EP2567898B1 - Beutel mit mehreren Kammern und Verfahren zu dessen Herstellung - Google Patents
Beutel mit mehreren Kammern und Verfahren zu dessen Herstellung Download PDFInfo
- Publication number
- EP2567898B1 EP2567898B1 EP11007384.8A EP11007384A EP2567898B1 EP 2567898 B1 EP2567898 B1 EP 2567898B1 EP 11007384 A EP11007384 A EP 11007384A EP 2567898 B1 EP2567898 B1 EP 2567898B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- foil
- film
- pouch
- compartment
- compartments
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims description 38
- 239000011888 foil Substances 0.000 claims description 79
- 239000000203 mixture Substances 0.000 claims description 42
- 239000003599 detergent Substances 0.000 claims description 35
- 238000004140 cleaning Methods 0.000 claims description 26
- 238000007789 sealing Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 238000011049 filling Methods 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 21
- 239000002671 adjuvant Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 238000004851 dishwashing Methods 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- 229920002125 SokalanĀ® Polymers 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 229920000615 alginic acid Polymers 0.000 claims description 2
- 235000010443 alginic acid Nutrition 0.000 claims description 2
- 229920013820 alkyl cellulose Polymers 0.000 claims description 2
- 239000005018 casein Substances 0.000 claims description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 2
- 235000021240 caseins Nutrition 0.000 claims description 2
- 229920003086 cellulose ether Polymers 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims description 2
- 229920001206 natural gum Polymers 0.000 claims description 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 239000000463 material Substances 0.000 description 16
- 239000007789 gas Substances 0.000 description 11
- 238000012856 packing Methods 0.000 description 5
- 238000007666 vacuum forming Methods 0.000 description 5
- 235000011837 pasties Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000003856 thermoforming Methods 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000010412 laundry washing Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B9/00—Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
- B65B9/10—Enclosing successive articles, or quantities of material, in preformed tubular webs, or in webs formed into tubes around filling nozzles, e.g. extruded tubular webs
- B65B9/20—Enclosing successive articles, or quantities of material, in preformed tubular webs, or in webs formed into tubes around filling nozzles, e.g. extruded tubular webs the webs being formed into tubes in situ around the filling nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
- B65D81/3261—Flexible containers having several compartments
- B65D81/3272—Flexible containers having several compartments formed by arranging one flexible container within another
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B2220/00—Specific aspects of the packaging operation
- B65B2220/16—Packaging contents into primary and secondary packaging
- B65B2220/20—Packaging contents into primary and secondary packaging the primary packaging being bags, the secondary packaging being further bags, the primary bags being either finished or formed concurrently with the secondary bags
Definitions
- the present invention relates to a multi-compartment pouch with one or more inner compartments surrounded by one or more outer compartments, a method for making such a multi-compartment pouch as well as to the use of said pouch in methods for washing or cleaning an article or a surface.
- Detergent and cleaning products are commercially available in various different forms, including for example tablets as well as powdery, granular, pasty, gel-like and liquid compositions.
- unit-packaged detergent compositions have become increasingly popular due to the convenience of dosing them and the improved safety for the user as the risk of unintended contact with said compositions is diminished.
- a water-disintegrable packing e.g. a water-soluble foil, any unintended contact with the composition may be completely avoided, as during manual handling the composition is protected by said packing which will only disintegrate upon contact with water, e.g. inside the dosing chamber of a laundry or a dishwashing machine.
- the packing comprises several compartments, it is even possible to simultaneously dose two different compounds or compositions at the same time in one single step, which otherwise are not compatible with each other during storage.
- Using a multi-compartment packing wherein each compartment is packed in different packing material it is also possible to provide pouches that sequentially release the contents of the individual compartments.
- a further drawback of multi-compartment pouches wherein the compartments are arranged solely in an adjacent manner is the fact, that compartments comprising a liquid content are always in risk of being damaged or even bursting during handling or under mechanical impact, thus leaking their liquid content.
- the same drawback is found in multi-compartment pouches wherein a liquid-containing compartment is located on the outside of said pouch above another compartment. The same is true for hygroscopic contents.
- WO 02/42408 A2 discloses water-soluble containers of essentially rectangular outer shape comprising a plurality of internal partitioning walls to separate the different compartments from one another. Said containers are made by thermoforming or vacuum-forming. Even though these pouches provide a good mechanical stability even for liquid contents if said liquid contents are filled into an inner compartment, the process of making these pouches by thermoforming or vacuum-forming is rather expensive. Also US 2005/00033982 A1 describes compartment detergent pouches having walls composed of a water-soluble or dispersible water-containing polymer film made by vacuum-forming.
- the present invention provides a multi-compartment pouch according to claim 4 comprising one or more inner compartment(s) and one or more outer compartment(s), the latter surround(s) at least 75 % of the outer surface of said inner compartment(s).
- Water-sensitive and/or liquid compounds or components preferably may be filled into said inner compartment(s) and thus are protected from environmental humidity and/or mechanical impact by both the additional water-disintegrable film or foil surrounding the outer compartment(s) as well as the content of said outer compartment(s).
- an inner compartment comprising liquid content is damaged, for example due to mechanical impact, said content leaks into said outer compartment, there being absorbed by the preferably solid content of said outer compartment.
- the whole multi-compartment pouch maybe formed from rather thin water-disintegrable film or foils, e.g. having a thickness of less than 1 mm, for example in form of a sachet.
- the pouches of the present invention preferably represent a sachet and not a rectangular container, made by moulding, thermoforming or vacuum-forming.
- the present invention provides a method for making a multi-compartment pouch comprising one or more inner compartments and one or more outer compartments, the latter surrounding at least 75 % of the outer surface of said inner compartment(s), each compartment being completely surrounded by at least one water-disintegrable film or foil, comprising the steps of: (i) providing an assembly of essentially tubular shape comprising at least one inner tube, which optionally may already be filled with at least one detergent or cleaning adjuvant, and at least one outer tube, the latter surrounding at least 75 % of the outer surface of said inner tube(s), by forming said tubes from at least one water-disintegrable film or foil having a set of opposed lateral edges and sealing said lateral edges either to each other or another part of the lateral surface of said tube (vertical seal) to fix said tubes, (ii) filling in at least one of the inner and/or the outer tubes a portion of detergent and/or cleaning adjuvant, (iv) introducing at least one seal below and/or above said portion of detergent and/or
- Said outer compartment(s) preferably surround(s) at least 80 % of the outer surface of the said inner compartment(s), more preferably at least 85 %, even more preferably at least 90 %, particularly preferably at least 95 % and most preferably essentially the whole outer surface of said inner compartment(s) (except for the small part of the surface at which the horizontal seals are located).
- a film or foil is water-disintegrable if it dissolves, disperses, melts or ruptures upon contact with water or an aqueous solution.
- the water-disintegrable film or foil used for making the multi-compartment pouch of the present invention does not leave more than 20 wt.-%, even more preferably not more 10 wt.-% and most preferably less than 5 wt.-% of solid residue when 10 grams of said material are placed in a vessel, completely covered with 100 mL of water having a temperature of max. 50Ā°C, preferably of max. 40Ā°C, more preferably of max.
- a cold water-soluble film or foil i.e. a film or foil which disintegrates at a temperature of 25 Ā°C or below under conditions described above, to cover the outer surface of the outer compartments, i.e. to form the outer tube(s) of the assembly of essentially tubular shape used in the method of the present invention, while a film substantially insoluble in water having a temperature of 25Ā°C or below, but being soluble in water having a temperature of 40 Ā°C or above maybe used for surrounding one or more of the inner compartments, i.e. for forming one or more of the inner tube(s). In this way, retarded release of the content of said inner compartments may be achieved.
- the velocity of disintegration may also be controlled by the thickness of the film or foil.
- the thickness of the film or foil used is in the range of from 10 ā m to 100 ā m, both for the thickness of the film before it is formed into an essentially tubular shape as well for the thickness of the films or foils in the multi-compartment pouch, i.e. after having been formed into tubular shape.
- films or foils of different disintegration behavior in water may be either made of a different basic film or foil material, i.e. comprise different polymers, or they may be made of the same basic foil material, wherein a part of said foil material is treated on its surface by physical or chemical means to control the disintegration behavior.
- the multi-compartment pouches of the present invention represent a sachet, i.e. usually they more or less have a pillow shape having at least two flat outer edges formed by horizontal top and bottom seals, whereas the middle part of the sachet lying between said flat edges is extended in volume due to the filling of the compartment(s).
- the assembly of essentially tubular shape preferably is formed from at least one continuous flat roll or sheet of the aforementioned films or foils using the VFFS technique by flapping said film or foil around a preferably hollow forming tube, more preferably an essentially conical hollow forming tube and vertically sealing said edges either to each other or to another part of the lateral surface of said tube to fix the tubular shape of the foil.
- a vertical form-film-seal machine is used which is continuously operated.
- the film or foil From a continuous roll the film or foil approaches the back of the hollow forming tube and is formed around said forming tube into an essentially tubular shape for example by forming collars. The film or foil is then guided downwards along said forming tube, for example by low friction rollers and vertically sealed, for example by heat-sealing bar clamps on its edges. If the vertical form-fill-seal technique is used it is preferred to introduce one horizontal seal before starting filling of the film tube to create an open bag which then may be filled with substances dispensed through the hollow forming tube into the center of the bag. When filling is completed, the bag, i.e. the compartment in terms of the present invention, may be closed by introducing a further horizontal seal above the filled-in material.
- Another advantage of the present invention is that for forming a multi-compartment pouch of the present invention no thermoforming, vacuum-forming or filling on a rotary drum as described for example in US 3,057,127 is needed. Hence the use of all of these methods preferably is excluded in the process of making the multi-compartment pouch of the present invention.
- VFFS-technique A further advantage of the VFFS-technique is the fact that the compartments usually are not completely filled and thus remain more flexible and deformable than a pouch which is completely filled. This higher flexibility and deformability ensures that the multi-compartment pouches of the present invention can be easily fit into dosing chambers of different shape.
- the remaining space in the compartments above the filling with detergent and/or cleaning adjuvant may be filled with a gas or a mixture of gases, including for example air, nitrogen, noble gases and the like, without being limited to them, either at atmospheric, positive or negative pressure.
- the gas or the mixture of gases may be inert towards the contents of the compartment, but it may as well be suitable to trigger a chemical reaction with the composition or one or more of its ingredients. If a gas or a mixture of gases is filled into at least one compartment, preferably said gas or gas mixture does not leak out of the multi-compartment pouch, neither through the seals nor through the foil itself.
- the sealing in the machine direction i.e. the direction in which the foil material is moved during making of the tube(s) in a traditional VFFS machine, is called the vertical seal due to its vertical position in said traditional VFFS machine.
- a folded strip of film or foil may be closed to fix a tubular shape and/or the vertical seal may divide a preformed tube into two compartment tubes.
- the vertical seal may be a rim protruding from the outer surface or the inner surface of the tube or the vertical seal may be an integrated part of the outer wall of the tube or an inner sidewall which divides the tubes into two compartments.
- a tube already fixed by a vertical seal may be further divided into three compartments by adding two additional vertical seals.
- Each of said vertical seals may be independently form an angle of from above 0 to 90Ā° with one or more horizontal seals, including 10, 15, 30, 45, 60, 75, 80 and 85Ā°.
- Each vertical seal may be arranged to another vertical seal to include an angle in the range of from 0 to 90Ā°, including 5, 10, 15, 30, 45, 60, 75, 80 and 85Ā°.
- a horizontal seal closes the bottom side of a tube to create an open chamber (or a plurality of open chambers if the tube had previously been divided into more than one tube by adding additional vertical seals).
- the compartments are closed by introducing a further horizontal seal at the top, i.e. above the filling level of said compartments.
- Said top seal may simultaneously create a further open chamber (or plurality of further open chambers) above the filled and closed compartment, i.e.
- a bottom seal can be introduced as well when introducing a top horizontal seal. This may be used to create a further compartment inside the same pouch or the horizontal seal may be divided for instance by cutting to produce one multi-compartment pouch and start a new open chamber for a further multi-compartment pouch.
- Each horizontal seal may be arranged to another horizontal seal to include an angle in the range of from 0 to 90Ā°, including 5, 10, 15, 30, 45, 60, 75, 80 and 85Ā°.
- the method of the present invention preferably may comprise the steps of iii) filling at least one gas into at least one of the compartments before horizontally sealing it, and/or v) removing the sealed pouch from the remaining film or foil.
- Removing the sealed pouch from the remaining film or foil may for example be achieved by cutting through a horizontal seal forming the bottom seal of one pouch and the top seal of a further pouch.
- the multi-compartment pouch comprises one or more inner compartment(s) and one or more outer compartment(s), the latter surrounding at least 75 % of the outer surface of said inner compartment(s), the compartments being filled with detergents or cleaning adjuvants wherein each compartment is completely surrounded by at least one layer of at least one water-disintegrable film or foil and wherein the number of vertical seals per number of compartments in the pouch is above 0 but below 2.
- the compartments inside said multi-compartment pouch preferably are essentially fixed in their relative position to each other at least by the horizontal top and bottom seals of the pouch.
- the pouch of the present invention preferably does not comprise any freely movable inner compartments inside the outer compartments.
- the number of vertical seals necessary to form and seal compartments is reduced in comparison to conventional methods of forming multi-compartment sachets by introducing a preformed sachet into a further sachet, as described for example in EP 0 132 726 A2 . This further reduces the efforts with respect to time and costs in the production process.
- At least one and more preferably all of the compartments in the pouch of the present invention are filled with a compound or a composition independently selected from the group comprising detergents, cleaning adjuvants and mixtures thereof, even more preferably independently selected from the group comprising dish-washing detergents, laundry detergents, machine cleaning and maintenance detergents, components of the aforementioned detergents, water softening compounds or compositions, lime-scale-preventing compounds or compositions, rinse-aid compounds or compositions or mixtures thereof, wherein most preferably each compartment comprises a different compound or composition.
- a compound or a composition independently selected from the group comprising detergents, cleaning adjuvants and mixtures thereof, even more preferably independently selected from the group comprising dish-washing detergents, laundry detergents, machine cleaning and maintenance detergents, components of the aforementioned detergents, water softening compounds or compositions, lime-scale-preventing compounds or compositions, rinse-aid compounds or compositions or mixtures thereof, wherein most preferably each compartment comprises a different compound or composition.
- detergent includes both fully formulated and ready to use detergent composition as well as components thereof, including for example anionic, cationic, nonionic and amphoteric surfactants, soaps, builders, enzymes, polymers, bleaching agents, bleach activators, bleach catalysts, optical brighteners, sud suppressors, dispersants, anti-redeposition agents, soil release agents, metal ion sequestrants, corrosion inhibitors, crystal growth inhibitors, colorants, dyes, perfumes, organic solvents, and the like as well as mixtures thereof without being limited to these.
- anionic, cationic, nonionic and amphoteric surfactants soaps, builders, enzymes, polymers, bleaching agents, bleach activators, bleach catalysts, optical brighteners, sud suppressors, dispersants, anti-redeposition agents, soil release agents, metal ion sequestrants, corrosion inhibitors, crystal growth inhibitors, colorants, dyes, perfumes, organic solvents, and the like as well as mixtures thereof without being limited to these.
- the pouch of the present invention is a multi-compartment pouch, it is possible to provide a fully formulated detergent composition wherein interfering compounds may be separated during transport and storing and are mixed only upon the start of the washing cycle. It may for example be preferable to separate compounds having bleaching activity from enzyme composition by filling them into different compartments. As well e.g. combinations of for example detergents and rinse aids or detergents and lime scale preventing compositions are possible.
- the compounds or compositions filled into each compartment independently may represent a solid, including powders, granules, crystals, pellets, beads, compressed solids, blocks, a paste, a cream, a wax, a gel, a liquid, a gas or a mixture thereof.
- said inner compartment(s) may be filled with at least one pasty, creamy, waxy, gel-like or liquid compound or composition and said outer compartment(s) may be filled with at least one solid compound or composition.
- said outer compartment(s) may be filled with at least one pasty, creamy, waxy, gel-like or liquid compound or composition while said inner compartment(s) may be filled with at least one solid compound or composition.
- said solid substances are hygroscopic and thus are stabilized against environmental humidity both by the content of the outer compartment as well as the additional film or foil surrounding the outer compartment.
- the pouch may be divided into a plurality of compartments by introducing additional vertical and/or horizontal seals.
- the water-disintegrable film or foil preferably comprises a polymer selected from the group comprising polyvinyl alcohols (PVA), polyvinyl pyrrolidone (PVP), polyvinyl acetate, polyacrylic acid and salts thereof, polyacrylamide (PAA), polyacrylonitrile (PAN), polyalkylene oxides, polyethylene imine, cellulose ethers, hydroxyalkylcelluloses, carboxyalkylcelluloses, alkylcelluloses, polyalkylene glycols, alginates, casein, polysaccharides including gelatines and starches, natural gums including guar gum, copolymers thereof and blends thereof.
- said polymer has a molecular weight in the range of from 1,000 to 750,000 g/mol.
- Each seal independently may be established by applying any of heat, steam, radiation, ultrasonics, pressure, solvents, adhesives or a combination thereof to the contact surface of the parts of said film or foil to be sealed.
- the width of each seal independently is in the range of from 0.3 to 30 mm.
- the edges of a seal may be folded for making the seal smaller and/or the edges less sharp or jagged.
- the two edges of a film to be sealed to fix its tubular shape may be pushed inwards before sealing them, for example by pressurized air, to obtain a smaller seal which at the edge is four film or foil layers thick instead of two.
- Each seal independently may also be folded towards or pressed against the body of the multi-compartment pouch and further may be fixed with a sealing aid.
- all of the film or foil present in the pouch consists of exactly one type of film or foil.
- the whole pouch is formed from the same roll or sheet of film or foil.
- the compartments present in the pouch may be formed by (i) spirally rolling or folding the film or foil to form at least one inner tube surrounded by at least one outer tube and then fixing this assembly by sealing a part the film or foil forming the inner tube with a part of the film or foil forming the outer tube before filling the tubes and horizontally sealing them according to steps (ii) and (iv) of the method described above.
- the film or foil preferably may be folded in such a way that a narrow tube is located inside a wider tube, for example an "o-in-O"-shape.
- the vertical seal may be introduced preferably at that point where the lateral edges of the folded film or foil are overlaid, said seal thus fixing three layers of film or foil material to each other.
- FIG. 1 a A view of a cross-section through an assembly of essentially tubular shapes made in that way is schematically shown in figure 1 a showing one sheet of water-disintegrable film or foil 3 folded to form an inner tube 1 essentially completely surrounded by an outer tube 2 , wherein the lateral edges of the film or foil sheet are fixed by a vertical seal 4 .
- Figure 1b shows a plan view on a multi-compartment pouch according to the present invention made from the assembly shown in figure 1 a by introducing horizontal top and bottom seals 5 .
- the vertical seal 4 on the back of said pouch is indicated by dotted lines.
- the pouch comprises one inner compartment 6a and one outer compartment 7a , obtained by horizontally sealing the top and bottom of both the inner tube 1 and the outer tube 2 of the assembly of figure 1a .
- the inner compartment 6a is surrounded by at least two layers of foil in each direction, it is represented in light grey.
- both, the inner compartment as well as the outer compartment are further divided to form four compartments in total, namely two inner compartments 6a and 6b as well as two outer compartments 7a and 7b , as shown in figure 1 c. (The vertical seal 4 is not shown in figure 1 c.)
- the assembly When introducing a further vertical seal 4 , for example opposed to the first vertical seal already shown in figure 1a , the assembly is divided into three tubes, namely one inner tube 1 and two outer tubes 2a and 2b .
- a cross-sectional as well as a plan view of this embodiment are shown in figure 2a and 2b , respectively.
- the vertical seals 4 are not shown in the plan view of figures 2b and 2c .
- the pouch of the present invention may be made from at least two different films or foils as well.
- the films or foils surrounding the inner compartment(s) preferably have a disintegration behavior in water different from that of the film or foil surrounding said outer compartment(s).
- the film or foil surrounding the outer compartment(s) does more readily disintegrate in water than that surrounding the inner compartments, thus leading to an even more retarded release of the content of the inner compartments. If more than one inner compartment is present, even said inner compartments may comprise different films or foils.
- a film or foil which readily disintegrates in water having a temperature of 20 Ā°C or less for surrounding the outer compartments, while a film or foil which only disintegrates in water at temperatures equal to or above 30 Ā°C may be used for surrounding one or more of the inner compartments.
- compartments of these embodiments preferably may be formed by (i) separately forming and vertically sealing each tube, before placing the inner tube(s) inside the outer tube(s) to obtain an essentially tubular assembly before filling the tubes and horizontally sealing them according to steps (ii) and (iv) of the method described above.
- FIG. 3a An example of an assembly according to this embodiment made by a "tube-in-tubeā process is shown in figure 3a .
- a first film 3 is folded into a tube and closed with a vertical seal 4 .
- Another tube of different diameter is prepared in the same way.
- further vertical seals may be introduced into the tube having the smaller diameter, i.e. the tube to used as the inner tube 1 to create even more compartments.
- the tube of smaller diameter, i.e. the inner tube 1 is placed into the tube of larger diameter, i.e. the outer tube 2 .
- Figure 3b shows a plan view on a multi-compartment pouch according to this embodiment (vertical seals not shown).
- At least one further horizontal seal may be introduced over the whole width of the pouch to double the number of compartments and obtain an arrangement similar to that already schematically represented in figure 1c .
- a multi-compartment pouch as shown in figure 3b or as shown in figure 3c may be obtained, having one outer compartment 7a and one or more inner, e.g. three inner compartments 6a, 6b and 6c .
- a single compartment nor the whole pouch of the present invention generally is limited to a certain size. However, it is preferable that the total amount of detergent and/or cleaning adjuvants present in the compartments of the pouch is in the range of from 5 to 100 g, more preferably of from 7.5 to 50 g and most preferably of from 10 to 30 g.
- the amount of detergent and/or cleaning adjuvant present in one compartment depends upon the detergent and/or cleaning adjuvant as well as the total number of compartments per pouch and may for example be in the range of from 0.1 to 99.5 g, more preferably of from 0.5 to 95 g, and even more preferably of from 1 to 75 g.
- the volume of the pouch preferably may be in the range of from 3 to 250 mL, more preferably of from 4 to 150 mL, and most preferably of from 5 to 50 mL.
- the pouch of the present invention preferably is made by the method of the present invention.
- the method for making the multi-compartment pouch of the present invention may comprise further steps.
- the pouches formed by the method as described above may be further packed individually and/or in larger containers for shipment.
- the pouches also may be folded in order to arrange the compartments present in said pouch in a superposed position or attached to each other to provide a more compact form.
- Such folded forms may be fixed using an adhesive material, a casing, a mantle, a tape, a cord, a string, a rope, a thread or the like. It may be preferable that the material used for fixing said arrangement disintegrates in water as well.
- the present invention also provides a method for washing or cleaning an article or a surface comprising the steps of:
- the articles or surfaces to be washed or cleaned include laundry, tableware made of porcelain, ceramics, glass material and the like, cutlery, hard surfaces such as floors, sanitary surfaces and the like, without being limited to these.
- the pouches of the present invention may be used in washing and/or cleaning said articles or surfaces, both in manual as well as in automatic washing and/or cleaning.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Wrappers (AREA)
- Packages (AREA)
- Detergent Compositions (AREA)
- Bag Frames (AREA)
Claims (14)
- Ein Verfahren zur Herstellung eines Mehrkammerbeutels umfassend eine oder mehrere innere Kammern (6a - 6c) und eine oder mehrere ƤuĆere Kammern (7a - 7d), wobei letztere mindestens 75 % der ƤuĆeren OberflƤche dieser inneren Kammer(n) (6a - 6c) umgeben und jede Kammer (6a - 7 d) vollstƤndig von mindestens einem in Wasser abbaubaren Film oder einer solchen Folie (3) umgeben ist, umfassend die Schritte des:i) Bereitstellens einer Anordnung von im Wesentlichen schlauchfƶrmiger Form, umfassend mindestens einen inneren Schlauch (1), welcher wahlweise bereits mit mindestens einem Detergens oder einem Reinigungshilfsmittel befĆ¼llt sein kann und mindestens einen ƤuĆeren Schlauch (2), wobei letzterer mindestens 75 % der ƤuĆeren OberflƤche dieses (dieser) inneren Schlauchs (SchlƤuche) (1) umgibt, durch Ausbilden dieser SchlƤuche aus mindestens einem in Wasser abbaubaren Film oder einer entsprechenden Folie (3) mit einem Satz gegenĆ¼berliegender Seitenkanten und Versiegeln dieser Seitenkanten entweder miteinander oder mit einem anderen Teil der MantelflƤche dieses Schlauchs (vertikale Naht 4), um diese SchlƤuche zu fixieren,ii) EinfĆ¼llens einer Menge an Detergens und/oder Reinigungshilfsmittel in mindestens einen der inneren und/oder der ƤuĆeren SchlƤuche,iv) EinfĆ¼hrens mindestens einer Naht unterhalb und/oder oberhalb dieser Menge an Detergens und/oder Reinigungshilfsmittel (horizontale Naht 5).
- Das Verfahren gemĆ¤Ć Anspruch 1, wobei diese Anordnung von im Wesentlichen schlauchfƶrmiger Form aus mindestens einer Endlosrolle oder einem Bogen dieses Films oder dieser Folie unter Verwendung der vertikalen Form-FĆ¼ll-VerschluĆ (VFFS) Technik durch Umschlagen dieses Films oder dieser Folie um ein vorzugsweise hohles Rohr und vertikales Versiegeln dieser Kanten miteinander oder mit einem anderen Teil der MantelflƤche dieses Schlauchs.
- Das Verfahren gemĆ¤Ć Anspruch 1 oder 2, weiterhin umfassend die Schritte des:i) EinfĆ¼llens mindestens eines Gases in mindestens eine der Kammern (6a - 7d), bevor sie horizontal versiegelt wird, und/oderii) Entfernen des versiegelten Beutels von dem verbleibenden Film oder der Folie.
- Ein Mehrkammerbeutel umfassend eine oder mehrere innere Kammer(n) (6a - 6c) und eine oder mehrere ƤuĆere Kammer(n) (7a - 7d), wobei letztere mindestens 75 % der ƤuĆeren OberflƤche dieser inneren Kammer(n) umgeben, die Kammern (6a - 7d) mit Detergenzien und/oder Reinigungshilfsmitteln befĆ¼llt sind, jede Kammer (6a - 7d) vollstƤndig von mindestens einer Schicht aus mindestens einem Film oder einer Folie (3) umschlossen ist und die Zahl der vertikalen NƤhte (4) pro Zahl an Kammern (6a - 7d) in dem Beutel oberhalb von 0, aber unterhalb von 2 liegt, dadurch gekennzeichnet, dass der mindestens eine Film oder die Folie (3) in Wasser abbaubar ist und der Beutel durch ein Verfahren gemĆ¤Ć Anspruch 1 hergestellt ist, wobei entweder(A) der Film oder die Folie (3), der bzw. die in dem Beutel vorhanden ist, genau aus einer Art von Film oder Folie besteht und die Kammern (6a - 7d) durch spiralfƶrmiges Wickeln des Films oder der Folie (3) gebildet sind, um mindestens einen inneren Schlauch (1) zu bilden, der von mindestens einem ƤuĆeren Schlauch (2) umgeben ist, und anschlieĆendes Fixieren dieser Anordnung durch VerschweiĆen eines Teils des Films oder der Folie (3), welche(r) den inneren Schlauch (1) bildet, mit einem Teil des Films oder der Folie, welche(r) den ƤuĆeren Schlauch (2) bildet, vor dem BefĆ¼llen der SchlƤuche und ihrem horizontalen Versiegeln gemĆ¤Ć den Schritten (ii) und (iv), oder(B) der Beutel mindestens zwei unterschiedliche Filme oder Folien (3) umfasst und wobei der Film oder die Folie (3), welcher die innere(n) Kammer(n) (6a - 6c) umgibt, vorzugsweise ein Abbauverhalten in Wasser aufweist, welches sich von dem des Films oder der Folie (3), welche(r) diese ƤuĆere(n) Kammer(n) (7a) umgibt, unterscheidet und wobei die Kammern durch separates Ausbilden und vertikales Versiegeln jedes Schlauchs gebildet werden, bevor der bzw. die innere(n) Schlauch bzw. SchlƤuche (1) im Inneren des bzw. der ƤuĆeren Schlauch bzw. SchlƤuche angeordnet werden, um eine im Wesentlichen schlauchfƶrmige Anordnung zu erhalten, bevor die SchlƤuche befĆ¼llt und gemĆ¤Ć den Schritten (ii) und (iv) horizontal versiegelt werden.
- Das Verfahren oder der Beutel gemĆ¤Ć einem der vorhergehenden AnsprĆ¼che, wobei zumindest eine und vorzugsweise alle der Kammern (6a - 7d) in diesem Beutel mit einer Verbindung oder einer Zusammensetzung befĆ¼llt sind, die unabhƤngig voneinander aus der Gruppe umfassend Detergenzien und Reinigungshilfsmittel und Mischungen derselben ausgewƤhlt sind, noch bevorzugter unabhƤngig voneinander aus der Gruppe umfassend GeschirrspĆ¼lmittel, Waschmittel, Maschinenreinigungs- und -pflegemittel, Bestandteile der vorgenannten Detergenzien, wasserenthƤrtende Verbindungen oder Zusammensetzungen, Kesselsteinverhindernde Verbindungen oder Zusammensetzungen, KlarspĆ¼lverbindungen oder -zusammensetzungen oder Mischungen derselben ausgewƤhlt sind, wobei am bevorzugtesten jede Kammer eine unterschiedliche Verbindung oder Zusammensetzung umfasst.
- Ein Verfahren oder ein Beutel gemĆ¤Ć einem der vorhergehenden AnsprĆ¼che, wobei die Verbindungen oder Zusammensetzungen, die in jede Kammer eingefĆ¼llt sind, unabhƤngig voneinander einen Feststoff, eine Paste, eine Creme, ein Wachs, ein Gel, eine FlĆ¼ssigkeit, ein Gas oder eine Mischung derselben darstellen kƶnnen.
- Ein Verfahren oder ein Beutel gemĆ¤Ć einem der vorhergehenden AnsprĆ¼che, wobei der Beutel durch EinfĆ¼hrung zusƤtzlicher vertikaler (4) und/oder horizontaler NƤhte (5) in eine Vielzahl von Kammern (6a - 7d) unterteilt ist.
- Ein Verfahren oder ein Beutel gemĆ¤Ć einem der vorhergehenden AnsprĆ¼che, wobei der/die in Wasser abbaubare Film oder Folie (3) ein Polymer, ausgewƤhlt aus der Gruppe umfassend Polyvinylalkohole (PVA), Polyvinylpyrrolidon (PVP), Polyvinylacetat, PolyacrylsƤure und Salze derselben, Polyacrylamid (PAA), Polyacrylonitril (PAN), Polyalkylenoxide, Polyethylenimin, Celluloseether, Hydroxyalkylcellulosen, Carboxyalkylcellulosen, Alkylcellulosen, Polyalkylenglykole, Alginate, Casein, Polysaccharide inklusive Gelatine und StƤrken, natĆ¼rliche Harze inklusive Guarkernmehl, Copolymere derselben und Gemischen derselben umfasst.
- Ein Verfahren oder ein Beutel gemĆ¤Ć einem der vorhergehenden AnsprĆ¼che, wobei jede Naht unabhƤngig voneinander durch Anwendung von WƤrme, Dampf, Strahlung, Ultraschall, Druck, Lƶsungsmitteln, Klebstoffen oder einer Kombination derselben auf die KontaktflƤche der Teile des Films oder der Folie, die versiegelt werden sollen, hergestellt wird, wobei vorzugsweise die Breite jeder Naht unabhƤngig voneinander in dem Bereich von 0,3 bis 30 mm ist.
- Ein Verfahren gemĆ¤Ć einem der AnsprĆ¼che 1 bis 3 oder 5 bis 9, wobei der Film oder die Folie (3), die in dem Beutel vorhanden ist, aus genau einer Art von Film oder Folie besteht und wobei die Kammern (6a - 7d) vorzugsweise durch (i) spiralfƶrmiges Wickeln oder Falten des Films oder der Folie (3) gebildet sind, um mindestens einen inneren Schlauch (1), der von mindestens einem ƤuĆeren Schlauch (2) umgeben ist, zu bilden und anschlieĆendes Fixieren dieser Anordnung durch Versiegeln eines Teils des Films oder der Folie (3), welche den inneren Schlauch (1) bildet, mit einem Teil des Films oder der Folie, die den ƤuĆeren Schlauch (2) bildet, vor dem BefĆ¼llen der SchlƤuche und ihrem horizontalen Versiegeln gemĆ¤Ć den Schritten (ii) und (iv).
- Ein Verfahren gemĆ¤Ć einem der AnsprĆ¼che 1 bis 3 oder 5 bis 9, wobei der Beutel mindestens zwei unterschiedliche Filme oder Folien (3a, 3b) umfasst und wobei der Film oder die Folie (3a), welche den/die inneren Beutel (6a - 6c) umgibt, ein Abbauverhalten in Wasser aufweist, welches sich von dem des Films oder der Folie (3b), der/die die ƤuĆere(n) Kammer(n) (7a) umgibt, unterscheidet und wobei die Kammern vorzugsweise durch (i) separates Ausbilden und vertikales Versiegeln jedes Schlauches, bevor der/die innere(n) Schlauch/SchlƤuche (1) in den/die ƤuĆeren Schlauch/SchlƤuche (2) eingebracht werden, gebildet werden, um eine im Wesentlichen schlauchfƶrmige Anordnung vor dem BefĆ¼llen der SchlƤuche und ihrem horizontalen Versiegeln gemĆ¤Ć den Schritten (ii) und (iv) zu erhalten.
- Ein Verfahren oder ein Beutel gemĆ¤Ć einem der vorhergehenden AnsprĆ¼che, wobei die Gesamtmenge an Detergens und/oder Reinigungshilfsmitteln, die in den Kammern (6a - 7d) des Beutels vorhanden ist, im Bereich von 5 bis 100 g, bevorzugter von 7,5 bis 50 g und am bevorzugtesten von 10 bis 30 g liegt.
- Ein Verfahren gemĆ¤Ć einem der AnsprĆ¼che 2, 3 oder 5 bis 12, wobei die Zahl der vertikalen NƤhte (4) pro Zahl der Kammern (6a - 7d) in dem Beutel mehr als 0, aber weniger als 2 ist.
- Ein Verfahren zum Waschen oder Reinigen eines Gegenstands oder einer OberflƤche umfassend die Schritte des:i) In-Kontakt-Bringen eines Mehrkammerbeutels gemĆ¤Ć einem der AnsprĆ¼che 4 bis 9 oder 12 mit Wasser, um eine wƤssrige Lƶsung zu bilden, die Detergens(-zien) und/oder Reinigungshilfsmittel umfasst,ii) In-Kontakt-Bringen des Gegenstands oder der OberflƤche, die gewaschen und/oder gereinigt werden soll, mit dieser wƤssrigen Lƶsung.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11007384.8A EP2567898B1 (de) | 2011-09-09 | 2011-09-09 | Beutel mit mehreren Kammern und Verfahren zu dessen Herstellung |
ES11007384.8T ES2545984T3 (es) | 2011-09-09 | 2011-09-09 | Bolsa de mĆŗltiples compartimentos y procedimiento para fabricarla |
PL11007384T PL2567898T3 (pl) | 2011-09-09 | 2011-09-09 | Wielokomorowa poduszeczka i sposĆ³b jej wytwarzania |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11007384.8A EP2567898B1 (de) | 2011-09-09 | 2011-09-09 | Beutel mit mehreren Kammern und Verfahren zu dessen Herstellung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2567898A1 EP2567898A1 (de) | 2013-03-13 |
EP2567898B1 true EP2567898B1 (de) | 2015-07-08 |
Family
ID=44759342
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11007384.8A Active EP2567898B1 (de) | 2011-09-09 | 2011-09-09 | Beutel mit mehreren Kammern und Verfahren zu dessen Herstellung |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2567898B1 (de) |
ES (1) | ES2545984T3 (de) |
PL (1) | PL2567898T3 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11464384B1 (en) | 2022-03-31 | 2022-10-11 | Techtronic Cordless Gp | Water soluable package for a floor cleaner |
EP3469065B1 (de) | 2016-06-13 | 2023-04-26 | The Procter & Gamble Company | Verfahren zum waschen von geweben |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10059912B2 (en) * | 2013-06-19 | 2018-08-28 | Conopco, Inc. | Multi-compartment water-soluble capsules |
EP2924105A1 (de) * | 2014-03-28 | 2015-09-30 | The Procter and Gamble Company | Dosierungsartikel fĆ¼r wasserlƶsliche Einheit |
EP2924106A1 (de) * | 2014-03-28 | 2015-09-30 | The Procter and Gamble Company | Dosierungsartikel fĆ¼r wasserlƶsliche Einheit |
NL2012647B1 (en) | 2014-04-17 | 2016-07-18 | Otium Packaging Tech B V | Multi-compartment bag. |
PL2982735T5 (pl) * | 2014-08-07 | 2021-09-27 | The Procter & Gamble Company | <span style="left: 312.2px; top: 141.177px; font-size: 20.0008px; font-family: serif; transform: scaleX(1.00034);">KOMPOZYCJA DETERGENTU PIORÄCEGO |
MX2019007193A (es) | 2017-01-04 | 2019-09-05 | Church & Dwight Co Inc | Un sistema y un metodo relacionado para formar un paquete de camaras multiples. |
US10689182B1 (en) | 2017-07-12 | 2020-06-23 | Jonathon L. Thompson | Multi-compartment disposable pouch |
KR102039385B1 (ko) * | 2018-09-18 | 2019-11-01 | ģ£¼ģķģ¬ ģėøė¦æ | ź³ ģķ ė¹ė ė“ė¶ģ ģ”ģģ¬ė£ ģ¶©ģ§ģ©źø°ź° ė“ģ¬ėģ“ ģė ź³ ģ ė° ģ”ģ ģ ģøµ ķ¼ķ©ė¹ė ė° ź·ø ģ ģ”°ė°©ė² |
DE102019133514A1 (de) * | 2019-12-09 | 2021-06-10 | Henkel Ag & Co. Kgaa | Verfahren zur Herstellung einer Schlauchbeutelverpackung und Schlauchbeutelverpackung |
KR102677176B1 (ko) * | 2021-08-26 | 2024-06-21 | ź¹ģķø | ė¤ģ¤ ź³µź°ģ“ źµ¬ė¹ėė ķģ°ģ¹ |
CN115072055B (zh) * | 2022-07-15 | 2023-09-19 | ęø©å·åøčēŗ¢äŗéęéå ¬åø | äøē§ęčÆéé¶éØ件čŖåØē»åå°č£ č£ ē½® |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3057127A (en) | 1960-10-10 | 1962-10-09 | Procter & Gamble | Sealing soluble film packets |
DE3326249A1 (de) | 1983-07-21 | 1985-01-31 | Henkel Kgaa | Wasch-, spuel- oder reinigungsmittelverpackung |
GB8605734D0 (en) | 1986-03-07 | 1986-04-16 | Unilever Plc | Dispensing treatment agents |
AU2002239349A1 (en) | 2000-11-27 | 2002-06-03 | The Procter & Gamble Company | Detergent products, methods and manufacture |
ES2308209T3 (es) * | 2003-06-03 | 2008-12-01 | THE PROCTER & GAMBLE COMPANY | Bolsa de detergente. |
ZA200605213B (en) * | 2005-06-24 | 2007-09-26 | J Lok Co | Device for forming partitioned film packages |
WO2008068779A2 (en) * | 2006-12-07 | 2008-06-12 | Shilpan Pravinchandra Patel | Water soluble film based package, process and apparatus for sealing said package |
US20080274239A1 (en) * | 2007-05-01 | 2008-11-06 | Kraft Foods Holdings, Inc. | Ingredient Package and Method |
-
2011
- 2011-09-09 ES ES11007384.8T patent/ES2545984T3/es active Active
- 2011-09-09 PL PL11007384T patent/PL2567898T3/pl unknown
- 2011-09-09 EP EP11007384.8A patent/EP2567898B1/de active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3469065B1 (de) | 2016-06-13 | 2023-04-26 | The Procter & Gamble Company | Verfahren zum waschen von geweben |
US11464384B1 (en) | 2022-03-31 | 2022-10-11 | Techtronic Cordless Gp | Water soluable package for a floor cleaner |
Also Published As
Publication number | Publication date |
---|---|
ES2545984T3 (es) | 2015-09-17 |
EP2567898A1 (de) | 2013-03-13 |
PL2567898T3 (pl) | 2015-12-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2567898B1 (de) | Beutel mit mehreren Kammern und Verfahren zu dessen Herstellung | |
EP1303585B2 (de) | Artikel enthaltend eingeschlossene zusammensetzungen | |
ES2248294T3 (es) | Composiciones en bolsa. | |
ES2329725T3 (es) | Productos detergentes, metodos y fabricacion. | |
US20040142131A1 (en) | Compositions | |
US20060016716A1 (en) | Injection moulded containers | |
EP1276845B1 (de) | Zusammensetzungen in beuteln | |
EP1539605B1 (de) | Wasserlƶslicher behƤlter | |
ZA200105052B (en) | Water soluble package. | |
EP1539606B1 (de) | Verbesserungen in behƤltern oder diese betreffend | |
JP2004500285A (ja) | å°åŗęåćććę°“ęŗ¶ę§å®¹åØ | |
EP1387797B1 (de) | Wasserlƶsliche behƤlter mit einrichtungen zur freigabe von gas | |
WO2002085737A1 (en) | Water-soluble container having at least two openings | |
JP4902082B2 (ja) | å°č¢å „ćēµęē© | |
US20110127271A1 (en) | Packaging | |
MXPA05002490A (es) | Producto envasado que comprende bolsitas flexibles y llenas de liquido. | |
GB2367828A (en) | Water-soluble containers containing aqueous compositions | |
GB2387598A (en) | Water-soluble container and a process for its preparation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
17P | Request for examination filed |
Effective date: 20130703 |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
17Q | First examination report despatched |
Effective date: 20130731 |
|
17Q | First examination report despatched |
Effective date: 20130814 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C11D 17/04 20060101ALI20150126BHEP Ipc: B65B 9/20 20120101ALI20150126BHEP Ipc: B65B 9/10 20060101AFI20150126BHEP Ipc: B65D 81/32 20060101ALI20150126BHEP Ipc: B65B 31/00 20060101ALI20150126BHEP |
|
INTG | Intention to grant announced |
Effective date: 20150210 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 735189 Country of ref document: AT Kind code of ref document: T Effective date: 20150715 Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602011017604 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2545984 Country of ref document: ES Kind code of ref document: T3 Effective date: 20150917 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 735189 Country of ref document: AT Kind code of ref document: T Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: PL Ref legal event code: T3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20151008 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20151009 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20151109 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20151108 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602011017604 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
26N | No opposition filed |
Effective date: 20160411 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150930 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150909 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 6 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20110909 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 20170921 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20170824 Year of fee payment: 7 Ref country code: SE Payment date: 20170921 Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 8 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20150708 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180910 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180909 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180909 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20200907 Year of fee payment: 10 Ref country code: FR Payment date: 20200914 Year of fee payment: 10 Ref country code: GB Payment date: 20200922 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20200922 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20201120 Year of fee payment: 10 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20210909 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210909 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210930 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210909 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20221125 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210910 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230411 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210909 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20240910 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20240918 Year of fee payment: 14 |