EP2553298A1 - Gas-dispensing device and facility comprising such a device - Google Patents

Gas-dispensing device and facility comprising such a device

Info

Publication number
EP2553298A1
EP2553298A1 EP11712938A EP11712938A EP2553298A1 EP 2553298 A1 EP2553298 A1 EP 2553298A1 EP 11712938 A EP11712938 A EP 11712938A EP 11712938 A EP11712938 A EP 11712938A EP 2553298 A1 EP2553298 A1 EP 2553298A1
Authority
EP
European Patent Office
Prior art keywords
gas
dispensing
housing
emergency evacuation
movable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11712938A
Other languages
German (de)
French (fr)
Inventor
Laurent Allidieres
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Original Assignee
Air Liquide SA
LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Liquide SA, LAir Liquide SA pour lEtude et lExploitation des Procedes Georges Claude filed Critical Air Liquide SA
Publication of EP2553298A1 publication Critical patent/EP2553298A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K11/00Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves
    • F16K11/02Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit
    • F16K11/06Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit comprising only sliding valves, i.e. sliding closure elements
    • F16K11/072Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit comprising only sliding valves, i.e. sliding closure elements with pivoted closure members
    • F16K11/074Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit comprising only sliding valves, i.e. sliding closure elements with pivoted closure members with flat sealing faces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K17/00Safety valves; Equalising valves, e.g. pressure relief valves
    • F16K17/36Safety valves; Equalising valves, e.g. pressure relief valves actuated in consequence of extraneous circumstances, e.g. shock, change of position
    • F16K17/38Safety valves; Equalising valves, e.g. pressure relief valves actuated in consequence of extraneous circumstances, e.g. shock, change of position of excessive temperature
    • F16K17/386Safety valves; Equalising valves, e.g. pressure relief valves actuated in consequence of extraneous circumstances, e.g. shock, change of position of excessive temperature the closure members being rotatable or pivoting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/1624Destructible or deformable element controlled
    • Y10T137/1797Heat destructible or fusible
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/1842Ambient condition change responsive
    • Y10T137/1939Atmospheric
    • Y10T137/1963Temperature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/8593Systems
    • Y10T137/86493Multi-way valve unit
    • Y10T137/86501Sequential distributor or collector type

Definitions

  • Gas distribution device and installation comprising such a device.
  • the present invention relates to a device and a gas distribution installation.
  • the invention relates to a gas distribution device for sequentially relating multiple sources of pressurized gas to a user, the device comprising a housing having a plurality of gas inlets for connection to gas sources. respective and an output intended to be connected to a user member, a selectively movable distribution member relative to the body in different distribution positions allowing the selective communication and in turn of each input with the output while the other inputs are isolated from the exit.
  • Industrial applications in particular using hydrogen gas, include a gas distribution system connected to one or more pressure tanks.
  • pressurized hydrogen tanks can be connected in parallel to a fuel cell.
  • the emptying of the tanks is done sequentially, that is to say one after the other.
  • reversing units to preferentially empty one tank relative to the other. These plants are typically composed of two regulators mounted in parallel and set at two different expansion pressures. The tank connected to the line with the regulator set at the highest expansion pressure is then emptied first. These reversing units are adapted to the case of two tanks connected to the application.
  • the safety gas shutdown function is provided downstream by a solenoid valve on the common circuit.
  • a known system uses a bayonet comprising as many solenoid valves as tanks connected in parallel to the same user output.
  • a PLC ensures the opening sequences of the solenoid valves according to the tank to be drained.
  • These installations require a large number of valves and fuses as well as a programming logic of the control automaton of the assembly. This architecture is expensive and not very compact and increases the probability of nuisance tripping of the fuses.
  • An object of the present invention is to overcome all or part of the disadvantages of the prior art noted above.
  • the device according to the invention is essentially characterized in that the device comprises an emergency evacuation system movable in an active position. wherein all the gas inlets are forced into forced connection simultaneously with a gas exhaust outlet.
  • embodiments of the invention may include one or more of the following features:
  • the emergency evacuation system comprises a thermal fuse
  • the emergency evacuation system comprises a selectively movable actuator manually or electromechanically
  • the actuator is movable in translation and comprises an end protruding outside the casing with a view to its actuation
  • the emergency evacuation system is movable from a neutral position to the active position, in the neutral position the emergency evacuation system allowing the selective displacement of the dispensing member in the dispensing positions, in position active, the emergency evacuation system moving the dispenser member in a disengaged position preventing said dispensing positions,
  • the dispenser member is constrained by a return member to the disengaged position and that in neutral position the emergency evacuation system forms a removable stop preventing the displacement of the dispensing member to the disengaged position ,
  • the dispensing member is rotatable relative to the body, said dispensing positions being defined by respective angular positions of the dispensing member relative to the body and the inputs,
  • the dispensing member is movable in translation relative to the body to the disengaged position
  • the dispensing member comprises an internal channel having a downstream end in communication with the outlet and an upstream end capable of being placed in communication with one or all the inlets according to the position of the dispensing member relative to the body; - the emergency evacuation system is repositionable in its neutral position after being moved to the active position,
  • the emergency evacuation system comprises a thermal fuse comprising a metal eutectic having a determined melting temperature of between 85 ° C. and 120 ° C. and preferably between 105 ° C. and 115 ° C.,
  • the housing consists of one or more assembled parts
  • the housing comprises an outlet for evacuating any internal leaks
  • the device comprises one or more seals ensuring the fluidic sealing of the gas path between the moving parts relative to each other
  • the dispenser member is rotatably mounted relative to the housing about an axis mounted on the housing;
  • the gas evacuation outlet coincides with the outlet intended to be connected to a user organ of the gas.
  • the invention also relates to a gas distribution installation from several pressurized gas sources used sequentially to supply a user, the installation comprising a dispensing device according to any one of the above characteristics or below. said sources being respectively fluidly connected to the gas inlets of the housing, the user being fluidly connected to the outlet of the housing.
  • the invention may also relate to any alternative device or method comprising any combination of the above or below features.
  • FIG. 1 represents a schematic and partial view illustrating the structure of an exemplary gas distribution installation according to the invention
  • FIG. 2 represents a schematic and partial rear view of a first example of a gas distribution device according to the invention
  • FIG. 3 represents a view in longitudinal section along the line AA of the gas distribution device of FIG. 2,
  • FIG. 4 represents a schematic and partial rear view of a second example of a gas distribution device according to the invention
  • FIG. 5 represents a view in longitudinal section along the line AA of the gas distribution device of FIG. 4.
  • FIG. 1 illustrates a nonlimiting example of an installation comprising four gas sources (E1 to E4) such as pressurized gas tanks (for example hydrogen).
  • the four sources E1 to E4 are connected in parallel to a gas distributor device comprising an output S1 connected to a user U of gas (for example a fuel cell).
  • the four sources E1 to E4 are fluidly connected to respective inputs 1, 2, 3, 4 of the disassembly device 14.
  • the allocation device is operable to supply the user U from the drained sources sequentially.
  • the dispensing device 14 has an emergency evacuation system 7, 27 for purging the gas coming from said sources E1 to E4, the emergency evacuation system 7, 27 being common to all four gas sources.
  • This emergency evacuation system 7, 17 evacuates the gas to an outlet in a controlled manner and / or in response to a dangerous situation (in the event of a fire, for example).
  • the gas distribution device 14 comprises a housing 20, 30, for example consisting of two parts 20, 30.
  • the housing 20, 30 comprises at one of its several orifices forming gas inlets 1, 2, 3, 4 intended to be connected to respective gas sources E1, E2, E3, E4.
  • Another end of the housing 20, 30 comprises an orifice forming a gas outlet S1 intended to be connected to a user unit U of the gas supplied by the sources E1, E2, E3, E4.
  • a dispensing member 9 is movably disposed in the body 20, 30.
  • the dispensing member 9 is selectively movable relative to the body 20, 30 and the inputs 1, 2, 3, 4 in different dispensing positions allowing the selectively and successively placing each input 1, 2, 3, 4 with the output S1 (while the other inputs are isolated from the output S1).
  • the dispensing member 9 is rotatable in the housing 20, 30 about a longitudinal axis 1 1 1 mounted in the housing 20, 30.
  • the detecting member 9 includes a can 1 ntern e having u not end downstream in communication with the output S1 and an upstream end may be placed in communication with one or all the inputs 1, 2, 3, 4 according to the position of the dispensing member 9 relative to the body 2, 13.
  • the angular position of the dispensing member 9 is for example controlled via an electromagnetic actuator or quite the appropriate control system (not shown).
  • the four inputs 1, 2, 3, 4 are arranged at 90 degrees relative to each other with respect to the axis 1 1 1.
  • the inputs 1 to 4 can therefore be put successively in communication with the output S1 via the channel 10.
  • the distribution member 9 passes through positions at 45 ° in which there is an isolation between the output S1 the inputs 1 to 4.
  • the dispensing member 9 is sealed against the face of the housing 20 provided with the inputs 1 to 4 via a return element such as one or more springs 17 and / or one or more washers of Belleville .
  • the seal between the channel 10 and the orifices may be provided by one or more O-rings or any other suitable means.
  • the return element 17 which forces the dispensing member 9 against the inlets 1 to 4 is supported for example on a thermal fuse 7 and an actuator forming a mechanical spacer 27.
  • Another element 1 1 reminder such as a spring (including a compression spring) biases the dispensing member 9 towards the output S1. In this so-called neutral position, the emergency evacuation system 7, 17, 27 allows a normal (sequential) operation of the dispenser 14.
  • the emergency evacuation system 7, 1 1, 17, 27, however, is movable in a so-called active position in which all the gas inlets 1, 2, 3, 4 are forced in relation simultaneously with an evacuation outlet. gas.
  • the fuse 7 melts from a determined temperature threshold.
  • the return member 1 1 then slides the dispensing member 9 longitudinally to the outlet S1.
  • the seal between the channel 10 and the face of the housing 20,30 is then lost. In this position, all the inputs 1 to 4 are then simultaneously in communication with the output S1 and an optional natural leakage orifice 13.
  • the actuator 27 is movable in translation in the housing 20, 30 and comprises an end projecting outside the housing to allow its actuation.
  • a new thermal fuse 7 and / or the actuator 27 are repositionable (reset in neutral position).
  • the evacuation of the gas when switching to the active position is performed for example via the output S1.
  • this evacuation of the gas borrows another dedicated orifice for this purpose.
  • the inputs 1, 2, 3, 4 can be placed in fluid communication with another discharge port.
  • the housing 2, 30 may also include an orifice 13 for collecting and evacuating natural leaks which would occur at the seal 12 and between the inputs 1 to 4 and the outlet S1.
  • the outlet S1 may coincide with a pipe 15 which engages inside the housing 20, 30 or even within a housing of the body of the dispensing member 9.
  • One or more seals 16 may be provided to seal between the pipe 15 and the housing 20, 30 and the dispensing member 9. This piping can also provide a guiding function of the dispensing member 9 in its translation between the neutral position and the active position.
  • FIGS. 4 and 5 differs from those of FIGS. 2 and 3 only in that it does not comprise an actuator. That is, only a thermal fuse keeps the dispensing member 9 in the dispensing positions.
  • a thermal fuse keeps the dispensing member 9 in the dispensing positions.
  • the invention thus makes it possible to achieve a sequential supply of several gas sources with a safety evacuation system which purges the installation in case of fire and / or in case of a situation deemed dangerous via a separate command.
  • the structure is simpler and less expensive than existing solutions.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)

Abstract

The invention relates to a gas-dispensing device for connecting a plurality of pressurized gas sources (E1, E2, E3, E4) to a user (U), the device including a housing (20, 30) provided with a plurality of gas inlets (1, 2, 3, 4) to be connected to respective gas sources (E1, E2, E3, E4) and an outlet (S1) to be connected to a user member (U), a dispensing member (9) that selectively movable, relative to the body (20, 30), into separate dispensing positions for selectively putting each inlet (1, 2, 3, 4) in communication with the outlet (S1) in turn, while the other inlets are isolated from the outlet (S1), characterized in that the device comprises an emergency discharge system (7, 1 1, 17, 27) that is movable into an operative position in which all the gas inlets (1, 2, 3, 4) are simultaneously forcedly connected to a gas discharge outlet.

Description

Dispositif de distribution de gaz et installation comportant un tel dispositif.  Gas distribution device and installation comprising such a device.
La présente invention concerne un dispositif et u ne instal lation de distribution de gaz. The present invention relates to a device and a gas distribution installation.
L'invention concerne plus particulièrement un dispositif de distribution de gaz pou r mettre en relation de façon séquentielle plusieurs sources de gaz sous pression avec un utilisateur, le dispositif comprenant un boîtier muni de plusieurs entrées de gaz destinées à être raccordées à des sources de gaz respectives et une sortie destinée à être raccordée à un organe utilisateur, un organe de distribution sélectivement mobile relativement au corps dans des positions de distribution distinctes permettant la mise en communication sélective et tour à tour de chaque entrée avec la sortie tandis que les autres entrées sont isolées de la sortie.  More particularly, the invention relates to a gas distribution device for sequentially relating multiple sources of pressurized gas to a user, the device comprising a housing having a plurality of gas inlets for connection to gas sources. respective and an output intended to be connected to a user member, a selectively movable distribution member relative to the body in different distribution positions allowing the selective communication and in turn of each input with the output while the other inputs are isolated from the exit.
Des applications industrielles, notamment utilisant de l'hydrogène gazeux, comprennent un système de distribution de gaz relié à un ou plusieurs réservoirs sous pression.  Industrial applications, in particular using hydrogen gas, include a gas distribution system connected to one or more pressure tanks.
Par exemple, dans certaines applications util isant l'hydrogène comme vecteur d'énergie, plusieurs réservoirs d'hydrogène sous pression peuvent être reliés en parallèle à une pile à combustible. La vidange des réservoirs est faite séquentiellement, c'est-à-dire l'un après l'autre.  For example, in some applications using hydrogen as an energy carrier, several pressurized hydrogen tanks can be connected in parallel to a fuel cell. The emptying of the tanks is done sequentially, that is to say one after the other.
La plupart des installations existantes utilisent des centrales d'inversion permettant de vider préférentiellement un réservoir par rapport à l'autre. Ces centrales sont typiquement composées de deux détendeurs montés en parallèles et réglés à deux pressions de détente différentes. Le réservoir branché sur la ligne comportant le détendeur réglé à la plus haute pression de détente se vide alors en premier. Ces centrales d'inversion sont adaptées au cas de deux réservoirs connectés à l'application. La fonction de coupure de gaz de sécurité est assurée en aval par une électrovanne sur le circuit commun.  Most of the existing installations use reversing units to preferentially empty one tank relative to the other. These plants are typically composed of two regulators mounted in parallel and set at two different expansion pressures. The tank connected to the line with the regulator set at the highest expansion pressure is then emptied first. These reversing units are adapted to the case of two tanks connected to the application. The safety gas shutdown function is provided downstream by a solenoid valve on the common circuit.
Pour parer aux conséquences d'un incendie il est possible d'installer un fusible thermique sur chaque ligne, en amont de la centrale d'inversion.  To avoid the consequences of a fire, it is possible to install a thermal fuse on each line, upstream of the reversing unit.
Dans le cas où plus de deux réservoirs sont connectés en parallèle, les centrales d'inversion doivent être remplacées par d'autres dispositifs. Par exemple, un système connu utilise une baïonnette comprenant autant d'électrovannes que de réservoirs reliés en parallèle à la même sortie utilisateur. Un automate assure les séquences d'ouverture des électrovannes en fonction du réservoir à vidanger. Pour protéger les réservoirs du feu via un clapet d'évacuation sensible à la chaleur (fusible thermique notamment), il est alors nécessaire d'installer un tel clapet sur chaque ligne (en plus de chaque électrovanne). Ces installations nécessitent un grand nombre de vannes et fusibles ainsi qu'une logique de programmation de l'automate de contrôle de l'ensemble. Cette architecture et coûteuse, peu compacte et augmente la probabilité de déclenchements intempestifs des fusibles. In the case where more than two tanks are connected in parallel, the reversing units must be replaced by other devices. For example, a known system uses a bayonet comprising as many solenoid valves as tanks connected in parallel to the same user output. A PLC ensures the opening sequences of the solenoid valves according to the tank to be drained. To protect the fire tanks via a heat-sensitive discharge valve (particularly thermal fuse), it is then necessary to install such a valve on each line (in addition to each solenoid valve). These installations require a large number of valves and fuses as well as a programming logic of the control automaton of the assembly. This architecture is expensive and not very compact and increases the probability of nuisance tripping of the fuses.
Un but de la présente invention est de pallier tout ou partie des inconvénients de l'art antérieur relevés ci-dessus.  An object of the present invention is to overcome all or part of the disadvantages of the prior art noted above.
A cette fin, le dispositif selon l'invention, par ailleurs conforme à la définition générique qu'en donne le préambule ci-dessus, est essentiellement caractérisé en ce que le dispositif comporte un système d'évacuation d'urgence déplaçable dans une position active dans laquelle toutes les entrées de gaz sont mise en relation forcée simultanément avec une sortie d'évacuation de gaz.  To this end, the device according to the invention, furthermore in accordance with the generic definition given in the preamble above, is essentially characterized in that the device comprises an emergency evacuation system movable in an active position. wherein all the gas inlets are forced into forced connection simultaneously with a gas exhaust outlet.
Par ailleurs, des modes de réalisation de l'invention peuvent comporter l'une ou plusieurs des caractéristiques suivantes :  Furthermore, embodiments of the invention may include one or more of the following features:
- le système d'évacuation d'urgence comprend un fusible thermique, - le système d'évacuation d'urgence comprend un actionneur sélectivement mobile manuellement ou de façon électromécanique,  the emergency evacuation system comprises a thermal fuse, the emergency evacuation system comprises a selectively movable actuator manually or electromechanically,
- l'actionneur est mobile en translation et comprend une extrémité faisant saillie en dehors du boîtier en vue de son actionnement,  the actuator is movable in translation and comprises an end protruding outside the casing with a view to its actuation,
- le système d'évacuation d'urgence est déplaçable d'une position neutre vers la position active, en position neutre le système d'évacuation d'urgence autorisant le déplacement sélectif de l'organe de distribution dans les positions de distribution, en position active, le système d'évacuation d'urgence déplaçant l'organe de distribution dans une position débrayée empêchant lesdites positions de distribution,  - the emergency evacuation system is movable from a neutral position to the active position, in the neutral position the emergency evacuation system allowing the selective displacement of the dispensing member in the dispensing positions, in position active, the emergency evacuation system moving the dispenser member in a disengaged position preventing said dispensing positions,
- l'organe de distribution est contraint par un organe de rappel vers la position débrayée et en ce qu'en position neutre le système d'évacuation d'urgence forme une butée amovible empêchant le déplacement de l'organe de distribution vers la position débrayée,  - The dispenser member is constrained by a return member to the disengaged position and that in neutral position the emergency evacuation system forms a removable stop preventing the displacement of the dispensing member to the disengaged position ,
- l'organe de distribution est mobile en rotation relativement au corps, lesdites positions de distribution étant définies par des positions angulaires respectives de l'organe de distribution par rapport au corps et aux entrées,  - The dispensing member is rotatable relative to the body, said dispensing positions being defined by respective angular positions of the dispensing member relative to the body and the inputs,
- l'organe de distribution est déplaçable en translation relativement au corps vers la position débrayée,  - The dispensing member is movable in translation relative to the body to the disengaged position,
- l'organe de distribution comprend un canal interne ayant une extrémité aval en communication avec la sortie et une extrémité amont susceptible d'être mise en communication avec une ou toutes les entrées selon la position de l'organe de distribution relativement au corps, - le système d'évacuation d'urgence est repositionnable dans sa position neutre après avoir été déplacé en position active, the dispensing member comprises an internal channel having a downstream end in communication with the outlet and an upstream end capable of being placed in communication with one or all the inlets according to the position of the dispensing member relative to the body; - the emergency evacuation system is repositionable in its neutral position after being moved to the active position,
- le système d'évacuation d'urgence comprend un fusible thermique comprenant un eutectique métallique ayant une température de fusion déterminée comprise entre 85°C et 120 °C degrés et de préférence comprise entre 105°C et 1 15°C degrés,  the emergency evacuation system comprises a thermal fuse comprising a metal eutectic having a determined melting temperature of between 85 ° C. and 120 ° C. and preferably between 105 ° C. and 115 ° C.,
- le boîtier est constitué d'une pièce ou plusieurs pièces assemblées, the housing consists of one or more assembled parts,
- le boîtier comprend une sortie d'évacuation d'éventuelles fuites internes,the housing comprises an outlet for evacuating any internal leaks,
- le dispositif comprend un ou des joints d'étanchéité assurant l'étanchéité fluidique du trajet de gaz entre les pièces mobiles les unes par rapport aux autresthe device comprises one or more seals ensuring the fluidic sealing of the gas path between the moving parts relative to each other
(en particulier entre le boîtier et l'organe de distribution), (in particular between the housing and the dispensing member),
- l'organe de distribution est monté rotatif relativement au boîtier autour d'un axe monté sur le boîtier,  the dispenser member is rotatably mounted relative to the housing about an axis mounted on the housing;
- la sortie d'évacuation de gaz coïncide avec la sortie destinée à être raccordée à un organe utilisateur du gaz.  the gas evacuation outlet coincides with the outlet intended to be connected to a user organ of the gas.
L'invention concerne également une installation de distribution de gaz à partir de plusieurs sources de gaz sous pression utilisées séquentiellement pour alimenter un utilisateur, l'installation comprenant un dispositif de distribution conforme à l'une quelconque des caractéristiques ci-dessus ou ci-dessous, lesdites sources étant raccordées fluidiquement respectivement aux entrées de gaz du boîtier, l'utilisateur étant raccordé fluidiquement avec la sortie du boîtier.  The invention also relates to a gas distribution installation from several pressurized gas sources used sequentially to supply a user, the installation comprising a dispensing device according to any one of the above characteristics or below. said sources being respectively fluidly connected to the gas inlets of the housing, the user being fluidly connected to the outlet of the housing.
L'invention peut concerner également tout dispositif ou procédé alternatif comprenant toute combinaison des caractéristiques ci-dessus ou ci-dessous.  The invention may also relate to any alternative device or method comprising any combination of the above or below features.
D'autres particu larités et avantages apparaîtront à la lectu re de la description ci-après, faite en référence aux figures dans lesquelles :  Other particularities and advantages will appear on reading the description below, with reference to the figures in which:
- la figure 1 représente une vue schématique et partielle illustrant la structure d'un exemple d'installation de distribution de gaz selon l'invention,  FIG. 1 represents a schematic and partial view illustrating the structure of an exemplary gas distribution installation according to the invention,
- la figure 2 représente une vue de derrière, schématique et partielle, d'un premier exemple de dispositif de distribution de gaz selon l'invention,  FIG. 2 represents a schematic and partial rear view of a first example of a gas distribution device according to the invention,
- la figure 3 représente une vue en coupe longitudinale selon la ligne AA du dispositif de distribution de gaz de la figure 2,  FIG. 3 represents a view in longitudinal section along the line AA of the gas distribution device of FIG. 2,
- la figure 4 représente une vue de derrière, schématique et partielle, d'un deuxième exemple de dispositif de distribution de gaz selon l'invention,  FIG. 4 represents a schematic and partial rear view of a second example of a gas distribution device according to the invention,
- la figure 5 représente une vue en coupe longitudinale selon la ligne AA du dispositif de distribution de gaz de la figure 4.  FIG. 5 represents a view in longitudinal section along the line AA of the gas distribution device of FIG. 4.
La figure 1 illustre un exemple non limitatif d'installation comprenant quatre sources de gaz (E1 à E4) tel que des réservoirs de gaz sous pression (par exemple de l'hydrogène). Les quatre sources E1 à E4 sont reliées en parallèle à un dispositif 14 distributeur de gaz comprenant une sortie S1 reliée à un utilisateur U de gaz (par exemple une pile à combustible). Les quatre sources E1 à E4 sont raccordées fluidiquement à des entrées 1 , 2, 3, 4 respectives du dispositif 14 de d istribution . Le d ispositif de d istribution est commandable pour al imenter l'utilisateur U à partir des sources vidangées de façon séquentielle. FIG. 1 illustrates a nonlimiting example of an installation comprising four gas sources (E1 to E4) such as pressurized gas tanks (for example hydrogen). The four sources E1 to E4 are connected in parallel to a gas distributor device comprising an output S1 connected to a user U of gas (for example a fuel cell). The four sources E1 to E4 are fluidly connected to respective inputs 1, 2, 3, 4 of the disassembly device 14. The allocation device is operable to supply the user U from the drained sources sequentially.
Selon une caractéristique avantageuse de l'invention, le dispositif 14 de distribution possède un système 7, 27 d'évacuation d'urgence permettant de purger le gaz provenant desdites sources E1 à E4, le système 7, 27 d'évacuation d'urgence étant commun aux quatre sources de gaz. Ce système 7, 17 d'évacuation d'urgence évacue le gaz vers une sortie de façon commandée et/ou en réponse à une situation dangereuse (en cas de feu par exemple).  According to an advantageous characteristic of the invention, the dispensing device 14 has an emergency evacuation system 7, 27 for purging the gas coming from said sources E1 to E4, the emergency evacuation system 7, 27 being common to all four gas sources. This emergency evacuation system 7, 17 evacuates the gas to an outlet in a controlled manner and / or in response to a dangerous situation (in the event of a fire, for example).
Dans l'exempl e de réalisation non imitatif décrit aux figures 2 et 3, le dispositif 14 de distribution de gaz comporte un boîtier 20, 30, par exemple constitué de deux parties 20, 30. Le boîtier 20, 30 comprend à une de ses extrémités plusieurs orifices formant des entrées de gaz 1 , 2, 3, 4 destinées à être raccordées à des sources de gaz E1 , E2, E3, E4 respectives. Une autre extrémité du boîtier 20, 30 comprend un orifice formant une sortie S1 de gaz destinée à être raccordée à un organe utilisateur U du gaz fourni par les sources E1 , E2, E3, E4.  In the non-imitative exemplary embodiment described in FIGS. 2 and 3, the gas distribution device 14 comprises a housing 20, 30, for example consisting of two parts 20, 30. The housing 20, 30 comprises at one of its several orifices forming gas inlets 1, 2, 3, 4 intended to be connected to respective gas sources E1, E2, E3, E4. Another end of the housing 20, 30 comprises an orifice forming a gas outlet S1 intended to be connected to a user unit U of the gas supplied by the sources E1, E2, E3, E4.
Un organe 9 de distribution est disposé de façon mobile dans le corps 20, 30. L'organe 9 de distribution est sélectivement mobile relativement au corps 20, 30 et aux entrées 1 , 2, 3, 4 dans des positions de distribution distinctes permettant la mise en communication sélective et tour à tour de chaque entrée 1 , 2, 3, 4 avec la sortie S1 (pendant que les autres entrées sont isolées de la sortie S1 ).  A dispensing member 9 is movably disposed in the body 20, 30. The dispensing member 9 is selectively movable relative to the body 20, 30 and the inputs 1, 2, 3, 4 in different dispensing positions allowing the selectively and successively placing each input 1, 2, 3, 4 with the output S1 (while the other inputs are isolated from the output S1).
Par exemple, l'organe 9 de distribution est rotatif dans le boîtier 20, 30 autour d'un axe 1 1 1 longitudinal monté dans le boîtier 20, 30. L'organe 9 de d istri bution com prend u n cana l 1 0 i ntern e ayant u ne extrém ité aval en communication avec la sortie S1 et une extrémité amont susceptible d'être mise en communication avec une ou toutes les entrées 1 , 2, 3, 4 selon la position de l'organe 9 de distribution relativement au corps 2, 13. La position angulaire de l'organe 9 de distribution est par exemple commandée via un actionneur électromagnétique ou tout a u tre système de commande approprié (non représenté).  For example, the dispensing member 9 is rotatable in the housing 20, 30 about a longitudinal axis 1 1 1 mounted in the housing 20, 30. The detecting member 9 includes a can 1 ntern e having u not end downstream in communication with the output S1 and an upstream end may be placed in communication with one or all the inputs 1, 2, 3, 4 according to the position of the dispensing member 9 relative to the body 2, 13. The angular position of the dispensing member 9 is for example controlled via an electromagnetic actuator or quite the appropriate control system (not shown).
Par exemple, les quatre entrées 1 , 2, 3, 4 sont disposées à 90 degrés les unes relativement aux autres par rapport à l'axe 1 1 1 . De cette façon, à chaque rotation de 90 degrés, les entrées 1 à 4 peuvent donc être mises successivement en communication avec la sortie S1 via le canal 10. Comme représenté, entre deux positions de distribution, l'organe 9 de distribution passe par des positions à 45° dans lesquelles il y a une isolation entre la sortie S1 les entrées 1 à 4. Selon une architecture possible, l'organe 9 de distribution est contraint de façon étanche contre la face du boîtier 20 pourvue des entrées 1 à 4 via un élément de rappel tel qu'un ou des ressorts 17 et/ou une ou des rondelles de Belleville. L'étanchéité entre le canal 10 et les orifices peut être assurée par un ou des joints 12 torique ou tout autre moyen approprié. For example, the four inputs 1, 2, 3, 4 are arranged at 90 degrees relative to each other with respect to the axis 1 1 1. In this way, at each rotation of 90 degrees, the inputs 1 to 4 can therefore be put successively in communication with the output S1 via the channel 10. As shown, between two distribution positions, the distribution member 9 passes through positions at 45 ° in which there is an isolation between the output S1 the inputs 1 to 4. According to one possible architecture, the dispensing member 9 is sealed against the face of the housing 20 provided with the inputs 1 to 4 via a return element such as one or more springs 17 and / or one or more washers of Belleville . The seal between the channel 10 and the orifices may be provided by one or more O-rings or any other suitable means.
L'élément 17 de rappel qui contraint l'organe 9 de distribution contre les entrées 1 à 4 prend appui par exemple sur un fusible thermique 7 et un actionneur formant une cale 27 mécanique.  The return element 17 which forces the dispensing member 9 against the inlets 1 to 4 is supported for example on a thermal fuse 7 and an actuator forming a mechanical spacer 27.
Un autre élément 1 1 de rappel tel qu'un ressort (notamment un ressort de compression) sollicite l'organe 9 de distribution en direction de la sortie S1 . Dans cette position dite neutre le système 7, 17, 27 d'évacuation d'urgence permet un fonctionnement normal (séquentiel) du distributeur 14.  Another element 1 1 reminder such as a spring (including a compression spring) biases the dispensing member 9 towards the output S1. In this so-called neutral position, the emergency evacuation system 7, 17, 27 allows a normal (sequential) operation of the dispenser 14.
Le système 7, 1 1 , 17, 27 d'évacuation d'urgence est cependant déplaçable dans une position dite active dans laquelle toutes les entrées 1 , 2, 3, 4 de gaz sont mise en relation forcée simultanément avec une sortie d'évacuation de gaz.  The emergency evacuation system 7, 1 1, 17, 27, however, is movable in a so-called active position in which all the gas inlets 1, 2, 3, 4 are forced in relation simultaneously with an evacuation outlet. gas.
Par exemple, en cas de feu, le fusible 7 fond à partir d'un seuil de température déterminé. L'organe de rappel 1 1 fait alors coulisser l'organe de distribution 9 longitudinalement vers la sortie S1 . L'étanchéité entre le canal 10 et la face du boîtier 20,30 est alors perdue. Dans cette position, toutes les entrées 1 à 4 sont alors en simultanément en communication avec la sortie S1 et un orifice de fuite naturelle 13 facultatif.  For example, in the event of a fire, the fuse 7 melts from a determined temperature threshold. The return member 1 1 then slides the dispensing member 9 longitudinally to the outlet S1. The seal between the channel 10 and the face of the housing 20,30 is then lost. In this position, all the inputs 1 to 4 are then simultaneously in communication with the output S1 and an optional natural leakage orifice 13.
Le même résultat se produit lorsque la cale 27 est déplacée (manuellement ou automatiquement). Par exemple l'actionneur 27 est mobile en translation dans le boîtier 20, 30 et comprend une extrémité faisant saillie en dehors du boîtier pour permettre son actionnement.  The same result occurs when shim 27 is moved (manually or automatically). For example the actuator 27 is movable in translation in the housing 20, 30 and comprises an end projecting outside the housing to allow its actuation.
C'est-à-dire que deux commandes distinctes (via un fusible 7 thermique et/ou via un actionneur 27) permettent une évacuation d'urgence de gaz.  That is to say that two separate commands (via a thermal fuse 7 and / or via an actuator 27) allow an emergency evacuation of gas.
De préférence, un nouveau fusible 7 thermique et/ou l'actionneur 27 sont repositionnable (réarmement en position neutre).  Preferably, a new thermal fuse 7 and / or the actuator 27 are repositionable (reset in neutral position).
L'évacuation du gaz en cas de commutation en position active est réalisée par exemple via la sortie S1 . Bien entendu il est possible de prévoir que cette évacuation du gaz emprunte un autre orifice dédié à cet effet. Par exemple, en position active les entrées 1 , 2, 3, 4 peuvent être mises en communication fluidique avec un autre orifice d'évacuation.  The evacuation of the gas when switching to the active position is performed for example via the output S1. Of course it is possible to provide that this evacuation of the gas borrows another dedicated orifice for this purpose. For example, in the active position the inputs 1, 2, 3, 4 can be placed in fluid communication with another discharge port.
Le boîtier 2, 30 peut également comporter un orifice 13 de collecte et d'évacuation des fuites naturelles qui se produiraient au niveau de l'étanchéité 12 et entre les entrées 1 à 4 et la sortie S1 . Comme représenté, la sortie S1 peut coïncider avec une tuyauterie 15 qui s'engage à l'intérieur du boîtier 20, 30 voir même à l'intérieur d'un logement du corps de l'organe 9 de distribution. Un ou des joints 16 d'étanchéité peuvent être prévus pour assurer l'étanchéité entre la tuyauterie 15 et le boîtier 20, 30 et l'organe 9 de distribution. Cette tuyauterie peut également assurer une fonction de guidage de l'organe 9 de distribution dans sa translation entre la position neutre et la position active. The housing 2, 30 may also include an orifice 13 for collecting and evacuating natural leaks which would occur at the seal 12 and between the inputs 1 to 4 and the outlet S1. As shown, the outlet S1 may coincide with a pipe 15 which engages inside the housing 20, 30 or even within a housing of the body of the dispensing member 9. One or more seals 16 may be provided to seal between the pipe 15 and the housing 20, 30 and the dispensing member 9. This piping can also provide a guiding function of the dispensing member 9 in its translation between the neutral position and the active position.
La variante de réalisation représentée aux figures 4 et 5 se distingue de celles des figures 2 et 3 uniquement en ce qu'elle ne comporte pas d'actionneur. C'est-à-dire que seul un fusible thermique maintient l'organe 9 de distribution dans les positions de distribution. Par soucis de concision les éléments identiques à ceux décrits ci-dessus ne sont décrits une seconde fois et sont désignés par les mêmes références numériques.  The embodiment variant shown in FIGS. 4 and 5 differs from those of FIGS. 2 and 3 only in that it does not comprise an actuator. That is, only a thermal fuse keeps the dispensing member 9 in the dispensing positions. For the sake of brevity, the elements identical to those described above are not described a second time and are designated by the same reference numerals.
L'invention permet donc de réal iser une alimentation séquentielle de plusieurs sources de gaz avec un système d'évacuation de sécurité qui purge l'installation en cas de feu et/ou en cas de situation jugée dangereuse via une commande séparée.  The invention thus makes it possible to achieve a sequential supply of several gas sources with a safety evacuation system which purges the installation in case of fire and / or in case of a situation deemed dangerous via a separate command.
La structure est plus simple et moins coûteuse que les solutions existantes.  The structure is simpler and less expensive than existing solutions.

Claims

REVENDICATIONS
1 . Dispositif de distnbution de gaz pour mettre en relation de façon séquentielle plusieurs sources (E1 , E2, E3, E4) de gaz sous pression avec un utilisateur (U), le dispositif comprenant un boîtier (20, 30) muni de plusieurs entrées de gaz (1 , 2, 3, 4) destinées à être raccordées à des sources de gaz (E1 , E2, E3, E4) respectives et une sortie (S1 ) destinée à être raccordée à un organe utilisateur (U), un organe (9) de distribution sélectivement mobile relativement au corps (20, 30) dans des positions de distribution distinctes permettant la m ise en communication sélective et tour à tour de chaque entrée (1 , 2, 3, 4) avec la sortie (S1 ) tandis que les autres entrées sont isolées de la sortie (S1 ), caractérisé en ce que le dispositif comporte un système (7, 1 1 , 17, 27) d'évacuation d'urgence déplaçable dans une position active dans laquelle toutes les entrées (1 , 2, 3, 4) de gaz sont mise en relation forcée simultanément avec une sortie d'évacuation de gaz, le système (7, 1 1 , 17, 27) d'évacuation d'urgence étant déplaçable d'une position neutre vers la position active et en ce qu'en position neutre le système (7, 1 1 , 17, 27) d'évacuation d'urgence autorise le déplacement sélectif de l'organe (9) de distribution dans les positions de distribution en ce que, en position active, le système (7, 1 1 , 17, 27) d'évacuation d'urgence déplace l'organe (9) de distribution dans une position débrayée empêchant lesdites positions de distribution, l'organe (9) de distribution étant contraint par un organe (1 1 ) de rappel vers la position débrayée et en ce q u 'en position neutre le système (7, 1 1 , 17, 27) d'évacuation d'urgence forme une butée (7, 27) amovible empêchant le déplacement de l'organe (9) de distribution vers la position débrayée et en ce que le système (7, 1 1 , 17, 27) d'évacuation d'urgence comprend un fusible (7) thermique. 1. Gas distortion device for sequentially connecting a plurality of sources (E1, E2, E3, E4) of pressurized gas with a user (U), the device comprising a housing (20, 30) having a plurality of gas inlets (1, 2, 3, 4) for connection to respective gas sources (E1, E2, E3, E4) and an outlet (S1) for connection to a user member (U), a member (9) ) of selectively movable distribution relative to the body (20, 30) in discrete distribution positions allowing the selective communication and in turn communication of each input (1, 2, 3, 4) with the output (S1) while the other inputs are isolated from the output (S1), characterized in that the device comprises an emergency evacuation system (7, 1 1, 17, 27) movable in an active position in which all the inputs (1, 2, 3, 4) are forcedly connected simultaneously with an evacuation outlet of gas, the emergency evacuation system (7, 1 1, 17, 27) being movable from a neutral position to the active position and that in the neutral position the system (7, 1 1, 17, 27) for emergency evacuation allows the selective displacement of the dispensing member (9) in the dispensing positions in that, in the active position, the exhaust system (7, 1 1, 17, 27) emergency moves the dispensing member (9) into a disengaged position preventing said dispensing positions, the dispensing member (9) being constrained by a return member (1 1) to the disengaged position and in that neutral position the emergency evacuation system (7, 1 1, 17, 27) forms a removable stop (7, 27) preventing movement of the dispensing member (9) towards the disengaged position and in that the emergency evacuation system (7, 11, 17, 27) comprises a thermal fuse (7).
2. Dispositif selon la revendication 1 , caractérisé en ce que le système (7, 1 1 , 17, 2 7) d'évacuation d'urgence comprend un actionneur (27) sélectivement mobile manuellement ou de façon électromécanique.  2. Device according to claim 1, characterized in that the system (7, 1 1, 17, 2 7) emergency evacuation comprises an actuator (27) selectively movable manually or electromechanically.
3. Dispositif selon la revendication 2, caractérisé en ce que l'actionneur (27) est mobile en translation et comprend une extrémité faisant saillie en dehors du boîtier (2,3) en vue de son actionnement.  3. Device according to claim 2, characterized in that the actuator (27) is movable in translation and comprises an end projecting outside the housing (2,3) for its actuation.
4. Dispositif selon l'une quelconque des revendications 1 à 3, caractérisé en ce que l'organe (9) de distribution est mobile en rotation relativement au corps (20, 30), lesdites positions de distribution étant définies par des positions angulaires respectives de l'organe (9) de distribution par rapport au corps (2, 3) et aux entrées (1 , 2, 3, 4). 4. Device according to any one of claims 1 to 3, characterized in that the dispensing member (9) is rotatable relative to the body (20, 30), said dispensing positions being defined by respective angular positions. the dispensing member (9) with respect to the body (2, 3) and the inlets (1, 2, 3, 4).
5. Dispositif selon l'une quelconque des revendications 1 à 4, caractérisé en ce que l'organe (9) de distribution est déplaçable en translation relativement au corps (2, 3) vers la position débrayée. 5. Device according to any one of claims 1 to 4, characterized in that the member (9) of distribution is movable in translation relative to the body (2, 3) to the disengaged position.
6. Dispositif selon l'une quelconque des revendications 1 à 5, caractérisé en ce que l'organe (9) de distribution comprend un canal (10) interne ayant une extrémité aval en communication avec la sortie (S1 ) et une extrémité amont susceptible d'être mise en communication avec une ou toutes les entrées ( 1 , 2 , 3, 4) selon la position de l'organe (9) de distribution relativement au corps (2, 13).  6. Device according to any one of claims 1 to 5, characterized in that the member (9) of distribution comprises an internal channel (10) having a downstream end in communication with the output (S1) and an upstream end susceptible to be placed in communication with one or all the inputs (1, 2, 3, 4) according to the position of the dispensing member (9) relative to the body (2, 13).
7. Dispositif selon l'une quelconque des revendications 1 à 6, caractérisé en ce que le système d'évacuation d'urgence comprend un fusible (7) thermique comprenant un eutectique métallique ayant une température de fusion déterminée comprise entre 85°C et 120 °C degrés et de préférence comprise entre 105°C et 1 15°C degrés.  7. Device according to any one of claims 1 to 6, characterized in that the emergency evacuation system comprises a thermal fuse (7) comprising a metal eutectic having a determined melting temperature of between 85 ° C and 120 ° C. ° C degrees and preferably between 105 ° C and 1 15 ° C degrees.
8. Dispositif selon l'une quelconque des revendications 1 à 7, caractérisé en ce que le boîtier est constitué d'une pièce ou plusieurs pièces assemblées.  8. Device according to any one of claims 1 to 7, characterized in that the housing consists of one piece or several assembled parts.
9. Dispositif selon l'une quelconque des revendications 1 à 8, caractérisé en ce que la sortie d'évacuation de gaz coïncide avec la sortie destinée à être raccordée à un organe utilisateur du gaz.  9. Device according to any one of claims 1 to 8, characterized in that the gas discharge outlet coincides with the outlet intended to be connected to a user member of the gas.
10. Installation de distribution de gaz à partir de plusieurs sources (E1 , E2, E3, E4) de gaz sous pression utilisées séquentiellement pour alimenter un utilisateur (U), l'installation comprenant un dispositif de distribution conforme à l'une quelconque des revendications 1 à 9, lesdites sources (E1 , E2, E3, E4) étant raccordées fluidiquement respectivement aux entrées de gaz (1 , 2,3, 4) du boîtier (2, 3), l'utilisateur (U) étant raccordé fluidiquement avec la sortie (S1 ) du boîtier (2, 3).  10. Installation for distributing gas from a plurality of sources (E1, E2, E3, E4) of pressurized gas used sequentially to supply a user (U), the installation comprising a distribution device in accordance with any one of Claims 1 to 9, said sources (E1, E2, E3, E4) being respectively fluidly connected to the gas inlets (1, 2, 3, 4) of the housing (2, 3), the user (U) being fluidly connected with the output (S1) of the housing (2, 3).
EP11712938A 2010-04-02 2011-03-01 Gas-dispensing device and facility comprising such a device Withdrawn EP2553298A1 (en)

Applications Claiming Priority (2)

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FR1052496A FR2958368B1 (en) 2010-04-02 2010-04-02 DEVICE FOR DISTRIBUTING GAS AND INSTALLATION COMPRISING SUCH A DEVICE
PCT/FR2011/050413 WO2011121200A1 (en) 2010-04-02 2011-03-01 Gas-dispensing device and facility comprising such a device

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EP2553298A1 true EP2553298A1 (en) 2013-02-06

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EP (1) EP2553298A1 (en)
CN (1) CN102822578B (en)
CA (1) CA2788945A1 (en)
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WO (1) WO2011121200A1 (en)

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CN102822578B (en) 2014-07-16
WO2011121200A1 (en) 2011-10-06
US8931502B2 (en) 2015-01-13
CA2788945A1 (en) 2011-10-06
FR2958368B1 (en) 2012-07-27
CN102822578A (en) 2012-12-12
FR2958368A1 (en) 2011-10-07

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