EP2398653A1 - Sicherheitselement zur kennzeichnung und/oder identifikation von gegenständen - Google Patents
Sicherheitselement zur kennzeichnung und/oder identifikation von gegenständenInfo
- Publication number
- EP2398653A1 EP2398653A1 EP10704767A EP10704767A EP2398653A1 EP 2398653 A1 EP2398653 A1 EP 2398653A1 EP 10704767 A EP10704767 A EP 10704767A EP 10704767 A EP10704767 A EP 10704767A EP 2398653 A1 EP2398653 A1 EP 2398653A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- isomers
- security element
- element according
- security
- matrix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000126 substance Substances 0.000 claims abstract description 11
- 230000005855 radiation Effects 0.000 claims abstract description 8
- 230000003595 spectral effect Effects 0.000 claims abstract description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 6
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 claims description 6
- 239000005711 Benzoic acid Substances 0.000 claims description 4
- 235000010233 benzoic acid Nutrition 0.000 claims description 4
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000000862 absorption spectrum Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000001028 reflection method Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
-
- G—PHYSICS
- G07—CHECKING-DEVICES
- G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
- G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
- G07D7/14—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using chemical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/387—Special inks absorbing or reflecting ultraviolet light
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F3/0297—Forms or constructions including a machine-readable marking, e.g. a bar code
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F3/03—Forms or constructions of security seals
- G09F3/0305—Forms or constructions of security seals characterised by the type of seal used
- G09F3/0341—Forms or constructions of security seals characterised by the type of seal used having label sealing means
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/08—Fastening or securing by means not forming part of the material of the label itself
- G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
-
- B42D2035/16—
-
- B42D2035/34—
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F2003/0276—Safety features, e.g. colour, prominent part, logo
- G09F2003/0277—Tamper resistant
Definitions
- Security element for identifying and / or identifying objects
- the invention relates to a security element for the identification and / or identification of objects, according to the preamble of the main claim.
- a security and / or security document in which at least two different luminescent substances emitting at different emission wavelengths are arranged at different locations on the surface of the document and form a luminescent substance pattern, each emission wavelength being associated with a character and each location of a character position Selection of the various luminescent dyes in conjunction with which a machine-readable string of characters is formed.
- the invention is therefore based on the object
- the security element according to the invention contains at least two isomers of a substance whose spectral properties differ and can be detected in the THz frequency range
- the security element i. the isomers are recognized in the form of a structure using radiation in the THz range, whereas they can not be distinguished under UV illumination, in the visible or in the near infrared range.
- isomers of different substances or types of molecules can be used, the transition from one substance or molecular species to another, which can be used to make the structure of the security element visible at a different THz frequency, without permanent and costly Monitoring of counterfeiters is not noticeable. If such a transition is nevertheless noticed, it is again associated with great technical effort for imitation, i. The hurdle for counterfeiting is high and every change provides a new time advantage.
- the isomers for forming the structure may be arranged two- or three-dimensionally on a support, for example, a bar code or another pattern code, but also
- the carrier can be part of the security element, for example as a label, which is applied to the object to be marked.
- the carrier may also be the object itself or part of it.
- the isomers are selected from structural isomers, e.g. Positional isomers, or stereoisomers such as enantiomers or diastereomers.
- structural isomers by way of example, o-, m- or p-toluic acid may be considered as isomers of the substance benzoic acid.
- the isomers are incorporated or embedded in a suitable host material or matrix so that they can be applied to the desired support and are protected against environmental influences (moisture, mechanical stress and the like).
- the invention relates to an article which is provided with the security element according to the invention, wherein the article may be a security or value document or a product such as a drug, a semiconductor device or the like.
- FIGURE schematically shows a security and / or value document with the security element according to the invention, which concerns banknotes, identity cards, other documents, data cards, tickets, adhesive labels, packaging banderols, e.g. in medicines or the like, can act.
- the invention is based on the recognition that numerous rich organic substances or their molecules have multiple isomeric compounds, ie chemical compounds of the same empirical formula, but different chemical structure and sometimes with different physical and biological properties.
- the isomers are composed of the same functional groups, the functional groups being geometrically differently arranged.
- the isomers of a molecule according to the invention have UV, visible and NIR properties.
- Vibration frequencies are different for the different isomers, i. different isomers have different spectra, e.g. Absorption spectra in the THz range. This property is used in the invention.
- the security and / or valuable document 1 shown in the figure has a carrier 2, which consists for example of paper, cardboard, plastic, textiles or mixed forms of these, in the form of films, fabric layers of any kind or the like.
- a carrier 2 On such a carrier 2 is a security element
- the respective bars of the barcode structure of the security element 3 contain a first isomer
- the number of isomers used is not limited to two, it can be selected according to the desired pattern. It is also possible to use several isomers of different molecules. In this case, the isomers are introduced or embedded in a matrix or more as host materials, which are applied to the support, for example, printed on and protect the isomers against undesired influences, while allowing the recognizability of the isomers.
- One possible embodiment of the isomers used for the security element are, for example, the isomers of benzoic acid, namely o-, m- and p-toluic acid, in which a CH 3 group is attached to the base molecule of the benzoic acid at different points on the carbon ring.
- the absorption spectrum with detectable maxima is eg between 0.6 and 1.1 THz.
- a device for generating and coherently detecting terahertz radiation For reading out or checking the barcode of the security element 3, a device for generating and coherently detecting terahertz radiation is used.
- a device usually has a pulsed laser beam source which activates a transmitting antenna for generating terahertz radiation in the sensitive region of the isomers used via a photosensitive element, for example a photodiode.
- a receiving antenna which is likewise provided with a light-sensitive element and can be activated by the laser radiation optionally via delay elements, receives the emitted terahertz radiation which is transmitted through the security element 3 in the transmission or absorption process, the measured variable obtained being for example representing an absorption curve. can be evaluated.
- To generate a continuous terahertz radiation in a frequency range it is also possible to use two laser sources which are detuned with respect to one another.
- the detection of the security element can be carried out with the device described above also in the reflection method.
- other or additional techniques may be used which result in enhancement of THz contrast, e.g., heterodyne techniques or other techniques of frequency enhancement may be provided.
- a plurality of isomeric compounds is suitable for the invention.
- Particularly suitable isomers from the large amount of organic molecules are to be selected those which have the greatest possible contrast, that is to say the largest possible extent in the THz range at frequencies for which the currently existing THz scanners are provided.
- the isomers must be long-term stable and a suitable host material for the isomers must be available.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- Computer Security & Cryptography (AREA)
- Business, Economics & Management (AREA)
- Accounting & Taxation (AREA)
- Finance (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Credit Cards Or The Like (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009009604A DE102009009604B4 (de) | 2009-02-17 | 2009-02-17 | Sicherheitselement mit einer Struktur zur Kennzeichnung und/oder Identifikation von Gegenständen sowie seine Verwendung zur Kennzeichnung und Identifikation eines Gegenstandes |
PCT/EP2010/001048 WO2010094494A1 (de) | 2009-02-17 | 2010-02-15 | Sicherheitselement zur kennzeichnung und/oder identifikation von gegenständen |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2398653A1 true EP2398653A1 (de) | 2011-12-28 |
EP2398653B1 EP2398653B1 (de) | 2016-11-09 |
Family
ID=42046473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10704767.2A Active EP2398653B1 (de) | 2009-02-17 | 2010-02-15 | Sicherheitselement zur kennzeichnung und/oder identifikation von gegenständen |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP2398653B1 (de) |
DE (1) | DE102009009604B4 (de) |
WO (1) | WO2010094494A1 (de) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1261790B (de) * | 1962-05-23 | 1968-02-22 | Dr Hellmut Glubrecht | Verfahren zur Echtheitskennzeichnung von Urkunden |
US20040000787A1 (en) * | 2000-04-24 | 2004-01-01 | Rakesh Vig | Authentication mark for a product or product package |
DE102006017155B4 (de) * | 2006-04-03 | 2008-08-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Identifikationselement |
DE102006017764A1 (de) | 2006-04-12 | 2007-10-18 | Bundesdruckerei Gmbh | Sicherheits- und/oder Wertdokument |
DE102007025891A1 (de) * | 2007-06-01 | 2008-12-11 | Johann Wolfgang Goethe-Universität Frankfurt am Main | Vorrichtung und Verfahren zur Erzeugung und Erfassung kohärenter elektromagnetischer Strahlung im THz-Frequenzbereich |
-
2009
- 2009-02-17 DE DE102009009604A patent/DE102009009604B4/de active Active
-
2010
- 2010-02-15 EP EP10704767.2A patent/EP2398653B1/de active Active
- 2010-02-15 WO PCT/EP2010/001048 patent/WO2010094494A1/de active Application Filing
Non-Patent Citations (1)
Title |
---|
See references of WO2010094494A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE102009009604A1 (de) | 2010-08-19 |
WO2010094494A1 (de) | 2010-08-26 |
WO2010094494A9 (de) | 2010-12-02 |
EP2398653B1 (de) | 2016-11-09 |
DE102009009604B4 (de) | 2011-01-27 |
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