EP2492335A1 - Method and device for homogenising a mixture of solid fuel in a liquid - Google Patents
Method and device for homogenising a mixture of solid fuel in a liquid Download PDFInfo
- Publication number
- EP2492335A1 EP2492335A1 EP12155176A EP12155176A EP2492335A1 EP 2492335 A1 EP2492335 A1 EP 2492335A1 EP 12155176 A EP12155176 A EP 12155176A EP 12155176 A EP12155176 A EP 12155176A EP 2492335 A1 EP2492335 A1 EP 2492335A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mixture
- cross
- sectional constriction
- size distribution
- solid fuel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
- C10L1/326—Coal-water suspensions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/50—Mixing liquids with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
- B01F25/4334—Mixers with a converging cross-section
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/44—Mixers in which the components are pressed through slits
- B01F25/441—Mixers in which the components are pressed through slits characterised by the configuration of the surfaces forming the slits
- B01F25/4412—Mixers in which the components are pressed through slits characterised by the configuration of the surfaces forming the slits the slits being formed between opposed planar surfaces, e.g. pushed again each other by springs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/44—Mixers in which the components are pressed through slits
- B01F25/442—Mixers in which the components are pressed through slits characterised by the relative position of the surfaces during operation
- B01F25/4422—Mixers in which the components are pressed through slits characterised by the relative position of the surfaces during operation the surfaces being maintained in a fixed but adjustable position, spaced from each other, therefore allowing the slit spacing to be varied
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/44—Mixers in which the components are pressed through slits
- B01F25/442—Mixers in which the components are pressed through slits characterised by the relative position of the surfaces during operation
- B01F25/4423—Mixers in which the components are pressed through slits characterised by the relative position of the surfaces during operation the surfaces being part of a valve construction, formed by opposed members in contact, e.g. automatic positioning caused by spring pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
Definitions
- the subject of the present invention is a method and an apparatus for homogenizing a mixture of solid fuel in a liquid.
- the process is particularly preferably used in the homogenization and dispersion of carbon particles in hydrocarbons, such as, for example, a light fuel oil.
- Liquid hydrocarbons such as light fuel oil are widely used in combustion processes.
- light fuel oil is often used in homes for heating and heat supply in industry and commerce.
- Even in the power plant area light fuel oil is used as ignition or support fuel.
- coal, especially lignite, mixed with fuel oil could be used as fuel for heat production in industry and commerce.
- the object of the present invention is to at least partially overcome the disadvantages known from the prior art and in particular to provide a method and a device, with which a mixture of a solid fuel in a liquid can be produced, which achieves a high homogeneity with respect to the distribution of the solid particles in the liquid and with respect to the grain size distribution of the solid fuel and with which it is possible to use a non-decombining mixture of solid fuel in To produce liquids.
- the input mixture comprises solid fuel particles dispersed in a liquid.
- the method according to the invention it is possible to finely disperse these fuel particles, wherein the middle Particle diameter is significantly reduced and the distribution of solid fuel particles in the liquid is made uniform.
- Preferred is a process control with a pressure of 2000 bar absolute upstream of the cross-sectional constriction and from 5 to 10 bar absolute downstream of the cross-sectional constriction.
- the cross-sectional constriction is designed so that the flow velocity in the gap is more than 100 m / s [meters per second].
- cross-sectional constriction is understood to mean that the mixture before it enters the cross-sectional constriction can flow through a cross-section through which is larger than the cross-section through which the cross-sectional constriction can flow.
- the cross-sectional constriction is understood as meaning a gap through which the mixture must flow.
- the cross-sectional constriction has a gap of a gap height of less than 1 mm [millimeter], preferably less than 0.5 mm, in particular less than 0.2 mm.
- the freely flow-through cross section upstream of the cross-sectional constriction, the size of the cross-sectional constriction, ie the freely flow-through cross-section of the cross-sectional constriction and the freely flowable cross-section downstream of the cross-sectional constriction are chosen so that a pressure drop of about 200 to 400 bar absolute upstream of the cross-sectional constriction to 1 to 6 bar absolute downstream of the cross-sectional constriction takes place.
- the cross-sectional constriction is designed so that the flow of the mixture is directed during or after passage of the cross-sectional constriction against at least one baffle.
- the flow paths of the mixture are designed so that the mixture, after flowing through the cross-sectional constriction, strikes a baffle element, which further leads to a reduction of the particle diameter.
- the turbulent flow which arises when passing through the cross-sectional constriction breaks up any laminar or pseudo-laminar flow profiles that may be present, mixing the mixture, thereby equalizing the particle distribution in the liquid and equalizing the particle size distribution.
- a solid fuel is understood in particular to mean a carbonaceous solid fuel.
- the solid fuel is preferably coal, such as lignite, hard coal or charcoal, in particular lignite, preferably in the form of lignite dust or lignite coke.
- Other possible solid fuels are bitumen, asphalt, tar, peat, xylitol and lignite coke.
- a hydrocarbon compounds comprising carbon and hydrogen, especially carbon and hydrogen exist.
- the inventive method in a liquid comprising a plurality of hydrocarbons of different chain lengths. Such liquids occur regularly at certain distillation stages in petroleum refining.
- the process according to the invention for homogenizing solid fuel, in particular brown coal in so-called light fuel oil has proved to be particularly advantageous.
- this is light fuel oil according to the German industrial standard DIN 51603. This may include one or more additives in addition to hydrocarbons.
- a solvent which forms an azeotropic mixture with water is, for example, toluene.
- an azeotropic mixture is meant a mixture which can not be separated by ordinary distillation.
- Solvents which form an azeotropic mixture with water can be used for dewatering coal, as these water bound in the coal can be dissolved out. This is equally possible with other solid fuels.
- An example of such a solvent is toluene.
- the liquid also contains water, preferably water.
- water preferably water.
- foreign components can be dissolved out of the coal in an advantageous manner, which are harmful in the further process for secondary products.
- alkali metals such as sodium, which are soluble in water, can be dissolved out of the solid fuel particles.
- the inventive method causes an increase in the total surface area of the solid fuel particles by reducing the diameter and a more uniform distribution of the solid fuel particles in the water, the amount of extraneous foreign matter dissolved significantly improved.
- the inventive method as a precursor for a demineralization can be used, as described for example in DE 10 2004 038 235 A1.
- the grain size distribution is the probability distribution that indicates the probability of the occurrence of a specific grain size.
- the expectation value is the value of the grain size, which usually results from frequent sampling.
- the position of the maximum value of the particle size distribution is understood to be that particle size for which the highest probability is present.
- the width at half grain size distribution is understood to mean the width of the grain size distribution at half the maximum value of the grain size distribution.
- the pressure difference across the cross-sectional constriction ie the difference of the pressure upstream and downstream of the cross-sectional constriction can be set so that the expected value and / or the position of the maximum value of the grain size distribution shift towards smaller grain sizes, ie the input mixture an expectation and / or has a position of the maximum value of the particle size distribution which is smaller than the corresponding value of the output particle size distribution.
- the difference in pressure becomes a downstream position as compared with a position upstream of the cross-sectional constriction the cross-sectional constriction and / or the size of the cross-sectional constriction set so that the width decreases at half the height of the particle size distribution.
- step 1.c the flow direction of the mixture changes at least once by at least 30 °.
- the pressure increase or the degree of pressure increase in the promotion in step 1.b is adjustable, for example by appropriate selection and control of the funding.
- the size of the cross-sectional constriction and / or the pressure build-up before flowing through the cross-sectional constriction can be adjusted advantageously the particle size distribution of the output particle size distribution of the starting mixture. That is, by adjusting the size of the cross-sectional constriction and / or the pressure, the average grain size and / or the width of the grain size distribution of the starting mixture can be variably adjusted. Furthermore, it is thus possible to achieve a distribution of the solid fuel particles in the liquid that corresponds to a specification. It is thus also the homogeneity of the distribution of the particles in the liquid adjustable.
- the cross-sectional constriction is formed by at least one seat valve.
- a poppet valve allows, by adjusting the gap size of the valve opening, so the gap between the valve body and the valve seat, a variation of the size of the cross-sectional constriction. This can be achieved by appropriate measures such as a change in the bias of a spring, with which the valve body is pressed against the valve seat or under variation of a back pressure, with which the valve body is pressed against the valve seat. By changing these parameters, the size of the cross-sectional constriction can be set to predefinable values.
- the solids content of the input mixture is 50 wt .-% and more.
- the solid fuel is coal, such as lignite or hard coal, and particularly preferably lignite.
- the Applicant has found that despite the abrasive properties of the coal and the relative hardness of the solid fuel particles with the process of the invention, a good reduction in grain size and good homogenization have been achieved.
- the solids content of the initial mixture and thus also of the starting mixture is preferably in the range from 50% by weight to 80% by weight, particularly preferably in the range from 50% by weight to 70% by weight.
- the input mixture is before or during step 1.a. premixed.
- a pump understood preferably a piston pump.
- the use of a piston pump has the advantage over other pumps that the delivery rate of the pump is independent of the pressure.
- pressures of up to 2,000 bar can be achieved before the cross-sectional constriction.
- Advantageous are conveying means in which the pressure before the cross-sectional constriction can be increased to 500 bar and more, preferably to 1000 bar and more, and more preferably to 1500 bar and more.
- the size of the cross-sectional constriction is adjustable by a valve, in particular a seat valve.
- valve and in particular a poppet valve it is possible to make the size of the cross-sectional constriction easily adjustable and to keep variable in certain areas.
- a seat valve has been found to be preferred, since there is the cross-sectional constriction through the gap, which results in open valve between the valve seat and valve body, which can thus be adjusted by changing the bias or the opening of the poppet valve necessary force.
- Fig. 1 schematically shows an embodiment of an apparatus 1 for homogenizing solid fuel in a liquid.
- the device 1 comprises a conveying means 2, in the present embodiment a piston pump with a piston 3.
- the piston 3 is linearly movable in a first direction of movement 4 in a guide channel 5. Due to the movement of the piston 3, a positive or negative pressure is generated in a delivery chamber 6, depending on the direction of movement 4.
- an input mixture can be conveyed through an inlet 7 into the delivery chamber 6.
- the input 7 can be reversibly closed by a valve 8.
- the mixture can be conveyed through a delivery chamber outlet 9.
- the delivery chamber outlet 9 can be reversibly closed by a corresponding valve 10.
- the inlet mixture flows toward a cross-sectional constriction 12.
- This cross-sectional constriction 12 is formed by a seat valve 13, which comprises a valve body 14 and a valve seat 15.
- the cross-sectional constriction 12 represents an annular gap whose gap height is preferably less than 1 mm [millimeter], more preferably less than 0.5 mm, in particular less than 0.2 mm.
- the cross-sectional constriction 12 is present as an annular gap between the valve body 14 and the valve seat 15.
- the flow-through cross section widened again for the stream 11 it comes when flowing through the cross-sectional constriction 12 to an acceleration of the material flow 11 and a subsequent slowing down.
- the material flow 11 follows the flow path 16. This has two changes in the flow direction.
- the material flow 11 is pressed against baffles 17, which also act as deflection means 38. These are formed, on the one hand, from the side of the valve body 14 facing the flow and, on the other hand, by the regions of the valve outer body 18 lying next to the valve seat 15. After flowing through the flow path 16 of the material flow 11 is conveyed as output mixture from the output 19.
- the deflection means 38 thus cause a twice deflection of the flow by 90 °.
- Fig. 2 1 schematically shows the apparatus 1 for homogenizing a mixture of solid fuel in a liquid in a larger context.
- a prefeed pump 20 and a premixer 21 are formed upstream of the device 1, a prefeed pump 20 and a premixer 21 are formed.
- the pre-mixer 21 is a premix of solid fuel, such as lignite dust, with the liquid, such as light fuel oil.
- a pre-mixer 21 a static mixer or a Zahnkranzdispergator or a mixing vessel with agitator can be used.
- the prefeed pump 20 conveys the premix as an input mixture from the premixer 21 to the device 1 according to the invention.
- the prefeed pump 20 may be, for example, a gear pump.
- FIG. 3 schematically shows a section of a device 1, at which the operating principle and the process control according to the present invention will be explained in more detail.
- a mixture 22 of solid fuel particles 25 in a liquid 24 is conveyed from the delivery chamber 6 through the delivery chamber exit 9 in the direction of the cross-sectional constriction 12.
- the solid fuel particles 23 abut against the baffles 17 and are comminuted with each other there as well as with impacts.
- the cross-sectional constriction 12 is given by the gap between a valve seat 15 and a valve body 14 of a seat valve 13.
- the size of the cross-sectional constriction 12 can be adjusted in conjunction with the delivery pressure 26.
- the mixture 22 After flowing through the cross-sectional constriction 12, the mixture 22 has a discharge pressure 27, with which the mixture 22 flows through the outlet 19.
- the solid fuel particles 23 have a smaller diameter after flowing through the cross-sectional constriction 12.
- Fig. 4 shows schematically the particle size distribution of the mixture.
- the input particle size distribution 28 Before passing through the cross-sectional constriction 12, the input particle size distribution 28 is present. After flowing through the cross-sectional constriction 12, the output particle size distribution 29 is present. Shown in each case is the probability P of the occurrence of a grain size d, both in each case given in relative units.
- the input grain size distribution 28 has a maximum value which is present at a position 31.
- the output grain size distribution has a maximum value 32 at a position 33.
- the layer 31 of the maximum value 30 of the input grain size distribution 28 differs from the layer 33 of the maximum value 32 of the input grain size distribution 28.
- the layer 33 is shifted towards smaller grain sizes compared to the layer 31.
- the input grain size distribution 28 has a full width at half height 34 (full with half maximum). This is determined by taking a horizontal cut through the input grain size distribution 28 at half the maximum value 30 and looking at the width of this cut. Similarly, a full width at half height 35 of the output grain size distribution 29 may be formed.
- the full width at half height 34 of the input particle size distribution 28 is significantly greater than the full width at half height 35 of the output particle size distribution 29.
- the method according to the invention thus leads to smaller particle sizes of the solid fuel particles 23 and to a narrower output particle size distribution 29. Simultaneously, the formation of turbulent flows as it flows through the cross-sectional constriction 12, the particles are more evenly distributed.
- the expected value 36 of the input particle size distribution 28 is also at a different point than the expected value 37 of the output particle size distribution 29.
- a process control is selected in which the resulting starting mixture is stable for a long time, that is not segregated.
- preference is given to choosing liquids 24 which have the same density as the solid fuel particles 23, whereby the use of additives for changing the density of the liquid 24 is possible and according to the invention.
- such an additive is chosen so that the density of the liquid 24 is as close as possible to the density of the solid fuel particles 23.
- the inventive method and the device 1 advantageously allow the formation of a homogeneously mixed starting mixture of solid fuel particles 23 in a liquid 24.
- This can be designed so that there is substantially no density difference between the solid fuel particles 23 and the liquid 24, in particular by Adding additives to the liquid 24.
- a non-segregating dispersion of solid fuel particles 23 in liquid 24 can be generated, which can be used without hesitation, for example, as a fuel, without the fireplaces compared to the combustion of pure liquid 24 must be designed significantly different.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Chemical & Material Sciences (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
Description
Gegenstand der vorliegenden Erfindung ist ein Verfahren und eine Vorrichtung zum Homogenisieren einer Mischung von Festbrennstoff in einer Flüssigkeit. Besonders bevorzugt findet das Verfahren Anwendung bei der Homogenisierung und Dispergierung von Kohlenpartikeln in Kohlenwasserstoffen wie beispielsweise einem leichten Heizöl.The subject of the present invention is a method and an apparatus for homogenizing a mixture of solid fuel in a liquid. The process is particularly preferably used in the homogenization and dispersion of carbon particles in hydrocarbons, such as, for example, a light fuel oil.
Flüssige Kohlenwasserstoffe wie beispielsweise leichtes Heizöl werden vielfältig in Verbrennungsprozessen eingesetzt. Beispielsweise wird leichtes Heizöl oftmals in Wohnhäusern zur Beheizung und zur Wärmebereitstellung in Industrie und Gewerbe eingesetzt. Auch im Kraftwerksbereich wird leichtes Heizöl als Zünd- oder Stützbrennstoff eingesetzt. Es besteht das Bedürfnis einer Änderung der Brennstoffe, insbesondere auch im Hinblick auf Kostengesichtspunkte. Beispielsweise könnte Kohle, insbesondere Braunkohle, mit Heizöl gemischt als Brennstoff zur Wärmebereitstellung in Industrie und Gewerbe eingesetzt werden. Jedoch ist es in diesem Zusammen erforderlich, eine Entmischung von Festbrennstoff und Heizöl zu verhindern. Eine solche könnte zu Beschädigungen der Feueranlagen führen oder die Verbrennung erst gar nicht ermöglichen.Liquid hydrocarbons such as light fuel oil are widely used in combustion processes. For example, light fuel oil is often used in homes for heating and heat supply in industry and commerce. Even in the power plant area, light fuel oil is used as ignition or support fuel. There is a need to change the fuels, especially with regard to cost aspects. For example, coal, especially lignite, mixed with fuel oil could be used as fuel for heat production in industry and commerce. However, in this combination it is necessary to prevent segregation of solid fuel and fuel oil. Such could lead to damage to the fire equipment or even not possible combustion.
Aus der
Der vorliegenden Erfindung liegt die Aufgabe zugrunde, die aus dem Stand der Technik bekannten Nachteile zumindest teilweise zu überwinden und insbesondere ein Verfahren und eine Vorrichtung anzugeben, mit dem eine Mischung eines Festbrennstoffs in einer Flüssigkeit erzeugt werden kann, die eine hohe Homogenität in Bezug auf die Verteilung der Feststoffpartikel in der Flüssigkeit und in Bezug auf die Korngrößenverteilung des Festbrennstoffs erreicht und mit denen es möglich ist, eine nicht entmischende Mischung von Festbrennstoff in Flüssigkeiten zu erzeugen.The object of the present invention is to at least partially overcome the disadvantages known from the prior art and in particular to provide a method and a device, with which a mixture of a solid fuel in a liquid can be produced, which achieves a high homogeneity with respect to the distribution of the solid particles in the liquid and with respect to the grain size distribution of the solid fuel and with which it is possible to use a non-decombining mixture of solid fuel in To produce liquids.
Diese Aufgaben werden gelöst durch die Merkmale der unabhängigen Ansprüche. Die jeweiligen abhängigen Ansprüche sind auf vorteilhafte Weiterbildungen gerichtet.These objects are achieved by the features of the independent claims. The respective dependent claims are directed to advantageous developments.
Die in den Patentansprüchen einzeln aufgeführten Merkmale sind in beliebiger, technologisch sinnvoller Weise miteinander kombinierbar und können durch erläuternde Sachverhalte aus der Beschreibung ergänzt werden, wobei weitere Ausführungsvarianten der Erfindung aufgezeigt werden.The features listed individually in the claims can be combined with each other in any technologically meaningful manner and can be supplemented by explanatory facts from the description, with further embodiments of the invention being shown.
Gegenstand der vorliegenden Erfindung ist ein Verfahren zum Homogenisieren einer Mischung von Festbrennstoff in einer Flüssigkeit, gekennzeichnet durch die folgenden Schritte:
- a. Förderung einer Eingangsmischung umfassend Festbrennstoff in einer Flüssigkeit in Richtung mindestens einer Querschnittsverengung;
- b. Erhöhung des Drucks der Eingangsmischung bei Förderung der Eingangsmischung in Richtung der mindestens einen Querschnittsverengung; und
- c. Entspannung der Eingangsmischung beim Durchtreten durch die mindestens eine Querschnittsverengung unter Bildung einer Ausgangsmischung.
- a. Conveying an input mixture comprising solid fuel in a liquid in the direction of at least one cross-sectional constriction;
- b. Increasing the pressure of the input mixture while conveying the input mixture in the direction of the at least one cross-sectional constriction; and
- c. Relaxation of the input mixture when passing through the at least one cross-sectional constriction to form a starting mixture.
Die Eingangsmischung umfasst Festbrennstoffpartikel, die in einer Flüssigkeit dispergiert sind. Durch das erfindungsgemäße Verfahren ist es möglich, diese Brennstoffpartikel fein zu dispergieren, wobei der mittlere Teilchendurchmesser signifikant verringert und die Verteilung der Festbrennstoffpartikel in der Flüssigkeit vergleichmäßigt wird. Bevorzugt ist hierbei eine Verfahrensführung, bei der in Verfahrensschritt 1.c der Druck der Mischung um einen Faktor von bis zu 200, besonders bevorzugt von bis zu 400 und insbesondere sogar von bis zu 500 verringert wird. Dies bedeutet, dass der Quotient des Drucks der Eingangsmischung vor der Querschnittsverengung zum Druck der Ausgangsmischung stromabwärts der Querschnittsverengung im Bereich von 150 und 500 liegt. Bevorzugt ist eine Verfahrensführung mit einem Druck von 2000 bar absolut stromaufwärts der Querschnittsverengung und von 5 bis 10 bar absolut stromabwärts der Querschnittsverengung. Bevorzugt ist die Querschnittsverengung so gestaltet, dass die Strömungsgeschwindigkeit im Spalt bei mehr als 100 m/s [Meter pro Sekunde] liegt.The input mixture comprises solid fuel particles dispersed in a liquid. By the method according to the invention it is possible to finely disperse these fuel particles, wherein the middle Particle diameter is significantly reduced and the distribution of solid fuel particles in the liquid is made uniform. In this case, preference is given to a process procedure in which, in process step 1.c, the pressure of the mixture is reduced by a factor of up to 200, particularly preferably up to 400 and in particular even up to 500. This means that the quotient of the pressure of the inlet mixture before the cross-sectional constriction to the pressure of the starting mixture downstream of the cross-sectional constriction is in the range of 150 and 500. Preferred is a process control with a pressure of 2000 bar absolute upstream of the cross-sectional constriction and from 5 to 10 bar absolute downstream of the cross-sectional constriction. Preferably, the cross-sectional constriction is designed so that the flow velocity in the gap is more than 100 m / s [meters per second].
Durch die schlagartige Entspannung beschleunigt die Mischung beim Durchtreten durch die Querschnittsverengung, es kommt zu Stößen der Festbrennstoffpartikel aneinander und an den Wänden bzw. Begrenzungen im Förderbereich. Durch diese werden die Festbrennstoffpartikel zerkleinert. Unter dem Begriff Querschnittsverengung wird verstanden, dass die Mischung vor Eintritt in die Querschnittsverengung einen durchströmbaren Querschnitt durchströmen kann, der größer ist als der durchströmbare Querschnitt in der Querschnittsverengung. Insbesondere wird unter der Querschnittsverengung ein Spalt verstanden, durch den die Mischung strömen muss. Bevorzugt ist eine Ausgestaltung, bei der sich die Querschnittsverengung einen Spalt einer Spalthöhe von weniger als 1 mm [Millimeter], bevorzugt von weniger als 0,5 mm, insbesondere von weniger als 0,2 mm aufweist. Bevorzugt ist eine Verfahrensführung, bei der der frei durchströmbare Querschnitt stromaufwärts der Querschnittsverengung, die Größe der Querschnittsverengung, also der frei durchströmbare Querschnitt der Querschnittsverengung und der frei durchströmbare Querschnitt stromabwärts der Querschnittsverengung so gewählt werden, dass ein Druckabfall von etwa 200 bis 400 bar absolut stromaufwärts der Querschnittsverengung auf 1 bis 6 bar absolut stromabwärts der Querschnittsverengung erfolgt. Bevorzugt ist die Querschnittsverengung so gestaltet, dass der Strom der Mischung beim oder nach Durchtreten der Querschnittsverengung gegen mindestens eine Prallfläche gelenkt wird.The sudden relaxation accelerates the mixture as it passes through the cross-sectional constriction, it comes to collisions of the solid fuel particles together and on the walls or boundaries in the delivery area. By this, the solid fuel particles are crushed. The term cross-sectional constriction is understood to mean that the mixture before it enters the cross-sectional constriction can flow through a cross-section through which is larger than the cross-section through which the cross-sectional constriction can flow. In particular, the cross-sectional constriction is understood as meaning a gap through which the mixture must flow. Preferred is an embodiment in which the cross-sectional constriction has a gap of a gap height of less than 1 mm [millimeter], preferably less than 0.5 mm, in particular less than 0.2 mm. Preference is given to a process control in which the freely flow-through cross section upstream of the cross-sectional constriction, the size of the cross-sectional constriction, ie the freely flow-through cross-section of the cross-sectional constriction and the freely flowable cross-section downstream of the cross-sectional constriction are chosen so that a pressure drop of about 200 to 400 bar absolute upstream of the cross-sectional constriction to 1 to 6 bar absolute downstream of the cross-sectional constriction takes place. Preferably, the cross-sectional constriction is designed so that the flow of the mixture is directed during or after passage of the cross-sectional constriction against at least one baffle.
Bevorzugt sind die Strömungswege der Mischung so gestaltet, dass die Mischung nach Durchströmen der Querschnittsverengung auf ein Prallelement trifft, welches weiter zur Verringerung der Partikeldurchmesser führt. Gleichzeitig sorgt die bei Durchtreten durch die Querschnittsverengung entstehende turbulente Strömung zu einem Aufbrechen gegebenenfalls vorliegender laminarer oder pseudo-laminarer Strömungsprofile, es kommt zu einer Durchmischung der Mischung, wodurch eine Vergleichmäßigung der Partikelverteilung in der Flüssigkeit und eine Vergleichmäßigung der Partikelgrößenverteilung erreicht wird.Preferably, the flow paths of the mixture are designed so that the mixture, after flowing through the cross-sectional constriction, strikes a baffle element, which further leads to a reduction of the particle diameter. At the same time, the turbulent flow which arises when passing through the cross-sectional constriction breaks up any laminar or pseudo-laminar flow profiles that may be present, mixing the mixture, thereby equalizing the particle distribution in the liquid and equalizing the particle size distribution.
Unter einem Festbrennstoff wird insbesondere ein kohlenstoffhaltiger Festbrennstoff verstanden. Bevorzugt handelt es sich bei dem Festbrennstoff um Kohle wie Braunkohle, Steinkohle oder Holzkohle, insbesondere um Braunkohle, bevorzugt in der Form von Braunkohlenstaub oder Braunkohlenkoks. Weitere mögliche Festbrennstoffe sind Bitumen, Asphalt, Teer, Torf, Xylit und Braunkohlenkoks.A solid fuel is understood in particular to mean a carbonaceous solid fuel. The solid fuel is preferably coal, such as lignite, hard coal or charcoal, in particular lignite, preferably in the form of lignite dust or lignite coke. Other possible solid fuels are bitumen, asphalt, tar, peat, xylitol and lignite coke.
Gemäß einer vorteilhaften Ausgestaltung des erfindungsgemäßen Verfahrens umfasst die Flüssigkeit mindestens einen der folgenden Stoffe:
- a. mindestens einen Kohlenwasserstoff;
- b. ein Lösungsmittel, welches mit Wasser ein azeotropes Gemisch bildet; und
- c. Wasser.
- a. at least one hydrocarbon;
- b. a solvent which forms an azeotropic mixture with water; and
- c. Water.
Unter einem Kohlenwasserstoff werden Verbindungen verstanden, die Kohlenstoff und Wasserstoff umfassen, die insbesondere aus Kohlenstoff und Wasserstoff bestehen. Vorteilhaft einsetzbar ist das erfindungsgemäße Verfahren bei einer Flüssigkeit umfassend mehrere Kohlenwasserstoffe unterschiedlicher Kettenlängen. Solche Flüssigkeiten treten regelmäßig bei bestimmten Destillationsstufen in der Erdölraffination auf. Besonders vorteilhaft hat sich das erfindungsgemäße Verfahren zum Homogenisieren von Festbrennstoff wie insbesondere Braunkohle in so genanntem leichten Heizöl erwiesen. Bevorzugt handelt es sich dabei um leichtes Heizöl nach der Deutschen Industrienorm DIN 51603. Dieses kann neben Kohlenwasserstoffen auch ein oder mehrere Additive umfassen.By a hydrocarbon is meant compounds comprising carbon and hydrogen, especially carbon and hydrogen exist. Advantageously, the inventive method in a liquid comprising a plurality of hydrocarbons of different chain lengths. Such liquids occur regularly at certain distillation stages in petroleum refining. The process according to the invention for homogenizing solid fuel, in particular brown coal in so-called light fuel oil, has proved to be particularly advantageous. Preferably, this is light fuel oil according to the German industrial standard DIN 51603. This may include one or more additives in addition to hydrocarbons.
Ein Lösungsmittel, welches mit Wasser ein azeotropes Gemisch bildet, stellt beispielsweise Toluol dar. Unter einem azeotropen Gemisch wird ein Gemisch verstanden, welches nicht durch gewöhnliche Destillation getrennt werden kann. Lösungsmittel, welche mit Wasser ein azeotropisches Gemisch bilden, können zur Entwässerung von Kohle eingesetzt werden, da mit diesen in der Kohle gebundenes Wasser herausgelöst werden kann. Dies ist gleichermaßen mit anderen Festbrennstoffen möglich. Ein Beispiel für ein solches Lösungsmittel ist Toluol.A solvent which forms an azeotropic mixture with water is, for example, toluene. By an azeotropic mixture is meant a mixture which can not be separated by ordinary distillation. Solvents which form an azeotropic mixture with water can be used for dewatering coal, as these water bound in the coal can be dissolved out. This is equally possible with other solid fuels. An example of such a solvent is toluene.
Weiterhin ist es möglich, dass die Flüssigkeit auch Wasser enthält, bevorzugt Wasser ist. Durch die Homogenisierung von Festbrennstoffpartikeln, insbesondere von Kohlepartikeln in Wasser, können in vorteilhafter Weise Fremdbestandteile aus der Kohle herausgelöst werden, welche im weiteren Verfahren schädlich für Folgeprodukte sind. So können zum Beispiel Alkalimetalle wie Natrium, die in Wasser löslich sind, aus den Festbrennstoffpartikeln herausgelöst werden. Da das erfindungsgemäße Verfahren eine Vergrößerung der gesamten Oberfläche der Festbrennstoffpartikel durch die Verringerung des Durchmessers und eine gleichmäßigere Verteilung der Festbrennstoffpartikel im Wasser bewirkt, verbessert sich die Menge an herausgelösten Fremdbestandteilen erheblich. Somit kann das erfindungsgemäße Verfahren als Vorstufe für ein Demineralisationsverfahren benutzt werden, wie es beispielsweise in der DE 10 2004 038 235 A1 beschrieben wird.Furthermore, it is possible that the liquid also contains water, preferably water. By the homogenization of solid fuel particles, in particular of carbon particles in water, foreign components can be dissolved out of the coal in an advantageous manner, which are harmful in the further process for secondary products. For example, alkali metals such as sodium, which are soluble in water, can be dissolved out of the solid fuel particles. Since the inventive method causes an increase in the total surface area of the solid fuel particles by reducing the diameter and a more uniform distribution of the solid fuel particles in the water, the amount of extraneous foreign matter dissolved significantly improved. Thus, the inventive method as a precursor for a demineralization can be used, as described for example in
Gemäß einer weiteren vorteilhaften Ausgestaltung des erfindungsgemäßen Verfahrens weist die Eingangsmischung eine Eingangskorngrößenverteilung und die Ausgangsmischung eine Ausgangskorngrößenverteilung auf, die sich in mindestens einem der folgenden Faktoren unterscheiden:
- a. dem Erwartungswert der Korngrößenverteilung;
- b. der Lage des Maximalwerts der Korngrößenverteilung; und
- c. der Breite bei halber Höhe der Korngrößenverteilung.
- a. the expected value of the particle size distribution;
- b. the location of the maximum value of the particle size distribution; and
- c. the width at half height of the particle size distribution.
Unter der Korngrößenverteilung wird die Wahrscheinlichkeitsverteilung verstanden, die die Wahrscheinlichkeit des Auftretens einer bestimmten Korngröße angibt. Unter dem Erwartungswert wird der Wert der Korngröße verstanden, der sich in der Regel bei oftmaligen Stichproben ergibt. Unter der Lage des Maximalwerts der Korngrößenverteilung wird jene Korngröße verstanden, für deren Auftreten die höchste Wahrscheinlichkeit vorliegt. Unter der Breite bei halber Korngrößenverteilung wird die Breite der Korngrößenverteilung bei der Hälfte des Maximalwerts der Korngrößenverteilung verstanden.The grain size distribution is the probability distribution that indicates the probability of the occurrence of a specific grain size. The expectation value is the value of the grain size, which usually results from frequent sampling. The position of the maximum value of the particle size distribution is understood to be that particle size for which the highest probability is present. The width at half grain size distribution is understood to mean the width of the grain size distribution at half the maximum value of the grain size distribution.
Gemäß dem erfindungsgemäßen Verfahren kann insbesondere der Druckunterschied über die Querschnittsverengung, also die Differenz des Drucks stromaufwärts und stromabwärts der Querschnittsverengung so eingestellt werden, dass der Erwartungswert und/oder die Lage des Maximalwerts der Korngrößenverteilung sich hin zu kleineren Korngrößen verschieben, also die Eingangsmischung einen Erwartungswert und/oder eine Lage des Maximalwerts der Korngrößenverteilung aufweist, der kleiner ist als der entsprechende Wert der Ausgangskorngrößenverteilung. Zudem wird der Unterschied des Drucks im Vergleich zu einer Position stromaufwärts der Querschnittsverengung zu einer Position stromabwärts der Querschnittsverengung und/oder die Größe der Querschnittsverengung so eingestellt, dass die Breite bei halber Höhe der Korngrößenverteilung sinkt. Bevorzugt ist hierbei eine Verfahrensführung, bei der der Quotient der Breite bei halber Höhe der Eingangskorngrößenverteilung zur Breite bei halber Höhe der Ausgangskorngrößenverteilung im Bereich von 20 bis 100 liegt, bevorzugt beträgt dieser Quotient mindestens 10.According to the method according to the invention, in particular the pressure difference across the cross-sectional constriction, ie the difference of the pressure upstream and downstream of the cross-sectional constriction can be set so that the expected value and / or the position of the maximum value of the grain size distribution shift towards smaller grain sizes, ie the input mixture an expectation and / or has a position of the maximum value of the particle size distribution which is smaller than the corresponding value of the output particle size distribution. In addition, the difference in pressure becomes a downstream position as compared with a position upstream of the cross-sectional constriction the cross-sectional constriction and / or the size of the cross-sectional constriction set so that the width decreases at half the height of the particle size distribution. In this case, preference is given to a process control in which the quotient of the width at half the height of the input particle size distribution to the width at half the height of the output particle size distribution is in the range from 20 to 100, preferably this quotient is at least 10.
Gemäß einer weiteren vorteilhaften Ausgestaltung des erfindungsgemäßen Verfahrens ändert sich in Schritt 1.c die Strömungsrichtung der Mischung mindestens einmal um mindestens 30°.According to a further advantageous embodiment of the method according to the invention, in step 1.c the flow direction of the mixture changes at least once by at least 30 °.
Es hat sich gezeigt, dass es vorteilhaft ist, den Strömungsweg, den die Mischung beim erfindungsgemäßen Verfahren zurücklegt, so zu gestalten, dass mindestens eine signifikante Umlenkung der Strömungsrichtung erfolgt, bevorzugt sogar zwei und mehr Änderungen der Strömungsrichtung. Besonders bevorzugt sind dabei Änderungen der Strömungsrichtung etwa im rechten Winkel oder mehr. Durch die entsprechenden Kollisionen bei der Umlenkung kommt es zu einer weiteren Reduktion der Teilchengröße der Festbrennstoffpartikel und zur Bildung von turbulenten Strömungen, die eine weitere Vermischung der Mischung begünstigen.It has been shown that it is advantageous to design the flow path which the mixture covers in the method according to the invention in such a way that at least a significant deflection of the flow direction takes place, preferably even two or more changes in the flow direction. Particular preference is given to changes in the flow direction approximately at right angles or more. The corresponding collisions during the deflection result in a further reduction in the particle size of the solid fuel particles and in the formation of turbulent flows, which promote further mixing of the mixture.
Weiterhin bedingen scharfe Richtungsänderungen der Strömung ein Aufbrechen eventueller laminarer oder quasi-laminarer Strömungen oder Randströmungen. Hierdurch wird eine weitere Homogenisierung der Verteilung der Partikel in der Flüssigkeit erreicht, da turbulente Strömungen erzeugt werden, die zu einer Durchmischung der Flüssigkeit führen.Furthermore, sharp changes in the direction of the flow cause a break-up of any laminar or quasi-laminar flows or edge flows. As a result, a further homogenization of the distribution of the particles in the liquid is achieved because turbulent flows are generated, which lead to a mixing of the liquid.
Gemäß einer weiteren vorteilhaften Ausgestaltung des Verfahrens ist mindestens einer der folgenden Parameter einstellbar:
- a. die Größe der mindestens einen Querschnittsverengung; und
- b. der Druck der Eingangsmischung, der in Schritt 1.b erreicht wird.
- a. the size of the at least one cross-sectional constriction; and
- b. the pressure of the input mixture, which is reached in step 1.b.
Alternativ oder zusätzlich ist auch die Druckerhöhung bzw. das Maß der Druckerhöhung bei der Förderung in Schritt 1.b einstellbar, beispielsweise durch entsprechende Wahl und Ansteuerung der Fördermittel. Durch die Einstellung der Größe der Querschnittsverengung und/oder des Druckaufbaus vor Durchströmen der Querschnittsverengung kann in vorteilhafter Weise die Korngrößenverteilung der Ausgangskorngrößenverteilung der Ausgangsmischung eingestellt werden. Das heißt, durch Einstellung der Größe der Querschnittsverengung und/oder des Drucks kann die mittlere Korngröße und/oder die Breite der Korngrößenverteilung der Ausgangsmischung variabel eingestellt werden. Weiterhin kann so eine einer Vorgabe entsprechende Verteilung der Festbrennstoffpartikel in der Flüssigkeit erreicht werden. Es ist also hierüber auch die Homogenität der Verteilung der Partikel in der Flüssigkeit einstellbar.Alternatively or additionally, the pressure increase or the degree of pressure increase in the promotion in step 1.b is adjustable, for example by appropriate selection and control of the funding. By adjusting the size of the cross-sectional constriction and / or the pressure build-up before flowing through the cross-sectional constriction can be adjusted advantageously the particle size distribution of the output particle size distribution of the starting mixture. That is, by adjusting the size of the cross-sectional constriction and / or the pressure, the average grain size and / or the width of the grain size distribution of the starting mixture can be variably adjusted. Furthermore, it is thus possible to achieve a distribution of the solid fuel particles in the liquid that corresponds to a specification. It is thus also the homogeneity of the distribution of the particles in the liquid adjustable.
Gemäß einer weiteren bevorzugten Ausgestaltung des Verfahrens ist die Querschnittsverengung durch mindestens ein Sitzventil gebildet.According to a further preferred embodiment of the method, the cross-sectional constriction is formed by at least one seat valve.
Der Einsatz eines Sitzventils erlaubt, durch Einstellung der Spaltgröße der Ventilöffnung, also des Spalts zwischen Ventilkörper und Ventilsitz, eine Variation der Größe der Querschnittsverengung. Dies kann durch entsprechende Maßnahmen wie beispielsweise eine Änderung der Vorspannung einer Feder, mit der der Ventilkörper gegen den Ventilsitz gepresst wird oder unter Variation eines Hinterdrucks, mit dem der Ventilkörper gegen den Ventilsitz gepresst wird, erreicht werden. Durch Änderung dieser Parameter kann so die Größe der Querschnittsverengung auf vorgebbare Werte eingestellt werden.The use of a poppet valve allows, by adjusting the gap size of the valve opening, so the gap between the valve body and the valve seat, a variation of the size of the cross-sectional constriction. This can be achieved by appropriate measures such as a change in the bias of a spring, with which the valve body is pressed against the valve seat or under variation of a back pressure, with which the valve body is pressed against the valve seat. By changing these parameters, the size of the cross-sectional constriction can be set to predefinable values.
Gemäß einer weiteren vorteilhaften Ausgestaltung des erfindungsgemäßen Verfahrens liegt der Feststoffanteil der Eingangsmischung bei 50 Gew.-% und mehr.According to a further advantageous embodiment of the method according to the invention, the solids content of the input mixture is 50 wt .-% and more.
Insbesondere handelt es sich bei dem Festbrennstoff um Kohle wie Braunkohle oder Steinkohle und besonders bevorzugt um Braunkohle. Die Anmelderin hat festgestellt, dass trotz der abrasiven Eigenschaften der Kohle und der relativen Härte der Festbrennstoffpartikel mit dem erfindungsgemäßen Verfahren eine gute Verringerung der Korngröße und eine gute Homogenisierung erreicht wurden. Bevorzugt liegt der Feststoffanteil der Eingangsmischung und damit auch der Ausgangsmischung im Bereich von 50 Gewichts-% bis 80 Gewichts-%, besonders bevorzugt im Bereich 50 Gew.-% bis 70 Gew.%.In particular, the solid fuel is coal, such as lignite or hard coal, and particularly preferably lignite. The Applicant has found that despite the abrasive properties of the coal and the relative hardness of the solid fuel particles with the process of the invention, a good reduction in grain size and good homogenization have been achieved. The solids content of the initial mixture and thus also of the starting mixture is preferably in the range from 50% by weight to 80% by weight, particularly preferably in the range from 50% by weight to 70% by weight.
Gemäß einer weiteren vorteilhaften Ausgestaltung des erfindungsgemäßen Verfahrens wird die Eingangsmischung vor oder während Schritt 1.a. vorgemischt.According to a further advantageous embodiment of the method according to the invention, the input mixture is before or during step 1.a. premixed.
Dies kann insbesondere durch einen statischen Mischer oder einen Mischer mit Rührwerk erfolgen. Durch eine Vormischung kann erreicht werden, dass die Homogenisierung der Ausgangsmischung weiter verbessert wird, da es sich gezeigt hat, dass die Mischeffizienz ebenso wie die Effizienz des Verkleinerungsprozesses der Festbrennstoffpartikel in der Flüssigkeit höher ist, wenn die Eingangsmischung vorgemischt wird.This can be done in particular by a static mixer or a mixer with stirrer. By premixing, it can be achieved that the homogenization of the starting mixture is further improved, as it has been shown that the mixing efficiency as well as the efficiency of the reduction process of the solid fuel particles in the liquid is higher when the input mixture is premixed.
Gemäß einem weiteren Aspekt der vorliegenden Erfindung wird eine Vorrichtung zum Homogenisieren einer Mischung von Festbrennstoff in einer Flüssigkeit vorgeschlagen, die umfasst:
- a. mindestens ein Fördermittel zur Fördern und Erhöhen des Drucks einer Eingangsmischung aus Festbrennstoff in einer Flüssigkeit hin zu mindestens einer Querschnittsverengung; und
- b. Umlenkmittel zum mindestens einmaligen Umlenken der Mischung beim Durchtreten durch die mindestens eine Querschnittsverengung unter Bildung einer Ausgangsmischung.
- a. at least one conveying means for conveying and increasing the pressure of an input mixture of solid fuel in a liquid towards at least one cross-sectional constriction; and
- b. Deflection means for deflecting the mixture at least once when passing through the at least one cross-sectional constriction to form a starting mixture.
Unter dem Fördermittel wird insbesondere eine Pumpe verstanden, bevorzugt eine Kolbenpumpe. Der Einsatz einer Kolbenpumpe hat im Vergleich zu anderen Pumpen den Vorteil, dass die Fördermenge der Pumpe vom Druck unabhängig ist. Durch Einsatz entsprechender Kolbenpumpen können Drücke von bis zu 2.000 bar vor der Querschnittsverengung erreicht werden. Vorteilhaft sind Fördermittel, bei denen der Druck vor der Querschnittsverengung auf 500 bar und mehr, bevorzugt auf 1000 bar und mehr und besonders bevorzugt auf 1500 bar und mehr erhöht werden kann.Under the funding is in particular a pump understood, preferably a piston pump. The use of a piston pump has the advantage over other pumps that the delivery rate of the pump is independent of the pressure. By using appropriate piston pumps, pressures of up to 2,000 bar can be achieved before the cross-sectional constriction. Advantageous are conveying means in which the pressure before the cross-sectional constriction can be increased to 500 bar and more, preferably to 1000 bar and more, and more preferably to 1500 bar and more.
Gemäß einer vorteilhaften Ausgestaltung der erfindungsgemäßen Vorrichtung ist die Größe der Querschnittsverengung durch ein Ventil, insbesondere ein Sitzventil, einstellbar.According to an advantageous embodiment of the device according to the invention, the size of the cross-sectional constriction is adjustable by a valve, in particular a seat valve.
Durch ein Ventil und insbesondere ein Sitzventil ist es möglich, die Größe der Querschnittsverengung leicht einstellbar zu machen und in gewissen Bereichen variierbar zu halten. Insbesondere hat sich ein Sitzventil als bevorzugt geeignet herausgestellt, da dort die Querschnittsverengung durch den Spalt, welcher sich bei geöffnetem Ventil zwischen Ventilsitz und Ventilkörper ergibt, gegeben ist, der somit durch Änderung der Vorspannung oder zur Öffnung des Sitzventils notwendigen Kraft eingestellt werden kann.By a valve and in particular a poppet valve, it is possible to make the size of the cross-sectional constriction easily adjustable and to keep variable in certain areas. In particular, a seat valve has been found to be preferred, since there is the cross-sectional constriction through the gap, which results in open valve between the valve seat and valve body, which can thus be adjusted by changing the bias or the opening of the poppet valve necessary force.
Die im Rahmen des Dokuments für das erfindungsgemäße Verfahren offenbarten Details und Vorteile lassen sich auf die erfindungsgemäße Vorrichtung übertragen und anwenden und umgekehrt. Im Folgenden soll die Erfindung anhand der beigefügten Figuren näher erläutert werden, ohne dass sie auf die dort gezeigten Details und Ausführungsbeispiele beschränkt wäre. Es zeigen schematisch:
- Fig. 1:
- ein Ausführungsbeispiel einer erfindungsgemäßen Vorrichtung im Schnitt;
- Fig. 2:
- ein Ausführungsbeispiel der vorliegenden Erfindung mit Zusatzaggregaten;
- Fig. 3:
- einen Teil einer erfindungsgemäßen Vorrichtung zur Illustration des Verfahrensprinzips; und
- Fig. 4
- eine erläuternde Ansicht der Korngrößenverteilung der Eingangs- und der Ausgangsmischung.
- Fig. 1:
- an embodiment of a device according to the invention in section;
- Fig. 2:
- an embodiment of the present invention with additional units;
- 3:
- a part of a device according to the invention for illustrating the method principle; and
- Fig. 4
- an explanatory view of the grain size distribution of the input and the output mixture.
Die entsprechenden Stoffströme sind durch Pfeile 11 gekennzeichnet. Nach Passieren des Förderkammerausgangs 9 strömt die Eingangsmischung auf eine Querschnittsverengung 12 zu. Diese Querschnittsverengung 12 wird durch ein Sitzventil 13 gebildet, welches einen Ventilkörper 14 und einen Ventilsitz 15 umfasst. In diesem Ausführungsbeispiel stellt also die Querschnittsverengung 12 einen Ringspalt dar, dessen Spalthöhe bevorzugt kleiner als 1 mm [Millimeter], besonders bevorzugt bei weniger als 0,5 mm, insbesondere bei weniger als 0,2 mm liegt. Im Betrieb liegt die Querschnittsverengung 12 als ringförmiger Spalt zwischen Ventilkörper 14 und Ventilsitz 15 vor. Stromabwärts der Querschnittsverengung 12 verbreitert sich der durchströmbare Querschnitt für den Stoffstrom 11 erneut, es kommt beim Durchströmen der Querschnittsverengung 12 zu einer Beschleunigung des Stoffstroms 11 und zu einer anschließenden Verlangsamung. Beim Durchströmen der Querschnittsverengung 12 folgt der Stoffstrom 11 dem Strömungspfad 16. Dieser weist jeweils zwei Änderungen der Strömungsrichtung auf. Beim Durchströmen des Strömungspfades 16 wird der Stoffstrom 11 gegen Prallflächen 17 gedrückt, die auch als Umlenkmittel 38 wirken. Diese sind zum einen aus der der Strömung entgegen gewandten Seite des Ventilkörpers 14 und zum anderen durch die neben dem Ventilsitz 15 liegenden Bereiche des Ventilaußenkörpers 18 gebildet. Nach Durchströmen des Strömungspfads 16 wird der Stoffstrom 11 als Ausgangsmischung aus dem Ausgang 19 gefördert. Die Umlenkmittel 38 bewirken also eine zweimalige Umlenkung der Strömung um jeweils 90°.The corresponding streams are indicated by
Die Eingangskorngrößenverteilung 28 weist eine volle Breite bei halber Höhe 34 (full with half maximum) auf. Diese wird bestimmt, indem man einen waagerechten Schnitt durch die Eingangskorngrößenverteilung 28 bei der Hälfte des Maximalwerts 30 bildet und die Breite dieses Schnitts betrachtet. Analog kann eine volle Breite bei halber Höhe 35 der Ausgangskorngrößenverteilung 29 gebildet werden. Die volle Breite bei halber Höhe 34 der Eingangskorngrößenverteilung 28 ist deutlich größer als die volle Breite bei halber Höhe 35 der Ausgangskorngrößenverteilung 29. Das erfindungsgemäße Verfahren führt also zu kleineren Korngrößen der Festbrennstoffpartikel 23 und zu einer schmaleren Ausgangskorngrößenverteilung 29. Gleichzeitig werden durch die Bildung turbulenter Strömungen beim Durchströmen durch die Querschnittsverengung 12 die Teilchen gleichmäßiger verteilt. Auch der Erwartungswert 36 der Eingangskorngrößenverteilung 28 liegt an einem anderen Punkt als der Erwartungswert 37 der Ausgangskorngrößenverteilung 29.The input grain size distribution 28 has a full width at half height 34 (full with half maximum). This is determined by taking a horizontal cut through the input grain size distribution 28 at half the maximum value 30 and looking at the width of this cut. Similarly, a full width at
Aufgrund der lokal im Festbrennstoffpartikel vorliegenden Unterschiede der Eigenschaften und des Verhaltens der einzelnen Stoffe der Festbrennstoffpartikel 23 kann durch eine entsprechende Einstellung von Förderdruck 26, Ventilkraft 25 und Größe der Querschnittsverengung 12 erreicht werden, dass nur die festen Kohlenstoffanteile dispergieren, während die Aschebildner nicht dispergiert werden, um diese in einem nachgeschalteten Separationsschritt abtrennen zu können, beispielsweise mit einer Mehrphasendekanter. Bevorzugt wird eine Verfahrensführung gewählt, bei der die entstehende Ausgangsmischung langzeitstabil ist, das heißt sich nicht entmischt. Hierzu werden bevorzugt Flüssigkeiten 24 gewählt, die die gleiche Dichte wie die Festbrennstoffpartikel 23 aufweisen, wobei auch der Einsatz von Additiven zur Veränderung der Dichte der Flüssigkeit 24 möglich und erfindungsgemäß ist. Bevorzugt wird ein solches Additiv gewählt, dass sich die Dichte der Flüssigkeit 24 möglichst der Dichte der Festbrennstoffpartikel 23 angleicht.Due to the differences in the properties and the behavior of the individual substances of the
Das erfindungsgemäße Verfahren und die erfindungsgemäße Vorrichtung 1 erlauben in vorteilhafter Weise die Bildung einer homogen durchmischten Ausgangsmischung von Festbrennstoffpartikeln 23 in einer Flüssigkeit 24. Diese kann so gestaltet werden, dass im Wesentlichen kein Dichteunterschied zwischen den Festbrennstoffpartikeln 23 und der Flüssigkeit 24 vorliegt, insbesondere auch durch Zugabe von Additiven zu der Flüssigkeit 24. So kann eine nicht entmischende Dispersion von Festbrennstoffpartikeln 23 in Flüssigkeit 24 erzeugt werden, die beispielsweise als Brennstoff bedenkenlos eingesetzt werden kann, ohne dass die Feuerstätten im Vergleich zur Verbrennung der reinen Flüssigkeit 24 erheblich anders ausgestaltet sein müssen.The inventive method and the
- 11
- Vorrichtung zum Homogenisieren einer Mischung von Festbrennstoff in einer FlüssigkeitApparatus for homogenizing a mixture of solid fuel in a liquid
- 22
- Fördermittelfunding
- 33
- Kolbenpiston
- 44
- erste Bewegungsrichtungfirst direction of movement
- 55
- Führungskanalguide channel
- 66
- Förderkammerdelivery chamber
- 77
- Eingangentrance
- 88th
- VentilValve
- 99
- FörderkammerausgangConveying chamber output
- 1010
- VentilValve
- 1111
- Stoffstrommaterial flow
- 1212
- QuerschnittsverengungCross-sectional narrowing
- 1313
- Sitzventilpoppet valve
- 1414
- Ventilkörpervalve body
- 1515
- Ventilsitzvalve seat
- 1616
- Strömungspfadflow path
- 1717
- Prallflächebaffle
- 1818
- VentilaußenkörperValve outer body
- 1919
- Ausgangoutput
- 2020
- Vorförderpumpeprefeed
- 2121
- Vormischerpremixer
- 2222
- Mischungmixture
- 2323
- FestbrennstoffpartikelSolid fuel particles
- 2424
- Flüssigkeitliquid
- 2525
- Ventilkraftvalve power
- 2626
- Förderdruckdelivery pressure
- 2727
- Ausströmdruckoutflow pressure
- 2828
- EingangskorngrößenverteilungInput grain size distribution
- 2929
- AusgangskorngrößenverteilungInitial particle size distribution
- 3030
- Maximalwertmaximum value
- 3131
- Lagelocation
- 3232
- Maximalwertmaximum value
- 3333
- Lagelocation
- 3434
- volle Breite bei halber Höhefull width at half height
- 3 53 5
- volle Breite bei halber Höhefull width at half height
- 3636
- Erwartungswertexpected value
- 3737
- Erwartungswertexpected value
- 3838
- Umlenkmitteldeflecting
Claims (10)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102011012504A DE102011012504A1 (en) | 2011-02-25 | 2011-02-25 | Method and apparatus for homogenizing a mixture of solid fuel in a liquid |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2492335A1 true EP2492335A1 (en) | 2012-08-29 |
EP2492335B1 EP2492335B1 (en) | 2018-09-26 |
Family
ID=45592234
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12155176.6A Active EP2492335B1 (en) | 2011-02-25 | 2012-02-13 | Method and device for homogenising a mixture of solid fuel in a liquid |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP2492335B1 (en) |
DE (1) | DE102011012504A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3581261A1 (en) * | 2018-06-14 | 2019-12-18 | Tetra Laval Holdings & Finance S.A. | Homogenizer for liquid food |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2933760A1 (en) * | 1979-08-21 | 1981-03-12 | Kurt Dipl.-Ing. 6380 Bad Homburg Bojak | QUASI LIQUID FUEL ON A CARBON DUST BASE |
US4950307A (en) * | 1986-03-17 | 1990-08-21 | Texaco Inc. | Preparation of a high-solids concentration low rank coal slurry |
WO2001080985A1 (en) * | 2000-04-20 | 2001-11-01 | Tracto-Technik Gmbh | Static mixing element |
DE10310442A1 (en) * | 2003-03-11 | 2004-09-23 | Rolf Schüler | Super cavitation assembly promotes molecular integration of fluids by rapid flow reversal within chamber incorporating variable geometry plug |
DE102004038235A1 (en) | 2004-08-05 | 2006-03-16 | Rwe Power Ag | Demineralization of brown coal comprises suspending powdered coal in water and separating demineralized product from mineral-containing water |
US20080202601A1 (en) * | 2007-02-28 | 2008-08-28 | Shigeo Ando | Injection Valve of High Pressure Homogenizer and Injection Valve Unit of the Same |
DE102007034253A1 (en) | 2007-07-16 | 2009-01-22 | Technische Universität Dresden | Preparing flammable liquid, useful e.g. as fuel, from carbon-containing solid material and hydrocarbon containing liquid comprises contacting carbon-containing solid material with carbon-containing liquid and exposing to ultrasonic field |
US20100202960A1 (en) * | 2007-09-12 | 2010-08-12 | M. Technique Co., Ltd. | Titanium dioxide superfine particles and method for producing the same |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61268344A (en) * | 1985-01-22 | 1986-11-27 | Funken:Kk | Method and apparatus for continuous kneading of powder such as fine powdery coal of oil coke in order to prepare slurry |
CA2050624C (en) * | 1990-09-06 | 1996-06-04 | Vladimir Vladimirowitsch Fissenko | Method and device for acting upon fluids by means of a shock wave |
DE4037665A1 (en) * | 1990-11-27 | 1992-06-04 | Dieter Bliesener | Multistage homogenisation assembly with variable throttle cross=section - facilitating adjustments during process operation without interruption and without additional hydraulic medium |
-
2011
- 2011-02-25 DE DE102011012504A patent/DE102011012504A1/en not_active Withdrawn
-
2012
- 2012-02-13 EP EP12155176.6A patent/EP2492335B1/en active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2933760A1 (en) * | 1979-08-21 | 1981-03-12 | Kurt Dipl.-Ing. 6380 Bad Homburg Bojak | QUASI LIQUID FUEL ON A CARBON DUST BASE |
US4950307A (en) * | 1986-03-17 | 1990-08-21 | Texaco Inc. | Preparation of a high-solids concentration low rank coal slurry |
WO2001080985A1 (en) * | 2000-04-20 | 2001-11-01 | Tracto-Technik Gmbh | Static mixing element |
DE10310442A1 (en) * | 2003-03-11 | 2004-09-23 | Rolf Schüler | Super cavitation assembly promotes molecular integration of fluids by rapid flow reversal within chamber incorporating variable geometry plug |
DE102004038235A1 (en) | 2004-08-05 | 2006-03-16 | Rwe Power Ag | Demineralization of brown coal comprises suspending powdered coal in water and separating demineralized product from mineral-containing water |
US20080202601A1 (en) * | 2007-02-28 | 2008-08-28 | Shigeo Ando | Injection Valve of High Pressure Homogenizer and Injection Valve Unit of the Same |
DE102007034253A1 (en) | 2007-07-16 | 2009-01-22 | Technische Universität Dresden | Preparing flammable liquid, useful e.g. as fuel, from carbon-containing solid material and hydrocarbon containing liquid comprises contacting carbon-containing solid material with carbon-containing liquid and exposing to ultrasonic field |
US20100202960A1 (en) * | 2007-09-12 | 2010-08-12 | M. Technique Co., Ltd. | Titanium dioxide superfine particles and method for producing the same |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3581261A1 (en) * | 2018-06-14 | 2019-12-18 | Tetra Laval Holdings & Finance S.A. | Homogenizer for liquid food |
WO2019238862A1 (en) * | 2018-06-14 | 2019-12-19 | Tetra Laval Holdings & Finance S.A. | Homogenizer for liquid food and method of homogenizing |
US12053748B2 (en) | 2018-06-14 | 2024-08-06 | Tetra Laval Holdings & Finance S.A. | Homogenizer for liquid food |
Also Published As
Publication number | Publication date |
---|---|
EP2492335B1 (en) | 2018-09-26 |
DE102011012504A1 (en) | 2012-08-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE102005037026B4 (en) | cavitation mixer | |
EP2247516B1 (en) | Biomass transport installation for introduction into a pressurised container | |
DE102004028406B4 (en) | Within a cylinder arranged injection screw | |
WO2007118788A1 (en) | Continuous process for performing a chemical reaction in which a gaseous phase is added to a charge stream comprising one or more solid phases which have been dissolved or dispersed in water | |
DE3851106T2 (en) | Device for mixing flowable media. | |
DE1296582B (en) | Device for separating substances by foam flotation | |
DE102008000432A1 (en) | Rührkesselreaktor and methods for carrying out a polymerization reaction using such a stirred tank reactor | |
DE2040919A1 (en) | Screw extruder with static mixer | |
EP1475143B1 (en) | Apparatus for dispersing or homogenising | |
EP1278593A1 (en) | Static mixing element | |
DE102007040645A1 (en) | Extruder i.e. planetary gear extruder, for use during extrusion of plastic i.e. polyethylene terephthalate, has degasifying vent that is formed in housing, where degassing opening runs oblong and diagonal to longitudinal axis of extruder | |
DE102016013785A1 (en) | Tire sealant mixing device | |
DE3686720T2 (en) | SLAG DISPENSING SYSTEM FOR A GASIFICATION REACTOR FOR SOLID FUELS. | |
EP1637301A2 (en) | screw extruder and vacuum pump arrangement | |
DE102012008169A1 (en) | Planetary rolling construction or modular structured extruder for processing plastic material in e.g. food industry for manufacturing brush, has tooth ends exhibiting slant that is more steep than that of slant of flanks to gear diameter | |
DE102009024269A1 (en) | Mixing device for a gas burner | |
EP2492335B1 (en) | Method and device for homogenising a mixture of solid fuel in a liquid | |
DE2432860A1 (en) | Continuous mixer for dispersing matls. in liqs. - is fed by non-clogging premixer for mixt. components | |
DE60201985T2 (en) | DEVICE FOR THE HOMOGENEOUS LIQUID DISTRIBUTION IN A CONTAINER AND ITS APPLICATION | |
DE102009055665A1 (en) | Method and apparatus for high pressure mixing of filled polyurethane resins | |
DE2226621C3 (en) | Atomizing burner | |
EP3710224B1 (en) | Plasticating screw | |
DE2340726A1 (en) | Combined mixing and milling of pastes - fine dispersions achieved in one machine by sequential action | |
EP4093535B1 (en) | Method for producing a stable hydrocarbon-water dispersion for improving combustion processes, and a water-hydrocarbon dispersion that is easily separable into at least two phases as part of the clean-up process at accident locations | |
EP1245877A1 (en) | Mechanical seal arrangement |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
17P | Request for examination filed |
Effective date: 20120919 |
|
17Q | First examination report despatched |
Effective date: 20140724 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20180503 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: ACKERMANN, RALF |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1046045 Country of ref document: AT Kind code of ref document: T Effective date: 20181015 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 502012013491 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20180926 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181226 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181227 Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181226 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190126 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190126 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502012013491 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20190627 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20190213 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190213 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190228 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190213 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190213 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 1046045 Country of ref document: AT Kind code of ref document: T Effective date: 20190213 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190213 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20120213 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180926 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CZ Payment date: 20230202 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20230216 Year of fee payment: 12 Ref country code: BE Payment date: 20230220 Year of fee payment: 12 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230516 |