino, di- (C 1 -C 4 -alkyl) amino, C 3 -C 6 -cycloalkylamino, (C 1 -C 4 -alkyl) carbonyl, (C 1 -C 4 -alkoxy) carbonyl,
R3 besonders bevorzugt für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C4-Alkyloder C3-C6-Cycloalkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Carboxy, Hydroxy, C C4-Alkyl, C C4-Haloalkyl, C3-C6-Cycloalkyl, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, C C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C2-C4-Alkoxycarbonyl, C2-C6- Alkylcarbonyl oder einem Phenylring oder einem 4-, 5- oder 6-gliedrigen aromatischen, teilgesättigten oder gesättigten heterozyklischen Ring stehen, wobei der Phenylring bzw. heterozyklischen Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, C C4-Alkyl, C3-C6-Cycloalkyl, C C4-Haloalkyl, C2-C4-Haloalkenyl, C2-C4- Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Hydroxy, Ci-C4-Alkoxy, Ci-C4-Haloalkoxy, oder besonders bevorzugt für C2-C4-Alkoxycarbonyl, C2-C4-Alkylcarbonyl, C2-C4-Alkylaminocarbonyl steht, oder R 3 particularly preferably represents hydrogen or represents in each case optionally mono- or polysubstituted, identically or differently substituted C 1 -C 4 -alkyl or C 3 -C 6 -cycloalkyl, where the substituents can be selected independently of one another from halogen, cyano, carboxy, hydroxy, CC 4 alkyl, CC 4 haloalkyl, C 3 -C 6 cycloalkyl, CC 4 alkoxy, CC 4 haloalkoxy, CC 4 alkylthio, CC 4 alkylsulfmyl, CC 4 alkylsulfonyl, C 2 -C 4 alkoxycarbonyl , C 2 -C 6 - alkylcarbonyl or a phenyl ring or a 4-, 5- or 6-membered aromatic, partially saturated or saturated heterocyclic ring, wherein the phenyl ring or heterocyclic ring optionally monosubstituted or polysubstituted by identical or different substituents, and wherein the substituents can be independently selected from hydrogen, CC 4 alkyl, C 3 -C 6 cycloalkyl, CC 4 haloalkyl, C 2 -C 4 haloalkenyl, C 2 -C 4 haloalkynyl, C 3 -C 6 -Halocycloalkyl, halogen, cyano, hydroxy, Ci-C 4 -alkoxy, Ci-C 4 -haloalkoxy, or particularly preferably for C 2 -C 4 -alkoxycarbonyl, C 2 -C 4 -alkylcarbonyl, C 2 -C 4 -alkylaminocarbonyl stands, or
R3 besonders bevorzugt für einen Phenylrmg, einen 5- oder 6-gliedrigen aromatischen heterozyklischen Ring oder einen 4-, 5- oder 6-gliedrigen, teilgesättigten oder gesättigten heterozyklischen Ring steht, welcher 1 -3 Heteroatome aus der Reihe N, S, O enthalten kann wobei der Phenylring bzw. heterozyklische Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, C C4-Alkyl, C2-C4-Alkenyl, C2-C4-Alkinyl, C3-C6- Cycloalkyl, CrC4-Haloalkyl, C2-C4-Haloalkenyl, C2-C4-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carbamoyl, N02, Hydroxy, C C4-Alkoxy, Ci-C4-Haloalkoxy, oder R3 ganz besonders bevorzugt für Wasserstoff, Methyl, Ethyl, n-Propyl, iso-Propyl, n-Butyl, iso- Butyl, sec-Butyl, tert-Butyl, cyclo-Propyl, cyclo-Butyl, Azetidin, Oxetan, Thietan, Pyrrolidin, Pyrazolidin, Imidazolidin, Imidazolidinon, Tetrahydrofuran, Tetrahydrothiophen, Tetrahydrothiophendioxid, Thiazolin, Thiazolidin, Piperidin, Piperazin, Tetrahydropyran, Dihydrofuranon, Dioxan, Morpholin, Thiomorpholin, Thiomorpholindioxid, Phenyl, Pyridyl, oder R 3 particularly preferably represents a phenyl ring, a 5- or 6-membered aromatic heterocyclic ring or a 4-, 5- or 6-membered, partially saturated or saturated heterocyclic ring which contains 1 -3 heteroatoms from the series N, S, O where the phenyl ring or heterocyclic ring is optionally mono- or polysubstituted by identical or different substituents, and where the substituents can be selected independently of one another from hydrogen, CC 4 -alkyl, C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 3 -C 6 - cycloalkyl, C r C 4 haloalkyl, C 2 -C 4 haloalkenyl, C 2 -C 4 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, carbamoyl, N0 2, Hydroxy, CC 4 alkoxy, Ci-C 4 -haloalkoxy, or R 3 most particularly preferred for hydrogen, methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl , cyclo-propyl, cyclo-butyl, azetidine, oxetane, thietane, pyrrolidine, pyrazolidine, imidazolidine, imidazolidinone, tetrahydrofuran, tetrahyd rothiophene, tetrahydrothiophene dioxide, thiazoline, thiazolidine, piperidine, piperazine, tetrahydropyran, dihydrofuranone, dioxane, morpholine, thiomorpholine, thiomorpholino dioxide, phenyl, pyridyl, or
R3 insbesondere bevorzugt für Wasserstoff, Methyl, iso-Propyl, cyclo-Propyl oder tert-Butyl steht. R 3 particularly preferably represents hydrogen, methyl, isopropyl, cyclopropyl or tert-butyl.
R4 bevorzugt für Wasserstoff, C C4-Alkyl, C C4-Haloalkyl, Halogen, Cyano, C C4-Alkoxy, C C4- Haloalkoxy, C C4-Alkylthio oder Ci-C4-Haloalkylthio steht, zwei benachbarte Reste R4 ebenfalls bevorzugt für -(CH2)3-, -(CH2)4-, -(CH2)5-, -(CH=CH-)2-, -OCH20-, -0(CH2)20-,-OCF20-, -(CF2)20-, -0(CF2)20-, -(CH=CH-CH=N)- oder -(CH=CH-N=CH)- stehen, R 4 is preferably hydrogen, CC 4 alkyl, CC 4 haloalkyl, halogen, cyano, CC 4 alkoxy, CC 4 - haloalkoxy, CC 4 alkylthio or Ci-C 4 haloalkylthio, two adjacent radicals R 4 are also preferred for - (CH 2 ) 3 -, - (CH 2 ) 4 -, - (CH 2 ) 5 -, - (CH = CH-) 2 -, -OCH 2 O-, -O (CH 2 ) 2 O- , -OCF 2 0-, - (CF 2 ) 2 0-, -O (CF 2 ) 2 O-, - (CH = CH-CH = N) - or - (CH = CH-N = CH) - stand .
R4 besonders bevorzugt für Wasserstoff, C C4-Alkyl, Ci-C2-Haloalkyl, Halogen, Cyano oder C C2- Haloalkoxy steht zwei benachbarte Reste R4 besonders bevorzugt für -(CH2)4-, -(CH=CH-)2-, -0(CH2)20-, -0(CF2)20-, - (CH=CH-CH=N)- oder -(CH=CH-N=CH)- stehen, R4 steht ganz besonders bevorzugt für Wasserstoff, Methyl, Trifluormethyl, Cyano, Fluor, Chlor, Brom, Iod oder Trifluormethoxy. Ganz besonders bevorzugt stehen ausserdem zwei benachbarte Reste R4 für -(CH2)4-, oder -(CH=CH-)2-. R 4 is particularly preferably hydrogen, CC 4 alkyl, C 1 -C 2 haloalkyl, halogen, cyano or CC 2 - haloalkoxy is preferably two adjacent radicals R 4 is - (CH 2 ) 4 -, - (CH = CH- ) 2 -, -O (CH 2 ) 2 O-, -O (CF 2 ) 2 O-, - (CH = CH-CH = N) - or - (CH = CH-N = CH) -, R 4 very particularly preferably represents hydrogen, methyl, trifluoromethyl, cyano, fluorine, chlorine, bromine, iodine or trifluoromethoxy. Very particularly preferably, two adjacent radicals R 4 are - (CH 2 ) 4 -, or - (CH = CH-) 2 -.
R4 steht insbesondere bevorzugt für Chlor, Fluor oder Brom, R 4 particularly preferably represents chlorine, fluorine or bromine,
R4 steht weiterhin insbesondere bevorzugt für Iod oder Cyano. zwei benachbarte Reste R4 stehen insbesondere bevorzugt für -(CH=CH-)2 n bevorzugt für 0, 1 , 2 steht, n besonders bevorzugt für 1 oder 2 steht, n ganz besonders bevorzugt für 1 steht, R 4 furthermore particularly preferably represents iodine or cyano. two adjacent radicals R 4 are particularly preferably - (CH =CH-) 2 n is preferably 0, 1, 2, n is more preferably 1 or 2, n is very particularly preferably 1,
R5 bevorzugt für C C4-Alkyl, C3-C6-Cycloalkyl, C C4-Haloalkyl, d-C6-Halocycloalkyl, C2-C6- Alkenyl, C2-C4-Haloalkenyl, C2-C4-Alkinyl, C2-C4-Haloalkinyl, CrC4-Alkoxy, Ci-C4-Haloalkoxy, C C4-Alkylthio, C C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Halo- alkylsulfinyl, Ci-C4-Haloalkylsulfonyl, Halogen, Cyano, Nitro oder C3-C6-Trialkylsilyl steht, R 5 is preferably CC 4 alkyl, C 3 -C 6 cycloalkyl, CC 4 haloalkyl, dC 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 4 haloalkenyl, C 2 -C 4 alkynyl , C 2 -C 4 haloalkynyl, C r C 4 alkoxy, Ci-C4 haloalkoxy, alkylthio CC 4, CC 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC -Halo- 4 alkylsulfinyl, C 1 -C 4 -haloalkylsulfonyl, halogen, cyano, nitro or C 3 -C 6 -trialkylsilyl,
R5 besonders bevorzugt für C C4-Alkyl, C3-C6-Cycloalkyl, Ci-C4-Haloalkyl, Ci-C6-Halocycloalkyl, C2-C6-Alkenyl, C2-C4-Haloalkenyl, C2-C4-Alkinyl, C2-C4-Haloalkinyl, C C4-Alkoxy, C C4- Haloalkoxy, Fluor, Chlor, Brom, Iod, Cyano, Nitro oder C3-C6-Trialkylsilyl steht, R 5 particularly preferred for CC 4 alkyl, C 3 -C 6 cycloalkyl, Ci-C 4 haloalkyl, Ci-C 6 -Halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 4 haloalkenyl, C 2 C 4 alkynyl, C 2 -C 4 haloalkynyl, CC 4 alkoxy, CC 4 haloalkoxy, fluoro, chloro, bromo, iodo, cyano, nitro or C 3 -C 6 trialkylsilyl,
R5 ganz besonders bevorzugt für Methyl, Fluor, Chlor, Brom oder Iod steht, R 5 very particularly preferably represents methyl, fluorine, chlorine, bromine or iodine,
R5 insbesondere bevorzugt für Methyl oder Chlor steht, R 5 particularly preferably represents methyl or chlorine,
Qx bevorzugt für einen gebenenfalls einfach oder mehrfach, gleich oder verschieden durch R7 substituierten 5-6 gliedrigen heteroaromatischen Ring steht, welcher 1-3 Heteroatome aus der Reihe N, O, S enthalten kann, oder für Phenyl steht, Qx preferably represents an optionally mono- or polysubstituted by identical or different substituent R 7 substituted 5-6 membered heteroaromatic ring, which may contain 1-3 heteroatoms from the series N, O, S, or represents phenyl,
Qx besonders bevorzugt für einen gebenenfalls einfach oder mehrfach, gleich oder verschieden durch R7 substituierten, 5- oder 6-gliedrigen Ring steht, ausgewählt aus der Gruppe bestehend aus Furan, Thiophen, Triazol, Imidazol, Thiazol, Oxazol, Isoxazol, Isothiazol, Thiadiazol, Oxadiazol, Pyrrol, Pyridin, Pyrimidin, Pyridazin, Pyrazin, Phenyl oder Pyrazol, Qx particularly preferably represents an optionally mono- or polysubstituted by identical or different substituents represented by R 7, 5- or 6-membered ring selected from the group consisting of furan, thiophene, triazole, imidazole, thiazole, oxazole, isoxazole, isothiazole, thiadiazole , Oxadiazole, pyrrole, pyridine, pyrimidine, pyridazine, pyrazine, phenyl or pyrazole,
Qx ganz besonders bevorzugt für Thiazol, Oxazol, Pyrrol, Imidazol, Triazol, Pyrimidin, Phenyl oder für Pyrazol steht, welches durch die Gruppe R7 Qx very particularly preferably represents thiazole, oxazole, pyrrole, imidazole, triazole, pyrimidine, phenyl or pyrazole, which is represented by the group R 7
einfach substituiert ist, wobei Z, R und p die oben angegebenen allgemeinen bzw. die unten angegebenen bevorzugten oder besonders bevorzugten Bedeutungen haben können, is monosubstituted, where Z, R and p may have the abovementioned general or the preferred or particularly preferred meanings given below,
A bevorzugt für gegebenenfalls, einfach oder mehrfach, substituiertes -(Ci-C4-alkylen)-, -(C2-C4- alkenylen)-, -(C2-C4-alkinylen)-, -R8-(C3-C6-cycloalkyl)-R8-, -R8-0-R8-, -R8-S-R8-, -R8-S(=0)-R8-, -R8-S(=0)2-R8-, -R8-NH-(C C4-Alkyl)-, -R8-N(C C4-Alkyl)-R8, -R8-C=NO(C C4-Alkyl), -R8- C(=0)-R8, -R8-C(=S)-R8, -R8-C(=0)NH-R8, R8-C(=0)N(C C4-Alkyl)-R8, -R8-S(=0)2NH-R8, -R8- S(=0)2N(C C4-Alkyl)-R8, -R8-NH(C=0)0-R8, -R8-N(C C4-Alkyl)-(C=0)0-R8, -R8- NH(C=0)NH-R8, -R8-NHS(=0)2-R8, -R8-N(C C4-Alkyl)S(=0)2-R8, R8-NH-R8, R8-C(=0)-C(=0)- R8, R8-C(OH)-R8 , R8-Qz-R8 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Nitro, Hydroxy, C C6-Alkyl, C C6-Alkyoxy oder Halogen-Ci-C6-Alkyl, wobei Qz die oben angegebenen allgemeinen bzw. die unten angegebenen bevorzugten oder besonders bevorzugten Bedeutungen haben kann A preferably represents optionally mono- or poly-substituted - (Ci-C 4 alkylene) -, - (C 2 -C 4 - alkenylene), - (C 2 -C 4 alkynylene), -R 8 - (C 3 -C 6 cycloalkyl) -R 8 -, -R 8 -O-R 8 -, -R 8 -SR 8 -, R 8 -S (= O) -R 8 -, -R 8 -S (= O) 2 -R 8 -, -R 8 -NH- (CC 4 alkyl) -, -R 8 -N (CC 4 -alkyl) -R 8 , -R 8 -C = NO (CC 4 -alkyl), -R 8 --C (= O) -R 8 , -R 8 -C (= S) -R 8 , -R 8 -C (= O) NH-R 8 , R 8 -C (= O) N (CC 4 alkyl) -R 8 , -R 8 -S (= O) 2 NH-R 8 , -R 8 - S (= O) 2 N (CC 4 alkyl) -R 8 , -R 8 -NH (C = O) O-R 8 , -R 8 -N (CC 4 alkyl) - (C = O ) 0-R 8 , -R 8 - NH (C = O) NH-R 8 , -R 8 -NHS (= O) 2 -R 8 , -R 8 -N (CC 4 -alkyl) S (= 0 ) 2 -R 8 , R 8 -NH-R 8 , R 8 -C (= O) -C (= O) - R 8 , R 8 -C (OH) -R 8 , R 8 -Qz-R 8 where the substituents can be selected independently of one another from halogen, cyano, nitro, hydroxy, CC 6 alkyl, CC 6 -alkoxy or halogeno-C 1 -C 6 -alkyl, where Q z are the general or the preferred radicals given above or particularly preferred meanings
A besonders bevorzugt für -CH2-, -CH20-, -CH2OCH2-, -CH2S-, -CH2SCH2-, -CH2N(C C4-Alkyl)-, -CH2N(C C4-Alkyl)CH2-, -CH(Hal)-, -C(Hal)2-, -CH(CN)-, CH2(CO)-, CH2(CS)-, CH2CH(OH)-, -Cyclopropyl-, CH2(CO)CH2-, -CH(C C4-Alkyl)-, -C(Di-C C6-Alkyl)-, -CH2CH2-, -CH=CH-, - C=C-, -C=NO(C C6-Alkyl), -C(=0)(C C4-Alkyl)- steht, A particularly preferred for -CH 2 -, -CH 2 O-, -CH 2 OCH 2 -, -CH 2 S-, -CH 2 SCH 2 -, -CH 2 N (CC 4 alkyl) -, -CH 2 N (CC 4 alkyl) CH 2 -, -CH (Hal) -, -C (Hal) 2 -, -CH (CN) -, CH 2 (CO) -, CH 2 (CS) -, CH 2 CH (OH) -, -cyclopropyl-, CH 2 (CO) CH 2 -, -CH (CC 4 -alkyl) -, -C (di-C 6 -alkyl) -, -CH 2 CH 2 -, -CH = CH-, -C = C-, -C = NO (CC 6 -alkyl), -C (= O) (CC 4 -alkyl) -,
A ganz besonders bevorzugt für -CH2-, -CH(CH3), C(CH3)2, -CH2CH2-, -CH(CN)-, -CH20- oder -C(=0)-CH2-steht, A is very particularly preferably -CH 2 -, -CH (CH 3 ), C (CH 3 ) 2 , -CH 2 CH 2 -, -CH (CN) -, -CH 2 O- or -C (= 0) -CH 2- stands,
A insbesonders bevorzugt für CH2, CH(CH3), -CH20- oder -C(=0)-CH2- steht, A particularly preferably represents CH 2 , CH (CH 3 ), -CH 2 O- or -C (= O) -CH 2 -,
Qz bevorzugt für einen 3- bis 4-gliedrigen, teilweise gesättigten oder gesättigten, oder für einen 5 bis 6-gliedrigen, teilweise gesättigten, gesättigten oder aromatischen Ring steht,wobei der Ring gegebenenfalls 1 -3 Heteroatome aus der Reihe N,S,0 enthalten kann, wobei der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6- Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Hydroxy, C C4-Alkoxy, Ci-C4-Haloalkoxy, C C4- Alkylthio, C C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkylsulfmyl, C C4-Haloalkylsulfonyl, Qz preferably represents a 3- to 4-membered, partially saturated or saturated, or for a 5- to 6-membered, partially saturated, saturated or aromatic ring, wherein the ring is optionally 1 -3 heteroatoms from the series N, S, 0 may contain, where the ring is optionally mono- or polysubstituted by identical or different substituents, and wherein the substituents may be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 - Alkynyl, C 3 -C 6 -cycloalkyl, C 1 -C 6 -haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, hydroxy, CC 4 - alkoxy, Ci-C4-haloalkoxy, CC 4 - alkylthio, CC 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 -Haloalkylsulfmyl, CC 4 haloalkylsulfonyl,
Qz besonders bevorzugt für einen 3- bis 4-gliedrigen, teilweise gesättigten oder gesättigten, oder für einen 5-gliedrigen, teilweise gesättigten, gesättigten oder aromatischen Ring steht, wobei der Ring gegebenenfalls 1 -2 Heteroatome aus der Reihe N,S,0 enthalten kann, wobei der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-Cö-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6- Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Hydroxy, C C4-Alkoxy, C C4-Haloalkoxy, C C4- Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkylsulfmyl, C C4-Haloalkylsulfonyl, Qz ganz besonders bevorzugt für Azetidin, Oxetan oder Thietan, Pyrrolidin, Pyrrolin, Pyrazolidin, Pyrazolin, Imidazolidin, Imidazolidon, Imidazolin, Tetrahydrofuran, Tetrahydrothiophen, Thiazolidin, Isothiazolidin, Isoxazolin, steht, welche gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Methyl, Ethyl, iso- Propyl, Hydroxy, Methoxy, Trifluormethoxy, Fluor, Chlor, Brom, Cyano, Difluormethyl, Trifluormethyl, bevorzugt für C C6-Alkyl steht oder für den Rest Q.sup.2 is particularly preferably a 3- to 4-membered, partially saturated or saturated, or a 5-membered, partially saturated, saturated or aromatic ring, the ring optionally containing 1 -2 heteroatoms from the series N, S, O. where the ring is optionally mono- or polysubstituted by identical or different substituents, and where the substituents can be selected independently of one another from hydrogen, C 1 -C 6 -alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, Ci-C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 - haloalkynyl, C 3 - C 6 halocycloalkyl, halogen, cyano, hydroxy, CC 4 -alkoxy, CC 4 haloalkoxy, CC 4 - alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 -Haloalkylsulfmyl, CC 4 -Haloalkylsulfonyl, Qz very particularly preferably for azetidine, oxetane or thietane, pyrrolidine, pyrroline, pyrazolidine, pyrazoline, imidazolidine, imidazolidone, imidazoline, tetrahydrofuran, tetrahydrothiophene, thiazolidine, isothiazolidine, isoxazoline, which optionally mono- or polysubstituted the same or different is, and wherein the substituents can be independently selected from hydrogen, methyl, ethyl, iso-propyl, hydroxy, methoxy, trifluoromethoxy, fluorine, chlorine, bromine, cyano, difluoromethyl, trifluoromethyl, preferably CC 6 alkyl or for the rest
weiterhin bevorzugt für C3-C6-Cycloalkoxy steht, besonders bevorzugt für Methyl steht oder für den Rest furthermore preferably represents C 3 -C 6 -cycloalkoxy, more preferably represents methyl or the radical
steht,  stands,
R9 unabhängig voneinander bevorzugt für Wasserstoff, Halogen, Cyano, C C4-Alkyl, C C4-Alkoxy, Ci-C4-Haloalkyl, C C4-Haloalkoxy, C C4-Haloalkylsulfonyl oder (Ci-C4-Alkyl)Ci-C4-Alkoxyimino steht, R 9 independently of one another are preferably hydrogen, halogen, cyano, CC 4 alkyl, CC 4 -alkoxy, C 1 -C 4 -haloalkyl, CC 4 -haloalkoxy, CC 4 -haloalkylsulfonyl or (C 1 -C 4 -alkyl) C 1 -C 4 -alkyl 4- alkoxyimino stands,
R9 unabhängig voneinander besonders bevorzugt für Wasserstoff, Halogen, Cyano oder C C4- Haloalkyl steht, R 9 independently of one another particularly preferably represents hydrogen, halogen, cyano or CC 4 -haloalkyl,
R9 unabhängig voneinander ganz besonders bevorzugt für Fluor, Chlor oder Brom steht, R9 insbesondere bevorzugt für Chlor steht, p bevorzugt für 1, 2 oder 3 steht, p besonders bevorzugt für 1 oder 2 steht, p ganz besonders bevorzugt für 1 steht, R 9 independently of one another very particularly preferably represents fluorine, chlorine or bromine, R 9 particularly preferably represents chlorine, p is preferably 1, 2 or 3, p is more preferably 1 or 2, p is very particularly preferably 1,
Z bevorzugt für N, CH, CF, CC1, CBr oder CI steht, Z is preferably N, CH, CF, CC1, CBr or CI,
Z besonders bevorzugt für N, CH, CF, CC1 oder CBr steht, Z particularly preferably represents N, CH, CF, CC1 or CBr,
Z ganz besonders bevorzugt für N, CC1 oder CH steht, Z very particularly preferably represents N, CC1 or CH,
R8 bevorzugt für linear oder verzweigtes -(Ci-C4-alkylen)-oder für eine direkte Bindung steht R 8 preferably represents linear or branched - (C 1 -C 4 -alkylene) or represents a direct bond
R8 besonders bevorzugt für Methyl, Ethyl, Propyl, iso-Propyl, n-Butyl, sec-Butyl oder -iso-Butyl oder eine direkte Bindung steht R 8 particularly preferably represents methyl, ethyl, propyl, iso-propyl, n-butyl, sec-butyl or iso-butyl or a direct bond
R8 ganz besonders bevorzugt für Methyl oder Ethyl oder eine direkte Bindung steht R 8 very particularly preferably represents methyl or ethyl or a direct bond
QY bevorzugt für einen 5-oder 6-gliedrigen, teilweise gesättigten oder gesättigten heterozyklischen oder heteroaromatischen Ring oder ein aromatisches 8-, 9- oder 10-gliedriges annelliertes heterobicyclisches Ringsystem steht, wobei die Heteroatome ausgewählt sein können aus der Reihe N, S, O, wobei der Ring oder das Ringsystem, gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6- Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, Nitro, Hydroxy, Ci-C4-Alkoxy, d-C4-Haloalkoxy, C C4- Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkyl- sulfmyl, C i -C4-Haloalkylsulfonyl, oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei Phenyl oder der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden mit Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-Cö-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Nitro, Hydroxy, Ci-C4-Alkoxy, C C4-Haloalkoxy substituiert sein können, Q Y preferably represents a 5- or 6-membered, partially saturated or saturated heterocyclic or heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system, where the heteroatoms can be selected from the series N, S, O, wherein the ring or the ring system is optionally mono- or polysubstituted by identical or different substituents, and wherein the substituents may be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 - cycloalkyl, Ci-C6-haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, Ci-C 4 alkoxy, dC 4 haloalkoxy, CC 4 - alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 alkylsulfonyl, haloalkylthio CC 4, CC 4 haloalkyl sulfmyl, C i -C 4 haloalkylsulfonyl, or wherein the substituents may be independently selected from phenyl or a 5- or 6-g song heteroaromatic ring, said phenyl or the ring is optionally mono- or polysubstituted, identically or differently, with Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, C -Cö haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, nitro, hydroxy, Ci-C 4 alkoxy, CC 4 haloalkoxy may be substituted,
QY besonders bevorzugt für einen gegebenenfalls einfach oder mehrfach substituierten 5- oder 6- gliedrigen heteroaromatischen Ring der Reihe Q-l bis Q-53 und Q-58 bis Q-59, Q62 bis Q63, einen aromatisches 9-gliedriges annelliertes heterobicyclisches Ringsystem Q-54 bis Q-56 sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 bis Q-61 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus CrC3-Alkyl, d-C3-Haloalkyl, Ci-C2- Alkoxy , Halogen, Cyano, Hydroxy, Nitro oder C C2-Haloalkoxy, oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei Phenyl oder der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden mit Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-Cö-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, N02, Hydroxy, Ci-C4-Alkoxy, C C4-Haloalkoxy substituiert sein können, Q Y particularly preferably represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q1 to Q-53 and Q-58 to Q-59, Q62 to Q63, a 9-membered aromatic heterobicyclic ring system Q-54 to Q-56 and to a 5-membered heterocyclic ring Q-60 to Q-61, wherein the substituents can be independently selected from C r C 3 alkyl, dC 3 haloalkyl, Ci-C 2 - alkoxy, halogen, cyano, hydroxy, nitro or CC 2 haloalkoxy, or wherein the substituents can be independently selected from phenyl or a 5- or 6-membered heteroaromatic ring, wherein phenyl or the ring is optionally mono- or polysubstituted, identically or differently, with Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 Cycloalkyl, C 1 -C 6 haloalkyl, C 2 -C 6 haloalkenyl, C 2 -C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, halo, cyano, NO 2 , hydroxy, C 1 -C 4 alkoxy, CC 4 -haloalkoxy may be substituted,
QY ganz besonders bevorzugt für einen gegebenenfalls einfach oder mehrfach substituierten 5- oder 6-gliedrigen heteroaromatischen Ring der Reihe Q-36 bis Q-40 ,Q43, Q-58 bis Q-59, Q62, Q63, einen aromatisches 9-gliedriges annelliertes heterobicyclisches Ringsystem Q-54 bis Q-56 sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 bis Q-61 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus C C3-Alkyl, Ci-C3-Haloalkyl, C C2- Alkoxy, Halogen, Cyano, Hydroxy, Nitro oder Ci-C2-Haloalkoxy, oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei Phenyl oder der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden mit Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Nitro, CrC4-Alkoxy, d-C4-Haloalkoxy substituiert sein können, Q Y most preferably represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q-36 to Q-40, Q43, Q-58 to Q-59, Q62, Q63, an aromatic 9-membered fused heterobicyclic ring system Q-54 to Q-56 and also a 5-membered heterocyclic ring Q-60 to Q-61, where the substituents can be selected independently of one another from CC 3 -alkyl, C 1 -C 3 -haloalkyl, CC 2 - Alkoxy, halogen, cyano, hydroxy, nitro or Ci-C 2 haloalkoxy, or wherein the substituents can be independently selected from phenyl or a 5- or 6-membered heteroaromatic ring, wherein phenyl or the ring optionally mono- or polysubstituted, identical or differently, with Ci-C 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, CC 6 haloalkyl, C 2 -C 6 haloalkenyl, C 2 - C 6 haloalkynyl, C 3 -C 6 halocycloalkyl, halogen, cyano, nitro, C r C 4 alkoxy, dC 4 haloalkoxy substitu can be
QY insbesonders bevorzugt für einen gegebenenfalls einfach oder mehrfach gleich oder verschieden substituierten heteroaromatischen Ring der Reihe Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 und Q63, sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Methyl, Ethyl, cyclo-Propyl, tert-Butyl, Chlor, Fluor, Iod, Brom, Cyano, Nitro, Difluormethyl, Trifluormethyl, Pentafluorethyl, n- Heptafluorpropyl und iso-Heptafluorpropyl oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Methyl, Ethyl, cyclo-Propyl, tert-Butyl, Chlor, Fluor, Iod, Brom, Cyano, Nitro, Difluormethyl, Trifluormethyl, Pentafluorethyl., n-Heptafluorpropyl und iso-Heptafluorpropyl, Die oben aufgeführten Ringe oder Ringsysteme können gegebenenfalls unabhängig voneinander zusätzlich durch Oxo, Thioxo, (=0)=NH, (=0)=N-CN, (=0)2 substituiert sein. Beispielhaft seien genannt Tetrahydrothiophendioxid, Imidazolidon. Q Y particularly preferred for an optionally mono- or polysubstituted or differently substituted heteroaromatic ring of the series Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 and Q63, as well as for a 5-membered heterocyclic ring Q-60, where the substituents can be selected independently of one another from methyl, ethyl, cyclopropyl, tert-butyl, chlorine, fluorine, iodine, bromine, cyano, nitro, difluoromethyl, trifluoromethyl, pentafluoroethyl, n-heptafluoropropyl and isoheptafluoropropyl or where the substituents can be selected independently of one another from phenyl or a 5- or 6-membered heteroaromatic ring, where the substituents can be selected independently of one another from methyl, ethyl, cyclopropyl, tert-butyl, Chlorine, fluorine, iodine, bromine, cyano, nitro, difluoromethyl, trifluoromethyl, pentafluoroethyl, n-heptafluoropropyl and isoheptafluoropropyl, The rings or ring systems listed above may optionally be substituted independently by oxo, thioxo, (= O) = NH, (= O) = N-CN, (= O) 2 . Examples include tetrahydrothiophene dioxide, imidazolidone.
Die Oxogruppe als Substituent an einem Ring-C-Atom bedeutet dann beispielsweise eine Carbonylgruppe im heterocyclischen Ring. Dadurch sind vorzugsweise auch Lactone und Lactame umfasst. Die Oxogruppe kann auch an den Heteroringatomen, die in verschiedenen Oxidationsstufen existieren können, z.B. bei N und S, auftreten und bilden dann beispielsweise die divalenten Gruppen -N(O)-, -S(O)- (auch kurz SO) und -S(0)2- (auch kurz S02) im heterocyclischen Ring. Im Fall von - N(O)- und -S(0)-Gruppen sind jeweils beide Enantiomere umfasst. Andere Substituenten als die Oxogruppe können an einem heterocyclischen Ring auch an einem Heteroatom gebunden sein, beispielsweise an einem Stickstoffatom, wenn dabei ein Wasserstoffatom am Stickstoffatom des Grundkörpers ersetzt wird. Im Falle des Stickstoffatoms und auch anderer Heteroatome wie z. B. des Schwefelatoms, kommt auch eine weitere Substitution unter Bildung von quartären Ammoniumverbindungen oder Sulfoniumverbindungen in Frage. Insbesondere können die Verbindungen der Formeln (I) in Form verschiedener Regioisomere vorliegen. Beispielsweise in Form von Mischungen aus Verbindungen mit der Definition Q62 bzw. Q63 oder in Form von Mischungen aus Q58 und Q59. Erfindungsgemäß umfasst sind daher auch Wirkstoffkombinationen enthaltend Mischungen aus Verbindungen der Formeln (I), wobei QY die Bedeutungen Q62 und Q63, sowie Q58 und Q59 hat und die Verbindungen in verschiedenen Mischungsverhältnissen vorliegen können, und einen oder mehrere Wirkstoffe aus der Gruppe (II). Bevorzugt sind dabei Mischungsverhältnisse aus Verbindungen der Formel (I), worin der Rest QY für Q62 oder für Q58 steht zu Verbindungen der Formel (I) worin der Rest Qy für Q63 oder für Q59 steht, von 60:40 bis 99: 1, besonders bevorzugt von 70:30 bis 97:3, ganz besonders bevorzugt von 80:20 bis 95:5. Insbesondere bevorzugt sind die folgenden Mischungsverhältnisse einer Verbindung der Formel (I), wobei QY die Bedeutung Q62 oder Q58 hat zur Verbindung der Formel (I), wobei QY die Bedeutung Q63 oder Q59 hat: 80:20; 81 : 19; 82: 18; 83: 17; 84:16; 85: 15, 86: 14; 87: 13; 88: 12; 89: 11; 90:10, 91 :9; 92:8; 93:7; 96:6; 95;5. The oxo group as a substituent on a ring C atom then means, for example, a carbonyl group in the heterocyclic ring. As a result, lactones and lactams are preferably also included. The oxo group can also occur on the hetero ring atoms, which can exist in different oxidation states, for example at N and S, and then form, for example, the divalent groups -N (O) -, -S (O) - (also short SO) and -S (0) 2 - (also short S0 2 ) in the heterocyclic ring. In the case of - N (O) and -S (0) groups, both enantiomers are included. Substituents other than the oxo group may also be bonded to a heteroatom on a heterocyclic ring, for example a nitrogen atom, if a hydrogen atom on the nitrogen atom of the main body is replaced. In the case of the nitrogen atom and other heteroatoms such. As the sulfur atom, is also a further substitution to form quaternary ammonium compounds or sulfonium compounds in question. In particular, the compounds of formulas (I) may be in the form of various regioisomers. For example in the form of mixtures of compounds with the definition Q62 or Q63 or in the form of mixtures of Q58 and Q59. Accordingly, the invention also includes active compound combinations comprising mixtures of compounds of the formulas (I), where Q Y has the meanings Q62 and Q63, and Q58 and Q59 and the compounds can be present in different mixing ratios, and one or more active compounds from the group (II) , While mixing ratios of from compounds of formula (I) wherein the radical Q Y is Q62 or Q58 are preferred to compounds of formula (I) wherein the radical Qy represents Q63 or Q59, from 60:40 to 99: 1, more preferably from 70:30 to 97: 3, most preferably from 80:20 to 95: 5. Especially preferred are the following mixing ratios of a compound of formula (I) wherein Q Y is Q62 or Q58 to the compound of formula (I) wherein Q Y is Q63 or Q59: 80:20; 81: 19; 82: 18; 83: 17; 84:16; 85: 15, 86: 14; 87: 13; 88: 12; 89: 11; 90:10, 91: 9; 92: 8; 93: 7; 96: 6; 95; 5th
Weiterhin bevorzugt sind Wirkstoffkombinationen enthaltend mindestens einen Wirkstoff der Formel (1-1) Also preferred are combinations of active substances containing at least one active substance of the formula (1-1)
in welcher in which
R3 für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes C C6-Alkyl, C C6-Alkoxy, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-Ci2-Cycloalkyl, C3- Ci2-Cycloalkyl-Ci-C6-Alkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Amino, Cyano, Nitro, Hydroxy, Ci-C6-Alkyl, C3-C6-Cycloalkyl, C1 -C4- Alkoxy, Ci-C4-Haloalkoxy, C C4-Alkylthio, C2-C6-Alkoxycarbonyl, Ci-C6-Alkylcarbonyl C3-C6- Cycloalkylamino oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, R 3 is hydrogen or each optionally mono- or polysubstituted by identical or different substituents CC 6 alkyl, CC 6 alkoxy, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 2 cycloalkyl, C 3 - Ci 2 cycloalkyl-Ci-C6-alkyl, wherein the substituents may be independently selected from halogen, amino, cyano, nitro, hydroxy, Ci-C 6 alkyl, C 3 -C 6 cycloalkyl, C 1 -C4- alkoxy, Ci-C4-haloalkoxy, CC 4 -alkylthio, C 2 -C 6 alkoxycarbonyl, Ci-C6-alkylcarbonyl, C3 -C6- cycloalkylamino or a 5- or 6-membered heteroaromatic ring,
R4 für Halogen, Cyano oder Methyl steht, R 4 is halogen, cyano or methyl,
R5 für Methyl oder Chlor steht, R 5 is methyl or chlorine,
Z für N, CC1 oder CH steht, Z is N, CC1 or CH,
Qy für einen gegebenenfalls einfach oder mehrfach substituierten 5- oder 6-gliedrigen heteroaromatischen Ring der Reihe Q-36 bis Q-40 ,Q43, Q-58 bis Q-59, Q62, Q63, einen aromatisches 9-gliedriges annelliertes heterobicyclisches Ringsystem Q-54 bis Q-56 sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 bis Q-61 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Ci-C3-Alkyl, Ci-C3-Haloalkyl, d-C2-Alkoxy, Halogen, Cyano, Hydroxy, Nitro oder C C2-Haloalkoxy, wobei die Verbindungen der Formel (1-1) in Form von Salzen vorliegen können, und einen oder mehrere Wirkstoffe ausgewählt aus der Gruppe (II), Qy represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q-36 to Q-40, Q43, Q-58 to Q-59, Q62, Q63, a 9-membered aromatic heterobicyclic ring system Q- 54 to Q-56 and also a 5-membered heterocyclic ring Q-60 to Q-61, where the substituents can be selected independently of one another from C 1 -C 3 -alkyl, C 1 -C 3 -haloalkyl, C 1 -C 2 -alkoxy, Halogen, cyano, hydroxy, nitro or CC 2 -haloalkoxy, where the compounds of the formula (1-1) may be present in the form of salts, and one or more active substances selected from the group (II),
Besonders bevorzugt sind Kombinationen enthaltend mindestens einen der als bevorzugt, besonders bevorzugt, ganz besonders bevorzugt oder insbesondere bevorzugt angegebenen Wirkstoffe der Formel (1-1) und einen oder mehrere Wirkstoffe ausgewählt aus der Gruppe (II). Particular preference is given to combinations containing at least one of the active compounds of the formula (1-1) given as preferred, particularly preferred, very particularly preferred or particularly preferred, and one or more active compounds selected from the group (II).
Bevorzugt, besonders bevorzugt, ganz besonders bevorzugt oder insbesondere bevorzugt sind Wirkstoffe der Formel (1- 1), wobei bevorzugt für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C6-Alkyl, C C6-Alkoxy, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6- Cycloalkyl, C3-C6-Cycloalkyl-Ci-C6-Alkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Amino, Hydroxy, Ci-C6-Alkyl, C1 -C4- Alkoxy, Ci-C4-Haloalkoxy, Ci-C4-Alkylthio, Cj-Cb-Cycloalkyl, einem 5 oder 6-gliedrigen heteroaromatischen Ring enthaltend 1 -2 Heteroatome aus der Reihe N,0, S, wobei nicht zwei Sauerstoffatome im Ring benachbart sind, besonders bevorzugt für_einen der folgenden Reste steht Preferred, particularly preferred, very particularly preferred or particularly preferred The compounds of formula (1 1), preferably represents hydrogen or represents in each case optionally monosubstituted or polysubstituted by identical or different substituents, Ci-C 6 alkyl, CC 6 alkoxy, C 2 -C 6 alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 - cycloalkyl, C 3 -C cycloalkyl-Ci-C stands 6 6 alkyl, wherein the substituents may be independently selected from halogen, cyano, amino, hydroxy, Ci-C 6 alkyl , C 1 -C4- alkoxy, Ci-C4-haloalkoxy, Ci-C4 alkylthio, Cj-C b cycloalkyl, a 5 or 6-membered heteroaromatic ring containing 1 -2 heteroatoms from the series N, 0, S in which two oxygen atoms are not adjacent in the ring, more preferably one of the following radicals
R4 bevorzugt für Halogen, Cyano oder Methyl steht, R 4 is preferably halogen, cyano or methyl,
R4 besonders bevorzugt für Chlor und Cyano steht, R 4 particularly preferably represents chlorine and cyano,
R4 ebenfalls besonders bevorzugt für Brom, Fluor, Jod oder Methyl steht, R 4 is also particularly preferably bromine, fluorine, iodine or methyl,
R5 bevorzugt und besonders bevorzugt für Methyl steht, Z bevorzugt für N oder CH steht, R 5 is preferably and more preferably methyl, Z is preferably N or CH,
QY bevorzugt für einen gegebenenfalls einfach oder mehrfach gleich oder verschieden substituierten heteroaromatischen Ring der Reihe Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 und Q63, sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Methyl, Ethyl, cyclo-Propyl, tert-Butyl, Chlor, Fluor, Iod, Brom, Cyano, Nitro, Difluormethyl, Trifluormethyl, Pentafluorethyl., n-Heptaf uorpropyl und iso-Heptafluorpropyl. QY is preferably an optionally mono- or polysubstituted or differently substituted heteroaromatic ring of the series Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 and Q63, as well as a 5 -member heterocyclic ring Q-60, wherein the substituents can be independently selected from methyl, ethyl, cyclo-propyl, tert-butyl, chlorine, fluorine, iodine, bromine, cyano, nitro, difluoromethyl, trifluoromethyl, pentafluoroethyl, n Heptafuoropropyl and isoheptafluoropropyl.
QY besonders bevorzugt für einen gegebenenfalls einfach oder mehrfach gleich oder verschieden substituierten heteroaromatischen Ring der Reihe Q-58 und Q-59 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Methyl, Ethyl, cyclo-Propyl, tert-Butyl, Difluormethyl, Trifluormethyl, Pentafluorethyl., n-Heptafluorpropyl und iso-Heptafluorpropyl. QY particularly preferably represents an optionally mono- or polysubstituted or different substituted heteroaromatic ring of the series Q-58 and Q-59, wherein the substituents can be independently selected from methyl, ethyl, cyclo-propyl, tert-butyl, difluoromethyl, trifluoromethyl, pentafluoroethyl, n-heptafluoropropyl and iso-heptafluoropropyl.
Insbesondere können die Verbindungen der Formeln (1-1) in Form verschiedener Regioisomere vorliegen. Beispielsweise in Form von Mischungen aus Verbindungen mit der Definition Q62 bzw. Q63 oder in Form von Mischungen aus Q58 und Q59. Erfindungsgemäß umfasst sind daher auch Wirkstoffkombinationen enthaltend Mischungen aus Verbindungen der Formeln (1-1), wobei QY die Bedeutungen Q62 und Q63, sowie Q58 und Q59 hat und die Verbindungen in verschiedenen Mischungsverhältnissen vorliegen können, und einen oder mehrere Wirkstoffe aus der Gruppe (II). Bevorzugt sind dabei Mischungsverhältnisse aus Verbindungen der Formel (I), worin der Rest QY für Q62 oder für Q58 steht zu Verbindungen der Formel (I) worin der Rest Qy für Q63 oder für Q59 steht, von 60:40 bis 99: 1, besonders bevorzugt von 70:30 bis 97:3, ganz besonders bevorzugt von 80:20 bis 95:5. Insbesondere bevorzugt sind die folgenden Mischungsverhältnisse einer Verbindung der Formel (I), wobei QY die Bedeutung Q62 oder Q58 hat zur Verbindung der Formel (I), wobei QY die Bedeutung Q63 oder Q59 hat: 80:20; 81 : 19; 82: 18; 83: 17; 84: 16; 85: 15, 86: 14; 87: 13; 88: 12; 89: 11 ; 90: 10, 91 :9; 92:8; 93 :7; 96:6; 95;5. In particular, the compounds of formulas (1-1) may be in the form of various regioisomers. For example in the form of mixtures of compounds with the definition Q62 or Q63 or in the form of mixtures of Q58 and Q59. Therefore, according to the invention also includes combinations of active substances containing mixtures of compounds of formulas (1-1), wherein Q Y has the meanings Q62 and Q63, and Q58 and Q59 and the compounds may be present in different mixing ratios, and one or more active compounds from the group ( II). While mixing ratios of from compounds of formula (I) wherein the radical Q Y is Q62 or Q58 are preferred to compounds of formula (I) wherein the radical Qy represents Q63 or Q59, from 60:40 to 99: 1, more preferably from 70:30 to 97: 3, most preferably from 80:20 to 95: 5. Especially preferred are the following mixing ratios of a compound of formula (I) wherein QY is Q62 or Q58 to the compound of formula (I) wherein Q Y is Q63 or Q59: 80:20; 81: 19; 82: 18; 83: 17; 84: 16; 85: 15, 86: 14; 87: 13; 88: 12; 89: 11; 90: 10, 91: 9; 92: 8; 93: 7; 96: 6; 95; 5th
Weiterhin bevorzugt sind Wirkstoffkombinationen enthaltend mindestens einen Wirkstoff der allgemeinen Formel (I) oder (1-1) und einen Wirkstoff der Gruppe (II) ausgewählt aus Further preferred are combinations of active ingredients containing at least one active substance of the general formula (I) or (1-1) and an active compound of the group (II) selected from
Bitertanol bitertanol
Bixafen  bixafen
Carpropamid  carpropamid
Fenamidone  fenamidone
Fluopicolide  fluopicolide
Fluopyram  fluopyram
Fluoxastrobin  fluoxastrobin
Fluquinconazol  fluquinconazole
Isotianil  isotianil
Metominostrobin  metominostrobin
Pencycuron  pencycuron
Penflufen  penflufen
Prochloraz  prochloraz
Propamocarb  propamocarb
Propineb  propineb
Prothioconazol  prothioconazole
Spiroxamine  spiroxamine
Tebuconazol  tebuconazole
Triadimenol  triadimenol
Triazoxide  triazoxide
Trifloxystrobin Ametoctradintrifloxystrobin ametoctradin
Azoxystrobinazoxystrobin
Benthiavalicarbbenthiavalicarb
Boscalidboscalid
Carbendazimcarbendazim
Carboxincarboxin
Chlorothalonilchlorothalonil
Cymoxanilcymoxanil
Cyproconazolcyproconazole
Cyprodinilcyprodinil
CyzofamidCyzofamid
DifenoconazoleDifenoconazole
Dimoxystrobindimoxystrobin
Epoxiconazolepoxiconazole
Fenpropidinfenpropidin
FerimzoneFerimzone
Fluazinamfluazinam
Fludioxonilfludioxonil
Flutolanilflutolanil
Flutriafolflutriafol
Fluxapyroxadfluxapyroxad
Gentamycingentamicin
Hymexazolhymexazol
Imazalilimazalil
Ipconazolipconazole
Isoprothiolaneisoprothiolane
Isopyrazam asugamycinIsopyrazam asugamycin
Mancozebmancozeb
Mandipropamidmandipropamid
Manebmaneb
Mefenoxammefenoxam
Metalaxylmetalaxyl
Metconazolemetconazole
Metrafenonemetrafenone
Orysastrobinorysastrobin
Penthiopyradpenthiopyrad
Picoxystrobinpicoxystrobin
ProbenazoleProbenazole
Propiconazolepropiconazole
Proquinazidproquinazid
Pyraclostrobinpyraclostrobin
Pyrimethanilpyrimethanil
Pyroquilonpyroquilon
Quinoxyfenquinoxyfen
Sedaxanesedaxane
Tetraconazole Thiophanate-methyl tetraconazole Thiophanate-methyl
Thiram  thiram
Tolclofos-methyl  Tolclofos-methyl
Tricyclazole  Tricyclazole
Triticonazol  triticonazole
Validamycin  validamycin
F o s etyl -Aluminium  F o s etyl -aluminum
Weiterhin besonders bevorzugt sind Wirkstoffkombinationen enthaltend mindestens einen Wirkstoff der allgemeinen Formel (I) oder (I-l) und einen Wirkstoff der Gruppe (II) ausgewählt aus Also particularly preferred are combinations of active substances containing at least one active substance of the general formula (I) or (I-I) and an active compound of the group (II) selected from
Bitertanol bitertanol
Bixafen  bixafen
Carpropamid  carpropamid
Fenamidone  fenamidone
Fluopicolide  fluopicolide
Fluopyram  fluopyram
Fluoxastrobin  fluoxastrobin
Fluquinconazol  fluquinconazole
Isotianil  isotianil
Metominostrobin  metominostrobin
Pencycuron  pencycuron
Penflufen  penflufen
Prochloraz  prochloraz
Propamocarb  propamocarb
Propineb  propineb
Prothioconazol  prothioconazole
Spiroxamine  spiroxamine
Tebuconazol  tebuconazole
Triadimenol  triadimenol
Triazoxide  triazoxide
Trifloxystrobin  trifloxystrobin
Fludioxonil  fludioxonil
Ipconazol  ipconazole
Imazalil  imazalil
Mancozeb  mancozeb
Metalaxyl  metalaxyl
Mefenoxam  mefenoxam
Sedaxane  sedaxane
Azoxystrobin  azoxystrobin
Orysastrobin  orysastrobin
Carbendazim  carbendazim
Boscalid  boscalid
Flutolanil  flutolanil
Fluxapyroxad F o s etyl -Aluminium fluxapyroxad Fos etyl-aluminum
Ganz besonders bevorzugt sind Wirkstoffkombinationen enthaltend genau einen Wirkstoff der Fontiel (I-l -l) bis (1-1-60) und einen oder mehrere Wirkstoffe der Gruppe (II). Very particular preference is given to active ingredient combinations containing exactly one active ingredient of Fontiel (I-1-l) to (1-1-60) and one or more active substances of group (II).
Weiterhin ganz besonders bevorzugt sind Wirkstoffkombinationen enthaltend die im folgenden angegebenen Mischungen aus Wirkstoffen der Formel (I-l-l) bis (1-1-60) und einen oder mehrere Wirkstoffe der Gruppe (II). Furthermore, very particular preference is given to active ingredient combinations comprising the mixtures of active compounds of the formula (I-I-1) to (I-1-60) given below and one or more active compounds of the group (II).
Diese Mischungen liegen bevorzugt in einem Mischungsverhältnis von 80:20 bis 99: 1 vor. Beiespielhaft erwähnt sei die Mischung I-l -1/1-1-7, wobei die Verbindung der Formel I-l-l zur Verbindung der Formel 1-1-7 in einem Mischungs Verhältnis von 80:20 bis 99: 1 vorliegt. Ebenfalls beispielhaft erwähnt sie die Mischung 1-1-2/ 1-1-8 wobei die Verbindung der Formel 1-1-2 zur Verbindung der Formel 1-1-8 in einem Mischungsverhältnis von 80:20 bis 99: 1 vorliegt. -1-1-/1-1-7, These mixtures are preferably present in a mixing ratio of 80:20 to 99: 1. Be¬ playfully mentioned is the mixture Il -1 / 1-1-7, wherein the compound of formula III to the compound of formula 1-1-7 in a mixing ratio of 80:20 to 99: 1 is present. Also by way of example, it mentions the mixture 1-1-2 / 1-1-8 wherein the compound of the formula 1-1-2 to the compound of the formula 1-1-8 in a mixing ratio of 80:20 to 99: 1 is present. -1-1- / 1-1-7,
-1-2/ 1-1-8,  -1-2 / 1-1-8,
-1-3/1-1-9,  -1-3 / 1-1-9,
_1_4/1_1_10,  _1_4 / 1_1_10,
1-5/1-1-11,  1-5 / 1-1-11,
1-6/1-1-12,  1-6 / 1-1-12,
-1-13/1-1-1-19,  -1-13 / 1-1-1-19,
1-14/1-1-20,  1-14 / 1-1-20,
I-1-15/I-1-21, I-1-15 / I-1-21,
1-16/1-1-22,  1-16 / 1-1-22,
1-17/1-1-23,  1-17 / 1-1-23,
-1-18/1-1-24,  -1-18 / 1-1-24,
1-25/1-1-31,  1-25 / 1-1-31,
1-1-26/1-1-32, 1-1-26 / 1-1-32,
-1-27/ 1-1-33,  -1-27 / 1-1-33,
1-28/1-1-34,  1-28 / 1-1-34,
-1-29/1-1-35,  -1-29 / 1-1-35,
1-30/1-1-36,  1-30 / 1-1-36,
1-1-37/1-1-43, 1-1-37 / 1-1-43,
-1-38/1-1-44,  -1-38 / 1-1-44,
-1-39/1-1-45,  -1-39 / 1-1-45,
-1-40/1-1-46, I_l_41/I_l_47, 1-1 -42/1-1 -48, I-1-49/I-1-55, 1-1 -50/1-1 -56, I-1-51/I-1-57, 1-1 -52/1-1 -58, I-1-53/I-1-59, 1-1 -54/1-1 -60. -1-40 / 1-1-46, I_l_41 / I_l_47, 1-1 -42 / 1-1 -48, I-1-49 / I-1-55, 1-1 -50 / 1-1 -56, I-1-51 / I-1 57, 1-1 -52 / 1-1-58, I-1-53 / I-1-59, 1-1 -54 / 1-1 -60.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-1) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-1) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-2) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-2) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-3) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-3) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-4) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-4) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-5) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-5) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-6) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-6) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-7) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-7) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-8) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-8) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-9) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-9) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-10) und genau einen Particularly preferred are combinations containing the active ingredient (1-1-10) and exactly one
Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (I-l-l l) und genau einen Particularly preferred are combinations containing the active ingredient (I-l-l l) and exactly one
Wirkstoff der Gruppe II in Tabelle 1 angegebenen Mischungsverhältnissen. Active substance of group II in Table 1 mixing ratios.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-12) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-13 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particularly preferred are combinations containing the active ingredient (1-1-12) and exactly one Active compound of group II in the mixing ratios indicated in Table 1. Particularly preferred are combinations containing the active ingredient (1-1-13 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-14 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-14 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-15 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-15 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-16 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active substance (1-1-16 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-17 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-17 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-18 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-18 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-19 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-19 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-20 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-20 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-21 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-21 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-22 und genau einen Wirkstoff der Gruppe II in Tabelle 1 ange; ^ebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active substance (1-1-22 and exactly one active compound of group II in Table 1), uniform mixing ratios,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-23 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-23 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-24 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-24 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-25 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-25 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-26 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-26 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-27 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-27 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-28 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-28 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-29 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-29 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-30 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-31 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Especially preferred are combinations containing the active ingredient (1-1-30 and exactly one Active compound of group II in the mixing ratios indicated in Table 1. Particularly preferred are combinations containing the active ingredient (1-1-31 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-32 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-32 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-33 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-33 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-34 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-34 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-35 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-35 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-36 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active substance (1-1-36 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-37 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-37 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-38 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations comprising the active ingredient (1-1-38 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-39 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-39 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-40 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-40 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-41 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-41 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-42 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-42 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-43 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-43 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-44 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-44 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-45 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-45 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-46 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-46 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-47 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen, Particular preference is given to combinations containing the active ingredient (1-1-47 and exactly one active compound of group II in the mixing ratios indicated in Table 1,
Insbesondere bevorzugt sind Kombinati onen enthaltend den Wirkstoff (1-1-48 und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Especially preferred are combinations containing the active ingredient (1-1-48 and exactly one Active substance of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-49) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particularly preferred are combinations containing the active ingredient (1-1-49) and exactly one active ingredient of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-50) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-50) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-51) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-51) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-52) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-52) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-53) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Especially preferred are combinations containing the active ingredient (1-1-53) and exactly one active ingredient of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-54) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-54) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-55) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-55) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-56) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Especially preferred are combinations containing the active ingredient (1-1-56) and exactly one active ingredient of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-57) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particularly preferred are combinations containing the active ingredient (1-1-57) and exactly one active ingredient of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-58) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-58) and exactly one active ingredient of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-59) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particularly preferred are combinations containing the active ingredient (1-1-59) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Insbesondere bevorzugt sind Kombinationen enthaltend den Wirkstoff (1-1-60) und genau einen Wirkstoff der Gruppe II in den in Tabelle 1 angegebenen Mischungsverhältnissen. Particular preference is given to combinations comprising the active ingredient (1-1-60) and exactly one active compound of group II in the mixing ratios indicated in Table 1.
Die Wirkstoffkombinationen können darüber hinaus auch weitere fungizid, akarizid oder insektizid wirksame Zumischkomponenten enthalten. The active ingredient combinations may also contain other fungicidal, acaricidal or insecticidal Zumischkomponenten beyond.
Wenn die Wirkstoffe in den erfindungsgemäßen Wirkstoffkombinationen in bestimmten Gewichtsverhältnissen vorhanden sind, zeigt sich die verbesserte Wirkung. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in einem relativ großen Bereich variiert werden. Im allgemeinen enthalten die erfindungsgemäßen Kombinationen Wirkstoffe der Formel (I) zum Mischpartner der Gruppe (II) im Verhältnis von 625: 1 bis 1 : 625; bevorzugt in den in der nachfolgenden Tabelle 1 angegeben bevorzugten und besonders bevorzugten Mischungsverhältnissen: • die Mischungsverhältnisse basieren auf Gewichtsverhältnissen. Das Verhältnis ist zu verstehen als Wirkstoff der Formel (I):Mischpartner bis Formel (I):Mischpartner If the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the improved effect is shown. However, the weight ratios of the active ingredients in the drug combinations can be varied within a relatively wide range. In general, the combinations according to the invention contain active compounds of the formula (I) to the mixing partner of the group (II) in the ratio of 625: 1 to 1: 625; preferably in the preferred and particularly preferred mixing ratios given in Table 1 below: • the mixing ratios are based on weight ratios. The ratio is to be understood as the active ingredient of the formula (I): Mixture partner to formula (I): Mischpartner
Tabelle 1: Table 1:
Mischpartner bevorzugtes besonders ganz besonders Mischpartner preferred especially very special
Mischungsverhältnis bevorzugtes bevorzugtes  Mixing ratio preferred preferred
MiMi s chungs verhältni schungsverhältnis s  Mixture ratio s
Bitertanol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25 Bitertanol 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Bixafen 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Bixafen 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Carpropamid 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Carpropamide 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fenamidone 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fenamidone 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
F o s etyl -Aluminium 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fosetyl-aluminum 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fluopicolide 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fluopicolide 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fluopyram 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fluopyram 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fluoxastrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fluoxastrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fluquinconazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fluquinconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Isotianil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Isotianil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Metominostrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Metominostrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Pencycuron 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Pencycuron 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Penflufen 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Penflow 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Prochloraz 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Prochloraz 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Propamocarb 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Propamocarb 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Propineb 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Propynb 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Prothioconazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Prothioconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Spiroxamine 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Spiroxamine 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Tebuconazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Tebuconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Triadimenol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Triadimenol 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Triazoxide 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Triazoxide 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Trifloxystrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Trifloxystrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Ametoctradin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Ametoctradine 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Azoxystrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Azoxystrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Benthiavalicarb 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Benthiavalicarb 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Boscalid 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Boscalid 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Carbendazim 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Carbendazim 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Carboxin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25 Mischpartner bevorzugtes besonders ganz besonders Carboxin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25 Mischpartner preferred especially very special
Mischungsverhältnis bevorzugtes bevorzugtes  Mixing ratio preferred preferred
MiMi s chungs verhältni schungsverhältnis s  Mixture ratio s
Chlorothalonil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25 Chlorothalonil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Cymoxanil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Cymoxanil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Cyproconazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Cyproconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Cyprodinil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Cyprodinil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Cyazofamid 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Cyazofamide 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Difenoconazole 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Difenoconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Dimoxystrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Dimoxystrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Epoxiconazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Epoxiconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fenpropidin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fenpropidin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Ferimzone 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Ferimzone 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fluazinam 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fluazinam 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fludioxonil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fludioxonil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Flutolanil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Flutolanil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Flutriafol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Flutriafol 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Fluxapyroxad 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Fluxapyroxad 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Gentamycin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Gentamycin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Hymexazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Hymexazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Imazalil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Imazalil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Ipconazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Ipconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Isoprothiolane 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Isoprothiolane 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Isopyrazam 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Isopyrazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Kasugamycin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Kasugamycin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Mancozeb 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Mancozeb 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Mandipropamid 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Mandipropamide 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Maneb 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Maneb 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Mefenoxam 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Mefenoxam 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Metalaxyl 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Metalaxyl 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Metconazole 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Metconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Metrafenone 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Metrafenone 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Orysastrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Orysastrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Penthiopyrad 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Penthiopyrad 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Picoxystrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25Picoxystrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Probenazole 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25 Mischpartner bevorzugtes besonders ganz besonders Sample azoles 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25 Mischpartner preferred especially very special
Mischungsverhältnis bevorzugtes bevorzugtes  Mixing ratio preferred preferred
MiMi s chungs verhältni schungsverhältnis s  Mixture ratio s
Propiconazole 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Propiconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Proquinazid 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Proquinazide 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Pyraclostrobin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Pyraclostrobin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Pyrimethanil 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Pyrimethanil 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Pyroquilon 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Pyroquilone 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Quinoxyfen 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Quinoxyfen 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Sedaxane 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Sedaxane 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Tetraconazole 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Tetraconazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Thiophanate-methyl 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Thiophanate-methyl 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Thiram 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Thiram 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Tolclofos-methyl 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Tolclofos-methyl 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Tricyclazole 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Tricyclazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Triticonazol 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Triticonazole 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Validamycin 625 : 1 bis 1 : 625 125 : 1 bis 1 : 125 25 : 1 bis 1 : 25  Validamycin 625: 1 to 1: 625 125: 1 to 1: 125 25: 1 to 1:25
Beim Einsatz der erfindungsgemäßen Wirkstoffkombinationen als Fungizide, Insektizide oder Akarizide können die Aufwandmengen je nach Applikationsart innerhalb eines größeren Bereiches variiert werden. Die Aufwandmenge der erfindungsgemäßen Wirkstoffkombinationen beträgt bei der Behandlung von Pflanzenteilen, z.B. Blättern von 0,1 bis 1000 g/ha, bevorzugt von 10 bis 500 g/ha, besonders bevorzugt von 50 bis 300 g/ha (bei Anwendung durch Gießen oder Tropfen kann die Aufwandmenge sogar verringert werden, vor allem wenn inerte Substrate wie Steinwolle oder Perlit verwendet werden); bei der Saatgutbehandlung von 1 bis 2000 g pro 100 kg Saatgut, bevorzugt von 2 bis 1000 g pro 100 kg Saatgut, besonders bevorzugt von 3 bis 750 g pro 100 kg Saatgut, ganz besonders bevorzugt von 5 bis 500 g pro 100 kg Saatgut; bei der Bodenbehandlung von 0,1 bis 5000 g/ha, bevorzugt von 1 bis 1000 g/ha. When using the active compound combinations according to the invention as fungicides, insecticides or acaricides, the application rates can be varied within a relatively wide range, depending on the mode of administration. The application rate of the active compound combinations according to the invention is in the treatment of parts of plants, e.g. Leaves from 0.1 to 1000 g / ha, preferably from 10 to 500 g / ha, more preferably from 50 to 300 g / ha (when applied by pouring or drop, the application rate can even be reduced, especially if inert substrates such as rock wool or perlite are used); in the seed treatment from 1 to 2000 g per 100 kg of seed, preferably from 2 to 1000 g per 100 kg of seed, more preferably from 3 to 750 g per 100 kg of seed, most preferably from 5 to 500 g per 100 kg of seed; in the soil treatment from 0.1 to 5000 g / ha, preferably from 1 to 1000 g / ha.
Diese Aufwandmengen seien nur beispielhaft und nicht limitierend im Sinne der Erfindung genannt. These application rates are given by way of example only and not by way of limitation within the meaning of the invention.
Die erfindungsgemäßen Wirkstoffkombinationen können eingesetzt werden, um Pflanzen innerhalb eines gewissen Zeitraumes nach der Behandlung gegen den Befall durch phytopathogene Pilze und/oder tierische Schädlinge zu schützen. Der Zeitraum, innerhalb dessen Schutz herbeigeführt wird, erstreckt sich im Allgemeinen auf 1 bis 28 Tage, bevorzugt auf 1 bis 14 Tage, besonders bevorzugt auf 1 bis 10 Tage, ganz besonders bevorzugt auf 1 bis 7 Tage nach der Behandlung der Pflanzen mit den Wirk- stoffen bzw. auf bis zu 200 Tage nach einer Saatgutbehandlung. The active compound combinations according to the invention can be used to protect plants within a certain period of time after the treatment against attack by phytopathogenic fungi and / or animal pests. The period of time within which protection is afforded generally ranges from 1 to 28 days, preferably from 1 to 14 days, more preferably from 1 to 10 days, most preferably from 1 to 7 days after treatment of the plants with the active - up to 200 days after seed treatment.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich bei guter Pflanzenverträglichkeit, günstiger Warmblütertoxizität und guter Umweltverträglichkeit zum Schutz von Pflanzen und Pflanzenorganen, zur Steigerung der Ernteerträge, Verbesserung der Qualität des Erntegutes und zur Be- kämpfung von phytopathogenen Pilzen wie Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes usw. und von tierischen Schädlingen, insbesondere Insekten, Spinnentieren, Helminthen, Nematoden und Mollusken, die in der Landwirtschaft, im Gartenbau, bei der Tierzucht, in Forsten, in Gärten und Freizeiteinrichtungen, im Vorrats- und Materialschutz sowie auf dem Hygienesektor vorkommen. Sie können vorzugsweise als Pflanzenschutz - mittel eingesetzt werden. Sie sind gegen normal sensible und resistente Arten sowie gegen alle oder einzelne Entwicklungsstadien wirksam. The active compound combinations according to the invention are suitable for plant tolerance, favorable warm-blooded toxicity and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling phytopathogenic fungi such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc. and of animal pests, in particular insects, arachnids, helminths, nematodes and mollusks, used in agriculture, horticulture, livestock, forestry, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector occurrence. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
Die erfindungsgemäßen Wirkstoffkombinationen besitzen sehr gute fungizide Eigenschaften und lassen sich zur Bekämpfung von phytopathogenen Pilzen, wie Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes usw. einsetzen. Die erfindungsgemäßen Wirkstoffkombinationen eignen sich besonders gut zur Bekämpfung Phytophthora infestans, Plasmopara viticola und Botrytis cinerea. The active compound combinations according to the invention have very good fungicidal properties and can be used for controlling phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc. The active compound combinations according to the invention are particularly suitable for controlling Phytophthora infestans, Plasmopara viticola and Botrytis cinerea.
Beispielhaft, aber nicht begrenzend, seien einige Erreger von pilzlichen und bakteriellen Erkrankungen, die unter die oben aufgezählten Oberbegriffe fallen, genannt: By way of example, but not by way of limitation, some pathogens of fungal and bacterial diseases, which fall under the abovementioned generic terms, are mentioned:
Fungizide lassen sich im Pflanzenschutz zur Bekämpfung von Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes und Deuteromycetes einsetzen. Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
Bakterizide lassen sich im Pflanzenschutz zur Bekämpfung von Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae und Streptomycetaceae einsetzen. Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
Beispielhaft aber nicht begrenzend seien einige Erreger von pilzlichen und bakteriellen Erkrankungen, die unter die oben aufgezählten Oberbegriffe fallen, genannt: Erkrankungen, hervorgerufen durch Erreger des Echten Mehltaus wie z.B. By way of example but not limitation, some pathogens of fungal and bacterial diseases, which fall under the generic names enumerated above, are named: Diseases caused by powdery mildews such as e.g.
Blumeria- Arten, wie beispielsweise Blumeria graminis; Blumeria species such as Blumeria graminis;
Podosphaera-Arten, wie beispielsweise Podosphaera leucotricha; Podosphaera species, such as Podosphaera leucotricha;
Sphaerotheca-Arten, wie beispielsweise Sphaerotheca fuliginea; Sphaerotheca species, such as Sphaerotheca fuliginea;
Uncinula-Arten, wie beispielsweise Uncinula necator; Uncinula species, such as Uncinula necator;
Erkrankungen, hervorgerufen durch Erreger von Rostkrankheiten wie z.B. Diseases caused by causative agents of rust diseases, such as
Gymnosporangium-Arten, wie beispielsweise Gymnosporangium sabinae Hemileia-Arten, wie beispielsweise Hemileia vastatrix; Gymnosporangium species, such as Gymnosporangium sabinae Hemileia species, such as Hemileia vastatrix;
Phakopsora-Arten, wie beispielsweise Phakopsora pachyrhizi und Phakopsora meibomiae; Puccinia-Arten, wie beispielsweise Puccinia recondita;  Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species, such as Puccinia recondita;
Uromyces-Arten, wie beispielsweise Uromyces appendiculatus; Uromyces species, such as Uromyces appendiculatus;
Erkrankungen, hervorgerufen durch Erreger der Gruppe der Oomyceten wie z.B. Diseases caused by pathogens of the group of Oomycetes, e.g.
Bremia-Arten, wie beispielsweise Bremia lactucae; Bremia species, such as Bremia lactucae;
Peronospora-Arten, wie beispielsweise Peronospora pisi oder P. brassicae;  Peronospora species such as Peronospora pisi or P. brassicae;
Phytophthora-Arten, wie beispielsweise Phytophthora infestans; Phytophthora species, such as Phytophthora infestans;
Plasmopara-Arten, wie beispielsweise Plasmopara viticola; Plasmopara species, such as Plasmopara viticola;
Pseudoperonospora-Arten, wie beispielsweise Pseudoperonospora humuli oder Pseudoperonospora species, such as Pseudoperonospora humuli or
Pseudoperonospora cubensis; Pseudoperonospora cubensis;
Pythium-Arten, wie beispielsweise Pythium ultimum;  Pythium species such as Pythium ultimum;
Blattfleckenkrankheiten und Blattwelken, hervorgerufen durch z.B.  Leaf spot diseases and leaf wilt caused by e.g.
Alternaria-Arten, wie beispielsweise Alternaria solani;  Alternaria species, such as Alternaria solani;
Cercospora-Arten, wie beispielsweise Cercospora beticola; Cercospora species, such as Cercospora beticola;
Cladiosporum-Arten, wie beispielsweise Cladiosporium cucumerinum;  Cladiosporum species, such as Cladiosporium cucumerinum;
Cochliobolus-Arten, wie beispielsweise Cochliobolus sativus  Cochliobolus species, such as Cochliobolus sativus
(Konidienform: Drechslera, Syn: Helminthosporium);  (Conidia form: Drechslera, Syn: Helminthosporium);
Colletotrichum-Arten, wie beispielsweise Colletotrichum lindemuthanium;  Colletotrichum species, such as Colletotrichum lindemuthanium;
Cycloconium-Arten, wie beispielsweise Cycloconium oleaginum; Cycloconium species such as cycloconium oleaginum;
Diaporthe -Arten, wie beispielsweise Diaporthe citri;  Diaporthe types, such as Diaporthe citri;
Elsinoe-Arten, wie beispielsweise Elsinoe fawcettii;  Elsinoe species, such as Elsinoe fawcettii;
Gloeosporium-Arten, wie beispielsweise Gloeosporium laeticolor;  Gloeosporium species, such as, for example, Gloeosporium laeticolor;
Glomerella-Arten, wie beispielsweise Glomerella cingulata;  Glomerella species, such as Glomerella cingulata;
Guignardia-Arten, wie beispielsweise Guignardia bidwelli; Guignardia species, such as Guignardia bidwelli;
Leptosphaeria-Arten, wie beispielsweise Leptosphaeria maculans;  Leptosphaeria species, such as Leptosphaeria maculans;
Magnaporthe-Arten, wie beispielsweise Magnaporthe grisea;  Magnaporthe species, such as Magnaporthe grisea;
Mycosphaerella-Arten, wie beispielsweise Mycosphaerelle graminicola;  Mycosphaerella species, such as Mycosphaerelle graminicola;
Phaeosphaeria-Arten, wie beispielsweise Phaeosphaeria nodorum;  Phaeosphaeria species, such as Phaeosphaeria nodorum;
Pyrenophora-Arten, wie beispielsweise Pyrenophora teres; Pyrenophora species, such as, for example, Pyrenophora teres;
Ramularia-Arten, wie beispielsweise Ramularia collo-cygni;  Ramularia species, such as Ramularia collo-cygni;
Rhynchosporium-Arten, wie beispielsweise Rhynchosporium secalis;  Rhynchosporium species, such as Rhynchosporium secalis;
Septoria-Arten, wie beispielsweise Septoria apii;  Septoria species, such as Septoria apii;
Typhula-Arten, wie beispielsweise Typhula incarnata;  Typhula species, such as Typhula incarnata;
Venturia-Arten, wie beispielsweise Venturia inaequalis; Venturia species, such as Venturia inaequalis;
Wurzel- und Stengelkrankheiten, hervorgerufen durch z.B. Corticium-Arten, wie beispielsweise Corticium graminearum; Root and stem diseases, caused by eg Corticium species, such as Corticium graminearum;
Fusarium-Arten, wie beispielsweise Fusarium oxysporum;  Fusarium species such as Fusarium oxysporum;
Gaeumannomyces-Arten, wie beispielsweise Gaeumannomyces graminis;  Gaeumannomyces species such as Gaeumannomyces graminis;
Rhizoctonia-Arten, wie beispielsweise Rhizoctonia solani;  Rhizoctonia species, such as Rhizoctonia solani;
Tapesia-Arten, wie beispielsweise Tapesia acuformis; Tapesia species, such as Tapesia acuformis;
Thielaviopsis-Arten, wie beispielsweise Thielaviopsis basicola;  Thielaviopsis species, such as Thielaviopsis basicola;
Ähren- und Rispen erkrankungen (inklusive Maiskolben), hervorgerufen durch z.B.  Ear and panicle diseases (including corncob) caused by e.g.
Alternaria-Arten, wie beispielsweise Alternaria spp.;  Alternaria species, such as Alternaria spp .;
Aspergillus-Arten, wie beispielsweise Aspergillus flavus;  Aspergillus species, such as Aspergillus flavus;
Cladosporium- Arten, wie beispielsweise Cladosporium spp.; Cladosporium species such as Cladosporium spp .;
Claviceps-Arten, wie beispielsweise Claviceps purpurea;  Claviceps species, such as Claviceps purpurea;
Fusarium-Arten, wie beispielsweise Fusarium culmorum;  Fusarium species such as Fusarium culmorum;
Gibberella-Arten, wie beispielsweise Gibberella zeae;  Gibberella species, such as Gibberella zeae;
Monographella-Arten, wie beispielsweise Monographella nivalis;  Monographella species, such as Monographella nivalis;
Erkrankungen, hervorgerufen durch Brandpilze wie z.B. Diseases caused by fire fungi, e.g.
Sphacelotheca-Arten, wie beispielsweise Sphacelotheca reiliana;  Sphacelotheca species, such as Sphacelotheca reiliana;
Tilletia-Arten, wie beispielsweise Tilletia caries;  Tilletia species, such as Tilletia caries;
Urocystis-Arten, wie beispielsweise Urocystis occulta;  Urocystis species, such as Urocystis occulta;
Ustilago-Arten, wie beispielsweise Ustilago nuda;  Ustilago species such as Ustilago nuda;
Fruchtfäule hervorgerufen durch z.B. Fruit rot caused by e.g.
Aspergillus-Arten, wie beispielsweise Aspergillus flavus;  Aspergillus species, such as Aspergillus flavus;
Botrytis-Arten, wie beispielsweise Botrytis cinerea;  Botrytis species, such as Botrytis cinerea;
Penicillium-Arten, wie beispielsweise Penicillium expansum;  Penicillium species such as Penicillium expansum;
Sclerotinia-Arten, wie beispielsweise Sclerotinia sclerotiorum;  Sclerotinia species, such as Sclerotinia sclerotiorum;
Verticilium-Arten, wie beispielsweise Verticilium alboatrum; Verticilium species such as Verticilium alboatrum;
Samen- und bodenbürtige Fäulen und Welken, sowie Sämlingserkrankungen, hervorgerufen durch z.B. Seed and soil rots and wilts, as well as seedling diseases caused by e.g.
Fusarium-Arten, wie beispielsweise Fusarium culmorum; Fusarium species such as Fusarium culmorum;
Phytophthora Arten, wie beispielsweise Phytophthora cactorum;  Phytophthora species, such as Phytophthora cactorum;
Pythium-Arten, wie beispielsweise Pythium ultimum;  Pythium species such as Pythium ultimum;
Rhizoctonia-Arten, wie beispielsweise Rhizoctonia solani; Rhizoctonia species, such as Rhizoctonia solani;
Sclerotium-Arten, wie beispielsweise Sclerotium rolfsii;  Sclerotium species, such as Sclerotium rolfsii;
Krebserkrankungen, Gallen und Hexenbesen, hervorgerufen durch z.B.  Cancers, galls and witches brooms caused by e.g.
Nectria-Arten, wie beispielsweise Nectria galligena;  Nectria species, such as Nectria galligena;
Welkeerkrankungen hervorgerufen durch z.B.  Wilt diseases caused by e.g.
Monilinia-Arten, wie beispielsweise Monilinia laxa; Monilinia species, such as Monilinia laxa;
Deformationen von Blättern, Blüten und Früchten, hervorgerufen durch z.B. Taphrina-Arten, wie beispielsweise Taphrina deformans; Deformations of leaves, flowers and fruits, caused by eg Taphrina species, such as Taphrina deformans;
Degenerationserkrankungen holziger pflanzen, hervorgerufen durch z.B. Degenerative diseases of woody plants, caused by e.g.
Esca-Arten, wie beispielsweise Phaemoniella clamydospora; Esca species, such as Phaemoniella clamydospora;
Blüten- und Samenerkrankungen, hervorgerufen durch z.B. Flower and seed diseases caused by e.g.
Botrytis-Arten, wie beispielsweise Botrytis cinerea; Botrytis species, such as Botrytis cinerea;
Erkrankungen von Pflanzenknollen, hervorgerufen durch z.B.  Diseases of plant tubers caused by e.g.
Rhizoctonia-Arten, wie beispielsweise Rhizoctonia solani; Rhizoctonia species, such as Rhizoctonia solani;
Erkrankungen, hervorgerufen durch bakterielle Erreger wie z.B. Diseases caused by bacterial agents such as e.g.
Xanthomonas-Arten, wie beispielsweise Xanthomonas campestris pv. oryzae; Xanthomonas species, such as Xanthomonas campestris pv. Oryzae;
Pseudomonas-Arten, wie beispielsweise Pseudomonas syringae pv. lachrymans; Pseudomonas species, such as Pseudomonas syringae pv. Lachrymans;
Erwinia-Arten, wie beispielsweise Erwinia amylovora; Erwinia species, such as Erwinia amylovora;
Bevorzugt können die folgenden Krankheiten von Soja-Bohnen bekämpft werden: Pilzkrankheiten an Blättern, Stängeln, Schoten und Samen verursacht durch z.B.  Preferably, the following diseases of soybean beans can be controlled: fungal diseases on leaves, stems, pods and seeds caused by e.g.
Alternaria leaf spot (Alternaria spec. atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)), Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye Leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica Leaf Spot (Phyllosticta sojaecola), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola). Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Powdery Mildew (Phyllosticta sojaecola) Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight (Stemphylium botryosum), Target Spot (Corynespora cassiicola ).
Pilzkrankheiten an Wurzeln und der Stängelbasis verursacht durch z.B. Fungal diseases on roots and stem base caused by e.g.
Black Root Rot (Calonectria crotalariae), Charcoal Rot (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Rot, and Pod and Collar Rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Rot (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. caulivora), Phytophthora Rot (Phytophthora megasperma), Brown Stem Rot (Phialophora gregata), Pythium Rot (Pythium aphanidermatum, Pythium irreguläre, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Rot, Stem Decay, and Damping-Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Rot (Thielaviopsis basicola). Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregular, Pythium Debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).
Dabei lassen sich die erfindungsgemäßen Wirkstoffkombinationen mit besonders gutem Erfolg zur Be- kämpfung von Getreidekrankheiten, wie z.B. gegen Puccinia-Arten und von Krankheiten im Wein-, Obst- und Gemüseanbau, wie z.B. gegen Botrytis-, Venturia- oder Alternaria-Arten, einsetzen. In this case, the active compound combinations according to the invention can be used with particular success for the purpose of combating cereal diseases, such as against Puccinia species and diseases in wine, fruit and vegetable crops, such as against Botrytis, Venturia or Alternaria species use.
Darüber hinaus weisen die erfindungsgemäßen Wirkstoffkombinationen auch sehr gute antimykotische Wirkungen auf. Sie besitzen ein sehr breites antimykotisches Wirkungsspektrum, insbesondere gegen Dermatophyten und Sprosspilze, Schimmel und diphasische Pilze (z.B. gegen Candida-Spezies wie Candida albicans, Candida glabrata) sowie Epidermophyton floccosum, Aspergillus-Spezies wie Aspergillus niger und Aspergillus fumigatus, Trichophyton-Spezies wie Trichophyton mentagrophytes, Microsporon-Spezies wie Microsporon canis und audouinii. Die Aufzählung dieser Pilze stellt keinesfalls eine Beschränkung des erfassbaren mykotischen Spektrums dar, sondern hat nur erläuternden Charakter. Darüber hinaus weisen die erfindungsgemäßen Wirkstoffkombinationen auch sehr gute Insektizide Wirkungen auf. Sie besitzen ein sehr breites insektizies Wirkungsspektrum, insbesondere gegen folgende tierische Schädlinge: In addition, the active compound combinations according to the invention also have very good antifungal effects. They have a very broad antimycotic spectrum of activity, in particular against dermatophytes and yeasts, mold and diphasic fungi (eg against Candida species such as Candida albicans, Candida glabrata) and Epidermophyton floccosum, Aspergillus species such as Aspergillus niger and Aspergillus fumigatus, Trichophyton species such as Trichophyton mentagrophytes, Microsporon species such as Microsporon canis and audouinii. The list of these fungi is by no means a limitation of the detectable mycotic spectrum, but has only an explanatory character. In addition, the active compound combinations according to the invention also have very good insecticidal effects. They have a very broad insecticidal activity spectrum, in particular against the following animal pests:
Aus der Ordnung der Anoplura (Phthiraptera) z.B. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.. Aus der Klasse der Arachnida z.B. Acarus spp., Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Nuphersa spp., Oligonychus spp., Ornitho- doros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici. From the order of the Anoplura (Phthiraptera) e.g. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp .. From the class of the arachnids e.g. Acarus spp., Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri , Eutetranychus spp., Eriophyes spp., Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Nuphersa spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.
Aus der Klasse der Bivalva z.B. Dreissena spp.. From the class of bivalva, e.g. Dreissena spp ..
Aus der Ordnung der Chilopoda z.B. Geophilus spp., Scutigera spp.. Aus der Ordnung der Coleoptera z.B. Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apion spp., Apogonia spp., Atomaria spp., Attagenus spp., Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabro- tica spp., Dichocrocis spp., Diloboderus spp., Epilachna spp., Epitrix spp., Faustinus spp., Gibbium psylloides, Hellula undalis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnostema consanguinea, Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Lixus spp., Luperodes spp., Lyctus spp., Megascelis spp., Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus spp., Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllotreta spp., Popillia japonica, Premnotrypes spp., Psylliodes spp., Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Stemechus spp., Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp.. Aus der Ordnung der Collembola z.B. Onychiurus armatus. Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus. From the order of Chilopoda eg Geophilus spp., Scutigera spp. From the order of Coleoptera eg Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp. , Anthrenus spp., Apion spp., Apogonia spp., Atomaria spp., Attagenus spp., Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp. Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabotica spp., Dichocrocis spp., Diloboderus spp., Epilachna spp., Epitrix spp., Faustinus spp , Gibbium psylloides, Hellula and alis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnostema consanguinea, Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Lixus spp., Luperodes spp., Lyctus spp., Megascelis spp., Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus spp., Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllotreta spp., Popillia japonica, Premnotrypes spp. , Psylliodes spp., Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Stemechus spp., Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp. Xylotrechus spp., Zabrus spp. From the order of the Collembola eg Onychiurus armatus. From the order of Diplopoda eg Blaniulus guttulatus.
Aus der Ordnung der Diptera z.B. Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chironomus spp., Chrysomyia spp., Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dasyneura spp., Delia spp., Dermatobia hominis, Drosophila spp., Echinocnemus spp., Fannia spp., Gastrophilus spp., Hydrellia spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp.. Lucilla spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia spp., Phorbia spp., Prodiplosis spp., Psila rosae, Rhagoletis spp., Stomoxys spp., Tabanus spp., Tannia spp., Tetanops spp., Tipula spp.. Aus der Klasse der Gastropoda z.B. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.. From the order of Diptera e.g. Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chironomus spp., Chrysomyia spp., Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dasyneura spp., Delia spp., Dermatobia hominis, Drosophila spp., Echinocnemus spp., Fannia spp., Gastrophilus spp., Hydrellia spp., Hylemyia spp., Hyppobosca spp ., Hypoderma spp., Liriomyza spp. Lucilla spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia spp., Phorbia spp., Prodiplosis spp., Psila rosae, Rhagoletis spp., Stomoxys spp , Tabanus spp., Tannia spp., Tetanops spp., Tipula spp. From the class of Gastropoda, for example Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp.
Aus der Klasse der Helminthen z.B. Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp, Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp, Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti. From the class of helminths e.g. Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp, Dictyocaulus filaria, Diphyllobothrium latum , Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosome spp, Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti.
Weiterhin lassen sich Protozoen, wie Eimeria, bekämpfen. Aus der Ordnung der Heteroptera z.B. Anasa tristis, Antestiopsis spp., Blissus spp., Calocons spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Monaionion atratum, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp. Furthermore, protozoa, such as Eimeria, can be combated. From the order of Heteroptera eg Anasa tristis, Antestiopsis spp., Blissus spp., Calocons spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp , Eusystus spp., Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Monaionion atratum, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus Spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.
Aus der Ordnung der Homoptera z.B. Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Euscelis bilobatus, Ferrisia spp., Geococcus coffeae, Hieroglyphus spp., Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Meto- polophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes spp., Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp.. Aus der Ordnung der Hymenoptera z.B. Athalia spp., Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.. From the order of Homoptera e.g. Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp , Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii , Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp , Eriosoma spp., Erythroneura spp., Euscelis bilobatus, Ferrisia spp., Geococcus coffeae, Hieroglyphus spp., Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax stria Tellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp. Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata Spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes spp., Trioza spp., Typhlocyba spp., Una Spis spp., Viteus vitifolii, Zygina spp. From the order of Hymenoptera e.g. Athalia spp., Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
Aus der Ordnung der Isopoda z.B. Armadillidium vulgare, Oniscus asellus, Porcellio scaber. From the order of isopods e.g. Armadillidium vulgare, Oniscus asellus, Porcellio scaber.
Aus der Ordnung der Isoptera z.B. Acromyrmex spp., Atta spp., Cornitermes cumulans, Microtermes obesi, Odontotermes spp., Reticulitermes spp, Aus der Ordnung der Lepidoptera z.B. Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Barathra brassicae, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocerus spp., Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diatraea saccharalis, Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Etiella spp., Eulia spp., Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivoria flavofasciata, Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca testulalis, Mamestra brassicae, Mocis spp., Mythimna separata, Nymphula spp., Oiketicus spp., Oria spp., Orthaga spp., Ostrinia spp., Oulema oryzae, Panolis flammea, Parnara spp., Pectinophora spp., Perileucoptera spp., Phthorimaea spp., Phyllocnistis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp., Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scotia segetum, Sesamia spp., Sparganothis spp., Spodoptera spp., Stathmopoda spp., Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix spp., Tricho- plusia spp., Tuta absoluta, Virachola spp.. From the order of the Isoptera eg Acromyrmex spp., Atta spp., Cornitermes cumulans, Microtermes obesi, Odontotermes spp., Reticulitermes spp. From the order of Lepidoptera, for example, Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Barathra brassicae, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius , Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choristoneura spp., Clysia ambiguella, Cnaphalocerus spp., Cnephasia spp., Conopomorpha spp., Conotrachelus spp. , Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diatraea saccharalis, Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia kuehniella, Epinotia spp., Epiphyas postvittana, Etiella spp., Eulia spp. Eupoecilia ambiguella, Euproctis spp., Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homon a spp., Hyponomeuta padella, Kakivoria flavofasciata, Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca testulalis, Mamestra brassicae, Mocis spp., Mythimna separata, Nymphula spp., Oiketicus spp., Oria spp., Orthaga spp., Ostrinia spp., Oulema oryzae, Panolis flammea, Parnara spp., Pectinophora spp., Perileucoptera spp. Phthorimaea spp., Phyllocnis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp., Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scotia segetum, Sesamia spp., Sparganothis spp., Spodoptera spp., Stathmopoda spp., Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix spp. Tri cho-plusia spp., Tuta absoluta, Virachola spp.
Aus der Ordnung der Orthoptera z.B. Acheta domesticus, Blatta orientalis, Blattella germanica, Dichroplus spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria. Aus der Ordnung der Siphonaptera z.B. Ceratophyllus spp., Xenopsylla cheopis. From the order of Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Dichroplus spp., Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria. From the order of siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.
Aus der Ordnung der Symphyla z.B. Scutigerella spp.. From the order of Symphyla e.g. Scutigerella spp ..
Aus der Ordnung der Thysanoptera z.B. Anaphothrips obscurus, Baliothrips biformis, Drepanothris reuteri, Enneothrips Hävens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.. Aus der Ordnung der Thysanura z.B. Lepisma saccharina. From the order of Thysanoptera e.g. Anaphothrips obscurus, Baliothrips biformis, Drepanothris reuteri, Enneothrips hevens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp. From the order of Thysanura e.g. Lepisma saccharina.
Zu den pflanzenparasitären Nematoden gehören z.B. Aphelenchoides spp., Bursaphelenchus spp., Ditylenchus spp., Globodera spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Trichodorus spp., Tylenchulus semipenetrans, Xiphinema spp.. Im Materialschutz lassen sich die erfindungsgemäßen Wirkstoffkombinationen zum Schutz von technischen Materialien gegen Befall und Zerstörung durch unerwünschte Mikroorganismen einsetzen. The plant parasitic nematodes include, for example, Aphelenchoides spp., Bursaphelenchus spp., Ditylenchus spp., Globodera spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Trichodorus spp., Tylenchulus semipenetrans, Xiphinema spp .. In the protection of materials, the active compound combinations according to the invention can be used to protect industrial materials against infestation and destruction by undesired microorganisms.
Unter technischen Materialien sind im vorliegenden Zusammenhang nichtlebende Materialien zu verstehen, die für die Verwendung in der Technik zubereitet worden sind. Beispielsweise können technische Materialien, die durch erfindungsgemäße Wirkstoffe vor mikrobieller Veränderung oder Zerstörung geschützt werden sollen, Klebstoffe, Leime, Papier und Karton, Textilien, Leder, Holz, Anstrichmittel und Kunst- stoffartikel, Kühlschmierstoffe und andere Materialien sein, die von Mikroorganismen befallen oder zersetzt werden können. Im Rahmen der zu schützenden Materialien seien auch Teile von Produktionsanlagen, beispielsweise Kühlwasserkreisläufe, genannt, die durch Vermehrung von Mikroorganismen beeinträchtigt werden können. Im Rahmen der vorliegenden Erfindung seien als technische Materialien vorzugsweise Klebstoffe, Leime, Papiere und Kartone, Leder, Holz, Anstrichmittel, Kühlschmiermittel und Wärmeübertragungsflüssigkeiten genannt, besonders bevorzugt Holz. Technical materials as used herein mean non-living materials that have been prepared for use in the art. For example, engineering materials to be protected from microbial alteration or destruction by the active compounds of the present invention may be adhesives, glues, paper and board, textiles, leather, wood, paints and plastics, coolants, and other materials that infiltrate or decompose microorganisms can be. In the context of the materials to be protected are also parts of production plants, such as cooling water circuits, called, which can be affected by the proliferation of microorganisms. In the context of the present invention, technical materials which may be mentioned are preferably adhesives, glues, papers and cartons, leather, wood, paints, cooling lubricants and heat transfer fluids, particularly preferably wood.
Als Mikroorganismen, die einen Abbau oder eine Veränderung der technischen Materialien bewirken können, seien beispielsweise Bakterien, Pilze, Hefen, Algen und Schleimorganismen genannt. Vorzugsweise wirken die erfindungsgemäßen Wirkstoffkombinationen gegen Pilze, insbesondere Schimmelpilze, holzverfärbende und holzzerstörende Pilze (Basidiomyceten) sowie gegen Schleimorganismen und Algen. As microorganisms that can cause degradation or a change in the technical materials, for example, bacteria, fungi, yeasts, algae and mucus organisms may be mentioned. The active compound combinations according to the invention preferably act against fungi, in particular molds, wood-discolouring and wood-destroying fungi (Basidiomycetes) and against slime organisms and algae.
Es seien beispielsweise Mikroorganismen der folgenden Gattungen genannt: There may be mentioned, for example, microorganisms of the following genera:
Alternaria, wie Alternaria tenuis, Alternaria, such as Alternaria tenuis,
Aspergillus, wie Aspergillus niger,  Aspergillus, such as Aspergillus niger,
Chaetomium, wie Chaetomium globosum, Chaetomium, such as Chaetomium globosum,
Coniophora, wie Coniophora puetana,  Coniophora, like Coniophora puetana,
Lentinus, wie Lentinus tigrinus,  Lentinus, like Lentinus tigrinus,
Penicillium, wie Penicillium glaucum,  Penicillium, such as Penicillium glaucum,
Polyporus, wie Polyporus versicolor,  Polyporus, such as Polyporus versicolor,
Aureobasidium, wie Aureobasidium pullulans, Aureobasidium, such as Aureobasidium pullulans,
Sclerophoma, wie Sclerophoma pityophila,  Sclerophoma, such as Sclerophoma pityophila,
Trichoderma, wie Trichoderma viride,  Trichoderma, like Trichoderma viride,
Escherichia, wie Escherichia coli,  Escherichia, like Escherichia coli,
Pseudomonas, wie Pseudomonas aeruginosa,  Pseudomonas, such as Pseudomonas aeruginosa,
Staphylococcus, wie Staphylococcus aureus. Staphylococcus, such as Staphylococcus aureus.
Außerdem wurde gefunden, dass die erfindungsgemäßen Wirkstoffkombinationen eine hohe msektizide In addition, it has been found that the active compound combinations according to the invention have a high insecticidal activity
Wirkung gegen Insekten zeigen, die technische Materialien zerstören. Show effect against insects that destroy technical materials.
Beispielhaft und vorzugsweise - ohne jedoch zu limitieren - seien die folgenden Insekten genannt: Käfer wie Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus. By way of example and preferably without limiting however, the following insects are mentioned: Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus.
Hautflügler wie Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur. Hymenoptera such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.
Termiten wie Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus. Borstenschwänze wie Lepisma saccharina. Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus. Bristle tails like Lepisma saccharina.
Unter technischen Materialien sind im vorliegenden Zusammenhang nicht-lebende Materialien zu verstehen, wie vorzugsweise Kunststoffe, Klebstoffe, Leime, Papiere und Kartone, Leder, Holz, Holzverarbeitungsprodukte und Anstrichmittel. Technical materials in the present context are non-living materials, such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.
Ganz besonders bevorzugt handelt es sich bei dem vor Insektenbefall zu schützenden Material um Holz und Holzverarbeitungsprodukte. Most preferably, the material to be protected from insect attack is wood and woodworking products.
Unter Holz und Holzverarbeitungsprodukten, welche durch die erfindungsgemäßen Wirkstoffkombinationen geschützt werden kann, ist beispielhaft zu verstehen: Bauholz, Holzbalken, Eisenbahnschwellen, Brückenteile, Bootsstege, Holzfahrzeuge, Kisten, Paletten, Container, Telefonmasten, Holzverkleidungen, Holzfenster und -türen, Sperrholz, Spanplatten, Tischlerarbeiten oder Holzprodukte, die ganz allgemein beim Hausbau oder in der Bautischlerei Verwendung finden. By wood and wood products, which can be protected by the active compound combinations according to the invention, is to be understood by way of example: timber, wooden beams, railway sleepers, bridge parts, boat jetties, wooden vehicles, crates, pallets, containers, telephone poles, wood cladding, wooden windows and doors, plywood, chipboard, Carpentry or wood products commonly used in home construction or joinery.
Die Wirkstoffkombinationen können als solche, in Form von Konzentraten oder allgemein üblichen Formulierungen wie Pulver, Granulate, Lösungen, Suspensionen, Emulsionen oder Pasten angewendet werden. The active compound combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
Die genannten Formulierungen können in an sich bekannter Weise hergestellt werden, z.B. durch Vermischen der Wirkstoffe mit mindestens einem Lösungs- bzw. Verdünnungsmittel, Emulgator, Dispergier- und/oder Binde- oder Fixiermittels, Wasser-Repellent, gegebenenfalls Sikkative und UV-Stabilisatoren und gegebenenfalls Farbstoffen und Pigmenten sowie weiteren Verarbeitungshilfsmitteln. The formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments, and further processing aids.
Die zum Schutz von Holz und Holzwerkstoffen verwendeten Insektiziden Wirkstoffkombinationen oder Konzentrate enthalten den erfindungsgemäßen Wirkstoff in einer Konzentration von 0,0001 bis 95 Gew.-%, insbesondere 0,001 bis 60 Gew.-%. Die Menge der eingesetzten Wirkstoffkombinationen bzw. Konzentrate ist von der Art und dem Vorkommen der Insekten und von dem Medium abhängig. Die optimale Einsatzmenge kann bei der Anwendung jeweils durch Testreihen ermittelt werden. Im allgemeinen ist es jedoch ausreichend 0,0001 bis 20 Gew.-%, vorzugsweise 0,001 bis 10 Gew.-%, des Wirkstoffs, bezogen auf das zu schützende Material, einzusetzen. The insecticidal active ingredient combinations or concentrates used for the protection of wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60 wt .-%. The amount of active ingredient combinations or concentrates used depends on the nature and occurrence of the insects and on the medium. The optimal amount used can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the material to be protected.
Die Wirkstoffkombinationen eignen sich auch zur Bekämpfung von tierischen Schädlingen, insbesondere von Insekten, Spinnentieren und Milben, die in geschlossenen Räumen, wie beispielsweise Wohnungen, Fabrikhallen, Büros, Fahrzeugkabinen u.ä. vorkommen. Sie können zur Bekämpfung dieser Schädlinge in Haushaltsinsektizid-Produkten verwendet werden. Sie sind gegen sensible und resistente Arten sowie gegen alle Entwicklungsstadien wirksam. Zu diesen Schädlingen gehören: The active substance combinations are also suitable for controlling animal pests, in particular insects, arachnids and mites, which are used in enclosed spaces such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
Aus der Ordnung der Scorpionidea z.B. Buthus occitanus. From the order of Scorpionidea e.g. Buthus occitanus.
Aus der Ordnung der Acarina z.B. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae. Aus der Ordnung der Araneae z.B. Aviculariidae, Araneidae. From the order of Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae. From the order of the Araneae e.g. Aviculariidae, Araneidae.
Aus der Ordnung der Opiliones z.B. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium. From the order of Opiliones e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
Aus der Ordnung der Isopoda z.B. Oniscus asellus, Porcellio scaber. From the order of isopods e.g. Oniscus asellus, Porcellio scaber.
Aus der Ordnung der Diplopoda z.B. Blaniulus guttulatus, Polydesmus spp. Aus der Ordnung der Chilopoda z.B. Geophilus spp. From the order of diplopoda e.g. Blaniulus guttulatus, Polydesmus spp. From the order of Chilopoda e.g. Geophilus spp.
Aus der Ordnung der Zygentoma z.B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus. From the order of Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
Aus der Ordnung der Blattaria z.B. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. Aus der Ordnung der Saltatoria z.B. Acheta domesticus. From the order of the Blattaria e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa. From the order of Saltatoria e.g. Acheta domesticus.
Aus der Ordnung der Isoptera z.B. Kalotermes spp., Reticulitermes spp. From the order of Isoptera e.g. Kalotermes spp., Reticulitermes spp.
Aus der Ordnung der Psocoptera z.B. Lepinatus spp., Liposcelis spp. From the order of Psocoptera e.g. Lepinatus spp., Liposcelis spp.
Aus der Ordnung der Coleptera z.B. Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum. From the order of Coleptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
Aus der Ordnung der Diptera z.B. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa. From the order of Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.
Aus der Ordnung der Lepidoptera z.B. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella. From the order of Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
Aus der Ordnung der Siphonaptera z.B. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis. From the order of siphonaptera e.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
Aus der Ordnung der Hymenoptera z.B. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum. From the order of Hymenoptera e.g. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
Aus der Ordnung der Anoplura z.B. Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis. Aus der Ordnung der Heteroptera z.B. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans. From the order of the Anoplura e.g. Pediculus humanus capitis, Pediculus humanus corporis, Phthirus pubis. From the order of Heteroptera, e.g. Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.
Die Anwendung erfolgt in Aerosolen, drucklosen Sprühmitteln, z.B. Pump- und Zerstäub er sprays, Nebelautomaten, Foggern, Schäumen, Gelen, Verdampferprodukten mit Verdampferplättchen aus Cellulose oder Kunststoff, Flüssigverdampfern, Gel- und Membranverdampfern, propellergetriebenen Verdampfern, energielosen bzw. passiven Verdampfungssystemen, Mottenpapieren, Mottensäckchen und Mottengelen, als Granulate oder Stäube, in Streuködern oder Köderstationen. Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprayers, fog machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-less or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in straw baits or bait stations.
Die erfindungsgemäßen Wirkstoffkombinationen wirken nicht nur gegen Pflanzen-, Hygiene- und Vorratsschädlinge, sondern auch auf dem veterinärmedizinischen Sektor gegen tierische Parasiten (Ektoparasiten) wie Schildzecken, Lederzecken, Räudemilben, Laufmilben, Fliegen (stechend und leckend), parasitierende Fliegenlarven, Läuse, Haarlinge, Federlinge und Flöhe. Zu diesen Parasiten gehören: The active compound combinations of the invention not only against plant, hygiene and storage pests, but also in the veterinary sector against animal parasites (ectoparasites) such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, Featherlings and fleas. These parasites include:
Aus der Ordnung der Anoplurida z.B. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp. From the order of the Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
Aus der Ordnung der Mallophagida und den Unterordnungen Amblycerina sowie Ischnocerina z.B. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp. Aus der Ordnung Diptera und den Unterordnungen Nematocerina sowie Brachycerina z.B. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilla spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp. From the order of Mallophagida and the suborders Amblycerina and Ischnocerina eg Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp. From the order Diptera and the suborders Nematocerina and Brachycerina eg Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp. , Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Lucilla spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
Aus der Ordnung der Siphonapterida z.B. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp. Aus der Ordnung der Heteropterida z.B. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp. From the order of siphonapterida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp. From the order of the heteropterid e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
Aus der Ordnung der Blattarida z.B. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp. From the order of Blattarida e.g. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
Aus der Unterklasse der Acaria (Acarida) und den Ordnungen der Meta- sowie Mesostigmata z.B. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp. From the subclass of Acaria (Acarida) and the orders of Meta and Mesostigmata e.g. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp ., Sternostoma spp., Varroa spp.
Aus der Ordnung der Actinedida (Prostigmata) und Acaridida (Astigmata) z.B. Acarapis spp., Cheyletiella spp., Omithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp. From the order of Actinedida (Prostigmata) and Acaridida (Astigmata) e.g. Acarapis spp., Cheyletiella spp., Omithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp , Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich auch zur Bekämpfung von Arthropoden, die landwirtschaftliche Nutztiere, wie z.B. Rinder, Schafe, Ziegen, Pferde, Schweine, Esel, Kamele, Büffel, Kaninchen, Hühner, Puten, Enten, Gänse, Bienen, sonstige Haustiere wie z.B. Hunde, Katzen, Stubenvögel, Aquarienfische sowie sogenannte Versuchstiere, wie z.B. Hamster, Meerschweinchen, Ratten und Mäuse befallen. Durch die Bekämpfung dieser Arthropoden sollen Todesfälle und Leistungsminderungen (bei Fleisch, Milch, Wolle, Häuten, Eiern, Honig usw.) vermindert werden, so dass durch den Einsatz der erfindungsgemäßen Wirkstoffkombinationen eine wirtschaftlichere und einfachere Tierhaltung möglich ist. Die Anwendung der erfindungsgemäßen Wirkstoffkombinationen geschieht im Veterinärsektor in bekannter Weise durch enterale Verabreichung in Form von beispielsweise Tabletten, Kapseln, Tränken, Drenchen, Granulaten, Pasten, Boli, des feed-through- Verfahrens, von Zäpfchen, durch parenterale Verabreichung, wie zum Beispiel durch Injektionen (intramuskulär, subcutan, intravenös, intraperitonal u.a.), Implantate, durch nasale Applikation, durch dermale Anwendung in Form beispielsweise des Tauchens oder Badens (Dippen), Sprühens (Spray), Aufgießens (Pour-on und Spot-on), des Waschens, des Einpuderns sowie mit Hilfe von wirkstoffhaltigen Formkörpern, wie Halsbändern, Ohrmarken, Schwanzmarken, Gliedmaßenbändern, Halftern, Markierungsvorrichtungen usw. The active compound combinations according to the invention are also suitable for controlling arthropods, the livestock, such as cattle, sheep, goats, horses, pigs, donkeys, camels, buffalos, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs , Cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested. By controlling these arthropods deaths and reductions in performance (in meat, milk, wool, hides, eggs, honey, etc.) are reduced so that a more economical and easier animal husbandry is possible through the use of the active compound combinations according to the invention. The application of the active compound combinations according to the invention takes place in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boluses, the feed-through process, suppositories, by parenteral Administration, for example by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, dipping or bathing (dipping), spraying, pouring (pour-on and spot -on), washing, powdering and with the aid of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.
Bei der Anwendung für Vieh, Geflügel, Haustiere etc. kann man die Wirkstoffkombinationen als Formulierungen (beispielsweise Pulver, Emulsionen, fließfähige Mittel), die die Wirkstoffe in einer Menge von 1 bis 80 Gew.-% enthalten, direkt oder nach 100 bis 10 000-facher Verdünnung anwenden oder sie als chemisches Bad verwenden. Die erfindungsgemäßen Wirkstoffkombinationen können gegebenenfalls in bestimmten Konzentrationen bzw. Aufwandmengen auch als Herbizide, Safener, Wachstumsregulatoren oder Mittel zur Verbesserung der Pflanzeneigenschaften, oder als Mikrobizide, beispielsweise als Fungizide, Antimykotika, Bakterizide, Virizide (einschließlich Mittel gegen Viroide) oder als Mittel gegen MLO (Mycoplasma-like-organism) und RLO (Rickettsia-like-organism) verwendet werden. Die vorliegende Erfindung betrifft weiterhin Formulierungen und daraus bereitete Anwendungsformen als Pflanzenschutzmittel und/oder Schädlingsbekämpfungsmittel wie z. B. Drench-, Drip- und Spritzbrühen, umfassend mindestens eine der erfindungsgemäßen Wirkstoffkombinationen. Gegebenenfalls enthalten die Anwendungsformen weitere Pflanzenschutzmittel und/oder Schädlingsbekämpfungsmittel und/oder die Wirkung verbessernde Adjuvantien wie Penetrationsförderer, z. B. vegetative Öle wie beispielsweise Rapsöl, Sonnenblumenöl, Mineralöle wie beispielsweise Paraffinöle, Alkylester vegetativer Fettsäuren wie beispielsweise Rapsöl- oder Sojaölmethylester oder Alkanol-alkoxylate und/oder Spreitmittel wie beispielsweise Alkylsiloxane und/oder Salze z.B. organische oder anorganische Ammonium- oder Phosphomiumsalze wie beispielsweise Ammoniumsulfat oder Diammonium-hydrogenphosphat und /oder die Retention fördernde Mittel wie z. B. Dioctylsulfosuccinat oder Hydroxypropyl-guar Polymere und/oder Humectants wie z.B. Glycerin und / oder Dünger wie beispielsweise Ammonium-, Kalium- oder Phosphor-enthaltende Dünger. When used for livestock, poultry, pets, etc., the active ingredient combinations may be used as formulations (for example, powders, emulsions, flowables) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath. The active compound combinations according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as anti-MLO agents ( Mycoplasma-like-organism) and RLO (Rickettsia-like-organism). The present invention further relates to formulations and application forms prepared therefrom as crop protection agents and / or pesticides such. B. drench, drip and spray, comprising at least one of the active compound combinations according to the invention. If appropriate, the use forms contain other crop protection agents and / or pesticides and / or the effect of improving adjuvants such as penetration enhancers, eg. For example, vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetal fatty acids such as rapeseed oil or soybean oil methyl ester or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts, e.g. organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such. Dioctylsulfosuccinate or hydroxypropyl-guar polymers and / or humectants, e.g. Glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer.
Übliche Formulierungen sind beispielsweise wasserlösliche Flüssigkeiten (SL), Emulsionskonzentrate (EC), Emulsionen in Wasser (EW), Suspensionskonzentrate (SC, SE, FS, OD), in Wasser dispergierbare Granulate (WG), Granulate (GR) und Kapselkonzentrate (CS); diese und weitere mögliche Formuliertypen sind beispielsweise durch Crop Life International und in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO/WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576 beschrieben. Gegebenenfalls enthalten die Formulierungen neben einem oder mehreren erfindungsgemäßen Wirkstoffen weitere agrochemische Wirkstoffe. Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ; These and other possible formulation types are described, for example, by Crop Life International and in Pesticide Specifications, Manual on Development and Use of FAO and WHO Specifications for Pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. Optionally, the formulations contain in addition to one or more active substances according to the invention further agrochemical active substances.
Vorzugsweise handelt es sich um Formulierungen oder Anwendungsformen, welche Hilfsstoffe, wie beispielsweise Streckmittel, Lösemittel, Spontanitätsförderer, Trägerstoffe, Emulgiermittel, Dispergiermittel, Frostschutzmittel, Biozide, Verdicker und/oder weitere Hilfsstoffe, wie beispielsweise Adjuvantien enthalten. Ein Adjuvant in diesem Kontext ist eine Komponente, die die biologische Wirkung der Formulierung verbessert, ohne dass die Komponente selbst eine biologische Wirkung hat. Beispiele für Adjuvantien sind Mittel, die die Retention, das Spreitverhalten, das Anhaften an der Blattoberfläche oder die Penetration fördern. They are preferably formulations or use forms which contain auxiliaries, such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, antifreeze agents, biocides, thickeners and / or further auxiliaries, for example adjuvants. An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen der Wirkstoffe mit Hilfsstoffen wie beispielsweise Streckmitteln, Lösemitteln und/oder festen Trägerstoffen und/oder weiteren Hilfsstoffen wie beispielsweise oberflächenaktive Stoffe. Die Herstellung der Formulierungen erfolgt entweder in geeigneten Anlagen oder auch vor oder während der Anwendung. These formulations are prepared in a known manner, e.g. by mixing the active ingredients with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants. The preparation of the formulations is carried out either in suitable systems or before or during use.
Als Hilfsstoffe können solche Stoffe Verwendung finden, die geeignet sind, der Formulierung des Wirkstoffs oder den aus diesen Formulierungen bereiteten Anwendungsformen (wie z.B. gebrauchsfähigen Pflanzenschutzmitteln wie Spritzbrühen oder Saatgutbeizen) besondere Eigenschaften, wie bestimmte physikalische, technische und/oder biologische Eigenschaften, zu verleihen. As excipients there may be used those substances which are suitable for conferring special properties, such as certain physical, technical and / or biological properties, to the formulation of the active substance or to the forms of use prepared from these formulations (for example usable plant protection agents such as spray or seed dressing).
Als Streckmittel eignen sich z.B. Wasser, polare und unpolare organische chemische Flüssigkeiten z.B. aus den Klassen der aromatischen und nicht-aromatischen Kohlenwasserstoffe (wie Paraffine, Alkylbenzole, Alkylnaphthaline, Chlorbenzole), der Alkohole und Polyole (die ggf. auch substituiert, verethert und/oder verestert sein können), der Ketone (wie Aceton, Cyclohexanon), Ester (auch Fette und Öle) und (Poly-)Ether, der einfachen und substituierten Amine, Amide, Lactame (wie N- Alkylpyrrolidone) und Lactone, der Sulfone und Sulfoxide (wie Dimethylsulfoxid). As extender, e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide).
Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organische Lösemittel als Hilfslösemittel verwendet werden. Als flüssige Lösemittel kommen im Wesentlichen infrage: Aromaten, wie Xylol, Toluol oder Alkylnaphthaline, chlorierte Aromaten oder chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone, wie Aceton, Methyl- ethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösemittel wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser. In the case of using water as an extender, e.g. also organic solvents can be used as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
Grundsätzlich können alle geeigneten Lösemittel verwendet werden. Geeignete Lösemittel sind beispielsweise aromatische Kohlenwasserstoffe, wie z.B. Xylol, Toluol oder Alkylnaphthaline, chlorierte aromatische oder aliphatische Kohlenwasserstoffe, wie z.B. Chlorbenzol, Chlorethylen, oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie z.B. Cyclohexan, Paraffine, Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie z.B. Methanol, Ethanol, iso-Propanol, Butanol oder Glykol sowie deren Ether und Ester, Ketone wie z.B. Aceton, Methyl ethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösemittel, wie Dimethylsulfoxid, sowie Wasser. In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons, such as, for example, xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, such as chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, such as methanol, ethanol, iso-propanol, butanol or glycol and their ethers and Esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide, and water.
Grundsätzlich können alle geeigneten Trägerstoffe eingesetzt werden. Als Trägerstoffe kommen insbesondere infrage: z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und natürliche oder synthetische Silikate, Harze, Wachse und /oder feste Düngemittel. Mischungen solcher Trägerstoffe können ebenfalls verwendet werden. Als Trägerstoffe für Granulate kommen infrage: z.B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Papier, Kokosnussschalen, Maiskolben und Tabak- stängel. Auch verflüssigte gasförmige Streckmittel oder Lösemittel können eingesetzt werden. Insbesondere eignen sich solche Streckmittel oder Trägerstoffe, welche bei normaler Temperatur und unter Normaldruck gasförmig sind, z.B. Aerosol-Treibgase, wie Halogenkohlenwasserstoffe, sowie Butan, Propan, Stickstoff und Kohlendioxid. In principle, all suitable carriers can be used. Suitable carriers are, in particular: Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used. Suitable carriers for granules are: e.g. Cracked and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stalks. Also, liquefied gaseous diluents or solvents can be used. Particularly suitable are those diluents or carriers which are gaseous at normal temperature and under normal pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.
Beispiele für Emulgier- und/oder Schaum erzeugende Mittel, Dispergiermittel oder Benetzungsmittel mit ionischen oder nicht-ionischen Eigenschaften oder Mischungen dieser oberflächenaktiven Stoffe sind Salze von Polyacrylsäure, Salze von Lignosulphonsäure, Salze von Phenolsulphonsäure oder Naphthalmsulphonsäure, Polykondensate von Ethylenoxid mit Fettalkoholen oder mit Fettsäuren oder mit Fettaminen, mit substituierten Phenolen (vorzugsweise Alkylphenole oder Arylphenole), Salze von Sulphobernsteinsäureestern, Taurinderivate (vorzugsweise Alkyltaurate), Phosphorsäureester von polyethoxylierten Alkoholen oder Phenole, Fettsäureester von Polyolen, und Derivate der Verbindungen enthaltend Sulphate, Sulphonate und Phosphate, z.B. Alkylarylpolyglycolether, Alkyl- sulfonate, Alkylsulfate, Arylsulfonate, Eiweißhydrolysate, Lignin-Sulfitablaugen und Methylcellulose. Die Anwesenheit einer oberflächenaktiven Substanz ist vorteilhaft, wenn einer der Wirkstoff und/oder einer der inerten Trägerstoffe nicht in Wasser löslich ist und wenn die Anwendung in Wasser erfolgt. Als weitere Hilfsstoffe können in den Formulierungen und den daraus abgeleiteten Anwendungsformen Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferrocyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyaninfarbstoffe und Nähr- und Spurennährstoffe, wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink vorhanden sein. Weiterhin enthalten sein können Stabilisatoren wie Kältestabilisatoren, Konservierungsmittel, Oxidationsschutzmittel, Lichtschutzmittel oder andere die chemische und / oder physikalische Stabilität verbessernde Mittel. Weiterhin enthalten sein können schaumerzeugende Mittel oder Entschäumer. Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyltaurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, for example alkylarylpolyglycol ethers, alkyl- sulfonates, alkyl sulfates, arylsulfonates, protein hydrolysates, lignin-sulphite liquors and methylcellulose. The presence of a surfactant is advantageous when one of the active ingredients and / or one of the inert carriers is not soluble in water and when applied in water. As further auxiliaries, dyes such as inorganic pigments, eg iron oxide, titanium oxide, ferrocyan blue and organic dyes, such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients, such as salts of iron, manganese, boron, in the formulations and the applications derived therefrom, can be used. Copper, cobalt, molybdenum and zinc may be present. Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers.
Ferner können die Formulierungen und daraus abgeleiteten Anwendungsformen als zusätzliche Hilfsstoffe auch Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulverige, körnige oder latexförmige Polymere enthalten, wie Gummiarabikum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholipide, wie Kephaline und Lecithine, und synthetische Phospholipide. Weitere Hilfsstoffe können mineralische und vegetabile Öle sein. Further, the formulations and applications derived therefrom may also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins, and synthetic phospholipids. Other auxiliaries may be mineral and vegetable oils.
Gegebenenfalls können noch weitere Hilfsstoffe in den Formulierungen und den daraus abgeleiteten Anwendungsformen enthalten sein. Solche Zusatzstoffe sind beispielsweise Duftstoffe, schützende Kolloide, Bindemittel, Klebstoffe, Verdicker, thixotrope Stoffe, Penetrationsförderer, Retentionsförderer, Stabilisatoren, Sequestiermittel, Komplexbildner, Humectans, Spreitmittel. Im Allgemeinen können die Wirkstoffe mit jedem festen oder flüssigen Zusatzstoff, welches für Formulierungszwecke gewöhnlich verwendet wird, kombiniert werden. Als Retentionsförderer kommen alle diejenigen Substanzen in Betracht, die die dynamische Oberflächenspannung verringern wie beispielsweise Dioctylsulfosuccinat oder die die Visko-Elastizität erhöhen wie beispielsweise Hydroxypropyl-guar Polymere. Optionally, further auxiliaries may be present in the formulations and in the use forms derived therefrom. Such additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents. In general, the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes. As retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.
Als Penetrationsförderer kommen im vorliegenden Zusammenhang alle diejenigen Substanzen in Betracht, die üblicherweise eingesetzt werden, um das Eindringen agrochemischer Wirkstoffen in Pflanzen zu verbessern. Penetrationsförderer werden in diesem Zusammenhang dadurch definiert, dass sie aus der (in der Regel wässerigen) Applikationsbrühe und/oder aus dem Spritzbelag in die Kutikula der Pflanze eindringen und dadurch die Stoffbeweglichkeit (Mobilität) der Wirkstoffe in der Kutikula erhöhen können. Die in der Literatur (Baur et al., 1997, Pesticide Science 51, 131-152) beschriebene Methode kann zur Bestimmung dieser Eigenschaft eingesetzt werden. Beispielhaft werden genannt Alkoholalkoxylate wie beispielsweise Kokosfettethoxylat (10) oder Isotridecylethoxylat (12), Fettsäureester wie beispielsweise Rapsöl- oder Sojaölmethylester, Fettamine Alkoxylate wie beispielsweise Tallowamine ethoxylat (15) oder Ammonium und / oder Phosphonium-Salze wie beispielsweise Ammoniumsulfat oder Diammonium-hydrogenphosphat. Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants. Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.
Der Wirkstoffgehalt der aus den handelsüblichen Formulierungen bereiteten Anwendungsformen kann in weiten Bereichen variieren. Die Wirkstoffkonzentration der Anwendungsformen liegt im Bereich von 0,00000001 bis 97 Gew.-% Wirkstoff, vorzugsweise im Bereich von 0,0000001 bis 97 Gew.-%, besonders bevorzugt im Bereich von 0,000001 bis 83 Gew.-% oder 0,000001 bis 5 Gew.-% und ganz besonders bevorzugt im Bereich von 0,0001 bis 1 Gew.-%. Der erfindungsgemäßen Wirkstoffkombinationen können in ihren handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischung mit anderen Wirkstoffen wie Insektiziden, Lockstoffen, Sterilantien, Bakteriziden, Akariziden, Nematiziden, Fungiziden, wachstumsregulierenden Stoffen, Herbiziden, Safenern, Düngemitteln oder Semiochemicals vorliegen. Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Herbiziden, Düngemitteln, Wachstumsregulatoren, Safenern, Semiochemicals, oder auch mit Mitteln zur Verbesserung der Pflanzeneigenschaften ist möglich. The active substance content of the application forms prepared from the commercial formulations can vary within wide ranges. The active ingredient concentration of the use forms is in the range of 0.00000001 to 97 wt .-% of active ingredient, preferably in the range of 0.0000001 to 97 wt .-%, particularly preferably in the range of 0.000001 to 83 wt .-% or 0, 000001 to 5 wt .-% and most preferably in the range of 0.0001 to 1 wt .-%. The active compound combinations according to the invention can be present in their commercially available formulations and in the formulations prepared from these formulations in admixture with other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals. A mixture with other known active ingredients, such as herbicides, fertilizers, growth regulators, safeners, semiochemicals, or with agents for improving the plant properties is possible.
Die erfindungsgemäßen Wirkstoffkombinationen können ferner beim Einsatz als Fungizide und/oder Insektizide in ihren handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischung mit Synergisten vorliegen. Synergisten sind Verbindungen, durch die die Wirkung der Wirkstoffe gesteigert wird, ohne dass der zugesetzte Synergist selbst aktiv wirksam sein muss. The active compound combinations according to the invention can furthermore be present in mixtures with synergists when used as fungicides and / or insecticides in their commercial formulations and in the forms of use prepared from these formulations. Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.
Die erfindungsgemäßen Wirkstoffkombinationen können ferner beim Einsatz als Fungizide und/oder Insektizide in ihren handelsüblichen Formulierungen sowie in den aus diesen Formulierungen bereiteten Anwendungsformen in Mischungen mit Hemmstoffen vorliegen, die einen Abbau des Wirkstoffes nach Anwendung in der Umgebung der Pflanze, auf der Oberfläche von Pflanzenteilen oder in pflanzlichen Geweben vermindern. When used as fungicides and / or insecticides, the active compound combinations according to the invention can also be present in their commercial formulations and in the forms of use prepared from these formulations in mixtures with inhibitors which inhibit degradation of the active substance after application in the environment of the plant, on the surface of plant parts or in plant tissues.
Die Anwendung geschieht in einer den Anwendungsformen angepassten üblichen Weise. The application is done in a custom forms adapted to the application forms.
Erfindungsgemäß können alle Pflanzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich natürlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechnologische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Sproß, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft Blätter, Nadeln, Stengel, Stämme, Blüten, Fruchtkörper, Früchte und Saatgut sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Früchte, Samen, Stecklinge, Knollen, Rhizome, Ableger, Saatgut, Brutzwiebeln, Absenker und Ausläufer. According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including plant varieties that can be protected or not protected by plant variety protection rights. Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, for example fruits, seeds, cuttings, tubers, rhizomes, offshoots, seeds, bulbs, sinkers and shoots.
Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirkstoffkombinationen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z.B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Auf- streichen, Injizieren und bei Vermehrungsmaterial, insbesondere bei Saatgut, weiterhin durch ein- oder mehrschichtiges Umhüllen. Dabei können die Wirkstoffkombinationen vor der Behandlung durch Mischen der einzelnen Wirkstoffe hergestellt werden. Oder die Behandlung erfolgt nacheinander durch Einsatz zunächst einer Verbindung der Formel (I) oder (1-1) gefolgt von der Behandlung mit einem Wirkstoff der Gruppe II. Es ist jedoch auch möglich die Pflanzen oder Pflanzenteile zunächst mit einem Wirkstoff der Gruppe II zu behandeln und die Behandlung mit einer Verbindung der Formel I oder (1-1) anzuschließen. The treatment according to the invention of the plants and plant parts with the active compound combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, eg by dipping, spraying, evaporating, atomizing, spreading, spreading painting, injecting and propagating material, in particular seed, by single or multi-layer coating. The active substance combinations can be prepared before the treatment by mixing the individual active ingredients. Or the treatment is carried out successively by using first a compound of formula (I) or (1-1) followed by treatment with a group II active ingredient. However, it is also possible to first treat the plants or plant parts with a group II active ingredient and to join the treatment with a compound of formula I or (1-1).
Als Pflanzen, welche erfindungsgemäß behandelt werden können, seien folgende erwähnt: Baumwolle, Flachs, Weinrebe, Obst, Gemüse, wie Rosaceae sp. (beispielsweise Kernfrüchte wie Apfel und Birne, aber auch Steinfrüchte wie Aprikosen, Kirschen, Mandeln und Pfirsiche und Beerenfrüchte wie Erdbeeren), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (beispielsweise Bananenbäume und -plantagen), Rubiaceae sp. (beispielsweise Kaffee), Theaceae sp., Sterculiceae sp., Rutaceae sp. (beispielsweise Zitronen, Organen und Grapefruit); Solanaceae sp. (beispielsweise Tomaten), Liliaceae sp., Asteraceae sp. (beispielsweise Salat), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (beispielsweise Gurke), Alliaceae sp. (beispielsweise Lauch, Zwiebel), Papilionaceae sp. (beispielsweise Erbsen); Hauptnutzpflanzen, wie Gramineae sp. (beispielsweise Mais, Rasen, Getreide wie Weizen, Roggen, Reis, Gerste, Hafer, Hirse und Triticale), Asteraceae sp. (beispielsweise Sonnenblume), Brassicaceae sp. (beispielsweise Weißkohl, Rotkohl, Brokkoli, Blumenkohl, Rosenkohl, Pak Choi, Kohlrabi, Radieschen sowie Raps, Senf, Meerrettich und Kresse), Fabacae sp. (beispielsweise Bohne, Erdnüsse), Papilionaceae sp. (beispielsweise Sojabohne), Solanaceae sp. (beispielsweise Kartoffeln), Chenopodiaceae sp. (beispielsweise Zuckerrübe, Futterrübe, Mangold, Rote Rübe); Nutzpflanzen und Zierpflanzen in Garten und Wald. As plants which can be treated according to the invention, mention may be made of the following: cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (for example, pome fruits such as apple and pear, but also drupes such as apricots, cherries, almonds and peaches and soft fruits such as strawberries), Ribesioidae sp., Juglandaceae sp., Betulaceae sp., Anacardiaceae sp., Fagaceae sp., Moraceae sp., Oleaceae sp., Actinidaceae sp., Lauraceae sp., Musaceae sp. (for example, banana trees and plantations), Rubiaceae sp. (for example, coffee), Theaceae sp., Sterculiceae sp., Rutaceae sp. (for example, lemons, organs and grapefruit); Solanaceae sp. (for example tomatoes), Liliaceae sp., Asteraceae sp. (for example, lettuce), Umbelliferae sp., Cruciferae sp., Chenopodiaceae sp., Cucurbitaceae sp. (for example cucumber), Alliaceae sp. leek, onion), Papilionaceae sp. (for example, peas); Main crops, such as Gramineae sp. (for example corn, turf, cereals such as wheat, rye, rice, barley, oats, millet and triticale), Asteraceae sp. (for example sunflower), Brassicaceae sp. (for example, white cabbage, red cabbage, broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radishes and rapeseed, mustard, horseradish and cress), Fabacae sp. (for example, bean, peanuts), Papilionaceae sp. (for example, soybean), Solanaceae sp. (for example potatoes), Chenopodiaceae sp. (for example, sugar beet, fodder beet, Swiss chard, beet); Crops and ornamental plants in the garden and forest.
In Abhängigkeit von den Pflanzenarten oder Pflanzensorten, ihrem Standort und ihren Wachstumsbedingungen (Böden, Klima, Vegetationsperiode, Ernährung) kann die erfindungsgemäße Behandlung auch zu überadditiven ("synergistischen") Effekten führen. So sind zum Beispiel die folgenden Effekte möglich, die über die eigentlich zu erwartenden Effekte hinausgehen: verringerte Aufwandmengen und/oder erweitertes Wirkungsspektrum und/oder erhöhte Wirksamkeit der Wirkstoffe und Zusammensetzungen, die erfindungsgemäß eingesetzt werden können, besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegenüber Trockenheit oder Wasser- oder Bodensalzgehalt, erhöhte Blühleistung, Ernteerleichterung, Reifebeschleunigung, höhere Erträge, größere Früchte, größere Pflanzenhöhe, intensiver grüne Farbe des Blatts, frühere Blüte, höhere Qualität und/oder höherer Nährwert der Ernteprodukte, höhere Zuckerkonzentration in den Früchten, bessere Lagerfähigkeit und/oder Verarbeitbarkeit der Ernteprodukte. In gewissen Aufwandmengen können die erfindungsgemäßen Wirkstoffkombinationen auch eine stärkende Wirkung auf Pflanzen ausüben. Sie eignen sich daher für die Mobilisierung des pflanzlichen Abwehrsystems gegen Angriff durch unerwünschte phytopathogene Pilze und/oder Mikroorganismen und/oder Viren. Dies kann gegebenenfalls einer der Gründe für die erhöhte Wirksamkeit der erfindungsgemäßen Kombinationen sein, zum Beispiel gegen Pilze. Pflanzenstärkende (resistenzinduzierende) Substanzen sollen im vorliegenden Zusammenhang auch solche Substanzen oder Substanzkombinationen bedeuten, die fähig sind, das pflanzliche Abwehrsystem so zu stimulieren, daß die behandelten Pflanzen, wenn sie im Anschluß daran mit unerwünschten phytopathogenen Pilzen und/oder Mikroorganismen und/oder Viren inokkuliert werde, einen beträchtlichen Resistenzgrad gegen diese unerwünschten phytopathogenen Pilze und/oder Mikroorganismen und/oder Viren aufweisen. Im vorliegenden Fall versteht man unter unerwünschten phytopathogenen Pilzen und/oder Mikroorganismen und/oder Viren phytopathogene Pilze, Bakterien und Viren. Die erfindungsgemäßen Substanzen lassen sich daher zum Schutz von Pflanzen gegen Angriff durch die erwähnten Pathogene innerhalb eines gewissen Zeitraums nach der Behandlung einsetzen. Der Zeitraum, über den eine Schutzwirkung erzielt wird, erstreckt sich im allgemeinen von 1 bis 10 Tagen, vorzugsweise 1 bis 7 Tagen, nach der Behandlung der Pflanzen mit den Wirkstoffen. Depending on the plant species or plant cultivars, their location and their growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention can also lead to superadditive ("synergistic") effects. Thus, for example, the following effects are possible, which go beyond the expected effects: reduced application rates and / or extended spectrum of action and / or increased efficacy of the active ingredients and compositions that can be used according to the invention, better plant growth, increased tolerance to high or low Temperatures, increased tolerance to drought or water or soil salinity, increased flowering, harvest relief, ripening, higher yields, larger fruits, greater plant height, intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, better storage and / or processability of the harvested products. At certain application rates, the active compound combinations according to the invention can also exert a strengthening effect on plants. They are therefore suitable for mobilizing the plant defense system against attack by undesirable phytopathogenic fungi and / or microorganisms and / or viruses. This may optionally be one of the reasons for the increased effectiveness of the combinations according to the invention, for example against fungi. Plant-strengthening (resistance-inducing) substances in the present context should also mean those substances or combinations of substances which are able to stimulate the plant defense system so that the treated plants, when subsequently inocculated with undesirable phytopathogenic fungi and / or microorganisms and / or viruses a considerable degree of resistance to these unwanted phytopathogenic fungi and / or microorganisms and / or viruses. In the present case, phytopathogenic fungi, bacteria and viruses are understood to be undesirable phytopathogenic fungi and / or microorganisms and / or viruses. The substances according to the invention can therefore be employed for the protection of plants against attack by the mentioned pathogens within a certain period of time after the treatment. The period of time over which a protective effect is achieved generally extends from 1 to 10 days, preferably 1 to 7 days, after the treatment of the plants with the active substances.
Zu Pflanzen und Pflanzensorten, die vorzugsweise erfindungsgemäß behandelt werden, zählen alle Pflanzen, die über Erbgut verfügen, das diesen Pflanzen besonders vorteilhafte, nützliche Merkmale verleiht (egal, ob dies durch Züchtung und/oder Biotechnologie erzielt wurde). Pflanzen und Pflanzensorten, die ebenfalls vorzugsweise erfindungsgemäß behandelt werden, sind gegen einen oder mehrere biotische Stressfaktoren resistent, d. h. diese Pflanzen weisen eine verbesserte Abwehr gegen tierische und mikrobielle Schädlinge wie Nematoden, Insekten, Milben, phytopathogene Pilze, Bakterien, Viren und/oder Viroide auf. Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology). Plants and plant varieties which are also preferably treated according to the invention are resistant to one or more biotic stressors, i. H. These plants have an improved defense against animal and microbial pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids.
Pflanzen und Pflanzensorten, die ebenfalls erfindungsgemäß behandelt werden können, sind solche Pflanzen, die durch erhöhte Ertragseigenschaften gekennzeichnet sind. Ein erhöhter Ertrag kann bei diesen Pflanzen z. B. auf verbesserter Pflanzenphysiologie, verbessertem Pflanzenwuchs und verbesserter Pflanzenentwicklung, wie Wasserverwertungseffizienz, Wasserhalteeffizienz, verbesserter Stickstoffverwertung, erhöhter Kohlenstoffassimilation, verbesserter Photosynthese, verstärkter Keimkraft und beschleunigter Abreife beruhen. Der Ertrag kann weiterhin durch eine verbesserte Pflanzenarchitektur (unter Stress- und nicht-Stress-Bedingungen) beeinflußt werden, darunter frühe Blüte, Kontrolle der Blüte für die Produktion von Hybridsaatgut, Keimpflanzenwüchsigkeit, Pflanzengröße, Internodienzahl und -abstand, Wurzelwachstum, Samengröße, Fruchtgröße, Schotengröße, Schoten- oder Ährenzahl, Anzahl der Samen pro Schote oder Ähre, Samenmasse, verstärkte Samenfüllung, verringerter Samenausfall, verringertes Schotenplatzen sowie Standfestigkeit. Zu weiteren Ertragsmerkmalen zählen Samenzusammensetzung wie Kohlenhydratgehalt, Proteingehalt, Ölgehalt und Ölzusammensetzung, Nährwert, Verringerung der nährwidrigen Verbindungen, verbesserte Verarbeitbarkeit und verbesserte Lagerfähigkeit. Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties. An increased yield can in these plants z. B. based on improved plant physiology, improved plant growth and improved plant development, such as water efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination and accelerated Abreife. Yield can be further influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for hybrid seed production, seedling vigor, plant size, internode count and spacing, root growth, seed size, fruit size, Pod size, pod or ear number, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed drop, reduced pod popping and stability. Other yield-related traits include seed composition such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction of nontoxic compounds, improved processability, and improved shelf life.
Pflanzen, die erfindungsgemäß behandelt werden können, sind Hybridpflanzen, die bereits die Eigenschaften der Heterosis bzw. des Hybrideffekts exprimieren, was im allgemeinen zu höherem Ertrag, höherer Wüchsigkeit, besserer Gesundheit und besserer Resistenz gegen biotische und abiotische Streßfaktoren führt. Solche Pflanzen werden typischerweise dadurch erzeugt, daß man eine ingezüchtete pollensterile Elternlinie (den weiblichen Kreuzungspartner) mit einer anderen ingezüchteten pollenfertilen Elternlinie (dem männlichen Kreuzungsp artner) kreuzt. Das Hybridsaatgut wird typischerweise von den pollensterilen Pflanzen geerntet und an Vermehrer verkauft. Pollensterile Pflanzen können manchmal (z. B. beim Mais) durch Entfahnen (d. h. mechanischem Entfernen der männlichen Geschlechtsorgane bzw. der männlichen Blüten), produziert werden; es ist jedoch üblicher, daß die Pollensterilität auf genetischen Determinanten im Pflanzengenom beruht. In diesem Fall, insbesondere dann, wenn es sich bei dem gewünschten Produkt, da man von den Hybridpflanzen ernten will, um die Samen handelt, ist es üblicherweise günstig, sicherzustellen, daß die Pollenfertilität in Hybridpflanzen, die die für die Pollensterilität verantwortlichen genetischen Determinanten enthalten, völlig restoriert wird. Dies kann erreicht werden, indem sichergestellt wird, daß die männlichen Kreuzungspartner entsprechende Fertilitätsrestorergene besitzen, die in der Lage sind, die Pollenfertilität in Hybridpflanzen, die die genetischen Determinanten, die für die Pollensterilität verantwortlich sind, enthalten, zu restorieren. Genetische Determinanten für Pollensterilität können im Cytoplasma lokalisiert sein. Beispiele für cytoplasmatische Pollensterilität (CMS) wurden zum Beispiel für Brassica-Arten beschrieben (WO 1992/005251, WO 1995/009910, WO 1998/27806, WO 2005/002324, WO 2006/021972 und US 6,229,072). Genetische Determinanten für Pollensterilität können jedoch auch im Zellkerngenom lokalisiert sein. Pollensterile Pflanzen können auch mit Methoden der pflanzlichen Biotechnologie, wie Gentechnik, erhalten werden. Ein besonders günstiges Mittel zur Erzeugung von pollensterilen Pflanzen ist in WO 89/10396 beschrieben, wobei zum Beispiel eine Ribonuklease wie eine Barnase selektiv in den Tapetumzellen in den Staubblättern exprimiert wird. Die Fertilität kann dann durch Expression eines Ribonukleasehemmers wie Barstar in den Tapetumzellen restoriert werden (z. B. WO 1991/002069). Pflanzen oder Pflanzensorten (die mit Methoden der Pflanzenbiotechnologie erhalten werden), die erfindungsgemäß behandelt werden können, sind herbizidtolerante Pflanzen, d. h. Pflanzen, die gegenüber einem oder mehreren vorgegebenen Herbiziden tolerant gemacht worden sind. Solche Pflanzen können durch Selektion von Pflanzen, die eine Mutation enthalten, die solch eine Herbizidtoleranz verleiht, erhalten werden. Insbesondere eignen sich die erfindungsgemäßen Wirkstoffkombinationen zur Behandlung von Saatgut. Bevorzugt sind dabei die vorstehend als bevorzugt oder besonders bevorzugt genannten erfindungsgemäßen Kombinationen zu nennen. So entsteht ein großer Teil des durch phytopathogene Pilze und/oder tierische Schädlinge verursachten Schadens an Kulturpflanzen bereits durch den Befall des Saatguts während der Lagerung und nach dem Einbringen des Saatguts in den Boden sowie während und unmittelbar nach der Keimung der Pflanzen. Diese Phase ist besonders kritisch, da die Wurzeln und Sprosse der wachsenden Pflanze besonders empfindlich sind und bereits ein geringer Schaden zum Absterben der ganzen Pflanze führen kann. Es besteht daher ein insbesondere großes Interesse daran, das Saatgut und die keimende Pflanze durch den Einsatz geeigneter Mittel zu schützen. Die Bekämpfung von phytopathogenen Pilzen und/oder tierischen Schädlingen durch die Behandlung des Saatguts von Pflanzen ist seit langem bekannt und ist Gegenstand ständiger Verbesserungen. Dennoch ergeben sich bei der Behandlung von Saatgut eine Reihe von Problemen, die nicht immer zufrieden stellend gelöst werden können. So ist es erstrebenswert, Verfahren zum Schutz des Saatguts und der keimenden Pflanze zu entwickeln, die das zusätzliche Ausbringen von Pflanzenschutzmitteln nach der Saat oder nach dem Auflaufen der Pflanzen überflüssig machen. Es ist weiterhin erstrebenswert, die Menge des eingesetzten Wirkstoffs dahingehend zu optimieren, dass das Saatgut und die keimende Pflanze vor dem Befall durch phytopathogene Pilze und/oder tierische Schädlinge bestmöglich geschützt werden, ohne jedoch die Pflanze selbst durch den eingesetzten Wirkstoff zu schädigen. Insbesondere sollten Verfahren zur Behandlung von Saatgut auch die intrinsischen fungiziden und/oder Insektiziden Eigenschaften transgener Pflanzen einbeziehen, um einen optimalen Schutz des Saatguts und auch der keimenden Pflanze bei einem minimalen Aufwand an Pflanzenschutzmitteln zu erreichen. Plants which can be treated according to the invention are hybrid plants which already express the properties of heterosis or hybrid effect, which generally leads to higher yield, higher vigor, better health and better resistance to biotic and abiotic stress factors. Such plants are typically produced by crossing an inbred male sterile parental line (the female crossover partner) with another inbred male fertile parent line (the male crossbred partner). The hybrid seed is typically harvested from the male sterile plants and sold to propagators. Pollen sterile plants can sometimes be produced (eg in maize) by delaving (ie mechanical removal of the male reproductive organs or the male flowers); however, it is more common for male sterility to be due to genetic determinants in the plant genome. In this case, especially when the desired product, as one wants to harvest from the hybrid plants, is the seeds, it is usually beneficial to ensure that the pollen fertility in hybrid plants containing the genetic determinants responsible for male sterility , completely restored. This can be accomplished by ensuring that the male crossing partners possess appropriate fertility restorer genes capable of restoring pollen fertility in hybrid plants containing the genetic determinants responsible for male sterility. Genetic determinants of pollen sterility may be localized in the cytoplasm. Examples of cytoplasmic male sterility (CMS) have been described, for example, for Brassica species (WO 1992/005251, WO 1995/009910, WO 1998/27806, WO 2005/002324, WO 2006/021972 and US 6,229,072). However, genetic determinants of pollen sterility may also be localized in the nuclear genome. Pollen sterile plants can also be obtained using plant biotechnology methods such as genetic engineering. A particularly convenient means of producing male-sterile plants is described in WO 89/10396, wherein, for example, a ribonuclease such as a barnase is selectively expressed in the tapetum cells in the stamens. The fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells (eg WO 1991/002069). Plants or plant varieties (obtained by plant biotechnology methods) which can be treated according to the invention are herbicidally tolerant plants, ie plants made tolerant to one or more given herbicides. Such plants can be obtained by selection of plants containing a mutation conferring such herbicide tolerance. In particular, the active compound combinations according to the invention are suitable for the treatment of seed. Preference is given to mention the combinations according to the invention mentioned above as being preferred or particularly preferred. Thus, a large part of the damage to crops caused by phytopathogenic fungi and / or animal pests already occurs through the infestation of the seed during storage and after introduction of the seed into the soil and during and immediately after germination of the plants. This phase is particularly critical, as the roots and shoots of the growing plant are particularly sensitive and even minor damage can lead to the death of the entire plant. There is therefore a particular interest in protecting the seed and the germinating plant by the use of suitable agents. The control of phytopathogenic fungi and / or animal pests by the treatment of the seed of plants has long been known and is the subject of constant improvement. Nevertheless, there are a number of problems in the treatment of seeds that can not always be satisfactorily resolved. Thus, it is desirable to develop methods of protecting the seed and the germinating plant, which eliminate the need for additional crop protection after sowing or after emergence of the plants. It is also desirable to optimize the amount of active ingredient used so that the seed and the germinating plant are best protected against attack by phytopathogenic fungi and / or animal pests, but without damaging the plant itself by the active ingredient used. In particular, methods for treating seed should also include the intrinsic fungicidal and / or insecticidal properties of transgenic plants in order to achieve optimum protection of the seed and also the germinating plant with a minimum of pesticides.
Die vorliegende Erfindung bezieht sich daher insbesondere auch auf ein Verfahren zum Schutz von Saatgut und keimenden Pflanzen vor dem Befall durch phytopathogene Pilze und/oder tierische Schädlinge, indem das Saatgut mit einem erfindungsgemäßen Wirkstoffkombinationen behandelt wird. Das erfindungsgemäße Verfahren zum Schutz von Saatgut und keimenden Pflanzen vor dem Befall durch phytopathogene Pilze und/oder tierische Schädlinge umfasst ein Verfahren, in dem das Saatgut zur gleichen Zeit mit einer Verbindung der Formel (I) und einem Wirkstoff aus der oben aufgeführten Gruppe (II) behandelt wird. Es umfasst auch ein Verfahren, in dem das Saatgut zu unterschiedlichen Zeiten mit einer Verbindung der Formel (I) und einem Wirkstoff aus der oben aufgeführten Gruppe (II) behandelt wird. Die Erfindung bezieht sich ebenfalls auf die Verwendung der erfindungsgemäßen Wirkstoffkombinationen zur Behandlung von Saatgut zum Schutz des Saatguts und der keimenden Pflanze vor phytopathogenen Pilzen und/oder durch phytopathogene Pilze und/oder tierischen Schädlingen. Weiterhin bezieht sich die Erfindung auf Saatgut, welches zum Schutz vor phytopathogenen Pilzen und/oder tierischen Schädlingen mit einer erfindungsgemäßen Wirkstoffkombination behandelt wurde. Die Erfindung bezieht sich auch auf Saatgut, welches zur gleichen Zeit mit einer Verbindung der Formel (I) und einem Wirkstoff aus der Gruppe II behandelt wurde. Die Erfindung bezieht sich weiterhin auf Saatgut, welches zu unterschiedlichen Zeiten mit einer Verbindung der Formel (I) und einem Wirkstoff aus der Gruppe II behandelt wurde. Bei Saatgut, welches zu unterschiedlichen Zeiten mit einer Verbindung der Formel (I) und einem Wirkstoff aus der Gruppe II behandelt wurde, können die einzelnen Wirkstoffe der erfindungsgemäßen Wirkstoffkombination in unterschiedlichen Schichten auf dem Saatgut enthalten sein. Dabei können die Schichten, die eine Verbindung der Formel (I) und einen Wirkstoff aus der gruppe II enthalten, gegebenenfalls durch eine Zwischenschicht getrennt sein. Die Erfindung bezieht sich auch auf Saatgut, bei dem eine Verbindung der Formel (I) und ein Wirkstoff aus der gruppe II als Bestandteil einer Umhüllung oder als weitere Schicht oder weitere Schichten zusätzlich zu einer Umhüllung aufgebracht sind. The present invention therefore also relates, in particular, to a method for protecting seed and germinating plants from infestation by phytopathogenic fungi and / or animal pests by treating the seed with a combination of active substances according to the invention. The method according to the invention for protecting seed and germinating plants from infestation by phytopathogenic fungi and / or animal pests comprises a method in which the seed is at the same time treated with a compound of the formula (I) and an active compound from the above-mentioned group (II ) is treated. It also comprises a process in which the seed is treated at different times with a compound of formula (I) and an active ingredient from the group (II) listed above. The invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the germinating plant from phytopathogenic fungi and / or by phytopathogenic fungi and / or animal pests. Furthermore, the invention relates to seed which has been treated with a combination of active substances according to the invention for protection against phytopathogenic fungi and / or animal pests. The invention also relates to seed treated at the same time with a compound of formula (I) and a group II active ingredient. The invention further relates to seed which has been treated at different times with a compound of formula (I) and a group II active ingredient. In the case of seed which has been treated at different times with a compound of the formula (I) and an active compound from group II, the individual active compounds of the active ingredient combination according to the invention may be present in different layers on the seed. In this case, the layers which comprise a compound of the formula (I) and an active compound from group II may optionally be separated by an intermediate layer. The invention also relates to seed in which a compound of formula (I) and an active compound from group II are applied as part of a coating or as a further layer or further layers in addition to a coating.
Ein Vorteil der vorliegenden Erfindung besteht in der synergistischen Erhöhung der Insektiziden Wirksamkeit der erfindungsgemäßen Wirkstoffkombinationen gegenüber dem Insektiziden Einzelwirkstoff, die über die zu erwartende Wirksamkeit der beiden einzeln angewendeten Wirkstoffe hinausgeht. Vorteilhaft ist auch die synergistische Erhöhung der fungiziden Wirksamkeit der erfindungsgemäßen Wirkstoffkombinationen gegenüber dem fungiziden Einzelwirkstoff, die über die zu erwartende Wirksamkeit des einzeln angewendeten Wirkstoffs hinausgeht. Damit wird eine Optimierung der Menge der eingesetzten Wirkstoffe ermöglicht. Ebenso ist es als vorteilhaft anzusehen, dass die erfindungsgemäßen Wirkstoffkombinationen insbesondere auch bei transgenem Saatgut eingesetzt werden können. An advantage of the present invention is the synergistic increase in the insecticidal activity of the active compound combinations according to the invention over the insecticidal single active substance, which goes beyond the expected efficacy of the two individually applied active ingredients. Also advantageous is the synergistic increase in the fungicidal activity of the active compound combinations according to the invention compared with the fungicidal single active substance, which goes beyond the expected effectiveness of the individually applied active ingredient. This allows optimization of the amount of active ingredients used. Likewise, it is considered to be advantageous that the active compound combinations according to the invention can be used in particular also in transgenic seed.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich zum Schutz von Saatgut jeglicher Pflanzensorte wie bereits vorstehend genannt, die in der Landwirtschaft, im Gewächshaus, in Forsten oder im Gartenbau eingesetzt wird. Insbesondere handelt es sich dabei um Saatgut von Mais, Erdnuss, Canola, Raps, Mohn, Soja, Baumwolle, Rübe (z.B. Zuckerrübe und Futterrübe), Reis, Hirse, Weizen, Gerste, Hafer, Roggen, Sonnenblume, Tabak, Kartoffeln oder Gemüse (z.B. Tomaten, Kohlgewächse, Salat, usw.). Die erfindungsgemäßen Wirkstoffkombinationen eignen sich ebenfalls zur Behandlung des Saatguts von Obstpflanzen und Gemüse wie vorstehend bereits genannt. Besondere Bedeutung kommt der Behandlung des Saatguts von Mais, Soja, Baumwolle, Reis, Rüben, Weizen und Canola oder Raps zu. Im Rahmen der vorliegenden Erfindung wird die erfindungsgemäße Wirkstoffkombination alleine oder in einer geeigneten Formulierung auf das Saatgut aufgebracht. Vorzugsweise wird das Saatgut in einem Zustand behandelt, in dem es so stabil ist, dass keine Schäden bei der Behandlung auftreten. Im Allgemeinen kann die Behandlung des Saatguts zu jedem Zeitpunkt zwischen der Ernte und der Aussaat erfolgen. Üblicherweise wird Saatgut verwendet, das von der Pflanze getrennt und von Kolben, Schalen, Stängeln, Hülle, Wolle oder Fruchtfleisch befreit wurde. So kann zum Beispiel Saatgut verwendet werden, das geerntet, gereinigt und bis zu einem Feuchtigkeitsgehalt von unter 15 Gew.-% getrocknet wurde. Alternativ kann auch Saatgut verwendet werden, das nach dem Trocknen z.B. mit Wasser behandelt und dann erneut getrocknet wurde. The active compound combinations according to the invention are suitable for the protection of seed of any plant variety as already mentioned above, which is used in agriculture, in the greenhouse, in forests or in horticulture. In particular, these are corn, peanut, canola, rapeseed, poppy, soybean, cotton, turnip (eg sugarbeet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower, tobacco, potatoes or vegetables ( eg tomatoes, cabbages, Salad, etc.). The active compound combinations according to the invention are likewise suitable for the treatment of the seed of fruit plants and vegetables as already mentioned above. Of particular importance is the treatment of the seeds of corn, soybeans, cotton, rice, beets, wheat and canola or oilseed rape. In the context of the present invention, the active ingredient combination according to the invention is applied to the seed alone or in a suitable formulation. Preferably, the seed is treated in a state where it is so stable that no damage occurs during the treatment. In general, the treatment of the seed can be done at any time between harvesting and sowing. Usually, seed is used which has been separated from the plant and freed from flasks, shells, stems, hull, wool or pulp. For example, seed may be used which has been harvested, cleaned and dried to a moisture content below 15% by weight. Alternatively, seed can also be used, which after drying, for example, treated with water and then dried again.
Im Allgemeinen muss bei der Behandlung des Saatguts darauf geachtet werden, dass die Menge der auf das Saatgut aufgebrachten erfindungsgemäßen Wirkstoffkombination und/oder weiterer Zusatzstoffe so gewählt wird, dass die Keimung des Saatguts nicht beeinträchtigt bzw. die daraus hervorgehende Pflanze nicht geschädigt wird. Dies ist vor allem bei Wirkstoffen zu beachten, die in bestimmten Aufwandmengen phytotoxische Effekte zeigen können. In general, when treating the seed, care must be taken that the amount of the active ingredient combination and / or other additives applied to the seed is chosen so that germination of the seed is not impaired or the resulting plant is not damaged. This is especially important for active ingredients, which can show phytotoxic effects in certain application rates.
Die erfindungsgemäßen Mittel können unmittelbar aufgebracht werden, also ohne weitere Komponenten zu enthalten und ohne verdünnt worden zu sein. In der Regel ist es vorzuziehen, die Mittel in Form einer geeigneten Formulierung auf das Saatgut aufzubringen. Geeignete Formulierungen und Verfahren für die Saatgutbehandlung sind dem Fachmann bekannt und werden z.B. in den folgenden Dokumenten beschrieben: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 AI, WO 2002/080675 AI, WO 2002/028186 A2. Die erfindungsgemäß verwendbaren Wirkstoffe können in die üblichen Beizmittel-Formulierungen überführt werden, wie Lösungen, Emulsionen, Suspensionen, Pulver, Schäume, Slurries oder andere Hüllmassen für Saatgut, sowie ULV-Formulierungen. The agents according to the invention can be applied directly, ie without containing further components and without being diluted. In general, it is preferable to apply the agents to the seed in the form of a suitable formulation. Suitable formulations and methods for seed treatment are known to those skilled in the art and are described e.g. in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 AI, WO 2002/080675 AI, WO 2002/028186 A2. The active compounds which can be used according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.
Diese Formulierungen werden in bekannter Weise hergestellt, indem man die Wirkstoffe mit üblichen Zusatzstoffen vermischt, wie zum Beispiel übliche Streckmittel sowie Lösungs- oder Verdünnungsmittel, Farbstoffe, Netzmittel, Dispergiermittel, Emulgatoren, Entschäumer, Konservierungsmittel, sekundäre Verdickungsmittel, Kleber, Gibberelline und auch Wasser. These formulations are prepared in a known manner by mixing the active ingredients with conventional additives, such as conventional extenders and solvents or diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and water.
Als Farbstoffe, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle für derartige Zwecke üblichen Farbstoffe in Betracht. Dabei sind sowohl in Wasser wenig lösliche Pigmente als auch in Wasser lösliche Farbstoffe verwendbar. Als Beispiele genannt seien die unter den Bezeichnungen Rhodamin B, C.I. Pigment Red 112 und C.I. Solvent Red 1 bekannten Farbstoffe. Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. There are both in Water sparingly soluble pigments as well as water-soluble dyes usable. Examples which may be mentioned are the dyes known under the names Rhodamine B, CI Pigment Red 112 and CI Solvent Red 1.
Als Netzmittel, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle zur Formulierung von agrochemischen Wirkstoffen üblichen, die Benetzung fördernden Stoffe in Frage. Vorzugsweise verwendbar sind Alkylnaphthalin-Sulfonate, wie Diiso- propyl- oder Diisobutylnaphthalin-Sulfonate. Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds. Preference is given to using alkylnaphthalene sulfonates, such as diisopropyl or diisobutylnaphthalene sulfonates.
Als Dispergiermittel und/oder Emulgatoren, die in den erfindungsgemäß verwendbaren Beizmittel- Formulierungen enthalten sein können, kommen alle zur Formulierung von agrochemischen Wirkstoffen üblichen nichtionischen, anionischen und kationischen Dispergiermittel in Betracht. Vorzugsweise verwendbar sind nichtionische oder anionische Dispergiermittel oder Gemische von nichtionischen oder anionischen Dispergiermitteln. Als geeignete nichtionische Dispergiermittel sind insbesondere Ethylenoxid-Propylenoxid Blockpolymere, Alkylphenolpolyglykolether sowie Tristryryl- phenolpolyglykolether und deren phosphatierte oder sulfatierte Derivate zu nennen. Geeignete anionische Dispergiermittel sind insbesondere Ligninsulfonate, Polyacrylsäuresalze und Arylsulfonat- Formaldehydkondensate. Suitable dispersants and / or emulsifiers which may be present in the seed dressing formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active compounds. Preferably usable are nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants. Particularly suitable nonionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives. Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.
Als Entschäumer können in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen alle zur Formulierung von agrochemischen Wirkstoffen üblichen schaumhemmenden Stoffe enthalten sein. Vorzugsweise verwendbar sind Silikonentschäumer und Magnesiumstearat. Als Konservierungsmittel können in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen alle für derartige Zwecke in agrochemischen Mitteln einsetzbaren Stoffe vorhanden sein. Beispielhaft genannt seien Dichlorophen und Benzylalkoholhemiformal. Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds. Preferably usable are silicone defoamers and magnesium stearate. Preservatives which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Examples include dichlorophen and Benzylalkoholhemiformal.
Als sekundäre Verdickungsmittel, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle für derartige Zwecke in agrochemischen Mitteln einsetzbaren Stoffe in Frage. Vorzugsweise in Betracht kommen Cellulosederivate, Acrylsäurederivate, Xanthan, modifizierte Tone und hochdisperse Kieselsäure. Suitable secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and finely divided silica.
Als Kleber, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen alle üblichen in Beizmitteln einsetzbaren Bindemittel in Frage. Vorzugsweise genannt seien Polyvinylpyrrolidon, Polyvinylacetat, Polyvinylalkohol und Tylose. Als Gibberelline, die in den erfindungsgemäß verwendbaren Beizmittel-Formulierungen enthalten sein können, kommen vorzugsweise die Gibberelline AI, A3 (= Gibberellinsäure), A4 und A7 infrage, besonders bevorzugt verwendet man die Gibberellinsäure. Die Gibberelline sind bekannt (vgl. R. Wegler„Chemie der Pflanzenschutz- und Schädlingsbekämpfungsmittel", Bd. 2, Springer Verlag, 1970, S. 401-412). Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents. Preferably mentioned are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and Tylose. Gibberellins which may be present in the seed dressing formulations which can be used in accordance with the invention are preferably the gibberellins AI, A3 (= gibberellic acid), A4 and A7, particularly preferably gibberellic acid. The gibberellins are known (see R. Wegler "Chemie der Pflanzenschutz- und Schädlingsbekungsmittel", Vol. 2, Springer Verlag, 1970, p. 401-412).
Die erfindungsgemäß verwendbaren Beizmittel-Formulierungen können entweder direkt oder nach vorherigem Verdünnen mit Wasser zur Behandlung von Saatgut der verschiedensten Art, auch von Saatgut transgener Pflanzen, eingesetzt werden. Dabei können im Zusammenwirken mit den durch Expression gebildeten Substanzen auch zusätzliche synergistische Effekte auftreten. The seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds, including seed of transgenic plants. In this case, additional synergistic effects may occur in interaction with the substances formed by expression.
Zur Behandlung von Saatgut mit den erfindungsgemäß verwendbaren Beizmittel-Formulierungen oder den daraus durch Zugabe von Wasser hergestellten Zubereitungen kommen alle üblicherweise für die Beizung einsetzbaren Mischgeräte in Betracht. Im einzelnen geht man bei der Beizung so vor, dass man das Saatgut in einen Mischer gibt, die jeweils gewünschte Menge an Beizmittel-Formulierungen entweder als solche oder nach vorherigem Verdünnen mit Wasser hinzufügt und bis zur gleichmäßigen Verteilung der Formulierung auf dem Saatgut mischt. Gegebenenfalls schließt sich ein Trocknungsvorgang an. For the treatment of seed with the seed dressing formulations which can be used according to the invention or the preparations prepared therefrom by the addition of water, all mixing devices customarily usable for the dressing can be considered. Specifically, in the pickling procedure, the seed is placed in a mixer which adds either desired amount of seed dressing formulations either as such or after prior dilution with water and mixes until evenly distributed the formulation on the seed. Optionally, a drying process follows.
Die erfindungsgemäßen Wirkstoffkombinationen eignen sich auch zur Steigerung des Ernteertrages. Sie sind außerdem mindertoxisch und weisen eine gute Pflanzenverträglichkeit auf. The active compound combinations according to the invention are also suitable for increasing crop yield. They are also low toxicity and have good plant tolerance.
Die erfindungsgemäßen Wirkstoffkombinationen weisen auch eine starke stärkende Wirkung in Pflanzen auf. Sie eignen sich daher zur Mobilisierung pflanzeneigener Abwehrkräfte gegen Befall durch unerwünschte Mikroorganismen. The active compound combinations according to the invention also have a strong tonic effect in plants. They are therefore suitable for mobilizing plant-own defenses against attack by unwanted microorganisms.
Unter pflanzenstärkenden (resistenzinduzierenden) Stoffen sind im vorliegenden Zusammenhang solche Substanzen zu verstehen, die in der Lage sind, das Abwehrsystem von Pflanzen so zu stimulieren, dass die behandelten Pflanzen bei nachfolgender Inokulation mit unerwünschten Mikroorganismen weitgehende Resistenz gegen diese Mikroorganismen entfalten. In the present context, plant-strengthening (resistance-inducing) substances are to be understood as meaning those substances which are capable of stimulating the defense system of plants in such a way that the treated plants exhibit extensive resistance to these microorganisms with subsequent inoculation with undesired microorganisms.
Unter unerwünschten Mikroorganismen sind im vorliegenden Fall phytopathogene Pilze, Bakterien und Viren zu verstehen. Die erfindungsgemäßen Stoffe können also eingesetzt werden, um Pflanzen innerhalb eines gewissen Zeitraumes nach der Behandlung gegen den Befall durch die genannten Schaderreger zu schützen. Der Zeitraum, innerhalb dessen Schutz herbeigeführt wird, erstreckt sich im Allgemeinen von 1 bis 10 Tage, vorzugsweise 1 bis 7 Tage nach der Behandlung der Pflanzen mit den Wirkstoffen. Undesirable microorganisms in the present case are phytopathogenic fungi, bacteria and viruses. The substances according to the invention can therefore be used to protect plants within a certain period of time after the treatment against the infestation by the said pathogens. The period within which protection is provided generally extends from 1 to 10 days, preferably 1 to 7 days after the treatment of the plants with the active ingredients.
Die aufgeführten Pflanzen können besonders vorteilhaft erfindungsgemäß mit den erfindungsgemäßen Wirkstoffmischungen behandelt werden. Die bei den Wirkstoffkombinationen oben angegebenen Vorzugsbereiche gelten auch für die Behandlung dieser Pflanzen. Besonders hervorgehoben sei die Pflanzenbehandlung mit den im vorliegenden Text speziell aufgeführten Wirkstoffkombinationen. Die gute Insektizide und fungizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen geht aus den nachfolgenden Beispielen hervor. Während die einzelnen Wirkstoffe in ihrer Wirkung Schwächen aufweisen, zeigen die Kombinationen eine Wirkung, die über eine einfache Wirkungssummierung hinausgeht. Ein synergistischer Effekt liegt bei Insektiziden und Fungiziden immer dann vor, wenn die Insektizide bzw. fungizide Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe. The listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention. The preferred ranges given above for the active substance combinations also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the active ingredient combinations specifically mentioned in the present text. The good insecticidal and fungicidal action of the active compound combinations according to the invention is evident from the examples below. While the individual active ingredients have weaknesses in their effect, the combinations show an effect that goes beyond a simple sum of effects. A synergistic effect is always present in the case of insecticides and fungicides whenever the insecticidal or fungicidal action of the active substance combinations is greater than the sum of the effects of the individually applied active substances.
Die zu erwartende Insektizide oder fungizide Wirkung für eine gegebene Kombination zweier Wirkstoffe kann nach S.R. Colby („Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967, 15, 20-22) wie folgt berechnet werden: The expected insecticidal or fungicidal activity for a given combination of two drugs can be found in S.R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicidal Combinations", Weeds 1967, 15, 20-22) are calculated as follows:
Wenn If
X den Abtötungsgrad bzw. Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m ppm bzw. g/ha bedeutet, X means the degree of killing or efficiency, expressed in% of the untreated control, when using the active substance A in an application rate of m ppm or g / ha,
Y den Abtötungsgrad bzw. Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Ein- satz des Wirkstoffes B in einer Aufwandmenge von n ppm bzw. g/ha bedeutet und Y means the degree of killing or efficiency, expressed in% of the untreated control, when using the active ingredient B at an application rate of n ppm or g / ha, and
E den Abtötungsgrad bzw. Wirkungsgrad, ausgedrückt in % der unbehandelten Kontrolle, beim Einsatz der Wirkstoffe A und B in Aufwandmengen von m und nppm bzw. g/ha bedeutet, E means the degree of killing or efficiency, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and nppm or g / ha,
X x Y X x Y
dann ist E = X + Y --—— then E = X + Y ----
100  100
Dabei wird der Abtötungsgrad bzw. Wirkungsgrad in % ermittelt. Es bedeutet 0 % ein Abtötungsgrad bzw. Wirkungsgrad, der demjenigen der Kontrolle entspricht, während ein Abtötungsgrad von 100 % bedeutet, dass alle Tiere tot sind und ein Wirkungsgrad von 100 % bedeutet, dass kein Befall beobachtet wird. The degree of kill or efficiency is determined in%. It means 0% a degree of kill or efficiency equal to that of the control, while a kill rate of 100% means that all animals are dead and an efficiency of 100% means that no infestation is observed.
Ist die tatsächliche fungizide oder Insektizide Wirkung größer als berechnet, so ist die Kombination in ihrer Wirkung überadditiv, d.h. es liegt ein synergistischer Effekt vor. In diesem Fall muss der tatsächlich beobachtete Wirkungsgrad größer sein als der aus der oben angeführten Formel errechnete Wert für den erwarteten Wirkungsgrad (E). Beispiel A If the actual fungicidal or insecticidal effect is greater than calculated, then the combination is over-additive in its effect, ie there is a synergistic effect. In this case, the actual observed efficiency must be greater than the expected efficiency value (E) calculated from the above formula. Example A
Myzus persicae -Test  Myzus persicae test
Lösungsmittel: 78 Gewichtsteile Aceton  Solvent: 78 parts by weight of acetone
1 ,5 Gewichtsteile Dimethylformamid  1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile Alkylarylpolyglykolether  Emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.  To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Kohlblätter (Brassica oleracea), die stark von der Grünen Pfirsichblattlaus (Myzus persicae) befallen sind, werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt. Cabbage leaves (Brassica oleracea) which are heavily infested with the green peach aphid (Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Blattläuse abgetötet wurden; 0 % bedeutet, dass keine Blattläuse abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel. After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen z. B. die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen: In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
Tabelle A - 1 : Myzus persicae Table A - 1: Myzus persicae
In den getesteten Mischungen aus Verbindung (I-l-l /Verbindung (1-1-7) bzw. Verbindung (1-1- In the tested mixtures of compound (I-1-l / compound (1-1-7) or compound (1-1-)
2)/Verbindung (1-1-8) lagen die Verbindungen (I-l-l) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% vor, die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%. 2) / compound (1-1-8), the compounds (III) and (1-1-2) were in each case about 85% and about 84% respectively, the compounds (1-1-7) and / or (1-1-8) each about 15%.
Tabelle A - 2: Myzus persicae Table A - 2: Myzus persicae
*gef. = gefundene Wirkung  * Found. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung  ** calc. = calculated according to the Colby formula
*** In den getesteten Mischungen aus Verbindung (I-l-l /Verbindung (1-1-7) bzw. Verbindung (1-1- 2)/Verbindung (1-1-8) lagen die Verbindungen (I-l-l) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% vor, die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%. Beispiel B *** In the mixtures of Compound (III / Compound (1-1-7) and Compound (1-1-2) / Compound (1-1-8) tested, the compounds (III) and (1-), respectively, were 85% and 84% respectively, and the compounds (1-1-7) and (1-1-8) each about 15% in each case Example B
Phaedon cochleariae - Larven -Test  Phaedon cochleariae - larval test
Lösungsmittel: 78 Gewichtsteile Aceton  Solvent: 78 parts by weight of acetone
1 ,5 Gewichtsteile Dimethylformamid  1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile Alkylarylpolyglykolether  Emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit  To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with
emulgatorhaltigem Wasser auf die gewünschte Konzentration.  emulsifier-containing water to the desired concentration.
Kohlblätter (Brassica oleracea) werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt und mit Larven des Meerrettichblattkäfers (Phaedon cochleariae) besetzt, solange die Blätter noch feucht sind. Cabbage leaves (Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and with larvae of the horseradish beetle (Phaedon cochleariae) as long as the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Käferlarven abgetötet wurden; 0 % bedeutet, dass keine Käferlarven abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.  After the desired time the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen:  In this test, the following active ingredient combinations according to the present application show a synergistically enhanced effectiveness compared to the individually applied active ingredients:
Tabelle B 1 : Phaedon cochleariae Larven - Test  Table B 1: Phaedon cochleariae larval test
er in ungsgemä  he in ungsgemä
Tabelle B 2: Phaedon cochleariae Larven - Test Table B 2: Phaedon cochleariae larval test
er in ungsgemä  he in ungsgemä
gef. = gefundene Wirkung  gef. = found effect
ber. = nach der Colby-Formel berechnete Wirkung  Calculated = calculated according to the Colby formula
*** In den getesteten Mischungen aus Verbindung (I-l-l /Verbindung (1-1-7) bzw. Verbindung (1-1- 2)/Verbindung (1-1-8) lagen die Verbindungen (I-l-l) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% vor, die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%. *** In the mixtures of Compound (III / Compound (1-1-7) and Compound (1-1-2) / Compound (1-1-8) tested, the compounds (III) and (1-), respectively, were 1-2) in each case to about 85% or about 84% before, the compounds (1-1-7) and (1-1-8) in each case about 15%.
Beispiel C Example C
Spodoptera frugiperda - Larven -Test  Spodoptera frugiperda - larval test
Lösungsmittel: 78 Gewichtsteile Aceton  Solvent: 78 parts by weight of acetone
1 ,5 Gewichtsteile Dimethylformamid  1.5 parts by weight of dimethylformamide
Emulgator: 0,5 Gewichtsteile Alkylarylpolyglykolether  Emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit  To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted with
emulgatorhaltigem Wasser auf die gewünschte Konzentration.  emulsifier-containing water to the desired concentration.
Kohlblätter (Brassica oleracea) werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt und mit Larven des Heerwurms (Spodoptera frugiperda) besetzt, solange die Blätter noch feucht sind.  Cabbage leaves (Brassica oleracea) are treated by spraying with the preparation of active compound in the desired concentration and are populated with larvae of the armyworm (Spodoptera frugiperda) while the leaves are still moist.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Raupen abgetötet wurden; 0 % bedeutet, dass keine Raupen abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.  After the desired time the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigen die folgenden Wirkstoffkombinationen gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Wirkstoffen:  In this test, the following active ingredient combinations according to the present application show a synergistically enhanced effectiveness compared to the individually applied active ingredients:
Tabelle C 1 : Spodoptera frugiperda Larven - Test  Table C 1: Spodoptera frugiperda larvae test
gef. = gefundene Wirkung  gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung  ** calc. = calculated according to the Colby formula
*** In den getesteten Mischungen aus Verbindung (1-1-1 / erbindung (1-1-7) bzw. Verbindung (1-1- 2)/Verbindung (1-1-8) lagen die Verbindungen (1-1-1) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% Λ die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%. Tabelle C - 2: Spodoptera frugiperda Larven - Test *** In the tested mixtures of compound (1-1-1 / compound (1-1-7) and compound (1-1-2) / compound (1-1-8), respectively, the compounds (1-1 -1) or (1-1-2) in each case to about 85% or about 84% Λ the compounds (1-1-7) or (1-1-8) in each case about 15%. Table C - 2: Spodoptera frugiperda larvae test
* gef. = gefundene Wirkung  * gef. = found effect
** ber. = nach der Colby-Formel berechnete Wirkung  ** calc. = calculated according to the Colby formula
*** In den getesteten Mischungen aus Verbindung (1-1-1 / erbindung (1-1-7) bzw. Verbindung (1-1- 2)/Verbindung (1-1-8) lagen die Verbindungen (1-1-1) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% vor, die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%.  *** In the tested mixtures of compound (1-1-1 / compound (1-1-7) and compound (1-1-2) / compound (1-1-8), respectively, the compounds (1-1 -1) or (1-1-2) in each case about 85% or about 84% before, the compounds (1-1-7) or (1-1-8) in each case about 15%.
Beispiel D Example D
Aphis gossypii - Test  Aphis gossypii test
Lösungsmittel: 7 Gewichtsteile Dimethylformamid  Solvent: 7 parts by weight of dimethylformamide
Emulgator: 2 Gewichtsteile Alkylarylpolyglykolether  Emulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.  To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Baumwollblätter (Gossypium hirsutum), die stark von der Baumwollblattlaus (Aphis gossypii) befallen sind, werden durch Spritzen mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt. Cotton leaves (Gossypium hirsutum) which are heavily infested with the cotton aphid (Aphis gossypii) are treated by spraying with the preparation of active compound in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Blattläuse abgetötet wurden; 0 % bedeutet, dass keine Blattläuse abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel. After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigt die folgende Wirkstoffkombination gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Verbindungen: Tabelle D: Aphis gossypii - Test In this test, the following active ingredient combination according to the present application shows a synergistically enhanced effectiveness compared to the individually used compounds: Table D: Aphis gossypii test
gef.=gefundeneWirkung  gef. = found effective
** ber. = nach der Colby-Formel berechnete Wirkung  ** calc. = calculated according to the Colby formula
*** In den getesteten Mischungen aus Verbindung (I-l-l /Verbindung (1-1-7) bzw. Verbindung (1-1- 2/Verbindung (1-1-8) lagen die Verbindungen (I-l-l) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% vor, die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%. Beispiel E *** In the mixtures of Compound (III / Compound (1-1-7) and Compound (1-1-2 / Compound (1-1-8)) tested, the compounds (III) and (1-1 -2) in each case about 85% or about 84% before, the compounds (1-1-7) and (1-1-8) in each case about 15%. Example E
Myzus persicae - Test (Run-off - Applikation)  Myzus persicae - Test (Run-off - Application)
Lösungsmittel: 7 Gewichtsteile Dimethylformamid  Solvent: 7 parts by weight of dimethylformamide
Emulgator: 2 Gewichtsteile Alkylarylpolyglykolether  Emulsifier: 2 parts by weight of alkylaryl polyglycol ether
Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt man 1 Gewichtsteil Wirkstoff mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit emulgatorhaltigem Wasser auf die gewünschte Konzentration.  To prepare a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
Kohlblätter (,Brassica oleracea), die stark von der Grünen Pfirsichblattlaus (Myzus persicae) befallen sind, werden durch eine Tropfnassspritzung mit der Wirkstoffzubereitung in der gewünschten Konzentration behandelt.  Cabbage leaves (Brassica oleracea) which are heavily infested with the green peach aphid (Myzus persicae) are treated by dripping wet spray with the preparation of active compound in the desired concentration.
Nach der gewünschten Zeit wird die Abtötung in % bestimmt. Dabei bedeutet 100 %, dass alle Blattläuse abgetötet wurden; 0 % bedeutet, dass keine Blattläuse abgetötet wurden. Die ermittelten Abtötungswerte verrechnet man nach der Colby-Formel.  After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula.
Bei diesem Test zeigt die folgende Wirkstoffkombination gemäß vorliegender Anmeldung eine synergistisch verstärkte Wirksamkeit im Vergleich zu den einzeln angewendeten Verbindungen:  In this test, the following active ingredient combination according to the present application shows a synergistically enhanced effectiveness compared to the individually used compounds:
Tabelle E: Myzus persicae Table E: Myzus persicae
gef.=gefundeneWirkung  gef. = found effective
** ber. = nach der Colby-Formel berechnete Wirkung  ** calc. = calculated according to the Colby formula
*** In den getesteten Mischungen aus Verbindung (1-1-1 /Verbindung (1-1-7) bzw. Verbindung (1-1- 2)/Verbindung (1-1-8) lagen die Verbindungen (1-1-1) bzw. (1-1-2) jeweils zu ca. 85% bzw. ca. 84% Λ die Verbindungen (1-1-7) bzw. (1-1-8) jeweils zu ca 15%.  *** In the mixtures of Compound (1-1-1 / Compound (1-1-7) and Compound (1-1-2) / Compound (1-1-8)) tested, the compounds (1-1 -1) or (1-1-2) in each case to about 85% or about 84% Λ the compounds (1-1-7) or (1-1-8) in each case about 15%.

Claims

Patentansprüche Patent claims
1. Wirkstoffkombinationen enthaltend eine synergistisch wirksame Kombination aus mindestens einer Verbindung der allgemeinen Formel (I), 1. Active ingredient combinations containing a synergistically effective combination of at least one compound of the general formula (I),
in welcher in which
R1 für Wasserstoff, Amino, Hydroxy oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl oder C3- Cö-Cycloalkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Nitro, Hydroxy, Ci-C4-Alkoxy, Ci-C4-Alkylthio, C C4- Alkylsulfmyl, Ci-C4-Alkylsulfonyl, (C C4-Alkoxy)carbonyl, C C4-Alkylamino, Di-(C C4-alkyl)amino, C3-C6-Cycloalkylamino oder (Ci-C4-Alkyl)C3-C6-cycloalkylamino, wherein _ _ _ _ the substituents can be independently selected from halogen, cyano, nitro, hydroxy, Ci-C 4 -alkoxy, Ci-C 4 -alkylthio, CC 4 -alkylsulfmyl, Ci-C 4 -alkylsulfonyl, (CC 4 -alkoxy)carbonyl, CC 4 -alkylamino, di-(CC 4 -alkyl)amino, C 3 -C6-cycloalkylamino or (Ci-C 4 -alkyl)C 3 -C6-cycloalkylamino,
R2 für Wasserstoff, C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C4- Alkoxy, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6-Cycloalkylamino, Ci-Cö-Alkoxy- carbonyl oder Ci-C6-Alkylcarbonyl steht, R 2 for hydrogen, CC 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, CC 4 -alkoxy, Ci-C 4 -alkylamino, di-(Ci -C 4 -alkyl)amino, C 3 -C6-cycloalkylamino, Ci-Cö-alkoxy-carbonyl or Ci-C 6 -alkylcarbonyl,
R3 für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C6-Alkyl, Ci-C6-Alkoxy, C2-C6-Alkenyl, C2-C6-Alkinyl, C3- Ci2-Cycloalkyl, C3-Ci2-Cycloalkyl-C C6-Alkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Amino, C3-C6-Cycloalkyl-amino, Halogen, Cyano, Carboxy, Carbamoyl Nitro, Hydroxy, Ci-C6-Alkyl, Ci-C6-Haloalkyl, C3-C6- Cycloalkyl, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4- Alkylsulfonyl, Ci-C6-Alkoxycarbonyl, Ci-C6-Alkylcarbonyl , C3-C6-Trialkylsilyl oder einem gesättigten oder teilgesättigten heterocyclischen Ring, einem aromatischen oder heteroaromatischen Ring oder einem gesättigten, teilgesättigten oder aromatischen hetero- bizyklischen Ring, wobei der Ring oder das Ringsystem gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist mit SF5, Halogen, Cyano, Nitro, Hydroxy, Amino, Carboxy, Carbamoyl, Aminosulfonyl, C C6-Alkyl, C3-C6-Cycloalkyl, C C4-Alkoxy, C C6-Haloalkyl, C C4-Haloalkoxy, C C4-Alkylthio, C C4-Alkylsulfmyl, C C4-Alkylsulfonyl, Ci-C4-Alkylsulfimino, Ci-C4-Alkylsulfimino-Ci-C4-alkyl, C C4- Alkylsulflmino-C2-C5-alkylcarbonyl, Ci-C4-Alkylsulfoximino, Ci-C4-Alkylsulfoximino-Ci- C4-alkyl, Ci-C4-Alkylsulfoximino-C2-C5-alkylcarbonyl, C C6-Alkoxycarbonyl, Ci-C6- Alkylcarbonyl, C3-C6-Trialkylsilyl, Benzyl C2-C6-Alkenyl, C2-C6-Alkinyl, C2-C6- Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Ci-C4-Haloalkylthio, C1 -C4- Haloalkylsulfinyl, CrC4-Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-R 3 is hydrogen or for optionally mono- or polysubstituted, identically or differently substituted Ci-C 6 -alkyl, Ci-C 6 -alkoxy, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -Ci 2 -cycloalkyl, C 3 -Ci 2 -cycloalkyl-C C6-alkyl, where the substituents can be independently selected from amino, C 3 -C6-cycloalkyl-amino, halogen, cyano, carboxy, carbamoyl nitro, hydroxy, Ci -C 6 -alkyl, Ci-C 6 -haloalkyl, C 3 -C 6 -cycloalkyl, CC 4 -alkoxy, CC 4 -haloalkoxy, CC 4 -alkylthio, Ci-C 4 -alkylsulfmyl, CC 4 -alkylsulfonyl, Ci- C 6 -alkoxycarbonyl, Ci-C 6 -alkylcarbonyl, C 3 -C6-trialkylsilyl or a saturated or partially saturated heterocyclic ring, an aromatic or heteroaromatic ring or a saturated, partially saturated or aromatic heterobicyclic ring, the ring or the ring system optionally is substituted once or multiple times, identically or differently, with SF 5 , halogen, cyano, nitro, hydroxy, amino, carboxy, carbamoyl, aminosulfonyl, CC 6 -alkyl, C 3 -C 6 -cycloalkyl, CC 4 -alkoxy, CC 6 - Haloalkyl, CC 4 -Haloalkoxy, CC 4 -Alkylthio, CC 4 -Alkylsulfmyl, CC 4 -Alkylsulfonyl, Ci-C 4 -Alkylsulfimino, Ci-C 4 -Alkylsulfimino-Ci-C 4 -alkyl, CC 4 - Alkylsulflmino-C 2 -C 5 -alkylcarbonyl, Ci-C 4 -alkylsulfoximino, Ci-C 4 -alkylsulfoximino-Ci-C 4 -alkyl, Ci-C 4 -alkylsulfoximino-C 2 -C 5 -alkylcarbonyl, CC 6 -alkoxycarbonyl , Ci-C 6 -alkylcarbonyl, C 3 -C 6 -trialkylsilyl, benzyl C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 2 -C 6 -haloalkenyl, C 2 -C6-haloalkynyl, C 3 -C6-halocycloalkyl, Ci-C 4 -haloalkylthio, C 1 -C4- haloalkylsulfinyl, C r C 4 -haloalkylsulfonyl, Ci-C 4 -alkylamino, di-(Ci-C 4 -alkyl)amino, C 3 -
Cö-Cycloalkylamino, oder einem 3- bis 6-gliedrigen Ring, wobei der Ring gegebenenfalls substituiert sein kann durch C C6-Alkyl, Halogen, Cyano Nitro, Halogen(C C6)-Alkyl, C C6-Alkoxy oder Halogen(Ci-C6)-Alkoxy, oder Cδ-cycloalkylamino, or a 3- to 6-membered ring, where the ring can optionally be substituted by CC 6 -alkyl, halogen, cyano nitro, halogen (CC 6 )-alkyl, CC 6 -alkoxy or halogen (Ci-C 6 )-Alkoxy, or
R3 für Ci-Cö-Alkoxycarbonyl, Ci-C6-Alkylcarbonyl, Ci-C6-Alkylaminocarbonyl oder Di(d- C6)alkylaminocarbonyl steht, oder R 3 represents Ci-Cö-alkoxycarbonyl, Ci-C6-alkylcarbonyl, Ci-C6-alkylaminocarbonyl or di(d-C6)alkylaminocarbonyl, or
R3 weiterhin für einen einfach oder mehrfach, gleich oder verschieden substituierten 5- oder 6- gliedrigen aromatischen oder heteroaromatischen Ring, einen 4, 5- oder 6-gliedrigen teilweise gesättigten Ring oder gesättigten heterozyklischen Ring, oder einen gesättigten, teilgesättigten oder aromatischen hetero-bizyklischen Ring steht, welcher gegebenenfalls ein bis drei Heteroatome aus der Reihe O, S oder N enthalten kann, wobei die Substituenten unabhängig voneinander ausgewählt sind aus SF5; Halogen, Cyano, Nitro, Hydroxy, Amino, Carboxy, Carbamoyl, Ci-C6-Alkyl, C3-C6-Cycloalkyl, Ci-C4-Alkoxy, C C6-Haloalkyl, C C4-Haloalkoxy, C C4-Alkylthio, C C4-Alkylsulfmyl, C C4- Alkylsulfonyl, Ci-C4-Alkylsulfimino, Ci-C4-Alkylsulfimino-Ci-C4-alkyl, C1 -C4- Alkylsulfimino-C 1 -C5-alkylcarbonyl, C 1 -C4-Alkylsulfoximino, C 1 -C4-Alkylsulfoximino-C 1 - C4-alkyl, Ci-C4-Alkylsulfoximino-C2-C5-alkylcarbonyl, Ci-C6-Alkoxycarbonyl, CI-CÖ- Alkylcarbonyl, C3-C6-Trialkylsilyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C2-C6-Haloalkenyl, C2- C6-Haloalkinyl, C3-C6-Halocycloalkyl, Ci-C4-Haloalkylthio, Ci-C4-Haloalkylsulfinyl, C C4-Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(C C4-alkyl)amino, C3-C6-Cycloalkylamino, oder einem 3- bis 6-gliedrigen Ring, wobei der Ring geben enfalls substituiert sein kann durch Ci-C6-Alkyl, Halogen, Cyano Nitro, Halogen(Ci-C6)-Alkyl, Ci-C6-Alkoxy oder Halogen(C 1 -C6)-Alkoxy, R 3 further represents a single or multiple, identically or differently substituted 5- or 6-membered aromatic or heteroaromatic ring, a 4, 5- or 6-membered partially saturated ring or saturated heterocyclic ring, or a saturated, partially saturated or aromatic heterocyclic ring. bicyclic ring, which may optionally contain one to three heteroatoms from the series O, S or N, the substituents being independently selected from SF 5; Halogen, Cyano, Nitro, Hydroxy, Amino, Carboxy, Carbamoyl, Ci-C 6 -alkyl, C 3 -C 6 -cycloalkyl, Ci-C 4 -alkoxy, CC 6 -haloalkyl, CC 4 -haloalkoxy, CC 4 -alkylthio , CC 4 -alkylsulfmyl, CC 4 - alkylsulfonyl, Ci-C 4 -alkylsulfimino, Ci-C 4 -alkylsulfimino-Ci-C 4 -alkyl, C 1 -C4- alkylsulfimino-C 1 -C 5 -alkylcarbonyl, C 1 - C 4 -alkylsulfoximino, C 1 -C 4 -alkylsulfoximino-C 1 - C 4 -alkyl, Ci-C 4 -alkylsulfoximino-C 2 -C 5 -alkylcarbonyl, Ci-C6-alkoxycarbonyl, C I -C O -alkylcarbonyl, C 3 -C 6 -trialkylsilyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 2 -C 6 -haloalkenyl, C 2 - C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, Ci- C 4 -haloalkylthio, Ci-C 4 -haloalkylsulfinyl, CC 4 -haloalkylsulfonyl, Ci-C 4 -alkylamino, di-(CC 4 -alkyl)amino, C 3 -C6-cycloalkylamino, or a 3- to 6-membered ring , where the ring can optionally be substituted by Ci-C 6 -alkyl, halogen, cyano nitro, halogen (Ci-C 6 )-alkyl, Ci-C 6 -alkoxy or halogen (C 1 -C 6 )-alkoxy,
R2 und R3 miteinander über zwei bis sechs Kohlenstoffatome verbunden sein können und einen Ring ausbilden, der gegebenenfalls zusätzlich ein weiteres Stickstoff-, Schwefel- oder Sauerstoffatom enthält und gegebenenfalls einfach bis vierfach mit C C2-Alkyl, Ci-C2-R 2 and R 3 can be connected to one another via two to six carbon atoms and form a ring which optionally also contains a further nitrogen, sulfur or oxygen atom and optionally has one to four times with CC 2 -alkyl, Ci-C 2 -
Haloalkyl, Halogen, Cyano, Amino Ci-C2-Alkoxy oder C C2-Haloalkoxy substituiert sein kann, Haloalkyl, halogen, cyano, amino Ci-C 2 -alkoxy or CC 2 -haloalkoxy can be substituted,
R2, R3 weiterhin gemeinsam für =S(C C4-Alkyl)2, =S(0)(C C4-Alkyl)2, stehen, R4 für Wasserstoff, Halogen, Cyano, Nitro C C4-Alkyl, C C4-Haloalkyl, C2-C6-Alkenyl, C2- C6-Haloalkenyl, C2-C6-Alkinyl, C C4-Alkoxy, C C4-Haloalkoxy, SF5, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, Ci-C4-Halo-alkyl-sulfmyl, Ci-C4-Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6- Cycloalkylamino, (C C4-Alkoxy)imino, (Ci-C4-Alkyl)(Ci-C4-Alkoxy)imino, (C1 -C4- Haloalkyl)(C C4-Alkoxy)imino oder C3-C6-Trialkylsilyl steht, oder zwei R4 über benachbarte Kohlenstoffatome einen Ring ausbilden, der für -(CH2)3-, -(CH2)4-, - (CH2)5-, -(CH=CH-)2-, -OCH20-, -0(CH2)20-, -OCF20-, -(CF2)20-, -0(CF2)20-, -(CH=CH- CH=N)- oder -(CH=CH-N=CH)- steht, zwei R4 weiterhin über benachbarte Kohlenstoffatome die folgenden anellierten Ringe ausbilden, die gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert sind, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C3- C6-Cycloalkyl, Ci-C6-Haloalkyl, C3-C6-Halocycloalkyl, Halogen, Ci-C6-Alkoxy, C C4- Alkylthio(C 1 -C6-alkyl), C C4-Alkylsulfmyl(C C6-alkyl), C C4-Alkylsulfonyl(C 1 -C6-alkyl), C 1 - C4-Alkylamino, Di-(Ci-C4-alkyl)amino oder C3-C6-Cycloalkylamino, R 2 , R 3 together also represent =S(CC 4 -alkyl) 2 , =S(0)(CC 4 -alkyl) 2 , R 4 for hydrogen, halogen, cyano, nitro CC 4 -alkyl, CC 4 -haloalkyl, C 2 -C 6 -alkenyl, C 2 - C 6 -haloalkenyl, C 2 -C 6 -alkynyl, CC 4 -alkoxy, CC 4 -Haloalkoxy, SF 5 , CC 4 -alkylthio, Ci-C 4 -alkylsulfmyl, CC 4 -alkylsulfonyl, CC 4 -haloalkylthio, Ci-C 4 -halo-alkyl-sulfmyl, Ci-C 4 -haloalkylsulfonyl, Ci-C 4 -Alkylamino, Di-(Ci-C 4 -alkyl)amino, C 3 -C6- Cycloalkylamino, (CC 4 -Alkoxy)imino, (Ci-C 4 -Alkyl)(Ci-C 4 -Alkoxy)imino, ( C 1 -C4- haloalkyl)(CC 4 -alkoxy)imino or C 3 -C6-trialkylsilyl, or two R 4 form a ring via adjacent carbon atoms which is -(CH 2 ) 3 -, -(CH 2 ) 4 -, - (CH 2 ) 5 -, -(CH=CH-) 2 -, -OCH 2 0-, -0(CH 2 ) 2 0-, -OCF 2 0-, -(CF 2 ) 2 0- , -0(CF 2 ) 2 0-, -(CH=CH- CH=N)- or -(CH=CH-N=CH)-, two R 4 continue to form the following fused rings via neighboring carbon atoms, which are optionally substituted once or multiple times, identically or differently, the substituents being able to be independently selected from hydrogen, Ci-C 6 alkyl, C 3 -C 6 cycloalkyl, Ci-C6 haloalkyl, C 3 -C 6 halocycloalkyl , halogen, Ci-C 6 -alkoxy, CC 4 -alkylthio(C 1 -C 6 -alkyl), CC 4 -alkylsulfmyl(CC 6 -alkyl), CC 4 -alkylsulfonyl(C 1 -C 6 -alkyl), C 1 - C 4 -alkylamino, di-(Ci-C 4 -alkyl)amino or C 3 -C6-cycloalkylamino,
n für 0 bis 3 steht, n stands for 0 to 3,
R5 für Ci-C6-Alkyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, Ci-C6-Halocycloalkyl, C2-C6-Alkenyl, C2-C6-Haloalkenyl, C2-C6-Alkinyl, C2-C6-Haloalkinyl, C C4-Alkoxy, Ci-C4-Haloalkoxy, Ci-C4-Alkylthio, C C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4- Haloalkylsulfinyl, Ci-C4-Haloalkylsulfonyl, Halogen, Cyano, Nitro oder C3-CÖ- Trialkylsilyl steht, R 5 for Ci-C 6 -alkyl, C 3 -C 6 -cycloalkyl, Ci-C 6 -haloalkyl, Ci-C 6 -halocycloalkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -haloalkenyl, C 2 -C6-alkynyl, C 2 -C6-haloalkynyl, CC 4 -alkoxy, Ci-C 4 -haloalkoxy, Ci-C 4 -alkylthio, CC 4 -alkylsulfmyl, CC 4 -alkylsulfonyl, CC 4 -haloalkylthio, CC 4 -haloalkylsulfinyl , Ci-C 4 -haloalkylsulfonyl, halogen, cyano, nitro or C 3 -C O - trialkylsilyl,
Qx für einen gegebenenfalls einfach oder mehrfach, gleich oder verschieden durch R7 substituierten, aromatischen oder heteroaromatischen 5-bis 6-gliedrigen Ring steht, welcher 1-3 Heteroatome aus der Reihe N, S, O enthalten kann, Qx for one, if necessary, single or multiple, the same or different through R 7 substituted, aromatic or heteroaromatic 5- to 6-membered ring, which can contain 1-3 heteroatoms from the series N, S, O,
A für gegebenenfalls, einfach oder mehrfach, substituiertes -(Ci-C6-alkylen)-, -(C2-C6- alkenylen)-, -(C2-C6-alkinylen)-, -R8-(C3-C6-Cycloalkyl)-R8-, -R8-0-R8-, -R8-S-R8-, -R8- S(=0)-R8-, -R8-S(=0)2-R8-, -R8-N(C C6-Alkyl)-R8-, -R8-C=NO(C C6-Alkyl)- R8, - CH[C02(Ci-C6-Alkyl)-, -R8-C(=0)-R8, -R8-C(=0)NH-R8, R8-C(=0)N(C C6-Alkyl)-R8, - R8-C(=0)NHNH-R8-, -R8-C(=0)N(C C6-Alkyl)-NH-R8-, -R8-C(=0)NHN(C C6-Alkyl)-R8, -R8-0(C=0)-R8, -R8-0(C=0)NH-R8, -R8-0(C=0)N(C C6-Alkyl)-R8, -R8-S(=0)2NH-R8, - R8-S(=0)2N(C C6-Alkyl)-R8, -R8-S(C=0)-R8, -R8-S(C=0)NH-R8, -R8-S(C=0)N(C C6- Alkyl)-R8, -R8-NHNH-R8, -R8-NHN(C C6-Alkyl)-R8, -R8-N(C C6-Alkyl)-NH-R8, -R8- N(C C6-Alkyl)-N(Ci-C6-Alkyl)-R8, -R8-N=CH-0-R8, -R8-NH(C=0)0-R8, -R8-N(C C6- Alkyl)-(C=0)0-R8, -R8-NH(C=0)NH-R8, -R8-NH(C=S)NH-R8, -R8-NHS(=0)2-R8, R8-NH- R8, R8-C(=0)-C(=0)-R8, R8-C(OH)-R8 , R8-NH(C=0)-R8, R8-Qz-R8 , R8-C(=N-NR'2)-R8 , R8-C(=C-R'2)-R8 oder -R8-N(C C6-Alkyl)S(=0)2-R8 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Nitro, Hydroxy, C C6-Alkyl, C C6-Alkyoxy, Halogen-Ci-C6-Alkyl, Amino, (Ci-C6-Alkyl)amino, Di(C C6-Alkyl)amino, C3-C6-Cycloalkyl wobei -(C3-C6-Cycloalkyl)- im Ring gegebenenfalls 1 bis 2 Heteroatome ausgewählt aus der Reihe N,S,0 enthalten kann, A for optionally, mono- or polysubstituted -(Ci-C 6 -alkylene)-, -(C 2 -C 6 -alkenylene)-, -(C 2 -C 6 -alkynylene)-, -R 8 -(C 3 -C 6 -cycloalkyl)-R 8 -, -R 8 -0-R 8 -, -R 8 -SR 8 -, -R 8 - S(=0)-R 8 -, -R 8 -S( =0) 2 -R 8 -, -R 8 -N(CC 6 -alkyl)-R 8 -, -R 8 -C=NO(CC 6 -alkyl)- R 8 , - CH[C0 2 (Ci- C 6 -Alkyl)-, -R 8 -C(=0)-R 8 , -R 8 -C(=0)NH-R 8 , R 8 -C(=0)N(CC 6 -Alkyl)- R 8 , -R 8 -C(=0)NHNH-R 8 -, -R 8 -C(=0)N(CC 6 -alkyl)-NH-R 8 -, -R 8 -C(=0) NHN(CC 6 -Alkyl)-R 8 , -R 8 -0(C=0)-R 8 , -R 8 -0(C=0)NH-R 8 , -R 8 -0(C=0) N(CC 6 -Alkyl)-R 8 , -R 8 -S(=0) 2 NH-R 8 , - R 8 -S(=0) 2 N(CC 6 -Alkyl)-R 8 , -R 8 -S(C=0)-R 8 , -R 8 -S(C=0)NH-R 8 , -R 8 -S(C=0)N(CC 6 - Alkyl)-R 8 , -R 8 -NHNH-R 8 , -R 8 -NHN(CC 6 -Alkyl)-R 8 , -R 8 -N(CC 6 -Alkyl)-NH-R 8 , -R 8 - N(CC 6 -Alkyl)- N(Ci-C 6 -Alkyl)-R 8 , -R 8 -N=CH-0-R 8 , -R 8 -NH(C=0)0-R 8 , -R 8 -N(CC 6 - Alkyl)-(C=0)0-R 8 , -R 8 -NH(C=0)NH-R 8 , -R 8 -NH(C=S)NH-R 8 , -R 8 -NHS(= 0) 2 -R 8 , R 8 -NH- R 8 , R 8 -C(=0)-C(=0)-R 8 , R 8 -C(OH)-R 8 , R 8 -NH(C =0)-R 8 , R 8 -Qz-R 8 , R 8 -C(=N-NR' 2 )-R 8 , R 8 -C(=C-R' 2 )-R 8 or -R 8 -N (CC 6 -Alkyl)S(=0) 2 -R 8 , where the substituents can be independently selected from halogen, cyano, nitro, hydroxy, CC 6 -alkyl, CC 6 -alkyoxy, halogen-Ci-C 6 -Alkyl, amino, (Ci-C 6 -alkyl)amino, di(CC 6 -alkyl)amino, C 3 -C 6 -cycloalkyl, where -(C 3 -C6-cycloalkyl)- optionally has 1 to 2 heteroatoms selected in the ring from the series N,S,0 can contain,
R8 für linear oder verzweigtes -(Ci-C6-alkylen)- steht oder für eine direkte Bindung steht, wobei mehrere R8 unabhängig voneinander für linear oder verzweigtes-(C C6-alkylen)- oder für eine direkte Bindung stehen, beispielsweise steht R8-0-R8- für -(C C6-alkylen)-0-(Ci-C6-alkylen)-, -(C C6-alkylen)-0-, -O- (Ci-C6-alkylen)-, oder -O-, wobei R' für Alkyl, Alkylcarbonyl, Alkenyl, Alkinyl, welche gegebenenfalls ein- oder mehrfach durch Halogen substituiert sein können, steht, R 8 represents linear or branched -(Ci-C 6 -alkylene)- or represents a direct bond, with several R 8 independently representing linear or branched -(C C 6 -alkylene)- or a direct bond, for example R 8 -0-R 8 - represents -(CC 6 -alkylene)-0-(Ci-C 6 -alkylene)-, -(CC 6 -alkylene)-0-, -O- (Ci-C 6 - alkylene)-, or -O-, where R' represents alkyl, alkylcarbonyl, alkenyl, alkynyl, which may optionally be substituted one or more times by halogen,
Qz für einen 3- bis 4-gliedrigen, teilweise gesättigten oder gesättigten, oder für einen 5 bis 6- gliedrigen, teilweise gesättigten, gesättigten oder aromatischen Ring steht oder für ein 6 bis 10-gliedriges bizyklisches Ringsystem steht, wobei der Ring oder das bizyklische Ringsystem gegebenenfalls 1 -3 Heteroatome aus der Reihe N, S, O enthalten kann, wobei der Ring oder das bizyklische Ringsystem gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6- Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carbamoyl, Nitro, Hydroxy, C C4-Alkoxy, C C4-Haloalkoxy, C C4- Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkyl- sulfmyl, Ci-C4-Haloalkylsulfonyl, Ci-C4-Alkylamino, Di-(Ci-C4-alkyl)amino, C3-C6- Cycloalkylamino, (C C6-Alkyl)carbonyl, (Ci-C6-Alkoxy)carbonyl, (Ci-C6-Qz stands for a 3- to 4-membered, partially saturated or saturated, or for a 5 to 6-membered, partially saturated, saturated or aromatic ring or stands for a 6 to 10-membered bicyclic ring system, where the ring or the bicyclic Ring system may optionally contain 1-3 heteroatoms from the series N, S, O, where the ring or the bicyclic ring system is optionally substituted once or more, identically or differently, and where the substituents can be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C6 alkenyl, C 2 -C6 alkynyl , C 3 -C 6 - cycloalkyl, Ci-C6-haloalkyl, C 2 -C6-haloalkenyl, C 2 -C6-haloalkynyl, C 3 -C6-halocycloalkyl, halogen, cyano, carbamoyl, nitro, hydroxy, CC 4 -alkoxy , CC 4 -Haloalkoxy, CC 4 -Alkylthio, Ci-C 4 -Alkylsulfmyl, CC 4 -Alkylsulfonyl, CC 4 -Haloalkylthio, CC 4 -Haloalkyl-sulfmyl, Ci-C 4 -Haloalkylsulfonyl, Ci-C 4 -Alkylamino, Di -(Ci-C 4 -alkyl)amino, C 3 -C 6 - cycloalkylamino, (C C6-alkyl)carbonyl, (Ci-C 6 -alkoxy)carbonyl, (Ci-C 6 -
Alkyl)aminocarbonyl, Di-(C i -C4-alkyl)aminocarbonyl, alkyl)aminocarbonyl, di-(C i -C 4 -alkyl)aminocarbonyl,
QY für einen 5-oder 6-gliedrigen, teilweise gesättigten oder gesättigten heterozyklischen oder heteroaromatischen Ring oder ein aromatisches 8-, 9- oder 10-gliedriges annelliertes heterobicyclisches Ringsystem steht, wobei der Ring oder das Ringsystem, gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-Ce- Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C6-Haloalkyl, C2-C6- Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, Nitro, Hydroxy, Ci-C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, C C4- Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkylsulfmyl, C C4- Haloalkylsulfonyl, C C4-Alkylamino, Di-(C C4-alkyl)amino, C3-C6-Cycloalkylamino, (Cr C6-Alkyl)carbonyl, (Ci-C6-Alkoxy)carbonyl, (Ci-C6-Alkyl)aminocarbonyl, Di-(Ci-C4- alkyl)aminocarbonyl, Tri-(Ci-C2)alkylsilyl, (Ci-C4-Alkyl)(Ci-C4-Alkoxy)imino, oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei Phenyl oder der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden mit Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Nitro, Hydroxy, C C4-Alkoxy, Ci-C4-Haloalkoxy substituiert sein können, QY stands for a 5- or 6-membered, partially saturated or saturated heterocyclic or heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system, where the ring or the ring system, optionally single or multiple, the same or different is substituted, and where the substituents can be independently selected from hydrogen, Ci-Ce-alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, C 3 -C 6 cycloalkyl, CC 6 haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C6-haloalkynyl, C 3 -C6-halocycloalkyl, halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, Ci-C 4 -alkoxy, CC 4 -haloalkoxy, CC 4 -alkylthio , CC 4 - alkylsulfmyl, CC 4 -alkylsulfonyl, CC 4 -haloalkylthio, CC 4 -haloalkylsulfmyl, CC 4 - haloalkylsulfonyl, CC 4 -alkylamino, di-(CC 4 -alkyl)amino, C 3 -C6-cycloalkylamino, (Cr C 6 -alkyl)carbonyl, (Ci-C 6 -alkoxy)carbonyl, (Ci-C6-alkyl)aminocarbonyl, di-(Ci-C 4 -alkyl)aminocarbonyl, tri-(Ci-C 2 )alkylsilyl, (Ci -C 4 -alkyl)(Ci-C 4 -alkoxy)imino, or where the substituents can be independently selected from phenyl or a 5- or 6-membered heteroaromatic ring, where phenyl or the ring is optionally single or multiple, identical or various with Ci-C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, Ci-C6-haloalkyl, C 2 -C 6 -haloalkenyl, C 2 - C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, nitro, hydroxy, CC 4 -alkoxy, Ci-C 4 -haloalkoxy can be substituted,
R7 für Wasserstoff, C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C6- Haloalkyl, C2-C6-Haloalkenyl, C3-C6-Cycloalkoxy oder R 7 for hydrogen, CC 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, CC 6 - haloalkyl, C 2 -C 6 -haloalkenyl, C 3 - C 6 -cycloalkoxy or
steht, R9 unabhängig voneinander für Wasserstoff, Ci-C6-Alkyl, C3-C6-Cycloalkyl, Ci-Cö-Haloalkyl, Halogen, Cyano, Nitro, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio oder C C4- Haloalkylthio steht, p für 0 bis 4 steht, stands, R 9 independently represent hydrogen, Ci-C 6 -alkyl, C 3 -C6-cycloalkyl, Ci-Cö-haloalkyl, halogen, cyano, nitro, CC 4 -alkoxy, CC 4 -haloalkoxy, CC 4 -alkylthio or CC 4 - Haloalkylthio stands, p stands for 0 to 4,
Z für N, CH, CF, CC1, CBr oder CI steht, die Verbindungen der allgemeinen Formel (I) außerdem N-Oxide und Salze umfassen (I), und ein oder mehrere Fungizide der Gruppe (II) ausgewählt aus Z stands for N, CH, CF, CC1, CBr or CI, the compounds of the general formula (I) also comprise N-oxides and salts (I), and one or more fungicides from group (II) selected from
(1) Inhibitoren der Ergosterol-Biosynthese, wie beispielsweise Aldimorph, Azaconazol, Bitertanol, Bromuconazol, Cyproconazol, Diclobutrazol, Difenoconazol, Diniconazol, Diniconazol-M, Dodemorph, Dodemorph Acetat, Epoxiconazol, Etaconazol, Fenarimol, Fenbuconazol, Fenhexamid, Fenpropidin, Fenpropimorph, Fluquinconazol, Flurprimidol, Flusilazol, Flutriafol, Furconazol, Furconazol-Cis, Hexaconazol, Imazalil, Imazalil Sulfat, Imibenconazol, Ipconazol, Metconazol, Myclobutanil, Naftifin, Nuarimol, Oxpoconazol, Paclobutrazol, Pefurazoat, Penconazol, Piperalin, Prochloraz, Propiconazol, Prothioconazol, Pyributicarb, Pyrifenox, Quinconazol, Simeconazol, Spiroxamin, Tebuconazol, Terbinafin, Tetraconazol, Triadimefon, Triadimenol, Tridemorph, Triflumizol, Triforin, Triticonazol, Uniconazol, Uniconazol-p, Viniconazol, Voriconazol, l -(4-Chlorphenyl)-2-(lH-l ,2,4-triazol-l - yl)cycloheptanol, Methyl-l-(2,2-dimethyl-2,3-dihydro-lH-inden-l -yl)-lH-imidazol-5-carboxylat, N'-{5-(Difluormethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl} -N-ethyl-N- methylimidoformamid, N-Ethyl-N-methyl-N'-{2-methyl-5-(trifluormethyl)-4-[3- (trimethylsilyl)propoxy]phenyl}imidoformamid und 0-[l -(4-Methoxyphenoxy)-3,3- dimethylbutan-2-yl]-lH-imidazol-l -carbothioat. (1) Inhibitors of ergosterol biosynthesis, such as Aldimorph, Azaconazole, Bitertanol, Bromuconazole, Cyproconazole, Diclobutrazol, Difenoconazole, Diniconazole, Diniconazole-M, Dodemorph, Dodemorph Acetate, Epoxiconazole, Etaconazole, Fenarimol, Fenbuconazole, Fenhexamid, Fenpropidine, Fenpropimorph, Fluquinconazole, Flurprimidol, Flusilazole, Flutriafol, Furconazole, Furconazole-Cis, Hexaconazole, Imazalil, Imazalil Sulfate, Imibenconazole, Ipconazole, Metconazole, Myclobutanil, Naftifin, Nuarimol, Oxpoconazole, Paclobutrazol, Pefurazoate, Penconazole, Piperaline, Prochloraz, Propiconazole, Prothioconazole, Pyributic arb , Pyrifenox, Quinconazole, Simeconazole, Spiroxamine, Tebuconazole, Terbinafine, Tetraconazole, Triadimefon, Triadimenol, Tridemorph, Triflumizole, Triforin, Triticonazole, Uniconazole, Uniconazole-p, Viniconazole, Voriconazole, l -(4-chlorophenyl)-2-(lH- l,2,4-triazol-l - yl)cycloheptanol, methyl l-(2,2-dimethyl-2,3-dihydro-lH-inden-l -yl)-lH-imidazole-5-carboxylate, N' -{5-(Difluoromethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl} -N-ethyl-N-methylimidoformamide, N-ethyl-N-methyl-N'-{2-methyl-5 -(trifluoromethyl)-4-[3-(trimethylsilyl)propoxy]phenyl}imidoformamide and 0-[l-(4-methoxyphenoxy)-3,3-dimethylbutan-2-yl]-lH-imidazole-l-carbothioate.
(2) Inhibitoren der Respiration (Atmungsketten-Inhibitoren), wie beispielsweise Bixafen, Boscalid, Carboxin, Diflumetorim, Fenfuram, Fluopyram, Flutolanil, Fluxapyroxad, Furametpyr, Furmecyclox, Isopyrazam Mischung des syn-epimeren Razemates 1RS,4SR,9RS und des anti- empimeren Razemates 1RS,4SR,9SR, Isopyrazam (anti-epimeres Razemat ), Isopyrazam (anti- epimeres Enantiomer 1R,4S,9S), Isopyrazam (anti-epimeres Enantiomer 1 S,4R,9R), Isopyrazam (syn-epimeres Razemat 1RS,4SR,9RS), Isopyrazam (syn-epimeres Enantiomer 1R,4S,9R), Isopyrazam (syn-epimeres Enantiomer 1 S,4R,9S), Mepronil, Oxycarboxin, Penflufen, Penthiopyrad, Sedaxane, Thifluzamid, l -Methyl-N-[2-(l , 1,2,2 -tetrafluorethoxy)phenyl]-3- (trifluormethyl)- 1 H-pyrazol-4-carboxamid, 3-(Difluormethyl)- 1 -methyl-N-[2-( 1 , 1 ,2,2- tetrafluorethoxy)phenyl] -1 H-pyrazol-4-carboxamid, 3-(Difluormethyl)-N-[4-fluor-2-( 1,1 ,2,3,3,3- hexafluorpropoxy)phenyl]-l-methyl-lH-pyrazol-4-carboxamid, N-[l -(2,4-Dichlorphenyl)-l - methoxypropan-2-yl] -3 -(difluormethyl)- 1 -methyl- 1 H-pyrazol-4-carboxamid, 5,8-Difluor-N-[2-(2- fluor-4-{[4-(lTifluormethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amm N-[9- (Dichlormethylen)-l,2,3,4-te1rahydro-l,4-methanonaphtha (2) Inhibitors of respiration (respiratory chain inhibitors), such as Bixafen, Boscalid, Carboxin, Diflumetorim, Fenfuram, Fluopyram, Flutolanil, Fluxapyroxad, Furametpyr, Furmecyclox, Isopyrazam Mixture of the syn-epimeric racemate 1RS,4SR,9RS and the anti- empimerene racemates 1RS,4SR,9SR, isopyrazam (anti-epimeric racemate), isopyrazam (anti-epimeric enantiomer 1R,4S,9S), isopyrazam (anti-epimeric enantiomer 1S,4R,9R), isopyrazam (syn-epimeric racemate 1RS ,4SR,9RS), isopyrazam (syn-epimeric enantiomer 1R,4S,9R), isopyrazam (syn-epimeric enantiomer 1S,4R,9S), mepronil, oxycarboxin, penflufen, penthiopyrad, sedaxane, thifluzamide, l -methyl-N -[2-(l, 1,2,2-tetrafluorethoxy)phenyl]-3-(trifluoromethyl)- 1H-pyrazole-4-carboxamide, 3-(difluoromethyl)- 1-methyl-N-[2-( 1 , 1,2,2-tetrafluoroethoxy)phenyl] -1 H-pyrazole-4-carboxamide, 3-(difluoromethyl)-N-[4-fluoro-2-(1,1,2,3,3,3-hexafluoropropoxy )phenyl]-l-methyl-lH-pyrazole-4-carboxamide, N-[l -(2,4-dichlorophenyl)-l - methoxypropan-2-yl] -3 -(difluoromethyl)- 1 -methyl- 1 H-pyrazole-4-carboxamide, 5,8-difluoro-N-[2-(2-fluoro-4-{[4-(lTifluoromethyl )pyridin-2-yl]oxy}phenyl)ethyl]quinazoline-4-amm N-[9-(Dichloromethylene)-1,2,3,4-te1rahydro-1,4-methanonaphtha
lH-pyrazol-4-carboxamid, N-[(l S,4R)-9-(Diclilonnethylen)-l,2,3,4-tetrahydro-l,4- methanonaphthalen-5-yl]-3-(difluormethyl)-l-methyl-lH-pyrazol-4-carboxam und N-[(1R,4S)- 9-(Dichlormethylen)- 1 ,2,3 ,4-tetrahydro- 1 ,4-methanonaphthalen-5-yl]-3 -(difluormethyl)- 1 -methyl- 1 H-pyrazol-4-carboxamid. lH-pyrazole-4-carboxamide, N-[(l S,4R)-9-(diclilonnethylene)-l,2,3,4-tetrahydro-l,4-methanonaphthalen-5-yl]-3-(difluoromethyl) -l-methyl-lH-pyrazole-4-carboxam and N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3 -(difluoromethyl)- 1 -methyl- 1 H-pyrazole-4-carboxamide.
(3) Inhibitoren der Respiration (Atmungsketten-Inhibitoren) am Komplex III der Atumungskette, wie beispielsweise Ametoctradin, Amisulbrom, Azoxystrobin, Cyazofamid, Coumethoxystrobin, Coumoxystrobin, Dimoxystrobin, Enestroburin, Famoxadon, Fenamidon, Fenoxystrobin, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyrametostrobin, Pyraoxystrobin, Pyribencarb, Triclopyricarb, Trifloxystrobin, (2E)-2-(2-{[6-(3- Chlor-2-methylphenoxy)-5-fluorpyrimidin-4-yl]oxy}phenyl)-2-(methoxyimino)-N- methylethanamid, (2E)-2-(Methoxyimino)-N-methyl-2-(2-{[({(lE)-l-[3- (trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)ethanamid, (2E)-2-(Methoxyimino)- N-methyl-2-{2-[(E)-({l-[3-(1rifluormethyl)phenyl]ethoxy}imino)methyl]phenyl}ethanamid, (2E)- 2-{2-[({[(lE)-l-(3-{[(E)-l-Fluor-2- phenylethenyl] oxy } phenyl)ethyliden] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N- methylethanamid, (2E)-2-{2-[({[(2E,3E)-4-(2,6-Dichlorphenyl)but-3-en-2- yliden] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N-methylethanamid, 2-Chlor-N-( 1,1,3- trimethyl-2,3-dihydro- 1 H-inden-4-yl)pyridin-3 -carboxamid, 5-Methoxy-2-methyl-4-(2- {[({(IE)- 1 -[3-(trifluormethyl)phenyl]ethyliden} amino)oxy]methyl}phenyl)-2,4-dihydro-3H-l ,2,4-triazol- 3 -on, Methyl-(2E)-2- {2-[( {cyclopropyl[(4- methoxyphenyl)imino]methyl} sulfanyl)methyl]phenyl} -3-methoxyprop-2-enoat, N-(3-Ethyl- 3,5,5-trimethylcyclohexyl)-3-(formylamino)-2-hydroxybenzamid, 2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid und (2R)-2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl } -2-methoxy-N-methylacetamid. (3) Inhibitors of respiration (respiratory chain inhibitors) on complex III of the respiratory chain, such as ametoctradine, amisulbrom, azoxystrobin, cyazofamid, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, famoxadone, fenamidone, fenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, Orys astrobin , picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, pyribencarb, triclopyricarb, trifloxystrobin, (2E)-2-(2-{[6-(3-chloro-2-methylphenoxy)-5-fluoropyrimidin-4-yl]oxy}phenyl) -2-(methoxyimino)-N-methylethanamide, (2E)-2-(methoxyimino)-N-methyl-2-(2-{[({(lE)-l-[3-(trifluoromethyl)phenyl]ethylidene} amino)oxy]methyl}phenyl)ethanamide, (2E)-2-(methoxyimino)- N-methyl-2-{2-[(E)-({l-[3-(1rifluoromethyl)phenyl]ethoxy}imino) methyl]phenyl}ethanamide, (2E)- 2-{2-[({[(lE)-l-(3-{[(E)-l-fluoro-2-phenylethenyl] oxy } phenyl)ethylidene] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N-methylethanamide, (2E)-2-{2-[({[(2E,3E)-4-(2,6-dichlorophenyl)but-3-ene -2- ylidene] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N-methylethanamide, 2-chloro-N-(1,1,3-trimethyl-2,3-dihydro-1H-indene- 4-yl)pyridine-3 -carboxamide, 5-methoxy-2-methyl-4-(2- {[({(IE)- 1 -[3-(trifluoromethyl)phenyl]ethylidene} amino)oxy]methyl}phenyl )-2,4-dihydro-3H-1,2,4-triazol-3-one, methyl-(2E)-2-{2-[({cyclopropyl[(4-methoxyphenyl)imino]methyl} sulfanyl)methyl ]phenyl} -3-methoxyprop-2-enoate, N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-(formylamino)-2-hydroxybenzamide, 2-{2-[(2,5-dimethylphenoxy )methyl]phenyl}-2-methoxy-N-methylacetamide and (2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide.
(4) Inhibitoren der Mitose und Zellteilung, wie beispielsweise Benomyl, Carbendazim, Chlorfenazol, Diethofencarb, Ethaboxam, Fluopicolid, Fuberidazol, Pencycuron, Thiabendazol, Thiophanat-Methyl, Thiophanat, Zoxamid, 5-Chlor-7-(4-methylpiperidin-l-yl)-6-(2,4,6- trifluorphenyl)[l,2,4]triazolo[l,5-a]pyrimidin und 3-Chlor-5-(6-chlorpyridin-3-yl)-6-methyl-4- (2,4,6-trifluorphenyl)pyridazin. (4) Inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fluopicolide, fuberidazole, pencycuron, thiabendazole, thiophanate-methyl, thiophanate, zoxamid, 5-chloro-7-(4-methylpiperidine-l- yl)-6-(2,4,6-trifluorophenyl)[l,2,4]triazolo[l,5-a]pyrimidine and 3-chloro-5-(6-chloropyridin-3-yl)-6-methyl -4-(2,4,6-trifluorophenyl)pyridazine.
(5) Verbindungen mit Multisite-Aktivität, wie beispielsweise Bordeauxmischung, Captafol, Captan, Chlorothalonil, Kupferzubereitungen wie Kupferhydroxid, Kupfernaphthenat, Kupferoxid, Kupferoxychlond, Kupfersulfat, Dichlofluanid, Dithianon, Dodine, Dodine freie Base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatinacetat, Iminoctadin, Iminoctadinalbesilat, Iminoctadintriacetat, Mankupfer, Mancozeb, Maneb, Metiram, Zinkmetiram, Kupfer-Oxin, Propamidin, Propineb, Schwefel und Schwefelzubereitungen wie beispielsweise Calciumpolysulfid, Thiram, Tolylfluanid, Zineb und Ziram. (5) Compounds with multisite activity, such as Bordeaux mixture, captafol, captan, chlorothalonil, copper preparations such as copper hydroxide, copper naphthenate, Copper oxide, copper oxychloride, copper sulfate, dichlofluanid, dithianone, dodine, dodine free base, ferbam, fluorofolpet, folpet, guazatin, guazatin acetate, iminoctadine, iminoctadinal besilate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, Sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram.
(6) Resistenzinduktoren, wie beispielsweise Acibenzolar-S-Methyl, Isotianil, Probenazol und Tiadinil. (6) Resistance inducers such as acibenzolar-S-methyl, isotianil, probeazole and tiadinil.
(7) Inhibitoren der Aminosäure- und Protein-Biosynthese, wie beispielsweise Andoprim, Blasticidin-S, Cyprodinil, Kasugamycin, Kasugamycin Hydrochlorid Hydrat, Mepanipyrim, Pyrimethanil und 3 -(5-Fluor-3,3 ,4,4-tetramethyl-3 ,4-dihydroisoquinolin- 1 -yl)quinolin. (7) Inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim, pyrimethanil and 3 -(5-fluoro-3,3,4,4-tetramethyl-3 ,4-dihydroisoquinolin-1-yl)quinoline.
(8) Inhibitoren der ATP Produktion, wie beispielsweiseFentin Acetat, Fentin Chlorid, Fentin Hydroxid und Silthiofam. (8) Inhibitors of ATP production such as fentin acetate, fentin chloride, fentin hydroxide and silthiofam.
(9) Inhibitoren der Zellwandsynthese, wie beispielsweise Benthiavalicarb, Dimethomorph, Flumorph, Iprovalicarb, Mandipropamid, Polyoxins, Polyoxorim, Validamycin A und Valifenalat. (9) Inhibitors of cell wall synthesis, such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamid, polyoxins, polyoxorim, validamycin A and valifenalate.
(10) Inhibitoren der Lipid- und Membran-Synthese, wie beispielsweise Biphenyl, Chloroneb, Dicloran, Edifenphos, Etridiazol, Iodocarb, Iprobenfos, Isoprothiolan, Propamocarb, Propamocarb Hydrochlorid, Prothiocarb, Pyrazophos, Quintozen, Tecnazene und Tolclofos- Methyl. (10) Inhibitors of lipid and membrane synthesis, such as biphenyl, chloroneb, dicloran, edifenphos, etridiazole, iodocarb, iprobefos, isoprothiolane, propamocarb, propamocarb hydrochloride, prothiocarb, pyrazophos, quintozene, tecnazene and tolclofos-methyl.
(11) Inhibitoren der Melanin-Biosynthese, wie beispielsweiseCarpropamid, Diclocymet, Fenoxanil, Fthalid, Pyroquilon, Tricyclazol und 2,2,2-Trifluorethyl {3-methyl-l-[(4- methylbenzoyl)amino]butan-2-yl}carbamat. (11) Inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, fthalide, pyroquilon, tricyclazole and 2,2,2-trifluoroethyl {3-methyl-l-[(4-methylbenzoyl)amino]butan-2-yl} carbamate.
(12) Inhibitoren der Nukleinsäuresynthese, wie beispielsweise Benalaxyl, Benalaxyl-M (Kiralaxyl), Bupirimat, Clozylacon, Dimethirimol, Ethirimol, Furalaxyl, Hymexazol, Metalaxyl, Metalaxyl-M (Mefenoxam), Ofurace, Oxadixyl und Oxolinsäure. (12) Nucleic acid synthesis inhibitors such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacone, dimethirimol, ethirimole, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixyl and oxolinic acid.
(13) Inhibitoren der Signaltransduktion, wie beispielsweiseChlozolinat, Fenpiclonil, Fludioxonil, Iprodion, Procymidon, Quinoxyfen und Vinclozolin. (13) Signal transduction inhibitors such as chlozolinate, fenpiclonil, fludioxonil, iprodione, procymidone, quinoxyfen and vinclozolin.
(14) Entkoppler, wie beispielsweise Binapacryl, Dinocap, Ferimzon, Fluazinam und Meptyldinocap. (15) Weitere Verbindungen, wie beispielsweise Benthiazol, Bethoxazin, Capsimycin, Carvon, Chinomethionat, Pyriofenon (Chlazafenon), Cufraneb, Cyflufenamid, Cymoxanil, Cyprosulfamide, Dazomet, Debacarb, Dichlorophen, Diclomezin, Difenzoquat, Difenzoquat Methylsulphat, Diphenylamin, Ecomat, Fenpyrazamin, Flumetover, Fluoromid, Flusulfamid, Flutianil, Fosetyl-Aluminium, Fosetyl-Calcium, Fosetyl-Natrium, Hexachlorbenzol, Irumamycin, Methasulfocarb, Methylisothiocyanat, Metrafenon, Mildiomycin, Natamycin, Nickel Dimethyldithiocarbamat, Nitrothal-Isopropyl, Octhilinone, Oxamocarb, Oxyfenthiin, Pentachlorphenol und dessen Salze, Phenothnn, Phosphorsäure und deren Salze, Propamocarb- Fosetylat, Propanosin-Natrium, Proquinazid, Pyrimorph, Pyrrolnitrin, Tebufloquin, Tecloftalam, Tolnifanid, Triazoxid, Trichlamid, Zarilamid, (3S,6S,7R,8R)-8-Benzyl-3-[({3- [(isobutyryloxy)methoxy] -4-methoxypyridin-2-yl } carbonyl)amino] -6-methyl-4,9-dioxo- 1 ,5- dioxonan-7-yl 2-methylpropanoat, 1 -(4-{4-[(5R)-5-(2,6-Difluorphenyl)-4,5-dihydro-l ,2-oxazol-3- yl] - 1 ,3 -thiazol-2-yl}piperidin- 1 -yl)-2-[5-methyl-3 -(trifluormethyl)-l H-pyrazol- 1 -yl] ethanon, 1 -(4- {4-[(5S)-5-(2,6-Difluorphenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2- [5-methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]ethanon, l-(4-{4-[5-(2,6-Difluorphenyl)-4,5- dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(1rinuormethyl)-lH- pyrazol-l-yl]ethanon, l-(4-Methoxyphenoxy)-3,3-dimethylbutan-2-yl-lH-imidazol-l-carboxylat, 2,3,5,6-Tetrachlor-4-(methylsulfonyl)pyridin, 2,3-Dibutyl-6-chlorthieno[2,3-d]pyrimidin-4(3H)- on, 2,6-Dimethyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol-l,3,5,7(2H,6H)-tetron, 2-[5-Methyl-3- (trifluormethyl)-lH-pyrazol-l-yl]-l-(4-{4-[(5R)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3- thiazol-2-yl}piperidin-l-yl)ethanon, 2-[5-Methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]-l-(4-{4- [(5S)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanon, 2-[5- Methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]-l-{4-[4-(5-phenyl-4,5-dihydro-l,2-oxazol-3-yl)-l,3- thiazol-2-yl]piperidin-l-yl} ethanon, 2-Butoxy-6-iod-3-propyl-4H-chromen-4-on, 2-Chlor-5-[2- chlor-1 -(2,6-difluor-4-methoxyphenyl)-4-methyl-lH-imidazol-5-yl]pyridin, 2-Phenylphenol und dessen Salze, 3-(4,4,5-Trifluor-3,3-dimethyl-3,4-dihydroisoquinolin-l-yl)quinolin, 3,4,5- Trichlorpyridin-2,6-dicarbonitril, 3-[5-(4-Chlorphenyl)-2,3-dimethyl-l,2-oxazolidin-3-yl]pyridin, 3-Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6-methylpyridazin, 4-(4-Chlorphenyl)-5-(2,6- difluorphenyl)-3,6-dimethylpyridazin, 5-Amino-l ,3,4-thiadiazol-2-thiol, 5-Chlor-N'-phenyl-N'- (prop-2-in-l-yl)thiophen-2-sulfonohydrazid, 5-Fluor-2-[(4-fluorbenzyl)oxy]pyrimidin-4-amin, 5- Fluor-2-[(4-methylbenzyl)oxy]pyrimidin-4-amin, 5-Methyl-6-octyl[l ,2,4]triazolo[l ,5- a]pyrimidin-7-amin, Ethyl-(2Z)-3-amino-2-cyan-3-phenylprop-2-enoat, N'-(4-{[3-(4-(14) Decouplers such as Binapacryl, Dinocap, Ferimzon, Fluazinam and Meptyldinocap. (15) Other compounds, such as benthiazole, bethoxazine, capsimycin, carvone, quinomethionate, pyriofenone (chlazafenone), cufraneb, cyflufenamide, cymoxanil, cyprosulfamide, dazomet, debacarb, dichlorophene, diclomezin, difenzoquat, difenzoquat methyl sulfate, diphenylamine, Ecomat, fenpyrazamine, Flumetover, Fluoromide, Flusulfamide, Flutianil, Fosetyl Aluminum, Fosetyl Calcium, Fosetyl Sodium, Hexachlorobenzene, Irumamycin, Methasulfocarb, Methyl Isothiocyanate, Metrafenone, Mildiomycin, Natamycin, Nickel Dimethyldithiocarbamate, Nitrothal Isopropyl, Octhilinone, Oxamocarb, Oxyfenthiine, Pentachlor phenol and its Salts, phenothnn, phosphoric acid and its salts, propamocarb fosetylate, propanosine sodium, proquinazide, pyrimorph, pyrrolnitrin, tebufloquine, tecloftalam, tolnifanide, triazoxide, trichlamide, zarilamide, (3S,6S,7R,8R)-8-benzyl-3 -[({3- [(isobutyryloxy)methoxy] -4-methoxypyridin-2-yl } carbonyl)amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl 2-methylpropanoate, 1 -(4-{4-[(5R)-5-(2,6-Difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidine - 1 -yl)-2-[5-methyl-3 -(trifluoromethyl)-l H-pyrazol- 1 -yl] ethanone, 1 -(4- {4-[(5S)-5-(2,6- Difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(trifluoromethyl)- lH-pyrazol-l-yl]ethanone, l-(4-{4-[5-(2,6-difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3- thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(1rinuormethyl)-lH-pyrazol-l-yl]ethanone, l-(4-methoxyphenoxy)-3,3-dimethylbutane- 2-yl-lH-imidazole-l-carboxylate, 2,3,5,6-tetrachloro-4-(methylsulfonyl)pyridine, 2,3-dibutyl-6-chlorothieno[2,3-d]pyrimidine-4(3H )-one, 2,6-dimethyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrole-l,3,5,7(2H,6H)-tetron , 2-[5-Methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]-l-(4-{4-[(5R)-5-phenyl-4,5-dihydro-l,2- oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanone, 2-[5-methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]-l-( 4-{4-[(5S)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanone, 2 -[5- Methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]-l-{4-[4-(5-phenyl-4,5-dihydro-l,2-oxazol-3-yl) -l,3- thiazol-2-yl]piperidin-l-yl} ethanone, 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-chloro-5-[2-chloro- 1 -(2,6-difluoro-4-methoxyphenyl)-4-methyl-1H-imidazol-5-yl]pyridine, 2-phenylphenol and its salts, 3-(4,4,5-trifluoro-3,3- dimethyl-3,4-dihydroisoquinolin-l-yl)quinoline, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3-[5-(4-chlorophenyl)-2,3-dimethyl-l,2-oxazolidine -3-yl]pyridine, 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6-methylpyridazine, 4-(4-chlorophenyl)-5-(2,6-difluorophenyl) -3,6-dimethylpyridazine, 5-amino-l,3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N'-(prop-2-yn-l-yl)thiophene-2- sulfonohydrazide, 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidine-4-amine, 5-fluoro-2-[(4-methylbenzyl)oxy]pyrimidine-4-amine, 5-methyl-6-octyl[ l ,2,4]triazolo[l ,5- a]pyrimidine-7-amine, ethyl (2Z)-3-amino-2-cyano-3-phenylprop-2-enoate, N'-(4-{[ 3-(4-
Chlorbenzyl)-l,2,4-thiadiazol-5-yl]oxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamid, N-(4-Chlorbenzyl)-3-[3-methoxy-4-(prop-2-in-l-yloxy)phenyl]propanamid, N-[(4- Chlorphenyl)(cyan)methyl]-3-[3-methoxy-4-(prop-2-in-l-yloxy)phenyl]propanamid, N-[(5-Brom- 3-chlorpyridin-2-yl)methyl]-2,4-dichlorpyridin-3-carboxamid, N-[l-(5-Brom-3-chlorpyridin-2- yl)ethyl]-2,4-dichlorpyridin-3-carboxamid, N-[l-(5-Brom-3-chlorpyridin-2-yl)ethyl]-2-fluor-4- iodpyridin-3-carboxamid, N-{(E)-[(Cyclopropylmethoxy)imino][6-(difluormethoxy)-2,3- difluorphenyl]methyl} -2-phenylacetamid, N- {(Z)-[(Cyclopropylmethoxy)imino] [6-Chlorobenzyl)-1,2,4-thiadiazol-5-yl]oxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, N-(4-Chlorobenzyl)-3-[3-methoxy-4- (prop-2-yn-l-yloxy)phenyl]propanamide, N-[(4-chlorophenyl)(cyano)methyl]-3-[3-methoxy-4-(prop-2-yn-l-yloxy)phenyl ]propanamide, N-[(5-bromo-3-chloropyridin-2-yl)methyl]-2,4-dichloropyridine-3-carboxamide, N-[l-(5-bromo-3-chloropyridine-2- yl)ethyl]-2,4-dichloropyridine-3-carboxamide, N-[l-(5-bromo-3-chloropyridin-2-yl)ethyl]-2-fluoro-4-iodopyridine-3-carboxamide, N- {(E)-[(Cyclopropylmethoxy)imino][6-(difluoromethoxy)-2,3-difluorophenyl]methyl} -2-phenylacetamide, N- {(Z)-[(Cyclopropylmethoxy)imino] [6-
(difluormethoxy)-2,3-difluoφhenyl]methyl}-2-phenylacetarnid, N'-{4-[(3-Tert-butyl-4-cyano-l,2- thiazol-5-yl)oxy]-2-chlor-5-methylphenyl}-N-ethyl-N-methylimidoforma N-Methyl-2-(l-{[5- methyl-3 -(trifluormethyl)-l H-pyrazol- 1 -yl] acetyl} piperidin-4-yl)-N-( 1 ,2,3,4- tetrahydronaphthalen-l-yl)-l,3-thiazol-4-carboxamid, N-Methyl-2-(l-{[5-methyl-3- (trifluormethyl)- 1 H-pyrazol-1 -yl] acetyl} piperidin-4-yl)-N-[( 1 R)- 1 ,2,3,4-tetrahydronaphthalen- 1 - yl] - 1 ,3 -thiazol-4-carboxamid, N-Methyl-2-( 1 - { [5-methyl-3 -(trifluormethyl)- 1 H-pyrazol- 1 - yl]acetyl}piperidin-4-yl)-N-[(l S)-l ,2,3,4-tetrahydronaphthalen-l -yl]-l ,3-thiazol-4-carboxamid, Pentyl- {6-[( { [( 1 -methyl- 1 H-tetrazol-5-yl)(phenyl)methyliden] amino} oxy)methyl]pyridin-2- yl}carbamat, Phenazin-1 -carbonsäure, Chinolin-8-ol, Chinolin-8-olsulfat(2: l) und Tert-butyl {6- [( { [( 1 -methyl-1 H-te1razol-5-yl)(phenyl)m (difluoromethoxy)-2,3-difluoroφhenyl]methyl}-2-phenylacetarnide, N'-{4-[(3-tert-butyl-4-cyano-1,2-thiazol-5-yl)oxy]-2- chloro-5-methylphenyl}-N-ethyl-N-methylimidoforma yl)-N-(1,2,3,4-tetrahydronaphthalen-l-yl)-l,3-thiazole-4-carboxamide, N-methyl-2-(l-{[5-methyl-3-(trifluoromethyl )- 1 H-pyrazol-1 -yl] acetyl} piperidin-4-yl)-N-[( 1 R)- 1,2,3,4-tetrahydronaphthalen-1-yl] - 1,3-thiazol-4 -carboxamide, N-methyl-2-( 1 - { [5-methyl-3 -(trifluoromethyl)- 1 H-pyrazol- 1 - yl]acetyl}piperidin-4-yl)-N-[(l S)- l ,2,3,4-tetrahydronaphthalen-l -yl]-l ,3-thiazol-4-carboxamide, pentyl- {6-[( { [( 1 -methyl- 1 H-tetrazol-5-yl)(phenyl )methylidene]amino}oxy)methyl]pyridin-2-yl}carbamate, phenazine-1-carboxylic acid, quinolin-8-ol, quinolin-8-ol sulfate(2:l) and tert-butyl {6- [( { [ ( 1 -methyl-1 H-te1razol-5-yl)(phenyl)m
(16) Weitere Verbindungen, wie beispielsweise l-Methyl-3-(trifluormethyl)-N-[2'- (1rifluormethyl)biphenyl-2-yl]-lH-pyrazol-4-carboxarnid, N-(4'-Chlorbiphenyl-2-yl)-3- (difluormethyl)-l -methyl-1 H-pyrazol-4-carboxamid, N-(2',4'-Dichlorbiphenyl-2-yl)-3- (difluormethyl)-l -methyl-1 H-pyrazol-4-carboxamid, 3-(Difluormethyl)-l-methyl-N-[4'- (trifluormethyl)biphenyl-2-yl]-lH-pyrazol-4-carboxamid, N-(2',5'-Difluorbiphenyl-2-yl)-l- methyl-3-(trifluormethyl)-lH-pyrazol-4-carboxamid, 3-(Difluormethyl)-l-methyl-N-[4'-(prop-l- in-l-yl)biphenyl-2-yl]-lH-pyrazol-4-carboxamid, 5-Fluor-l,3-dimethyl-N-[4'-(prop-l-in-l- yl)biphenyl-2-yl]-l H-pyrazol -4-carboxamid, 2-Chlor-N-[4'-(prop-l-in-l-yl)biphenyl-2-yl]pyridin- 3 -carboxamid, 3-(Difluormethyl)-N-[4'-(3 ,3-dimethylbut- 1 -in-1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H- pyrazol-4-carboxamid, N-[4'-(3,3-Dimethylbut-l-in-l-yl)biphenyl-2-yl]-5-fluor-l,3-dimethyl-lH- pyrazol-4-carboxamid, 3-(Difluormethyl)-N-(4'-ethinylbiphenyl-2-yl)-l-methyl-lH-pyrazol-4- carboxamid, N-(4'-Ethinylbiphenyl-2-yl)-5-fluor-l,3-dimethyl-l H-pyrazol -4-carboxamid, 2- Chlor-N-(4'-ethinylbiphenyl-2-yl)pyridin-3-carboxamid, 2-Chlor-N-[4'-(3,3-dimethylbut-l -in-1 - yl)biphenyl-2-yl]pyridin-3-carboxamid, 4-(Difluormethyl)-2-methyl-N-[4'- (trifluormethyl)biphenyl-2-yl]-l,3-thiazol-5-carboxamid, 5-Fluor-N-[4'-(3-hydroxy-3-methylbut- 1 -in- 1 -yl)biphenyl-2-yl]- 1 ,3 -dimethyl- 1 H-pyrazol-4-carboxamid, 2-Chlor-N-[4'-(3-hydroxy-3 - methylbut-l-in-l-yl)biphenyl-2-yl]pyridin-3-carboxamid, 3-(Difluormethyl)-N-[4'-(3-methoxy-3- methylbut- 1 -in-1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H-pyrazol -4-carboxamid, 5-Fluor-N-[4'-(3 - methoxy-3 -methylbut- 1 -in- 1 -yl)biphenyl-2-yl]- 1 ,3 -dimethyl- 1 H-pyrazol-4-carboxamid, 2-Chlor- N-[4'-(3-methoxy-3-methylbut-l -in-1 -yl)biphenyl-2-yl]pyridin-3-carboxamid, (5-Brom-2- methoxy-4-methylpyridin-3-yl)(2,3,4-trimethoxy-6-methylphenyl)methanon und N-[2-(4-{[3-(4- Chlorphenyl)prop-2-in-l-yl]oxy}-3-methoxyphenyl)ethyl]-N2-(methylsulfonyl)valinamid, 4-Oxo- 4-[(2-phenylethyl)amino]butansäure und But-3-yn-l-yl {6-[({[(Z)-(l-methyl-lH-tetrazol-5- yl)(phenyl)methylen]amino}oxy)methyl]pyridin-2-yl}carbamat. (16) Other compounds, such as l-methyl-3-(trifluoromethyl)-N-[2'-(1rifluoromethyl)biphenyl-2-yl]-lH-pyrazole-4-carboxarnide, N-(4'-chlorobiphenyl- 2-yl)-3-(difluoromethyl)-l -methyl-1 H-pyrazole-4-carboxamide, N-(2',4'-dichlorobiphenyl-2-yl)-3-(difluoromethyl)-l -methyl- 1 H-pyrazole-4-carboxamide, 3-(difluoromethyl)-l-methyl-N-[4'-(trifluoromethyl)biphenyl-2-yl]-lH-pyrazole-4-carboxamide, N-(2',5 '-Difluorobiphenyl-2-yl)-l-methyl-3-(trifluoromethyl)-lH-pyrazole-4-carboxamide, 3-(difluoromethyl)-l-methyl-N-[4'-(prop-l-in- l-yl)biphenyl-2-yl]-lH-pyrazole-4-carboxamide, 5-fluoro-l,3-dimethyl-N-[4'-(prop-l-yn-l-yl)biphenyl-2- yl]-l H-pyrazole -4-carboxamide, 2-chloro-N-[4'-(prop-l-yn-l-yl)biphenyl-2-yl]pyridine-3-carboxamide, 3-(difluoromethyl) -N-[4'-(3,3-dimethylbut-1-yn-1-yl)biphenyl-2-yl] - 1-methyl-1H-pyrazole-4-carboxamide, N-[4'-(3 ,3-Dimethylbut-l-yn-l-yl)biphenyl-2-yl]-5-fluoro-l,3-dimethyl-lH-pyrazole-4-carboxamide, 3-(difluoromethyl)-N-(4'- ethynylbiphenyl-2-yl)-l-methyl-lH-pyrazole-4-carboxamide, N-(4'-ethynylbiphenyl-2-yl)-5-fluoro-l,3-dimethyl-lH-pyrazole-4-carboxamide , 2-chloro-N-(4'-ethynylbiphenyl-2-yl)pyridine-3-carboxamide, 2-chloro-N-[4'-(3,3-dimethylbut-l -yn-1 -yl)biphenyl- 2-yl]pyridine-3-carboxamide, 4-(difluoromethyl)-2-methyl-N-[4'-(trifluoromethyl)biphenyl-2-yl]-l,3-thiazole-5-carboxamide, 5-fluoro- N-[4'-(3-hydroxy-3-methylbut-1-yn-1-yl)biphenyl-2-yl]-1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N -[4'-(3-hydroxy-3-methylbut-l-yn-l-yl)biphenyl-2-yl]pyridine-3-carboxamide, 3-(difluoromethyl)-N-[4'-(3-methoxy -3-methylbut- 1 -yn-1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H-pyrazole -4-carboxamide, 5-fluoro-N-[4'-(3 - methoxy-3 - methylbut-1-yn-1-yl)biphenyl-2-yl]-1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N-[4'-(3-methoxy-3-methylbut -l -yn-1 -yl)biphenyl-2-yl]pyridine-3-carboxamide, (5-bromo-2-methoxy-4-methylpyridin-3-yl)(2,3,4-trimethoxy-6-methylphenyl )methanone and N-[2-(4-{[3-(4-chlorophenyl)prop-2-yn-l-yl]oxy}-3-methoxyphenyl)ethyl]-N2-(methylsulfonyl)valinamide, 4-oxo - 4-[(2-phenylethyl)amino]butanoic acid and but-3-yn-l-yl {6-[({[(Z)-(l-methyl-lH-tetrazole-5- yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate.
2. Wirkstoffkombinationen gemäß Anspruch 1, dadurch gekennzeichnet, dass 2. Active ingredient combinations according to claim 1, characterized in that
R1 für Wasserstoff, C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Cyano(C C6-alkyl), C C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, CrC4-Alkoxy-Ci-C4- alkyl, Ci-C4-Alkylthio-Ci-C4-alkyl, Ci-C4-Alkylsulfmyl-Ci-C4-alkyl oder C C4-Alkylsul- fonyl-Ci-C4-alkyl steht, R 1 for hydrogen, CC 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, cyano(CC 6 -alkyl), CC 6 -haloalkyl, C 2 - C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, C r C 4 -alkoxy-Ci-C 4 -alkyl, Ci-C 4 -alkylthio-Ci-C 4 -alkyl, Ci-C 4 -alkylsulfmyl-Ci- C 4 -alkyl or CC 4 -alkylsulfonyl-Ci-C 4 -alkyl,
R2 für Wasserstoff oder C C6-Alkyl steht. R 2 represents hydrogen or CC 6 alkyl.
R3 für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C4-Alkyl, C C4-Alkoxy, C2-C4-Alkenyl, C2-C4-Alkinyl, C3- Cö-Cycloalkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Carboxy, Carbamoyl,, Nitro, Hydroxy, Ci-C4-Alkyl, C C4- Haloalkyl, C3-C6-Cycloalkyl, C C4-Alkoxy, C C4-Haloalkoxy, C C4-Alkylthio, C C4- Alkylsulfinyl, C C4-Alkylsulfonyl, Ci-C4-Alkoxycarbonyl, Ci-C4-Alkylcarbonyl oder einem Phenylrmg oder einem 4, 5- oder 6-gliedrigen, aromatischen teilgesättigten oder gesättigten heterozyklischen Ring stehen, wobei der Phenylring bzw. heterozyklische Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6- Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C6-Haloalkyl, C2-C6- Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, N02, Hydroxy, Ci-C4-Alkoxy, C C4-Haloalkoxy, Ci-C4-Alkylthio, C C4- Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4-Haloalkylsulfmyl, C C4- Haloalkylsulfonyl, C C4-Alkylamino, Di-(C C4-alkyl)amino, C3-C6-Cycloalkylamino, (Cr C6-Alkyl)carbonyl, (Ci-C6-Alkoxy)carbonyl oder R 3 is hydrogen or for C 2 -C 4 -alkenyl, C 2 -C 4 -alkynyl, C 3 -C cycloalkyl , which are optionally substituted once or more, identically or differently stands, where the substituents can be independently selected from halogen, cyano, carboxy, carbamoyl, nitro, hydroxy, Ci-C 4 -alkyl, CC 4 -haloalkyl, C 3 -C 6 -cycloalkyl, CC 4 -alkoxy, CC 4 -haloalkoxy, CC 4 -alkylthio, CC 4 -alkylsulfinyl, CC 4 -alkylsulfonyl, Ci-C 4 -alkoxycarbonyl, Ci-C 4 -alkylcarbonyl or a phenylrmg or a 4, 5- or 6-membered, aromatic partially saturated or saturated heterocyclic ring, whereby the phenyl ring or heterocyclic ring is optionally substituted once or more, identically or differently, and where the substituents can be independently selected from hydrogen, Ci-C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, CC 6 -haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C6 -haloalkynyl, C 3 -C6-halocycloalkyl, halogen, cyano, carboxy, carbamoyl, N0 2 , Hydroxy, Ci-C 4 -alkoxy, CC 4 -haloalkoxy, Ci-C 4 -alkylthio, CC 4 - alkylsulfmyl, CC 4 -alkylsulfonyl, CC 4 -haloalkylthio, CC 4 -haloalkylsulfmyl, CC 4 - haloalkylsulfonyl, CC 4 -alkylamino, di-(CC 4 -alkyl)amino, C 3 -C6-cycloalkylamino, (Cr C 6 -alkyl)carbonyl, (Ci-C 6 -alkoxy)carbonyl or
R3 für C2-C4-Alkoxycarbonyl, C2-C4-Alkylcarbonyl, C2-C4-Alkylaminocarbonyl oder C2-C4. R 3 is C 2 -C 4 alkoxycarbonyl, C 2 -C 4 alkylcarbonyl, C 2 -C 4 alkylaminocarbonyl or C 2 -C 4 .
Dialkylaminocarbonyl steht, oder dialkylaminocarbonyl stands, or
R3 für einen Phenylring, einen 5- oder 6-gliedrigen aromatischen heterozyklischen Ring oder einen 4-, 5- oder 6-gliedrigen teilgesättigten oder gesättigten heterozyklischen Ring steht, welcher 1-3 Heteroatome aus der Reihe N, S, O enthalten kann, wobei der Phenylring bzw. heterozyklische Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C4-Alkyl, C2-C4-Alkenyl, C2-C4-Alkinyl, C3-C6-Cycloalkyl, C C4-Haloalkyl, C2-C4-Haloalkenyl, C2-C4-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, N02, Hydroxy, Ci-C4-Alkoxy, Ci-C4-Haloalkoxy, C C4- Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, Ci-C4-Haloalkylthio, C C4- Haloalkylsulfinyl, Ci-C4-Haloalkylsulfonyl, C C4-Alkylamino, Di-( C C4-alkyl)amino, C3-C6-Cycloalkylamino, (C i -C4-Alkyl)carbonyl, (C i -C4-Alkoxy)carbonyl, R 3 represents a phenyl ring, a 5- or 6-membered aromatic heterocyclic ring or a 4-, 5- or 6-membered partially saturated or saturated heterocyclic ring, which can contain 1-3 heteroatoms from the series N, S, O, where the phenyl ring or heterocyclic ring is optionally substituted once or more, identically or differently, and where the substituents can be independently selected from hydrogen, Ci-C 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 -alkynyl, C 3 -C 6 -cycloalkyl, CC 4 -haloalkyl, C 2 -C 4 -haloalkenyl, C 2 -C 4 -haloalkynyl, C 3 -C6-halocycloalkyl, halogen, cyano, carboxy, carbamoyl, N0 2 , Hydroxy, Ci-C 4 -alkoxy, Ci-C 4 -haloalkoxy, CC 4 - Alkylthio, Ci-C 4 -alkylsulfmyl, CC 4 -alkylsulfonyl, Ci-C 4 -haloalkylthio, CC 4 - haloalkylsulfinyl, Ci-C 4 -haloalkylsulfonyl, CC 4 -alkylamino , di-(CC 4 -alkyl)amino, C 3 -C6-cycloalkylamino, (C i -C 4 -alkyl)carbonyl, (C i -C 4 -alkoxy)carbonyl,
R4 für Wasserstoff, Ci-C4-Alkyl, Ci-C4-Haloalkyl, Halogen, Cyano, Ci-C4-Alkoxy, C C4- Haloalkoxy, Ci-C4-Alkylthio oder Ci-C4-Haloalkylthio steht, zwei benachbarte Reste R4 ebenfalls für -(CH2)3-, -(CH2)4-, -(CH2)5-, -(CH=CH-)2-, -OCH20-, - 0(CH2)20-,-OCF20-, -(CF2)20-, -0(CF2)20-, -(CH=CH-CH=N)- oder -(CH=CH-N=CH)- stehen, n für 0, 1 , 2 steht, R 4 represents hydrogen, Ci-C 4 -alkyl, Ci-C 4 -haloalkyl, halogen, cyano, Ci-C 4 -alkoxy, CC 4 -haloalkoxy, Ci-C 4 -alkylthio or Ci-C 4 -haloalkylthio, two neighboring radicals R 4 also for -(CH 2 ) 3 -, -(CH 2 ) 4 -, -(CH 2 ) 5 -, -(CH=CH-) 2 -, -OCH 2 0-, - 0( CH 2 ) 2 0-,-OCF 2 0-, -(CF 2 ) 2 0-, -0(CF 2 ) 2 0-, -(CH=CH-CH=N)- or -(CH=CH- N=CH)-, n stands for 0, 1, 2,
R5 für C C4-Alkyl, C3-C6-Cycloalkyl, C C4-Haloalkyl, Ci-C6-Halocycloalkyl, C2-C6-Alkenyl, C2-C4-Haloalkenyl, C2-C4-Alkinyl, C2-C4-Haloalkinyl, CrC4-Alkoxy, Ci-C4-Haloalkoxy, Ci-C4-Alkylthio, C C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4-Haloalkylthio, C C4- Haloalkylsulfinyl, Ci-C4-Haloalkylsulfonyl, Halogen, Cyano, Nitro oder C3-C6- Trialkylsilyl steht, R 5 for CC 4 -alkyl, C 3 -C 6 -cycloalkyl, CC 4 -haloalkyl, Ci-C 6 -halocycloalkyl, C 2 -C 6 -alkenyl, C 2 -C 4 -haloalkenyl, C 2 -C 4 - Alkynyl, C 2 -C 4 -haloalkynyl, C r C 4 -alkoxy, Ci-C 4 -haloalkoxy, Ci-C 4 -alkylthio, CC 4 -alkylsulfmyl, CC 4 -alkylsulfonyl, CC 4 -haloalkylthio, CC 4 - haloalkylsulfinyl , Ci-C 4 -haloalkylsulfonyl, halogen, cyano, nitro or C 3 -C 6 -trialkylsilyl,
Qx für einen gebenenfalls einfach oder mehrfach, gleich oder verschieden durch R7 substituierten 5-6 gliedrigen heteroaromatischen Ring steht, welcher 1-3 Heteroatome aus der Reihe N, O, S enthalten kann, oder für Phenyl steht, Qx represents a 5-6 membered heteroaromatic ring, which may contain 1-3 heteroatoms from the series N, O, S, or is phenyl, which may be substituted once or multiple times, identically or differently by R 7 ,
A für gegebenenfalls, einfach oder mehrfach, substituiertes -(C C4-alkylen)-, -(C2-C4- alkenylen)-, -(C2-C4-alkinylen)-, -R8-(C3-C6-cycloalkyl)-R8-, -R8-0-R8-, -R8-S-R8-, -R8- S(=0)-R8-, -R8-S(=0)2-R8-, -R8-NH-(C C4-Alkyl)-, -R8-N(C C4-Alkyl)-R8, -R8-C=NO(C C4-Alkyl), -R8-C(=0)-R8, -R8-C(=S)-R8, -R8-C(=0)NH-R8, R8-C(=0)N(C C4-Alkyl)-R8, - R8-S(=0)2NH-R8, -R8-S(=0)2N(C C4-Alkyl)-R8, -R8-NH(C=0)0-R8, -R8-N(C C4-Alkyl)- (C=0)0-R8, -R8-NH(C=0)NH-R8, -R8-NHS(=0)2-R8, -R8-N(C C4-Alkyl)S(=0)2-R8, R8- NH-R8, R8-C(=0)-C(=0)-R8, R8-C(OH)-R8 , R8-Qz-R8 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Nitro, Hydroxy, C C6-Alkyl, C C6-Alkyoxy oder Halogen-C C6-Alkyl, A for optionally, mono- or polysubstituted -(CC 4 -alkylene)-, -(C 2 -C 4 -alkenylene)-, -(C 2 -C 4 -alkynylene)-, -R 8 -(C 3 - C 6 -cycloalkyl)-R 8 -, -R 8 -0-R 8 -, -R 8 -SR 8 -, -R 8 - S(=0)-R 8 -, -R 8 -S(=0 ) 2 -R 8 -, -R 8 -NH-(CC 4 -alkyl)-, -R 8 -N(CC 4 -alkyl)-R 8 , -R 8 -C=NO(CC 4 -alkyl), -R 8 -C(=0)-R 8 , -R 8 -C(=S)-R 8 , -R 8 -C(=0)NH-R 8 , R 8 -C(=0)N( CC 4 -Alkyl)-R 8 , - R 8 -S(=0) 2 NH-R 8 , -R 8 -S(=0) 2 N(CC 4 -Alkyl)-R 8 , -R 8 -NH (C=0)0-R 8 , -R 8 -N(CC 4 -alkyl)- (C=0)0-R 8 , -R 8 -NH(C=0)NH-R 8 , -R 8 -NHS(=0) 2 -R 8 , -R 8 -N(CC 4 -Alkyl)S(=0) 2 -R 8 , R 8 - NH-R 8 , R 8 -C(=0)-C (=0)-R 8 , R 8 -C(OH)-R 8 , R 8 -Qz-R 8 , where the substituents can be independently selected from halogen, cyano, nitro, hydroxy, CC 6 -alkyl, CC 6 -alkyoxy or halogen-C C 6 -alkyl,
Qz für einen 3- bis 4-gliedrigen, teilweise gesättigten oder gesättigten, oder für einen 5 bis 6- gliedrigen, teilweise gesättigten, gesättigten oder aromatischen Ring steht, wobei der Ring gegebenenfalls 1 -3 Heteroatome aus der Reihe N,S,0 enthalten kann, wobei der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, C C6-Haloalkyl, C2-C6- Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Hydroxy, Ci-C4-Alkoxy, C C4-Haloalkoxy, d-Q-Alkylthio, C1-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4- Haloalkylthio, Ci-C4-Haloalkylsulfinyl, CrC4-Haloalkylsulfonyl, für Ci-Cö-Alkyl steht oder für den Rest Qz represents a 3- to 4-membered, partially saturated or saturated, or a 5- to 6-membered, partially saturated, saturated or aromatic ring, the ring optionally containing 1-3 heteroatoms from the series N,S,0 can, whereby the ring is optionally substituted once or more, identically or differently, and where the substituents can be independently selected from hydrogen, Ci-C 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl , C 3 -C 6 -cycloalkyl, CC 6 -haloalkyl, C 2 -C 6 - Haloalkenyl, C 2 -C6 haloalkynyl, C 3 -C6 halocycloalkyl, halogen, cyano, hydroxy, Ci-C 4 -alkoxy, CC 4 -haloalkoxy, dQ-alkylthio, C 1 -C 4 -alkylsulfmyl, CC 4 -alkylsulfonyl , CC 4 - haloalkylthio, Ci-C 4 -haloalkylsulfinyl, C r C 4 -haloalkylsulfonyl, represents Ci-C ö -alkyl or the rest
steht, stands,
R7 weiterhin _ für C3-C6-Cycloalkoxy steht, R 7 continues to represent C 3 -C6-cycloalkoxy,
R9 unabhängig voneinander _ für Wasserstoff, Halogen, Cyano, C C4-Alkyl, C C4-Alkoxy, C C4-Haloalkyl, C C4-Haloalkoxy, C C4-Haloalkylsulfonyl oder (C C4-Alkyl)Ci-C4- Alkoxyimino steht, p für 1, 2 oder 3 steht, R 9 independently represents hydrogen, halogen, cyano, CC 4 -alkyl, CC 4 -alkoxy, CC 4 -haloalkyl, CC 4 -haloalkoxy, CC 4 -haloalkylsulfonyl or (CC 4 -alkyl)Ci-C 4 -alkoxyimino , p stands for 1, 2 or 3,
Z für N, CH, CF, CC1, CBr oder CI steht, Z stands for N, CH, CF, CC1, CBr or CI,
R8 für linear oder verzweigtes -(Ci-C4-alkylen)-oder für eine direkte Bindung steht R 8 represents linear or branched -(Ci-C 4 -alkylene)-or a direct bond
QY für einen 5-oder 6-gliedrigen, teilweise gesättigten oder gesättigten heterozyklischen oder heteroaromatischen Ring oder ein aromatisches 8-, 9- oder 10-gliedriges annelliertes heterobicyclisches Ringsystem steht, wobei die Heteroatome ausgewählt sein können aus der Reihe N, S, O, wobei der Ring oder das Ringsystem, gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiert ist, und wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Wasserstoff, Ci-C6-Alkyl, C2-C6-Alkenyl, C2-C6- Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6- Halocycloalkyl, Halogen, Cyano, Carboxy, Carbamoyl, Nitro, Hydroxy, Ci-C4-Alkoxy, C GpHaloalkoxy, C C4-Alkylthio, Ci-C4-Alkylsulfmyl, C C4-Alkylsulfonyl, C C4- Haloalkylthio, C C4-Haloalkylsulfinyl, Ci-C4-Haloalkylsulfonyl, oder wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Phenyl oder einem 5- oder 6-gliedrigen heteroaromatischen Ring, wobei Phenyl oder der Ring gegebenenfalls einfach oder mehrfach, gleich oder verschieden mit C C6-Alkyl, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6-Cycloalkyl, Ci-C6-Haloalkyl, C2-C6-Haloalkenyl, C2-C6-Haloalkinyl, C3-C6-Halocycloalkyl, Halogen, Cyano, Nitro, Hydroxy, C C4-Alkoxy, Ci-C4-Haloalkoxy substituiert sein können. Wirkstoffkombinationen gemäß einem der Ansprüche 1 oder 2 enthaltend mindestens QY represents a 5- or 6-membered, partially saturated or saturated heterocyclic or heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system, where the heteroatoms can be selected from the series N, S, O, where the ring or the ring system is optionally mono or multiple substituted in the same or different ways, and where the substituents can be independently selected from hydrogen, Ci-C 6 alkyl, C 2 -C6 alkenyl, C 2 -C 6 - Alkynyl, C 3 -C 6 -cycloalkyl, Ci-C 6 -haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, carboxy, carbamoyl, nitro , hydroxy, Ci-C 4 -alkoxy, C GpHaloalkoxy, CC 4 -alkylthio, Ci-C 4 -alkylsulfmyl, CC 4 -alkylsulfonyl, CC 4 -haloalkylthio, CC 4 -haloalkylsulfinyl, Ci- C 4 -haloalkylsulfonyl , or where the Substituents can be independently selected from phenyl or a 5- or 6-membered heteroaromatic ring, with phenyl or the ring optionally being single or multiple, identical or different with CC 6 -alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 -alkynyl, C 3 -C 6 -cycloalkyl, Ci-C6-haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl , C 3 -C 6 -halocycloalkyl, halogen, cyano, nitro, hydroxy, CC 4 -alkoxy, Ci-C 4 -haloalkoxy can be substituted. Active ingredient combinations according to one of claims 1 or 2 containing at least
Wirkstoff der Formel (1-1), Active ingredient of formula (1-1),
in welcher in which
R3 für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C6-Alkyl, Ci-C6-Alkoxy, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-Ci2- Cycloalkyl, C3-Ci2-Cycloalkyl-Ci-C6-Alkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Amino, Cyano, Nitro, Hydroxy, Ci-Ce- Alkyl, C3-C6-Cycloalkyl, C C4-Alkoxy, Ci-C4-Haloalkoxy, C C4-Alkylthio, C2-C6- Alkoxycarbonyl, Ci-C6-Alkylcarbonyl C3-C6-Cycloalkylamino oder einem 5- oder 6- gliedrigen heteroaromatischen Ring, R 3 is hydrogen or for optionally mono- or polysubstituted, identically or differently substituted Ci-C 6 -alkyl, Ci-C 6 -alkoxy, C 2 -C6-alkenyl, C 2 -C6-alkynyl, C 3 -Ci 2 - Cycloalkyl, C 3 -Ci 2 -cycloalkyl-Ci-C6-alkyl, where the substituents can be independently selected from halogen, amino, cyano, nitro, hydroxy, Ci-Ce-alkyl, C 3 -C 6 -cycloalkyl, CC 4 -alkoxy, Ci-C 4 -haloalkoxy, CC 4 -alkylthio, C 2 -C 6 -alkoxycarbonyl, Ci-C6-alkylcarbonyl C 3 -C6-cycloalkylamino or a 5- or 6-membered heteroaromatic ring,
R4 für Halogen, Cyano oder Methyl steht, R 4 represents halogen, cyano or methyl,
R5 für Methyl oder Chlor steht, R 5 represents methyl or chlorine,
Z für N, CC1 oder CH steht, Z stands for N, CC1 or CH,
Qy für einen gegebenenfalls einfach oder mehrfach substituierten 5- oder 6-gliedrigen heteroaromatischen Ring der Reihe Q-36 bis Q-40 ,Q43, Q-58 bis Q-59, Q62, Q63, einen aromatisches 9-gliedriges annelliertes heterobicyclisches Ringsystem Q-54 bis Q-56 sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 bis Q-61 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Ci-C3-Alkyl, C C3-Haloalkyl, Ci-C2- Alkoxy, Halogen, Cyano, Hydroxy, Nitro oder C C2-Haloalkoxy, wobei die Verbindungen der Formel (1-1) in Form von Salzen vorliegen können Qy represents an optionally mono- or polysubstituted 5- or 6-membered heteroaromatic ring of the series Q-36 to Q-40, Q43, Q-58 to Q-59, Q62, Q63, an aromatic 9-membered fused heterobicyclic ring system Q- 54 to Q-56 and a 5-membered heterocyclic ring Q-60 to Q-61, where the substituents can be independently selected from Ci-C 3 -alkyl, CC 3 -haloalkyl, Ci-C 2 -alkoxy, Halogen, cyano, hydroxy, nitro or CC 2 -haloalkoxy, whereby the compounds of formula (1-1) can be present in the form of salts
Q-62 Q-63 und ein oder mehrere Fungizide der Gruppe (II). Q-62 Q-63 and one or more group (II) fungicides.
Wirkstoffkombinationen gemäß einem der Ansprüche 1 bis 3 enthaltend eine Mischung von Verbindungen der allgemeinen Formel (I) oder (I-l), in welchen Qy für Q62 und Q63 steht, wobei das Verhältnis einer Verbindung der Formel (I) oder (I-l), in welchen Qy für Q62 steht, zu einer Verbindung der Formel (I) oder (I-l), in welchen Qy für Q63 steht, 80:20 bis 99: 1 beträgt. Active ingredient combinations according to one of claims 1 to 3 containing a mixture of compounds of the general formula (I) or (I-l), in which Qy stands for Q62 and Q63, the ratio of a compound of the formula (I) or (I-l), in which Qy stands for Q62, to a compound of formula (I) or (I-l), in which Qy stands for Q63, is 80:20 to 99: 1.
Wirkstoffkombinationen gemäß einem der Ansprüche 1 bis 3 enthaltend eine Mischung von Verbindungen der allgemeinen Formel (I) oder (I-l) gemäß einem der Ansprüche 1 bis 3, in welchen Qy für Q58 und Q59 steht, wobei das Verhältnis einer Verbindung der Formel (I) oder (I-l), in welchen Qy für Q58 steht, zu einer Verbindung der Formel (I) oder (I-l), in welchen Qy für Q59 steht, 80:20 bis 99: 1 beträgt. Active ingredient combinations according to one of claims 1 to 3 containing a mixture of compounds of the general formula (I) or (I-l) according to one of claims 1 to 3, in which Qy stands for Q58 and Q59, the ratio of a compound of the formula (I) or (I-l), in which Qy represents Q58, to a compound of the formula (I) or (I-l), in which Qy represents Q59, is 80:20 to 99: 1.
Wirkstoffkombinationen gemäß Anspruch 3, dadurch gekennzeichnet, dass Active ingredient combinations according to claim 3, characterized in that
R3 für Wasserstoff oder für jeweils gegebenenfalls einfach oder mehrfach, gleich oder verschieden substituiertes Ci-C6-Alkyl, Ci-C6-Alkoxy, C2-C6-Alkenyl, C2-C6-Alkinyl, C3-C6- Cycloalkyl, C3-C6-Cycloalkyl-Ci-C6-Alkyl steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Halogen, Cyano, Amino, Hydroxy, Ci-Cö-Alkyl, Ci-C4-Alkoxy, Ci-C4-Haloalkoxy, C C4-Alkylthio, C3-C6-Cycloalkyl, einem 5 oder 6- gliedrigen heteroaromatischen Ring enthaltend 1 -2 Heteroatome aus der Reihe N,0, S, wobei nicht zwei Sauerstoffatome im Ring benachbart sind, R 3 for hydrogen or for optionally mono- or polysubstituted, identically or differently substituted Ci-C 6 -alkyl, Ci-C 6 -alkoxy, C 2 -C6-alkenyl, C 2 -C6-alkynyl, C 3 -C 6 - Cycloalkyl, C 3 -C6-cycloalkyl-Ci-C6-alkyl, where the substituents can be independently selected from halogen, cyano, amino, hydroxy, Ci-C ö -alkyl, Ci-C 4 -alkoxy, Ci-C 4 -haloalkoxy, CC 4 -alkylthio, C 3 -C6-cycloalkyl, a 5 or 6- membered heteroaromatic ring containing 1 -2 heteroatoms from the series N, 0, S, where no two oxygen atoms are adjacent in the ring,
R4 für Halogen, Cyano oder Methyl steht, R 4 represents halogen, cyano or methyl,
R5 für Methyl steht, R 5 stands for methyl,
Z für N oder CH steht, Z stands for N or CH,
QY für einen gegebenenfalls einfach oder mehrfach gleich oder verschieden substituierten heteroaromatischen Ring der Reihe Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 und Q63, sowie für ein 5-gliedrigen heterocyclischen Ring Q-60 steht, wobei die Substituenten unabhängig voneinander ausgewählt sein können aus Methyl, Ethyl, cyclo-Propyl, tert- Butyl, Chlor, Fluor, Iod, Brom, Cyano, Nitro, Difluormethyl, Trifluormethyl, Pentafluorethyl., n-Heptafluorpropyl und iso-Heptafluorpropyl. QY for a heteroaromatic ring of the series Q-37, Q-38, Q-39, Q-40, Q43, Q-58, Q-59, Q62 and Q63, which may be substituted once or multiple times in the same or different ways, as well as for a 5- membered heterocyclic ring Q-60, where the substituents can be independently selected from methyl, ethyl, cyclopropyl, tert-butyl, chlorine, fluorine, iodine, bromine, cyano, nitro, difluoromethyl, trifluoromethyl, pentafluoroethyl., n- Heptafluoropropyl and iso-heptafluoropropyl.
Wirkstoffkombinationen gemäß einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass das Verhältnis einer Verbindung der Formel (I) oder (I-l) oder einer Mischung von Verbindungen der Formel (I) oder (I-l) zu einer Verbindung der Gruppe (II) 625: 1 bis 1 :625 beträgt. Active ingredient combinations according to one of claims 1 to 6, characterized in that the ratio of a compound of the formula (I) or (I-l) or a mixture of compounds of the formula (I) or (I-l) to a compound of group (II) is 625: 1 to 1:625.
Wirkstoffkombinationen gemäß einem der Ansprüche 1 bis 7, wobei die Wirkstoffe der Gruppe (II) ausgewählt sind aus der Gruppe bestehend aus Active ingredient combinations according to one of claims 1 to 7, wherein the active ingredients of group (II) are selected from the group consisting of
(1) Inhibitoren der Ergosterol-Biosynthese, wie beispielsweise Aldimorph, Azaconazol, Bitertanol, Bromuconazol, Cyproconazol, Diclobutrazol, Difenoconazol, Diniconazol, Diniconazol-M, Dodemorph, Dodemorph Acetat, Epoxiconazol, Etaconazol, Fenarimol, Fenbuconazol, Fenhexamid, Fenpropidin, Fenpropimorph, Fluquinconazol, Flurprimidol, Flusilazol, Flutriafol, Furconazol, Furconazol-Cis, Hexaconazol, Imazalil, Imazalil Sulfat, Imibenconazol, Ipconazol, Metconazol, Myclobutanil, Naftifin, Nuarimol, Oxpoconazol, Paclobutrazol, Pefurazoat, Penconazol, Piperalin, Prochloraz, Propiconazol, Prothioconazol, Pyributicarb, Pyrifenox, Quinconazol, Simeconazol, Spiroxamin, Tebuconazol, Terbinafin, Tetraconazol, Triadimefon, Tnadimenol, Tndemorph, Triflumizol, Triforin, Triticonazol, Uniconazol, Uniconazol-p, Viniconazol, Voriconazol, l -(4-Chlorphenyl)-2-(lH-l ,2,4-triazol-l - yl)cycloheptanol, Methyl-l-(2,2-dimethyl-2,3-dihydro-lH-inden-l -yl)-lH-imidazol-5-carboxylat, N'-{5-(Difluormethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl} -N-ethyl-N- methylimidoformamid, N-Ethyl-N-methyl-N'-{2-methyl-5-(trifluormethyl)-4-[3- (trimethylsilyl)propoxy]phenyl}imidoformamid und 0-[l -(4-Methoxyphenoxy)-3,3- dimethylbutan-2-yl]-lH-imidazol-l -carbothioat. (2) Inhibitoren der Respiration (Atmungsketten-Inhibitoren), wie beispielsweise Bixafen, Boscalid, Carboxin, Diflumetorim, Fenfuram, Fluopyram, Flutolanil, Fluxapyroxad, Furametpyr, Furmecyclox, Isopyrazam Mischung des syn-epimeren Razemates 1RS,4SR,9RS und des anti- empimeren Razemates 1RS,4SR,9SR, Isopyrazam (anti-epimeres Razemat ), Isopyrazam (anti- epimeres Enantiomer 1R,4S,9S), Isopyrazam (anti-epimeres Enantiomer 1S,4R,9R), Isopyrazam (syn-epimeres Razemat 1RS,4SR,9RS), Isopyrazam (syn-epimeres Enantiomer 1R,4S,9R), Isopyrazam (syn-epimeres Enantiomer 1S,4R,9S), Mepronil, Oxycarboxin, Penflufen, Penthiopyrad, Sedaxane, Thifluzamid, l-Methyl-N-[2-(l, 1,2,2 -tetrafluorethoxy)phenyl]-3- (trifluormethyl)- 1 H-pyrazol-4-carboxamid, 3-(Difluormethyl)- 1 -methyl-N-[2-( 1 , 1 ,2,2- tetrafluorethoxy)phenyl] -1 H-pyrazol-4-carboxamid, 3-(Difluormethyl)-N-[4-fluor-2-( 1,1 ,2,3,3,3- hexafluorpropoxy)phenyl]-l-methyl-lH-pyrazol-4-carboxamid und N-[l-(2,4-Dichlorphenyl)-l- methoxypropan-2-yl] -3 -(difluormethyl)- 1 -methyl- 1 H-pyrazol-4-carboxamid. (1) Inhibitors of ergosterol biosynthesis, such as Aldimorph, Azaconazole, Bitertanol, Bromuconazole, Cyproconazole, Diclobutrazol, Difenoconazole, Diniconazole, Diniconazole-M, Dodemorph, Dodemorph Acetate, Epoxiconazole, Etaconazole, Fenarimol, Fenbuconazole, Fenhexamid, Fenpropidine, Fenpropimorph, Fluquinconazole, Flurprimidol, Flusilazole, Flutriafol, Furconazole, Furconazole-Cis, Hexaconazole, Imazalil, Imazalil Sulfate, Imibenconazole, Ipconazole, Metconazole, Myclobutanil, Naftifin, Nuarimol, Oxpoconazole, Paclobutrazol, Pefurazoate, Penconazole, Piperaline, Prochloraz, Propiconazole, Prothioconazole, Pyributic arb , Pyrifenox, Quinconazole, Simeconazole, Spiroxamine, Tebuconazole, Terbinafine, Tetraconazole, Triadimefon, Tnadimenol, Tndemorph, Triflumizole, Triforin, Triticonazole, Uniconazole, Uniconazole-p, Viniconazole, Voriconazole, l -(4-chlorophenyl)-2-(lH- l,2,4-triazol-l - yl)cycloheptanol, methyl l-(2,2-dimethyl-2,3-dihydro-lH-inden-l -yl)-lH-imidazole-5-carboxylate, N' -{5-(Difluoromethyl)-2-methyl-4-[3-(trimethylsilyl)propoxy]phenyl} -N-ethyl-N-methylimidoformamide, N-ethyl-N-methyl-N'-{2-methyl-5 -(trifluoromethyl)-4-[3-(trimethylsilyl)propoxy]phenyl}imidoformamide and 0-[l-(4-methoxyphenoxy)-3,3-dimethylbutan-2-yl]-lH-imidazole-l-carbothioate. (2) Inhibitors of respiration (respiratory chain inhibitors), such as Bixafen, Boscalid, Carboxin, Diflumetorim, Fenfuram, Fluopyram, Flutolanil, Fluxapyroxad, Furametpyr, Furmecyclox, Isopyrazam Mixture of the syn-epimeric racemate 1RS,4SR,9RS and the anti- empimeren racemates 1RS,4SR,9SR, isopyrazam (anti-epimeric racemate), isopyrazam (anti-epimeric enantiomer 1R,4S,9S), isopyrazam (anti-epimeric enantiomer 1S,4R,9R), isopyrazam (syn-epimeric racemate 1RS, 4SR,9RS), isopyrazam (syn-epimeric enantiomer 1R,4S,9R), isopyrazam (syn-epimeric enantiomer 1S,4R,9S), mepronil, oxycarboxin, penflufen, penthiopyrad, sedaxane, thifluzamide, l-methyl-N-[ 2-(l, 1,2,2 -tetrafluoroethoxy)phenyl]-3-(trifluoromethyl)- 1H-pyrazole-4-carboxamide, 3-(difluoromethyl)- 1 -methyl-N-[2-( 1 , 1 ,2,2-tetrafluorethoxy)phenyl] -1 H-pyrazole-4-carboxamide, 3-(difluoromethyl)-N-[4-fluoro-2-(1,1,2,3,3,3-hexafluoropropoxy)phenyl ]-l-methyl-lH-pyrazole-4-carboxamide and N-[l-(2,4-dichlorophenyl)-l-methoxypropan-2-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole -4-carboxamide.
(3) Inhibitoren der Respiration (Atmungsketten-Inhibitoren) am Komplex III der Atumungskette, wie beispielsweise Ametoctradin, Amisulbrom, Azoxystrobin, Cyazofamid, Dimoxystrobin, Enestroburin, Famoxadon, Fenamidon, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyrametostrobin, Pyraoxystrobin, Pyribencarb, Trifloxystrobin, (2E)-2-(2-{[6-(3-Chlor-2-methylphenoxy)-5-fluorpyrimidin-4-yl]oxy}phenyl)-2- (methoxyimino)-N-methylethanamid, (2E)-2-(Methoxyimino)-N-methyl-2-(2- { [( {( 1 E)- 1 -[3 - (trifluormethyl)phenyl]ethyliden}amino)oxy]methyl}phenyl)ethanamid, (2E)-2-(Methoxyimino)- N-methyl-2-{2-[(E)-({l-[3-(trifluormethyl)phenyl]ethoxy}imino)methyl]phenyl}ethanamid, (2E)-(3) Inhibitors of respiration (respiratory chain inhibitors) on complex III of the respiratory chain, such as ametoctradine, amisulbrom, azoxystrobin, cyazofamid, dimoxystrobin, enestroburin, famoxadone, fenamidone, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametos trobin , pyraoxystrobin, pyribencarb, trifloxystrobin, (2E)-2-(2-{[6-(3-chloro-2-methylphenoxy)-5-fluoropyrimidin-4-yl]oxy}phenyl)-2-(methoxyimino)-N -methylethanamide, (2E)-2-(methoxyimino)-N-methyl-2-(2- { [( {( 1 E)- 1 -[3 - (trifluoromethyl)phenyl]ethylidene}amino)oxy]methyl}phenyl )ethanamide, (2E)-2-(methoxyimino)- N-methyl-2-{2-[(E)-({l-[3-(trifluoromethyl)phenyl]ethoxy}imino)methyl]phenyl}ethanamide, ( 2E)-
2- {2-[({[(lE)-l-(3-{[(E)-l-Fluor-2- phenylethenyl] oxy } phenyl)ethyliden] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N- methylethanamid, (2E)-2-{2-[({[(2E,3E)-4-(2,6-Dichlorphenyl)but-3-en-2- yliden] amino } oxy)methyl]phenyl} -2-(methoxyimino)-N-methylethanamid, 2-Chlor-N-( 1,1,3- trimethyl-2,3-dihydro- 1 H-inden-4-yl)pyridin-3 -carboxamid, 5-Methoxy-2-methyl-4-(2- {[({(IE)- 1 -[3-(trifluormethyl)phenyl]ethyliden} amino)oxy]methyl}phenyl)-2,4-dihydro-3H-l ,2,4-triazol-2- {2-[({[(lE)-l-(3-{[(E)-l-fluoro-2-phenylethenyl] oxy } phenyl)ethylidene] amino } oxy)methyl]phenyl} -2-( methoxyimino)-N-methylethanamide, (2E)-2-{2-[({[(2E,3E)-4-(2,6-dichlorophenyl)but-3-en-2-ylidene]amino}oxy)methyl ]phenyl} -2-(methoxyimino)-N-methylethanamide, 2-chloro-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)pyridine-3-carboxamide, 5-Methoxy-2-methyl-4-(2- {[({(IE)- 1 -[3-(trifluoromethyl)phenyl]ethylidene} amino)oxy]methyl}phenyl)-2,4-dihydro-3H- l,2,4-triazole
3- on, Methyl-(2E)-2-{2-[({cyclopropyl[(4- methoxyphenyl)imino]methyl} sulfanyl)methyl]phenyl} -3-methoxyprop-2-enoat, N-(3-Ethyl- 3,5,5-trimethylcyclohexyl)-3-(formylamino)-2-hydroxybenzamid, 2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid und (2R)-2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl } -2-methoxy-N-methylacetamid. 3-one, Methyl-(2E)-2-{2-[({cyclopropyl[(4-methoxyphenyl)imino]methyl} sulfanyl)methyl]phenyl} -3-methoxyprop-2-enoate, N-(3-Ethyl - 3,5,5-trimethylcyclohexyl)-3-(formylamino)-2-hydroxybenzamide, 2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide and (2R)- 2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide.
(4) Inhibitoren der Mitose und Zellteilung, wie beispielsweise Benomyl, Carbendazim, Chlorfenazol, Diethofencarb, Ethaboxam, Fluopicolid, Fuberidazol, Pencycuron, Thiabendazol, Thiophanat-Methyl, Thiophanat, Zoxamid, 5-Chlor-7-(4-methylpiperidin-l-yl)-6-(2,4,6- trifluorphenyl)[l,2,4]triazolo[l,5-a]pyrimidin und 3-Chlor-5-(6-chlorpyridin-3-yl)-6-methyl-4- (2,4,6-trifluorphenyl)pyridazin. (4) Inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fluopicolide, fuberidazole, pencycuron, thiabendazole, thiophanate-methyl, thiophanate, zoxamid, 5-chloro-7-(4-methylpiperidine-l- yl)-6-(2,4,6-trifluorophenyl)[l,2,4]triazolo[l,5-a]pyrimidine and 3-chloro-5-(6-chloropyridin-3-yl)-6-methyl -4- (2,4,6-trifluorophenyl)pyridazine.
(5) Verbindungen mit Multisite-Aktivität, wie beispielsweise Bordeauxmischung, Captafol, Captan, Chlorothalonil, Kupferzubereitungen wie Kupferhydroxid, Kupfernaphthenat, Kupferoxid, Kupferoxychlorid, Kupfersulfat, Dichlofluanid, Dithianon, Dodine, Dodine freie Base, Ferbam, Fluorofolpet, Folpet, Guazatin, Guazatinacetat, Iminoctadin, Iminoctadinalbesilat, Iminoctadintriacetat, Mankupfer, Mancozeb, Maneb, Metiram, Zinkmetiram, Kupfer-Oxin, Propamidin, Propineb, Schwefel und Schwefelzubereitungen wie beispielsweise Calciumpolysulfid, Thiram, Tolylfluanid, Zineb und Ziram. (5) Compounds with multisite activity such as Bordeaux mixture, captafol, captan, chlorothalonil, copper preparations such as copper hydroxide, copper naphthenate, copper oxide, copper oxychloride, copper sulfate, dichlofluanid, dithianone, dodine, dodine free base, ferbam, fluorofolpet, folpet, guazatin, guazatin acetate , iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram.
(6) Resistenzinduktoren, wie beispielsweise Acibenzolar-S-Methyl, Isotianil, Probenazol und Tiadinil. (6) Resistance inducers such as acibenzolar-S-methyl, isotianil, probeazole and tiadinil.
(7) Inhibitoren der Aminosäure- und Protein-Biosynthese, wie beispielsweise Andoprim, Blasticidin-S, Cyprodinil, Kasugamycin, Kasugamycin Hydrochlorid Hydrat, Mepanipyrim und Pyrimethanil. (7) Inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil.
(8) Inhibitoren der ATP Produktion, wie beispielsweise Fentin Acetat, Fentin Chlorid, Fentin Hydroxid und Silthiofam. (8) Inhibitors of ATP production, such as fentin acetate, fentin chloride, fentin hydroxide and silthiofam.
(9) Inhibitoren der Zellwandsynthese, wie beispielsweise Benthiavalicarb, Dimethomorph, Flumorph, Iprovalicarb, Mandipropamid, Polyoxins, Polyoxorim, Validamycin A und Valifenalat. (9) Inhibitors of cell wall synthesis, such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamid, polyoxins, polyoxorim, validamycin A and valifenalate.
(10) Inhibitoren der Lipid- und Membran-Synthese, wie beispielsweise Biphenyl, Chloroneb, Dicloran, Edifenphos, Etridiazol, Iodocarb, Iprobenfos, Isoprothiolan, Propamocarb, Propamocarb Hydrochlorid, Prothiocarb, Pyrazophos, Quintozen, Tecnazene und Tolclofos- Methyl. (10) Inhibitors of lipid and membrane synthesis, such as biphenyl, chloroneb, dicloran, edifenphos, etridiazole, iodocarb, iprobefos, isoprothiolane, propamocarb, propamocarb hydrochloride, prothiocarb, pyrazophos, quintozene, tecnazene and tolclofos-methyl.
(11) Inhibitoren der Melanin -Biosynthese, wie beispielsweise Carpropamid, Diclocymet, Fenoxanil, Phthalid, Pyroquilon und Tricyclazol. (11) Inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, phthalide, pyroquilon and tricyclazole.
(12) Inhibitoren der Nukleinsäuresynthese, wie beispielsweise Benalaxyl, Benalaxyl-M (Kiralaxyl), Bupirimat, Clozylacon, Dimethirimol, Ethirimol, Furalaxyl, Hymexazol, Metalaxyl, Metalaxyl-M (Mefenoxam), Ofurace, Oxadixyl, Oxolinsäure. (12) Inhibitors of nucleic acid synthesis, such as Benalaxyl, Benalaxyl-M (Kiralaxyl), Bupirimate, Clozylacone, Dimethirimol, Ethirimol, Furalaxyl, Hymexazole, Metalaxyl, Metalaxyl-M (Mefenoxam), Ofurace, Oxadixyl, Oxolinic acid.
(13) Inhibitoren der Signaltransduktion, wie beispielsweise Chlozolinat, Fenpiclonil, Fludioxonil, Iprodion, Procymidon, Quinoxyfen und Vinclozolin. (13) Signal transduction inhibitors such as chlozolinate, fenpiclonil, fludioxonil, iprodione, procymidone, quinoxyfen and vinclozolin.
(14) Entkoppler, wie beispielsweise Binapacryl, Dinocap, Ferimzon, Fluazinam und Meptyldinocap. (14) Decouplers such as Binapacryl, Dinocap, Ferimzon, Fluazinam and Meptyldinocap.
(15) Weitere Verbindungen, wie beispielsweise Benthiazol, Bethoxazin, Capsimycin, Carvon, Chinomethionat, Chlazafenon, Cufraneb, Cyflufenamid, Cymoxanil, Cyprosulfamide, Dazomet, Debacarb, Dichlorophen, Diclomezin, Difenzoquat, Difenzoquat Methylsulphat, Diphenylamin, Ecomat, Fenpyrazamin, Flumetover, Fluoromid, Flusulfamid, Flutianil, Fosetyl-Aluminium, Fosetyl-Calcium, Fosetyl-Natrium, Hexachlorbenzol, Irumamycin, Methasulfocarb, Methylisothiocyanat, Metrafenon, Mildiomycin, Natamycin, Nickel Dimethyldithiocarbamat, Nitrothal-Isopropyl, Octhilinone, Oxamocarb, Oxyfenthiin, Pentachlorphenol und dessen Salze, Phenothrin, Phosphorsäure und deren Salze, Propamocarb-Fosetylat, Propanosin-Natrium, Proquinazid, Pyrrolnitrin, Tebufloquin, Tecloftalam, Tolnifanid, Triazoxid, Trichlamid, Zarilamid, l-(4-{4-[(5R)-5-(2,6-Difluorphenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2- yl}piperidin-l-yl)-2-[5-methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]ethanon, l-(4-{4-[(5S)-5-(2,6- Difluorphenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3- (trifluormethyl)-lH-pyrazol-l-yl]ethanon, l-(4-{4-[5-(2,6-Difluorphenyl)-4,5-dihydro-l,2-oxazol- 3-yl]-l ,3-thiazol-2-yl}piperidin-l -yl)-2-[5-methyl-3-(trifluormethyl)-lH-pyrazol-l -yljethanon, 1 - (4-Methoxyphenoxy)-3,3-dimethylbutan-2-yl-lH-imidazol-l-carboxylat, 2,3,5,6-Tetrachlor-4- (methylsulfonyl)pyridin, 2,3-Dibutyl-6-chlorthieno[2,3-d]pyrimidin-4(3H)-on, 2-[5-Methyl-3- (trifluormethyl)-lH-pyrazol-l-yl]-l-(4-{4-[(5R)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3- thiazol-2-yl}piperidin-l-yl)ethanon, 2-[5-Methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]-l-(4-{4- [(5S)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanon, 2-[5- Methyl-3-(trifluormethyl)-lH-pyrazol-l-yl]-l-{4-[4-(5-phenyl-4,5-dihydro-l,2-oxazol-3-yl)-l,3- thiazol-2-yl]piperidin-l-yl}ethanon, 2-Butoxy-6-iod-3-propyl-4H-chromen-4-on, 2-Chlor-5-[2- chlor-1 -(2,6-difluor-4-methoxyphenyl)-4-methyl-lH-imidazol-5-yl]pyridin, 2-Phenylphenol und dessen Salze, 3,4,5-Trichlorpyridin-2,6-dicarbonitril, 3-[5-(4-Chlorphenyl)-2,3-dimethyl-l,2- oxazolidin-3-yl]pyridin, 3-Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6-methylpyridazin, 4- (4-Chlorphenyl)-5-(2,6-difluorphenyl)-3,6-dimethylpyridazin, 5-Amino-l,3,4-thiadiazol-2-thiol, 5-Chlor-N'-phenyl-N'-(prop-2-in-l-yl)thiophen-2-sulfonohydrazid, 5-Methyl-6- octyl[l ,2,4]triazolo[l ,5-a]pyrimidin-7-amin, Ethyl-(2Z)-3-amino-2-cyan-3-phenylprop-2-enoat, N-(4-Chlorbenzyl)-3-[3-methoxy-4-(prop-2-in-l-yloxy)phenyl]propanamid, N-[(4- Chlorphenyl)(cyan)methyl]-3-[3-methoxy-4-(prop-2-in-l-yloxy)phenyl]propanamid, N-[(5-Brom- 3-chlorpyridin-2-yl)methyl]-2,4-dichlorpyridin-3-carboxamid, N-[l-(5-Brom-3-chlorpyridin-2- yl)ethyl]-2,4-dichlorpyridin-3-carboxamid, N-[l-(5-Brom-3-chlorpyridin-2-yl)ethyl]-2-fluor-4- iodpyridin-3-carboxamid, N-{(E)-[(Cyclopropylmethoxy)imino][6-(difluormethoxy)-2,3- difluorphenyljmethyl} -2-phenylacetamid, N- {(Z)-[(Cyclopropylmethoxy)imino] [6-(15) Other compounds, such as benthiazole, bethoxazine, capsimycin, carvone, quinomethionate, chlazafenone, cufraneb, cyflufenamide, cymoxanil, cyprosulfamide, dazomet, debacarb, dichlorophene, diclomezin, difenzoquat, difenzoquat methyl sulfate, diphenylamine, ecomat, fenpyrazamine, flumetover, fluoromid , Flusulfamide, Flutianil, Fosetyl Aluminum, Fosetyl Calcium, Fosetyl Sodium, Hexachlorobenzene, Irumamycin, Methasulfocarb, Methyl Isothiocyanate, Metrafenone, Mildiomycin, Natamycin, Nickel Dimethyldithiocarbamate, Nitrothal Isopropyl, Octhilinone, Oxamocarb, Oxyfenthiine, Pentachlorophenol and its salts, Ph enothrin , phosphoric acid and its salts, propamocarb fosetylate, propanosine sodium, proquinazide, pyrrolnitrin, tebufloquine, tecloftalam, tolnifanide, triazoxide, trichlamide, zarilamide, l-(4-{4-[(5R)-5-(2,6- Difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(trifluoromethyl)- lH-pyrazol-l-yl]ethanone, l-(4-{4-[(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]- l,3-thiazol-2-yl}piperidin-l-yl)-2-[5-methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]ethanone, l-(4-{4-[5 -(2,6-Difluorophenyl)-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l -yl)-2-[5-methyl- 3-(trifluoromethyl)-lH-pyrazole-l-yljethanone, 1-(4-methoxyphenoxy)-3,3-dimethylbutan-2-yl-lH-imidazole-l-carboxylate, 2,3,5,6-tetrachloro- 4-(methylsulfonyl)pyridine, 2,3-dibutyl-6-chlorothieno[2,3-d]pyrimidin-4(3H)-one, 2-[5-methyl-3-(trifluoromethyl)-lH-pyrazole-l -yl]-l-(4-{4-[(5R)-5-phenyl-4,5-dihydro-l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidine- l-yl)ethanone, 2-[5-methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl]-l-(4-{4-[(5S)-5-phenyl-4,5-dihydro -l,2-oxazol-3-yl]-l,3-thiazol-2-yl}piperidin-l-yl)ethanone, 2-[5-methyl-3-(trifluoromethyl)-lH-pyrazol-l-yl ]-l-{4-[4-(5-phenyl-4,5-dihydro-l,2-oxazol-3-yl)-l,3-thiazol-2-yl]piperidin-l-yl}ethanone, 2-Butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-chloro-5-[2-chloro-1-(2,6-difluoro-4-methoxyphenyl)-4-methyl-lH -imidazol-5-yl]pyridine, 2-phenylphenol and its salts, 3,4,5-trichloropyridine-2,6-dicarbonitrile, 3-[5-(4-chlorophenyl)-2,3-dimethyl-1,2 - oxazolidin-3-yl]pyridine, 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6-methylpyridazine, 4-(4-chlorophenyl)-5-(2,6- difluorophenyl)-3,6-dimethylpyridazine, 5-amino-l,3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N'-(prop-2-yn-l-yl)thiophene 2-sulfonohydrazide, 5-methyl-6-octyl[l,2,4]triazolo[l,5-a]pyrimidine-7-amine, ethyl-(2Z)-3-amino-2-cyano-3-phenylprop- 2-enoate, N-(4-chlorobenzyl)-3-[3-methoxy-4-(prop-2-yn-l-yloxy)phenyl]propanamide, N-[(4-chlorophenyl)(cyano)methyl]- 3-[3-methoxy-4-(prop-2-yn-l-yloxy)phenyl]propanamide, N-[(5-bromo-3-chloropyridin-2-yl)methyl]-2,4-dichloropyridine-3 -carboxamide, N-[l-(5-bromo-3-chloropyridin-2-yl)ethyl]-2,4-dichloropyridine-3-carboxamide, N-[l-(5-bromo-3-chloropyridine-2- yl)ethyl]-2-fluoro-4-iodopyridine-3-carboxamide, N-{(E)-[(cyclopropylmethoxy)imino][6-(difluoromethoxy)-2,3-difluorophenyljmethyl}-2-phenylacetamide, N- {(Z)-[(Cyclopropylmethoxy)imino] [6-
(difluormethoxy)-2,3 -difluorphenyljmethyl } -2-phenylacetamid, N-Methyl-2-( 1 - { [5-methyl-3 - (trifluormethyl)- 1 H-pyrazol-1 -yl] acetyl} piperidin-4-yl)-N-( 1 ,2,3 ,4-tetrahydronaphthalen- 1 -yl)- 1 ,3-thiazol-4-carboxamid, N-Methyl-2-( 1 - { [5-methyl-3 -(trifluormethyl)- 1 H-pyrazol- 1 yl] acetyl }piperidin-4-yl)-N-[( 1 R)-l ,2,3 ,4-tetrahydronaphthalen-l -yl]- 1 ,3 -thiazol-4-carboxamid, N-Methyl-2-( 1 - { [5-methyl-3 -(trifluormethyl)-l H-pyrazol- 1 -yl] acetyl} piperidin-4-yl)-N-[( 1 S)- 1 ,2,3 ,4-tetrahydronaphthalen- 1 -yl]- 1 ,3 -thiazol-4-carboxamid, Pentyl- {6-[( { [( 1 -methyl- 1 H te1razol-5-yl)(phenyl)methyliden]amino}oxy)methyl]pyridin-2-yl}carbarriat, Phenazin-1 carbonsäure, Chinolin-8-ol und Chinolin-8-olsulfat(2: l). (difluoromethoxy)-2,3-difluorophenyljmethyl } -2-phenylacetamide, N-methyl-2-( 1 - { [5-methyl-3 - (trifluoromethyl)- 1 H-pyrazol-1 -yl] acetyl} piperidine-4 -yl)-N-(1,2,3,4-tetrahydronaphthalen-1-yl)- 1,3-thiazol-4-carboxamide, N-Methyl-2-( 1 - { [5-methyl-3 -(trifluoromethyl)- 1 H-pyrazol- 1 yl] acetyl }piperidin-4-yl)-N- [( 1 R)-l ,2,3 ,4-tetrahydronaphthalen-l -yl]- 1 ,3 -thiazole-4-carboxamide, N-methyl-2-( 1 - { [5-methyl-3 -(trifluoromethyl )-l H-pyrazol-1-yl]acetyl}piperidin-4-yl)-N-[(1S)-1,2,3,4-tetrahydronaphthalen-1-yl]-1,3-thiazol-4 -carboxamide, pentyl- {6-[( { [( 1 -methyl- 1 H te1razol-5-yl)(phenyl)methylidene]amino}oxy)methyl]pyridin-2-yl}carbarriate, phenazine-1 carboxylic acid, quinoline -8-ol and quinoline-8-ol sulfate(2:l).
(16) Weitere Verbindungen, wie beispielsweise l-Methyl-3-(trifluormethyl)-N-[2'- (1rifluormethyl)biphenyl-2-yl]-lH-pyrazol-4-carboxarnid, N-(4'-Chlorbiphenyl-2-yl)-3- (difluormethyl)-l-methyl-lH-pyrazol-4-carboxamid, N-(2',4'-Dichlorbiphenyl-2-yl)-3- (difluormethyl)-l-methyl-lH-pyrazol-4-carboxamid, 3-(Difluormethyl)-l -methyl -N-[4'- (trifluormethyl)biphenyl-2-yl]-lH-pyrazol-4-carboxamid, N-(2',5'-Difluorbiphenyl-2-yl)-l- methyl-3-(trifluormethyl)-lH-pyrazol-4-carboxamid, 3-(Difluormethyl)-l-methyl-N-[4'-(prop-l- in- 1 -yl)biphenyl-2-yl]- 1 H-pyrazol-4-carboxamid, 5-Fluor- 1 ,3-dimethyl-N-[4'-(prop- 1 -in- 1 - yl)biphenyl-2-yl]-l H-pyrazol -4-carboxamid, 2-Chlor-N-[4'-(prop-l-in-l-yl)biphenyl-2-yl]pyridin- 3 -carboxamid, 3 -(Difluormethyl)-N-[4'-(3,3 -dimethylbut- 1 -in- 1 -yl)biphenyl-2-yl]- 1 -methyl-1 H- pyrazol-4-carboxamid, N-[4'-(3,3-Dimethylbut-l-in-l-yl)biphenyl-2-yl]-5-fluor-l,3-dimethyl-lH- pyrazol-4-carboxamid, 3-(Difluormethyl)-N-(4'-ethinylbiphenyl-2-yl)-l-methyl-lH-pyrazol-4- carboxamid, N-(4'-Ethinylbiphenyl-2-yl)-5-fluor-l,3-dimethyl-l H-pyrazol -4-carboxamid, 2- Chlor-N-(4'-ethinylbiphenyl-2-yl)pyridin-3-carboxamid, 2-Chlor-N-[4'-(3,3-dimethylbut-l-in-l- yl)biphenyl-2-yl]pyridin-3-carboxamid, 4-(Difluormethyl)-2-methyl-N-[4'- (trifluormethyl)biphenyl-2-yl]-l,3-thiazol-5-carboxamid, 5-Fluor-N-[4'-(3-hydroxy-3-methylbut- 1 -in- 1 -yl)biphenyl-2-yl]- 1 ,3 -dimethyl- 1 H-pyrazol-4-carboxamid, 2-Chlor-N-[4'-(3-hydroxy-3 - methylbut-l-in-l-yl)biphenyl-2-yl]pyridin-3-carboxamid, 3-(Difluormethyl)-N-[4'-(3-methoxy-3- methylbut- 1 -in- 1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H-pyrazol -4-carboxamid, 5 -Fluor-N- [4'-(3 - methoxy-3 -methylbut- 1 -in- 1 -yl)biphenyl-2-yl]- 1 ,3 -dimethyl- 1 H-pyrazol-4-carboxamid, 2-Chlor- N-[4'-(3-methoxy-3-methylbut-l -in-1 -yl)biphenyl-2-yl]pyridin-3-carboxamid, (5-Brom-2- methoxy-4-methylpyridin-3-yl)(2,3,4-trimethoxy-6-methylphenyl)methanon und N-[2-(4-{[3-(4- Chlorphenyl)prop-2-in-l-yl]oxy}-3-methoxyphenyl)ethyl]-N2-(methylsulfonyl)valinamid. (16) Other compounds, such as l-methyl-3-(trifluoromethyl)-N-[2'-(1rifluoromethyl)biphenyl-2-yl]-lH-pyrazole-4-carboxarnide, N-(4'-chlorobiphenyl- 2-yl)-3-(difluoromethyl)-l-methyl-lH-pyrazole-4-carboxamide, N-(2',4'-dichlorobiphenyl-2-yl)-3-(difluoromethyl)-l-methyl-lH -pyrazole-4-carboxamide, 3-(difluoromethyl)-l -methyl -N-[4'-(trifluoromethyl)biphenyl-2-yl]-lH-pyrazole-4-carboxamide, N-(2',5'- Difluorobiphenyl-2-yl)-l-methyl-3-(trifluoromethyl)-lH-pyrazole-4-carboxamide, 3-(difluoromethyl)-l-methyl-N-[4'-(prop-l-in- 1 - yl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide, 5-fluoro-1,3-dimethyl-N-[4'-(prop-1-yn-1-yl)biphenyl-2-yl ]-l H-pyrazole -4-carboxamide, 2-chloro-N-[4'-(prop-l-yn-l-yl)biphenyl-2-yl]pyridin- 3 -carboxamide, 3 -(difluoromethyl)- N-[4'-(3,3-dimethylbut-1-yn-1-yl)biphenyl-2-yl]-1-methyl-1H-pyrazole-4-carboxamide, N-[4'-(3, 3-Dimethylbut-l-yn-l-yl)biphenyl-2-yl]-5-fluoro-l,3-dimethyl-lH-pyrazole-4-carboxamide, 3-(difluoromethyl)-N-(4'-ethynylbiphenyl -2-yl)-l-methyl-lH-pyrazole-4-carboxamide, N-(4'-ethynylbiphenyl-2-yl)-5-fluoro-l,3-dimethyl-l H-pyrazole -4-carboxamide, 2-Chloro-N-(4'-ethynylbiphenyl-2-yl)pyridine-3-carboxamide, 2-chloro-N-[4'-(3,3-dimethylbut-l-yn-l-yl)biphenyl-2 -yl]pyridine-3-carboxamide, 4-(difluoromethyl)-2-methyl-N-[4'-(trifluoromethyl)biphenyl-2-yl]-l,3-thiazole-5-carboxamide, 5-fluoro-N -[4'-(3-hydroxy-3-methylbut-1-yn-1-yl)biphenyl-2-yl]-1,3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4'-(3-hydroxy-3-methylbut-l-yn-l-yl)biphenyl-2-yl]pyridine-3-carboxamide, 3-(difluoromethyl)-N-[4'-(3-methoxy- 3-methylbut- 1 -yn- 1 -yl)biphenyl-2-yl] - 1 -methyl- 1 H-pyrazole -4-carboxamide, 5 -fluoro-N- [4'-(3 - methoxy-3 -methylbut - 1 -yn- 1 -yl)biphenyl-2-yl]- 1,3 -dimethyl- 1 H-pyrazole-4-carboxamide, 2-chloro- N-[4'-(3-methoxy-3-methylbut- l -in-1 -yl)biphenyl-2-yl]pyridine-3-carboxamide, (5-bromo-2-methoxy-4-methylpyridin-3-yl)(2,3,4-trimethoxy-6-methylphenyl) methanone and N-[2-(4-{[3-(4-chlorophenyl)prop-2-yn-l-yl]oxy}-3-methoxyphenyl)ethyl]-N2-(methylsulfonyl)valinamide.
9. Wirkstoffkombinationen gemäß einem der Ansprüche 1 bis 8, wobei die Wirkstoffe der Gruppe (II) ausgewählt sind aus der Gruppe bestehend aus: 9. Active ingredient combinations according to one of claims 1 to 8, wherein the active ingredients of group (II) are selected from the group consisting of:
Bitertanol Bitertanol
Bixafen Bixafen
Carpropamid Carpropamide
Fenamidone Fluopicolide Fenamidones Fluopicolide
FluopyramFluopyram
FluoxastrobinFluoxastrobin
FluquinconazolFluquinconazole
IsotianilIsotianil
MetominostrobinMetominostrobin
PencycuronPencycuron
PenflufenPenflufen
ProchlorazProchloraz
PropamocarbPropamocarb
PropinebPropineb
ProthioconazolProthioconazole
SpiroxamineSpiroxamine
TebuconazolTebuconazole
TriadimenolTriadimenol
TriazoxideTriazoxides
TrifloxystrobinTrifloxystrobin
AmetoctradinAmetoctradine
AzoxystrobinAzoxystrobin
BenthiavalicarbBenthiavalicarb
BoscalidBoscalid
CarbendazimCarbendazim
CarboxinCarboxine
ChlorothalonilChlorothalonil
CymoxanilCymoxanil
CyproconazolCyproconazole
CyprodinilCyprodinil
CyzofamidCyzofamide
DifenoconazoleDifenoconazole
DimoxystrobinDimoxystrobin
EpoxiconazolEpoxiconazole
FenpropidinFenpropidine
FerimzoneFerim zone
FluazinamFluazinam
FludioxonilFludioxonil
FlutolanilFlutolanil
Flutriafol FluxapyroxadFlutriafol Fluxapyroxad
GentamycinGentamycin
HymexazolHymexazole
Imazalil Imazalil
Ipconazol Ipconazole
Isoprothiolane Isoprothiolanes
IsopyrazamIsopyrazam
KasugamycinKasugamycin
Mancozeb Mancozeb
Mandipropamid Mandipropamide
Maneb Maneb
Mefenoxam Mefenoxam
MetalaxylMetalaxyl
MetconazoleMetconazole
MetrafenoneMetrafenone
OrysastrobinOrysastrobin
PenthiopyradPenthiopyrad
PicoxystrobinPicoxystrobin
ProbenazoleSample azoles
PropiconazolePropiconazole
ProquinazidProquinazide
PyraclostrobinPyraclostrobin
PyrimethanilPyrimethanil
PyroquilonPyroquilone
QuinoxyfenQuinoxyfen
Sedaxane Sedaxane
Tetraconazole Tetraconazole
Thiophanate-methylThiophanate-methyl
Thiram Thiram
Tolclofos-methyl Tolclofos-methyl
TricyclazoleTricyclazoles
TriticonazolTriticonazole
ValidamycinValidamycin
Fosetyl-Aluminium Fosetyl aluminum
10. Wirkstoffkombinationen gemäß einem der Ansprüche 1 bis 9, wobei die Verbindungen der Formel (I-l) ausgewählt sind aus der Gruppe bestehend aus den Verbindungen (I-l-l) bis (1-1- 60). 10. Active ingredient combinations according to one of claims 1 to 9, wherein the compounds of the formula (I-l) are selected from the group consisting of the compounds (I-l-l) to (1-1-60).
11. Wirkstoffkombinationen gemäß einem der Anspräche 4 oder 5, wobei die Mischungen von Verbindungen der Formel (I-l) ausgewählt sind aus der Gruppe bestehend aus 11. Active ingredient combinations according to one of claims 4 or 5, wherein the mixtures of compounds of the formula (I-l) are selected from the group consisting of
-1-1-/1-1-7, -1-1-/1-1-7,
-1-2/ 1-1-8, -1-2/ 1-1-8,
-1-3/1-1-9, -1-3/1-1-9,
.1-4/1-1-10, 1-1-5/1-1-11, .1-4/1-1-10, 1-1-5/1-1-11,
1-6/1-1-12, 1-6/1-1-12,
1-13/1-1-1-19, 1-13/1-1-1-19,
.1-14/1-1-20, 1-15/1-1-21, I-1-16/I-1-22, 1-17/1-1-23, 1-18/1-1-24, -1-25/1-1-31, -1-26/1-1-32, 1-1-27/ 1-1-33, .1-14/1-1-20, 1-15/1-1-21, I-1-16/I-1-22, 1-17/1-1-23, 1-18/1-1 -24, -1-25/1-1-31, -1-26/1-1-32, 1-1-27/ 1-1-33,
-1-28/1-1-34, -1-29/1-1-35, -1-30/1-1-36, -1-28/1-1-34, -1-29/1-1-35, -1-30/1-1-36,
1-37/1-1-43, 1-1-38/1-1-44, I-1-39/I-1-45, 1-1 -40/1-1 -46, I_l_41/I_l_47, 1-37/1-1-43, 1-1-38/1-1-44, I-1-39/I-1-45, 1-1 -40/1-1 -46, I_l_41/I_l_47,
1-1 -42/1-1 -48, I-1-49/I-1-55, 1-1 -50/1-1 -56, I-1-51/I-1-57, 1-1 -52/1-1 -58, I-1-53/I-1-59, 1-1 -54/1-1 -60. 1-1 -42/1-1 -48, I-1-49/I-1-55, 1-1 -50/1-1 -56, I-1-51/I-1-57, 1- 1 -52/1-1 -58, I-1-53/I-1-59, 1-1 -54/1-1 -60.
12. Agrochemische Zusammensetzung enthaltend Wirkstoffkombinationen gemäß einem der 12. Agrochemical composition containing combinations of active ingredients according to one of the
Ansprüche 1-11, sowie Streckmittel und/oder oberflächenaktive Stoffe. Claims 1-11, as well as extenders and/or surface-active substances.
13. Verwendung von Wirkstoffkombinationen gemäß einem der Ansprüche 1-11 oder einer Zusammensetzung gemäß Anspruch 12 zur Bekämpfung tierischer Schädlinge, phytopathogener Pilze, sowie zur Behandlung von Saatgut. 13. Use of active ingredient combinations according to any one of claims 1-11 or a composition according to claim 12 for combating animal pests, phytopathogenic fungi, and for treating seeds.
14. Verfahren zur Bekämpfung tierischer Schädlinge, dadurch gekennzeichnet, dass man Wirkstoffkombinationen wie in Anspruch 1-11 definiert oder eine Zusammensetzung gemäß Anspruch 12, auf tierische Schädlinge und/oder deren Lebensraum einwirken lässt. 14. A method for combating animal pests, characterized in that active ingredient combinations as defined in claims 1-11 or a composition according to claim 12 are allowed to act on animal pests and / or their habitat.
15. Verfahren zur Herstellung agrochemischer Zussamensetzungen, dadurch gekennzeichnet, dass man Wirkstoffkombinationen wie in Anspruch 1-11 definiert, mit Streckmitteln und/oder oberflächenaktiven Stoffen vermischt. 15. A process for producing agrochemical compositions, characterized in that active ingredient combinations as defined in claims 1-11 are mixed with extenders and/or surface-active substances.
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