EP2516355B1 - Schmelzbare/giessbare explosive zusammensetzung mit geringem schadenpotenzial - Google Patents
Schmelzbare/giessbare explosive zusammensetzung mit geringem schadenpotenzial Download PDFInfo
- Publication number
- EP2516355B1 EP2516355B1 EP10810766.5A EP10810766A EP2516355B1 EP 2516355 B1 EP2516355 B1 EP 2516355B1 EP 10810766 A EP10810766 A EP 10810766A EP 2516355 B1 EP2516355 B1 EP 2516355B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mass
- insensitive
- composition
- onta
- explosive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 101
- 239000002360 explosive Substances 0.000 title claims description 39
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims description 56
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 claims description 36
- 239000000015 trinitrotoluene Substances 0.000 claims description 36
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 32
- 229910052782 aluminium Inorganic materials 0.000 claims description 31
- 238000005266 casting Methods 0.000 claims description 21
- 239000000654 additive Substances 0.000 claims description 19
- 230000035945 sensitivity Effects 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 13
- 239000004411 aluminium Substances 0.000 claims description 11
- IAHOUQOWMXVMEH-UHFFFAOYSA-N 2,4,6-trinitroaniline Chemical compound NC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O IAHOUQOWMXVMEH-UHFFFAOYSA-N 0.000 claims description 3
- CVYZVNVPQRKDLW-UHFFFAOYSA-N 2,4-dinitroanisole Chemical compound COC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O CVYZVNVPQRKDLW-UHFFFAOYSA-N 0.000 claims description 3
- RSUBARQODWIKOQ-UHFFFAOYSA-N 3-methyl-2,4,6-trinitroaniline Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(N)=C1[N+]([O-])=O RSUBARQODWIKOQ-UHFFFAOYSA-N 0.000 claims description 3
- YYGJRRYSYLLCQH-UHFFFAOYSA-N 3-methyl-2,4,6-trinitrophenol Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C(O)=C1[N+]([O-])=O YYGJRRYSYLLCQH-UHFFFAOYSA-N 0.000 claims description 3
- CFYAUGJHWXGWHI-UHFFFAOYSA-N n-methyl-2,4,6-trinitroaniline Chemical compound CNC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O CFYAUGJHWXGWHI-UHFFFAOYSA-N 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 claims 1
- 238000005474 detonation Methods 0.000 description 11
- 238000001033 granulometry Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- UDHXJZHVNHGCEC-UHFFFAOYSA-N Chlorophacinone Chemical compound C1=CC(Cl)=CC=C1C(C=1C=CC=CC=1)C(=O)C1C(=O)C2=CC=CC=C2C1=O UDHXJZHVNHGCEC-UHFFFAOYSA-N 0.000 description 4
- 239000000028 HMX Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 description 3
- 230000037452 priming Effects 0.000 description 3
- 238000004088 simulation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- BEKZHETVNVFYCV-UHFFFAOYSA-N 1,3,8-trinitronaphthalene Chemical compound [O-][N+](=O)C1=CC=CC2=CC([N+](=O)[O-])=CC([N+]([O-])=O)=C21 BEKZHETVNVFYCV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000002238 attenuated effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000001788 irregular Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- KRQUFUKTQHISJB-YYADALCUSA-N 2-[(E)-N-[2-(4-chlorophenoxy)propoxy]-C-propylcarbonimidoyl]-3-hydroxy-5-(thian-3-yl)cyclohex-2-en-1-one Chemical compound CCC\C(=N/OCC(C)OC1=CC=C(Cl)C=C1)C1=C(O)CC(CC1=O)C1CCCSC1 KRQUFUKTQHISJB-YYADALCUSA-N 0.000 description 1
- 206010001488 Aggression Diseases 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000016571 aggressive behavior Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0033—Shaping the mixture
- C06B21/005—By a process involving melting at least part of the ingredients
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/02—Compositions or products which are defined by structure or arrangement of component of product comprising particles of diverse size or shape
Definitions
- the patent EP814069 thus describes a number of compositions associating a fuse part and a solid part.
- the fusible portion essentially comprises a nitrated aromatic such as Trinitrotoluene (TNT) which is associated with a phlegmatizer such as wax.
- TNT Trinitrotoluene
- the solid part generally comprises oxynitrotriazole (ONTA) which is a grain explosive whose vulnerability is reduced. ONTA is more particularly described by the patent EP-210881 .
- RDX reduced sensitivity Hexogen
- This insensitive Hexogene (known commercially under the brand name i-RDX deposited by Eurenco or under the name RS-RDX) is described in particular by US Pat. FR2887544 and FR2917169 .
- Table 1 below explains the results obtained: ⁇ b> Table 1 ⁇ / b> Explosive compositions Number of cards Impact pressure (Giga Pascals) TNT 40% / RDX insensitive 60% (supplier A) 234 1.7 TNT 40% / RDX insensitive 60% (supplier B) 234 1.7 TNT 40% / RDX not insensitive 60% 235 1.7
- the aim of the invention is to propose a fuse / flowable explosive composition with reduced vulnerability and in which the proportion of Hexogen (RDX) is increased relative to the proportion of oxynitrotriazole (ONTA) (which increases the detonation performances) but without diminishing the insensitivity of the composition thus obtained.
- RDX Hexogen
- ONTA oxynitrotriazole
- the subject of the invention is an explosive fuse / castable composition with reduced vulnerability, and comprising, on the one hand, a fusible part formed of at least one fusible explosive, and on the other hand a solid part comprising oxynitrotriazole.
- ONTA and Hexogen (RDX), a composition which is characterized in that the Hexogen is a Hexogen with reduced sensitivity, the granulometry of the insensitive Hexogene being between 315 micrometers and 800 micrometers, while the particle size of ONTA is between 200 micrometers and 400 micrometers, ONTA also has a bulk density greater than or equal to 0.95 g / cm 3 .
- the fusible explosive may be chosen from the following compounds: Trinitrotoluene, 2,4,6-Trinitro-N-methyl-Aniline, 2,4,6-Trinitro-3-methylphenol, 3 -Amino-Trinitrotoluene, 2,4,6-Trinitro-Aniline, 1,3,8-TriNitroNaphthalene and its isomeric mixture fusible at 115 ° C, 2,4-dinitroanisole (DNAN).
- the fusible portion will advantageously be between 30% and 40% of the total mass of the composition.
- the inventors have however chosen a larger particle size (thus a priori less suitable) because its association with the 200 to 400 micrometer particle size cut for ONTA leads to a lower porosity for the ONTA / RDX / Aluminum granular mixture and also for the composition. explosive which is then performed after casting TNT.
- ONTA type 1 is an ONTA with rounded, spheroidal grains with relatively few surface irregularities.
- ONTA type 2 is an ONTA whose grains have a more irregular outer shape.
- the figure 1 shows a grain photograph of a type 1 ONTA.
- figure 2 shows a grain photograph of a type 2 ONTA. These photographs were taken under a scanning electron microscope.
- the apparent density ⁇ b of ONTA Type 2 tested is between 0.75 g / cm3 and 0.85 g / cm3.
- the inventors have therefore sought to combine particle size fractions of oxynitrotriazole (having the most rounded grains) and insensitive Hexogene which make it possible to reduce this porosity. Cutting optimization granulometry and the choice of a ONTA with high apparent density have resulted in compactness of the optimal granular phase.
- This composition has a detonation velocity of 7250 m / s and a sensitivity criterion Cs of 115 Kcal 2 / mol. Its porosity is 0.3%.
- This composition has a detonation velocity of 7090 m / s and a sensitivity criterion Cs of 108 Kcal 2 / mol. Its porosity is 0.3%.
- This composition has a detonation velocity of 7177 m / sec and a test sensitivity of Cs 2 112 kcal / mol. Its porosity is 0.4%.
- This composition has a detonation velocity of 7075 m / s and a sensitivity criterion Cs of 106 Kcal 2 / mol. Its porosity is 0.4%.
- the explosive composition according to the invention can be used for the loading of all types of projectiles and military heads.
- This composition can be used to load artillery shells or the bodies of bombs or missiles.
- the solid part will then be incorporated in the fused part by homogenizing the mixture (in a tank equipped with a mixer).
- the melting and mixing will be carried out under vacuum.
- Casting in the ammunition body will also be performed under vacuum.
- a casting equipment that can be used for such a vacuum casting is described by the patent FR2923005 .
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mold Materials And Core Materials (AREA)
Claims (8)
- Explosive, schmelzbare/gießfähige Zusammensetzung mit verminderter Verletzbarkeit und aufweisend einerseits einen schmelzbaren Teil, welcher aus mindestens einem schmelzbaren Sprengstoff gebildet ist und andererseits einen festen Teil, welcher Oxinitrotriazol (ONTA) und Hexogen (RDX) und optional Aluminium aufweist, wobei die Zusammensetzung dadurch gekennzeichnet ist, dass das Hexogen ein Hexogen mit verminderter Empfindlichkeit ist, die Korngröße des unempfindlichen Hexogens zwischen 315 Mikrometer und 800 Mikrometer liegt, während die Korngröße des ONTA zwischen 200 Mikrometer und 400 Mikrometer liegt, wobei das ONTA außerdem eine Schüttdichte von größer oder gleich 0,95 g/cm3 besitzt,
und dass der feste Teil Folgendes verknüpft:- 15% bis 35% in Masse Oxinitrotriazol,- 24% bis 50% in Masse unempfindliches Hexogen und- 0 bis 25% in Masse Aluminium,wobei die Masseprozente auf die Gesamtmasse des festen Teils bezogen sind. - Explosive Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, dass der schmelzbare Sprengstoff aus den folgenden Verbindungen ausgewählt wird: Trinitrotoluen, 2,4,6-Trinitro-N-Methylanilin, 2,4,6-Trinitro-3-Methylphenol, 3-Amino-Trinitrotoluen, 2,4,6-Trinitro-Anilin, 1,3,8-Trinitronaphtalen und seine Mischung von bei 115°C schmelzbaren Isomeren, 2,4-Dinitroanisol (DNAN).
- Explosive Zusammensetzung nach einem der Ansprüche 1 oder 2, dadurch gekennzeichnet, dass der schmelzbare Teil zwischen 30% und 40% der Gesamtmasse der Zusammensetzung bildet.
- Explosive Zusammensetzung nach Anspruch 2, dadurch gekenntzeichnet, dass sie die folgende Zusammensetzung besitzt:- 15% bis 30% in Masse Oxinitrotriazol,- 15% bis 30% in Masse unempfindliches Hexogen,- 0 bis 15% in Masse Aluminium,- 20 % bis 33 % in Masse Trinitrotoluen,- 7% bis 10% in Masse einer Mischung aus Wachs und Zusatzstoffen zum Gießen,wobei die Masseprozente auf die Gesamtmasse der Zusammensetzung bezogen sind.
- Explosive Zusammensetzung nach Anspruch 4, dadurch gekennzeichnet, dass sie die folgende Zusammensetzung besitzt:- 21% in Masse Oxinitrotriazol,- 27% in Masse unempfindliches Hexogen,- 14% in Masse Aluminium,- 31 % in Masse Trinitrotoluen,- 7% in Masse einer Mischung aus Wachs und Zusatzstoffen zum Gießen.
- Explosive Zusammensetzung nach Anspruch 4, dadurch gekennzeichnet, dass sie die folgende Zusammensetzung besitzt:- 24% in Masse Oxinitrotriazol,- 24% in Masse unempfindliches Hexogen,- 14% in Masse Aluminium,- 31 % in Masse Trinitrotoluen,- 7% in Masse einer Mischung aus Wachs und Zusatzstoffen zum Gießen.
- Explosive Zusammensetzung nach Anspruch 4, dadurch gekennzeichnet, dass sie die folgende Zusammensetzung besitzt:- 29% in Masse Oxinitrotriazol,- 19% in Masse unempfindliches Hexogen,- 14% in Masse Aluminium,- 31 % in Masse Trinitrotoluen,- 7% in Masse einer Mischung aus Wachs und Zusatzstoffen zum Gießen.
- Explosive Zusammensetzung nach Anspruch 4, dadurch gekennzeichnet, dass sie die folgende Zusammensetzung besitzt:- 33% in Masse Oxinitrotriazol,- 15% in Masse unempfindliches Hexogen,- 14% in Masse Aluminium,- 31 % in Masse Trinitrotoluen,- 7% in Masse einer Mischung aus Wachs und Zusatzstoffen zum Gießen.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10810766T PL2516355T3 (pl) | 2009-12-23 | 2010-12-20 | Mało wrażliwe, odlewane kompozycje wybuchowe |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0906239A FR2954308B1 (fr) | 2009-12-23 | 2009-12-23 | Composition explosive fusible/coulable et a vulnerabilite reduite |
PCT/FR2010/000853 WO2011086246A1 (fr) | 2009-12-23 | 2010-12-20 | Composition explosive fusible/coulable et a vulnerabilite reduite |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2516355A1 EP2516355A1 (de) | 2012-10-31 |
EP2516355B1 true EP2516355B1 (de) | 2017-08-23 |
Family
ID=42316164
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10810766.5A Active EP2516355B1 (de) | 2009-12-23 | 2010-12-20 | Schmelzbare/giessbare explosive zusammensetzung mit geringem schadenpotenzial |
Country Status (7)
Country | Link |
---|---|
US (1) | US9242906B2 (de) |
EP (1) | EP2516355B1 (de) |
ES (1) | ES2645933T3 (de) |
FR (1) | FR2954308B1 (de) |
NO (1) | NO2516355T3 (de) |
PL (1) | PL2516355T3 (de) |
WO (1) | WO2011086246A1 (de) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2984885B1 (fr) * | 2011-12-21 | 2014-07-04 | Nexter Munitions | Procede de fabrication de granules d'une composition explosive comprimable et materiau esplosif obtenu avec un tel procede |
DE102020001794A1 (de) * | 2020-03-18 | 2021-09-23 | Diehl Defence Gmbh & Co. Kg | Schmelzgießbare Sprengstoffwirkmasse |
CN111948369B (zh) * | 2020-07-23 | 2022-11-15 | 西安近代化学研究所 | 超临界法制备的钝化nto包覆质量测评方法 |
CN113378250B (zh) * | 2021-04-23 | 2022-11-08 | 中国兵器装备集团自动化研究所有限公司 | 用于弹体熔铸炸药凝固成型的参数适配系统及生成方法 |
FR3123649A1 (fr) | 2021-06-03 | 2022-12-09 | Thales | Composition explosive fusible/coulable et son procédè de fabrication |
FR3141172A1 (fr) | 2022-10-20 | 2024-04-26 | Thales | Procédé de fabrication d'une composition explosive fusible/coulable. |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2506883C1 (de) * | 1975-02-19 | 1980-10-02 | Messerschmitt Boelkow Blohm | Verfahren zur Herstellung von Hochbrisanz-Sprengstofformkoerpern |
US3994756A (en) * | 1975-11-26 | 1976-11-30 | The United States Of America As Represented By The Secretary Of The Army | Castable composite explosive compositions containing a mixture of trinitrobenzene and trinitroxylene |
FR2584066B1 (fr) * | 1985-06-28 | 1987-08-07 | Poudres & Explosifs Ste Nale | Utilisation du 5-oxo 3-nitro, 1,2,4-triazole comme substance explosive et compositions pyrotechniques contenant du 5-oxo 3-nitro 1,2,4-triazole. |
DE3605634A1 (de) * | 1986-02-21 | 1987-08-27 | Messerschmitt Boelkow Blohm | Verfahren zur behandlung kristalliner sprengstoffe fuer hochleistungssprengladungen |
DE3804397C1 (en) * | 1988-02-12 | 1989-09-07 | Messerschmitt-Boelkow-Blohm Gmbh, 8012 Ottobrunn, De | Process for producing compressed explosive charges |
FR2677977A1 (fr) * | 1991-06-21 | 1992-12-24 | Giat Ind Sa | Procede de fabrication d'une charge explosive de grande puissance et dispositif de mise en óoeuvre du procede. |
FR2738562B1 (fr) * | 1995-09-08 | 1997-10-03 | Poudres & Explosifs Ste Nale | Compositions explosives coulees-fondues |
FR2750131B1 (fr) * | 1996-06-19 | 1998-07-17 | Giat Ind Sa | Composition explosive fusionnable/coulable et a vulnerabilite reduite |
DE19719073A1 (de) * | 1997-05-06 | 1998-11-12 | Diehl Stiftung & Co | Unempfindliche, preßbare Sprengstoffmischung |
US5996501A (en) * | 1997-08-27 | 1999-12-07 | The United States Of America As Represented By The Secretary Of The Air Force | Blast and fragmentation enhancing explosive |
US6884307B1 (en) * | 2002-04-12 | 2005-04-26 | Diehl Munitionssysteme Gmbh & Co. Kg | Insensitive explosive molding powder, paste process |
FR2886641A1 (fr) * | 2005-06-02 | 2006-12-08 | Saint Louis Inst | Particules d'explosif peu sensibles aux chocs et procede de traitement associe |
FR2887544B1 (fr) | 2005-06-02 | 2008-07-18 | Saint Louis Inst | Particules d'explosif peu sensibles aux chocs et procede de traitement associe |
FR2917169B1 (fr) | 2007-06-06 | 2009-09-11 | Eurenco France Sa | Procede de determination du caractere sensible ou insensible d'un hexogene. |
FR2923005B1 (fr) | 2007-10-29 | 2012-10-26 | Nexter Munitions | Procede de coulee d'un materiau explosif et dispositif de coulee mettant en oeuvre un tel procede |
WO2009060902A1 (ja) | 2007-11-06 | 2009-05-14 | Mitsubishi Materials Corporation | セラミックス基板、セラミックス基板の製造方法及びパワーモジュール用基板の製造方法 |
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2009
- 2009-12-23 FR FR0906239A patent/FR2954308B1/fr not_active Expired - Fee Related
-
2010
- 2010-12-20 US US13/515,647 patent/US9242906B2/en active Active
- 2010-12-20 ES ES10810766.5T patent/ES2645933T3/es active Active
- 2010-12-20 WO PCT/FR2010/000853 patent/WO2011086246A1/fr active Application Filing
- 2010-12-20 PL PL10810766T patent/PL2516355T3/pl unknown
- 2010-12-20 EP EP10810766.5A patent/EP2516355B1/de active Active
- 2010-12-20 NO NO10810766A patent/NO2516355T3/no unknown
Non-Patent Citations (1)
Title |
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None * |
Also Published As
Publication number | Publication date |
---|---|
NO2516355T3 (de) | 2018-01-20 |
PL2516355T3 (pl) | 2017-12-29 |
ES2645933T3 (es) | 2017-12-11 |
US9242906B2 (en) | 2016-01-26 |
FR2954308A1 (fr) | 2011-06-24 |
WO2011086246A1 (fr) | 2011-07-21 |
US20120305149A1 (en) | 2012-12-06 |
FR2954308B1 (fr) | 2012-02-24 |
EP2516355A1 (de) | 2012-10-31 |
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