EP2560806A1 - Réacteur à vis pour la transformation de matière organique à longue chaîne moléculaire - Google Patents

Réacteur à vis pour la transformation de matière organique à longue chaîne moléculaire

Info

Publication number
EP2560806A1
EP2560806A1 EP10722784A EP10722784A EP2560806A1 EP 2560806 A1 EP2560806 A1 EP 2560806A1 EP 10722784 A EP10722784 A EP 10722784A EP 10722784 A EP10722784 A EP 10722784A EP 2560806 A1 EP2560806 A1 EP 2560806A1
Authority
EP
European Patent Office
Prior art keywords
organic matter
chain organic
molecular chain
conduit
shafts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP10722784A
Other languages
German (de)
English (en)
Inventor
Giorgio Pecci
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP2560806A1 publication Critical patent/EP2560806A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/252Drive or actuation means; Transmission means; Screw supporting means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B29C48/404Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders the screws having non-intermeshing parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • B29C48/40Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
    • B29C48/405Intermeshing co-rotating screws
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B7/00Coke ovens with mechanical conveying means for the raw material inside the oven
    • C10B7/10Coke ovens with mechanical conveying means for the raw material inside the oven with conveyor-screws
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/06Rod-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/297Feeding the extrusion material to the extruder at several locations, e.g. using several hoppers or using a separate additive feeding
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • C10G2300/1014Biomass of vegetal origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the present invention refers to an apparatus for transforming long molecular chain organic matter.
  • mixtures of organic compounds of low molecular weight constitute the basic components of the fuels used to power vehicles such as aircraft, automobiles and the like.
  • Thermal scission techniques for implementing such transformation are therefore widespread: these techniques break the carbonaceous bonds using heat, which is applied to the material to be processed both from outside, and by means of combustion of part of the very material to be processed.
  • transformation plants that include a cylindrical chamber inside which the material is mechanically mixed, shredded, crushed, and ground. This causes the material to assume a viscous consistency and subjects it to forces of friction that are such as to increase its temperature and pressure, so producing the desired breakage of the molecular bonds.
  • This embodiment is also, however, not without drawbacks.
  • the aim of the present invention is to solve the above mentioned drawbacks, by devising an apparatus that makes it possible to achieve the transformation of long molecular chain organic matter with a solution that is structurally simple.
  • an object of the invention is to devise an apparatus that can cause the transformation of long molecular chain organic matter without imposing high operating speeds upon the elements involved.
  • Another object of the invention is to devise an apparatus that can operate in total safety, without risk of blowouts and explosions.
  • a further object of the invention is to devise an apparatus that ensures a high level of reliability in operation.
  • a further object of the invention is to devise an apparatus that can be easily made from elements and materials that are readily available on the market.
  • a further object of the invention is to devise an apparatus that can be made at low cost and applied safely.
  • an apparatus for transforming long molecular chain organic matter comprising at least one chamber that has at least one conduit inside it which is interposed between at least one inlet, for the introduction into said conduit of long molecular chain organic matter, and at least one outlet, for the expulsion of short molecular chain organic mixtures, obtained from the transformation of the long chain organic matter, characterised in that at least one active portion of said conduit is delimited by respective surfaces of at least one pair of rotors, arranged at least partly side by side inside said chamber, and, at said active portion, the simultaneous rotation of said rotors subjecting the long molecular chain organic matter to mechanical stresses, with consequent increase, due to friction, of the temperature and internal pressure, for the breakage of the long molecular chains.
  • Figure 1 is a plan view of an apparatus according to the invention.
  • Figure 2 schematically shows the operation and the motion of the rotors, at the active portion of the conduit.
  • an apparatus according to the invention is adapted to transform long molecular chain organic matter and comprises at least one chamber 2, inside which the transformation takes place.
  • the chamber 2 has at least one conduit 3 inside it, interposed between at least one inlet 4a, which allows the introduction into the conduit 3 of the long molecular chain organic matter to be transformed, and at least one outlet 4b, which allows the expulsion of the short molecular chain organic mixtures, obtained from the transformation of the long chain organic matter.
  • the long molecular chain organic matter that can be transformed by means of the apparatus 1 according to the invention can be any: by way of example, it is possible for it to be residues of plastic materials, polymeric materials (vulcanised rubber, thermoplastics etc., such as used tyres), vegetable flours, doughy or semi-liquid products, and so on.
  • the possibility of employing the apparatus 1 according to the invention for the transformation of different types of organic matter is not excluded.
  • At least one active portion 3a of the conduit 3 is delimited by respective surfaces of at least one pair of rotors 5, arranged at least partly side by side inside the chamber 2.
  • the simultaneous rotation of the rotors 5 subjects the long chain organic matter to mechanical stresses, which produce, by friction, a consequent increase in the temperature and internal pressure, capable of causing the breakage of the long molecular chains.
  • the above mentioned organic matter is subjected to mechanical stresses of various different types, as an effect of the simultaneous rotation of the two rotors 5: the matter, in fact, is stretched, crushed, milled, shredded, ground and so on.
  • the forces of friction, internal and external, generated between the various different layers of the organic matter present thus raise its pressure and the temperature of the matter until it produces the breakage of the long molecular chains, and the desired transformation of the organic matter introduced into the chamber 2 into short molecular chain organic mixtures.
  • the transformation achieves the separation of the respective solid, liquid and gaseous phases, which then exit from the outlet 4b.
  • the rotors 5 are substantially constituted of cylindrical shafts located side by side, which rotate in the same direction (with equal or different angular speeds) about respective axes, which are substantially parallel to the axis of the chamber 2 and inside thereto.
  • the chamber 2 is also preferably cylindrical in shape.
  • each shaft has at least one first upstream section 5 a and at least one second downstream section 5b: the active portion 3a of the conduit 3 is delimited by the downstream sections 5b of such shafts, which are arranged side by side and are proximate and substantially parallel.
  • the chamber 2 comprises two inlets 4a that feed into respective accommodation seats 6 of corresponding upstream sections 5a of the shafts: the spaces that are thus delimited by each of the upstream sections 5a and by the respective seat 6, constitute respective head branches 3b of the conduit 3 (which is therefore substantially Y-shaped), such branches feeding into the active portion 3 a.
  • each upstream section 5a of the shafts is substantially constituted by a first screw, the spiral 7 of which, wound around the stem of the shaft, is adapted to drag along the spaces the long molecular chain organic matter to be transformed (introduced into the branches 3 b through the inlets 4a).
  • the diameter of the downstream sections 5 b is greater than that of the upstream sections 5 a to obtain, precisely at the opposite-facing surfaces of the rotors 5, the maximum tangential speeds (and the maximum stresses), while along the upstream sections (smaller in diameter) the organic matter is simply dragged (and possibly preheated).
  • the lateral surfaces of the downstream sections 5b are substantially flat, and the section of the downstream sections 5b has a greater diameter than that of the upstream sections 5a, in order to obtain, at the active portion 3 a, greater tangential speeds (useful to the transformation of the organic matter).
  • the downstream sections 5b of the shafts are constituted by second screws (the pitch of which is the same as, or different from, that of the first screws already described), to produce the dragging of the organic matter being transformed along the active portion 3a. Also according to this embodiment, there is the possibility that the downstream sections 5b of the shafts have a greater diameter than that of the upstream sections 5 a, to increase the tangential speed.
  • Such organic matter can thus travel along the branches 3 b of the conduit 3, possibly pushed by the first screws which constitute the respective upstream sections 5 a of the rotors 5.
  • the organic matter can thus arrive at the active portion 3 a, in which, as shown previously, it is subjected to mechanical stresses that are such as to induce the breakage of the long molecular chains that compose it, thus obtaining the desired transformation into organic mixtures of various types, with short molecular chain.
  • the action of the two rotating surfaces makes it possible to maintain a low speed of rotation for the two rotors 5 (and consequently greater structural simplicity of the entire apparatus 1), but at the same time it ensures that stresses and frictions are obtained to an extent that are such as to guarantee the accomplishment of the desired transformation of the organic matter into short chain organic mixtures.
  • the organic mixtures obtained in the chamber 2 can then exit from the outlet 4b and be collected in suitable containers (and possibly undergo further refining treatments, according to the specific uses to which they are destined).
  • apparatuses 1 that are provided with three or more rotors 5, arranged for example side by side to define a plurality of active portions 3 a, or even having different shapes, possibly also in such a way that at least three rotors 5 contribute (with respective surface areas) to delimit the same active portion 3 a, should this be considered preferable according to the specific application needs.
  • the apparatus according to the invention fully achieves the intended aim, since the transformation of the long chain organic matter occurs in an active portion of a conduit that is delimited by the simultaneously rotating surfaces of at least two rotors, and this subjects the organic matter to mechanical stresses that are such as to induce their transformation into short molecular chain organic mixtures, with a structurally simple solution.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

Dispositif de transformation de matière organique à longue chaîne moléculaire, comprenant au moins une chambre (2) comportant au moins un conduit (3) à l'intérieur de cette dernière, interposé entre au moins une entrée (4a), pour l'introduction dans le conduit (3) de matière organique à longue chaîne moléculaire, et au moins une sortie (4b), pour l'expulsion de mélanges organiques à chaîne moléculaire courte, obtenus par la transformation de la matière organique à longue chaîne moléculaire. Au moins une portion active (3a) du conduit (3) est délimitée par les surfaces respectives d'au moins une paire de rotors (5), disposés au moins partiellement côte à côte à l'intérieur de la chambre (2). Au niveau de la portion active (3a), la rotation simultanée des rotors (5) soumet la matière organique à longue chaîne moléculaire à des contraintes mécaniques, avec une augmentation conséquente, du fait des frottements, de la température et de la pression interne, dans le but de briser les longues chaînes moléculaires.
EP10722784A 2010-04-21 2010-04-21 Réacteur à vis pour la transformation de matière organique à longue chaîne moléculaire Withdrawn EP2560806A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IT2010/000194 WO2011132210A1 (fr) 2010-04-21 2010-04-21 Réacteur à vis pour la transformation de matière organique à longue chaîne moléculaire

Publications (1)

Publication Number Publication Date
EP2560806A1 true EP2560806A1 (fr) 2013-02-27

Family

ID=43588866

Family Applications (1)

Application Number Title Priority Date Filing Date
EP10722784A Withdrawn EP2560806A1 (fr) 2010-04-21 2010-04-21 Réacteur à vis pour la transformation de matière organique à longue chaîne moléculaire

Country Status (3)

Country Link
EP (1) EP2560806A1 (fr)
AR (1) AR080965A1 (fr)
WO (1) WO2011132210A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3006935B1 (fr) * 2013-06-14 2016-01-29 Carolina Marchante Extrudeuse pour unite de traitement de matieres plastiques, et unite de traitement comprenant une telle extrudeuse
CN103522519A (zh) * 2013-10-30 2014-01-22 吴江市科时达纺织有限公司 双料口双螺杆挤出机
ITUB20159623A1 (it) * 2015-12-16 2017-06-16 Giorgio Pecci Stazione di degradazione per degradare una materia organica a catene molecolari lunghe e relativo apparato
MX2018015963A (es) 2016-06-21 2019-06-10 Golden Renewable Energy Llc Separador de carbon y metodo.
US10961062B2 (en) 2016-06-21 2021-03-30 Golden Renewable Energy, LLC Bag press feeder assembly
WO2018007964A1 (fr) 2016-07-05 2018-01-11 Golden Renewable Energy, LLC Système et procédé pour convertir des déchets de plastiques en combustible
US10233393B2 (en) 2016-07-08 2019-03-19 Golden Renewable Energy, LLC Heated airlock feeder unit
GB2574834B (en) * 2018-06-19 2021-02-10 Waste To Energy Tech Ltd Pyrolysis system
GB2574832B (en) * 2018-06-19 2021-07-21 Waste To Energy Tech Ltd System and method for processing a material by pyrolysis
IT202100027416A1 (it) * 2021-10-26 2023-04-26 Gustavo Bruno Torlasco Dispositivo di trasformazione per degradazione di materie organiche solide a catene molecolari lunghe in materia organica fluida e/o solida a catene molecolari corte.

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US7244060B2 (en) * 2001-11-29 2007-07-17 Kobe Steel, Ltd. Kneading apparatus

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US5017269A (en) * 1988-12-28 1991-05-21 Apv Chemical Machinery Inc. Method of continuously carbonizing primarily organic waste material
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EP1405895A1 (fr) * 2002-10-04 2004-04-07 Danieli Corus Technical Services BV Dispositif et procédé pour le traitement pyrolytique d'une matière, et son utilisation
EP1473137A1 (fr) * 2003-04-30 2004-11-03 Coperion Werner & Pfleiderer GmbH & Co. KG Procédé de fusion et homogénéisation de polyoléfines bimodales ou multimodales
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ITBO20060603A1 (it) * 2006-08-11 2008-02-12 Giorgio Pecci Dispositivo per la trasformazione di sostanze solide aventi legami chimici in catene lunghe in miscugli di componenti solidi e/o liquidi e/o gassosi a catene corte.

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Also Published As

Publication number Publication date
AR080965A1 (es) 2012-05-23
WO2011132210A1 (fr) 2011-10-27

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