WO2016001124A1 - Insecticidal active ingredient combinations - Google Patents

Abstract

The invention relates to active ingredient combinations that contain a known compound of formula (I) and one or more other pesticides and are suitable for controlling animal pests and are suitable as plant strengthener agents.

Description

 Insecticidal drug combinations

This application relates to mixtures of the compound of formula (I) explained below with at least one further active ingredient, which is preferably an insecticide or an acaricide or a nematicide. These mixtures (active ingredient combinations) are suitable for controlling animal pests and as a plant tonic.

The compound of the formula (I) is known from EP 0 268 915 A2, JP1993078323 A and WO 2012/029672 Al, where its use for controlling animal pests is described. Single drug combinations containing the compound of formula (I) have become known, see WO 2013/129688 Al. However, the acaricidal and / or insecticidal and / or nematicidal activity and / or range of action and / or the plant tolerance of this compound and of the known active substance combinations, in particular to crop plants, is not always sufficient.

It has now been found that drug combinations (drug mixtures) containing the compound of formula (I) and one or more compounds from the groups (1-1) to (1-29) described below and / or one or more compounds of more than preferably mentioned groups of mixing partners are synergistically effective and are suitable for controlling animal pests and as a plant tonic.

The inventive compound of the formula (I)

 (I) ·

 The active compound combinations according to the invention preferably contain the compound of the formula (I) and the mixing partner (s) in synergistically effective amounts.

The active compound combinations according to the invention contain, in addition to the compound of the formula (I), one or more compounds from the groups (1-1) to (1-29) described below and / or one or more compounds from groups of mixing partners which are more preferred.

(1-1) acetylcholinesterase (AChE) inhibitors, such as carbamates, eg alanycarb, aldicarb, bendocarb, benfuracarb, butocarboxime, butoxycarboxime, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, Oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamates, trimethacarb, XMC and xylylcarb or organophosphates, eg acephates, azamethiphos, azinphos-ethyl, azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinone, Dichlorvos / DDVP, Dicrotophos, Dimethoates, Dimethylvinphos, Disulfone, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl O- (methoxyaminothiophosphoryl) salicylate, Isoxathione, Malathion, Mecarbam, Methamidophos, Methidathione, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion, Parathion-methyl, Phenthoate, Phorates, Phosalones, Phosmet, Phosphamidone, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon and Vamidothion. (1-2) GABA-controlled chloride channel antagonists, such as, for example, cyclodiene organochlorines, for example chlordanes and endosulfan or phenylpyrazoles (fiproles), for example ethiprole and fipronil.

(1-3) Sodium channel modulators / voltage dependent sodium channel blockers such as pyrethroids, e.g. Acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha- Cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lR) trans isomers], deltamethrin, empenthrin [(EZ) (lR) isomers], esfenvalerates, etofenprox, fenpropathrin, fenvalerates, flucythrinates, Flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, permethrin, phenothrin [(lR) -trans isomer), prallethrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R) - isomer)], Tralomethrin and transfluthrin or DDT or methoxychlor.

(1-4) Nicotinergic acetylcholine receptor (nAChR) agonists such as neonicotinoids, e.g. Acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam or nicotine or sulfoxaflor or flupyradifurone. (1-5) Nicotinergic acetylcholine receptor (nAChR) allosteric activators, such as spinosines, e.g. Spinetoram and spinosad.

(1-6) chloride channel activators, such as avermectins / milbemycins, e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.

(1-7) Juvenile hormone mimics, such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen.

(1-8) agents with unknown or nonspecific modes of action, such as alkyl halides, eg methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or Borax or tartar emetic.

(1-9) Selective feeding inhibitors, e.g. Pymetrozine or flonicamide.

(1-10) mite growth inhibitors, e.g. Clofentezine, hexythiazox and diflovidazine or etoxazole.

(11) Insect intestinal membrane microbial disruptors, e.g. Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, Cry34 / 35Abl.

(1-12) Inhibitors of oxidative phosphorylation, ATP disruptors such as diafenthiuron or organotin compounds, e.g. Azocyclotin, Cyhexatin and Fenbutatin-oxide or Propargite or Tetradifon.

(1-13) Decoupling of oxidative phosphorylation by interruption of the H proton gradient, such as chlorfenapyr, DNOC, and sulfluramide.

(1-14) Nicotinergic acetylcholine receptor antagonists such as Bensultap, Cartap hydrochloride, Thiocyclam, and Thiosultap Sodium. (1-15) Type 0 inhibitors of chitin biosynthesis, such as bistrifluron, chlorofluorazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(1-16) Inhibitors of chitin biosynthesis, type 1, such as Bupro fezin.

(1-17) Moulting agents, dipteran, such as cyromazine. (1-18) Ecdysone receptor agonists, such as chromafenozides, halofenozides, methoxyfenozides, and tebufenozides.

(1-19) Octopaminergic agonists, such as amitraz.

(1-20) complex III electron transport inhibitors such as hydramethylnone or acequinocyl or fluacrypyrim. (1-21) Complex I electron transport inhibitors, for example, METI acaricides, e.g. Fenazaquin, Fenpyroximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).

(1-22) Voltage-dependent sodium channel blockers, eg indoxacarb or metaflumizone. (1-23) Inhibitors of acetyl-CoA carboxylase, such as tetronic and tetramic acid derivatives, eg spirodiclofen, spiromesifen and spirotetramat.

(1-24) Complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide. (1-25) Complex II electron transport inhibitors such as cyenopyrafen and cyflumetofen.

(1-28) ryanodine receptor effectors such as diamides, e.g. Chlorantraniliprole, Cyantraniliprole and Flubendiamide.

(1-29) Other agents such as afidopyropene, azadirachtin, benclothiaz, benzoximate, bifenazate, bromopropylate, quinomethionate, cryolite, dicofol, diflovidazine, fluensulfone, flometoquine, flufenerim, flufenoxystrobin, flufiprole, fluopyram, flupyradifurone, fufenocide, heptafluthrin, imidaclothiz, iprodione , Meperfluthrin, paichongding, pyflubumide, pyrifluquinazone, pyriminostrobin, tetramethylfluthrin and iodomethane; furthermore preparations based on Bacillus firmus (1-1582, BioNem, Votivo), and the following compounds: 3-bromo-N- {2-bromo-4-chloro-6 - [(1-cyclopropylethyl) carbamoyl] phenyl} - 1 - (3-chloropyridin-2-yl) -1 H -pyrazole-5-carboxamide (known from WO2005 / 077934) and 1 - {2-fluoro-4-methyl-5 - [(2,2,2-trifluoroethyl) sulfomyl] phenyl} -3- (trifluoromethyl) -1H-l, 2,4-triazol-5-amine (known from WO2006 / 043635), {1 '- [(2E) -3- (4-chlorophenyl) propane] 2-en-l-yl] -5-fluorospiro [indole-3,4'-piperidin] -l (2H) -yl} (2-chloropyridin-4-yl) -methanone (Known from

WO2003 / 106457), 2-chloro-N- [2- {1 - [(2E) -3- (4-chlorophenyl) prop-2-en-1-yl] piperidin-4-yl} -4-

(trifluoromethyl) phenyl] isonicotinamide (known from WO2006 / 003494), 3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-1,8-diazaspiro [4.5] dec-3-en-2-one ( known from WO2009 / 049851), 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-l, 8-diazaspiro [4.5] dec-3-en-4-yl-ethyl carbonate (known from WO2009 / 049851 ), 4- (But-2-yn-1-yloxy) -6- (3,5-dimethyl-piperidin-1-yl) -5-fluoropyrimidine (known from WO2004 / 099160), 4- (but-2-yne) l -yloxy) -6- (3-chlorophenyl) pyrimidine (known from WO2003 / 076415), PF1364 (CAS Reg. No. 1204776-60-2), 4- [5- (3,5-dichlorophenyl) -5 - (trifluoromethyl) -4,5-dihydro-l, 2-oxazol-3-yl] -2-methyl-N- {2-oxo-2 - [(2,2,2-trifluoroethyl) amino] ethyl} benzamide (known from WO2005 / 085216), 4- {5- [3-chloro-5- (trifluoromethyl) phenyl] -5- (trifluoromethyl) -4,5-dihydro-l, 2-oxazol-3-yl} -N - {2-oxo-2 - [(2,2,2-trifluoroethyl) amino] ethyl} -l-naphthamide (known from WO2009 / 002809), methyl 2- [2- ({[3-bromo-1 - (3-chloropyridin-2-yl) -1 H -pyrazol-5-yl] carbonyl} amino) -5-chloro-3-methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [2 - ({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3 methylbenzoyl] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [2- ({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO2005 / 085216), methyl 2- [3,5-dibromo-2 - ({[3-bromo-1- (3-chloropyridine) 2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethylhydrazinecarboxylate (known from WO2005 / 085216), Chlo ^ yridin-2-yl) -N- [4-cyano-2-methyl-6- (m

tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (known from WO2010 / 069502), N- [2- (5-amino-l, 3,4-thiadiazol-2-yl) -4-chloro -6-methylphenyl] -3-bromo-1- (3-chloro-2-yl) -1H-pyrazole-5-carboxamide (known from CN102057925), 3-chloro-N- (2-cyano-propane-2-yl) yl) -N- [4- (1, 1, l, 2,3,3,3-heptafluoropropan-2-yl) -2-methylphenyl] phthalamide (known from WO2012 / 034472), 8-chloro-N- [ (2-chloro-5-methoxyphenyl) sulfonyl] -6- (trifluoromethyl) imidazo [1,2-a] pyridine-2-carboxamide (known from WO2010 / 129500), 4- [5- (3,5-dichloro) henyl) -5- (trifluoromethyl) -4,5-dihydro-l, 2-oxazol-3-yl] -2-methyl-N- (1-oxidothietan-3-yl) -benzamide (known from WO2009 / 080250), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- (1-oxidothietan-3-yl ) benzamide (known from WO2012 / 029672), 1 - [(2-chloro, 3-hiazol-5-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [1,2-a] pyrimidine-1-one ium-2-olate (known from WO2009 / 099929), l - [(6-chloropyridin-3-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [1,2-a] pyrimidine-1-one ium-2-olate (known from WO2009 / 099929), ( 5S, 8R) -l - [(6-chloropyridin-3-yl) methyl] -9-nitro-2,3,5,6,7,8-hexahydro-1H-5,8-epoxyimidazo [1, 2] a] azepine (known from

WO2010 / 069266), (2E) -l - [(6-chloro-3-yl-yl) -methyl] -N'-nitro-2-pentylidenehydrazinecarboximidamide (known from WO2010 / 060231), 4- (3- {2, 6-Dichloro-4 - [(3,3-dichloroprop-2-en-1-yl) oxy] phenoxy} propoxy) -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN101337940), N- [2- (tert -Butylcarbamoyl) -4-chloro-6-methylphenyl] -1- (3-chloropyridin-2-yl) -3- (fluoromethoxy) -1H-pyrazole-5-carboxamide (known from WO2008 / 134969).

The active substances mentioned here with their "common name" are known and described, for example, in the Pesticide Handbook ("The Pesticide Manual" 16th Ed., British Crop Protection Council 2011) or searchable on the Internet (eg http://www.alanwood.net pesticides). ,

The active compound combinations Nos. 1 to 6 given in Table A are preferred.

The six mixing partners listed in the table represent a preferred group of mixing partners. Each of the active ingredient combinations (mixtures) Nos. 1 to 6 is a preferred embodiment of the present invention.

In the table, "(I)" represents the compound of the formula (I) The preferred, particularly preferred and most preferred mixing ratios given in the table are weight ratios, the ratio being understood in each case as the amount of compound of the formula (I) to amount of the specified mixing partner. Table A:

The (II) designated mixing partner of the mixture No. 4 is the compound Tetraniliprole having the formula

 known from WO 2010/069502.

The mixing partner of mixture No. 5, designated (III), is the compound formula

 known from WO 2012/000896.

The mixing partner of mixture No. 6, designated (IV), is the compound formula

known from EP 1 803 712 A1.

Further preferred mixing ratios in which the mixtures Nos. 1 to 6 given in Table A are present are 2000: 1 to 1: 2000, 1000: 1 to 1: 1000, 750: 1 to 1: 750, 500: 1 to 1: 500, 250: 1 to 1: 250, 200: 1 to 1: 200, 100: 1 to 1: 100, 95: 1 to 1:95, 90: 1 to 1:90, 85: 1 to 1: 85, 80: 1 to 1: 80, 75: 1 to 1:75, 70: 1 to 1:70, 65: 1 to 1:65, 60: 1 to 1:60, 55: 1 to 1:55, 45: 1 to 1:45, 40: 1 to 1:40, 35: 1 to 1:35, 30: 1 to 1:30, 20: 1 to 1:20, 15: 1 to 1:15, 10: 1 to 1: 10, 9: 1 to 1: 9, 8: 1 to 1: 8, 7: 1 to 1: 7, 6: 1 to 1: 6 4: 1 to 1: 4, 3: 1 to 1: 3, 2: 1 to 1: 2, 1: 1.

If the abbreviated form of the "common name" of an active ingredient is used in the context of this description, then all common derivatives, such as the esters and salts, and isomers, in particular optical isomers, are included, in particular the commercially available form or forms "Common name" denotes an ester or salt, so are all other common derivatives such as other esters and salts, the free acids and neutral compounds, and isomers, in particular optical isomers, in particular the commercial form or forms. The chemical link names given refer to at least one of the "common name" compounds, often a preferred compound.

The active compound combinations according to the invention are very suitable for controlling animal

Pests.

Surprisingly, the insecticidal and / or acaricidal and / or plant-enhancing and / or yield-increasing action of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active substances. There is an unpredictable true synergistic effect and not just an effect supplement.

The active compound combinations according to the invention, in particular the active compound combinations Nos. 1 to 6, can also be mixed with a further active ingredient, for example an insecticide / acaricide / nematicide.

Further, the compound of the formula (I) may be mixed with fungicides. The same applies to the mixtures according to the invention, in particular to those listed in Table A, which can also be mixed with fungicides and applied to plants or plant parts. In many cases, these mixtures with fungicides have synergistic effects. Examples of such fungicidal mixing partners are:

(B) inhibitors of nucleic acid synthesis, such as benalaxyl, benalaxyl-M (kiralaxyl), bupirimate, clozylacone, dimethirimol, ethirimol, furalaxyl, hymexazole, metalaxyl, metalaxyl-M (mefenoxam), ofürace, oxadixyl, oxolinic acid and octhilinone, (F- 2) inhibitors of mitosis and cell division, such as benomyl, carbendazim, chlorfenazole, diethofencarb, ethaboxam, fuberidazole, pencycuron, thiabendazole, thiophanate, thiophanate-methyl, zoxamide, fluopicolide, 5-chloro-7- (4-methylpiperidin-1-yl ) -6- (2,4,6-trifluorophenyl) [l, 2,4] triazolo [l, 5-a] pyrimidine,

(F-3) inhibitors of respiration (respiratory chain inhibitors), such as diflumetorim as an inhibitor at complex I of the respiratory chain; Bixafen, boscalid, carboxin, fenfuram, flutolanil, fluopyram, furametpyr, furmecyclox, isopyrazam (mixture of the yn-epimeric racemate \ RS, 4SR, 9RS and the αηίζ ^' epimeric racemate \ RS, 4SR, 9SR), isopyrazam (yyne) epimeric racemate \ RS, 4SR, 9RS), isopyrazam (yyn-epimeric enantiomer 1R, 4S, 9R), isopyrazam (yyn-epimeric enantiomer \ S, 4R, 9S), isopyrazam (anti-epimeric racemate \ RS, 4SR, 9SR) , Isopyrazam (αηίζ ^' epimeric enantiomer \ R, 4S, 9S), isopyrazam (αηίζ ^' epimeric enantiomer \ S, 4R, 9R),

Mepronil, oxycarboxine, penflufen, penthiopyrad, sedaxanes, thifluzamide, 3- (difluoromethyl) -1-methyl-N- [2- (1, 1, 2,2-tetrafluoroethoxy) phenyl] -1 H -pyrazole-4-carboxamide, 3 - (Difluoromethyl) -1-methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -l-methyl-N- [ 2- (l, 1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4-carboxamide, benzovindiflupyr, benodanil, 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H -inden-4-yl) pyridine-3-carboxamide, isofetamide, N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole 4-carboxamide, 5,8-difluoro-N- [2- (2-fluoro-4- {[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazolin-4-amine, benzovindiflupyr, N - [(1S, 4R) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl] -3- (difluoromethyl) -1-methyl-1H- pyrazole-4-carboxamide, N - [(1R, 4S) -9- (dichloromethylene) -l, 2,3,4-tetrahydro-1,4-methanonaphthalene-5-yl] -3- (difluoromethyl) -1 - methyl-1H-pyrazole-4-carboxamide, 3 - (difluoromethyl) -1 -methyl-N- (1, 1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, 1,3,5-trimethyl-N- (1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1 H -pyrazole-4-carboxamide, 1-methyl-3 - (trifluoromethyl) -N- (1, 1, 3 - trimethyl-2,3-dihydro-1H-inden-4-yl) -1-H-pyrazole-4-carboxamide, 1-methyl-3 - (trifluoromethyl) -N- [(3R) - 1, 1, 3 - trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, 1-methyl-3 - (trifluoromethyl) -N- [(3S)-1,1, 3 -trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [(3S) -1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, 3 - (difluoromethyl) -1-methyl-N - [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -LH-pyrazole-4-carboxamide, 1,3,5-trimethyl-N - [(3R) -l, l, 3-trimethyl- 2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, 1,3,5-trimethyl-N- [(3S) -1,3,3-trimethyl-2,3 -dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, as Inhibitors at the complex II of the respiratory chain; Amisulbrom, Azoxystrobin, Cyazofamide, Dimoxystrobin, Enestroburin, Famoxadone, Fenamidon, Fluoxastrobin, Kresoxim-Methyl, Metominostrobin, Orysastrobin, Picoxystrobin, Pyraclostrobin, Pyraoxystrobin, Pyrametostrobin, Pyribencarb, Trifloxystrobin, Ametoctradin, Coumethoxystrobin, Coumoxystrobin, Enoxastrobin, Flufenoxystrobin, Triclopyricarb, (2E ) -2- (2- {[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylacetamide, (2E) -2- (methoxyimino) -N-methyl-2- (2- {[({(1E) - 1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) acetamide, (2E) -2- ( methoxyimino) -N-methyl-2- {2 - [(E) - ({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} acetamide, (2E) -2- {2- [( {[(1E) -1 - (3 - {[(E) -1-Fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy) methyl-phenyl} -2- (methoxyimino) -N-methylacetamide, fenaminostrobin , 5-Methoxy-2-methyl-4- (2- {[({(IE) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H -l, 2,4-triazol-3-one, methyl (2E ) -2- {2 - [({cyclopropyl [(4-methoxyphenyl) imino] methyl} sulfanyl) methyl] phenyl} -3-methoxyacrylate, N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3- formamido-2-hydroxybenzamide, 2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, 2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2- methoxy-N-methylacetamide as inhibitors of the complex III of the respiratory chain,

(F-4) decouplers such as binapacryl, dinocap, fluazinam and meptyldinocap, ferimzone,

(F-5) inhibitors of ATP production, such as, for example, fentin acetate, fentin chloride, fentin hydroxide and silthiofam,

(F-6) inhibitors of amino acid and protein biosynthesis, such as andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim and pyrimethanil,

(F-7) signal transduction inhibitors such as fenpiclonil, fludioxonil, fluxapyroxad and quinoxyfen, 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline, oxytetracycline, streptomycin,

(F-8) Inhibitors of lipid and membrane synthesis, such as biphenyl, chlozolinate, edifenphos, etridiazole, iodocarb, Iprobenfos, iprodione, isoprothiolane, procymidone, propamocarb, propamocarb hydrochloride, pyrazophos, tolclofos-methyl and vinclozolin, chloroneb, dicloran , Prothiocarb, Quintozen, Tecnazene,

(F-9) inhibitors of ergosterol biosynthesis, such as aldimorph, azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, dodemorph, dodemorph acetate, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fenhexamide, fenpropidin, Fenpropimorph, fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole cis, hexaconazole, imazalil, imazalil sulfate, imibenconazole, ipconazole, metconazole, myclobutanil, naftifine, nuarimol, oxpoconazole, paclobutrazole, pefurazoate, penconazole, piperaline, prochloraz, propiconazole, Prothioconazole, pyributicarb, pyrifenox, quinconazole, simeconazole, spiroxamine, tebuconazole, terbinafine, tetraconazole, triadimefon, triadimenol, tridemorph, triflumizole, triforin, triticonazole, uniconazole, viniconazole and voriconazole, uniconazole-P, 1- (4-chlorophenyl) -2- (lH-l, 2,4-triazol-1-yl) cycloheptanol, methyl 1- (2,2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5- carboxylate, N '- {5- (difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, N-ethyl-N-methyl-N'- {2 -methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl} in

0- [1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl] -1H-imidazole-1-carbothioate, pyrisoxazole,

(F-10) inhibitors of cell wall synthesis, such as benthiavalicarb, dimethomorph, flumorph, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A valefenalate and polyoxin B,

(Fl l) inhibitors of melanin biosynthesis, such as carpropamide, diclocymet, fenoxanil, fthalide, pyroquilone tricyclazole, and 2,2,2-trifluoroethyl {3-methyl-1 - [(4-methylbenzoyl) amino] butane-2 yljcarbamat,

(F-12) resistance inducers, such as acibenzolar-S-methyl, probenazole and tiadinil, isotianil, laminarin,

(F-13) Compounds with multisite activity, such as Bordeaux mixture, captafol, captan, chlorothalonil, copper naphthenate, copper oxide, copper oxychloride, copper preparations, such as copper hydroxide, copper sulfate, dichlofluanid, dithianone, dodine and its free base, Ferbam, Fluorofolpet, Folpet, Guazatine, guazatine acetate, iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, zinc metiram, copper oxine, propamidine, propineb, sulfur and sulfur preparations such as calcium polysulfide, thiram, tolylfluanid, zineb and ziram, anilazine,

(F-14) Other compounds such as 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) -one, (2Z) -3-amino-2-cyano-3-phenylprop -2-enoic acid ethyl ester, N- [2- (1, 3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- (3 ', 4', 5'-trifluorobiphenyl-2-yl) -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,2,3,3 , 3-hexafluoropropoxy) phenyl] -1-methyl-1H-pyrazole-4-carboxamide, (2''-) - 2- (2- {[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidine 4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylethaneamide, (2'l ^' ) -2- {2 - [({[(2 £ ^' , 3 £ ^' ) -4- (2, 6-dichlorophenyl) but-3-en-2-ylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylethaneamide, N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3- (formylamino) -2-hydroxybenzamide, 5-methoxy-2-methyl-4- (2- {[({(1'-1 ') - 1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) -2,4-dihydro-3H-1, 2,4-triazol-3-one, (2'-1 ') - 2- (methoxyimino) -N-methyl-2- (2- {[({ (l '') - 1- [3- (trifluoromethyl) phenyl] ethyl ide n} amino) oxy] methyl} phenyl) ethanamide, (2'-1 ^' ) -2- (methoxyimino) -N-methyl-2- {2- [E- ({1 - [3

(trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} ethanamide, (2E) -2- {2- [({[(! £ ^" ) - 1 - (3 - {[(£) -! fluoro) 2-phenylethenyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methyl-ethanamide, 1- (2,2-dimethyl-2,3-dihydro-1H-indene 1 -yl) -1H-imidazole-5-carboxylic acid methyl ester, N '- {5- (difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidofo

0- {1- [(4-methoxyphenoxy) methyl] -2,2-dimethylpropyl} -1H-imidazole-1-carbothioate, N- [2- (4- {[3- (4-chlorophenyl) prop-2-yn -l-yl] oxy} -3-methoxyphenyl) ethyl] -N ² - (methylsulfonyl) valinamide, 5-amino-

1, 3,4-thiadiazole-2-thiol, propamocarb-fosetyl, 1 - [(4-methoxyphenoxy) methyl] -2,2-dimethylpropyl 1H-imidazole-1-carboxylate, 2,3,5,6-tetrachloro 4- (methylsulfonyl) pyridine, 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, 2-phenylphenol and its salts, 3,4,5-trichloropyridine-2,6-dicarbonyl, 3 [5- (4-chlorophenyl) -2,3-dimethylisoxazolidin-3-yl] pyridine, 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, 4- 4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, 8-hydroxyquinoline, 8-hydroxyquinoline sulfate, tebufloquine, 5-methyl-6-octyl-3,7-dihydro [l, 2,4 ] α-iazolo [l, 5-a] pyrimidine-7-amine, 5-ethyl-6-octyl-3,7-dihydro [l, 2,4] triazolo [l, 5-a] pyrimidin-7-amine , Ametoctradin, Benthiazole, Bethoxazine, Capsimycin, Carvone, Chinomethionate, Cufraneb, Cyflufenamid, Cymoxanil, Cyprosulfamide, Dazomet, Debacarb, Dichlorophene, Diclomezine, Difenzoquat, Difenzoquat Methyl Sulphate, Diphenylamine, Ecomat, Flumetover, Fluoromide, Flusulfamide, Flutianil, Fosetyl Aluminum, Fosetyl-calcium, Fosetyl- Sodium, hexachlorobenzene, irumamycin, methasulfocarb, (2 μg) - 2- {2 - [({cyclopropyl [(4-methoxyphenyl) imino] methyl} thio) methyl] phenyl} -3-methoxyacrylic acid methyl ester, methyl isothiocyanate, metrafenone, (5-Chloro-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone, Mildiomycin, Tolnifanide, N- (4-chlorobenzyl) -3- [3-methoxy -4- (prop-2-yn-1-yloxy) phenyl] propanamide, N - [(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yl) yloxy) phenyl] propanamide, N - [(5-bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-3-chloropyridine-2 -yl) ethyl] -2,4-dichloropyridine-3-carboxamide, N- [1- (5-bromo-

3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodopyridine-3-carboxamide, N- {() - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, N- {(ε ^' ) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, natamycin, nickel dimethyldithiocarbamate, nitrothal isopropyl, Octhilinone, oxamocarb, oxyfenthiine, pentachlorophenol and its salts, phenazine-1-carboxylic acid, phenothrin, phosphoric acid and its salts, propamocarb fosetylate, propanosine sodium, proquinazide, pyrrolnitrin, S-prop-2-en-l-yl 5-amino 2- (l-methylethyl) -

4- (2-methylphenyl) -3-oxo-2,3-dihydro-1H-pyrazole-1-carbothioate, tecloftalam, triazoxide, trichlamide, 5-chloro-N'-phenyl-N'-prop-2-yn 1-ylthiophene-2-sulfonohydrazide, zarilamide, N-methyl-2- (1- {5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N- [(lR) -l, 2,3,4-tetrahydronaphthalen-

1-yl] -1, 3-thiazole-4-carboxamide, N-methyl-2- (1 - {[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidine-4 yl) -N- (1,2,3,4-tetrahydronaphthalen-1-yl) -1,3-thiazole-4-carboxamide, 3- (difluoromethyl) -N- [4-fluoro-2- (1 , 1, 2,3,3,3-hexafluoropropoxy) phenyl] -1-methyl-1H-pyrazole-4-carboxamide and pentyl {6 - [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylidene] amino} oxy) methyl] pyridin-2-yl carbamate, pyriofenone (chlorazafenone), fenpyrazine, pyrimorph, (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl ) -l- (morpholin-4-yl) prop-2-en-1-one, (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridine) 4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (3S, 6S, 7R, 8R) -8-benzyl-3 - [({3 - [(iso-butyryloxy) ) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-l, 5-dioxonan-7-yl 2-methylpropanoate, 1- (4- {4 - [( 5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-t-wazol-2-yl} piperidin-1-yl) -2- [ 5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, 1- (4- {4 - [(5S) -5- (2,6-difluorophenyl) -4,5-dihydro-1 , 2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidine-1-yl) -2- [5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] ethanone , 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidine-1 -yl) -2- [5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] ethanone, 1- (4-methoxyphenoxy) -3,3-dimethylbutan-2-yl 1H-imidazole-1 carboxylates, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridines, 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-4 (3H) -one, 2,6-dimethyl -lH, 5H- [l, 4] dithiino [2,3-c: 5,6- c '] dipyrrole-l, 3,5,7 (2H, 6H) tetrone, 2- [5-methyl-3 - (trifluoromethyl) -lH-pyrazol-l-yl] - 1- (4- {4 - [(5R) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4 - [(5S) -5-phenyl-4,5-dihydro-1,2-d -oxazol-3-yl] -l, 3-thiazol-2-yl} piperidin-1-yl) ethanone, 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -l- {4- [4- (5-phenyl-4,5-dihydro-l, 2-oxazol-3-yl) -l, 3-thiazol-2-yl] -piperidin-1-yl} ethanone, 2-butoxy 6-iodo-3-propyl-4H-chromen-4-one, 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4-methyl-1H-imidazole-5 - yl] pyridines, 2-phenylphenol and salts, 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinolines, 3,4,5-trichloropyridine-2, 6-dicarbonitriles, 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3, 6-dimethylpyridazine,

5-amino-l, 3,4-thiadiazole-2-thiol, 5-chloro-N'-phenyl-N '- (prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, 5-fluoro-2 - [(4-fluorobenzyl) oxy] pyrimidin-4-amine, 5-fluoro-2 - [(4-methylbenzyl) oxy] pyrimidin-4-amine, 5-methyl-6-octyl [l, 2,4] triazolo [l, 5-a] pyrimidin-7-amine, ethyl (2Z) -3-amino-2-cyano-3-phenylacrylate, N '- (4- {[3- (4-chlorobenzyl) -1, 2, 4-thiadiazol-5-yl] oxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yne] 1-yloxy) phenyl] propanamides, N- [(4-chlorophenyl) (cyano) methyl] -3 - [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] -propanamide, N - [( 5-bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloronicotinamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodonicotinamide, N - {(E) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3 - difluorophenylmethyl} -2-phenylacetamide, N- {(Z) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide ide, N '- {4 - [(3-tert-butyl-4-cyano-1,2-thiazol-5-yl) oxy] -2-chloro-5-methylphenyl} -N-ethyl-N-methylimidoformamide, N-methyl-2- (1 - {[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -acetyl} -piperidin-4-yl) -N- (1,2,3,4 tetrahydronaphthalene-1-yl) -1,3-thiazole-4-carboxamide, N-methyl-2- (1 - {[5-methyl-3 - (trifluoromethyl) -1-H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N- [(1 R) -1,3,3,4-tetrahydronaphthalene-1-yl] -1,3-thiazole-4-carboxamide, N-methyl-2- (1 - { [5-methyl-3 - (trifluoromethyl) -1 H -pyrazol-1-yl] acetyl} piperidin-4-yl) -N- [(1S) -1, 2,3, 4-tetrahydronaphthalene-1-yl] - 1, 3 -thiazole-4-carboxamide, pentyl {6- [({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, phenazine-1-carboxylic acid, quinolin-8-ol, quinolin-8-ol sulfate (2: 1), tert-butyl {6- [({[(1-methyl-1H-tetrazol-5-yl ) (phenyl) methylene] amino} oxy) methyl] pyridine-2 yl carbamate, 1-methyl-3- (trifluoromethyl) -N- [2 '- (trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, N- (4'-chlorobiphenyl-2-yl) -3 (difluoro-methyl) -1-methyl-1H-pyrazole-4-carboxamide, N- (2 ', 4'-dichlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole 4-carboxamides, 3- (difluoromethyl) -1-methyl-N- [4 '- (trifluoromethyl) -biphenyl-2-yl] -1H-pyrazoles-4-carboxamides, N- (2', 5'-difluoro - biphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- [4 '- (prop-1 -yn-1 -yl) biphenyl-2-yl] -1-H-pyrazole-4-carboxamide, 5-fluoro-1,3-dimethyl-N- [4 '- (prop-1-yn-1-yl) biphenyl-2- yl] - 1 H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (prop-1 -yn-1-yl) biphenyl-2-yl] nicotinamide, 3 - (difluoromethyl) -N- [ 4 '- (3,3-dimethylbut-1 -yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, N- [4' - (3,3-dimethylbut -l-yn-1-yl) biphenyl-2-yl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, 3 - (difluoromethyl) -N- (4'-ethynyl-biphenyl-2-) yl) 1-methyl-1H-pyrazole-4-carboxamide, N- (4'-ethynyl-biphenyl-2-yl) -5-fluoro-1, 3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N - (4'-ethynylbiphenyl-2-yl) nicotinamide, 2-chloro-N- [4 '- (3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, 4- (difluoromethyl ) -2-methyl-N- [4 '- (trifluoromethyl) biphenyl-2-yl] -1,3-thiazole-5-carboxamide, 5-fluoro-N- [4' - (3-hydroxy-3-methylbut - 1 -yn-1-yl) biphenyl-2-yl] - 1, 3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (3-hydroxy-3-methylbut- 1-yn-1-yl) biphenyl-2-yl] nicotinamide, 3 - (difluoromethyl) -N- [4 '- (3-methoxy-3-methylbut-1 -yn-1-yl) biphenyl-2-yl ] - 1-methyl-1H-pyrazole-4-carboxamide, 5-fluoro-N- [4 '- (3-methoxy-3-methylbut-1 -yn-1-yl) biphenyl-2-yl] - 1 , 3-dimethyl-1H-pyrazole-4-carboxamide, 2-chloro-N- [4 '- (3-methoxy-3-methylbut-1 -yn-1-yl) biphenyl-2-yl] nicotinamide, ( 5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone, N- [2- (4- {[3- (4-chlorophenyl) propyl] 2-yn-1-yl] oxy} -3-met hoxyphenyl) ethyl] -N2- (methylsulfonyl) valinamide, 4-oxo

4- [(2-phenylethyl) amino] butanoic acid, but-3-yn-1-yl {6 - [({[(Z) - (1-methyl-1H-tetrazol-5-yl) (phenyl) methylene} ] amino} oxy) methyl] pyridin-2-yl} carbamate, 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidine-2 (1H) -one), propyl 3,4 , 5-trihydroxybenzoates, 1,3-dimethyl-N- (1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazoles-4-carboxamides, 1,3-dimethyl -N- [(3R) -l, l, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, 1,3-dimethyl-N - [(3S ) - 1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -LH-pyrazole-4-carboxamide, [3- (4-chloro-2-fluorophenyl) -

5- (2,4-difluorophenyl) -l, 2-oxazol-4-yl] (pyridin-3-yl) -methanol, (S) - [3- (4-chloro-2-fluorophenyl) -5- (2 , 4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) -methanol, (R) - [3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl ) -l, 2-oxazol-4-yl] (pyridin-3-yl) -methanol, 2- {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thiones, l- {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1 H -1, 2,4-triazol-5-yl thiocyanate, 5- (allylsulfanyl) -1 - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2] yl] methyl} -1H-l, 2,4-triazoles, 2- [1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro 3H-l, 2,4-triazoles-3-thiones, 2- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl 2,4-dihydro-3H-l, 2,4-triazole-3-thiones, 2- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazole-3-thionene, 1 - {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl yl} -lH-l, 2,4-triazol-5-yl thiocyanate, 1 - {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2] yl] methyl} - 1H- 1, 2,4- triazol-5-yl thiocyanate, 5- (allylsulfanyl) -1 - {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl } -LH-l, 2,4-triazole, 5- (allylsulfanyl) -l- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2] yl] methyl} -1H-l, 2,4-triazoles, 2 - [(2S, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4 yl] -2,4-dihydro-3H-1, 2,4-triazole-3-thionene, 2 - [(2R, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2, 6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1, 2,4-triazole-3-thionene, 2- [(2R, 4R, 5R) -1- (2,4-dichlorophenyl ) -5-hydroxy-2,6,6-rt ^

triazole-3-thiones, 2 - [(2S, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro- 3H-l, 2,4-triazole-3-thionene, 2 - [(2S, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4 -yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thionene, 2 - [(2R, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2 , 6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1, 2,4-triazole-3-thione, 2 - [(2R, 4R, 5S) -l- (2,4-) dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazole-3-thione, 2 - [(2S, 4R, 5S) -

1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethymethylene

 2-fluoro-6- (trifluoromethyl) -N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -benzamide, 2- (6-benzylpyridin-2-yl) quinazolines , 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazolines, 3 - (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolm-1-yl ) qumolme, abscisic acid, 3- (difluoromethyl) -N-methoxy-1-methyl-N- [1- (2,4,6-trichlorophenyl) propan-2-yl] -1H-pyrazole-4-carboxamide, N '- [5-bromo-6- (2,3-dihydro-1H-inden-2-yloxy) -2-methyl-pyridin-3-yl] -N-ethyl-N-methylimidoformamide N' - {5-bromo-6 - [1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformam of N '- {5-bromo-6 - [(1R) -l- (3, 5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimide amide, N '- {5-bromo-6 - [(1S) -1- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, N '- {5-bromo-6 - [(cis-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} - N-ethyl-N-methylimidoformamide, N '- {5-bromo-6 - [(trans-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, N- cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -l-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-N- (2-cyclopropylbenzyl) -3- (difluoro - methyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- (2-tert-butylbenzyl) -N-cyclopropyl-3 -

(difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl -lH-pyrazole-4-carboxamide, N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl -3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N - (5-fluoro-2-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro-1 -methyl-1H-pyrazole-4-carboxamide, N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N -cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro-6-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl) -N- ( 2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopr opyl-5-methylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-N- (2-cyclopropyl-5-methylbenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl- 1H-pyrazole-4-carboxamide, N- (2-tert-butyl-5-methylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- [5-chloro-2- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3- (difluoromethyl) -5 - fluoro-1-methyl-N- [5-methyl-2- (trifluoromethyl) benzyl] -1H-pyrazole-4-carboxamide, N- [2-chloro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3 - (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N- [3-chloro-2-fluoro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) - 5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, N-cyclopropyl-3 - (difluoromethyl) -N- (2-ethyl-4,5-dimethylbenzyl) -5-fluoro-1-methyl-1H pyrazole-4-carboxamides, N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -l-methyl-1H-pyrazoles-4-carbothioamides, 3- (difluoromethyl) -N- ( 7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1-methyl-1H-pyrazole-4-carboxamide, 3- (difluoromethyl) -N- [ (3R) -7-fluoro-1 , 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide, 3 - (difluoromethyl) -N - [(3S) - 7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide.

Furthermore, the compound of formula (I) can be mixed with herbicides. The same applies to the mixtures according to the invention, in particular to those listed in Table A, which can also be mixed with herbicides and applied to plants or plant parts. In many cases, these mixtures with herbicides have synergistic effects.

Examples of such herbicidal mixed partners are:

Acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim-sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminocycloprachlor-potassium, aminocyclopyrachloromethyl, aminopyralid, amitrole, ammonium sulfamate, anilofos, asulam, atrazine, azafenidine, azimsulfuron, beflubutamide, benazolin, benazolin-ethyl, benfluralin, benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone, benzobicyclone, benzofenap, bicyclopyrone, bifenox, bilanafos, bilanafos-sodium, bispyribac, bispyribac-sodium, bromacil, bromobutide, bromofenoxime, bromoxynil, bromoxynil-butyrate, -potassium, -heptanoate and - octanoate, busoxinone, butachlor, butafenacil, butamifos, butenachlor, butraline, butroxydim, butylate, cafenstrole, carbetamide, carfentrazone, carfentrazone-ethyl, chloramben, chlorbromuron, chlorfenac , chlorfenac-sodium, chlorfenprop, chlorofluorol, chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlorophth alim, chlorotoluron, chlorothal-dimethyl, chlorosulfuron, cinidone, cinidon-ethyl, cinmethylin, cinosulfuron, clacyfos, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cycloate, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cyprazine, 2,4-D, 2,4-D-butotyl, -butyl, -dimethylammonium, -diolamine, -ethyl, 2-ethylhexyl, -isobutyl, -isooctyl, isopropylammonium, -potassium, -triisopropanolammonium and -trolamine, 2,4-DB, 2,4-DB-butyl, - dimethylammonium, isooctyl, -potassium and -sodium, daimuron (dymron), dalapon, dazomet, n- decanol, desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofop-methyl, diclofop-P-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimethachlor , dimethametryn, dimethenamid, dimethenamid-P, dimetrasulfuron, dinitramine, dinoterb, diphenamid, diquat, diquat-dibromide, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethiozine, ethofumesate, ethoxyfen, ethoxyfen ethyl, ethoxysulfuron, etobenzanide, F-5231, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1H-tetrazole-1 -yl] -phenyl] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro-2- (trifluoromethyl) -1H-benzimidazol-4-yl] -1-methyl-6- (trifluoromethyl ) pyrimidine-2,4 (1H, 3H) -dione, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfone, fentrazamide, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-p-butyl, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazine, fluometuron, flurenol, flurenol-butyl, -dimethylammonium and -methyl, fluoroglycofen, fluoroglycofen-ethyl, flupropanate, flupyrsulfuron, flupyrsulfuron-methyl-sodium, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet-methyl, fomesafen, fomesafen-sodium, foramsulfuron, fosamine, glufosinate, glufosinate-ammonium, glufosinate-P-sodium, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate-ammonium, -isopropylammonium, -diammonium, -dimethylammonium, -potassium, -sodium and -trimesium, H- 9201, ie 0- (2,4-dimethyl-6-nitrophenyl) -0-ethylisopropylphosphoramidothioate, halauxifen, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfopethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfop methyl, hal oxyfop-P-methyl, hexazinone, HW-02, ie 1- (dimethoxyphosphoryl) ethyl (2,4-dichlorophenoxy) acetate, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyrisopropylammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyrimmonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, iodosulfuron-methyl-sodium, ioxynil, ioxynil-octanoate, -potassium and sodium, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole , karbutilate, KUH-043, ie 3 - ({[5- (difluoromethyl) -1-methyl-3- (trifluoromethyl) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dimethyl-4, 5-dihydro-l, 2-oxazole, ketospiradox, lactofen, lenacil, linuron, MCPA, MCPA-butotyl, -dimethylammonium, -2-ethylhexyl, -isopropylammonium, -potassium and -sodium, MCPB, MCPB-methyl, -ethyl and -sodium, mecoprop, mecoprop-sodium, and -butotyl, mecoprop-P, mecoprop-P-butotyl, -dimethylammonium, -2-ethylhexyl and -potassium, mefenacet, mefluidide, mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiopyrsulfuron, methiozolin, methyl isothiocyanate, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinate, monolinuron, monosulfuron, monosulfuron ester, MT-5950, ie N- [3-chloro-4- (1-methylethyl) phenyl] -2-methylpentanamide, NGGC-011, napropamide, NC-310, ie 4- (2,4-dichlorobenzoyl) -l-methyl-5-benzyloxypyrazole, neburon, nicosulfuron, nonanoic acid (Pelargonic acid), norflurazon, oleic acid (fatty acids), orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefon, oxyfluorfen, paraquat, paraquat dichloride, pebulate, pendimethalin, penoxsulam, pentachlorophenol, pentoxazone, pethoxamide, petroleum oils, phenmedipham , picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron , pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazolynate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, pyroxsulam, quinclorac, quinmerac, quino clamine, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, rimsulfuron, saflufenacil, sethoxydim, siduron, simazine, simetryn, sulcotrione, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron,, SYN -523, SYP-249, ie, 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, SYP-300 , ie, 1- [7-fluoro-3-oxo-4- (prop-2-yn-1-yl) -3,4-dihydro-2H-1,4-benzoxazin-6-yl] -3-propyl 2-thioxoimidazolidine-4,5-dione, 2,3,6-TBA, TCA (trifluoroacetic acid), TCA-sodium, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumetone, terbuthylazine, terbutryn, thenylchloro, thiazopyr, thiencarbazone , thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, tiafenacil topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron-methyl, triclopyr, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifluralin, triflusulfuron, triflusulfuron methyl, tr itosulfuron, urea sulfate, vernolate, ZJ-0862, ie 3,4-dichloro-N - [(4,6-dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following compounds:

see. WO 2001/094339 A1, WO 2001/079199 Al, US 20020016262 Al, WO 2002/098227 Al and WO 2012/122171 Al. Fruit / Vegetable Herbicides: Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam;

Cereal Herbicides: Isoproturon, Bromoxynil, Ioxynil, Phenoxies, Chlorsulfuron, Clodinafop, Diclofop, Diflufenican, Fenoxaprop, Florasulam, Fluroxypyr, Metsulfuron, Triasulfuron, Flucarbazone, Iodosulfuron, Propoxycarbazone, Picolinafen, Mesosulfuron, Beflubutamide, Pinoxaden, Amidosulfuron, Thifensulfuron, Tribenuron, Flupyrsulfuron, Sulfosulfuron, pyrasulfotole, pyroxsulam, flufenacet, tralkoxydim, pyroxasulfone;

Corn herbicides: atrazines, alachlor, bromoxynil, acetochlor, dicamba, clopyralid, (S) -dimethenamid, glufosinate, glyphosate, isoxaflutole, (S) -metolachlor, mesotrione, nicosulfuron, primisulfuron, rimsulfuron, sulcotrione, foramsulfuron, toramezone, tembotrione, saflufenacil, Thiencarbazone, flufenacet, pyroxasulfone;

Rice herbicides: Butachlor, Propanil, Azimsulfuron, Bensulfuron, Cyhalofop, Daimuron, Fentrazamide, Imazosulfuron, Mefenacet, Oxaziclomefone, Pyrazosulfuron, Pyributicarb, Quinclorac, Thiobencarb, Indanofan, Flufenacet, Fentrazamide, Halosulfuron, Oxaziclomefone, Benzobicyclone, Pyriftalid, Penoxsulam, Bispyribac, Oxadiargyl, Ethoxysulfuron, pretilachlor, mesotrione, tefuryltrione, oxadiazone, fenoxaprop, pyrimisulfan;

Woolly herbicides: Diuron, Fluometuron, MSMA, Oxyfluorfen, Prometryn, Trifluralin, Carfentrazone, Clethodim, Fluazifop -butyl, Glyphosate, Norflurazon, Pendimethalin, Pyrithiobac-sodium, Trifloxysulfuron, Tepraloxydim, Glufosinate, Flumioxazin, Thidiazuron;

Soy herbicides: alachlor, bentazone, trifluralin, chlorimuron-ethyl, cloransulam-methyl, fenoxaprop, fomesafen, fluazifop, glyphosate, imazamox, imazaquin, imazethapyr, (S) -metolachlor, metribuzin, pendimethalin, tepraloxydim, glufosinate;

Sugar beet herbicides: Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Lenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop;

Rape herbicides: Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim;

Particular preference is given to mixtures of the compound of the formula (I) or mixtures of the active compound combinations according to the invention with glyphosate. Further preferred are in particular mixtures of the compound of the formula (I) or mixtures of the active compound combinations according to the invention with glufosinate. The active compound combinations according to the invention are suitable for good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, nematodes and mollusks in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include: pests of the genus Arthropoda, in particular of the genus Arachnida eg Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp. Boophilus spp., Brevipalpus spp., Bryobia graminum, Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp. Glycyphagus domesticus, Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus spp., Neutrombicula autumnalis, Nuphersa spp., Oligonychus spp., Ornithodorus spp., Ornithonyssus spp., Panonychus Spp., Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp. Steneotarsonemus spinki, Tarsonemus spp., Tetranychus spp., Trombicula alfreddugesi, Vaejovis spp., Vasates lycopersici .; from the genus of Chilopoda, for example Geophilus spp., Scutigera spp .; from the order or class of the Collembola eg Onychiurus armatus, Sminthurus viridis; from the class Diplopoda eg Blaniulus guttulatus; from the class of the Insecta, eg from the order of the Blattodea eg Blattella asahinai, Blattella germanica, Blatta orientalis, Leucophaea maderae (Rhypaobia maderae), Panchlora spp., Parcoblatta spp., Periplaneta spp., Supella longipalpa, Loboptera decipiens, Neostylopyga rhombifolia , Pycnoscelus surinamensis; from the order of the Coleoptera eg Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agriotes spp., Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apion spp. , Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp. Cosmopolites spp., Costelytra zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferruginus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaeras spp., Epilachna spp , Epitrix spp., Faustinus spp., Gibbium psylloides, Gnathoceras cornutus, Hellula and alis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrapes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae , Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Listronotus (= Hyperodes) spp., Lixus spp., Luperodes spp., Luperomorpha xanthodera, Lyctus spp., Megascelis spp., Melanotus spp. Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryz ae, Otiorrhynchus spp., Oulema spp., Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., Ptinus spp. , Rhizobius ventralis, Rhizopertha dominica, Rhynchophorus spp., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Sinoxylon perforans, Sitophilus spp., Sitophilus oryzae, Sphenophorus spp., Stegobium paniceum, Starchus spp., Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides Mauritanianus, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp .; from the order of Diptera eg Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis spp., Ceratitis capitata, Chironomus spp. Chrysomyia spp., Chrysops spp., Chrysozona pluvialis, Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., Culicoides spp., Culiseta spp., Cuterebra spp., Dacus oleae, Dasyneura spp., Delia spp Dermatobia hominis, Drosophila spp., Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylemya spp., Hippobosca spp. Hypoderma spp., Liriomyza spp., Lucilla spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp. Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., P sila rosae, Rhagoletis spp., Sarcophaga spp., Simulium spp., Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Hippoboscoidea (= Pupipara), Toxotrypana curvicauda; from the suborder of the Heteroptera eg Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptoglossus occidentalis, Leptoglossus phyllopus, Lygocoris spp., Lygus Spp., Macropes excavatus, Megacopta cribraria, Miridae, Monaionion atratum, Nezara spp., Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scaptocoris castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp .; from the order of Hemiptera eg Acizzia acaciaebaileyanae, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Arytainilla spp., Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia tabaci, Blastopsylla occidentalis, Boreioglycaspis melaleucae, Brachycaudus helichrysi, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., Calligypona marginata, Capulinia spp., Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chondracris rosea, Chromaphis juglandicola, Chrysomphalus aonidum, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Cryptoneossa spp., Cte narytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diaspis spp., Diuraphis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Eucalyptolyma Spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp., Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., Idiocerus spp. , Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., Macrosteles facifrons, Mahanarva spp., Melanaphis sacchari, Metcalfiella spp., Metcalfa pruinosa, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Oxya chinensis, Pachypsylla Spp., Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psyllopsis spp., Psylla spp., Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoideus titanus , Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonocephela spp., Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp , Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the order of the Hymenoptera eg Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Lasius spp., Linepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp. , Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp .; from the order of Isopoda, for example, Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera eg Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of Lepidoptera eg Achroia grisella, Acronica major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Autographa spp., Barathra brassicae, Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choreutis pariana, Choristoneura spp., Chrysodixis chalcites, Clysia ambiguella , Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diacraea saccharalis, Diparopsis spp., Earias spp., Ecdytolopha aurantium, Elasmopalpus lignosellus, Eidana saccharina, Ephestia spp., Epinotia spp., Epiphyas postvittana, Erannis spp., Erschoviella musculana, Etiella spp., Eudocima spp., Eulia spp., Eupoecilia ambiguella, Euproctis spp. Euxoa spp., Feltia spp., Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampides spp , Laphygma spp., Laspeyresia molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca spp., Maruca testulalis, Mamestra brassicae , Melanitis leda, Mocis spp., Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp., Orthaga spp., Ostrinia spp., Panolis flammea, Parnara spp , Pectinophora spp., Perileucoptera spp., Phthorimaea spp., Phyllocnis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp. Pseudaletia spp., Pseudaletia Unipuncta, Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Scotia segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera praefica, Stathmopoda spp., Stenoma spp. Stomopteryx subsecivella, Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Virachola spp .; from the order of Orthoptera or Saltatoria eg Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; from the order of Phthiraptera eg Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloxera vastatrix, Phtirus pubis, Trichodectes spp .; from the order of Psocoptera eg Lepinotus spp., Liposcelis spp .; from the order of Siphonaptera, for example Ceratophyllus spp., Ctenocephalides spp., Pulex irritans, Tunga penetrans, Xenopsylla cheopsis; from the order of the Thysanoptera, for example, Anaphothrips obscurus, Baliothrips biformis, Chaetanaphothrips leeuweni, Drepanothrips reuteri, Enneothris flavens, Frankliniella spp., Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamomi, Thrips spp .; from the order of Zygentoma (= Thysanura), z. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; from the class of Symphyla eg Scutigerella spp .;

Pests of the Mollusca strain, in particular of the bivalve class, e.g. Dreissena spp., As well as from the class Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;

Animal parasites from the strains of Plathelminthes and Nematoda, eg Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Anoplocephala spp., Ascaris spp., Ascaridia spp. , Baylisascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dipylidium Spp., Dirofilaria spp., Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Eucoleus spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Filaroides spp., Gongylonema spp., Gyrodactylus spp., Habronema spp. , Haemonchus spp., Heligmosomoides spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Litomosoides spp., Loa Loa, Metastrongylus spp., Metorchis spp., Mesocestoides spp., Moniezia spp., Muellerius spp. , Necator spp., Nematodirus spp., Nippostrongylus spp., Oesophagostomum spp., Ollulanus spp., Onchocerca volvulus, Opisthorchis spp., Oslerus spp., Ostertagia spp., Oxyuris spp., Paracapillaria spp., Parafilaria spp., Paragonimus spp , Paramphistomum spp., Paranoplocephala spp., Parascaris spp., Passalurus spp., Protostrongylus spp., Schistosoma spp., Setaria spp., Spirocerca spp., Stephanofilaria spp., Stephanurus spp., Strongyloides fuelleborni, Strongyloides stercoralis, Strongylus spp , Syngamus spp., Taenia saginata, Taenia solium, Teladorsagia spp., Thelazia spp., Toxascaris spp., Toxocara spp., Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichobilharzia spp., Trichostrongylus spp. Trichuris trichuria, Uncinaria spp., Wuchereria bancrofti; Plant pests of the Nematoda strain, ie plant parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodorus spp , Globodera spp., Helicotylenchus spp., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchus spp., Paratrichodorus spp., Pratylenchus spp., Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp , Tylenchulus spp., Tylenchorhynchus spp., Xiphinema spp .; Furthermore, the order of the coccidia, eg Eimeria spp., Can be determined from the sub-region of the protozoa. fight.

The present invention further relates to formulations and application forms prepared therefrom as crop protection agents and / or pesticides such. B. drench, drip and spray, comprising at least one of the active compound combinations according to the invention. If appropriate, the use forms contain other crop protection agents and / or pesticides and / or the effect of improving adjuvants such as penetration enhancers, eg. As vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetable fatty acids such as rapeseed oil or soybean oil or alkanol alkoxylates and / or spreading agents such as alkyl siloxanes and / or salts z. As organic or inorganic ammonium or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or retention-promoting agents such. As dioctylsulfosuccinate or hydroxypropyl guar polymers and / or humectants such. As glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizer. Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS). ; These and other possible formulation types are described, for example, by Crop Life International and in Pesticide Specifications, Manual on Development and Use of FAO and WHO Specifications for Pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. If appropriate, the formulations contain, in addition to one or more active compounds according to the invention, further agrochemical active substances.

These are preferably formulations or application forms which contain excipients, such as extenders, solvents, spontaneity promoters, carriers, emulsifiers, Dispersants, antifreeze, biocides, thickeners and / or other auxiliaries, such as adjuvants included. An adjuvant in this context is a component that enhances the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents that promote retention, spreading behavior, adherence to the leaf surface, or penetration.

These formulations are prepared in a known manner, e.g. by mixing the active ingredients with excipients such as extenders, solvents and / or solid carriers and / or other excipients such as surfactants. The preparation of the formulations is carried out either in suitable systems or before or during use. As excipients there may be used those substances which are suitable for conferring special properties, such as certain physical, technical and / or biological properties, to the formulation of the active substance or to the forms of use prepared from these formulations (for example usable plant protection agents such as spray or seed dressing).

As extender, e.g. Water, polar and non-polar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified), ketones (such as acetone, cyclohexanone), Esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethylsulfoxide). In the case of using water as an extender, e.g. also organic solvents can be used as auxiliary solvents. Suitable liquid solvents are essentially: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol, and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide and dimethyl sulfoxide, and water.

In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, such as chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, such as Methanol, ethanol, z o-propanol, butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong polar solvents such as dimethyl sulfoxide, and water. Grandsätzlich all suitable carriers can be used. Suitable carriers are in particular: for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic minerals, such as finely divided silica, alumina and natural or synthetic silicates, resins, waxes and / or solids Fertilizer. Mixtures of such carriers can also be used. Suitable carriers for granules are: eg broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems. Also, liquefied gaseous diluents or solvents can be used. Particularly suitable are those extenders or carriers which are gaseous at normal temperature and under atmospheric pressure, for example aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.

Examples of emulsifying and / or foaming agents, dispersants or wetting agents having ionic or non-ionic properties or mixtures of these surfactants are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurates), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds containing sulphates, sulphonates and phosphates, eg Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates, protein hydrolysates, lignin sulfite waste liquors and methylcellulose. The presence of a surfactant is advantageous when one of the active ingredients and / or one of the inert carriers is not soluble in water and when applied in water. As further adjuvants, in the formulations and the applications derived therefrom, dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes, and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present. It may also contain foam-forming agents or defoamers.

Further, the formulations and applications derived therefrom may also contain, as additional auxiliaries, adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-type polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and the like natural phospholipids, such as cephalins and lecithins, and synthetic phospholipids. Other auxiliaries may be mineral and vegetable oils.

Optionally, further auxiliaries may be present in the formulations and in the use forms derived therefrom. Such additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestrants, complexing agents, humectants, spreading agents. In general, the active ingredients can be combined with any solid or liquid additive commonly used for formulation purposes.

As retention promoters are all those substances which reduce the dynamic surface tension such as dioctylsulfosuccinate or increase the visco-elasticity such as hydroxypropyl guar polymers.

Suitable penetration promoters in the present context are all those substances which are usually used to improve the penetration of agrochemical active substances into plants. Penetration promoters are in this context defined by the fact that they can penetrate from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant and thereby increase the material mobility (mobility) of the active ingredients in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut oil ethoxylate (10) or Isotridecylethoxylat (12), fatty acid esters such as rapeseed oil or soybean oil, fatty amine alkoxylates such as Tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.

According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. The plants which can be treated with the active compound combinations according to the invention include, for. The following plant species: turf, vines, cereals, for example wheat, barley, rye, oats, rice, corn and millet, triticale; Beets, for example sugar beets and fodder beets; Fruits, such as pome fruit, stone fruit and soft fruit, such as apples, pears, plums, peaches, almonds, cherries and berries, eg. Strawberries, raspberries, blackberries; Legumes, such as beans, lentils, Peas and soybeans; Oil crops such as rapeseed, mustard, poppy, olive, sunflower, coconut, castor oil, cocoa beans and peanuts; Cucurbits, for example squash, cucumbers and melons; Fiber plants, for example cotton, flax, hemp and jute; Citrus fruits, such as oranges, lemons, grapefruit and mandarins; Vegetables such as spinach, (headj salad, asparagus, cabbage, carrots, onions, tomatoes, potatoes and peppers, laurel family, such as avocado, cinnamomum, camphor or even plants such as tobacco, nuts, coffee, eggplant, sugarcane, tea, pepper , Vines, hops, bananas, natural rubber plants and ornamental plants, such as flowers, shrubs, deciduous trees and conifers.This enumeration is not limiting. Below plant parts are all aboveground and underground parts and organs of plants, such as shoot, leaf, flower and root By way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as roots, tubers and rhizomes are listed, and parts of plants also include harvested material and vegetative and generative propagation material, for example cuttings, tubers, rhiomes, offshoots and seeds The treatment according to the invention of the plants and plants parts with the active ingredient combinations are made directly or by acting on their environment, habitat or storage space according to the usual treatment methods, eg by dipping, (spraying) spraying, spraying, sprinkling, evaporating, atomizing, casting, atomizing, ) Spreading, foaming, brushing, injecting, pouring (drenchen), drip irrigation and in propagating material, especially in seeds, further by dry pickling, wet pickling, slurry pickling, encrusting, single or multi-layer wrapping.

A preferred direct treatment of the plants is foliar application, i. the active compound combinations according to the invention are applied to the foliage, wherein the treatment frequency and the application rate can be matched to the infestation pressure of the respective pest. In the case of systemically active compounds, the active compound combinations according to the invention also enter the plants via the root system. The treatment of the plants is then carried out by the action of the active compound combinations according to the invention on the habitat of the plant. This may be, for example, by drenching, mixing into the soil or the nutrient solution, i. the location of the plant (e.g., soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations of the invention, or by the soil application, i. The active compound combinations according to the invention are introduced in solid form (for example in the form of granules) into the location of the plants. In water rice crops this may also be by metering the invention in a solid application form (e.g., as granules) into a flooded paddy field.

The present invention therefore also relates in particular to a method for the protection of Seed and germinating plants from the infestation of pests by the seed is treated with the active compound combinations according to the invention. The method according to the invention for the protection of seeds and germinating plants from infestation by pests comprises a method in which the seed is treated simultaneously in one operation with the active ingredient of the formula (I) and mixed partner. It also includes a process in which the seed is treated at different times with the active ingredient of formula (I) and mixing partners.

The invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the resulting plant from animal pests. Furthermore, the invention relates to seed which has been treated for protection against animal pests with the active compound combinations according to the invention. The invention also relates to seed treated at the same time with the active ingredient of formula (I) and mixed partner. The invention further relates to seed which has been treated at different times with the active ingredient of the formula (I) and mixed partner. In the case of seed which has been treated at different times with the active ingredient of the formula (I) and mixed partner, the individual active ingredients of the agent according to the invention may be present in different layers on the seed. The layers containing the active ingredient of the formula (I) and mixing partner may optionally be separated by an intermediate layer. The invention also relates to seed in which the active ingredient of the formula (I) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.

Furthermore, the invention relates to seed which, after treatment with the active compound combinations according to the invention, is subjected to a film coating process in order to avoid dust abrasion on the seed.

One of the advantages of the present invention is that because of the particular systemic properties of the compositions of the invention, treatment of the seeds with these agents not only protects the seed itself but also the resulting plants after emergence from animal pests. In this way, the immediate treatment of the culture at the time of sowing or shortly afterwards can be omitted.

A further advantage is the fact that germination and emergence of the treated seed can be promoted by treating the seed with the active compound combinations according to the invention.

Likewise, it is considered to be advantageous that active compound combinations according to the invention can be used in particular also in transgenic seed. As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated. Traditional propagation and breeding methods may be supported or supplemented by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or bioengineering methods and genetic engineering methods. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. Genetically modified plants (or transgenic plants) are plants in which a heterologous gene has been stably integrated into the genome. The term "heterologous gene" essentially means a gene that is provided or assembled outside the plant or plant cell and that when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, provides the transformed plant with new or improved agronomic or other features in that it expresses a protein or polypeptide of interest, or that it downregulates or shuts down another gene present in the plant or other genes present in the plant (eg, by antisense technology, cosuppression technology , RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)). A heterologous gene that has been integrated into the genome is also called a transgene. A transgene that has been integrated into the plant genome is called a transformation event or transgenic event. The terms "parts" or "parts of plants" or "plant parts" have been explained above.

It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars. Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention may also give rise to superadditive ("synergistic") effects. Thus, for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvesting, acceleration of ripeness, higher crop yields, larger fruits, greater plant height, more intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, higher shelf life and / or workability of the crop Harvest products possible that go beyond the expected effects. The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants include the important crops such as cereals (wheat, rice), corn, soy, potato, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soy, potato, cotton and rapeseed should be highlighted. Traits which are particularly emphasized are the increased defense of the plants against insects by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and combinations thereof) are produced in the plants (hereinafter "Bt plants"). Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ^® (for example maize, cotton, soya beans), KnockOut ^® (for example maize), StarLink ^® (for example maize), Bollgard ^® ( cotton), NuCOTN ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties which are resistant under the trade names Roundup Ready ^® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ^® (tolerance to phosphinotricin, for example oilseed rape), IMI ^® (tolerance imidazolinones) and STS ^® (tolerance to sulphonylureas, for example maize). Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also the varieties marketed under the name Clearfield ^® (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits. The listed plants can be treated particularly advantageously according to the invention with the active substance mixtures according to the invention. The specified in the drug combinations above Preferential ranges also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the active ingredient combinations specifically mentioned in the present text.

When a fungicide, in particular one of groups Fl to F14, is added to the active compound combinations according to the invention, the resulting mixtures have an increased microbicidal action (in comparison to the antimicrobial compound or compounds within groups Fl to Fl4) and can be used to combat unwanted microorganisms, such as fungi and bacteria, are used in crop protection and material protection.

Fungicides can be used for the control of Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes. Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.

By way of example but not limitation, some pathogens of fungal and bacterial diseases, which fall under the above-enumerated generic terms, are named:

Diseases caused by powdery mildews such as e.g. Blumeria species such as Blumeria graminis;

Podosphaera species, such as Podosphaera leucotricha;

Sphaerotheca species, such as Sphaerotheca fuliginea;

Uncinula species, such as Uncinula necator;

Diseases caused by causative agents of rust diseases, such as Gymnosporangium species such as Gymnosporangium sabinae

Hemileia species, such as Hemileia vastatrix;

Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species, such as Puccinia recondita; Uromyces species, such as Uromyces appendiculatus; Diseases caused by pathogens of the group of Oomycetes such as Bremia species such as Bremia lactucae; Peronospora species such as Peronospora pisi or P. brassicae;

 Phytophthora species, such as Phytophthora infestans;

 Plasmopara species, such as Plasmopara viticola;

 Pseudoperonospora species, such as Pseudoperonospora humuli or

Pseudoperonospora cubensis;

 Pythium species such as Pythium ultimum;

 Leaf spot diseases and leaf wilt caused by e.g.

 Alternaria species, such as Alternaria solani;

 Cercospora species, such as Cercospora beticola;

Cladosporium species, such as Cladosporium cucumerinum;

 Cochliobolus species, such as Cochliobolus sativus

 (Conidia form: Drechslera, Syn: Helminthosporium);

 Colletotrichum species, such as Colletotrichum lindemuthanium;

 Cycloconium species such as cycloconium oleaginum;

Slide types such as Diaporthe citri;

 Elsinoe species, such as Elsinoe fawcettii;

 Gloeosporium species, such as, for example, Gloeosporium laeticolor;

 Glomerella species, such as Glomerella cingulata;

 Guignardia species, such as Guignardia bidwelli;

Leptosphaeria species, such as Leptosphaeria maculans;

 Magnaporthe species, such as Magnaporthe grisea;

Mycosphaerella species, such as Mycosphaerella graminicola and Mycosphaerella fijiensis; Phaeosphaeria species, such as Phaeosphaeria nodorum; Pyrenophora species, such as, for example, Pyrenophora teres;

 Ramularia species, such as Ramularia collo-cygni;

 Rhynchosporium species, such as Rhynchosporium secalis;

 Septoria species, such as Septoria apii;

Typhula species, such as Typhula incarnata;

 Venturia species such as Venturia inaequalis;

 Root and stem diseases caused by e.g.

 Corticium species, such as Corticium graminearum;

 Fusarium species such as Fusarium oxysporum;

Gaeumannomyces species such as Gaeumannomyces graminis;

 Rhizoctonia species, such as Rhizoctonia solani;

 Tapesia species, such as Tapesia acuformis;

 Thielaviopsis species, such as Thielaviopsis basicola;

 Ear and panicle diseases (including corncob) caused by e.g. Alternaria species, such as Alternaria spp .;

 Aspergillus species, such as Aspergillus flavus;

 Cladosporium species, such as Cladosporium cladosporioides;

 Claviceps species, such as Claviceps purpurea;

 Fusarium species such as Fusarium culmorum;

Gibberella species, such as Gibberella zeae;

 Monographella species such as Monographella nivalis;

 Diseases caused by fire fungi, e.g.

Sphacelotheca species, such as Sphacelotheca reiliana; Tilletia species such as Tilletia caries;

Urocystis species, such as Urocystis occulta;

Ustilago species such as Ustilago nuda;

Fruit rot caused by e.g.

Aspergillus species, such as Aspergillus flavus;

Botrytis species, such as Botrytis cinerea;

 Penicillium species such as Penicillium expansum and Penicillium purpurogenum;

 Sclerotinia species, such as Sclerotinia sclerotiorum;

 Verticilium species such as Verticilium alboatrum;

Seed and soil rots and wilts, as well as seedling diseases caused by e.g.

Fusarium species such as Fusarium culmorum;

 Phytophthora species, such as Phytophthora cactorum;

 Pythium species such as Pythium ultimum;

 Rhizoctonia species, such as Rhizoctonia solani;

Sclerotium species, such as Sclerotium rolfsii;

 Cancers, galls and witches brooms caused by e.g.

 Nectria species, such as Nectria galligena;

 Wilt diseases caused by e.g.

 Monilinia species such as Monilinia laxa;

Deformations of leaves, flowers and fruits caused by e.g.

 Taphrina species, such as Taphrina deformans;

 Degenerative diseases of woody plants caused by e.g.

Esca species such as Phaeomoniella chlamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea;

Flower and seed diseases caused by e.g. Botrytis species, such as Botrytis cinerea; Diseases of plant tubers caused by e.g. Rhizoctonia species, such as Rhizoctonia solani;

Helminthosporium species, such as Helminthosporium solani; Diseases caused by bacterial agents such as e.g. Xanthomonas species, such as Xanthomonas campestris pv. Oryzae; Pseudomonas species, such as Pseudomonas syringae pv. Lachrymans; Erwinia species, such as Erwinia amylovora;

Preferably, the following diseases of soybean beans can be controlled: fungal diseases on leaves, stems, pods and seeds caused by e.g.

Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)) , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye leaf spot (Cercospora sojina), Leptosphaerulina leaf spot (Leptosphaerulina trifolii), Phyllostica leaf spot (Phyllosticta sojaecola), Pod and Stem Blight (Phomopsis sojae), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma glycines), Stemphylium Leaf Blight ( Stemphylium botryosum), Target Spot (Corynespora cassiicola)

Fungal diseases on roots and stem base caused by e.g.

Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Stem Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium red (Pythium aphanidermatum, Pythium irregular, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia root red, Star decay, and Damping off (Rhizoctonia solani), Sclerotinia star decay {Sclerotinia sclerotiorum), Sclerotinia Southern Blight {Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola). The good effect of the active compound combinations according to the invention is evident from the following examples. While the individual active ingredients have weaknesses in effect, the combinations show an effect that goes beyond a simple action summation.

A synergistic effect is always present when the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients. applications

Formula for the kill rate of a combination of two drugs

The expected effect for a given combination of two drugs can be found in S.R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicidal Combinations", Weeds 15, 20-22, 1967) are calculated as follows: When

X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,

Y is the degree of killing, expressed in% of the untreated control, when the active substance B is used at a rate of ng / ha or at a concentration of n ppm, and E is the degree of killing, expressed as% of the untreated control, when using the active compounds A and B. in application rates of m and ng / ha or in a concentration of m and n ppm, then

 XY

E = X + Y- _{1 00}

If the actual kill rate is greater than the calculated kill rate (E), the combination is over-additive in its kill, i. there is a synergistic effect.

In the examples, the corresponding number according to Table A is given behind the mixing partner. In case of doubt, however, the name of the mixing partner takes precedence. Example A

Phaedon cochleariae - spray test (PHAECO)

Solvent: 78.0 parts by weight of acetone

1.5 parts by weight of dimethylformamide

Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water.

Chinese cabbage leaf discs (Brassica pekinensis) are sprayed with a preparation of active compound of the desired concentration and, after drying, are populated with larvae of the horseradish leaf beetle (Phaedon cochleariae).

 After the desired time, the effect is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed. The determined mortality values are calculated according to the Colby formula (see p. 37).

 In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:

 Table A-1: Phaedon cochleariae test

 Active substance concentration effect

in 2 ai / ha in% after 2 ^d

(I) = Aqi-O-chloro-S-200 0

pyridinyl) methyl] -2 (1H) -4O

pyridinylidenes] -2,2,2-

0.4 0

trifluoro-acetamide

 (II) [1- (3-chloropyridin-2-yl) -0.04

N- [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3- {[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide]

 (I) + (II) comp. *. **

 (10: 1) 0.4 + 0.04 33 0

inventively (I)

Fluopyram 200 0

 (I) + Fluopyram obs. * Cal. **

 (1: 1) 200 + 200 33 0

 according to the invention

 Table A-2: Phaedon cochleariae test

 * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula

Example B Myzus dry up - spray test (MYZUPE)

Solvent: 78 parts by weight of acetone

 1.5 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water. Chinese cabbage leaf discs (Brassica pekinensis) infested with all stages of the green peach aphid (Myzus persicae) are sprayed with an active compound preparation of the desired concentration.

 After the desired time, the effect is determined in%. 100% means that all aphids have been killed and 0% that no aphids have been killed. The determined kill values are calculated according to the Colby formula (see page 37).

 In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:

 Table B: Myzus persicae test

 * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula

Example C

Tetranychus urticae - spray test; OP-resistant (TETRUR)

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water. When necessary addition of ammonium salts or / and penetration promoters they are added in each case in a concentration of 1000 ppm of the preparation solution. Bean plants (Phaseolus vulgaris) which are heavily infested by all stages of the common spider mite {Tetranychus urticae) are treated by spraying with the preparation of active compound in the desired concentration.

 After the desired time, the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed. The determined kill values are calculated according to the Colby formula (see page 37).

 In this test, the following active ingredient combination according to the present application showed a synergistically enhanced efficacy compared to the individually applied active ingredients.

 Table C-1: Tetranychus urticae

 * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula

Example D

Spodoptera frusiperda - spray test (SPODFR)

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water. When necessary addition of ammonium salts or / and penetration promoters they are each added to the preparations solution in a concentration of 1000 ppm. Cotton leaves (Gossypium hirsutum) are sprayed with an active compound preparation of the desired concentration and populated with caterpillars of the armyworm (Spodoptera frugiperda).

 After the desired time the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that none of the caterpillars have been killed. The determined kill values are calculated according to the Colby formula (see page 37).

 In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:

 Table D: S odo tera fru i erda - Test

 * Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula

Example E

Myzus dry - spray test (MYZUPE)

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water. When necessary addition of ammonium salts or / and penetration promoters they are added in each case in a concentration of 1000 ppm of the preparation solution. Paprika plants (Capsicum annuum) which are heavily infested with the green peach aphid (Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.

After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula (see page 37).

In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:

Table E-1: Myzus persicae test

* Found. = found insecticidal activity, ex. = calculated effect according to the Colby formula Example F

Aphis ßossyyii - spray test (APHIGO)

Solvent: 7 parts by weight of dimethylformamide

Emulsifier: alkylaryl polyglycol ether

To prepare a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the stated parts by weight of solvent and filled with water containing an emulsifier concentration of 1000 ppm until reaching the desired concentration. Further test concentrations are obtained by dilution with emulsifier-containing water. When necessary addition of ammonium salts or / and penetration promoters they are added in each case in a concentration of 1000 ppm of the preparation solution.

Cotton plants (Gossypium hirsutum), which are heavily affected by the cotton aphid {Aphis gossypii), are sprayed with an active compound preparation of the desired concentration.

After the desired time the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined kill values are calculated according to the Colby formula (see page 1).

In this test, the following active ingredient combination according to the present application showed a synergistically enhanced effectiveness in comparison to the individually applied active ingredients:

Table F-1: Aphis gossypii test

 Active substance concentration effect

in ppm in% after 2 ^d

(I) = Aqi-O-chloro-S-0.8 5

pyridinyl) methyl] -2 (1H) -pyridinylidenes] -2,2,2-trifluoro-acetamides

 (III) 0.1-0

 (I) + (III) calculated.

 (8: 1) 0.8 + 0.1 45 5

inventively Table F-2: Aphis gossypü test

 * Found. = found insecticidal effect, ex. = calculated effect according to the Colby formula

Claims

claims

1. active substance combination of the formula (I)

 (I)

 and one or more compounds selected from the compounds listed in the following table

2. active substance combinations according to claim 1, in which in addition to the compound of formula (I) only one (1) compound selected from the compounds listed in the table.

3. Use of a combination of active substances according to one of claims 1 or 2 for controlling animal pests.

4. Use of a combination of active substances according to one of claims 1 or 2 for the treatment of seed.

5. Seed treated with an active ingredient combination according to one of claims 1 or 2.

6. Use of a combination of active substances according to one of claims 1 or 2 on transgenic plants.

7. A process for the preparation of a plant protection agent, characterized in that one mixes an active substance combination according to one of claims 1 or 2 with extenders and / or surface-active substances.