EP2468127A1 - Modeschmuckstück und Herstellungsverfahren eines solchen Schmuckstücks - Google Patents

Modeschmuckstück und Herstellungsverfahren eines solchen Schmuckstücks Download PDF

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Publication number
EP2468127A1
EP2468127A1 EP11193937A EP11193937A EP2468127A1 EP 2468127 A1 EP2468127 A1 EP 2468127A1 EP 11193937 A EP11193937 A EP 11193937A EP 11193937 A EP11193937 A EP 11193937A EP 2468127 A1 EP2468127 A1 EP 2468127A1
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EP
European Patent Office
Prior art keywords
composition
weight
fibers
elastomer
microfibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP11193937A
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English (en)
French (fr)
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EP2468127B1 (de
Inventor
Pascal Bourquard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Biwi SA
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Biwi SA
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    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44CPERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C27/00Making jewellery or other personal adornments
    • A44C27/001Materials for manufacturing jewellery
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44CPERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
    • A44C5/00Bracelets; Wrist-watch straps; Fastenings for bracelets or wrist-watch straps
    • A44C5/0053Flexible straps

Definitions

  • the present invention relates to jewelery pieces.
  • the invention also relates to a method of manufacturing such parts.
  • a piece of jewelry refers to any object of adornment, but also components used in the watch industry or in jewelery. More particularly, the invention relates to bracelets, such as watch bracelets.
  • the patent GB 2,349,239 discloses a watch case made of a composite material comprising a polymer matrix, such as epoxy or polyester, and fibers. No precise composition is however indicated. In addition, the specifications of a watch case does not correspond to the specifications of a bracelet for example.
  • An object of the present invention is therefore to overcome these disadvantages, by providing jewelry parts to use materials compatible with FDA standards or the Reach standard while having properties to meet their specifications.
  • a piece of jewelry at least partially made of a composite material comprising an elastomeric matrix in which are dispersed reinforcing fillers selected from the group comprising microfibers, polytetrafluoroethylene nanoparticles, and mixtures thereof, said composite material being obtained from a composition comprising between 60% and 95% by weight of at least one elastomer, between 0% and 5% by weight of microfibers and between 0% and 40% by weight of polytetrafluoroethylene nanoparticles, relative to the total weight of the composition, at least one of said reinforcing fillers being present.
  • Such a composition makes it possible to obtain, particularly during the injection manufacturing process, structures such as watch straps with holes, because of interesting mechanical properties (rigidity) and good distribution of the fibers.
  • the piece of jewelery is made from a composition comprising at least one elastomer and reinforcing fillers chosen from the group comprising microfibers, polytetrafluoroethylene nanoparticles, and mixtures thereof.
  • the elastomer is selected from the group consisting of nitrile elastomers and fluoroelastomers.
  • fluoroelastomers is used in the general sense independently of the fluorine content and refers to both fluorinated elastomers whose main chain is partially substituted, ie fluoroelastomers commonly called FKM, as well as fluorinated elastomers whose main chain is entirely substituted, that is to say the perfluoroelastomers commonly called FFKM.
  • FKM fluorinated elastomers
  • FFKM perfluoroelastomers
  • These elastomers may be used alone or in admixture with other suitable elastomers or types of FKM or FFKM.
  • Fluoroelastomers are amorphous polymers having a glass transition temperature below room temperature (25 ° C). They are distinguished from plastic polymers, such as PTFE. PTFE is a rigid thermoplastic polymer and not an elastomer.
  • the elastomer is a fluoroelastomer, and more preferably a fluoroelastomer of FKM type.
  • the amount of elastomer is between 60% and 95% by weight, preferably between 70% and 90% by weight relative to the total weight of the composition.
  • the reinforcing fillers are microfibres.
  • the composition according to the invention comprises between 0.1% and 4%, preferably between 0.2% and 2%, more preferably between 0.4% and 1.5%, and still more preferably between 0, 5% and 1.25% by weight of microfibers relative to the total weight of the composition.
  • the fibers used are microfibers defined by their average length of between 10 ⁇ m and 2 mm and by their mean diameter of between 50 ⁇ m and 0.5 mm.
  • the fibers are selected from the group consisting of aramid based fibers, wood fibers, glass fibers, carbon fibers and mixtures thereof.
  • aramid or Kevlar®-based fibers are used. These fibers may be incorporated into a masterbatch.
  • the masterbatch is chosen to meet FDA or Reach standards.
  • the average length / mean diameter ratio of the fibers is between 20 and 150 and preferably between 40 and 100. More preferably, short fibers are used, with a mean length / mean diameter ratio greater than 50.
  • the reinforcing fillers are nanoparticles of polytetrafluoroethylene (PTFE).
  • PTFE polytetrafluoroethylene
  • the composition preferably comprises between 10% and 40%, preferably between 15% and 35%, more preferably between 20% and 30% by weight of polytetrafluoroethylene nanoparticles relative to the total weight of the composition.
  • the nanoparticles of polytetrafluoroethylene may be incorporated into a masterbatch.
  • the masterbatch is chosen to meet FDA or Reach standards.
  • the PTFE nanoparticles may for example be generated in situ during the synthesis of the elastomer in order to have an interfacial connection of a chemical nature. More specifically, it is possible to use as an elastomer for the composition used in the invention, a fluoroelastomer comprising such nanoparticles of PTFE generated in situ such as Tecnoflon® elastomers produced according to the patented technology according to the patent EP 1031607 of Solvay Solexis.
  • microfibers and nanoparticles of PTFE can be used as a mixture.
  • fillers can be considered such as silica or carbon black.
  • the composition may also comprise vulcanizing or crosslinking agents specific to the elastomer, and other conventional additives commonly used by those skilled in the field of elastomer-based formulations, and more particularly fluoroelastomer-based formulations.
  • the crosslinking agents may be of the peroxide type, the concentration being optimized according to the practices known to those skilled in the art.
  • the composition may further comprise a coloring agent, such as a dye or, preferably, a pigment.
  • a coloring agent such as a dye or, preferably, a pigment. Mixtures of dyes and / or pigments can be used.
  • PTFE nanoparticles will be used for lightly loaded colors, such as light or pastel colors, and microfibers for charged colors, such as dark or bright colors.
  • the molding can be done by any known method, such as injection or compression.
  • the vulcanization (or cooking) is conducted in a known manner at a temperature generally between 130 ° C and 200 ° C, for a sufficient time that can vary depending on the room, for example between 60 and 300 seconds depending in particular on the cooking temperature, adopted vulcanization system and the kinetics of vulcanization of the composition.
  • a piece of jewelry according to the invention has improved mechanical strength. Furthermore, it has been observed, surprisingly, that the process according to the invention allows an improvement of the manufacturing process, namely a decrease in scrap. In addition, it has been observed a productivity gain with a decrease in the vulcanization time.
  • the piece of jewelry may be for example a bracelet, including a watch band. More specifically, a bracelet according to the invention may have particular shapes and cuts and nevertheless meet a stringent specifications in terms of mechanical strength, and more specifically in terms of tensile strength.
  • the present invention makes it possible to use fluoroelastomers, especially of the FKM type, which are compatible with FDA standards and the Reach standard.
  • Samples according to the invention were made with a FKM elastomer and 0.5%, 1.25% and 2% of Kevlar® microfibers. For comparison, a sample was made without microfiber.
  • the curves representing the stress as a function of the deformation are represented on the figure 1 .
  • the evolution of the stress is here given for deformations less than 150%, range of deformation in which the parts generally work at the macroscopic level.
  • Curve A corresponds to 0% microfibers
  • curve B corresponds to 0.5% microfibers
  • curve C corresponds to 1.25% microfibers
  • curve D corresponds to 2% microfibers.
  • Samples in accordance with the invention were made with a FKM elastomer (to be specified) and 0.5% by weight of Kevlar® microfibers. For comparison, a sample was made without microfiber.
  • the samples are rectangular specimens 20 mm wide and 3 mm thick. Rectangular holes spaced of different lengths were made in these specimens so as to simulate barb holes in a bracelet.
  • the holes have a dimension of 4x2.5 mm, with a radius of curvature of 0.2.
  • the letters A and B respectively represent the samples without and with microfibers.
  • the gain in tensile strength is 31%
  • the gain in holding tensile strength is 12%
  • the gain in tensile strength is 43%
  • the gain in holding at the traction is 48%.
  • Samples according to the invention were made with a Solvay Solexis FKM Tecnoflon® elastomer comprising 23% by weight of PTFE nanoparticles. For comparison, a sample was made without nanoparticles.
  • the samples are rectangular specimens 20 mm wide and 3 mm thick. Circular holes, 2 mm in diameter, and spaced of different lengths were made in these specimens so as to simulate barb holes in a bracelet.
  • the curve comprising diamonds corresponds to the samples without nanoparticles and the curve comprising squares corresponds to the samples with nanoparticles of PTFE according to the invention.
  • microfibers and / or nanoparticles of PTFE associated with a fluoroelastomer-type elastomer makes it possible to obtain a piece of jewelery such as a watch bracelet that may have particular shapes and cutouts and still respond to a severe specifications in terms of mechanical strength, and more specifically in terms of tensile strength, and in terms of compatibility with FDA standards and the Reach standard.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
EP20110193937 2010-12-23 2011-12-16 Modeschmuckstück und Herstellungsverfahren eines solchen Schmuckstücks Not-in-force EP2468127B1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH02165/10A CH704268A2 (fr) 2010-12-23 2010-12-23 Pièce de bijouterie et procédé de fabrication d'une telle pièce.

Publications (2)

Publication Number Publication Date
EP2468127A1 true EP2468127A1 (de) 2012-06-27
EP2468127B1 EP2468127B1 (de) 2014-03-26

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EP (1) EP2468127B1 (de)
CH (1) CH704268A2 (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3178875A1 (de) * 2015-12-11 2017-06-14 The Swatch Group Research and Development Ltd. Bequemes elastomermaterial
CN107924733A (zh) * 2015-09-03 2018-04-17 索尔维特殊聚合物意大利有限公司 缆线护套
CN108026229A (zh) * 2015-09-03 2018-05-11 索尔维特殊聚合物意大利有限公司 表带
US20190161607A1 (en) * 2016-06-13 2019-05-30 Solvay Specialty Polymers Italy S.P.A. Curable fluoroelastomer composition
EP3714725A1 (de) 2019-03-26 2020-09-30 Omega SA Schmuckstück aus elastomerverbundmaterial
CN111978601A (zh) * 2019-05-23 2020-11-24 斯沃奇集团研究及开发有限公司 由天然弹性体材料制成的首饰

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110573573A (zh) 2017-03-14 2019-12-13 索尔维特殊聚合物意大利有限公司 包含半晶质vdf聚合物和氟化热塑性弹性体嵌段共聚物的组合物

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5054299A (en) * 1990-02-28 1991-10-08 Maveety Susan C Jewelry, without fasteners, formed by the wearer by bending from a planar configuration into circular and/or other configurations to be worn as a necklace, bracelet, belt, etc, and reformed many times to serve as the same or other jewelry
FR2680727A1 (fr) * 1991-09-04 1993-03-05 Rosnoblet Philippe Materiaux composite haut de gamme carbonne/or.
EP1031607A1 (de) 1999-02-23 2000-08-30 Ausimont S.p.A. Fluorkautschukzusammensetzungen
GB2349239A (en) 1999-04-15 2000-10-25 Andrew R Thayer Watch case
US20080041099A1 (en) * 2004-06-15 2008-02-21 Yoshihiro Hirata Health Jewelry Utilizing Silicone Elastomer and Process for Producing the Same
US20090175135A1 (en) * 2007-10-31 2009-07-09 Movado Llc, A Limited Liability Company Integrated watch band and methods therefor
US7575800B2 (en) 2001-11-02 2009-08-18 Kitagawa Industries Co., Ltd. Sliding parts, precision parts and timepieces and electronic equipment using the same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5054299A (en) * 1990-02-28 1991-10-08 Maveety Susan C Jewelry, without fasteners, formed by the wearer by bending from a planar configuration into circular and/or other configurations to be worn as a necklace, bracelet, belt, etc, and reformed many times to serve as the same or other jewelry
FR2680727A1 (fr) * 1991-09-04 1993-03-05 Rosnoblet Philippe Materiaux composite haut de gamme carbonne/or.
EP1031607A1 (de) 1999-02-23 2000-08-30 Ausimont S.p.A. Fluorkautschukzusammensetzungen
GB2349239A (en) 1999-04-15 2000-10-25 Andrew R Thayer Watch case
US7575800B2 (en) 2001-11-02 2009-08-18 Kitagawa Industries Co., Ltd. Sliding parts, precision parts and timepieces and electronic equipment using the same
US20080041099A1 (en) * 2004-06-15 2008-02-21 Yoshihiro Hirata Health Jewelry Utilizing Silicone Elastomer and Process for Producing the Same
US20090175135A1 (en) * 2007-10-31 2009-07-09 Movado Llc, A Limited Liability Company Integrated watch band and methods therefor

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107924733A (zh) * 2015-09-03 2018-04-17 索尔维特殊聚合物意大利有限公司 缆线护套
CN108026229A (zh) * 2015-09-03 2018-05-11 索尔维特殊聚合物意大利有限公司 表带
EP3178875A1 (de) * 2015-12-11 2017-06-14 The Swatch Group Research and Development Ltd. Bequemes elastomermaterial
WO2017097439A1 (fr) * 2015-12-11 2017-06-15 The Swatch Group Research And Development Ltd Matière élastomérique confortable
US10732573B2 (en) 2015-12-11 2020-08-04 Omega Sa Comfortable elastomer material
US20190161607A1 (en) * 2016-06-13 2019-05-30 Solvay Specialty Polymers Italy S.P.A. Curable fluoroelastomer composition
JP2019517622A (ja) * 2016-06-13 2019-06-24 ソルベイ スペシャルティ ポリマーズ イタリー エス.ピー.エー. 硬化性フルオロエラストマー組成物
JP2020158766A (ja) * 2019-03-26 2020-10-01 オメガ・エス アー 複合エラストマー材料で作られた宝飾品
EP3714725A1 (de) 2019-03-26 2020-09-30 Omega SA Schmuckstück aus elastomerverbundmaterial
CN111748213A (zh) * 2019-03-26 2020-10-09 奥米加股份有限公司 由弹性体复合材料制成的珠宝首饰
US11140951B2 (en) 2019-03-26 2021-10-12 Omega Sa Piece of jewellery made of composite elastomer material
CN111978601A (zh) * 2019-05-23 2020-11-24 斯沃奇集团研究及开发有限公司 由天然弹性体材料制成的首饰
EP3741247A1 (de) 2019-05-23 2020-11-25 The Swatch Group Research and Development Ltd Schmuckstück aus natürlichem elastomermaterial
JP2020189083A (ja) * 2019-05-23 2020-11-26 ザ・スウォッチ・グループ・リサーチ・アンド・ディベロップメント・リミテッド 天然エラストマー材料で作られた装飾品
US20200367617A1 (en) * 2019-05-23 2020-11-26 The Swatch Group Research And Development Ltd Piece of jewellery made of natural elastomer material
US11672313B2 (en) 2019-05-23 2023-06-13 The Swatch Group Research And Development Ltd Piece of jewellery made of natural elastomer material

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EP2468127B1 (de) 2014-03-26
CH704268A2 (fr) 2012-06-29

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