EP2101573A2 - Improvement of the biological action of agrochemical compositions when applied to the cultivation substrate, suitable formulations and use thereof - Google Patents

Abstract

The action of agricultural pesticides containing active ingredients from the class of insecticidal phthalic acid diamides can be improved by adjuvants when applied to the ground. The invention relates to corresponding methods and suitable compositions.

Description

 Improvement of the biological effect of agrochemical compositions when applied to the culture substrate, suitable formulations and their application

The present invention relates to the improvement of the action of agrochemical compositions in soil application, the agrochemical compositions suitable for this application, and their use for control of noxious insects.

Agrochemical active substances can be applied in different ways for controlling harmful organisms. In addition to the foliar treatment, a treatment of the culture substrate can also be carried out. This may be soil, but also special substrates u.a. based on peat moss, coconut fiber, rock wool, e.g. Grodan®, pumice, expanded clay, e.g. Lecaton® or Lecadan®, clay granules, e.g. Seramis®, foams, e.g. Baystrat®, vermiculite, perlite, man-made earth, e.g. Hygromull®, or combinations of these substrates. All of these culture substrates are referred to below as soil. By applying active ingredients in or on the soil, both soil-borne pests are brought into contact with the active ingredient and the uptake of systemic agents by the roots is initiated. There are already a variety of tools known to improve the effect of agrochemical drugs in foliar treatment. These include, for example, penetration enhancers which facilitate penetration of the active ingredients into the plant (e.g., WO 03/000053). Corresponding adjuvants have not yet been described for the soil applications of insecticides and fungicides. Known is the influence of so-called "Soil Penetration Aids" which accelerate the penetration of irrigation water into dry soils (e.g., Agri-Prep® CS from Northwest Agricultural Products).

It is also known that surfactants can affect the distribution of permethrin in soil (Howell, McMullan PM (ed.), 1998, Adjuvante for Agrochemicals, Proceedings of the 5th International Symposium on Adjuvants for Agrochemicals, Memphis, USA, pp. 247-253 ).

Improvements of herbicidal agents by optimized formulations have also been described (Chung et al., Pesticide Science, 1993, 38 (2-3), pp. 250-252).

It has now surprisingly been found that the biological effect of soil-insect insecticidal compositions can be improved when these compositions contain an adjuvant. The adjuvant may either be already part of the concentrated formulation (in-can formulation) or added in the course of the preparation of the ready-to-use pesticide solution (tank mix application). The improved effect occurs both in the control of soil organisms and in the control of leaf pests or leaf diseases caused by the systemic Active ingredients are combated. ^"""In this way, the application rate an improved effect can be achieved by the compositions of this invention can be reduced to active substance or the same application rate. In addition, the water consumption can be minimized.

The subject of the present invention is therefore the use of adjuvants to improve the action of soil agrochemical compositions, e.g. by spraying on the floor, casting, side-dressing, shower-drenching, overhead drenching or application as part of an irrigation system (drip irrigation).

New suspension concentrates for this use have now been found containing

- At least one solid at room temperature agrochemical active ingredient from the group

Insecticides phthalic diamides,

at least one adjuvant,

In addition to concentrated formulations, the invention also relates to dilute, ready-to-use compositions. The invention furthermore relates to the use of these compositions for combating soil-borne harmful organisms and leaf pests.

An adjuvant in the context of the present invention is a substance which causes an improvement in the biological activity in the test system described below:

Young corn plants are planted in 1 liter containers with soil (sandy loam soil, 10% by weight moisture, pH 6.7). The plants grow in the glasshouse at 20 ⁰ C for 3 or 12

Days (to the 2- or 3-leaf stage) before casting. In this case, 0.25 mg or 0.5 mg of the insecticidal active ingredient (S) -3-chloro-N '- {2-methyl-4- [l, 2,2,2-tetrafluoro-l-

(trifluoromethyl) ethyl] phenyl} -N ² - (1-methyl-2-methylsulfonylethyl) phthalamide (known from WO

06/22225) and 60 mg of potential adjuvant in an Angiess volume of 60 ml. 1, 3, 7 or 14 days after casting the plants by placing larvae of the

Stage L2 of Spodoptera frugiperda infected and determined their mortality after every 7 days. As a control, the same test is performed without the addition of a potential adjuvant. When using the adjuvant according to the invention shows in this test increased mortality compared to the control. The mortality is not necessarily increased at any time, it can also only an improvement of the initial effect or the

Long-term effect occur. As examples of adjuvants according to the invention, mention may be made in particular of the following substances and compositions:

(1-1) dioctyl sodium sulfosuccinate, commercially available e.g. in the Geropon® product line,

(1-2) Compositions containing dioctyl sodium sulfosuccinate and sodium benzoate, available commercially, e.g. in the Aerosol® product line; preferably that is

Weight ratio of dioctyl sodium sulfosuccinate: sodium benzoate 5: 1 to 6: 1,

(1-3) End-capped alkoxylated fatty alcohols and end-capped alkoxylated straight-chain alcohols, commercially available e.g. in the Plurafac® product line; preferred are ethoxylated and / or butoxylated fatty alcohols and end-capped ethoxylated and / or butoxylated straight-chain alcohols,

(1-4) Tributylphenol polyglycol ethers having 10 to 15 EO units (where EO is ethylene oxide), commercially available e.g. in the Sapogenat® product line,

(1-5) Polyalkylene oxide-modified polymethylsiloxanes, commercially available e.g. in the Silwet ® range,

(1-6) Branched alkanol alkoxylates of the formula CH ₃ - (CH ₂ ), - CH ₂ -O - (- CH ₂ -CH ₂ -O-) _u -H, in which t is from 9 to 10, 5 and u are numbers from 6 to 25 (preferably from 8 to 12) and t and u represent average values, commercially available, for example in the Lutensol® product range,

(1-7) Betaine,

(1-8) polyalkoxylated triglycerides, wherein the triglyceride is preferably of vegetable origin, commercially available e.g. in the product line Crovol ®,

(1-9) Alkoxylated fatty amines, commercially available e.g. in the product range Armoblen®,

(1-10) Sodium laureth sulfate, commercially available e.g. in the product line Genapol ®,

(1-11) PEG-10 coconut alcohol, commercially available e.g. in the product line Genapol ®,

(1-12) Compositions comprising corn syrup, methylated soybean oil and nonionic emulsifier, commercially available e.g. in the Süperb® product range.

Phthalic diamides are known as compounds having insecticidal properties (cf., EP-A-0 919 542, EP-A-006 107, WO 01/00575, WO 01/00599, WO 01/46124, JP-A 2001-33 555 9, WO 01/02354, WO 01/21 576, WO 02/08 8074, WO 02/08 8075, WO 02/09 4765, WO 02/09 4766, WO 02/06 2807).

Such phthalic diamides are described by the formula (II):

in which

X ^B is halogen, cyano, Q-Cg-alkyl, C _r C ₈ haloalkyl, C _r C ₈ -alkoxy or C _r C ₈ - haloalkoxy,

R ^1B , R ^2B and R ^{3B are} independently hydrogen, cyano, optionally substituted by

Halogen substituted C ₃ -C ₈ cycloalkyl or for the group stand,

M represents optionally substituted achiral Cj-Cn-alkylene, achiral C ₃ -C ₂ alkenylene or C ₃ -C achiral is ₂ alkynylene,

Q ^B is hydrogen, halogen, cyano, nitro, C _r C ₈ haloalkyl, each optionally substituted C ₃ -C ₈ -Cyloalkyl, Ci-Cg--alkyl-carbonyl or Ci-Cg-alkoxy-carbonyl, ^4B respectively T§_R optionally substituted phenyl, hetaryl or represents the group,

T ^{B is} oxygen, -S (O) _n , - or -N (R ^5B > -,

R ^4B represents hydrogen, in each case optionally substituted d-Cu-alkyl, C ₃ -C ₂ -alkenyl, C ₃ - C n -alkynyl, C ₃ -C ₈ cycloalkyl, C ₃ -C ₈ cycloalkyl-C, -C ₆ -alkyl, C 1 -C ₆ -alkoxy-C 1 -C ₄ -alkyl, C 1 -C ₄ -alkylcarbonyl, C 1 -C ₈ -alkoxycarbonyl, phenyl, phenyl-C 1 -C 12 -alkyl, phenylC _r C ₄ -alkoxy, hetaryl, hetaryl-C _r C ₄ -alkyl,

R ^{5B is} hydrogen, each optionally substituted Q-Cg-alkyl-carbonyl, C] -C ₈ -alkoxycarbonyl, phenyl-carbonyl] or phenyl-Cj-C ₆ -alkoxycarbonyl, k is 1, 2, 3, or 4,

m is 0, 1 or 2,

R ^1B and R ²⁸ together form an optionally substituted 4- to 7-membered ring which may optionally be interrupted by heteroatoms,

L ^1B and L ^{3B are} independently hydrogen, halogen, cyano or in each case optionally substituted C _r C ₈ alkyl, C, -C ₈ alkoxy, Ci-C ₆ alkyl -S (O) _m -, phenyl, phenoxy or Hetaryloxy stand,

L ²⁸ is hydrogen, halogen, cyano, optionally substituted C _r Ci ₂ -alkyl, C ₂ - _{C] 2} alkenyl, _C2-Ci2 alkynyl, C _{r C] 2} haloalkyl, C ₃ -C ₈ - cycloalkyl, phenyl, hetaryl M2B_ _R 6B or the group ^M is ^κ,

M ^{2B is} oxygen or -S (O) _n , -,

R ^{6B is} in each case optionally substituted C 1 -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₃ -C ₆ -alkynyl C ₃ -C 9 -cycloalkyl, phenyl or hetaryl,

L ^1B and L ^3B or L ^IB and L ^2B each together form an optionally substituted 5- to 6-membered ring which may optionally be interrupted by heteroatoms,

The phthalic diamides of the acaricidal and / or insecticidal agents are generally defined by the formula (II). Preferred substituents or ranges of the radicals listed in the formulas mentioned above and below are explained below:

X ^B is preferably fluorine, chlorine, bromine, iodine, cyano, C _r C ₆ alkyl, C _r C ₆ haloalkyl, C ₁ - Cβ-alkoxy or Ci-C ₆ haloalkoxy.

R ^IB , R ^2B and R ^3B independently of one another preferably represent hydrogen, cyano, for

optionally halogen-substituted C ₃ -C ₆ -cycloalkyl or the group ,

M ^1B preferably represents achiral C _r C ₈ -alkylene, achiral C ₃ -C ₆ -alkenylene or achiral C ₃ - C ₆ -alkynylene.

Q ^B preferably represents hydrogen, halogen, cyano, nitro, C _r C ₆ haloalkyl or optionally substituted by fluorine, chlorine, Ci-C ₆ alkyl, or C) -C ₆ -alkoxy-substituted C ₃ -C ₈ - cycloalkyl, in which optionally one or two not directly adjacent ring members are replaced by oxygen and / or sulfur or for each optionally substituted by halogen C _r C ₆ alkylcarbonyl or C _r C ₆ alkoxycarbonyl or in each case optionally by halogen, Ci-C ₆ alkyl, C _r C ₆ -Haloalkyl, C _r C ₆ alkoxy, C _r C ₆ - haloalkoxy, cyano or nitro-substituted phenyl or hetaryl having 5 to 6 ring atoms (for example, furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, -pB_ _R 4B

Thiazolyl or thienyl) or for the group.

T ^B is preferably oxygen, -S (O) _n , - or -N (R ^5B > -.

R ^4B preferably represents hydrogen, in each case optionally fluorine- and / or chlorine-substituted C 1 -C ₈ -alkyl, C ₃ -C ₈ -alkenyl, C ₃ -C ₈ -alkynyl, C ₃ -C ₈ -cycloalkyl, C ₃ -C ₈ - cycloalkyl-Ci-C ₂ alkyl, QC _ö alkyl-carbonyl, C] _-C6 alkoxy-carbonyl, represents in each case optionally mono- to tetrasubstituted by halogen, C] _-C6 alkyl, Ci Cβ alkoxy, C ₁ -C ₄ - haloalkyl, C | -C ₄ haloalkoxy, nitro or cyano-substituted phenyl, phenyl-Q-C ₄ alkyl, phenyl-C _r C ₄ alkoxy, hetaryl or hetaryl-Ci C ₄ alkyl, wherein hetaryl has 5 to 6 ring atoms (for example, furanyl, pyridyl, imidazolyl, triazolyl, pyrazolyl, pyrimidyl, thiazolyl or thienyl).

R ^5B preferably represents hydrogen, in each case optionally substituted by fluorine and / or chlorine Ci-Cβ-alkyl-carbonyl, Ci-Cβ-alkoxycarbonyl, in each case optionally monosubstituted to fourfold by halogen, C _r C ₆ alkyl, Ci -C ₆ -alkoxy, C _r C ₄ -haloalkyl, C _r

C ₄ haloalkoxy, nitro or cyano-substituted phenyl-carbonyl or phenyl-C _r C ₄ - alkyloxycarbonyl.

k is preferably 1, 2 or 3.

m is preferably 0, 1 or 2.

R ^IB and R ^2B together preferably form a 5- to 6-membered ring which may optionally be interrupted by an oxygen or sulfur atom.

^IB L and L ^3B are each independently preferably represents hydrogen, cyano, fluorine, chlorine, bromine, iodine, C _r C ₆ alkyl, C _r C ₄ haloalkyl, C _r C ₆ alkoxy, C _r C ₄ haloalkoxy, C _r C ₄ - alkyl-S (O) _m -, C ₄ haloalkyl-S (O) _m -, in each case optionally mono- to trisubstituted by fluorine, chlorine, bromine, C _r C ₆ alkyl, C -C ₆ alkoxy, C, -C ₄ haloalkyl, C ₁ -C ₄ - haloalkoxy, cyano or nitro-substituted phenyl, phenoxy, Pyrdinyloxy, thiazolyloxy or pyrimidinyloxy. L ^2B preferably represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, in each case optionally substituted by fluorine and / or chlorine-substituted Ci-Cio-alkyl, C ₂ -C ₁₀ alkenyl, C ₂ -C ₆ - alkynyl, for in each case optionally substituted by fluorine, chlorine-substituted C ₃ -C ₆ cycloalkyl, in each case optionally mono- to trisubstituted by fluorine, chlorine, bromine, Ci-C ₆ alkyl, CpC ₆ - alkoxy, C _r C ₄ haloalkyl, CpC ₄ - Haloalkoxy, cyano or nitro substituted M? B_ _R 6B

Phenyl, pyridinyl, thienyl, pyrimidyl or thiazolyl, or for the group.

M ^2B is preferably oxygen or -S (O) _n , -.

R ^6B preferably represents in each case optionally fluorine- and / or chlorine-substituted Cp

C ₁ -C ₄ -alkyl, C ₂ -C ₈ -alkenyl, C ₃ -C ₆ -alkynyl or C ₃ -C ₆ -cycloalkyl, in each case optionally monosubstituted to trisubstituted by fluorine, chlorine, bromine, C ₁ -C ₆ -alkyl, CpC ₆ -alkoxy, CpC ₄ -HaIo- genalkyl, CpC ₄ -haloalkoxy, cyano or nitro-substituted phenyl, pyridyl,

Pyrimidinyl or thiazolyl.

L ^1B and L ^3B or L ^1B and L ^2B together preferably each form a 5- to 6-membered ring which is optionally substituted by fluorine and / or CpC ₂ -alkyi and which may optionally be interrupted by one or two oxygen atoms.

X ^B particularly preferably represents chlorine, bromine and iodine.

R ^1B , R ^2B and R ^3B independently of one another particularly preferably represent hydrogen or

, .1B -, B

Group ^κ .

M ^1B particularly preferably represents achiral CpCg-alkylene, achiral C ₃ -C ₆ -alkenylene or achiral C ₃ -C ₆ -alkynylene.

Q ^B particularly preferably represents hydrogen, fluorine, chlorine, cyano, trifluoromethyl, C ₃ -C ₆ -

Cycloalkyl or for the group ,

T ^B particularly preferably represents oxygen or -S (O) _n , -.

R ^4B particularly preferably represents hydrogen, in each case optionally mono- to trisubstituted by fluorine and / or chlorine, CpC ₆ alkyl, C ₃ -C ₆ alkenyl, C ₃ -C ₆ alkynyl or

C ₃ -C ₆ cycloalkyl.

k is particularly preferred for 1. 2 or 3.

m is more preferably 0, 1 or 2. L ^1B and L ^3B independently of one another particularly preferably represent hydrogen, fluorine, chlorine,

Bromine, iodine, cyano, C, -C ₄ alkyl, C _r C ₂ -haloalkyl, Ci-C ₄ alkoxy, C, -C ₂ haloalkoxy, in each case optionally mono- to disubstituted by fluorine, chlorine, bromine, C _{r is} C ₄ -alkyl,

C _r C ₄ alkoxy, Ci-C ₂ haloalkyl, Ci-C ₂ -haloalkoxy, cyano or nitro-substituted phenyl or phenoxy.

L ^2B particularly preferably represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, in each case optionally monosubstituted to trisubstituted by fluorine and / or chlorine, C ₁ -C ₆ -MB _R 6B

Alkyl, C ₂ -C ₆ -alkenyl, C ₂ -C ₆ -alkynyl, C ₃ -C ₆ -cycloalkyl or for the group ^{M κ} .

M ^2B is particularly preferably oxygen or -S (O) _n , -.

R ^6B particularly preferably represents in each case optionally monosubstituted to trisubstituted by fluorine and / or chlorine QC _ö alkyl, C ₂ -C ₆ alkenyl, C ₂ -Cβ alkynyl or C ₃ -C ₆ - cycloalkyl, in each case optionally mono- to disubstituted by fluorine, chlorine, bromine, Q C ₄ alkyl, C _r C ₄ alkoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano or nitro-substituted phenyl or pyridyl.

X ^B is most preferably iodine.

R ^1B and R ^2B are very particularly preferably hydrogen.

1 R R

R ^3B most preferably represents the group.

M ' ^B is very particularly preferably -C (CH ₃ ) ₂ CH ₂ - or -C (C ₂ Hj) ₂ CH ₂ -

Q ^B is very particularly preferably hydrogen, fluorine, chlorine, cyano, trifluoromethyl, C ₃ - TB_ _R 4B C ₆ -cycloalkyl or the group ' ^κ .

T ^B is very particularly preferably -S-, -SO- or -SO ₂ -.

R ^4B very particularly preferably represents in each case optionally mono- to trisubstituted by fluorine and / or chlorine, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl or tert-butyl, allyl, Butenyl or isoprenyl.

Independently of one another, L ^{1 B} and L ^3B very particularly preferably represent hydrogen, fluorine, chlorine, bromine, iodine, cyano, methyl, ethyl, n-propyl, isopropyl, tert-butyl, methoxy, ethoxy, trifluoromethyl, difluoromethoxy or trifluoromethoxy , L stands ^g anz particularly Favor ^g t represents hydrogen, fluorine, chlorine, bromine, iodine, cyano, represents in each case optionally substituted once to nine times by fluorine and / or chlorine-substituted methyl, ethyl, n-propyl, iso-propyl, n-butyl, iso-butyl, sec-butyl, tert-butyl, AHyI, M2B "6B

Butenyl or isoprenyl or for the group ^m .

M is most preferably oxygen or sulfur.

R ^6B very particularly preferably stands for in each case optionally up to nine times

Fluorine and / or chlorine-substituted methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, allyl, butenyl or isoprenyl, optionally once or twice by fluorine, chlorine, Bromine, methyl, ethyl, methoxy, trifluoromethyl, difluoromethoxy, trifluoromethoxy, cyano or nitro substituted phenyl.

In particular, the following compounds of the formula (II) may be mentioned in particular:

Table 1 :

No. X ^B _R 2B _R 3B L ^IB L ^2B _L 3B

II-1 IHH -C (CHj) ₂ CH ₂ SCH ₃ CH ₃ iso-C ₃ F ₇ H

II-2 IHH -C (CHJ) ₂ CH ₂ SOCH ₃ CH ₃ JSO-C ₃ F ₇ H

II-3 IHH -C (CH ₃ ) ₂ CH ₂ SO ₂ CH ₃ CH ₃ iso-C ₃ F ₇ H

In addition to at least one active substance and at least one adjuvant, the compositions according to the invention may preferably also contain further formulation auxiliaries:

at least one nonionic surfactant and / or at least one anionic surfactant one or more additives from the groups of antifreezes, antifoaming agents, preservatives, antioxidants, spreading agents, dyes and / or thickeners.

As examples of the further ingredients of the formulations according to the invention, mention may be made in particular of the following substances:

Suitable nonionic surfactants are all substances of this type conventionally usable in agrochemical compositions. Polyethylene oxide-polypropylene oxide block copolymers, polyethylene glycol ethers of linear alcohols, reaction products of fatty acids with ethylene oxide and / or propylene oxide, polyvinyl alcohol, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone, copolymers of polyvinyl acetate and polyvinylpyrrolidone and copolymers of (meth) acrylic acid and (meth ) acrylic acid esters, furthermore alkyl ethoxylates and alkylaryl ethoxylates, which may optionally be phosphated and optionally neutralized with bases, polyoxyamine derivatives and nonylphenol ethoxylates.

Suitable anionic surfactants are all substances of this type conventionally usable in agrochemical compositions. Preference is given to alkali metal and alkaline earth metal salts of alkylsulfonic acids or alkylarylsulfonic acids.

Another preferred group of anionic surfactants or dispersants are salts of polystyrenesulfonic acids, salts of polyvinylsulfonic acids, salts of naphthalenesulfonic acid-formaldehyde condensation products, salts of condensation products of naphthalenesulfonic acid, phenolsulfonic acid and formaldehyde and salts of lignosulfonic acid.

As antifreeze all commonly used in agrochemical agents substances of this type come into question. Preference is given to urea, glycerol, polyglycerol and polyglycerol derivatives, propanediol and propylene glycol.

Suitable foam-inhibiting substances are all substances customarily usable for this purpose in agrochemical compositions. Preferred are silicone oils and magnesium stearate.

Suitable preservatives are all substances customarily usable for this purpose in agrochemical compositions of this type. Examples which may be mentioned are Preventol® (Bayer AG) and Proxel®.

As antioxidants are all commonly used for this purpose in agrochemical agents substances into consideration. For example: propyl gallate, octyl gallate, Dodecyl gallate, butylated hydroxyanisole, propylparaben, sodium benzoate, 4,4 '- (2,3-dimethyltetramethylene) dibenzcatechin (Nordihydroguaiaretic acid) and butylhydroxytoluene. Preference is given to butylhydroxytoluene (2,6-di-t-butyl-4-methyl-phenol, BHT).

Suitable spreading agents are all substances customarily usable for this purpose in agrochemical compositions. Preference is given to polyether- or organo-modified polysiloxanes.

Suitable dyes are all substances customarily usable for this purpose in agrochemical compositions. Examples include titanium dioxide, carbon black, zinc oxide and blue pigments as well as permanent red FGR.

Suitable thickeners are all substances of this type conventionally usable in agrochemical compositions. Preference is given to silicates (such as, for example, Atagel® 50 from Engelhard) or xanthan gum (such as, for example, Kelzan® S from Kelko).

The preparation of the concentrated formulations according to the invention takes place in such a way that the components are mixed together in the respectively desired ratios. The order in which the ingredients are mixed together is arbitrary. Conveniently, one uses the solid components in a finely ground state. However, it is also possible first to subject the suspension formed after mixing the constituents to a coarse and then to a fine grinding so that the mean particle size is less than 20 μm. Preference is given to suspension concentrates in which the solid particles have an average particle size of between 1 and 10 μm.

The temperatures can be varied in carrying out the method according to the invention in a certain range. It generally works at temperatures between 10 ⁰ C and 60 ⁰ C, preferably between 15 ⁰ C and 40 ⁰ C.

For carrying out the process according to the invention, customary mixing and grinding devices which are used for the production of agrochemical formulations are suitable.

The compositions according to the invention are formulations which remain stable even after prolonged storage at elevated temperatures or in the cold, since no crystal growth is observed. They can be converted by dilution with water into homogeneous spray liquids. The application rate of the compositions according to the invention can be varied within a relatively wide range. It depends on the particular agrochemical active ingredients and their content in the compositions.

Compositions of the invention contain

- At least one active ingredient from the class of insecticides phthalic diamides and

- at least one adjuvant

In a preferred embodiment, compositions according to the invention contain:

at least one active ingredient selected from (II-1), (II-2) and (II-3)

at least one adjuvant,

In a particularly preferred embodiment, compositions according to the invention comprise:

at least one active ingredient selected from (II-1), (H-2) and (H-3)

at least one substance or composition selected from (H) to (1-12)

The compositions of the invention contain - when it comes to concentrated formulations

in general between 1 and 60% by weight of one or more of the agrochemically active compounds which can be used according to the invention, preferably 5 to 50% by weight and particularly preferably 10 to 30% by weight

generally between 1 and 50 wt .-% of at least one adjuvant of the invention, preferably 2 to 30 wt .-% and particularly preferably 5 to 20 wt .-%.

generally between 1 and 20% by weight of nonionic surfactants and / or anionic surfactants, preferably between 2.5 and 10% by weight,

generally between 1 and 20% by weight of antifreeze, preferably between 5 and 15% by weight,

- In general to additives between 0.1 and 20 wt .-%, preferably between

0.1 and 15 wt .-%. The compositions according to the invention generally contain between 0.05 and 10 g / l of adjuvant, preferably 0.1 to 8 g / l and more preferably 0.1 to 5 g / l, in the case of ready-to-use formulations (priming solutions).

Very particularly preferred concentrated formulations for soil application included

between 1 and 60% by weight of at least one active substance selected from (II-1), (II-2) and (II-3),

between 1 and 50% by weight of at least one substance or composition selected from (I-1) to (1-12),

between 1 and 20% by weight of at least one nonionic surfactant and / or anionic surfactant,

between 1 and 20 wt .-% antifreeze and

between 0.1 and 20% by weight of additives from the groups of foam-inhibiting agents, preservatives, antioxidants, spreading agents, dyes and / or thickeners.

In general, certain combinations of active ingredients and adjuvants are listed, which are listed in the following Table 2, each combination being preferred per se:

Very particular preference is likewise given to ready-to-use compositions for soil application which are formed by dilution of the abovementioned concentrated solutions. The compositions according to the invention are suitable with good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, nematodes and mollusks in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:

From the order of the Anoplura (Phthiraptera) e.g. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.

From the class of arachnids, e.g. Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp. , Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp. Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.

From the class of bivalva, e.g. Dreissena spp ..

From the order of Chilopoda e.g. Geophilus spp., Scutigera spp.

From the order Coleoptera eg Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp., Attagenus spp. Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, Melolontha melolontha, Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Popillia japonica, Premnotrypes spp., Psyl liodes chrysoccephala, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus Spp., Starchus spp., Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp.

From the order of Collembola e.g. Onychiurus armatus.

From the order of the Dermaptera e.g. Forficula auricularia.

From the order of diplopoda e.g. Blaniulus guttulatus.

From the order of Diptera e.g. Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysomyia spp., Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dermatobia hominis, Drosophila spp., Fannia spp. Gastrophilus spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp. Lucilia spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp., Stomoxys spp. Tabanus spp., Tannia spp., Tipula paludosa, Wohlfahrtia spp.

From the class Gastropoda, e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.

From the class of helminths e.g. Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp, Dictyocaulus filaria, Diphyllobothrium latum , Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosome spp, Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti.

Furthermore, protozoa, such as Eimeria, can be combated.

From the order of the Heteroptera eg Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp , Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.

From the order of Homoptera e.g. Acyrthosipon spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp , Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Doralis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp , Eriosoma spp., Erythroneura spp., Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis sacchari, Metcalfella spp., Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp. , Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, Sogatodes spp , Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Tri- aleurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii.

From the order of Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the order of isopods e.g. Armadillidium vulgaris, Oniscus asellus, Porcellio scaber.

From the order of Isoptera e.g. Reticulitermes spp., Odontotermes spp.

From the order of Lepidoptera, for example, Acronicta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp., Choristoneura fumiferana , Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoveφa spp., Heliothis spp., Hofinannophila pseudospretella, Homona magnanima, Hyponomeuta padella, Lophygma spp., Lithocolletis blancardella, Lithophane antennata, Loxagrotis albicosta, Lymantria spp., Malacosoma neustria, Mamestra brassicae, Mocis rep., Mythimna separata, Oria spp., Oulema oryzae , Panolis flammea, Pectinophora gossypiella, Phyllocnistis citrella, Pieris spp., Plutella xylostella, Prodenia spp., Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp. ,

From the order of Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotaipa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.

From the order of siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.

From the order of Symphyla e.g. Scutigerella immaculata.

From the order of Thysanoptera e.g. Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.

From the order of Thysanura e.g. Lepisma saccharina.

The plant parasitic nematodes include e.g. Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp. Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.

The compositions according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or agents for improving plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including anti-viral agents) or as anti-MLO agents ( Mycoplasma-like-organism) and RLO (Rickettsia-like-organism).

In addition to the previously mentioned agrochemical active ingredients, the compositions according to the invention may contain other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals as mixing partners. Particularly favorable mixing partners are, for example, the following:

fungicides:

Inhibitors of nucleic acid synthesis

Benalaxyl, benalaxyl-M, bupirimate, chiralaxyl, clozylacon, dimethirimol, ethirimol, furalaxyl, hymexazole, mefenoxam, metalaxyl, metalaxyl-M, ofurace, oxadixyl,

oxolinic

Inhibitors of mitosis and cell division

Benomyl, Carbendazim, Diethofencarb, Ethaboxam, Fuberidazole, Pencycuron, Thiabendazole, Thiophanate-methyl, Zoxamide

Inhibitors of the respiratory chain complex I

diflumetorim

Respiratory chain complex II inhibitors

Boscalid, Carboxin, Fenfuram, Flutolanil, Furametpyr, Furmecyclox, Mepronil, Oxycarboxin, Penthiopyrad, Thifluzamide

Inhibitors of the respiratory chain complex HI

Azoxystrobin, Cyazofamide, Dimoxystrobin, Enestrobin, Famoxadone, Fenamidon, Fluoxastrobin, Kresoximmethyl, Metominostrobin, Orysastrobin, Pyraclostrobin, Picoxystrobin, Trifloxystrobin

decoupler

Dinocap, fluazinam

Inhibitors of ATP production

Fentin acetate, fentin chloride, fentin hydroxide, silthiofam Inhibitors of amino acid and protein biosynthesis

Andoprim, blasticidin-S, cyprodinil, kasugamycin, kasugamycin hydrochloride hydrate, mepanipyrim, pyrimethanil

Inhibitors of signal transduction

Fenpiclonil, fludioxonil, quinoxyfen

Inhibitors of fat and membrane synthesis

Chlozolinate, iprodione, procymidone, vinclozolin

Ampropylfos, Potassium Ampropylfos, Edifenphos, Etridiazole, Iprobenfos (IBP), Isoprothiolane, Pyrazophos

Tolclofos-methyl, biphenyl

Iodocarb, propamocarb, propamocarb hydrochloride, propamocarb-fosetylate

Inhibitors of ergosterol biosynthesis

fenhexamid,

Azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutrazole, difenoconazole, diniconazole, diniconazole-M, epoxiconazole, etaconazole, fenarimol, fenbuconazole,

Fluquinconazole, flurprimidol, flusilazole, flutriafol, furconazole, furconazole-cis,

Hexaconazole, imazalil, imazalil sulfate imibenconazole, ipconazole, metconazole, myclobutanil,

Nuarimol, oxpoconazole, paclobutrazole, penconazole, pefurazoate prochloraz, propiconazole,

Prothioconazole, pyrifenox, simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triflumizole triforin, triticonazole, uniconazole, voriconazole, viniconazole,

Aldimorph, dodemoφh, dodemorphoacetate, fenpropidin, fenpropimorph, spiroxamine, tridemoφh,

Naftifine, pyributicarb, terbinafine

Inhibitors of cell wall synthesis Benthiavalicarb, Bialaphos, Dimethomorph, Flumoφh, Iprovalicarb, Mandipropamide, Polyoxins, Polyoxorim, Validamycin A

Inhibitors of melanin biosynthesis

Carpropamide, diclocymet, fenoxanil, phthalide, pyroquilon, tricyclazole

induction of resistance

Acibenzolar-S-methyl, probenazole, tiadinil

Multisite

Captafol, captan, chlorothalonil, copper salts such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulfate, copper oxide, oxine-copper and bordeaux mixture, dichlofluanid, dithianon, dodin, dodine free base, ferbam, folpet, fluorofolpet, guazatine,

Guazatine acetate, iminoctadine, iminoctadinal besylate, iminoctadine triacetate, mancopper, mancozeb, maneb, metiram, metiram zinc, propineb, sulfur and sulfur preparations containing calcium polysulphide, thiram, tolylfluanid, zineb, ziram

Other fungicides

Amibromdole, benthiazole, bethoxazine, capsimycin, carvone, quinomethionate, chloropicrin,

Cufraneb, Cyflufenamid, Cymoxanil, Dazomet, Debacarb, Diclomethine, Dichlorophene, Dicloran, Difenzoquat, Difenzoquat Methylsulphate, Diphenylamine, Ferimzone, Flumetover, Flusulfamide, Fluopicolide, Fluoroimide, Fosetyl-Aluminum, Fosetyl-Caclcium, Fosetyl-Sodium, Hexachlorobenzene, 8-Hydroxyquinoline Sulfate , Irumamycin, methasulphocarb, metrafenone, methyl isothiocyanate, mildiomycin, natamycin, nickel dimethyldithiocarbamate, nitrothal-isopropyl, octhilinone, oxamocarb, oxyfenthiine, pentachlorophenol and salts, 2-phenylphenol and salts, piperaline, propanosine sodium, proquinazide, pyribencarb, pyrrolnitrin, quintozene , Tecloftalam, Tecnazen, triazoxide, trichlamide, valiphenal, zarilamide,

2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluoφyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -

N-methylacetamide, 2 - [[[[1 - [3 (1 fluoro-2-phenylethyl) oxy] phenyl] ethylidene] amino] oxy] methyl] -alpha (methoxyimino) -N-methyl-alphaE-benzacetamide,

cis-1 - (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol,

1 - [(4-methoxyphenoxy) methyl] -2,2-dimethylpropyl-1H-imidazole-1-carboxylic acid,

2,3,5,6-tetrachloro-4- (methylsulfonyl) -pyridine,

2-butoxy-6-iodo-3-propyl-benzopyranone-4-one,

2-chloro-N- (2,3-dihydro-l, l, 3-trimethyl-lH-inden-4-yl) -3-pyridine carboxamide,

3,4,5-trichloro-2,6-pyridinedicarbonitrile,

3,4-Dichloro-N- (2-cyanophenyl) isothiazole-5-carboxamide (Isotianil)

3- [5- (4-chlorophenyl) -2,3-dimethylisoxazolidin-3-yl] pyridine,

5-Chloro-6- (2,4,6-trifluorophenyl) -N - [(1 R) -1,2,2-trimethylpropyl] [1,2,4] triazolo [1,5-a] pyrimidine-7 amine,

5-chloro-7- (4-methylpiperidino-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine,

5-chloro-N - [(1R) -1,2-dimethylpropyl] -6- (2,4,6-trifluoropheny1) [1,2,4] triazolo [1,5-a] pyrimidine-7 amine,

Methyl 2 - [[[cyclopropyl [(4-methoxyphenyl) imino] methyl] thio] methyl] -. Alpha.

(methoxymethylene) - benzoacetate,

Methyl 1 - (2,3-dihydro-2,2-dimethyl-1H-inden-1-yl) -1H-imidazole-5-carboxylate,

N- (3 ', 4'-dichloro-5-fluorobiphenyl-2-yl) -3- (difluoromethyl) -l-methyl-lH-pyrazole-4-carboxamide,

N- (3-ethyl-3,5,5-trimethyl-cyclohexyl) -3-formylamino-2-hydroxy-benzamide,

N- (4-chloro-2-nitrophenyl) -N-ethyl-4-methyl-benzenesulfonamid, N- (4-chlorobenzyl> 3- [3-methoxy-4- (prop-2-yn-l-yloxy) phenyl] propanaxnid,

N - [(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide,

N- (5-bromo-3-chloφyridin-2-yl) methyl-2,4-dichlornicotinamid,

N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide,

(2S) -N- [2- [4 - [[3- (4-chlorophenyl) -2-propynyl] oxy] -3-methoxyphenyl] ethyl] -3-methyl-2- [(methylsulfonyl) amino] butanamide.

N - {(Z) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-benzacetamide,

N- {2- [1,1'-bi (cyclopropyl) -2-yl] phenyl} -3- (difluoromethyl) yy1-methyl-1H-pyrazole-4-carboxamide,

N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2- (trifluoromethyl) benzamide,

N-ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) 4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide,

O- [1- (4-methoxyphenoxy) methyl] -2,2-dimethylpropyl] -1H-imidazole-1-carbothioic acid,

2-amino-4-methyl-N-phenyl-5-thiazolecarboxamide,

2,4-Dihydro-5-methoxy-2-methyl-4 - [[[[l- [3- (trifluoromethyl) phenyl] ethylidene] amino] oxy] methyl] phenyl] -3H-1 , 2,4-triazol-3-one (CAS No. 185336-79-2),

N- (6-methoxy-3-pyridinyl) cyclopropane carboxamide,

bactericides:

Bronopol, dichlorophen, nitrapyrin, nickel dimethyldithiocarbamate, kasugamycin, octhilinone, furancarboxylic acid, oxytetracycline, probenazole, streptomycin, tecloftalam, copper sulfate and other copper preparations. Insecticides / acaricides / nematicides:

Acetylcholinesterase (AChE) inhibitors

Carbamates, for example Alanycarb, Aldicarb, Aldoxycarb, Allyxycarb, Aminocarb, Bendiocarb, Benfuracarb, Bufencarb, Butacarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran,

Carbosulfan, cloethocarb, dimetilane, ethiofencarb, fenobucarb, fenothiocarb, formetanate, furathiocarb, isoprocarb, metam-sodium, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, promecarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, triazamates

Organophosphates, for example, acephates, azamethiphos, azinphos (-methyl, -ethyl), bromophos-ethyl, bromfenvinfos (-methyl), butathiofos, cadusafos, carbophenothione, chloroethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos

(-methyl / -ethyl), coumaphos, cyanofenphos, cyanophos, chlorfenvinphos, demeton-S-methyl, demeton-S-methylsulphone, dialifos, diazinon, dichlofenthione,

Dichlorvos / DDVP, Dicrotophos, Dimethoates, Dimethylvinphos, Dioxabenzofos, Disulfoton, EPN, Ethion, Ethoprophos, Etrimfos, Famphur, Fenamiphos, Fenitrothion, Fensulfothion, Fenthion, Flupyrazofos, Fonofos, Formothion, Fosmethilane, Fosthiazate, Heptenophos, Iodofenphos, Iprobenfos, Isazofos, Isofenphos, isopropyl-o-salicylate, isoxathione, malathion, mecarbam, methacrifos, methamidophos, methidathione,

Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion (-methyl / -ethyl), Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phosphocarb, Phoxim, Pirimiphos (-methylAethyl), Profenofos, Propaphos, Propetamphos, Prothiofos, Prothoate , Pyraclofos, Pyridaphenthion, Pyridathion, Quinalphos, Sebufos, Sulfotep, Sulprofos, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos,

Triclorfone, vamidothione

Sodium Channel Modulators / Voltage-Dependent Sodium Channel Blockers

Pyrethroids, for example acrinathrin, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentyl isomer, bioethanomethrin, biopermethrin,

Bioresmethrin, chlovaporthrin, cis-cypermethrin, cis-resmethrin, cis-permethrin, clocythrin, cycloprothrin, cyfluthrin, cyhalothrin, cypermethrin (alpha, beta, theta, zeta), cyphenothrin, deltamethrin, empenthrin (IR isomer), Esfenvalerate, Etofenprox, Fenfluthrin, fenpropathrin, fenpyrithrine, fenvalerate, flubrocythrinates, flucythrinates, flufenprox, flumethrin, fluvalinate, fubfenprox, gamma-cyhalothrin, imiprothrin, kadethrin, lambda-cyhalothrin, metofluthrin, permethrin (cis, trans), phenothrin (lR-trans isomer) , Prallethrin, Profuthrin, Protrifenbute, Pyresmethrin, Resmethrin, RU 15525, Silafluofen, Tau Fluvalinate, Tefluthrin, Terallethrin, Tetramethrin (-1R- isomer),

Tralomethrin, transfluthrin, ZXI 8901, pyrethrins (pyrethrum)

DDT

Oxadiazines, for example Indoxacarb

Semicarbazone, for example metaflumizone (BAS3201)

Acetylcholine receptor agonists / antagonists

Chloronicotinyls, for example acetamipride, clothianidin, dinotefuran, imidacloprid, nitenpyram, nithiazines, thiacloprid, thiamethoxam

Nicotine, Bensultap, Cartap

Acetylcholine receptor modulators

Spinosyne, for example Spinosad, Spinetoram

GABA-driven chloride channel antagonists

Organochlorines, for example, camphechlor, chlordane, endosulfan, gamma-HCH, HCH, heptachlor,

Lindane, Methoxychlor

Fiproles, for example, acetoprole, ethiprole, fipronil, pyrafluprole, pyriprole, vaniliprole

Chloride channel activators Mectins, for example Abamectin, Emamectin, Emamectin benzoate, Ivermectin, Lepimectin,

milbemycin

Juvenile hormone mimetics, for example, diofenolan, epofenonans, fenoxycarb, hydroprene, kinoprene,

Methoprene, pyriproxifen, triprene

Ecdysone agonists / disruptors

Diacylhydrazines, for example chromafenozide, Halofenozide, Methoxyfenozide, Tebufenozide

Inhibitors of chitin biosynthesis

Benzoylureas, for example bistrifluron, chlorofluazuron, diflubenzuron, fluazuron, flucycloxuron, fenphenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, penfluron, teflubenzuron, triflumuron

buprofezin

cyromazine

Inhibitors of oxidative phosphorylation, ATP disruptors

diafenthiuron

Organotin compounds, for example azocyclotin, cyhexatin, fenbutatin oxides

Decoupling of oxidative phosphorylation by interruption of the H proton gradient

Pyrroles, for example Chlorfenapyr

Dinitrophenols, for example binapacyrl, dinobutone, dinocap, DNOC, meptyldinocap

Site I electron transport inhibitors METI's, for example fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad,

tolfenpyrad

hydramethylnon

dicofol

Site II electron transport inhibitors

Rotenone

Site III electron transport inhibitors

Acequinocyl, Fluacrypyrim

Microbial disruptors of insect intestinal membrane

Bacillus thuringiensis strains

Inhibitors of fat synthesis

tetronic acids,

for example spirodiclofen, spiromesifen,

tetramic,

for example, spirotetramat, cis-3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-1-azaspiro [4.5] dec-3-en-2-one

carboxamides

for example flonicamide

Octopaminergic agonists,

for example Amitraz

Inhibitors of magnesium-stimulated ATPase,

propargite Nereistoxin Analog,

for example, thiocyclam hydrogen oxalate, thiosultap-sodium

Agonists of the ryanodine receptor,

benzoic acid dicarboxamides,

for example, Flubendiamid

anthranilamides,

for example, rynaxypyr (3-bromo-N- {4-chloro-2-methyl-6-

[(Methylamino) carbonyl] phenyl} -l- (3-chloropyridine-2-yl) -lH-pyrazole-5-carboxamide)

Biologics, hormones or pheromones

Azadirachtin, Bacillus spec, Beauveria spp., Codlemone, Metarrhizium spec,

Paecilomyces spec, thuringiensin, Verticillium spec.

Active substances with unknown or non-specific mechanisms of action

Fumigants, for example aluminum phosphides, methyl bromides, sulfuryl fluorides

Food inhibitors, for example Cryolite, Flonicamid, Pymetrozine

Mite growth inhibitors, for example clofentezine, etoxazole, hexythiazox

Amidoflumet, benclothiaz, benzoximate, bifenazate, bromopropylate, buprofezin, quinomethionate, chlordimeform, chlorobenzilate, chloropicrin, clothiazoben, cycloprene,

Cyflumetofen, Dicyclanil, Fenoxacrim, Fentrifanil, Flubenzimine, Flufenerim, Flutenzine, Gossyplure, Hydramethylnone, Japonilure, Metoxadiazone, Petroleum, Piperonylbutoxide, Potassium oleate, Pyralidyl, Sulfluramid, Tetradifon, Tetrasul, Tri- arathene, Verbutin

A mixture with other known active ingredients, such as herbicides, fertilizers, growth regulators, safeners, semiochemicals, or with agents for improving the plant properties is possible. The compositions according to the invention may furthermore be present in insecticides in their commercial formulations and in the formulations prepared from these formulations in admixture with synergists. Synergists are compounds by which the effect of the active ingredients contained in the compositions according to the invention is increased without the added synergist itself having to be actively active.

The compositions according to the invention may furthermore, when used as insecticides in their commercial formulations and in the forms of use prepared from these formulations, be present in mixtures with inhibitors which inhibit the degradation of the agrochemical active ingredient used in the environment of the plant, on the surface of parts of plants or in plants Reduce tissue.

The active substance content of the application forms prepared from the commercial formulations can vary within wide ranges. The active ingredient concentration of the use forms may be from 0.00000001 up to 95% by weight of active compound, preferably between 0.00001 and 1% by weight.

The application is done in a custom forms adapted to the application.

According to the invention, all plants and parts of plants can be treated. In this context, plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights. Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes. The plant parts also include crops and vegetative and generative propagation material, such as cuttings, tubers, rhizomes, offshoots and seeds.

The treatment according to the invention of the plants and plant parts with the compositions is carried out by soil treatment.

As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild or obtained by conventional biological breeding methods, such as crossing or protoplast fusion Plant species and plant varieties and their parts treated. In a further preferred embodiment, transgenic plants and plant cultivars obtained by genetic engineering, if appropriate in combination with conventional methods (Genetically Modified Organisms), and parts thereof are treated. The terms "parts" or "parts of plants" or "plant parts" have been explained above.

It is particularly preferred according to the invention to treat plants of the respective commercially available or in use plant cultivars. Plant varieties are understood as meaning plants having new traits which have been bred by conventional breeding, by mutagenesis or by recombinant DNA techniques. These can be varieties, biotypes and genotypes.

Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, vegetation period, diet), the treatment according to the invention may also give rise to superadditive ("synergistic") effects. Thus, for example, reduced application rates and / or extensions of the spectrum of action and / or an increase in the effect of the substances and agents usable in the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering power facilitated harvest, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher shelf life and / or machinability of the harvested products, which exceed the actual expected effects.

The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants to certain herbicidal active substances. Examples of transgenic plants are the important crops such as cereals (wheat, rice), corn, soybean, potato, sugar beets, tomatoes, peas and other vegetables, cotton, tobacco, rape, and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with special emphasis on maize, soya, potato, cotton, tobacco and oilseed rape. Traits that are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and snails by toxins produced in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (eg by the genes CryΙA (a) , CryΙA (b), CryΙA (c), CrylLA, CrylllA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CrylF, and combinations thereof) in the plants (hereinafter "Bt plants"). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins. Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soybean varieties and potato varieties which are sold under the trade names YIELD GARD® (eg corn, cotton, soya), KnockOut® (eg maize), StarLink® (eg maize), Bollgard® ( Cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties, which are sold under the trade names Roundup Ready® (tolerance to glyphosate eg corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, eg rapeseed), IMI® (tolerance against imidazolinone) and STS® (tolerance to sulfonylureas eg corn). As herbicide-resistant (grown on conventional herbicide tolerance) plants are also sold under the name Clearfield® varieties (eg corn) mentioned. Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.

The plants listed can be treated particularly advantageously according to the invention with the compositions according to the invention. The preferred ranges given above for the compositions also apply to the treatment of these plants. Particularly emphasized is the plant treatment with the compositions specifically listed in the present text.

The compositions of the invention not only work against plant, hygiene and

Stock pests, but also in the veterinary sector against animal parasites (ecto- and endoparasites) such as ticks, leather ticks, mange mites, mites, flies (stinging and licking), parasitizing fly larvae, lice, hair pieces, featherlings and fleas. These parasites include:

From the order of the Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.

From the order of Mallophagida and suborders Amblycerina and Ischnocerina, for example. Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.

From s of the order Diptera and the suborders Nematocerina and Brachycerina e.g. Aedes spp K, Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota Spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Murnrellellia sspppp., Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia Spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.

From the order of siphonapterida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.

From the order of the heteropterid e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.

From the order of Blattarida e.g. Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.

From the subclass of Acari (Acarina) and the orders of Meta and Mesostigmata e.g. Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp ., Sternostoma spp., Varroa spp.

From the order of Actinedida (Prostigmata) and Acaridida (Astigmata) e.g. Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp , Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The compositions according to the invention are also suitable for controlling arthropods, livestock, such as cattle, sheep, goats, horses, pigs, donkeys, Camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as dogs, cats, caged birds, aquarium fish and so-called experimental animals, such as hamsters, guinea pigs, rats and mice infested. The control of these arthropods is intended to reduce deaths and reductions in performance (in the case of meat, milk, wool, hides, eggs, honey, etc.), so that a more economical and simpler animal husbandry is possible through the use of the compositions according to the invention.

The use of the compositions according to the invention is carried out in the veterinary sector and in animal husbandry in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, drenches, granules, pastes, boilies, feed-through, suppositories, by parenteral administration, as by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying, pouring (pour-on and spot-on ), washing, powdering and with the aid of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.

In the livestock, poultry, domestic animal, etc. application, the compositions may be formulated (for example, powders, emulsions, flowables) containing the active ingredients in an amount of 1 to 80% by weight, directly or after 100 to 10,000 dilution or use as a chemical bath.

In addition, it has been found that the compositions according to the invention have a high insecticidal activity against insects which destroy industrial materials.

By way of example and preferably without limiting however, the following insects are mentioned:

Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus;

Skin fins such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur;

Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus; Bristle tails like Lepisma saccharina.

Technical materials in the present context are non-living materials, such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.

The ready-to-use agents may optionally contain further insecticides and optionally one or more fungicides.

With regard to possible additional admixing partners, reference is made to the above-mentioned insecticides and fungicides.

At the same time, the compositions according to the invention can be used to protect against the growth of objects, in particular hulls, sieves, nets, structures, quay systems and signal systems, which come into contact with seawater or brackish water.

Furthermore, the compositions according to the invention can be used alone or in combinations with other active substances as antifouling agents.

The compositions are also suitable for controlling animal pests in household, hygiene and storage protection, in particular insects, arachnids and mites, which are used in enclosed spaces, such as, for example, apartments, factory halls, offices,

Vehicle cabs u.a. occurrence. You can fight this pest alone or in

Combination with other active ingredients and excipients used in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:

From the order of Scorpionidea e.g. Buthus occitanus.

From the order of Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.

From the order of the Araneae e.g. Aviculariidae, Araneidae.

From the order of Opiliones e.g. Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.

From the order of the Isopoda eg Oniscus asellus, Porcellio scaber. From the order of the Diplopoda eg Blaniulus guttulatus, Polydesmus spp ..

From the order of Chilopoda e.g. Geophilus spp ..

From the order of Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.

From the order of the Blattaria e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.

From the order of Saltatoria e.g. Acheta domesticus.

From the order of the Dermaptera e.g. Forficula auricularia.

From the order of Isoptera e.g. Kalotermes spp., Reticulitermes spp.

From the order of Psocoptera e.g. Lepinatus spp., Liposcelis spp.

From the order of Coleoptera e.g. Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.

From the order of Diptera e.g. Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Simulium spp., Stomoxys Calcitrans, Tipula paludosa.

From the order of Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.

From the order of siphonaptera e.g. Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.

From the order of Hymenoptera e.g. Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.

From the order of the Anoplura e.g. Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastatrix, Phthirus pubis.

From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans. The application in the field of household insecticides is carried out alone or in combination with other suitable active ingredients such as phosphoric acid esters, carbamates, pyrethroids, neonicotinoids, growth regulators or active compounds from other known classes of insecticides.

The expected effect for a given combination of two drugs can be found in S.R. Colby, Weeds 15 (1967), 20-22 are calculated as follows:

If

X means the degree of killing, expressed in% of the untreated control, when using the active substance A at a rate of m g / ha or in a concentration of m ppm,

Y means the degree of killing, expressed in% of the untreated control, when using the active ingredient B in an application rate of n g / ha or in a concentration of n ppm, and

E the degree of kill, expressed in% of the untreated control, when using the

Active substances A and B in amounts of m and n g / ha or in a concentration of m and n ppm,

then

XY

E = X ₊ Y- ^" ΪÖÖ ~

If the actual kill rate is greater than calculated, the combination is over-additive in its kill, ie there is a synergistic effect. In this case, the actually observed kill rate must be greater than the expected kill rate (E) value calculated from the above formula.

Example A

Spodoptera frugiperda test

To prepare a suitable product solution, 1 part by weight of formulated product is mixed with water to the desired concentration. The desired adjuvant is added in a defined amount and mixed well.

Corn plants (Zea mays) are infused with the product solution of the desired concentration and infected with larvae of the armyworm {Spodoptera frugiperda).

After the desired time the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed. The determined kill values are calculated according to the Colby formula (see page 1).

In this test, z. Example, the following combinations of active ingredient and adjuvant according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:

Table A1, page 1

Plant damaging insects

Spodoptera frugiperda - test, infection 3 days after the drench application

* gef. = found effect

** calc. = calculated according to the Colby formula

Table A2, page 2

Plant damaging insects

Spodoptera frugiperda - test, infection 5 days after drench application

* gef. = found effect

** calc. = calculated according to the Colby formula

Claims

claims

1. A method for controlling animal pests by application of an agrochemical composition containing at least one agrochemical active ingredient from the class of insecticidal phthalic diamides in the culture substrate of a plant, characterized in that a composition containing at least one adjuvant is applied.

2. The method according to claim 1, characterized in that the adjuvant is selected from the group consisting of

Dioctyl sodium sulfosuccinate,

Compositions containing dioctyl sodium sulphosuccinate and sodium benzoate,

End-capped alkoxylated fatty alcohols and end-capped alkoxylated straight-chain alcohols,

Tributylphenol polyglycol ethers having 10 to 15 EO units (where EO is ethylene oxide),

Polyalkylene oxide-modified polymethylsiloxanes,

- Branched alkanol alkoxylates of the formula

CH ₃ - (CH ₂ ) _r CH ₂ -O - (- CH ₂ -CH ₂ -O-) _u -H, in which t is from 9 to 10.5 and u is from 6 to 25,

- Betaine,

Polyalkoxylated triglycerides,

Alkoxylated fatty amines,

Sodium laureth sulfate,

- PEG- 10 Coconut Alcohol and

Compositions comprising corn syrup, methylated soybean oil and nonionic

Emulsifier.

3. Agrochemical composition for use in soil containing

at least one agrochemical active ingredient from the class of insecticidal phthalic diamides,

at least one adjuvant selected from the group consisting of

Dioctyl sodium sulfosuccinate,

Compositions containing dioctyl sodium sulphosuccinate and sodium benzoate

- End-capped alkoxylated fatty alcohols and end-capped alkoxylated straight-chain alcohols

- Tributylphenolpolyglycolether with 10 to 15 EO units (where EO for

Ethylene oxide stands),

Polyalkylene oxide-modified polymethylsiloxanes,

- Branched alkanol alkoxylates of the formula CH ₃ - (CH ₂ ) _t -CH ₂ -O - (- CH ₂ -CH ₂ -O-) _u -H, in which t is from 9 to 10.5 and u for numbers from 6 to 25,

- Betaine,

Polyalkoxylated triglycerides,

Alkoxylated fatty amines,

Sodium laureth sulfate,

- PEG-10 Coconut Alcohol and

Compositions comprising corn syrup, methylated soybean oil and nonionic emulsifier.

4. The composition according to claim 3, containing

at least one nonionic surfactant and / or at least one anionic surfactant,

one or more additives from the groups of antifreezes, antifoaming agents, preservatives, antioxidants, spreading agents, dyes and / or thickeners.

5. The composition according to claim 4, comprising

between 1 and 60% by weight of at least one agrochemical active ingredient from the classes of insecticidal phthalic diamides,

between 1 and 50% by weight of at least one adjuvant,

between 1 and 20% by weight of at least one nonionic surfactant and / or anionic surfactant,

between 1 and 20 wt .-% antifreeze and

between 0, 1 and 20% by weight of additives from the groups of foam-inhibiting agents, preservatives, antioxidants, spreading agents, dyes and / or thickeners.

Composition according to any one of Claims 3 to 5, characterized in that it contains at least one active substance selected from the group consisting of (U-I), (π-2) and (π-3)

No. x ^B _R 1B _R 2B _R 3B L ^IB L ^2B L ^3B

II-1 IHH -C (CH ₂ ) ₂ CH ₂ SCH ₃ CH ₃ iso-C ₃ F ₇ H

π-2 IHH -C (CHj) ₂ CH ₂ SOCH ₃ CH ₃ iso-C ₃ F ₇ H

π-3 IHH -C (CH ₃ ) ₂ CH ₂ SO ₂ CH ₃ CH ₃ iso-C ₃ F ₇ H

7. Use of adjuvants for improving the action of plant protection products containing at least one active substance from the class of insecticidal phthalic diamides in soil application.

8. Use according to claim 7, characterized in that at least one adjuvant selected from the group consisting of

Dioctyl sodium sulfosuccinate,

Compositions containing dioctyl sodium sulphosuccinate and sodium benzoate,

End-capped alkoxylated fatty alcohols and end-capped alkoxylated straight-chain alcohols,

Tributylphenol polyglycol ethers having 10 to 15 EO units (where EO is ethylene oxide),

Polyalkylene oxide-modified polymethylsiloxanes,

- Branched alkanol alkoxylates of the formula

CH ₃ - (CH ₂ ), - CH ₂ -O - (- CH ₂ -CH ₂ -O-) _u -H, in which t is from 9 to 10.5, and u is from 6 to 25,

- Betaine,

Polyalkoxylated triglycerides,

Alkoxylated fatty amines, Sodium laureth sulfate,

- PEG- 10 Coconut Alcohol and

Compositions comprising corn syrup, methylated soybean oil and nonionic emulsifier,

is used.