EP2171106A1 - Method for ore enrichment by means of hydrophobic, solid surfaces - Google Patents
Method for ore enrichment by means of hydrophobic, solid surfacesInfo
- Publication number
- EP2171106A1 EP2171106A1 EP08785971A EP08785971A EP2171106A1 EP 2171106 A1 EP2171106 A1 EP 2171106A1 EP 08785971 A EP08785971 A EP 08785971A EP 08785971 A EP08785971 A EP 08785971A EP 2171106 A1 EP2171106 A1 EP 2171106A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hydrophobic
- substance
- solid
- dispersion
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 120
- 238000000034 method Methods 0.000 title claims abstract description 59
- 239000007787 solid Substances 0.000 title claims abstract description 54
- 239000000203 mixture Substances 0.000 claims abstract description 55
- 230000005661 hydrophobic surface Effects 0.000 claims abstract description 39
- 239000006185 dispersion Substances 0.000 claims abstract description 33
- 239000002002 slurry Substances 0.000 claims abstract description 32
- 239000000126 substance Substances 0.000 claims description 84
- 150000002736 metal compounds Chemical class 0.000 claims description 28
- 230000008569 process Effects 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 13
- 239000003960 organic solvent Substances 0.000 claims description 13
- 239000002270 dispersing agent Substances 0.000 claims description 11
- 238000000926 separation method Methods 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims description 4
- 150000007514 bases Chemical class 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052948 bornite Inorganic materials 0.000 claims description 2
- 229910052947 chalcocite Inorganic materials 0.000 claims description 2
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052951 chalcopyrite Inorganic materials 0.000 claims description 2
- 239000010433 feldspar Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000002612 dispersion medium Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 5
- 239000011707 mineral Substances 0.000 abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- 150000004706 metal oxides Chemical class 0.000 abstract description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical class [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 11
- 239000006249 magnetic particle Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 6
- 239000000470 constituent Substances 0.000 description 5
- 238000005188 flotation Methods 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- -1 alkali metal cation Chemical class 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- NJGCRMAPOWGWMW-UHFFFAOYSA-N octylphosphonic acid Chemical compound CCCCCCCCP(O)(O)=O NJGCRMAPOWGWMW-UHFFFAOYSA-N 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 150000001735 carboxylic acids Chemical group 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229910052595 hematite Inorganic materials 0.000 description 2
- 239000011019 hematite Substances 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 2
- 239000011133 lead Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052656 albite Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000008396 flotation agent Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000005021 gait Effects 0.000 description 1
- 229910052949 galena Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- GJVFBWCTGUSGDD-UHFFFAOYSA-L pentamethonium bromide Chemical compound [Br-].[Br-].C[N+](C)(C)CCCCC[N+](C)(C)C GJVFBWCTGUSGDD-UHFFFAOYSA-L 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052950 sphalerite Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 125000005369 trialkoxysilyl group Chemical group 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/005—Pretreatment specially adapted for magnetic separation
- B03C1/01—Pretreatment specially adapted for magnetic separation by addition of magnetic adjuvants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/02—Magnetic separation acting directly on the substance being separated
- B03C1/30—Combinations with other devices, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/08—Subsequent treatment of concentrated product
- B03D1/10—Removing adhering liquid from separated materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0002—Preliminary treatment
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0002—Preliminary treatment
- C22B15/0004—Preliminary treatment without modification of the copper constituent
- C22B15/0008—Preliminary treatment without modification of the copper constituent by wet processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C2201/00—Details of magnetic or electrostatic separation
- B03C2201/20—Magnetic separation whereby the particles to be separated are in solid form
Definitions
- the present invention relates to a method for separating at least one hydrophobic substance from a mixture comprising said at least one hydrophobic substance and at least one hydrophilic substance, and to the use of a solid, hydrophobic surface for separating at least one hydrophobic substance from the above-mentioned mixture.
- the invention comprises the separation of hydrophobic metal compounds, for example metal sulfides from a mixture of these hydrophobic metal compounds and hydrophilic metal oxides for ore enrichment by means of a hydrophobic surface.
- Flotation is a separation process in which water-dispersed or suspended substances are transported by adhering gas bubbles to the water surface where they are removed with a clearing device.
- air is introduced into the flotation bath and finely distributed.
- the hydrophobic particles, such as sulfidic ores, are difficult to wet with water and therefore adhere to the air bubbles. So these particles are carried by the air bubbles to the surface of the pool and can be skimmed off with the foam.
- a disadvantage of this process is that the air bubbles often lose their ballast on the way up. So that a sufficient yield can be obtained at all, chemical additives, for example xanthates, are added, which are intended to subsequently hydrophobicize the ore particles more strongly.
- the constant import in air is also associated with a high risk potential.
- the above-mentioned disadvantage could be circumvented in the so-called magnetic flotation.
- the sulfidic ore constituents are specifically coupled or coupled to magnetic particles in this method.
- a magnetic field is applied and the magnetic constituents containing the desired ore constituents are thus separated from the non-magnetic constituents.
- US 4,657,666 describes an ore enrichment method in which the hydrophobic magnetic particle selectively adheres to the hydrophobic sulfide ore.
- the magnetic particle is selected from magnetite or other magnetic iron oxides previously hydrophobized by attachment to silanes.
- the sulphidic ore is rendered hydrophobic with a mixture of flotation agents / collector agents in the presence of the oxidic gangue.
- the magnetic particle is separated from the ore by treatment with 50 vol .-% H 2 O 2 solution.
- US 4,906,382 discloses a process for the enrichment of sulfidic ores in which they are stirred with magnetic pigments modified with bifunctional molecules.
- One of the two functional groups adheres to the magnetic core.
- the magnetic particles can be reversibly agglomerated by varying the pH.
- the magnetic particles can be used to concentrate sulfide ores.
- the magnetite or hematite particles are modified with carboxylic acids or functionalized alkanols.
- a disadvantage of the methods for ore enrichment described in the prior art is that high magnetic fields are required to efficiently separate the magnetized particles from the original mixture. For this complex, expensive devices are necessary. Furthermore, it must be ensured that the magnetic particle coupled to the ore remains stably connected during the flotation process and can be effectively separated again after the separation.
- step (A) preparing a slurry or dispersion of the mixture to be treated in at least one suitable dispersant, (B) contacting the slurry or dispersion of step (A) with at least one solid, hydrophobic surface to attach the at least one hydrophobic substance to be separated thereon,
- step (C) removing the at least one solid, hydrophobic surface, to which the at least one hydrophobic substance is attached from step (B), from the slurry or dispersion in which the at least one hydrophilic substance is contained and (D) separating the at least one hydrophobic substance from the solid, hydrophobic surface.
- the method according to the invention serves to separate at least one hydrophobic substance from a mixture comprising this at least one hydrophobic substance and at least one hydrophilic substance.
- hydrophobic means that the corresponding surface can be hydrophobic on its own or can subsequently be hydrophobicized It is also possible for a hydrophobic surface to be additionally hydrophobicized.
- the at least one hydrophobic substance is at least one hydrophobic metal compound or carbon
- the at least one hydrophilic substance is preferably at least one hydrophilic metal compound.
- the process is used in particular for separating sulfidic ores from a mixture comprising these sulfidic ores and at least one hydrophilic metal compound selected from the group consisting of oxidic metal compounds.
- the at least one hydrophobic metal compound is preferably selected from the group consisting of sulfidic ores.
- the at least one hydrophilic metal compound is preferably selected from the group consisting of oxidic metal compounds.
- sulfidic ores which can be used according to the invention are selected, for example, from the group of copper ores consisting of chalcopyrite (copper pyrites) CuFeS 2 , bornite Co 5 FeS 4 , chalcocite (copper gloss) Cu 2 S and mixtures thereof.
- Suitable oxidic metal compounds which can be used according to the invention are preferably selected from the group consisting of silicon dioxide SiO 2 , preferably hexagonal modifications, feldspars, for example albite Ma (Si 3 Al) O 8 , mica, for example muscovite KAl 2 [(OH, F) 2 AISi 3 Oi 0 ], and mixtures thereof.
- untreated ore mixtures which are obtained from mine deposits are preferably used in the process according to the invention.
- an ore mixture to be used according to the invention to be separated prior to the process according to the invention is ground to a particle size ⁇ 100 ⁇ m, more preferably ⁇ 60 ⁇ m.
- Preferably usable ore mixtures have a content of sulfidic minerals of at least 0.4 wt .-%, particularly preferably at least 10 wt .-%, on. Examples of sulphidic minerals which are present in the ore mixtures which can be used according to the invention are those mentioned above.
- sulfides of metals other than copper may also be present in the ore mixtures, for example sulfides of lead, zinc, molybdenum, PbS, ZnS and / or MoS 2 .
- oxidic compounds of metals and semimetals for example silicates or borates or other salts of metals and semimetals, for example phosphates, sulfates or carbonates, may be present in the ore mixtures to be treated according to the invention.
- a typically used ore mixture which can be separated by the method according to the invention, has the following composition: about 30 wt .-% SiO 2 , about 10 wt .-% Na (Si 3 AI) O 8 , about 3 wt. -% Cu 2 S, about 1 wt .-% MoS 2 , balance chromium, iron, titanium and magnesium oxides.
- the individual steps of the method according to the invention are described in detail below:
- Step (A) of the method according to the invention comprises preparing a slurry or dispersion of the mixture to be treated in at least one suitable solvent.
- Suitable dispersants are all dispersants suitable in which the mixtures to be treated are not completely soluble.
- Suitable dispersants for the preparation of the slurry or dispersion according to step (A) of the process according to the invention are selected from the group consisting of water, water-soluble organic compounds and mixtures thereof.
- the dispersant in step (A) is water.
- the amount of dispersant can be chosen according to the invention so that a slurry or dispersion is obtained which is readily stirrable and / or conveyable.
- the amount of mixture to be treated based on the total slurry or dispersion, is up to 100% by weight, more preferably 0.5 to 10% by weight, most preferably 1 to 5% by weight.
- the slurry or dispersion can be prepared according to the invention by all methods known to those skilled in the art.
- the mixture to be treated and the corresponding amount of dispersant or dispersant mixture are combined in a suitable reactor, for example a glass reactor, and devices known to those skilled in the art stirred, for example in a glass pan with a mechanically stirred paddle stirrer.
- a suitable reactor for example a glass reactor
- devices known to those skilled in the art stirred for example in a glass pan with a mechanically stirred paddle stirrer.
- At least one adhesion-improving substance may be added in addition to the mixture to be treated and the dispersing agent or dispersing agent mixture.
- adhesion-enhancing substances are long and short-chain amines, ammonia, long-chain alkanes and long-chain, unbranched alcohols.
- the slurry or dispersion dodecylamine is added, the amount, based on the dry ore and magnetic particle amount, preferably 0.1 to 0.5 wt .-%, particularly preferably 0.3 wt .-% is.
- the optionally added adhesion-improving substance is generally added in an amount which is sufficient to ensure the adhesion-improving effect of this substance.
- the at least one adhesion-improving substance is added to 0.01 to 10 wt .-%, particularly preferably 0.05 to 0.5 wt .-%, each based on the total slurry or the dispersion.
- the at least one hydrophobic substance present in the mixture is hydrophobicized with at least one substance before step (B) of the process according to the invention.
- the hydrophobing of the at least one hydrophobic substance can be carried out before step (A), i. before preparing the slurry or dispersion of the mixture to be treated.
- step (A) i. before preparing the slurry or dispersion of the mixture to be treated.
- the hydrophobic substance it is also possible for the hydrophobic substance to be separated to be hydrophobized after preparing the slurry or dispersion according to step (A).
- the mixture to be treated is rendered hydrophobic before step (A) with a suitable substance.
- hydrophobizing substance all substances which are capable of further hydrophobicizing the hydrophobic metal compound to be separated off at the surface thereof.
- the hydrophobizing reagent is generally composed of a radical and an anchor group, wherein the anchor group preferably has at least 1, more preferably 3 reactive groups which interacts with the hydrophobic substance to be separated, preferably the hydrophobic metal compound to be separated.
- Suitable anchor groups are phosphonic acid groups or thiol groups.
- the hydrophobizing substances are selected from the group consisting of phosphorus-containing compounds of the general formula (I)
- R 1 is hydrogen or branched or unbranched dC 2 o-alkyl radical, C 2 -C 20 -
- R 3 branched or unbranched Ci-C 20 alkyl, C 2 -C 20 alkenyl, C 5 -C 20 -
- Aryl or heteroaryl radical preferably C 2 -C 20 -alkyrest
- R 2 is hydrogen, or branched or unbranched dC 20 alkyl, C 2 -C 20 -
- octylphosphonic acid is used, ie in general formula (I), R 1 is C 8 -alkyl and R 2 is OH.
- hydrophobicizing compounds are added individually or in admixture with each other in an amount of 0.01 to 50 wt .-%, particularly preferably 0.1 to 50 wt .-%, based on the mixture to be treated.
- These hydrophobicizing substances can be applied to the hydrophobic substance to be separated off, preferably the at least one metal compound to be separated off, by all methods known to the person skilled in the art.
- the mixture to be treated is ground and / or stirred with the appropriate amount of hydrophobizing substance, for example in a planetary ball mill. Suitable devices are known in the art.
- Step (B) of the process according to the invention comprises contacting the slurry or dispersion from step (A) with at least one solid, hydrophobic surface for attaching the at least one hydrophobic substance to be separated, preferably the at least one metal compound to be separated to the solid, hydrophobic surface.
- solid hydrophobic surface means that a surface is used which is hydrophobic and which either represents a one-piece surface, for example a plate or a treadmill, or which is the sum of the surfaces of many moving particles, for example the individual surfaces represents a variety of balls. Combinations of these designs are possible.
- the solid, hydrophobic surface is the inner wall of a tube, the surface of a plate, the tread or fixed surface of a treadmill, the inner wall of a reactor, the surface of three-dimensional bodies added to the slurry or dispersion. More preferably, the solid, hydrophobic surface is the inner wall of a reactor or the solid or mobile hydrophobic surface of a treadmill having fibrous micro 3D structures on the surface.
- a solid, hydrophobic surface is used, which is hydrophobic per se by the material which forms the solid, hydrophobic surface.
- hydrophobic surfaces which are not hydrophobic by themselves are applied by applying at least one hydrophobic layer.
- a solid surface made of metal, plastic, glass, wood or metal alloys is rendered hydrophobic by applying a hydrophobic compound, which is optionally surface-coated with suitable substances.
- this surface consisting of hydrophobic compounds is inherently hydrophobic enough to be used in the process according to the invention.
- the application of the hydrophobic layer can be done, for example, by vapor deposition.
- all the hydrophobic materials known to those skilled in the art, which are suitable for forming a corresponding hydrophobic layer can be used to form this hydrophobic layer.
- a hydrophobic layer is a layer that has no polar groups and therefore has a water-repellent character.
- Examples of suitable compounds are bifunctional compounds which adhere with the one functional group on the solid surface by a covalent or coordinate bond and adhere to the other hydrophobic functional group on the ore by a covalent or coordinative.
- groups which bind to the inorganic compound are the carboxyl group -COOH, the phosphonic acid group -PO 3 H 2 , the trihalosilyl group -SiHaI 3 with HaI independently of one another F, Cl, Br, I, trialkoxysilyl group -Si ( oR 5) 3 wherein R 5 is independently d-Ci 2 -alkyl and / or C 2 -C 2 -alkenyl.
- n 1 to 25, X independently of one another S or O, and
- R 6 branched or unbranched Ci-Cio-alkyl radical, ammonium, monovalent
- Metal cation for example alkali metal cation mean.
- R 6 denotes ammonium or a monovalent metal cation
- R 6 denotes ammonium or a monovalent metal cation
- the binding to the ore preferably takes place via a group of the general formula (IIIa)
- n 2 to 20 and R 6 is branched or unbranched dC 5 -alkyl radical.
- the solid, hydrophobic surface is the surface of a continuous treadmill which is agitated by the slurry or dispersion containing the mixture to be treated.
- the surface of the treadmill can be increased in a preferred embodiment by methods known in the art, for example by applying a three-dimensional structure on the treadmill.
- An example of such a three-dimensional structure are fibers attached to the surface of the treadmill.
- the treadmill can be made of any materials known and suitable to those skilled in the art, for example polymers such as polyethylene terephthalate, metallic materials such as aluminum, multi-component materials such as aluminum alloys.
- the fibers may also be of any suitable and suitable materials known to those skilled in the art.
- Step (C) of the method according to the invention comprises removing the at least one solid, hydrophobic surface to which the at least one hydrophobic substance, preferably the at least one hydrophobic metal compound is attached from step (B), from the slurry or dispersion in which the at least one a hydrophilic substance is included.
- the hydrophobic metal to be separated preferably the hydrophobic metal compound to be separated, is at least partially attached to the hydrophobic solid surface.
- the hydrophilic substance present in the mixture to be treated remains in the slurry or dispersion because it does not bind to the hydrophobic surface.
- Removal of the loaded, hydrophobic, solid surface may be accomplished by any method known to those skilled in the art. For example, a plate having the hydrophobic solid surface may be lifted out of a bath containing the slurry or dispersion. Furthermore, it is possible according to the invention that the hydrophobic, solid surface is mounted on a treadmill which moves through the slurry or dispersion. When the hydrophobic solid surface is attached to the inside of a pipe or reactor, in a preferred embodiment, the slurry or dispersion is passed through the reactor or through the pipe. Removal of the solid, hydrophobic surface thus occurs by passing the slurry or dispersion past this surface. It is also possible according to the invention that if the hydrophobic solid surface is the inner wall of a reactor, the removal of this hydrophobic, solid surface is effected by draining the slurry or dispersion to be treated from the reactor. Step (D):
- Step (D) comprises separating the at least one hydrophobic material, preferably the at least one hydrophobic metal compound, from the solid, hydrophobic surface.
- step (C) the hydrophobic, solid surface with the hydrophobic substance to be separated from the reaction mixture to be treated, at least partially laden.
- This separation can be carried out by any of the methods known to those skilled in the art, which are suitable for separating the hydrophobic substance from the surface mentioned without impairing either the hydrophobic substance and / or the surface.
- the separation in step (D) of the process according to the invention is carried out by treating the solid, hydrophobic surface with a substance selected from the group consisting of organic solvents, basic compounds, acidic compounds, oxidizing agents, surface-active compounds and mixtures thereof.
- organic solvents examples include methanol, ethanol, propanol, for example n-propanol or isopropanol, aromatic solvents, for example benzene, toluene, xylenes, ethers, for example diethyl ether, methyl t-butyl ether and mixtures thereof.
- Examples of basic compounds which can be used according to the invention are aqueous solutions of basic compounds, for example aqueous solutions of alkali metal and / or alkaline earth metal hydroxides, for example KOH, NaOH, aqueous ammonia solutions, aqueous solutions of organic amines of the general formula R 7 3N, where R 7 is selected from the group consisting of Ci-C 8 alkyl, optionally substituted with further functional groups.
- the acidic compounds may be mineral acids, for example, HCl, H 2 SO 4 , HNO 3 or mixtures thereof, organic acids, for example carboxylic acids.
- H 2 O 2 can be used as the oxidizing agent, for example as a 30% strength by weight aqueous solution (perhydrol).
- Examples of surface-active compounds which can be used according to the invention are nonionic, anionic, cationic and / or zwitterionic surfactants.
- the hydrophobic solid surface, to which the hydrophobic material to be separated is attached is washed with an organic solvent, more preferably with acetone, to form the hydrophobic substance separated from the hydrophobic, solid surface.
- an organic solvent more preferably with acetone
- This process can also be supported mechanically.
- the organic solvent or another separation reagent mentioned above is applied with pressure on the hydrophobic surface which is loaded with the hydrophobic ore.
- ultrasound may be used to assist the separation process, if appropriate in addition.
- the organic solvent is used in an amount sufficient to dissolve as much as possible of the entire adhering to the hydrophobic surface amount of the hydrophobic metal compounds thereof.
- 20 to 100 ml of the organic solvent is used per gram of hydrophobic and hydrophilic fabric to be purified. It is preferred according to the invention that the hydrophobic solid surface is treated with several smaller portions, for example two portions of the organic solvent, which together give said total amount.
- the hydrophobic substance to be separated is present as a slurry or dispersion in said organic solvent.
- the hydrophobic substance may be separated from the organic solvent by any of the methods known to those skilled in the art, for example decanting, filtering, distilling off the organic solvent or settling the solids at the bottom of the container, after which the ore may be skimmed off at the bottom.
- the hydrophobic substance to be separated off preferably the hydrophobic metal compound to be separated, is separated from the organic solvent by filtration.
- the hydrophobic substance obtainable in this way can be purified by further methods known to the person skilled in the art.
- the solvent can, if appropriate after purification, be recycled back to the process according to the invention.
- the hydrophobic solid surface from which the hydrophobic substance has been separated in step (D) is dried.
- This drying may be carried out by any method known to the person skilled in the art, for example by treatment in an oven at a temperature of, for example, 30 to 100 ° C.
- the hydrophobic, solid surface, which has optionally been dried is re-introduced into the oven Inventive process returned, ie used again in step (B) of the method according to the invention.
- the method according to the invention can be carried out so that the treadmill is continuously passed through the slurry or dispersion to be treated, treated with a solvent to separate the hydrophobic particles, dried, and returned to the bath to be treated.
- the present invention also relates to the use of a solid, hydrophobic surface for separating at least one hydrophobic substance, preferably a hydrophobic metal compound or carbon, from a mixture comprising said at least one hydrophobic substance and at least one hydrophilic substance, preferably at least one hydrophilic metal compound.
- a solid, hydrophobic surface for separating at least one hydrophobic substance, preferably a hydrophobic metal compound or carbon, from a mixture comprising said at least one hydrophobic substance and at least one hydrophilic substance, preferably at least one hydrophilic metal compound.
- FIG. 1 shows a particularly preferred embodiment of the method according to the invention, in which a continuous treadmill is used as the hydrophobic solid surface.
- the numerals have the following meanings:
- Separating agent for example organic solvent
- FIG. 2 shows an enlarged detail of the treadmill in the mixture of at least one hydrophobic substance and at least one hydrophilic substance with the following meaning
- Example: A 100 mL beaker is so coated with hydrophobized magnetite (surface-coated with 1-dodecyltriclosilan, wherein 1 nm 2 magnetite surface is loaded with about 10 to 50 molecules of trichlorosilane, diameter of magnetite particles 10 nm), that has an area on the walls of about 40 cm 2 is hydrophobic.
- the recovered amount of Cu 2 S corresponds to a relative amount of 76%.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08785971A EP2171106B1 (en) | 2007-07-17 | 2008-07-08 | Method for ore enrichment by means of hydrophobic, solid surfaces |
PL08785971T PL2171106T3 (en) | 2007-07-17 | 2008-07-08 | Method for ore enrichment by means of hydrophobic, solid surfaces |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP07112607 | 2007-07-17 | ||
EP08785971A EP2171106B1 (en) | 2007-07-17 | 2008-07-08 | Method for ore enrichment by means of hydrophobic, solid surfaces |
PCT/EP2008/058854 WO2009010422A1 (en) | 2007-07-17 | 2008-07-08 | Method for ore enrichment by means of hydrophobic, solid surfaces |
Publications (2)
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EP2171106A1 true EP2171106A1 (en) | 2010-04-07 |
EP2171106B1 EP2171106B1 (en) | 2011-09-14 |
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EP08785971A Not-in-force EP2171106B1 (en) | 2007-07-17 | 2008-07-08 | Method for ore enrichment by means of hydrophobic, solid surfaces |
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US (1) | US8408395B2 (en) |
EP (1) | EP2171106B1 (en) |
JP (1) | JP5496091B2 (en) |
CN (1) | CN101778957B (en) |
AR (1) | AR067567A1 (en) |
AT (1) | ATE524567T1 (en) |
AU (1) | AU2008277789B2 (en) |
BR (1) | BRPI0814075A2 (en) |
CA (1) | CA2693902C (en) |
CL (1) | CL2008002113A1 (en) |
ES (1) | ES2373621T3 (en) |
PE (1) | PE20090667A1 (en) |
PL (1) | PL2171106T3 (en) |
PT (1) | PT2171106E (en) |
UA (1) | UA99623C2 (en) |
WO (1) | WO2009010422A1 (en) |
ZA (1) | ZA201001077B (en) |
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WO2009010422A1 (en) | 2009-01-22 |
ATE524567T1 (en) | 2011-09-15 |
US20100200510A1 (en) | 2010-08-12 |
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CL2008002113A1 (en) | 2009-10-23 |
RU2010105290A (en) | 2011-08-27 |
PT2171106E (en) | 2011-10-06 |
AU2008277789B2 (en) | 2012-05-03 |
EP2171106B1 (en) | 2011-09-14 |
ZA201001077B (en) | 2011-04-28 |
JP5496091B2 (en) | 2014-05-21 |
ES2373621T3 (en) | 2012-02-07 |
PE20090667A1 (en) | 2009-07-04 |
UA99623C2 (en) | 2012-09-10 |
JP2010534554A (en) | 2010-11-11 |
BRPI0814075A2 (en) | 2015-02-03 |
CN101778957B (en) | 2012-07-04 |
US8408395B2 (en) | 2013-04-02 |
CN101778957A (en) | 2010-07-14 |
PL2171106T3 (en) | 2012-02-29 |
CA2693902C (en) | 2016-06-28 |
AU2008277789A1 (en) | 2009-01-22 |
CA2693902A1 (en) | 2009-01-22 |
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