EP2291314A1 - Sealing stopper for manual removal and reinsertion - Google Patents
Sealing stopper for manual removal and reinsertionInfo
- Publication number
- EP2291314A1 EP2291314A1 EP09755108A EP09755108A EP2291314A1 EP 2291314 A1 EP2291314 A1 EP 2291314A1 EP 09755108 A EP09755108 A EP 09755108A EP 09755108 A EP09755108 A EP 09755108A EP 2291314 A1 EP2291314 A1 EP 2291314A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stoppers
- stopper
- diameter
- head
- cork
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D39/00—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers
- B65D39/0005—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers made in one piece
- B65D39/0011—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers made in one piece from natural or synthetic cork, e.g. for wine bottles or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D39/00—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers
- B65D39/0052—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers made in more than one piece
- B65D39/0058—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers made in more than one piece from natural or synthetic cork, e.g. for wine bottles or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D39/00—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers
- B65D39/16—Closures arranged within necks or pouring openings or in discharge apertures, e.g. stoppers with handles or other special means facilitating manual actuation
Definitions
- the present invention relates to stoppers, for beverage containers, which are able to be manually removed and reinserted without the help of cork-screw devices and that assure the sealing of the container when inserted for the first time, and the plugging of the container in subsequent insertions.
- Cork stoppers are used from the XVIII Century to plug and/or seal wine containers and are spread in the market. Generally, there were no alternatives to cork stoppers until the emergence of sealing stoppers made from plastic material, in the middle of the nineties of the XX Century.
- the purpose of sealing a container is to avoid that drink leaks through the neck of the container and at the same time to avoid premature changes on the wine quality, which changes are usually imputed to the oxidation.
- the purpose of plugging a container is only to avoid that drink leaks through the neck of the container.
- a stopper When a stopper is used to seal, usually the container is stored in a laid down position, preventing the wine leaks and allowing a slow evolving of the wine only with the amount of oxygen which is given to it by means of the stopper itself.
- the container When a stopper is used to plug only, the container is stored upright and the liquid must have enough protection to avoid the oxidation over time or otherwise it is intended that the same become oxidised (for example, Porto Wine and Madeira wine).
- cork stoppers are usually used having lengths of about 38 to 54 mm and a diameter which is usually of 24 mm but which can vary according to the inner diameter of the neck. There must have a difference between the stopper diameter and the neck diameter of about 5.5 to 7.5 mm, in order to assure the sealing. These stoppers are inserted into the neck by compression up to about 15.5 mm and then inserted by a piston device, one of the stopper ends remaining at the same level as the upper end of the neck. These stoppers are never rounded at one end thereof, but they may have a chamfer of about 2 to 4 mm.
- the stoppers for sparkling wines are included in this group of stoppers which are used to seal a container.
- these stoppers may also being manually removed. This manual removal is possible because there is an internal pressure, outwardly exerted by gas released by the liquid, which helps the manual removal action.
- these stopper dimensions it is nearly impossible reusing them manually due to the recovered dimensions that they get after said manual removal action.
- these sparkling wine stoppers have lengths of about 48 mm and diameters of about 30.5 to 31 mm.
- stoppers which have lengths of about 27 to 29 mm, rounded at its lower end along about 2 cm of the length thereof, and with a diameter of about 19.5 to 20 mm, but which may vary according to the neck inner diameter, are usually used. The difference between the stopper diameter and the neck inner diameter is never above 2 mm, often being 1.5 mm.
- the stoppers which are used to plug have crowns from various materials such as plastic, glass, wood and cork. To bottle these stoppers no compression is required, whereby the bottling is achieved by means of a mechanical or manual force in the longitudinal direction, from outside to inside of the container, which force will insert the stopper into the neck of the container up to the crown. The crown rests outside the container in order to provide a later removal easier without the use of any cork screw device.
- the sealing stoppers from plastic material have tried to mimic the cork stoppers, either with relation to its general form, namely the dimensions and physical look thereof, or with relation to its sealing efficiency. Like for current cork stoppers, it is necessary a cork screw device to remove these plastic material stoppers from the neck of respective containers. For a very short rest period within the container, a wine is able to deal with the amount of oxygen entering the container due to a poor sealing provided by the plastic material stoppers, however, for longer rest periods of the wine within the container, some signs of premature oxidation arise, which significantly modify the organoleptic characteristics of wine.
- stopper s/sealings to plug and/or sealing containers of wine, and/or similar beverages, are the threaded capsules made from aluminium which are frequently used with other beverage than wine. These stoppers/sealings started to secure the wine market mainly due to a strong commercial attitude coming from Australia and New Zealand, where a significantly amount of bottled wine is sealed with this type of stoppers/sealings.
- the advantage of the threaded capsules resides in the manner they may be removed, since as a cork screw device is not needed they may be easily removed, which is very convenient especially in the catering sector.
- off-flavour related drawbacks arise due to reduction reactions in the wine by virtue of a complete absence of oxygen admission.
- the present invention relates to a cork stopper comprising an upper member or head and a lower member or body, for using with wine and/or beverages containers which comprises the advantages of:
- the cork stopper comprising an upper member or head and a lower member or body is characterized by:
- said head having an height of at least about 8 mm; said body being cylindrical and having a diameter of about 21 to 26 mm and a length of about 10 to 30 mm.
- the cork stopper of the present invention is characterized by said head having a diameter larger than the diameter of the body by at least about 3 mm, and by the shape of said stopper head being cylindrical, cubical, parallelepipedic, conical and the like.
- Said cork stopper of the invention can be made from natural cork, clogged natural cork, agglomerated cork and combination thereof, said head and/or said body may comprise at least one disk from natural cork.
- Said disk is a well known member for the skilled in the art, which disk can be bonded to any of the stopper ends.
- the cork stopper of the invention may have also, at least in one of its stopper ends, one chamfer of about 2 to 4 mm.
- said cork stopper head of the invention must have a diameter of 30 mm and a height of 20 mm and said body having a diameter of 23 mm and length of 25 mm.
- said head must have a diameter of 30 mm and height of 20 mm, said body having a diameter of 23 mm and length of 27 mm, the lower end of the body being chamfered with one chamfer of 2 mm.
- said head must have a diameter of 30 mm and a height of 15 mm, said body having a diameter of 24 mm and length of 27 mm, the lower end of the body being chamfered with one chamfer of 4 mm.
- said head must have a diameter of 30 mm and height of 20 mm, the head comprising one natural cork disk of 15 mm height, said body having a diameter of 23 mm and length of 25 mm, the lower end of the body being chamfered with one chamfer of 4 mm. Still in another preferred embodiment, said head must have a diameter of 30 mm and height of 20 mm, the head comprising one natural cork disk of 15 mm height, said body having a diameter of 21 mm and a length of 25 mm, the lower end of the body being chamfered with one chamfer of 4 mm.
- the stopper of the present invention is suitable to plug containers which have beverage selected from the group comprising wine, beer, spirit drinks, water, refrigerants and the like.
- Fig. 1 is a schematic side view of a prior art stopper
- Fig. 2A is a schematic side view of a first embodiment of the SSR stopper of the present invention.
- Fig. 2B is a schematic side view of second and third embodiments of the SSR stopper of the present invention.
- Fig. 3 is a schematic side view of a fourth embodiment of the SSR stopper of the present invention.
- Fig. 4 is a graphic which shows the absorption in bottle as a function of time from a sealing ability test
- Fig. 5 is a graphic which shows the free SCh content as a function of time from a sealing ability test
- Fig. 6 is a graphic which shows the total SCh content as a function of time for different stoppers used in a sealing ability test.
- the present invention relates to a novel cork stopper comprising an upper member (1) or head and a lower member (2) or body, for use with wine and/or beverage containers.
- cork stopper relates to stoppers made from natural cork, clogged natural cork, agglomerated cork and combination thereof.
- agglomerated cork stopper relates to an agglomerated cork stopper comprising at least 51 % (by weight) of granulated cork having a minimum grain size of 0,5 mm, a maximum specific weight of 60 Kg/m 3 and a water content equal or less than 8%.
- the term “manual” relates to any action performed by a user without using any automated, mechanical, electrical, electronic devices or the like.
- rounded stopper relates to a stopper which edge, of any of its ends, is rounded by friction.
- chamfered stopper relates to a stopper which edge, of any of its ends, is angularly cut, in order to decrease the face diameter of any of said ends, for example, to make easy to insert the stopper into the neck.
- reuse relates to a stopper which may be used for multiple insertions and/or removal from the neck of the container.
- first bottling or “first bottling action” relates to the first time, after its production, a stopper is inserted into the container neck. Usually this first action is performed in the factory and is usually done in an automated manner.
- disk relates to a cork member which can be bonded to any of the stopper ends.
- this member adheres to stopper end(s) by means of gluing and has exactly the same profile with respect to the end(s) where it is adhered. Usually its height is higher than at least about 1 mm, but may vary significantly. Usually this member is made from natural cork which has better quality than the respective cork where it is adhered.
- stoppers of the prior art are divided into three categories.
- the first category includes stoppers which seal a beverage container. This type of stoppers does not allow for its manual removal due the stopper is fully inserted within the neck of the container, and so require a cork screw device for the removal. These stoppers can not be used to plug again (/. e. , being reinserted in the same container) by means of a manual action only, or otherwise it is necessary to apply an high manual force after a rotation of 180° of the stopper ends to achieve such task, thus inserting the starting upper end of the stopper in the edge of the neck in order to subsequently push the stopper into the container neck.
- stoppers also seal the containers but they differ from the preceding category because they allow for manual removal. These stoppers have about 30.5 to 31 mm diameter (d) and about 48 mm length (c), Fig. 1, whereby the manual removal is achievable only due to the internal pressure outwardly exerted by gas released by the beverage itself, which pressure helps the manual removal action. Additionally, it becomes nearly impossible to reuse these stoppers manually due to its recovered external diameter (d) after the removal action.
- the third category comprises stoppers which are designed to plug (but not sealing) the containers, so as to prevent only beverage leaks through the neck of the container.
- These stoppers used with containers having the so-called “spirit” beverages, are usually able to be used manually only but they do not seal the container.
- These stoppers are formed by a cylindrical body with a small length and by a removal crown.
- said sealing stoppers have lengths (c) which may vary from about 38 to 54 cm and diameters (d) which must have a difference between the stopper diameter (d) and the neck diameter of about 5.5 to 7.5 mm, in order to assure the sealing effect.
- These stoppers are formed as single pieces by boring of natural cork or by extrusion or moulding of granulated cork, having a cylindrical shape, and the bottling process being usually mechanical and including, in both cases, a starting insertion into the neck of the container with a previous compression and a subsequent use of a piston so as to insert the remaining of the stopper into the container.
- the beverage container plug only stoppers have lengths which vary from about 27 to 29 mm and diameters which must have a difference between the stopper diameter and the neck diameter not higher than 2 mm.
- These stoppers comprise a head/crown and a body which are usually formed from different materials.
- the bottling process is performed by a mechanical or manual force, which is longitudinally exerted from outwards to inwards with respect to the container, to insert the stopper into the neck of the container up to the crown.
- the novel stopper of the present invention will form a fourth stopper category because it is able to seal and at the same time is manually removable, it is able to be reused/reinserted into the same container without the risk of become damaged or deteriorate the container content, and high forces or the use of mechanical devices are not required to the removal/reinsertion.
- the novel stopper of the present invention overcomes the drawbacks from the stoppers of the prior art, and gathers the main advantages of the latter.
- the SSR stopper herein disclosed comprises two members (1, 2).
- the existence of two members (1, 2), upper and lower, respectively, having different well defined sizes imparts the manual reuse ability to the SSR stopper, while keeping the sealing ability of the prior art sealing stoppers by the time of the first bottling. This association of features were not possible with stoppers of prior art.
- the upper member (1) or head of the SSR stopper is the part of the SSR stopper which remains outside the container neck after bottling, and must have an height (a', a") of at least about 8 mm, and if it has a circular profile, must have a diameter (da', da") which must be larger than the diameter (d ⁇ d") of the body (2) by at least about 3 mm.
- SSR stopper head (1) may be not circular only, being allowed to assume any profile obtainable by the SSR stopper production processes. It is also contemplated that the head
- (2) may comprise at least one cork disk (4) with the same profile in its upper end, if desired.
- the lower member (2) or body of the SSR stopper must be cylindrical and may comprise at least one cork disk (4) with the same profile and/or a chamfer (3) on its lower end.
- This lower member (2) or body is the part of the SSR stopper which remains fully within the container neck after bottling.
- the SSR stopper body (2) must have a length (c ⁇ c") of about 10 to 30 mm and, for the case of standard necks having diameters from 16.5 to 18 mm, must have a diameter (d ⁇ d") of about 21 to 26 mm.
- the dimensions (c ⁇ c"; d', d") of the SSR stopper body (2) of the present invention, particularly the length (c', c") of the SSR stopper body (2), reside between the production values for sealing stoppers and the production values for plugging but not sealing stoppers, both from prior art.
- the SSR stopper head (1) In the bottling process, the SSR stopper head (1) must be abutted to the edge of the container neck, the SSR stopper body (2) being fully inserted into the neck.
- the SSR stopper of the present invention is clearly advantageous because it keeps the advantages of the sealing action but overcomes the problems related with the manual removal and reuse evidenced by said sealing stoppers of prior art.
- an SSR stopper comprises an upper member (1) or head, having a circular cross-section, and a cylindrical lower member (2) or body.
- the head (1) and the body (2) are formed into a single cork piece.
- the head (1) has a diameter (da') of 30 mm and an height (a') of
- the body (2) having a diameter (d') of 23 mm and a length (c') of 25 mm.
- an SSR stopper comprises a head (1), having a circular cross-section, and a cylindrical body (2).
- the head (1) and the body (2) are formed into a single cork piece.
- the head (1) has a diameter (da') of 30 mm and a height (a') of 20 mm, the body (2) having a diameter (d') of 23 mm and a length (c') of 27 mm.
- This SSR stopper is further chamfered with a chamfer (3) of 2 mm, on the lower end of the stopper body (2).
- an SSR stopper comprises a head (1), having a circular cross-section, and a cylindrical body (2).
- the head (1) and the body (2) are formed into a single cork piece.
- the head (1) has a diameter (da') of 30 mm and an height (a') de 15 mm, the body (2) having a diameter (d') of 24 mm and a length (c') of 27 mm and the lower end of the body (2) being chamfered with a chamfer (3) of 4 mm.
- an SSR stopper comprises a head (1) having a circular cross-section and a cylindrical body (2).
- the head (1) and the body (2) are formed into a single cork piece.
- the head has a diameter (da") of 30 mm and a height (a") of 20 mm, comprising one disk (4) having an height (ad") of 15 mm.
- the body (2) has a diameter (d") of 23 mm, length (c") of 25 mm and a chamfer (3) of 4 mm on the lower end thereof.
- said head (1) has a diameter (da") of 30 mm and an height (a") of 20 mm, the head (1) comprising one disk (4), from natural cork, of 15 mm height, said body (2) having a diameter (d") of 21 mm and a length (c") of 25 mm, the lower end of the body being chamfered with a chamfer (3) of 4 mm.
- a number of agglomerated cork stoppers with the dimensions shown in table 1 were produced by extrusion followed of grinding to desired size in order to test it with bottles having standard neck (CETIE).
- the produced stoppers, shown in table 1 were subjected to a standard surface treatment with Bopsil in an amount of 15 mg/stopper.
- the stoppers were further subjected to a white washing process.
- Bottling tests were made to check the sealing ability of SSR stoppers of the present invention by comparison with the sealing ability of agglomerated stoppers of prior art.
- the stoppers selected for comparison were:
- agglomerated stoppers of prior art having 38 x 24 mm (length x diameter);
- SSR stoppers 15 (of Table 1 from example 1), which head has 30 mm diameter and 15 mm height and which body has 27 mm length and 24 mm diameter with a chamfer of 4 mm.
- All the agglomerated stoppers of prior art were made in a conventional manner, by extrusion of rods having 25 mm, and subjected to a standard surface treatment using Bopsil, 15 mg/stopper, and a white washing. All the SSR stoppers 15 were made by extrusion of 32 mm rods, followed of grinding and subjected to a standard surface treatment using Bopsil, 15 mg/stopper.
- Stoppers 15b were split into two groups, one of the groups was subjected to a white washing process (SSR stoppers 15b) and the other group was subjected to a cork like colour washing process (SSR stoppers 15c).
- the feed rate and temperature of the extrusion device are different in relation to the SSR stoppers of the invention and the agglomerated stoppers of prior art, due to different dimensions (above-mentioned) of respective rods.
- Greenish-white wine from "Sociedade Vinhos Borges” was used in the bottling test as well as "Bordalesas” bottles having a 750 mL capacity and a greenish colour.
- the stoppers were delivered as follows:
- a wine bottling line was used to bottle the agglomerated stoppers and a champagne bottling line was used to bottle the SSR stoppers.
- the absorption in the SSR stoppers is low and substantially lower than that of the agglomerated stoppers of the prior art. This occur since, due to the differences in the production process (described above), the SSR stoppers (formed herein from 32 mm rods) are more compressed than the agglomerated stoppers of the prior art (formed from 25 mm rods) and therefore the absorption of the former is lower than that of the latter. Additionally to the production process, the formulation used in the SSR stoppers has an amount of paraffin which is slightly higher than that used in the agglomerated stoppers of prior art. This may explain the different absorption, which means the absorption differences found in both types of stoppers do not have any relation with the shape thereof.
- the stoppers used in this test were the same as in the preceding example, comprising agglomerated stoppers of prior art and SSRb and SSRc stoppers of the present invention. Arrangements of three samples of wine were made. Each wine taster had necessarily to report one of said three samples as being different from the others (even if he/she did not find any in such condition). Following, the correct answers were established and compared with a so-called critical number which matched with the minimum number of correct answers in order to assume the samples as statistically different. This critical number is established in a table of the ISO rule and varies with the number of the tasters. In order to clarify the above-mentioned, there is shown below the Table 3 including the test data.
- the bottling test along one year have proved that the SSR stoppers according to the present invention, have a behaviour similar to that of agglomerated stoppers of prior art used as the reference stoppers.
- the differences found with respect to absorption are due to the different production process used (as above- mentioned) and not to the dimensions and shape of stoppers.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Closures For Containers (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PT104082A PT104082A (pt) | 2008-05-30 | 2008-05-30 | Rolha vedante de remoção e reinserção manual |
PCT/PT2009/000029 WO2009145652A1 (en) | 2008-05-30 | 2009-05-29 | Sealing stopper for manual removal and reinsertion |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2291314A1 true EP2291314A1 (en) | 2011-03-09 |
Family
ID=40933216
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09755108A Withdrawn EP2291314A1 (en) | 2008-05-30 | 2009-05-29 | Sealing stopper for manual removal and reinsertion |
Country Status (7)
Country | Link |
---|---|
US (1) | US20110108512A1 (pt) |
EP (1) | EP2291314A1 (pt) |
CN (1) | CN102112376A (pt) |
AU (1) | AU2009251945A1 (pt) |
PT (1) | PT104082A (pt) |
WO (1) | WO2009145652A1 (pt) |
ZA (1) | ZA201009266B (pt) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PT104894A (pt) * | 2009-12-17 | 2011-06-17 | Amorim & Irmaos S A | Rolha de inserção e remoção fácil para vinhos tranquilos |
US8714383B2 (en) * | 2011-08-19 | 2014-05-06 | Corson Family Enterprises, Llc | Compound bung for wine and spirits barrels |
PT108721A (pt) * | 2015-07-23 | 2017-01-23 | Amorim & Irmãos S A | Cápsula de deteção de violação de recipiente, sua utilização e processo de funcionamento |
FR3049272B1 (fr) * | 2016-03-22 | 2018-03-30 | Ets Barange - Fabrique De Bouchons | Bouchon composite pour vins effervescents |
EP4400441A1 (en) * | 2023-01-12 | 2024-07-17 | Sedacor - Sociedade Exportadora De Artigos de Cortica, Lda. | Cap for a capped stopper and method thereof |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE396710A (pt) * | ||||
US51141A (en) * | 1865-11-28 | Improved bottle | ||
FR717282A (fr) * | 1931-05-19 | 1932-01-06 | Tissier Ets | Bouchon en liège |
FR812359A (fr) * | 1936-05-07 | 1937-05-08 | Bouchon à double chanfrein | |
GB1572902A (en) * | 1976-04-29 | 1980-08-06 | Metal Box Co Ltd | Closures for liquid product containers |
US5421471A (en) * | 1994-04-15 | 1995-06-06 | Burgan; Hobart | Roll-proof bottle stopper |
FR2826636A3 (fr) * | 2001-06-28 | 2003-01-03 | Mugaburu Jose Maria Castro | Bouchon de liege perfectionne |
FR2871087B1 (fr) | 2004-06-07 | 2007-01-05 | Barange Fabrique De Bouchons S | Procede de fabrication d'un element comprenant au moins du liege, notamment d'un bouchon, et element obtenu par un tel procede |
WO2006061858A1 (en) | 2004-12-06 | 2006-06-15 | Emanuele Crespi | Closure for liquid container, particularly, for sparkling wine and champagne bottles |
-
2008
- 2008-05-30 PT PT104082A patent/PT104082A/pt unknown
-
2009
- 2009-05-29 WO PCT/PT2009/000029 patent/WO2009145652A1/en active Application Filing
- 2009-05-29 EP EP09755108A patent/EP2291314A1/en not_active Withdrawn
- 2009-05-29 CN CN2009801298570A patent/CN102112376A/zh active Pending
- 2009-05-29 AU AU2009251945A patent/AU2009251945A1/en not_active Abandoned
- 2009-05-29 US US12/995,162 patent/US20110108512A1/en not_active Abandoned
-
2010
- 2010-12-23 ZA ZA2010/09266A patent/ZA201009266B/en unknown
Non-Patent Citations (2)
Title |
---|
None * |
See also references of WO2009145652A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2009145652A1 (en) | 2009-12-03 |
ZA201009266B (en) | 2012-03-28 |
PT104082A (pt) | 2009-11-30 |
CN102112376A (zh) | 2011-06-29 |
US20110108512A1 (en) | 2011-05-12 |
AU2009251945A1 (en) | 2009-12-03 |
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Legal Events
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