EP2242363A1 - Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds - Google Patents

Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds

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Publication number
EP2242363A1
EP2242363A1 EP09709687A EP09709687A EP2242363A1 EP 2242363 A1 EP2242363 A1 EP 2242363A1 EP 09709687 A EP09709687 A EP 09709687A EP 09709687 A EP09709687 A EP 09709687A EP 2242363 A1 EP2242363 A1 EP 2242363A1
Authority
EP
European Patent Office
Prior art keywords
treatment
plants
spp
branches
inflorescences
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP09709687A
Other languages
German (de)
French (fr)
Inventor
Reiner Fischer
Heike Hungenberg
Wolfram Andersch
Xavier Alain Marie Van Waetermeulen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Intellectual Property GmbH
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Priority to EP09709687A priority Critical patent/EP2242363A1/en
Publication of EP2242363A1 publication Critical patent/EP2242363A1/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof

Definitions

  • the present invention relates to the use of tetramic acid derivatives for combating animal pests after stock treatments (spraying, painting, injection, application), treatments of branches, stems, shoots and branches (painting, spraying, application), inflorescence and bud treatments by injection.
  • insects and spider mites after parent treatment (eg by painting, spraying, applying, injecting), after treatment of stems, branches, twigs and shoots (eg by painting, spraying, application) and after injection into flower buds and inflorescences (in Professional circles known as bud-injection) are suitable.
  • the present invention relates to the use of tetramic acid derivatives for combating insects and spider mites by stem applications, branch, stalk, branch and shoot applications and inflorescence and flower bud treatments in the field or in closed systems (eg greenhouses or under foil cover) in annuals Cultures (eg ornamental plants) and perennial crops (eg tropical fruits, citrus, conifers, pome fruit, stone fruit, hops).
  • closed systems eg greenhouses or under foil cover
  • annuals Cultures eg ornamental plants
  • perennial crops eg tropical fruits, citrus, conifers, pome fruit, stone fruit, hops.
  • citrus such as oranges, grapefruit, tangerines, lemons, limes, bitter oranges, kumquats, satsumas, is understood to mean the use among perennial crops;
  • pomaceous fruits such as apples, pears and quinces
  • stone fruit such as pepper, nectarines, cherries, plums, plums, apricots
  • wine, hops, olives, tea and tropical crops such as mangoes, papayas, figs, pineapples, dates, bananas, durians, kakis, coconuts, cocoa, coffee, avocados, lychees, passion fruits, guavas, oil palm trees;
  • almonds and nuts such as hazelnuts, walnuts, pistachios, cashews, Brazil nuts, pecans, butternuts, chestnuts, hickory nuts, macadamia nuts, peanuts,
  • soft fruits such as currants, gooseberries, raspberries, blackberries, blueberries, strawberries, cranberries, kiwis, cranberries.
  • ornamental plants are understood to be annual and perennial plants, e.g. Cut flowers such as roses, carnations, gerberas, lilies, daisies, chrysanthemums, tulips, daffodils, anemones, poppies, amyrillis, dahlias, azaleas, mallows,
  • Bedding plants potted plants and perennials such as roses, marigolds, pansies, geraniums, fuchsias, hibiscus, chrysanthemums, hard-bitten lits, cyclamen, southern violets, sunflowers, begonias,
  • Shrubs and conifers such as ficus, rhododendron, spruce, fir, pine, yew, juniper, pine, oleander.
  • Thrips are preferred from the family of thrips (Thripidae): Frankliniella spp., Thrips spp., Heliothrips spp., Hercinothrips spp., Caliothrips spp., Scirthothrips spp. in crops such as soft fruits, ornamental plants, potatoes, tropical crops, wine, nuts, citrus, tea. Preference is given to the family of lice and wool lice (Pseudococcidae): Pericerga, Pseudococcus spp., Planococcus spp., Dysmicoccus spp., In crops such as citrus, stone and pome fruit, tea, wine, ornamentals and tropical crops.
  • cover-shield lice (Diaspididae): Quadraspidiotus spp., Aonidiella spp., Lepidosaphes spp., Aspidiotus spp., Parlatoria spp., Pseudaulacaspis spp., Unaspis spp., Pinnaspis spp., Selenaspidus spp., In cultures such as eg Citrus, pome fruit, stone fruit, almonds, nuts, olives, tea, ornamental plants, wine, tropical crops.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Plant parts are to be understood as meaning all aboveground and subterranean parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes.
  • the plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
  • the treatment according to the invention of the plants and plant parts with the active ingredient is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, injecting and in propagation material, in particular in seeds, further by single or multi-layer wrapping.
  • plants and their parts can be treated.
  • wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated.
  • transgenic plants and plant cultivars produced by genetic engineering Methods are optionally obtained in combination with conventional methods (Genetic Modified Organisms) and their parts treated.
  • the term “parts” or “parts of plants” or “plant parts” is explained above.
  • Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.
  • the treatment according to the invention may also give rise to superadditive ("synergistic") effects.
  • superadditive for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
  • the preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits").
  • traits are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or soil salt content, increased flowering efficiency, easier harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value harvest products, higher shelf life and / or workability of the harvested products.
  • Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances.
  • transgenic plants include the important crops such as cereals (wheat, rice), corn, soybean, potato, cotton, tobacco, oilseed rape and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybean, potato , Cotton, tobacco and oilseed rape.
  • Traits are particularly emphasized the increased Repelling the plants against insects, arachnids, nematodes and snails by toxins produced in the plants, in particular those by the genetic material from Bacillus thuringiensis (eg by the genes Cry ⁇ A (a), CryIA (b), Cry ⁇ A (c), CryllA , CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and their combinations) in the plants (hereinafter "Bt plants”). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins.
  • SAR systemic acquired resistance
  • Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene).
  • the genes which confer the desired properties (“traits") can also occur in combinations with one another in the transgenic plants.
  • Examples of “Bt plants” are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to Imidazolinone) and STS® (tolerance to sulfonylureas eg corn).
  • Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also mentioned under the name Clearf ⁇ eld® varieties (eg corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
  • the active compounds of the formulas (I) and (II) can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and microencapsulations in polymeric substances.
  • formulations are prepared in a known manner, e.g. by mixing the active compound with extenders, ie liquid solvents and / or solid carriers, optionally with the use of surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
  • organic solvents can also be used as auxiliary solvents.
  • liquid solvents are essentially in Question: Aromatics such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, eg petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their Ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Aromatics such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlor
  • Suitable solid carriers are:
  • Ammonium salts and ground natural minerals such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g.
  • nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Lignin-sulphite liquors and methylcellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations.
  • Other additives may be mineral and vegetable oils.
  • Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • inorganic pigments e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%, and additionally preferably extenders and / or surface-active agents.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
  • the application is done in a custom forms adapted to the application forms.
  • Banana trees of the "Cavendish” variety are treated in three replications against banana flower thrips (Thrips hawaiiensis) in which the active ingredients Example (H) (100 OD) are tested against the commercial standard Imidacloprid (100 SL) at the stated application rates In each case, three flower buds are treated, each being evaluated 3 and 91 days after the treatment by scoring the killing of the population on the flower or fruit stalks.
  • Banana trees (growth stage BBCH 1130) of the genus "Cavendish” consisting of mother plant and lateral shoot are treated in three replications after foliar treatment against Aspidiotus destructor and against the pineapple louse Dysmicoccus brevipes by pseudo-root application, for which 100 ml spray solution are applied, each containing 50 ml The leaves and 50 ml are sprayed onto the stem Before the stem application, the topmost seed layer is peeled off, which is common practice, the active ingredient (II) (SC 240) in a tank mix with 0.025% Hoestick (XL 500) against the commercial standards Chlorpyrifos-methyl (500 EC) and paraffin oil (Banole oil) (EC 600) tested.
  • II active ingredient
  • the evaluation takes place 3, 7, 14 and 22 days after the treatment, by scoring the killing of the pineapple louse on the trunk.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)

Abstract

The invention relates to the use of tetramic acid derivatives of formula (I) or (II) for controlling animal pests after treatment of the trunk (spraying, painting, injection, application), treatment of branches, stems, shoots and twigs (painting, spraying, application), and treatment of the inflorescences or buds by injection.

Description

Verwendung von Tetramsäurederivaten zur Bekämpfung von tierischen Schädlingen nach Stamm-, Zweig-, Blütenstand- und Knospenbehandlungen Use of tetramic acid derivatives for combating animal pests after stem, branch, inflorescence and bud treatments
Die vorliegende Erfindung betrifft die Verwendung von Tetramsäurederivaten zur Bekämpfung von tierischen Schädlingen nach Stammbehandlungen (Anspritzen, Anstreichen, Injektion, Aufbringen), Behandlungen von Ästen, Stängel, Trieben und Zweigen (Anstreichen, Anspritzen, Aufbringen), Blütenstand- und Knospenbehandlungen durch Injektion.The present invention relates to the use of tetramic acid derivatives for combating animal pests after stock treatments (spraying, painting, injection, application), treatments of branches, stems, shoots and branches (painting, spraying, application), inflorescence and bud treatments by injection.
Bekannt mit insektizider und/oder akarizider Wirkung sind Tetramsäurederivate (WO 98/05638) sowie deren cis-Isomeren (WO 04/007448).Known with insecticidal and / or acaricidal action are tetramic acid derivatives (WO 98/05638) and their cis isomers (WO 04/007448).
Weiterhin bekannt ist die Verwendung von Tetramsäurederivaten gegen Spinnmilben und Insekten nach Angiessen, Tröpfchenapplikation oder Bodeninjektion (WO 07/126691), sowie gegen Nematoden nach Blattaplikation (US Anmeldenummer 61/008507) als auch Bekämpfung von Pflanzenkrankheiten nach Drenchapplikation (EP Anmeldenummer 07150293).Also known is the use of tetramic acid derivatives against spider mites and insects after casting, droplet application or soil injection (WO 07/126691), and against nematodes after Blattaplikation (US application number 61/008507) and control of plant diseases after Drenchapplikation (EP application number 07150293).
Weitere Verwendungen sind in der WO 2007/131681 beschrieben.Further uses are described in WO 2007/131681.
Überraschenderweise wurde nun gefunden, dass die Verbindungen der Formeln (I) oder (II)Surprisingly, it has now been found that the compounds of the formulas (I) or (II)
auch gut zur Bekämpfung von Insekten und Spinnmilben nach Stammbehandlung (z.B. durch Anstreichen, Aufspritzen, Aufbringen, Injizieren), nach Behandlung von Stängel, Ästen, Zweigen und Trieben (z.B. durch Anstreichen, Aufspritzen, Aufbringen) und nach Injektion in Blütenknospen und Blütenstände (in Fachkreisen als bud-injection bekannt) geeignet sind.Also good for controlling insects and spider mites after parent treatment (eg by painting, spraying, applying, injecting), after treatment of stems, branches, twigs and shoots (eg by painting, spraying, application) and after injection into flower buds and inflorescences (in Professional circles known as bud-injection) are suitable.
Die vorliegende Erfindung betrifft demnach die Verwendung von Tetramsäurederivaten zur Bekämpfung von Insekten und Spinnmilben nach Stammanwendungen, Ast-, Stengel-, Zweig- und Triebanwendungen sowie Blütenstand- und Blütenknospenbehandlungen im Freiland oder in geschlossenen Systemen (z.B. Gewächshäuser oder unter Folien-Abdeckung) in einjährigen Kulturen (z.B. Zierpflanzen) und mehrjährigen Kulturen (z.B. tropische Früchte, Zitrus, Koniferen, Kernobst, Steinobst, Hopfen).Accordingly, the present invention relates to the use of tetramic acid derivatives for combating insects and spider mites by stem applications, branch, stalk, branch and shoot applications and inflorescence and flower bud treatments in the field or in closed systems (eg greenhouses or under foil cover) in annuals Cultures (eg ornamental plants) and perennial crops (eg tropical fruits, citrus, conifers, pome fruit, stone fruit, hops).
Die nur allgemein beschriebenen zu schützenden Kulturen sind im Folgenden differenziert und näher spezifiziert.The only generally described cultures to be protected are differentiated and specified below.
So versteht man hinsichtlich der Anwendung unter mehrjährigen Kulturen Zitrus, wie beispielsweise Orangen, Grapefruits, Mandarinen, Zitronen, Limetten, Bitterorangen, Kumquats, Satsumas;Thus, citrus, such as oranges, grapefruit, tangerines, lemons, limes, bitter oranges, kumquats, satsumas, is understood to mean the use among perennial crops;
aber auch Kernobst, wie beispielsweise Äpfel, Birnen und Quitten und Steinobst, wie beispielsweise Pfϊrsische, Nektarinen, Kirschen, Pflaumen, Zwetschgen, Aprikosen;but also pomaceous fruits, such as apples, pears and quinces, and stone fruit, such as pepper, nectarines, cherries, plums, plums, apricots;
weiterhin Wein, Hopfen, Oliven, Tee und tropische Kulturen, wie beispielsweise Mangos, Papayas, Feigen, Ananas, Datteln, Bananen, Durians (Stinkfrüchte), Kakis, Kokosnüsse, Kakao, Kaffee, Avocados, Litschies, Maracujas, Guaven, Ölpalmen;wine, hops, olives, tea and tropical crops such as mangoes, papayas, figs, pineapples, dates, bananas, durians, kakis, coconuts, cocoa, coffee, avocados, lychees, passion fruits, guavas, oil palm trees;
außerdem Mandeln und Nüsse wie beispielsweise Haselnüsse, Walnüsse, Pistazien, Cashewnüsse, Paranüsse, Pekannüsse, Butternüsse, Kastanien, Hickorynüsse, Macadamiannüsse, Erdnüsse,almonds and nuts such as hazelnuts, walnuts, pistachios, cashews, Brazil nuts, pecans, butternuts, chestnuts, hickory nuts, macadamia nuts, peanuts,
darüber hinaus auch Beerenfrüchte wie beispielsweise Johannisbeeren, Stachelbeeren, Himbeeren, Brombeeren, Heidelbeeren, Erdbeeren, Preiselbeeren, Kiwis, Cranberries.in addition, soft fruits such as currants, gooseberries, raspberries, blackberries, blueberries, strawberries, cranberries, kiwis, cranberries.
Hinsichtlich der Anwendung versteht man unter Zierpflanzen ein- und mehrjährige Pflanzen, z.B. Schnittblumen wie beispielsweise Rosen, Nelken, Gerbera, Lilien, Margeriten, Chrysanthemen, Tulpen, Narzissen, Anemonen, Mohn, Amyrillis, Dahlien, Azaleen, Malven,In terms of application, ornamental plants are understood to be annual and perennial plants, e.g. Cut flowers such as roses, carnations, gerberas, lilies, daisies, chrysanthemums, tulips, daffodils, anemones, poppies, amyrillis, dahlias, azaleas, mallows,
aber auch z.B. Beetpflanzen, Topfpflanzen und Stauden, wie beispielsweise Rosen, Tagetes, Stiefmütterchen, Geranien, Fuchsien, Hibiscus, Chrysanthemen, Fleißige Lieschen, Alpenveilchen, Ursambaraveilchen, Sonnenblumen, Begonien,but also e.g. Bedding plants, potted plants and perennials such as roses, marigolds, pansies, geraniums, fuchsias, hibiscus, chrysanthemums, hard-bitten lits, cyclamen, southern violets, sunflowers, begonias,
ferner z.B. Sträucher und Koniferen wie beispielsweise Ficus, Rhododendron, Fichten, Tannen, Kiefern, Eiben, Wacholder, Pinien, Oleander.further e.g. Shrubs and conifers such as ficus, rhododendron, spruce, fir, pine, yew, juniper, pine, oleander.
Bevorzugt sind aus der Familie der Thripse (Thripidae): Frankliniella spp., Thrips spp., Heliothrips spp., Hercinothrips spp., Caliothrips spp., Scirthothrips spp. in Kulturen wie z.B. Beerenfrüchte, Zierpflanzen, Kartoffeln, tropischen Kulturen, Wein, Nüsse, Zitrus, Tee. Bevorzugt sind aus der Familie der Schmier- und Wollläuse (Pseudococcidae): Pericerga, Pseudococcus spp., Planococcus spp., Dysmicoccus spp., in Kulturen wie z.B. Zitrus, Stein- und Kernobst, Tee, Wein, Zierpflanzen und tropischen Kulturen.Thrips are preferred from the family of thrips (Thripidae): Frankliniella spp., Thrips spp., Heliothrips spp., Hercinothrips spp., Caliothrips spp., Scirthothrips spp. in crops such as soft fruits, ornamental plants, potatoes, tropical crops, wine, nuts, citrus, tea. Preference is given to the family of lice and wool lice (Pseudococcidae): Pericerga, Pseudococcus spp., Planococcus spp., Dysmicoccus spp., In crops such as citrus, stone and pome fruit, tea, wine, ornamentals and tropical crops.
Bevorzugt sind aus der Familie der Napfschildläuse (Coccidae): Ceroplastes spp., Drosicha spp. Pulvinaria spp., Protopulminaria spp., Saissetia spp., Coccus spp., in mehrjährigen Kulturen wie z.B. Zitrus, Kernobst, Steinobst, Oliven, Wein, Kaffee, Tee, tropischen Kulturen, Zierpflanzen.Preference is given from the family of the Napfschildläuse (Coccidae): Ceroplastes spp., Drosicha spp. Pulvinaria spp., Protopulminaria spp., Saissetia spp., Coccus spp., In perennial crops, e.g. Citrus, pome fruit, stone fruit, olives, wine, coffee, tea, tropical crops, ornamental plants.
Bevorzugt sind aus der Familie der Deckelschildläuse (Diaspididae): Quadraspidiotus spp., Aonidiella spp., Lepidosaphes spp., Aspidiotus spp., Parlatoria spp., Pseudaulacaspis spp., Unaspis spp., Pinnaspis spp., Selenaspidus spp., in Kulturen wie z.B. Zitrus, Kernobst, Steinobst, Mandeln, Nüssen, Oliven, Tee, Zierpflanzen, Wein, tropischen Kulturen.Preference is given to the family of cover-shield lice (Diaspididae): Quadraspidiotus spp., Aonidiella spp., Lepidosaphes spp., Aspidiotus spp., Parlatoria spp., Pseudaulacaspis spp., Unaspis spp., Pinnaspis spp., Selenaspidus spp., In cultures such as eg Citrus, pome fruit, stone fruit, almonds, nuts, olives, tea, ornamental plants, wine, tropical crops.
Erfϊndungsgemäß können alle Pflanzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich natürlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechnologische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Sproß, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft Blätter, Nadeln, Stengel, Stämme, Blüten, Fruchtkörper, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Stecklinge, Knollen, Rhizome, Ableger und Samen.Erfϊndungsgemäß all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. Plant parts are to be understood as meaning all aboveground and subterranean parts and organs of the plants, such as shoot, leaf, flower and root, examples of which include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.
Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit dem Wirkstoff erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z.B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Aufstreichen, Injezieren und bei Vermehrungsmaterial, insbesondere bei Samen, weiterhin durch ein- oder mehrschichtiges Umhüllen.The treatment according to the invention of the plants and plant parts with the active ingredient is carried out directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, injecting and in propagation material, in particular in seeds, further by single or multi-layer wrapping.
Wie bereits oben erwähnt, können erfindungsgemäß alle Pflanzen und deren Teile behandelt werden. In einer bevorzugten Ausführungsform werden wild vorkommende oder durch konventionelle biologische Zuchtmethoden, wie Kreuzung oder Protoplastenfusion erhaltenen Pflanzenarten und Pflanzensorten sowie deren Teile behandelt. In einer weiteren bevorzugten Ausführungsform werden transgene Pflanzen und Pflanzensorten, die durch gentechnologische Methoden gegebenenfalls in Kombination mit konventionellen Methoden erhalten wird (Genetic Modifϊed Organisms) und deren Teile behandelt. Der Begriff "Teile" bzw. "Teile von Pflanzen" oder "Pflanzenteile" wird oben erläutert.As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated. In a further preferred embodiment, transgenic plants and plant cultivars produced by genetic engineering Methods are optionally obtained in combination with conventional methods (Genetic Modified Organisms) and their parts treated. The term "parts" or "parts of plants" or "plant parts" is explained above.
Besonders bevorzugt werden erfindungsgemäß Pflanzen der jeweils handelsüblichen oder in Gebrauch befindlichen Pflanzensorten behandelt. Unter Pflanzensorten versteht man Pflanzen mit neuen Eigenschaften ("Traits"), die sowohl durch konventionelle Züchtung, durch Mutagenese oder durch rekombinante DNA-Techniken gezüchtet worden sind. Dies können Sorten, Bio- und Genotypen sein.It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars. Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.
Je nach Pflanzenarten bzw. Pflanzensorten, deren Standort und Wachstumsbedingungen (Böden, Klima, Vegetationsperiode, Ernährung) können durch die erfindungsgemäße Behandlung auch überadditive ("synergistische") Effekte auftreten. So sind beispielsweise erniedrigte Aufwandmengen und/oder Erweiterungen des Wirkungsspektrums und/oder eine Verstärkung der Wirkung der erfindungsgemäß verwendbaren Stoffe und Mittel, besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, erleichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte möglich, die über die eigentlich zu erwartenden Effekte hinausgehen.Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention may also give rise to superadditive ("synergistic") effects. Thus, for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.
Zu den bevorzugten erfindungsgemäß zu behandelnden transgenen (gentechnologisch erhaltenen) Pflanzen bzw. Pflanzensorten gehören alle Pflanzen, die durch die gentechnologische Modifikation genetisches Material erhielten, welches diesen Pflanzen besondere vorteilhafte wertvolle Eigenschaften ("Traits") verleiht. Beispiele für solche Eigenschaften sind besseres Pflanzenwachstum, erhöhte Toleranz gegenüber hohen oder niedrigen Temperaturen, erhöhte Toleranz gegen Trockenheit oder gegen Wasser- bzw. Bodensalzgehalt, erhöhte Blühleistung, er- leichterte Ernte, Beschleunigung der Reife, höhere Ernteerträge, höhere Qualität und/oder höherer Ernährungswert der Ernteprodukte, höhere Lagerfähigkeit und/oder Bearbeitbarkeit der Ernteprodukte. Weitere und besonders hervorgehobene Beispiele für solche Eigenschaften sind eine erhöhte Abwehr der Pflanzen gegen tierische und mikrobielle Schädlinge, wie gegenüber Insekten, Milben, pflanzenpathogenen Pilzen, Bakterien und/oder Viren sowie eine erhöhte Toleranz der Pflanzen gegen bestimmte herbizide Wirkstoffe. Als Beispiele transgener Pflanzen werden die wichtigen Kulturpflanzen, wie Getreide (Weizen, Reis), Mais, Soja, Kartoffel, Baumwolle, Tabak, Raps sowie Obstpflanzen (mit den Früchten Äpfel, Birnen, Zitrusfrüchten und Weintrauben) erwähnt, wobei Mais, Soja, Kartoffel, Baumwolle, Tabak und Raps besonders hervorgehoben werden. Als Eigenschaften ("Traits") werden besonders hervorgehoben die erhöhte Abwehr der Pflanzen gegen Insekten, Spinnentiere, Nematoden und Schnecken durch in den Pflanzen entstehende Toxine, insbesondere solche, die durch das genetische Material aus Bacillus Thuringiensis (z.B. durch die Gene CryΙA(a), CryIA(b), CryΙA(c), CryllA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb und CrylF sowie deren Kombinationen) in den Pflanzen erzeugt werden (im folgenden "Bt Pflanzen"). Als Eigenschaften ("Traits") werden auch besonders hervorgehoben die erhöhte Abwehr von Pflanzen gegen Pilze, Bakterien und Viren durch Systemische Akquirierte Resistenz (SAR), Systemin, Phytoalexine, Elicitoren sowie Resistenzgene und entsprechend exprimierte Proteine und Toxine. Als Eigenschaften ("Traits") werden weiterhin besonders hervorgehoben die erhöhte Toleranz der Pflanzen gegenüber bestimmten herbiziden Wirkstoffen, beispielsweise Imidazolinonen, Sulfonylharnstoffen, Glyphosate oder Phosphinotricin (z.B. "PAT"-Gen). Die jeweils die gewünschten Eigenschaften ("Traits") verleihenden Gene können auch in Kombinationen miteinander in den transgenen Pflanzen vorkommen. Als Beispiele für "Bt Pflanzen" seien Maissorten, Baumwollsorten, Sojasorten und Kartoffelsorten genannt, die unter den Handelsbezeichnungen YIELD GARD® (z.B. Mais, Baumwolle, Soja), KnockOut® (z.B. Mais), StarLink® (z.B. Mais), Bollgard® (Baumwolle), Nucotn® (Baumwolle) und NewLeaf® (Kartoffel) vertrieben werden. Als Beispiele für Herbizid tolerante Pflanzen seien Maissorten, Baumwollsorten und Sojasorten genannt, die unter den Handelsbezeichnungen Roundup Ready® (Toleranz gegen Glyphosate z.B. Mais, Baumwolle, Soja), Liberty Link® (Toleranz gegen Phosphinotricin, z.B. Raps), IMI® (Toleranz gegen Imidazolinone) und STS® (Toleranz gegen Sulfonylharnstoffe z.B. Mais) vertrieben werden. Als Herbizid resistente (konventionell auf Herbizid-Toleranz gezüchtete) Pflanzen seien auch die unter der Bezeichnung Clearfϊeld® vertriebenen Sorten (z.B. Mais) erwähnt. Selbstverständlich gelten diese Aussagen auch für in der Zukunft entwickelte bzw. zukünftig auf den Markt kommende Pflanzensorten mit diesen oder zukünftig entwickelten genetischen Eigenschaften ("Traits").The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or soil salt content, increased flowering efficiency, easier harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value harvest products, higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants against certain herbicidal active substances. Examples of transgenic plants include the important crops such as cereals (wheat, rice), corn, soybean, potato, cotton, tobacco, oilseed rape and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybean, potato , Cotton, tobacco and oilseed rape. As properties ("Traits") are particularly emphasized the increased Repelling the plants against insects, arachnids, nematodes and snails by toxins produced in the plants, in particular those by the genetic material from Bacillus thuringiensis (eg by the genes CryΙA (a), CryIA (b), CryΙA (c), CryllA , CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF and their combinations) in the plants (hereinafter "Bt plants"). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins. Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance to Imidazolinone) and STS® (tolerance to sulfonylureas eg corn). Herbicide-resistant (conventionally grown on herbicide tolerance) plants are also mentioned under the name Clearfϊeld® varieties (eg corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.
Die Wirkstoffe der Formeln (I) und (II) können in die üblichen Formulierungen überführt werden, wie Lösungen, Emulsionen, Spritzpulver, Suspensionen, Pulver, Stäubemittel, Pasten, lösliche Pulver, Granulate, Suspensions-Emulsions-Konzentrate, Wirkstoff-imprägnierte Natur- und synthetische Stoffe sowie Feinstverkapselungen in polymeren Stoffen.The active compounds of the formulas (I) and (II) can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, active substance-impregnated natural and synthetic substances and microencapsulations in polymeric substances.
Diese Formulierungen werden in bekannter Weise hergestellt, z.B. durch Vermischen des Wirkstoffs mit Streckmitteln, also flüssigen Lösungsmitteln und/oder festen Trägerstoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln.These formulations are prepared in a known manner, e.g. by mixing the active compound with extenders, ie liquid solvents and / or solid carriers, optionally with the use of surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
Im Falle der Benutzung von Wasser als Streckmittel können z.B. auch organische Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen in Frage: Aromaten, wie Xylol, Toluol, oder Alkylnaphthaline, chlorierte Aromaten und chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z.B. Erdölfraktionen, mineralische und pflanzliche Öle, Alkohole, wie Butanol oder Glykol sowie deren Ether und Ester, Ketone wie Aceton, Methylethylketon, Methylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel, wie Dimethylformamid und Dimethylsulfoxid, sowie Wasser.In the case of using water as extender, for example, organic solvents can also be used as auxiliary solvents. As liquid solvents are essentially in Question: Aromatics such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, eg petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their Ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
Als feste Trägerstoffe kommen in Frage:Suitable solid carriers are:
z.B. Ammoniumsalze und natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteinsmehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate, als feste Trägerstoffe für Granulate kommen in Frage: z.B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Material wie Sägemehl, Kokosnussschalen, Maiskolben und Tabakstengeln; als Emulgier- und/oder schaumerzeugende Mittel kommen in Frage: z.B. nichtionogene und anionische Emulgatoren, wie Polyoxyethylen-Fettsäure-Ester, Polyoxyethylen- Fettalkohol-Ether, z.B. Alkylaryl-polyglykolether, Alkylsulfonate, Alkylsulfate, Arylsulfonate sowie Eiweißhydrolysate; als Dispergiermittel kommen in Frage: z.B. Lignin-Sulfitablaugen und Methylcellulose.e.g. Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as fumed silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as sawdust, coconut shells, corn cobs and tobacco stalks; suitable emulsifiers and / or foam formers are: e.g. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are: e.g. Lignin-sulphite liquors and methylcellulose.
Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulvrige, körnige oder latexförmige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospholipide, wie Kephaline und Lecithine und synthetische Phospholipide. Weitere Additive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations. Other additives may be mineral and vegetable oils.
Es können Farbstoffe wie anorganische Pigmente, z.B. Eisenoxid, Titanoxid, Ferrocyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyaninfarbstoffe und Spurennährstoffe wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gew.-% Wirkstoff, vorzugsweise zwischen 0,5 und 90 % und daneben bevorzugt Streckmittel und/oder oberflächenaktive Mittel. Der Wirkstoffgehalt der aus den handelsüblichen Formulierungen bereiteten Anwendungsformen kann in weiten Bereichen variieren. Die Wirkstoffkonzentration der Anwendungsformen kann von 0,0000001 bis zu 95 Gew.-% Wirkstoff, vorzugsweise zwischen 0,0001 und 1 Gew.-% liegen.The formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%, and additionally preferably extenders and / or surface-active agents. The active substance content of the application forms prepared from the commercial formulations can vary within wide ranges. The active ingredient concentration of the use forms may be from 0.0000001 to 95% by weight of active ingredient, preferably between 0.0001 and 1% by weight.
Die Anwendung geschieht in einer den Anwendungsformen angepassten üblichen Weise.The application is done in a custom forms adapted to the application forms.
Anwendungsbeispiele Thripse (Thripidae)Application examples Thrips (Thripidae)
Ganz besonders bevorzugt ist die Bekämpfung folgender Arten aus der Familie der Thripse (Thripidae) in folgenden Kulturen nach Blütenstand- und Knospenbehandlung:Very particular preference is given to the control of the following species from the family of thrips (Thripidae) in the following cultures after inflorescence and bud treatment:
Schmier- und Wollläuse (Pseudococcidae)Lubricants and mealybugs (Pseudococcidae)
Ganz besonders bevorzugt ist die Bekämpfung folgender Arten aus der Familie der Schmier- und Wollläuse (Pseudococcidae) in folgenden Kulturen nach Stammapplikation: Very particularly preferred is the control of the following species from the family of louse and scavenger (Pseudococcidae) in the following cultures after stock application:
Napfschildläuse (Coccidae)Napfschildläuse (Coccidae)
Ganz besonders bevorzugt ist die Bekämpfung folgender Arten aus der Familie der Napfschildläuse (Coccidae) in folgenden Kulturen bevorzugt nach Stammapplikation:Very particularly preferred is the control of the following species from the family of Napfschildläuse (Coccidae) in the following cultures, preferably after parent application:
Deckelschildläuse (Diaspididae) Lappardella (Diaspididae)
Ganz besonders bevorzugt ist die Bekämpfung folgender Arten aus der Familie der Deckelschildläuse (Diaspididae) in folgenden Kulturen bevorzugt nach Stammapplikation:Very particular preference is given to controlling the following species from the family of the lid-shield lice (Diaspididae) in the following cultures, preferably after stock application:
Beispiel 1 example 1
Bananenbäume der Sorte „Cavendish" werden in drei Replikationen gegen Bananenblütenthrips (Thrips hawaiiensis) behandelt. Dabei werden die Wirkstoffe Beispiel (H) (100 OD) gegen den kommerziellen Standard Imidacloprid (100 SL) in den angegebenen Aufwandmengen geprüft. Die Applikation erfolgt durch Injektion von je 80 ml Injektionslösung in die Blütenknospen. Es werden jeweils drei Blütenknospen behandelt. Die Auswertung erfolgt 3 und 91 Tage nach der Behandlung, indem man die Abtötung der Population an den Blüten- bzw. Fruchtständen bonitiert.Banana trees of the "Cavendish" variety are treated in three replications against banana flower thrips (Thrips hawaiiensis) in which the active ingredients Example (H) (100 OD) are tested against the commercial standard Imidacloprid (100 SL) at the stated application rates In each case, three flower buds are treated, each being evaluated 3 and 91 days after the treatment by scoring the killing of the population on the flower or fruit stalks.
Beispiel 2Example 2
Bananenbäume (Wachstumstadium BBCH 1130) der Sorte „Cavendish" bestehend aus Mutterpflanze und Seitentrieb werden in drei Replikationen nach Blattbehandlung gegen Aspidiotus destructor und gegen die Ananasschmierlaus Dysmicoccus brevipes durch Pseudo- Stammapplikation behandelt. Dazu werden je 100 ml Spritzlösung appliziert, wobei jeweils 50 ml auf die Blätter und 50 ml auf den Stamm gespritzt wird. Vor der Stammapplikation wird zunächst die oberste Stammschicht abgeschält, welches allgemeine Praxis ist. Dabei wird der Wirkstoff (II) (SC 240) in einer Tankmischung mit 0.025 % Hoestick (XL 500) gegen die kommerziellen Standards Chlorpyrifos-methyl (500 EC) und Paraffinöl (Banole oil) (EC 600) geprüft.Banana trees (growth stage BBCH 1130) of the genus "Cavendish" consisting of mother plant and lateral shoot are treated in three replications after foliar treatment against Aspidiotus destructor and against the pineapple louse Dysmicoccus brevipes by pseudo-root application, for which 100 ml spray solution are applied, each containing 50 ml The leaves and 50 ml are sprayed onto the stem Before the stem application, the topmost seed layer is peeled off, which is common practice, the active ingredient (II) (SC 240) in a tank mix with 0.025% Hoestick (XL 500) against the commercial standards Chlorpyrifos-methyl (500 EC) and paraffin oil (Banole oil) (EC 600) tested.
Die Auswertung erfolgt 3, 7, 14 und 22 Tage nach der Behandlung, indem man die Abtötung der Ananasschmierlaus am Stamm bonitiert.The evaluation takes place 3, 7, 14 and 22 days after the treatment, by scoring the killing of the pineapple louse on the trunk.
Beispiel 3 Example 3
Ca. 5 Jahre alte Orangenbäumchen der Sorte „Valencia" werden in drei Applikationen gegen die Rote Kalifornienschildlaus Aonidiella aurantii nach Stammapplikation durch Aufstreichen der Wirkstoffe behandelt. Dabei wird der Wirkstoff (II) (SC 240) gegen den kommerziellen Standard Imidacloprid in den angegebenen Aufwandmengen geprüft. Die Auswertung erfolgt 205 Tage nach der Behandlung in dem man den Befall auf den Früchten bonitiert.Approximately 5-year-old orange trees of the "Valencia" variety are treated in three applications against the red calf louse Aonidiella aurantii after application of the parent substance by testing the active substance (II) (SC 240) against the commercial standard imidacloprid at the stated application rates Evaluation takes place 205 days after the treatment in which one scores the infestation on the fruits.

Claims

Patentansprüche claims
1. Verwendung von Verbindungen der Formeln (I) oder (H)1. Use of compounds of the formulas (I) or (H)
zur Bekämpfung von Insekten und Spinnmilben nach Stammbehandlung, nach Behandlung von Stängel, Ästen, Zweigen und Trieben und nach Injektion in Blütenknospen und Blütenstände.for the control of insects and spider mites after stem treatment, after treatment of stems, branches, twigs and shoots and after injection into flower buds and inflorescences.
2. Verwendung von Verbindungen der Formeln (I) oder (II) gemäß Anspruch 1 zur Bekämpfung von Thripse nach Blütenstandbehandlung.2. Use of compounds of the formulas (I) or (II) according to claim 1 for controlling thrips after inflorescence treatment.
3. Verwendung von Verbindungen der Formeln (I) oder (DT) gemäß Anspruch 1 zur Bekämpfung von Thripse nach Knospenbehandlung.3. Use of compounds of the formulas (I) or (DT) according to claim 1 for controlling thrips after bud treatment.
4. Verwendung von Verbindungen der Formeln (I) oder (II) gemäß Anspruch 1 zur Bekämpfung von Schmier- und Wolläusen nach Stammbehandlung.4. Use of compounds of formulas (I) or (II) according to claim 1 for controlling lice and Wolläusen after parent treatment.
5. Verwendung von Verbindungen der Formeln (I) oder (II) gemäß Anspruch 1 zur Bekämpfung von Napfschlidlläusen nach Stammbehandlung.5. Use of compounds of the formulas (I) or (II) according to claim 1 for combating Napfschlidlläusen after parent treatment.
6. Verwendung von Verbindungen der Formeln (I) oder (II) gemäß Anspruch 1 zur Bekämpfung von Deckelschlidläusen nach Stammbehandlung.6. Use of compounds of the formulas (I) or (II) according to claim 1 for combating Deckelschlidläusen after parent treatment.
7. Verwendung der Verbindung der Formel (I) gemäß Anspruch 1-6.7. Use of the compound of formula (I) according to claim 1-6.
8. Verwendung der Verbindung der Formel (I) gemäß Anspruch 1-6. 8. Use of the compound of formula (I) according to claim 1-6.
EP09709687A 2008-02-13 2009-02-06 Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds Withdrawn EP2242363A1 (en)

Priority Applications (1)

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EP09709687A EP2242363A1 (en) 2008-02-13 2009-02-06 Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds

Applications Claiming Priority (3)

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EP08151372A EP2090167A1 (en) 2008-02-13 2008-02-13 Use of tetramic acid derivatives for combating animal pests by treating roots, branches, florescence and buds
PCT/EP2009/000816 WO2009100851A1 (en) 2008-02-13 2009-02-06 Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds
EP09709687A EP2242363A1 (en) 2008-02-13 2009-02-06 Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds

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EP2242363A1 true EP2242363A1 (en) 2010-10-27

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EP08151372A Ceased EP2090167A1 (en) 2008-02-13 2008-02-13 Use of tetramic acid derivatives for combating animal pests by treating roots, branches, florescence and buds
EP09709687A Withdrawn EP2242363A1 (en) 2008-02-13 2009-02-06 Use of tetramic acid derivatives for controlling animal pests after treatment of the trunk, the branches, the inflorescences or the buds

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US (2) US20100324303A1 (en)
EP (2) EP2090167A1 (en)
JP (1) JP5567500B2 (en)
KR (1) KR20100115777A (en)
CN (1) CN101945579A (en)
AU (1) AU2009214378B2 (en)
BR (1) BRPI0907854A8 (en)
CL (1) CL2009000297A1 (en)
MA (1) MA32072B1 (en)
NZ (1) NZ587308A (en)
WO (1) WO2009100851A1 (en)
ZA (1) ZA201005721B (en)

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EP2071952A1 (en) * 2007-12-21 2009-06-24 Bayer CropScience AG Use of tetramic acid derivatives for combating plant diseases through drench or drip application

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DK1277751T3 (en) * 1996-08-05 2007-02-26 Bayer Cropscience Ag 2- and 2,5-substituted phenylketoenols
DE10024934A1 (en) * 2000-05-19 2001-11-22 Bayer Ag Pesticidal agent contains synergistic mixture of 3-aryl-4-hydroxy-2-oxo-pyrroline derivative and nicotinergic acetylcholine receptor agonist or antagonist
DE10231333A1 (en) * 2002-07-11 2004-01-22 Bayer Cropscience Ag Cis-alkoxy-substituted 1-H-pyrrolidine-2,4-dione spirocyclic derivatives
DE102005003076A1 (en) * 2005-01-22 2006-07-27 Bayer Cropscience Ag Use of tetramic acid derivatives for controlling insects of the genus of plant lice (Sternorrhyncha)
DE102005044826A1 (en) * 2005-09-20 2007-03-29 Bayer Cropscience Ag Nicotinyls, pyrethroids and ketoenols as a gel or foam formulation for perennial crops
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DE102006033154A1 (en) * 2006-07-18 2008-01-24 Bayer Cropscience Ag Drug combinations with insecticidal and acaricidal properties
DE102007009957A1 (en) * 2006-12-27 2008-07-03 Bayer Cropscience Ag Process for improving the use of the productive potential of a transgenic plant e.g. maize, soya bean, cotton, tobacco, rice, comprises treating the plant with 3-aryl-pyrrolidin-2,4-dione compound
EP2071952A1 (en) * 2007-12-21 2009-06-24 Bayer CropScience AG Use of tetramic acid derivatives for combating plant diseases through drench or drip application

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AU2009214378B2 (en) 2015-03-26
JP5567500B2 (en) 2014-08-06
ZA201005721B (en) 2011-10-26
BRPI0907854A8 (en) 2016-03-01
MA32072B1 (en) 2011-02-01
US20100324303A1 (en) 2010-12-23
EP2090167A1 (en) 2009-08-19
WO2009100851A1 (en) 2009-08-20
AU2009214378A1 (en) 2009-08-20
NZ587308A (en) 2012-04-27
US20130296395A1 (en) 2013-11-07
JP2011511815A (en) 2011-04-14
CN101945579A (en) 2011-01-12
KR20100115777A (en) 2010-10-28
BRPI0907854A2 (en) 2015-07-21
WO2009100851A8 (en) 2010-08-19
CL2009000297A1 (en) 2010-03-05

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