EP2434500A1 - Câble de remorquage - Google Patents

Câble de remorquage Download PDF

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Publication number
EP2434500A1
EP2434500A1 EP10306011A EP10306011A EP2434500A1 EP 2434500 A1 EP2434500 A1 EP 2434500A1 EP 10306011 A EP10306011 A EP 10306011A EP 10306011 A EP10306011 A EP 10306011A EP 2434500 A1 EP2434500 A1 EP 2434500A1
Authority
EP
European Patent Office
Prior art keywords
halogen
free
band
banding
electrically conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10306011A
Other languages
German (de)
English (en)
Other versions
EP2434500B1 (fr
Inventor
Peter Ulfig
Walter Winkelbauer
Christian Dr. Cornelissen
Smaeil Basiry
Katja Dybowski
Peter Kroh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nexans SA
Original Assignee
Nexans SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nexans SA filed Critical Nexans SA
Priority to EP20100306011 priority Critical patent/EP2434500B1/fr
Publication of EP2434500A1 publication Critical patent/EP2434500A1/fr
Application granted granted Critical
Publication of EP2434500B1 publication Critical patent/EP2434500B1/fr
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Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame

Definitions

  • the invention relates to a conduit having an electrical conductor, which is preferably a stranded conductor, the conduit having a construction which gives the conduit a good flame retardance, as well as a high resistance to low temperatures, e.g. to -40 ° C in the cold in the impact test.
  • the line according to the invention can also be used as a single-core hawser line, e.g. be used for the medium voltage range, in particular as a flexible flame-retardant and cold-resistant single-core hawser.
  • the invention provides a method for producing the line according to the invention.
  • the object of the invention is to provide an alternative conduit, in particular a single-conductor conduit, which preferably has a good resistance to fire, as well as a good resistance to low temperatures, e.g. proved by a cold impact test according to EN60811-1-4.
  • polymer blends are said to be halogen-free if they contain no organic halogen compounds, especially no halogenated polymer components.
  • the layers, which are made of polymer blends, are extruded and crosslinked polymer blends, which are preferably each free of organic halogen compounds, in particular containing no organic chlorine compounds.
  • Polymer blends are said to be halogen-free for the purposes of the invention if, alternatively or in addition to being free of organic halogen compounds, they are volatile according to EN 50267-2-1 with respect to hydrochloric and hydrobromic ( ⁇ 0.5% HCl and HBr ) and halogen-free according to EN 60684-2 with respect to hydrogen fluoride ( ⁇ 0.1% HF volatile).
  • the cable according to the invention or the cable according to the invention comprises a conductor, in particular only one conductor, which is a stranded conductor and is preferably comprised of a halogen-free extruded inner conductive layer.
  • a bandage made of woven or nonwoven fabric can be arranged between the stranded conductor and the inner conductive layer, preferably of halogen-free, electrically conductive nonwoven fabric.
  • the conductor is preferably made of fine-stranded copper, preferably tinned, in particular class 5 according to EN 60228.
  • the outer jacket preferably consists of a crosslinked mixture which meets the requirements of EM102 according to EN 50264-1, particularly preferably according to EM104.
  • An exemplary mixture for the outer shell has or consists of a halogen-free polymer mixture containing as crosslinkable components 95 to 70 phr of at least one alkylene-vinyl acetate copolymer having at least 40 wt .-% vinyl acetate units and 5 to 30 phr of at least one polyalkylene polymer containing from 0.2 to 2 wt .-% dicarboxylic acid groups and a Crosslinking system, 100 to 250 phr of a flame retardant filler, 10 to 30 phr kaolin and 1 to 25 phr plasticizer.
  • the halogen-free polymer blend for the sheath comprises or consists of from 5 to 30 phr, preferably 10 to 25 phr, more preferably 15-20 phr of one or a mixture of polyalkylene graft copolymers containing 0.2 to 2% by weight of dicarboxylic acid units, preferably 0.5 to 1.0% by weight of dicarboxylic acid units, wherein the alkylene units are preferably ethylene and / or propylene and the dicarboxylic acid units are preferably maleic acid, and 95 to 70 phr, preferably 90 to 75 phr, more preferably 85 to 80 phr, more preferably 80 phr of one or a mixture of alkylene-vinyl acetate copolymers having a total of 40 wt .-% or more, preferably 50-70 wt .-%, more preferably 60 wt .-% Vinylacetateinpond, wherein the alkylene-vinyl
  • Preferred constituents or additives of the polymer blend for the shell which have no reactive groups with the crosslinkable components, flame retardant fillers, in particular selected from aluminum hydroxide, magnesium hydroxide and / or magnesium carbonate, to a total of 100 to 250 phr, preferably 140 to 180 phr, more preferably 150-160 phr, Kaolin, in particular selected from calcined kaolin, hard kaolin, soft kaolin and / or talc at 10 to 30 phr, more preferably 12 to 15 phr, in particular 12.5 phr, plasticizer, in particular adipate and / or sebacate, in particular Di-2 octyl sebacate, at 1 to 25 phr, preferably 10 to 20 phr, more preferably 13 to 15 phr, Anti-aging agents, for example TMQ (2,2,4-trimethyl-1,2-dihydroquinoline), ZMBI (zinc salt of 2-mercaptobenzimidazole),
  • a peroxide compound is preferably used, for example, [1,3 (or 1,4) -phenylenebis (1-methylethylidene)] bis [tert-butyl] peroxide, preferably with a co-activator, preferably a triallyl cyanurate, e.g. 2,4,6-tris (allyloxy) -1,3,5-triazine.
  • a co-activator preferably a triallyl cyanurate, e.g. 2,4,6-tris (allyloxy) -1,3,5-triazine.
  • the crosslinking system may comprise or consist of a co-activator in conjunction with the irradiation of the mixture with ionizing radiation.
  • the polyalkylene polymer having dicarboxylic acid groups is preferably a graft copolymer in which polyethylene, polypropylene and / or ethylene-propylene copolymer are grafted with a dicarboxylic acid-containing compound, for example, maleic anhydride and / or an aryl diacid ester.
  • the insulating layer preferably has a quality according to EI110 according to EN 50264-1 and is a halogen-free, extruded and crosslinked polymer mixture based on EPR.
  • the insulating layer has a layer thickness of 2 to 10 mm and the conductor has a cross section of 25 to 300 mm 2 .
  • a dimensioning of the layers and of the conductor cross-section can be determined by customary means and according to the applicable standards.
  • the line is preferably dimensioned for use in a voltage level of> 20 kV.
  • cables according to the invention meet the requirements according to EN 50264-1 for resistance to fuels based on mineral oil according to EM 102, preferably according to EM104, in conjunction with a high resistance to mineral oil.
  • the fuel resistance is determined, for example, as a slight change in tensile strength and elongation at break after storage for 7 days at 70 ° C in IRM903.
  • the inventive pipe has a resistance to aromatic mineral oils, eg determined after storage in IRM902 at 100 ° C.
  • the line has a good thermal resistance, in particular against load for 10 days at temperatures of 120 ° C, preferably in combination with a good resistance to water, eg according to IEC60811-1-3, and a good resistance to UV and ozone , Overall, the cable meets the requirements of the property profile EM104 according to EN 50264-1.
  • the line according to the invention is characterized in addition to the halogen-free by a special flame or fire resistance, which is for example represented by the fulfillment of the requirements of EN 50264-1, in particular with respect to the behavior of the line in case of fire.
  • a special flame or fire resistance which is for example represented by the fulfillment of the requirements of EN 50264-1, in particular with respect to the behavior of the line in case of fire.
  • the requirements of EN 60332-1-2 concerning flame propagation on a single, vertically arranged pipe are met, the requirements according to EN 50266-2-4 for flame propagation of cables according to the invention arranged in the bundle, the requirements of EN 61034-2 the evolution of flue gas, the requirements of EN 50305, point 9.2 on toxicity and the requirements of EN 50267-2-2 concerning the corrosivity of combustion gases.
  • the halogen-free conductivity of the conduit is determined by meeting the requirements for halogen freedom according to EN 50267-2-1 with regard to hydrogen chloride and according to EN 60684-2 with regard to fluorine.
  • the line according to the invention preferably also meets the requirements of NF F16101, category D for flame propagation, as well as the requirements according to UIC 564-2, appendix 9 on the burning behavior.
  • the line according to the invention preferably also meets the requirements according to EN 60811-1-4 item 8.5 with respect to the suitability for use at low temperatures, for example the existence the cold impact test at -40 ° C.
  • the line according to the invention meets the requirements for flame resistance, flame propagation and combustion behavior with freedom from organic halogen compounds, in particular halogen-free polymers in the crosslinked polymer mixtures contained, preferably in combination with a resistance to low temperatures, in particular permanent flexibility and resistance even at low temperatures of up to -40 ° C, for example, demonstrated by passing a cold impact test in a test method according to EN60811-1-4, more preferably down to -40 ° C.
  • the line according to the invention is preferably suitable for use as a cold-resistant and cold-elastic line at up to -40 ° C, for example at a load according to EN60811-1-4.
  • the line preferably has a rotationally symmetrical cross section, in which the successive layers are arranged in a constant layer thickness.
  • the line will be described below with reference to the successive layers in their sequence from the inner conductor 1 to the outer outer jacket 9.
  • the line is single-core according to the preferred embodiment.
  • the conductor 1 which consists in particular of tinned copper strands stranded together, is circumferentially surrounded by an inner conductive layer 2 made of a crosslinked, halogen-free, electrically conductive polymer mixture.
  • a banding made of halogen-free, electrically conductive nonwoven may optionally be arranged.
  • the inner conductive layer 2 is comprised of an insulation 3 of halogen-free crosslinked polymer mixture based on EPR. Particularly preferred is on the outer surface of the insulation 3, a second conductive layer 4 of crosslinked halogen-free, electrically conductive polymer mixture.
  • the metallic shielding 6 is contacted on its inside by the first banding 5 and on its outside by the second banding 7 and by a third banding 8 comprising glass cloth band.
  • the glass belt of the third band 8 is particularly preferably glass cloth band of silica glass, which is particularly preferably resistant to high temperatures, e.g. up to 1,000 ° C and in particular for use up to 1,000 ° C is suitable.
  • the outer jacket 9 comprises the third band 8 and preferably lies on the third band 8 and consists of a halogen-free crosslinked polymer mixture, in particular based on EVA.
  • This flexibility and flexing capability makes the cable suitable for installation in confined spaces and in applications where the duct is moved.
  • the pipe has the flexibility and bending ability preferably in combination with a low flame spread, eg according to NF F16101, category D and a burning behavior according to UIC 564-2, Appendix 9.
  • the line is particularly suitable for use as a supply line for electrical machines, in where the line is moved and moved in tight bending radii, for example, along a pantograph of a train, especially a locomotive.

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  • Insulated Conductors (AREA)
EP20100306011 2010-09-22 2010-09-22 Câble de remorquage Active EP2434500B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20100306011 EP2434500B1 (fr) 2010-09-22 2010-09-22 Câble de remorquage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20100306011 EP2434500B1 (fr) 2010-09-22 2010-09-22 Câble de remorquage

Publications (2)

Publication Number Publication Date
EP2434500A1 true EP2434500A1 (fr) 2012-03-28
EP2434500B1 EP2434500B1 (fr) 2013-02-13

Family

ID=43466427

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20100306011 Active EP2434500B1 (fr) 2010-09-22 2010-09-22 Câble de remorquage

Country Status (1)

Country Link
EP (1) EP2434500B1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103854729A (zh) * 2012-11-29 2014-06-11 陈下放 一种阻燃性高的电缆
CN103903719A (zh) * 2014-03-03 2014-07-02 安徽万博电缆材料有限公司 一种耐油防水自控温多芯同轴电缆
CN103971800A (zh) * 2014-05-26 2014-08-06 中科华核电技术研究院有限公司 耐高温电磁线圈用绕组线及其制造方法
CN104078151A (zh) * 2013-03-29 2014-10-01 无锡市苏南电缆有限公司 一种低烟无卤电力电缆
CN104505157A (zh) * 2014-12-22 2015-04-08 上海万普线缆有限公司 一种圆形耐寒电缆及其制造方法
CN104992775A (zh) * 2015-06-19 2015-10-21 张家港金海港电线电缆有限公司 一种耐用电线
CN105405522A (zh) * 2015-12-07 2016-03-16 无锡裕德电缆科技有限公司 轨道交通1500v及以下直流牵引阻燃电力电缆

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103903769A (zh) * 2014-03-03 2014-07-02 江苏珠影特种电缆有限公司 一种单芯耐火电缆
CA3038212C (fr) 2018-03-28 2023-02-28 General Cable Technologies Corporation Cable de communication de donnees resistant au feu

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060261A (en) * 1960-03-30 1962-10-23 Anaconda Wire & Cable Co Shielded electric cable
DE4007020A1 (de) * 1990-03-06 1991-09-12 Siemens Ag Kabel mit einer abschirmung
EP0938101A2 (fr) * 1998-02-21 1999-08-25 Alcatel Cordon électrique ou câble électrique
WO2008142385A1 (fr) * 2007-05-18 2008-11-27 Draka U.K. Limited Câble résistant au feu
US20090300909A1 (en) * 2008-06-10 2009-12-10 Southwire Company Low temperature applications of flame retardant power cable

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060261A (en) * 1960-03-30 1962-10-23 Anaconda Wire & Cable Co Shielded electric cable
DE4007020A1 (de) * 1990-03-06 1991-09-12 Siemens Ag Kabel mit einer abschirmung
EP0938101A2 (fr) * 1998-02-21 1999-08-25 Alcatel Cordon électrique ou câble électrique
WO2008142385A1 (fr) * 2007-05-18 2008-11-27 Draka U.K. Limited Câble résistant au feu
US20090300909A1 (en) * 2008-06-10 2009-12-10 Southwire Company Low temperature applications of flame retardant power cable

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103854729A (zh) * 2012-11-29 2014-06-11 陈下放 一种阻燃性高的电缆
CN104078151A (zh) * 2013-03-29 2014-10-01 无锡市苏南电缆有限公司 一种低烟无卤电力电缆
CN103903719A (zh) * 2014-03-03 2014-07-02 安徽万博电缆材料有限公司 一种耐油防水自控温多芯同轴电缆
CN103971800A (zh) * 2014-05-26 2014-08-06 中科华核电技术研究院有限公司 耐高温电磁线圈用绕组线及其制造方法
CN103971800B (zh) * 2014-05-26 2017-07-14 中广核研究院有限公司 耐高温电磁线圈用绕组线及其制造方法
CN104505157A (zh) * 2014-12-22 2015-04-08 上海万普线缆有限公司 一种圆形耐寒电缆及其制造方法
CN104992775A (zh) * 2015-06-19 2015-10-21 张家港金海港电线电缆有限公司 一种耐用电线
CN105405522A (zh) * 2015-12-07 2016-03-16 无锡裕德电缆科技有限公司 轨道交通1500v及以下直流牵引阻燃电力电缆

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