EP2508589A1

EP2508589A1 - Coal Water Slurry and Methods for Making the Coal Water Slurry

Info

Publication number: EP2508589A1
Application number: EP12163250A
Authority: EP
Inventors: Mingmin Wang; Junli Xue; Dejia Wang; Shiguang Li; Lishun Hu; Xijing Bi; Wenhua Li; Wei Chen
Original assignee: General Electric Co
Current assignee: General Electric Co
Priority date: 2011-04-07
Filing date: 2012-04-04
Publication date: 2012-10-10
Also published as: CN102732341A; CA2773735A1; US20120255221A1; IN2012DE01038A; KR20120115473A

Abstract

A coal water slurry comprises smaller and larger coal particles. The smaller coal particles are in a range of from about 20wt% to about 90wt% of the coal in the coal water slurry and comprise a mean particle size smaller than 25µm. The larger coal particles are in a range of from about 10wt% to about 80wt% of the coal in the coal water slurry and comprise a mean particle size in a range of from 50µm to 200µm. A method for making a coal water slurry is also presented.

Description

BACKGROUND

This invention relates generally to coal water slurry and methods for making the coal water slurry. More particularly, this invention relates to particle size distribution of coal in coal water slurry and methods for making the coal water slurry.
In coal gasification fields, two types of methods are usually employed to supply coal to a gasifier for gasification. One is pneumatically transporting pulverized coal with pressurized nitrogen and spraying the coal into a gasifier. Another is preparing a slurry of coal and water, which hereinafter is referred to as "coal water slurry," and supplying the coal water slurry to a gasifier. The "coal water slurry" method has been widely used because it is more reliable, easy transportable and adaptable to a higher gasification pressure than the method employing coal in a dry state.
Generally, higher coal concentration of a coal water slurry leads to higher gasification efficiency and lower consumption of coal and oxygen. Thus, during preparation, it is desirable to have higher concentration of the coal so as to economically gasify the coal water slurry.
There have been attempts to increase the coal concentration. For example, particle size distribution of coal in the coal water slurry may be modified to increase the coal concentration. However, in some current applications, the coal concentration may not be as high as desirable and may cause undesirable viscosity in the coal water slurry with the increase of the coal concentration in the water slurry concentration by modification of the coal particle size distribution.
Therefore, there is a need for new and improved coal water slurry and methods for making the coal water slurry to increase the coal concentration and avoid undesirable viscosity.

BRIEF DESCRIPTION

A coal water slurry is provided in accordance with one embodiment of the invention. The coal water slurry comprises smaller and larger coal particles. The smaller coal particles are in a range of from about 20wt% to about 90wt% of the coal in the coal water slurry and comprise a mean particle size smaller than 26µm. The larger coal particles are in a range of from about 10wt% to about 80wt% of the coal in the coal water slurry and comprise a mean particle size in a range of from 50µm to 200µm.
A method for making a coal water slurry is provided in accordance with another embodiment of the invention. The method comprises milling smaller coal particles in a range of from about 20wt% to about 90wt% of the coal in the coal water slurry and comprising a mean particle size smaller than 26µm, milling larger coal particles in a range of from about 10wt% to about 80wt% of the coal in the coal water slurry and comprising a mean particle size in a range of from 50µm to 200µm, and mixing the smaller coal particles, the larger coal particles, and water.

BRIEF DESCRIPTION OF THE DRAWINGS

The above and other aspects, features, and advantages of the present disclosure will become more apparent in light of the following detailed description when taken in conjunction with the accompanying drawings in which:

FIG. 1 is a schematic diagram of a coal particle size distribution in a coal water slurry in accordance with one embodiment of the invention;
FIG. 2 is an experimental diagram illustrating comparison of correlations of coal concentration and viscosity with and without smaller coal particles in the coal water slurry; and
FIGS. 3-6 are schematic flow charts illustrating preparation of the coal water slurry in accordance with various embodiments of the invention.

DETAILED DESCRIPTION OF THE DISCLOSURE

Preferred embodiments of the present disclosure will be described hereinbelow with reference to the accompanying drawings. In the following description, well-known functions or constructions are not described in detail to avoid obscuring the disclosure in unnecessary detail.
FIG. 1 illustrates a schematic diagram of a particle size distribution of coal for producing a coal water slurry in accordance with one embodiment of the invention. As used herein, the term "coal water slurry" may indicate a mixture of certain amounts of coal, water and additives for producing energy used in generating electricity, heating, support processing, and manufacturing. In recent years, use of coal water slurry has become an alternative to use of conventional fuel oil and coal.
Typically, a coal water slurry may comprise from about 55wt% to about 70wt% of coal particles, from about 30wt% to about 45wt% of water, and less than about 1wt% of additives. It should be noted that embodiments of the invention do not limit to any particular type of coal or additives for the coal water slurry. Non-limiting examples of additives include alkylnaphthelene sulfonate and polyoxyalkylene alkyl ether.
Generally, it is desirable to increase the coal concentration in the coal water slurry so as to improve gasification efficiency and reduce consumption of coal and oxygen. Higher coal concentration may be produced by pulverizing coal into a suitable particle size distribution while selecting suitable additives and appropriately mixing the coal, water and additives to manufacture the coal water slurry with suitable concentration, viscosity, stability, and quality. In embodiments of the invention, the coal particle size distribution in the coal water slurry may be selected so that smaller coal particles are dispersed into spaces between larger coal particles so as to increase the coal concentration in the coal water slurry.
As illustrated in FIG. 1, the particle size distribution of the coal 10 for producing the coal water slurry may comprise smaller coal particles 12 in a range of from about 20wt% to about 90wt% of a weight of the coal 10 and having a mean particle size smaller than about 26µm, and larger coal particles 11 in a range of from about 10wt% to about 80wt% of the weight of the coal 10 and having a mean particle size in a range of from about 50µm to about 200µm. In some applications, the particle size distribution of the coal may comprise the small coal particles 12 in a range of from about 30wt% to about 90wt% and the larger coal particles 11 in a range of from about 10wt% to about 70wt% of the weight of the coal 10, respectively. As used herein, wt% means a weight percentage.
In other applications, the particle size distribution of the coal 10 may comprise the small coal particles 12 in a range of from about 40wt% to about 90wt% and the larger coal particles 11 in a range of from about 10wt% to about 60wt% of the weight of the coal 10, respectively. In certain applications, the particle size distribution of the coal 10 may comprise the small coal particles 12 in a range of from about 50wt% to about 75wt% and the larger coal particles 11 in a range of from about 25wt% to about 50wt% of the weight of the coal 10, respectively.
Additionally, in some examples, the smaller coal particles 12 may have a mean particle size smaller than about 25µm, about 20µm, or about 15µm. In other examples, the smaller coal particles 12 may have a mean particle size smaller than about 10µm or about 5µm. In certain examples, the smaller coal particles 12 may have a mean in a range of from about 5µm to about 15µm. Alternatively, the smaller coal particles 12 may have a mean in a range of from about 10µm to about 15µm, or from 5µm to about 10µm. The larger coal particles 11 may have a mean particle size in a range of from about 50µm to about 70µm, from about 70µm to about 140µm, from about 90µm to about 140µm, from about 100µm to about 140µm, or from about 140µm to about 200µm.
Accordingly, after mixing, the smaller coal particles may be dispersed between the larger coal particles so as to increase the coal concentration of the coal water slurry to be produced. In some embodiments, the coal may comprise one or more of high rank coal, such as bituminous and anthracite, and low rank coal, such as sub-bituminous coal and lignite. In some examples, the coal particle distribution may comprise a mixture of the smaller low rank coal particles and the larger high rank coal particles, or the smaller high rank coal particles and the larger low rank coal particles. In one non-limiting example, both types of coal particles comprise low rank coal, such as the sub-bituminous coal and the lignite. Since the cost of low rank coal is lower, it may be cost-effective in some examples to produce the coal water slurry having higher coal concentration using the low rank coal.
Table-1 illustrates an experimental example of the coal particle size distribution for producing a coal water slurry in accordance with one embodiment. In this example, the coal comprises a low rank coal. Table-1 Coal particle size distribution

Mesh Particle size (µm) Weight percentage (wt%)

>8 >2500 0

8-14 1400-2500 3

14-40 850-1400 12

40-325 45-850 60

325-540 26-45 12.5

<540 <26 50
As can be seen from Table-1, the coal comprises about 50wt% of the smaller coal particles and about 50wt% of the larger coal particles. Particle sizes of the smaller coal particles are less than 26µm, and particle sizes of the larger coal particles in the range of from about 26µm to about 2500µm. For the embodiments of the invention, the smaller coal particles have a mean particle size smaller than 26µm. The larger coal particles have a mean particle size in a range of from about 50µm to about 200µm based on distribution of the weight percentages and the particle sizes thereof, as mentioned above.
FIG. 2 is an experimental diagram illustrating comparison of correlations of the coal concentration in the coal water slurry and viscosity with and without the smaller coal particles in the coal particle size distribution in accordance with one embodiment. As illustrated in FIG. 2, lines 13-14 illustrate the correlations of the coal water slurry concentration and the viscosity without and with the smaller coal particles, respectively.
As can be seen from the line 13, at a point 15, in the initiation of production of the coal water slurry, the coal concentration in the coal water slurry is less than 46%. With the amount of the coal increasing, the coal concentration reaches about 50% at a point 16 where the viscosity there of is less than 600cp. However, during preparation of the coal water slurry without the smaller coal particles, the flowability of the coal water slurry becomes worse at the point 16 such that it becomes disadvantageous to increase the coal concentration further in the coal water slurry.
For the line 14, under the similar operating conditions as those for the line 13, in the initiation, at a point 17, since the smaller coal particles are mixed with the larger coal particles, the coal concentration in the coal water slurry reaches about 54%. With the amount of the mixed coal increasing, the coal concentration reaches above 56% at a point 18 where the viscosity thereof exceeds 1400cp. Then, a certain amount of the additives may be added to decrease the viscosity of the coal water slurry to about 1300cp at a point 19, which is suitable for the flowability of the coal water slurry.
Accordingly, for the comparison of the lines 13-14 illustrated in FIG. 2, the coal water slurry having the mixture of the smaller coal particles and the larger coal particles may have the higher coal concentration and higher flowability than the coal water slurry without mixture of the smaller coal particles.
FIGS. 3-6 illustrate schematic flow charts illustrating preparation of the coal water slurry in accordance with various embodiments of the invention. As illustrated in FIG. 3, during preparation, according to a determined proportion of the smaller coal particles and the larger coal particles, certain amounts of starting coals 20, 21 are introduced into a coarse mill 22 and a fine mill 23 for milling, respectively.
It should be noted that in some applications, one or more coarse mills 22 and one or more fine mills 23 may be employed although one coarse mill 22 and one fine mill 23 are illustrated in FIG. 3. The particle sizes of the starting coals 20, 21 may be less than 3mm. Although two starting coals 20, 21 are illustrated in FIG. 3, one or more starting coal supply sources (not shown) may be employed to provide one or more starting coals 20, 21.
For the illustrated arrangement in FIG. 3, the coarse mill 22 is for wet milling of the starting coal 20 and the fine mill 23 is for dry milling of the starting coal 21. In non-limiting examples, the coarse mill 22 and the fine mill 23 may comprise ball mills, and the particle sizes of the starting coals 20, 21 may be different and not less than 3mm. In certain applications, either or both of the starting coals 20, 21 may comprise one or two of the low rank coal and the high rank coal, and the starting coals 20, 21 may be the same or different from each other. In one non-limiting example, the starting coals 20, 21 are the same low rank coal.
Accordingly, after the starting coals 20, 21 are introduced into the coarse mill 22 and the fine mill 23, respectively, according to determined particle size distribution of the smaller and larger coal particles, the fine mill 23 mills the starting coal 21 to produce the dry smaller coal particles having a mean particle size less than about 26µm. Meanwhile, with introduction of the starting coal 20 into the coarse mill 22, determined amounts of water 24 and additives 25 are also introduced into the coarse mill 22 to produce a coarse coal water slurry comprising the large coal particles having a mean particle size in the range of from about 50µm to about 200µm.
Subsequently, the dry smaller coal particles from the fine mill 23 and the coarse coal water slurry from the coarse mill 22 are introduced into a mixing vessel 26 for mixing to produce the coal water slurry with higher concentration for further processing, for example, for introduction into a gasifier 27 to produce energy. For some arrangements, during mixing, a mixer (not shown) may be employed to mix the dry smaller coal particles and the coarse coal water slurry within the mixing vessel 26, and feed rates of the dry smaller coal particles may be controlled into the mixing vessel 26 so as to ensure the water in the coarse coal water slurry to contact with the smaller coal particles and the smaller coal particles to disperse between the larger coal particles.
In certain applications, as illustrated in FIG. 3, before the coal water slurry with higher coal concentration is introduced into the gasifier 27 for processing, a filter 28 may be employed to receive and filter the coal water slurry from the mixing vessel 26 to remove impurities, such as rock in the coal water slurry, which is advantageous for processing of the coal water slurry in a gasifier. Alternatively, the filter 28 may not be employed.
FIG. 4 illustrates a schematic flow chart of the preparation of the coal water slurry in accordance with another embodiment of the invention. The arrangement in FIG. 4 differs from the arrangement in FIG. 3 in that the mixing vessel 26 in FIG. 3 is not employed in the arrangement in FIG. 4. For the arrangement in FIG. 4, the dry smaller coal particles from the fine mill 23 are introduced into the coarse mill 22 to mix with the larger coal particles, water and the additives while the starting coal 20 is milled in the coarse mill 22. In certain applications, a mixing vessel may also be employed behind the coarse mill 22. Again, a filter 28 may optionally be used before the coal water slurry is sent to the gasifier 27.
FIG. 5 illustrates a schematic flow chart of the preparation of the coal water slurry in accordance with yet another embodiment of the invention. In the arrangement in FIG. 5, during preparation of the smaller coal particles in the fine mill 23, certain amounts of water 29 and optionally additives 30 are also introduced into the fine mill 23 while the starting coal 21 is milled in the fine mill 23 to mix with the smaller coal particles. In some applications, one or more water supply sources and one or more additive supply sources may be employed to provide the water 24, 29 and the additives 25, 30 respectively. The water 24, 29 and the additives 25, 30 may be the same or different from each other. In some applications, the additives 25 and/or 30 may only be introduced into one of the mills or may be introduced into the mixing vessel 26.
In the arrangement of FIG. 6, all of the starting coal 31 is introduced into the coarse mill 22 for wet milling. During milling, a certain amount of a coarse coal 32 from the coarse mill 22 is introduced into the mixing vessel 26, which acts as the larger coal particles, and another amount of the coarse coal from the coarse mill 22 flows into the fine mill 23 for further wet milling to produce the smaller coal particles. Then, the smaller coal particles are mixed with the larger coal particles from the coarse mill 22 in the mixing vessel 26 to produce the coal water slurry with higher concentration. In certain applications, certain amounts of water and additives may be added into either of the mills or into the mixing vessel.
In embodiments of the invention, from about 20wt% to about 90wt% of the smaller coal particles 12 having a mean particle size smaller than 25um may be mixed with from about 10wt% to about 80wt% of larger coal particles 11 having a mean particle size in the range of from about 50µm to about 140µm so as to produce the coal water slurry with higher coal concentration. In some applications, low rank coal may be used to produce the coal particle size distribution so as to produce the coal water slurry with higher coal concentration, which is cost effective. In addition, during preparation of the coal water slurry, wet milling and/or dry milling may be employed so as to improve system flexibility to produce the coal water slurry.
While the disclosure has been illustrated and described in typical embodiments, it is not intended to be limited to the details shown, since various modifications and substitutions can be made without departing in any way from the spirit of the present disclosure. As such, further modifications and equivalents of the disclosure herein disclosed may occur to persons skilled in the art using no more than routine experimentation, and all such modifications and equivalents are believed to be within the scope of the disclosure as defined by the following claims.

Claims

A coal water slurry, comprising:
smaller coal particles (12) in a range of from about 20wt% to about 90wt% of the coal in the coal water slurry and having a mean particle size smaller than 26µm; and

larger coal particles (11) in a range of from about 10wt% to about 80wt% of the coal in the coal water slurry and having a mean particle size in a range of from 50µm to 200µm.
The coal water slurry of claim 1, wherein the smaller (12) and larger (11) coal particles comprise low rank coal.
The coal water slurry of claim 1 or claim 2, wherein the coal water slurry comprises the smaller coal particles (12) in a range of from about 40wt% to about 90wt% and preferably from about 50wt% to about 75wt% and the larger coal particles (11) in a range of from about 10wt% to about 60wt% and preferably from about 25wt% to about 50wt% of the coal in the coal water slurry, respectively.
The coal water slurry of claim 1 or claim 2, wherein the coal water slurry comprises the smaller coal particles (12) in a range of from about 30wt% to about 50wt% and the larger coal particles (11) in a range of from about 50wt% to about 70wt% of the coal in the coal water slurry, respectively.
The coal water slurry of claim 1, 2, 3 or 4, wherein the larger coal particles (11) have the mean particle size in a range of from about 50µm to about 140µm, and preferably from 90µm to 140µm, and more preferably from 100µm to 140µm.
The coal water slurry of claim 1, 2, 3 or 4, wherein the large coal particles (11) have a mean particle size in a range of from 140µm to 200µm.
The coal water slurry of any one of claims 1 to 6, wherein the smaller coal particles (12) have the mean particle size less than about 25um, and preferably less than about 15µm, and more preferably less than about 10µm.
The coal water slurry of any one of claims 1 to 6, wherein the smaller coal particles (12) have the mean particle size in a range of from about 10µm to about 15µm.
A method for making a coal water slurry, comprising:
milling smaller coal particles (12) in a range of from about 20wt% to about 90wt% of the coal in the coal water slurry and comprising a mean particle size smaller than 26µm;

milling larger coal particles (11) in a range of from about 10wt% to about 80wt% of the coal in the coal water slurry and having a mean particle size in a range of from 50µm to 200µm; and

mixing the smaller coal particles (12), the larger coal particles (11), and water, the method preferably further comprising filtering the coal water slurry after mixing of the smaller coal particles and the larger coal particles.
The method for making the coal water slurry of claim 9, wherein milling comprises using a coarse mill (22) for producing the larger coal particles (11) and a fine mill (23) for producing the smaller coal particles (12).
The method for making the coal water slurry of claim 10, wherein using the coarse mill (22) comprises wet milling and using the fine mill (23) comprises dry milling.
The method for making the coal water slurry of claim 9, 10 or 11, wherein:
mixing comprises introducing the smaller coal particles (12) and the larger coal particles (11) respectively into a mixing vessel; or

mixing comprises introducing the smaller coal particles (12) into the coarse mill (22) for mixing.
The method for making the coal water slurry of claim 10, wherein using the coarse mill (22) comprises wet milling and using the fine mill (23) comprises wet milling.
The method for making the coal water slurry of claim 13, further comprising introducing a portion of a coarse coal from the coarse mill (22) into a mixing vessel and another portion of the coarse coal into the fine mill (23) to produce the smaller coal particles for introduction into the mixing vessel.
The method for making the coal water slurry of any of claims 9 to 14, wherein:
the large coal particles (11) have a mean particle size in a range of from about 100µm to about 140µm; and/or

the mean particle size of the smaller coal particles (12) is less than about 25um; and/or

the smaller coal particles (12) are in a range of from about 50wt% to about 75wt% and the larger coal particles (11) are in a range of from about 25wt% to about 50wt% of the coal in the coal water slurry, respectively.