EP2366013B1

EP2366013B1 - Laundry compositions and methods of use

Info

Publication number: EP2366013B1
Application number: EP08878537.3A
Authority: EP
Inventors: Peter Forth; Thomas Merz
Original assignee: Ecolab USA Inc
Current assignee: Ecolab USA Inc
Priority date: 2008-12-04
Filing date: 2008-12-04
Publication date: 2020-05-13
Anticipated expiration: 2028-12-04
Also published as: PL2366013T3; CA2744352A1; EP2366013A1; WO2010064086A1; ES2809176T3; EP2366013A4; CA2744352C

Description

Field of the Invention

The present invention relates in general to fabric color and care compositions, for use prior to or during washing of textiles such as in pre-soak or wash cycles. In particular, the invention relates to color maintenance of the textiles or linens and to inhibition of dye transfer from the wash or pre-soak liquor onto the textiles. Additionally, the invention relates to reducing pilling of textiles. A stand alone composition is provided for such treatment of textiles. However, the composition of the invention may also be incorporated into a laundry pre-treatment or detergent. A method of treating textiles for the purpose of color maintenance and dye transfer inhibition is also provided.

Background of the Invention

State of the art textile-cleaning is stressful to the textiles being cleaned. Frequent washing of the garments in a washing machine followed by subsequent drying in a tumble dryer is associated with severe mechanical stress of the fabric. Forces of friction frequently lead to damage on the textile fabric, as evidenced by pilling. Each washing and drying operation as well as the use of the garments or linens causes further detachment and/or breakage of tiny fibers on the surface of the textile fabric.
In addition to the mechanical stresses of washing, drying, and wearing or using garments and linens, textiles are subjected to chemical stressors as well. The heat and alkalinity associated with the wash cycle of a residential washer may be harsh to the fabric. This harshness is compounded in the wash cycle of a professional or institutional washer where temperatures and alkalinity increase substantially as compared to those found in residential washers. Both the professional or institutional and the residential settings subject the textiles to conditions that promote dye release. Dye or colorant release is problematic for two reasons. First, the original color of the garment is compromised due to release of the colorant. That is, the garment fades. Second, the garment is then also subjected to dye in the wash liquor that can be absorbed by the garment resulting in graying of the original color. A classic example of such color release and transfer is when a red shirt is washed with white socks resulting in a faded red shirt and pink socks. Color release or fading and color transfer are both undesirable and result in unwanted side effects when washing textiles.
Anionic surfactants have a detrimental effect on color stability by removing (excess) dye from fabrics. The detrimental effect varies with the anionic surfactant type.
Laundry detergents are commercially available that ostensibly include "color-guarding" ingredients. It is not known whether or not these "color-guarding" ingredients serve to reduce color release or to inhibit color uptake, or both. Likewise, nonwoven sheets are also commercially available offering "color blocking." In order to use such sheets, a sheet is placed in the wash chamber. It is believed that these nonwoven sheets are effective at inhibiting color transfer to the garments from the wash liquor because the sheets have a large surface area with a higher affinity for the colorants than the garments thereby absorbing the dye from the wash liquor before the garments are affected. However, it is doubtful that such sheets are actually effective at reducing color release from the textiles. In the case of the nonwoven sheets, the sheeting must be retrieved from the laundry load and discarded. This adds another step and the possibility that the grayed nonwoven sheet will be mixed into the dryer and end up in a guest's bed at a hotel, mixed in with towels at a hospital or gym, or folded in with laundered clothes. In the institutional setting, all are unprofessional and undesirable. In the best case scenario, the nonwoven sheet is discarded into the trash ending up in a landfill. This is not ideal as the population strives to endorse and use environmentally friendly products.
US 2003/150064 A1 describes a textile-care composition that advantageously combines colour preservation with care of fibres and especially greying-inhibiting action was to be developed. That was achieved by means of a composition for textile care, comprising at least one cellulase and at least one colour-fixing polymer containing imidazolidine units.
WO 98/29529 A1 describes a detergent composition and method which utilize certain dye fixatives as fabric treatment agents that can impart fabric appearance benefits to fabrics and textiles laundered in washing solutions which contain such agents. Such dye fixatives are those which do not precipitate with anionic surfactants present in the detergent compositions and which do not therefore adversely affect the cleaning performance of such detergent products.
WO 97/28242 A1 describes a laundry additive composition and a method for its use are provided. The compositions include a dispersible polyolefin, preferably polyethylene, and at least one compound selected from the group consisting of dye fixative agents, chelating agents, dye transfer inhibiting agents, chlorine scavenging agents, free radical scavenging agents, cellulase enzymes and mixtures thereof.
WO 96/27649 A1 describes a laundry composition for use in the rinse cycle of laundry washing processes, and which improve colour-depth maintenance over single or multiple washing cycles. The laundry composition contains a cellulase enzyme and a cationic dye-fixing agent.
A need exists for a composition for treating textiles that may be provided as a stand alone composition that is useful regardless of the detergent or softener choice. Such a composition will be effective in reducing pilling, reducing dye or colorant release from textiles (in other words, enhancing color maintenance) and inhibiting dye or colorant uptake or transfer.

Summary of the Invention

The present invention provides a liquid, physically, microbiologically and chemically stable composition according to claim 1 with clearly visible customer benefit on colored and white textiles by color fixation, dye transfer inhibition and de-pilling of textiles. The benefit of using such composition is prolonged textile lifetime. In contradiction to prior art, compositions of the invention have a wide area of application. That is, compositions of the invention are relatively insensitive to the wash or presoak liquor pH, insensitive to water temperatures, wash process and chemical environment including surfactants and builders used during the wash cycle.
The composition of the present invention comprises

a) from 0.05 to 5.0 weight percent of a color fixation polymer comprised of at least one polydiallyl dialkyl ammonium compound,
b) from 0.01 to 2.0 weight percent of cellulase,
c) an enzyme stabilizing component comprised of from 5 to 40 weight percent of propylene glycol and from 10 to 50 weight percent of polyol comprising sorbitol,
d) an effective amount of buffer capable of maintaining the laundry composition at a pH below 12,

A laundry composition is disclosed comprising a color fixation polymer in an effective amount to maintain color in a washable textile, enzyme in an effective amount to remove pilling, and/or to aid in cleaning, and/or to prevent graying of the textile, an effective amount of an enzyme stabilizing component comprised of a polyol, and an effective amount of buffer capable of maintaining the composition at a pH to minimize enzyme denaturing. In an embodiment the composition of the invention comprises a pH below about eight. The laundry composition of the invention may further comprise water.
Alternatively, the composition of the invention may be provided as a concentrate and the end user may dilute the concentrate composition with water thereby creating a use concentrate on site.
In embodiments of the invention, the composition comprises less than 5 weight % anionic surfactant, less than 4 weight percent, or less than 3 weight percent anionic surfactant. The buffer may be comprised of trisodium citrate dihydrate, the color fixation polymer may be comprised of at least one polydiallyl dialkyl ammonium compound. In an embodiment the polydiallyl dialkyl ammonium compound is comprised of a chloride compound, in particular, polydiallyl dimethylammonium chloride and is effective in inhibiting color transfer.
The laundry composition of the invention comprises antimicrobial phenoxyethanol.
In addition to controlling the pH for enzyme stability, the enzyme stabilizing component is comprised of sorbitol and propylene glycol. The enzyme of the composition is comprised of cellulase.
A laundry composition for inhibiting dye transfer and maintaining color is taught comprising at least one polydiallyl dialkyl ammonium compound, cellulase, polyol comprising sorbitol, propylene glycol, an antimicrobial agent comprised of phenoxyethanol, and buffer for maintaining the composition at a pH suitable for enyzymatic stability.
The present invention also provides a method of treating washable textiles. Such method comprises the steps of placing the textiles having an initial color into a wash liquor; adding the composition of the invention to the wash liquor; and rinsing the textiles with water wherein the textiles substantially maintain their initial color and/or the textiles resist dye transfer from the wash liquor.

Detailed Description of the Invention

Definitions

For the following defined terms, these definitions shall be applied, unless a different definition is given in the claims or elsewhere in this specification.
Weight percent, percent by weight, % by weight, are synonyms that refer to the concentration of a substance as the weight of that substance divided by the weight of the composition and multiplied by 100.
The recitation of numerical ranges by endpoints includes all numbers subsumed within that range (e.g. 1 to 5 includes 1, 1.5, 2, 2.75, 3, 3.80, 4, and 5).
As used in this specification and the appended claims, the singular forms "a", "an", and "the" include plural referents unless the content clearly dictates otherwise. Thus, for example, reference to a composition containing "a compound" includes a mixture of two or more compounds. As used in this specification and the appended claims, the term "or" is generally employed in its sense including "and/or" unless the content clearly dictates otherwise.
The term "alkyl" refers to a straight or branched chain monovalent hydrocarbon radical having a specified number of carbon atoms. Alkyl groups may be unsubstituted or substituted with substituents that do not interfere with the specified function of the composition and may be substituted once or twice with the same or different group. Substituents may include alkoxy, hydroxy, mercapto, amino, alkyl substituted amino, nitro, carboxy, carbanoyl, carbanoyloxy, cyano, methylsulfonylamino, or halo, for example. Examples of "alkyl" include, but are not limited to, methyl, ethyl, n-propyl, isopropyl, n-butyl, s-butyl, t-butyl, n-pentyl, n-hexyl, 3-methylpentyl.
As used herein the term "polyol" refers to any organic molecule having more than one hydroxy group.
The term "surfactant" or "surface active agent" refers to an organic chemical that when added to a liquid changes the properties of that liquid at a surface.
The term "colorant" or "dye" or "pigment" are used interchangeably herein and refer to any textile-altering composition that alters the color of a textile.
Unless otherwise stated, all weight percentages provided herein reflect the weight percentage of the raw material as provided from the manufacturer. The active weight percent of each component is easily determined from the provided information by use of product data sheets as provided from the manufacturer.
Colored natural fibers, especially when of low quality, release redundant dyes not fixed to the fiber into a wash or presoak solution. Natural fibers derived from plants include those that are generally comprised of cellulose. Examples of plant derived cellulosic fibers include cotton, jute, flax, ramie, sisal, and hemp. Natural fibers derived from animals generally comprise proteins. Examples of protein derived fibers include silk, wool, angora, mohair and alpaca. Most if not all of these natural fibers suffer from color loss or fading. This color loss leads to a less favorable fabric appearance and dye transfer to other textiles. Such color transfer is most apparent on white textiles. The addition of a color fixation agent stops color loss and transfer.

Color Fixation Polymer

It has now surprisingly been found that colorants such as dyes or pigments can be stabilized without the use of anionic surfactants. In fact, the present invention is effective in the substantial absence of anionic surfactants. It has surprisingly been found that color stabilizing polymers can be used to inhibit deposition of colorants in pretreatment or wash liquor and also to maintain colorant in the textile fibers. Compositions of the invention are formulated with at least one color fixation polymer.
In the invention the color fixation polymer is comprised of a polydiallyl dialkyl ammonium compound, preferably a chloride. Polydiallyl dimethylammonium chloride is particularly preferred in one embodiment. Polydiallyl dimethylammonium chloride is commercially available from Sigma-Aldrich or Cognis. The color fixation polymer is included in compositions of the invention in an amount from 0.05 to 5.0 weight percent, from 0.10 to 3 weight percent, and from 0.50 up to 2.5 weight percent. The invention anticipates that other color-fixing polymers may be included as a combination of polymers, or a single color fixation polymer may be employed in compositions of the invention.

Enzyme

Washing natural textiles in washing machines lead to small, ball-shaped aggregates of loose fibers called pills. The addition of a special enzyme prevents the formation of these pills. Cellulases can contribute towards color retention and towards increasing fabric softness by removing pilling and microfibrils. Cellulases such as commercially available as Carezyme® from Novozymes are useful in the present invention. As stated, the presence of cellulases serves to prevent pilling of fabrics during the washing process. During these processes, abrasion and fiber damage result in formation of loose fibers or "fuzz" that can become entangled and form "pills." Cellulase enzymes also act to remove existing pilling formed during wear so as to restore the original fabric appearance during subsequent wash or other treatment cycles. Thus, fabrics with pills and fuzz often exhibit a worn appearance. Furthermore, given the propensity of damaged fibers to suffer further dye and pigment loss during both laundering and wear which exposes the un-dyed fiber core, this results in a faded appearance. Cellulase is included in compositions of the invention in an amount from 0.01 to 2.0 weight percent, optionally from 0.05 to 1.5 weight percent, or from 0.1 up to 1.0 weight percent.
An example of a suitable enzyme is sold under the trade name Carezyme® cellulase enzyme product. Carezyme® is a cellulase produced by submerged fermentation of a genetically modified Aspergillus microorganism. Carezyme® removes the microfibrils, caused by wear and washing, which protrude from a fiber. The activity of Carezyme® depends on the conditions in which the enzyme is exposed (pH, temperature, other ingredients in the product). Carezyme® can be obtained with a cellulytic activity of 4500 ecu/gram or higher. Other cellulase preparations will be known to those skilled in the art and their use as described herein will be included within the scope of the present invention.
Since enzymes are proteins, care must be taken when formulating compositions including such proteins to ensure that the proteins are not denatured during formulation, storage, or handling. The denaturation of proteins such as enzymes can be caused by high temperatures, chemical interaction or pH. When incorporating a relatively expensive ingredient such as an enzyme into a composition, it is desirable to retain its activity. Therefore, once the enzymatic agent is added to the composition of the invention, the composition is preferably not heated to a temperature that will cause the proteins that comprise the enzyme to denature. Denaturants include but are not limited to certain acids such as acetic acid, trichloroacetic acid, and sulfosalicylic acid. Other denaturants include most organic solvents such as ethanol, methanol, and acetone. Denaturants are preferably avoided and are not included in compositions of the invention. Or, if they are included another ingredient is added to the composition either to neutralize the denaturant or to protect the enzyme.
As one may appreciate, if the pH of the composition of the invention becomes too alkaline or acidic, the proteins that comprise the enzymes will denature. As such, it is desirable to maintain the pH of the composition at around neutral. Compositions of the invention may have a pH between 6 and 8. Of importance is the pH of the invention composition because storage at a high or low pH would inactivate any enzymes incorporated into the formulation. Less important is the pH of the wash liquor when using compositions of the invention. The pH of the wash liquor when using the composition of the invention is preferably below pH 12, below pH 11, or below pH 10. Above pH 12, cellulases such as those incorporated into compositions of the invention lose their activity. While the skilled artisan will recognize that compositions of the invention will still be effective at color maintenance without the enzymatic activity, it is desirable to retain this de-pilling capability of the invention.

Buffer

As previously discussed, it is desirable to maintain the pH of compositions of the invention at a pH below 12. Any buffering agent known in the art is useful for this purpose. Sodium citrates are useful in buffering compositions of the invention to ensure the pH of the composition does not become too highly alkaline thus denaturing the cellulasic enzyme. Preferably trisodium citrate dihydrate is included in compositions of the invention in an amount from 0.01 weight percent up to 0.3 weight percent, from 0.05 to 0.2 weight percent, from 0.08 to 0.18 weight percent.

Enzyme Stabilizers

In addition to stabilizing the enzymes of the composition by controlling the pH thereby limiting denaturation due to high alkalinity of acidity, the compositions also include enzyme stabilizers. The enzyme stabilizers act to protect the stability and thereby protect the activity of the enzymes. In the invention polyol comprising sorbitol is included in an amount from 10 to 50 weight percent, from 20 to 40 weight percent, from 25 to 35 weight percent.
Another enzyme stabilizing ingredient included in the compositions of the invention include propylene glycol. Propylene glycol is included in compositions of the invention in an amount from 5 to 40 weight percent, optionally from 10 to 30 weight percent, or from 15 to 25 weight percent. Without being bound by theory, it is believed that the polyol in combination with the propylene glycol of the invention serve to stabilize the enzyme.

Antimicrobial Agent

Compositions of the invention include an antimicrobial agent to limit or completely prohibit the growth of microbes when the composition is stored for extended periods of time. Due to the relatively gentle pH of the composition and the inclusion of water in diluted compositions of the invention, microbial growth may flourish and is of concern. Another concern when formulating compositions of the invention is to ensure that the antimicrobial agent does not compromise enzymatic activity. Surprisingly it was found that the preservative, phenoxyethanol, did not compromise enzyme stability in compositions of the invention. Phenoxyethanol is included in compositions of the invention in amount from 0.1 to 10 weight percent, from 0.2 to 7 weight percent, and from 0.5 to 5 weight percent.
Examples of other additional antimicrobial agents useful in compositions of the invention include but are not limited to those selected from parahydroxy benzoic acid and salts thereof, (C1-C4) alkyl parahydroxy benzoates, sorbic acid add and salts thereof, ortho hydroxybenzoic acid and salts thereof, benzoic acid and salts thereof, (C1-C4) alkyl benzoates, propionic acid and salts thereof, dehydroacetic acid and salts thereof, formic acid and salts thereof, and undec-10-enoic acid and salts thereof. Yet other examples of antimicrobial agents useful in compositions of the invention include but are not limited to preservatives selected from formaldehyde, paraformaldehyde, biphenyl-2-ol (ortho phenylphenol), 4,4-dimethyloxazolidine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitropropane-1,3-diol, 2,4-dichlorobenzyl alcohol, 5-chloro-2-(2,4-dichlorophenoxy)-phenol, 4-chloro-3,5-xylenol, 3,3'-bis-(1-hydroxymethyl-2,5-dioxoimidazolidinyl-4-yl)-1,1'-methylenedlu- rea (imidazolidinyl urea), poly(1-hexamethylene biguanidine hydrochloride), 2-phenoxyethanol, hexamethylenetetramine, benzyl alcohol, 1,3-bis-(hydroxymethyl)-5,5-dimethylimidazolidone-2,4-dione, 5-chloro-2-methylisothiazol-3(2H)-one, 2-methyl-isothiazol-3(2H)-one, benzisothiazolinone, 2-benzyl-4 chlorophenol, chlorhexidine and its digluconate, diacetate, and dihydrochloride salts, 1-phenoxy-propan-2-ol, cetyl pyridinium bromide and chloride, N-(hydroxymethyl-N-dihydroxymethyl-1,3-dioxo-2,5-imidazolinidyl-4)-N'-hydroxymethyl urea, sodium hydroxymethylglycinate, benzethonium chloride, benzalkonium chloride, bromide and saccharinate, 3-iodopropynylbutylcarbamate, benzisothiazolinone, triacetin, diazolidinyl urea, and cis-1-3-chloroallyl-3,5,7-triaza-1-azoniaadamantane chloride to name a few.

Water

Water is optionally included in compositions of the invention. Compositions of the invention are provided either as an undiluted concentrate or are as a somewhat diluted composition or may be diluted to a use composition. Compositions according to the invention may be provided in heavily diluted form and, in that case, contain up to 95% by weight water. However, they preferably contain less water, for example from 0 to 80% by weight, from 20 to 70% by weight, and from 30 to 60% by weight water.
It should be understood that the water provided as part of the concentrate can be relatively free of hardness. It is expected that the water can be deionized to remove a portion of the dissolved solids. The concentrate is then diluted with water available at the locale or site of dilution and that water may contain varying levels of hardness depending upon the locale. Although deionized is preferred for formulating the concentrate, the concentrate can be formulated with water that has not been deionized. That is, the concentrate can be formulated with water that includes dissolved solids, and can be formulated with water that can be characterized as hard water.
The water of dilution that can be used to dilute the concentrate can be characterized as hard water when it includes at least 1 grain hardness. It is expected that the water of dilution can include at least 5 grains hardness, at least 10 grains hardness, or at least 20 grains hardness.
It is expected that the concentrate will be diluted with the water of dilution in order to provide a use solution having a desired level of textile care properties. It is expected that the weight ratio of concentrate to water of dilution will be between 1:1 and 1:500, between 1:2 and 1:450, between 1:3 and 1:400, and between 1:5 and 1:350.
The compositions of the invention may further include defoamer, antiredeposition agent.

Delivery

The preferred embodiment is a liquid, liquid gel or gelled composition for color and fabric care.

Formulating Compositions of the Invention

Compositions of the invention may be prepared in continuous or batch processes. In one embodiment, the color fixation polymer is added to deionized water. Sorbitol and propylene glycol are combined and then added to the DI water/polymer blend. The combination is mixed to homogeneity. The buffer and antimicrobial agents are added before finally adding the enzyme.

Substantially Free of Anionic Surfactants

Compositions of the invention may be substantially free of anionic surfactants. Anionic surfactants are not necessary for efficacy of the invention and may even work in opposition to the goals of the invention. Anionic surfactants are preferably avoided in compositions of the invention but if they are included they are included in an amount less then 2 weight percent, less than 3 weight percent, less than 4 weight percent, and less than 5 weight percent. The anionic surfactants to avoid may include a negatively charged water solubilizing group. Examples of anionic surfactants which are preferably not incorporated into the formulations of the present invention may include the ammonium, substituted ammonium (e.g., mono-di-, and triethanolammonium), alkali metal and alkaline earth metal salts of C₆-C₂₀ fatty acids and rosin acids, linear and branched alkyl benzene sulfonates, alkyl sulfates, alkyl ether sulfates, alkane sulfonates, alpha olefin sulfonates, hydroxyalkane sulfonates, fatty acid monoglyceride sulfates, alkyl glyceryl ether sulfates, acyl sarcosinates and acyl N-methyltaurides.

Methods of Using Compositions of the Invention

The invention comprises color care compositions and methods of use to provide protection to textiles from fading and appearance change, in addition to fiber and color maintenance during consumer and industrial treatment of clothing and textiles. The compositions have several key performance actives that target common dye fading and textile damaging mechanisms experienced during the wash and dry processes, and during wear and exposure to the elements. Compositions of the invention may be useful in a presoak, prewash, or wash cycle of laundry. In general, it is desirable to incorporate compositions of the invention into the prewash or if there is no prewash at the beginning of the mainwash. Likewise, it is desirable to incorporate compositions of the invention into any cycle where preventing color uptake (such as graying) is important to avoid. In general, it is desirable to dose compositions of the invention when the textiles are first exposed to detergent and water thereby limiting the adverse effects of detergent and water on the color and texture of the textiles. Compositions of the invention are particularly useful when washing colored textiles. However, compositions of the invention also demonstrate desirable effects on white textiles as well with their reduction of pilling.
In an embodiment, the present invention is useful as a color and care composition for pre-soaking or pre-treating fabrics. In this first embodiment, the method of the present invention includes adding a predetermined volume or amount of the composition of the present invention to water or other cleaning solution. This pre-soak or pre-treatment is especially important for setting or fixing dyes. The methods of use provide for introduction of selected compositions in a hand-soak or machine pre-soak situation.
In another embodiment of the method of use of the present invention, the composition is added to a washing cycle, along with a laundry or fabric detergent composition or solution. In the main wash cycle, the present invention can be used either alone or in combination with a regular detergent or laundry additive such as a fabric softener.
In another embodiment, the present invention is a rinse additive, introduced either alone or in combination with a fabric softener. In addition, further compositions and methods of use of the present invention employ a dispensing device which provides for repeated and automatic dispensing of an effective dose of this composition through each machine cycle.
The compositions of the present invention can be prepared by a number of methods. Some convenient and satisfactory methods are disclosed in the following examples. The present invention can be better understood with reference to the following examples. These examples are intended to be representative of specific embodiments of the invention, and are not intended as limiting the scope of the invention.

Examples

For the following examples, a composition according to the invention was prepared according to the formulation provided in Table 1 below.

Table 1

Ingredient	Weight percent
Poly dimethyl diallyl¹ ammoniumchloride	1.79
Deionized Water	47.05
Sorbitol Solution²	28.57
Monopropylene Glycol³	20.0
Sodium Citrate Dihydrate, Granular⁴	0.14
2-Phenoxyethanol⁵	2.0
Cellulase-Enzyme (Proteinenzyme)⁶	0.45
	100.00

¹POLYQUARDT FDI available from Cognis at a 40% solution
²Neosorb 70/70 available from Roquette or Mritol 160 available from Amylum at a >50% concentration of sorbitol
³Available from Dow
⁴Available from Jungbunzlauer
⁵Available from Transol
⁶Carezyme 4500 L available from Novozymes

Example 1

The composition prepared according to Table 1 above was used to compare color maintenance of textiles. The Initial L values of duplicate colored textiles were taken before washing the textiles using a Hunter Lab instrument. A Hunter Lab Colorquest XE spectrophotometer was used with standardization settings as follows: Mode = RSIN, Viewing Area = Large, Port Size = 2.54 cm (1.00"), and UV Filter = 420nm. Hunter Lab measuring settings include: Selection: CIELAB, Illuminant: D65, and Observer: 10 degree. One set of the textiles was washed using a wash cycle as follows:
Fifteen g/l of Triplex Energy Gran and 2ml/l of Triplex Energy Plus (both available from Ecolab, Inc located in St. Paul, MN USA) were added to the wash bath. The textiles were washed for 4 minutes in a cold wash that was tap water temperature. The cold wash was followed by a 15 minute wash at 55°C. A secondbath was run for 10 minutes at 75 degrees C to which additional dosage of 10g/l of Triplex Energy Gran and 3ml/l of Turbo Break along with 5 of ml/1 Ozonit Super (also from Ecolab) was added.

The second set of textiles was washed using the same conditions except that 8ml/l of the composition of the invention prepared according to Table 1 above was added to the wash liquor. After the wash and dry cycles were complete, readings (L, a, b) were taken for each towel on the Hunter Lab Instrument. The dataset provided in Table 2 below shows the difference in color maintenance observed with and without the composition of the invention on colored textiles. Data is expressed in numbers on the Hunter Lab-scale:

Table 2

Color Maintenance	L	a	b	Color Distance
Initial Color (Unwashed)	39.8	58.4	28.6	-
Washed without Composition of Invention	43.4	59	27.2	3.96
Washed with Composition of the Invention	38.3	56.78	27.3	2.55

The data in Example 1 /Table 2 demonstrates that using compositions of the invention results in better color maintenance than when the same textiles are washed in the absence of compositions of the invention. A smaller color distance is indicative of better color maintenance as compared to the original textile. The less fade value, the better the result.

Example 2

This Example demonstrates the difference in dye transfer inhibition observed when washing white textiles with and without a composition of the invention. As in Example 1, the Initial L values of duplicate white textiles were taken before washing the textiles using a Hunter Lab instrument. All settings were identical to those provided in Example 1 except if listed. The duplicate white towels were washed in the same conditions as provided in Example 1 above, with and without inclusion of the composition of the invention. After the wash and dry cycles were complete, final readings (L, a, b) were taken for each textile on the Hunter Lab Instrument. The difference between the L initial and the L final is provided as the Color Distance in the table below.

Table 3

Reduction of dye transfer	L	a	b	Color Distance
Initial (Unwashed)	88.5	1.2	2.2	-
Washed without Composition of the Invention	81.2	8.7	3.6	10.52
Washed with Composition of the Invention	88.1	3.4	1.7	2.27

The data in Example 2/Table 3 demonstrates that using compositions of the invention results in reduction of dye transfer than when the same textiles are washed in the absence of compositions of the invention.

Example 3

This Example 3 supports data provided in Example 1 above except that the composition of the invention was included in both the prewash and the wash cycle. The Initial L values of duplicate colored textiles were taken before washing the textiles using a Hunter Lab instrument. The Initial L values were noted but are not provided herein. Duplicates of the new colored textiles were washed in horizontal drum washing extractors in a standard process using an Electrolux Wascator FLE 120 MP washer and employing a 15 minute pre-wash at 55°C. Ten grams granular Basis detergent available from Ecolab, Inc. was used in the pre-wash cycle for both sets of textiles per kg textile at water to textile ratio of 1:4. One set of colored textiles included 2 ml of the composition of the invention per kg textile prepared according to Table 1 above and the other did not include the composition of the invention. A 10 minute main wash at 75°C with a dosage of 10 grams per kg textile Basis granular detergent available from Ecolab was then undertaken. In the set of textiles that included the composition of the invention in the prewash, 2 ml per kg textile of the composition from Table 1 was again included. The other washer again lacked the composition of the invention. Both wash cycles also included 3 ml per kg textile of an alkali booster available as Turbo Break from Ecolab, Inc. located in St. Paul, MN
Following completion of the wash and a dry cycles, the L values of the colored textiles was again taken. This difference between the Initial L value and the final L value is provided in Table 4 below as ΔE. Table 4

Average Color Distance [AE]

Process without addition of invention composition 16.5

Process with addition of invention composition 2.67

The data provided in Example 3/Table 4 illustrates a higher degree of color maintenance when the composition of the invention was employed in the prewash and wash cycles as compared to when it was omitted. A smaller delta value shows less color change or greater color maintenance.

Example 4

Example 4 shows the efficacy of adding an antimicrobial agent to compositions of the invention in prohibiting microbial growth. Compositions A and B were prepared according to the following formulations provided in Table 5. Composition A included the antimicrobial agent 2-phenoxyethanol while Composition B (comparative) lacked any
antimicrobial agent.

Table 5

	Composition A	Composition B
Ingredient	Weight percent	Weight percent
Poly dimethyl diallyl¹ ammoniumchloride	1.79	1.79
Deionized Water	47.05	49.05
Sorbitol Solution²	28.57	28.57
Monopropylene Glycol³	20.0	20.0
Sodium Citrate Dihydrate, Granular⁴	0.14	0.14
2-Phenoxyethanol⁵	2.0	0.0
Cellulase-Enzyme (Proteinenzyme)⁶	0.45	0.45
	100.00	100.00

The microbiological susceptibility of the formulations of Composition A and comparative Composition B were tested according to AA CCM 4.2-051 for all purposes by adding 1% of a solution containing 3x10^-8 bacteria and 3x10^-7 fungi to a sample of each Composition A and B. The inoculated compositions were stored at 40°C for 21 days. After 21 days a sample was taken from each inoculated composition to determine bacterial and fungal load. The samples were returned to 40°C and stored for a total of 6 weeks after which another sample was taken to determine bacterial and fungal load. The data provided below in Table 6 demonstrates that the formulation without phenoxyethanol (comparative Composition B) is not microbiologically stable while the addition of 2% phenoxyethanol (Composition A) delivers sufficient microbiological stability.

Table 6

		Bacteria CFU*	Fungi CFU	Microbiological conservation
Composition B (without phenoxyethanol)	Fresh	7	21	Sufficient
Composition B (without phenoxyethanol)	21 days storage at 40°C	7	>1000	Insufficient
Composition A (with phenoxyethanol)	Fresh	7	14	Sufficient
Composition A (with phenoxyethanol)	6w storage at 40°C	7	7	Sufficient

Colony forming units

Example 5

This Example 5 illustrates the stability of the enzyme in compositions of the invention with and without antimicrobial agent. Compositions A and B were prepared according to Table 5 above. Compositions A and comparative Composition B were initially tested for enzymatic
activity (shown as "Fresh" in table 7 below). The Compositions were then stored at 35°C for 4 weeks after which they were again checked for enzymatic activity. The enzyme content was checked by an outside contractor (Henkel Analytical Services) according to a standard addition protocol known as "Prüfverfahren VTA 31-X-01002.01". The skilled artisan will know means to check enzyme activity by other suitable methods.

The data shown in Table 7 below shows the chemical stability of the compositions as shown by enzymatic activity of Carezyme® cellulase:

Table 7

	storage condition	Residual enzyme activity
Color Care booster without Phenoxyethanol	Fresh	100%
Color Care booster without Phenoxyethanol	4 weeks @ 35°C	86%
Color Care booster with Phenoxyethanol	Fresh	100%
	4 weeks @ 35°C	>95%

An enzyme activity above 80% after 4 weeks storage at 35°C corresponds to one year shelf stability under ambient conditions.

Claims

A liquid laundry composition, comprising:
a) from 0.05 to 5.0 weight percent of a color fixation polymer comprised of at least one polydiallyl dialkyl ammonium compound,

b) from 0.01 to 2.0 weight percent of cellulase,

c) an enzyme stabilizing component comprised of from 5 to 40 weight percent of propylene glycol and from 10 to 50 weight percent of polyol comprising sorbitol,

d) an effective amount of buffer capable of maintaining the laundry composition at a pH below 12,
further comprising from 0.1 to 10 weight percent of an antimicrobial agent comprised of phenoxyethanol.
The laundry composition of claim 1, wherein the composition comprises less than about 5 weight % anionic surfactant.
The laundry composition of claim 1, wherein the buffer is comprised of trisodium citrate dihydrate.
The laundry composition of claim 1, wherein the at least one polydiallyl dialkyl ammonium compound is comprised of polydiallyl dimethylammonium chloride.
The laundry composition of claim 1, wherein the buffer is effective at maintaining the pH below about 8.
The laundry composition of claim 1, further comprising water.
A method of treating washable textiles comprising the steps of:
a) placing the textiles having an initial color into a wash liquor;

b) adding to the wash liquor a liquid treating laundry composition according to anyone of claims 1 to 6 and

c) rinsing the textiles with water wherein the textiles substantially maintain their initial color and/or the textiles resist dye transfer from the wash liquor.