EP2082097B1 - Security film comprising a fibrous substrate - Google Patents

Security film comprising a fibrous substrate Download PDF

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Publication number
EP2082097B1
EP2082097B1 EP07858556.9A EP07858556A EP2082097B1 EP 2082097 B1 EP2082097 B1 EP 2082097B1 EP 07858556 A EP07858556 A EP 07858556A EP 2082097 B1 EP2082097 B1 EP 2082097B1
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EP
European Patent Office
Prior art keywords
security
tape
paper
sheet
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP07858556.9A
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German (de)
French (fr)
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EP2082097A2 (en
Inventor
Henri Rosset
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oberthur Fiduciaire SAS
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ArjoWiggins Security SAS
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Application filed by ArjoWiggins Security SAS filed Critical ArjoWiggins Security SAS
Priority to PL07858556T priority Critical patent/PL2082097T3/en
Publication of EP2082097A2 publication Critical patent/EP2082097A2/en
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Publication of EP2082097B1 publication Critical patent/EP2082097B1/en
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/40Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
    • D21H21/42Ribbons or strips

Definitions

  • the invention relates to the field of security documents. It relates to a security sheet comprising a security tape and the method of manufacturing the security sheet. It also concerns the security tape itself.
  • Security documents are produced from particularly fibrous materials and may include banknotes, identity cards, passports, driving licenses, visas, checks, vouchers, tickets or admission tickets to a cultural or sports event.
  • the introduction in strip of said security elements can in particular be done by supply ducts placed along the width and opening into the shape tank nearby. from round form, before the beginning of draining of a fibrous suspension on a fabric of a round form. After draining, a security sheet is obtained which is then pressed and then dried according to the current papermaking process.
  • the main drawback relating to said first method of obtaining a band containing security elements is the irregular dispersion of said security elements. Due to the introduction of the elements, it is difficult to obtain a band whose edges are regular and within which the distribution of the elements of security is relatively homogeneous, in the width (x) and in the length (y) but also in the thickness (z) of said security sheet.
  • bandwidth and spatial distribution (x, y, z) of the security elements can be particularly troublesome in the case of recognition and / or authentication and / or identification based on the spatial distribution (x, y , z) said security elements in said security document. Indeed, because of too great variability, the use of the position or the width of said band, or the spatial distribution of said security elements, for purposes of recognition and / or authentication and / or or identification, may in particular be impossible to implement.
  • recognition applies when a document or element of a document is compared to a reference to determine the authenticity of that document document or element
  • authentication means determining whether the document is authentic or whether it has been falsified or counterfeited
  • identity is the verification of the identity of the owner of a given document.
  • the type of problem mentioned above is encountered in the case of authentication of security elements automatically using a non-portable device based on the specific signal of one or more elements (s). ) of security.
  • some of said security elements are covered with a layer of fibers and / or mineral charges too thick to allow the correct detection of their specific signals by said automatic authentication device.
  • said introduced security threads generally have a width of less than 10 mm, a thickness of between 12 and 45 ⁇ m and are, in most cases, made up of ribbons of plastic materials, in particular based on polyester.
  • Said security son are in particular secured by visible or non-visible patterns, in positive and / or negative, optically variable devices and in particular holograms, luminescence and in particular fluorescence, magnetism, electrical conduction or still thermochromic.
  • Said security threads are incorporated inside the fibrous substrate constituting said security sheet is "en masse", that is to say completely covered with fibrous material, or “window”, said security thread being then located on the surface of said security sheet and en masse in the latter, for example in an alternating manner.
  • the windows thus described may or may not be through, depending on whether said security thread appears respectively on two or on one side of said security sheet.
  • the introduction of said security son en masse can in particular be carried out in a single jet, on a paper machine flat or round table.
  • the wire is introduced into the shaped tank before or shortly after the beginning of the draining of the fibrous suspension on the fabric.
  • the position of said security thread in the thickness of the final security sheet is determined in particular by the place and the insertion inclination of said security thread.
  • the jet thus obtained can then be married in the wet state, that is to say before drying, with other jets whose fibrous compositions can be identical or different and which can be formed on paper machines at the table flat or round.
  • Another way of introducing said security son en masse is to incorporate them between two successive jets produced on a flat table and / or a round shape, before the "marriage" of said successive jets by wet pressing.
  • Said jets can themselves be married to other jets whose compositions may be identical or different and which can be formed on a flat table or a round shape, before or after the introduction of said security son. After their marriage, the two successive streams comprising said security son are eventually married to the other jets and then dried according to the current papermaking process to obtain a security sheet.
  • said security threads may in particular be coated with an adhesive, for example heat-sealing products also called hot-reactive products.
  • the introduction of said security threads may in particular lead to a poor overlap of said security threads characterized, when they are introduced en masse, by a lack of material above said security threads and, when they are introduced in a window, by insufficient bridging.
  • bridging is meant the fibrous covering of a security thread introduced in the windows in the zones between the windows, that is to say at the places where the thread is contained in the mass of said security sheet.
  • the adhesives for example heat-sealing coatings, which can be added to said security threads develop their adhesive properties only after drying of said paper sheet containing said security threads, and the plastic materials constituting said security threads being hydrophobic
  • said security son of the art prior art do not develop any bond with the fibrous substrate of said security sheet during dewatering and pressing which take place in wet part, that is to say, before drying of the sheet. Consequently, the introduction of said security threads weakens said security sheet along the introduction strip, the adhesion properties of said security thread coated with an adhesive, for example a heat-sealing product, not being developed only during drying.
  • said security threads are too wide, their impermeability impedes the drainage of the water contained in the fibers located above the son and thus prevents the consolidation of the fibrous mat, which causes in particular breakage of the sheet partially wet paper during the production of security sheets containing said security threads.
  • the width of said security son exceeds about 1.5 cm, the fibrous mat is no longer strong enough and causes too many breaks of the paper sheet to allow a correct machinability of the paper machine.
  • the materials of which said security threads are composed are generally plastic films which are optionally metallized and then possibly coated with varnish.
  • Another disadvantage of said security threads is that they can be combined only with very fine particles and, in particular, by printing and / or metallization.
  • the incorporation of flat security elements and relatively small size, such as boards, is impossible because of the materials of which said security son are constituted.
  • the European patent application EP 0 557 157 of the Applicant describes the manufacture of a security sheet having monochrome or polychrome signs visible in transmitted light.
  • the security sheet is manufactured from at least two fibrous jets and a strip having monochrome or polychrome marks introduced between the two fibrous jets.
  • the strip thus introduced advantageously comprises cellulose fibers and a soluble and / or fusible binder product so that said product can be dispersed during the incorporation of the strip between the two jets so that the band disappears within sheet and that the printed marks are intimately linked to the sheet.
  • the band thus obtained is completely destructured within the security sheet.
  • Requirement FR 2 847 915 discloses the incorporation, into a secure paper, of a ribbon made of a different tissue from a paper.
  • the French patent application FR 2 679 934 of the Applicant describes a system for authenticating a security paper using a first chemical reagent present on the security paper, an authentication composition comprising a second chemical reagent forming a colored product with the first chemical reagent and an erasing composition of the colored product.
  • the chemical reaction occurring during the authentication between the second reagent and the first chemical reagent only produces a coloration of the zone where the reaction occurs.
  • WO 2006/095033 relates to a safety band comprising a ribbon of a cellulosic support formed of vegetable fibers.
  • the cohesion and the integration of the ribbon in the substrate of the strip are ensured by the creation of chemical bonds between the vegetable fibers contained in the ribbon and in the substrate, in particular hydrogen bonds, but do not allow the ribbon to maintain its integrity. and its cohesion within the substrate of the strip, especially when the strip is placed in a wet environment, in case of an attempt to recover the strip by a counter factor, for example.
  • the invention aims to further improve the security sheets.
  • the invention relates for this purpose to a security sheet comprising a fibrous substrate in which is incorporated, at least partially, a ribbon extending between two edges of said fibrous substrate, said security tape being made of paper.
  • the security tape comprises, in a preferred embodiment of the invention, at least one adhesive, for example at least one heat-sealing agent.
  • the ribbon also comprises, in a preferred embodiment of the invention, at least one security element.
  • the ribbon extends between two opposite edges of said security sheet.
  • substrate denotes a fibrous sheet that may especially comprise one or more fibrous layers.
  • jets will be used to denote layers produced continuously on the same paper machine and then associated with the wet state.
  • the invention can make it possible to provide a security sheet with security elements arranged in a band with a relatively homogeneous spatial distribution (x, y, z).
  • the above adhesive optimizes the adhesion of the security tape in the security sheet
  • the adhesive may for example be a heat-sealing coating, for example a heat-sealing varnish, an ultraviolet (UV) cross-linkable agent, an adhesive to be irradiated, a pressure-sensitive adhesive (PSA), a varnish with a solvent base, of the type polyester for example, an adhesive in the aqueous phase, etc.
  • a heat-sealing coating for example a heat-sealing varnish, an ultraviolet (UV) cross-linkable agent, an adhesive to be irradiated, a pressure-sensitive adhesive (PSA), a varnish with a solvent base, of the type polyester for example, an adhesive in the aqueous phase, etc.
  • UV ultraviolet
  • PSA pressure-sensitive adhesive
  • Mowilith DC aqueous dispersion of vinyl acetate homopolymer with particles of size ranging from 0.3 ⁇ m to 2 ⁇ m and glass transition temperature T g of 38 About C °, and solids dry content between 55 and 57%) and Vinamul 3265 from the company CELANESE; DH9004, DH9017, DH9044 and DL5001 from the company COLLANO; Primal NW1845, Primal LC40, Primal P308M and Primal EP6000 from ROHM &HAAS; the 006SDW078-2 from BASF.
  • the adhesive may advantageously be an adhesive based on polyvinyl acetate such as Mowilith DC.
  • Vinamul 3265 and Mowilith DC also perform very well in the wet crumple test.
  • Mowilith DC has very good results in the wash test.
  • Mowilith DC provides very good results in terms of adhesiveness, but the invention is not limited to a particular adhesive.
  • the adhesive is not present in the form of fibers or in particulate form.
  • the incorporation of the adhesive into the security tape can be done by coating.
  • the coating can be carried out at least partially at the core, that is to say reach in depth, or even in totality the security tape, or at the surface.
  • the coating is performed on the support used for the manufacture of the tape before cutting the support.
  • the coating can be performed during the manufacture of the support for the manufacture of the security tape.
  • the coating can be performed on one side of the support or on both sides of the support.
  • the adhesive can completely cover the face on which it is deposited.
  • the incorporation of the adhesive tape security can also be done by impregnation, by dipping the tape or the support for making it in a bath.
  • the safety tape retains its own cohesion after introduction into the fibrous substrate.
  • the structure of the security tape may be observable after its introduction into the fibrous substrate under certain conditions, for example in section or by vision in reflection or transmission.
  • the security tape may be observable by topography in the sheet.
  • the security tape can be observed by transparency in the sheet, in particular with the naked eye.
  • the security tape may comprise at least one security element on one of its faces, or even on each of its faces.
  • the security tape may have different security features on each side.
  • the security tape may have irregularly shaped edges, for example in the form of broken or wavy lines, crenellations, zigzag, among others.
  • the edges of the security tape may have the same shapes or different shapes, regular or irregular.
  • the security tape may be transparent or translucent or even opaque, for example a dark appearance, especially darker than the substrate. It can be introduced or not into the fibrous substrate window. The introduction in window can in particular make it possible to obtain different variations of opacity when the security tape is opaque.
  • the security tape can optionally be combined with a strip of thermoplastic material and / or metal, for example PET, laminated or hot rolled to the ribbon before its introduction into the fibrous substrate.
  • the security tape can still have different characteristics perceptible for example to the sight or touch.
  • the security tape may for example be embossed, thus creating a particular effect, for example a touch or surface relief, the ribbon may appear partially on the surface of the fibrous substrate.
  • the security tape may be coated with a thermoplastic polymer and optionally embossed as a result of this coating.
  • the security tape can be printed with drops of varnish, resin or thermo-inking ink, among others.
  • the ribbon comprises impressions, this may for example allow to obtain variable optical effects.
  • the security tape may comprise a heat-reflecting ink for creating at least one relief, this ink being activated before introduction of the ribbon in the fibrous substrate. Activation before incorporation reduces the risk of destructuring the sheet during swelling of the ink.
  • the security tape may comprise particles, for example detectable with the naked eye or with the touch, introduced in mass in the security tape, for example in the form of balls, for example balls of a synthetic material, for example the polyurethane, or mineral, for example glass, of dimension for example less than 300 microns, or by deposition by screen printing or gravure, for example in the form of beads, for example less than 100 microns in size.
  • particles for example detectable with the naked eye or with the touch
  • introduced in mass in the security tape for example in the form of balls, for example balls of a synthetic material, for example the polyurethane, or mineral, for example glass, of dimension for example less than 300 microns, or by deposition by screen printing or gravure, for example in the form of beads, for example less than 100 microns in size.
  • the security tape may comprise a textile band, for example knitted, integrated ribbon or laminated tape.
  • the security tape may include an embossed print, for example screen printed.
  • the safety tape may have a greasy, rough, smooth, silky, soft look, among other things.
  • the security tape may in particular comprise polymer deposits, in particular in the form of beads, for example polyurethane (PU) beads, glass, polyamides 6 or 12, styrene-acrylic pigments, polypropylene (PP) waxes or beads, polyethylene (PE), polyvinyl chloride (PVC), methyl methacrylate-based polymers, the ribbon being for example introduced in window.
  • polyurethane (PU) beads for example polyurethane (PU) beads, glass, polyamides 6 or 12, styrene-acrylic pigments, polypropylene (PP) waxes or beads, polyethylene (PE), polyvinyl chloride (PVC), methyl methacrylate-based polymers, the ribbon being for example introduced in window.
  • PU polyurethane
  • PP polypropylene
  • PE polyethylene
  • PVC polyvinyl chloride
  • methyl methacrylate-based polymers for example introduced in window.
  • a fibrous sheet preferably of light weight, for example between about 15 and 90 g / m 2 , according to a current papermaking process, that is to say for example by draining a suspension of fibers optionally comprising conventional fillers and additives in stationery, the possible specific safety elements, pressing of the fibrous mat obtained and drying.
  • This sheet is then optionally calendered which allows in particular to reduce its thickness, and then cut to form ribbons which are then wound into coils.
  • the addition of the adhesive to the security tape may in particular be done by a coating process, for example a coating, or by processes resulting from printing techniques of a paper base after its manufacture, for example coating air-blast, rotogravure, screen printing, curtain coating, flexography, among others.
  • a coating process for example a coating
  • processes resulting from printing techniques of a paper base after its manufacture for example coating air-blast, rotogravure, screen printing, curtain coating, flexography, among others.
  • a photogravure process is used.
  • the coating of the security tape can be done during the manufacture of the fibrous sheet, for example by surface coating on sizing press or impregnation.
  • the coating of the adhesive for example on a fibrous sheet used for the manufacture of the ribbon, can be carried out for example at a rate of 2 to 15 g / m 2 per side, preferably between 3 and 8 g / m 2 per face.
  • the sealing temperature can vary between 70 and 135 ° C, for example, depending on the adhesive used, and sealing can take place during drying of the security sheet.
  • a 20 g / m 2 wet-strength fibrous sheet is coated with an adhesive in the aqueous phase at a rate of 5 g / m 2. m 2 per side, using, for example, a photogravure process. This gives a satisfactory compromise between adhesion power and amount of coated material.
  • the introduction of said security ribbons within said fibrous substrate can in particular be done according to the introduction modes of the plastic security threads of the art. prior as described above or by laminating said security tapes between two sheets or fibrous layers which then constitute the base of said fibrous substrate.
  • Said security sheet proposed by the Applicant comprises at least one paper security tape which may be wider than said security threads of the prior art without presenting fibrous overlap defects or insufficient bridging as described above. This results in particular from the permeability of said paper security ribbons which promotes drainage, as well as the good affinity between the fibers of said paper security tape and the fibrous material of said substrate.
  • said security tapes can be incorporated in said fibrous substrate without causing an increase in the frequency of breakage of the sheet, and this in particular because of the preferred composition of said paper security tapes.
  • said security tapes preferably comprise hydrophilic fibrous materials, in particular such as cellulosic fibers or synthetic fibers or optionally mineral fibers treated by sizing, so as to develop with said fibrous substrate bonds making it possible to reduce its embrittlement due to in particular to the introduction of an element into said fibrous base.
  • the size is a fiber coating that allows in particular to make them hydrophilic.
  • the present invention can achieve if desired said elements in a band whose boundaries are clear and within which the distribution of security elements is homogeneous.
  • said substrate comprises, in addition to said security tape, at least one security element, in particular chosen from tracers, in particular nanoscale, security fibers, in particular metallic, magnetic (to soft and / or hard magnetism), or absorbent or excitable in the ultraviolet (UV), the visible or the infrared (IR) and in particular the near infrared (NIR), the flat and relatively small security elements such as that the boards, the pigments or agglomerates of pigments in particular absorbing or excitable under Laser illumination or in the ultraviolet (UV), the visible or the infrared (IR), in particular the near infrared (NIR), and the security threads (Generally based on plastics, in particular of polyester) comprising in particular an at least partial coating, metallic, metallized, iridescent or magnetic (with soft magnetism and / or hard), said coating being able in particular c have positive or negative motives and said patterns may in particular be obtained by demetallization, the chemical or biochemical infadification and
  • Said fibrous substrate may in particular comprise security elements visible to the naked eye, but it may also comprise tracers which are in the form of active material, particles or fibers, capable of generating a specific signal when these tracers are subject to to optronic, electrical, magnetic or electromagnetic excitation.
  • tracers constitute an identifiable substance through a distinctive property and used to mark an element (a security document in this case) and ensure its follow-up, the follow-up of its evolution or allow its recognition, authentication or identification.
  • the dielectric structures with a mirror effect consist of an alternation of high and low index layers, for example respectively of Hafnium dioxide and of silica, and may in particular be obtained by ion etching.
  • the paper security tape may be based on cellulosic fibers (in particular cotton fibers) and / or natural organic fibers other than cellulosic and / or synthetic fibers, for example such as polyester or polyester fibers. polyamide, and / or optionally mineral fibers, for example such as glass fibers.
  • the safety tape may not include polyvinyl alcohol (PVA) fibers.
  • said fibers are hydrophilic, in particular so as to develop chemical bonds, mainly hydrogen, with said fibrous substrate.
  • said security tape comprises by weight at least 50% of cellulosic fibers.
  • the fibrous substrate is based on fibers as described above for the ribbon.
  • the fibrous substrate and said security tape are based on the same fibers, that is to say that their fiber composition is the same in nature and preferably in the same proportions, this allows good affinity between the two components and may, in addition, be an additional means of authentication.
  • said security tape has a width of between 2 and 60 mm, preferably between 4 and 30 mm and more preferably between 10 and 20 mm.
  • said security tape may comprise perforations, in particular to promote drainage during the manufacture of said security sheet.
  • said security tape has a thickness of between 20 and 120 microns, preferably between 30 and 80 microns, and more preferably between 45 and 55 microns.
  • said security tape comprises at least one filigree pattern.
  • said fibrous substrate comprises at least one filigree pattern.
  • said fibrous substrate and said safety tape each comprise at least one filigree pattern, said patterns being complemented by superposition and / or association.
  • said filigree patterns may be superimposed so as to obtain a moire effect.
  • Such an effect reveals a particular pattern produced by the approximation of lines during the superposition of two patterns of periodic structure and in particular screened.
  • the security tape may include a watermark and possibly perforations around this watermark.
  • the security tape can still be colored, in particular having a different color from that of the substrate.
  • Another advantage of the invention in the case of a ribbon having a watermark is the use of its usual sheet making tools and processes. For example, it produces a stock of filigree papers, colored or not, which it cuts and stores in ribbons. At the desired moment, these ribbons will then be introduced during the production of security sheets, which will allow the paper manufacturer to work with a "veline canvas", that is to say, not embossed. Indeed the embossing of the fabric that allows the formation of watermarks on the security sheets of the prior art has the disadvantage of requiring several days of work. Thus, the incorporation of watermarks arranged on paper security ribbons makes it possible to gain flexibility in the planning of manufacture.
  • said paper security tape comprises at least one security element chosen from tracers, in particular nanoscale, security fibers, especially metallic, magnetic (with soft magnetism and / or hard), or absorbing or excitable in the ultraviolet (UV), the visible or the infrared (IR) and in particular the near infrared (NIR), the flat and relatively small security elements such as boards, pigments or pigment agglomerates particularly absorbent or excitable under laser illumination or in the ultraviolet (UV), visible or infrared (IR), in particular the near infrared (NIR), and security son (based on plastics, especially polyester) comprising in particular an at least partial coating, metallic, metallized, iridescent or magnetic (with soft and / or hard magnetism), said coating being able to include, in particular, positive or negative patterns, and
  • the units that may be obtained by demetallization, the chemical or biochemical infadification and / or authentication and / or identification reagents may in particular react with at least one
  • tracers in a security document by means of a security paper tape is located, which allows in particular to create an area, possibly invisible to the naked eye, recognition and / or authentication of said security document.
  • the recognition and / or authentication of said document may in particular be based on the intensity and / or the type of the signal generated by the tracers, considered individually or not, on the density of the tracers, or on their spatial distribution in a zone. predefined or not of the document.
  • randomly distributed tracers can form a unique signature and thus be used for identification purposes.
  • a security sheet of pigments or agglomerates of absorbent pigments in the infrared or in the near infrared as mentioned above can be used to make said sheet authenticatable, as described in the patent application.
  • WO 2005/034049 This same application recommends more particularly the use of kaolin and talc mixed, products that are common in the paper industry, in a security sheet area called variable distribution and especially watermarked.
  • the use of these compounds makes it possible, in particular, to authenticate said security sheet by infrared spectroscopy, in particular near-infrared spectroscopy, and better optical reading of bar-coded watermarks.
  • the present invention thus makes it possible to solve the above problem, for example by providing a security sheet comprising a filigree security tape made of fibrous material and a mixture of kaolin and talc in a proportion sufficient to promote spectroscopic authentication. infrared of said document or optical reading of said watermark.
  • the kaolin and talc content will be particularly high, but only in the zone containing said security tape, so that said security sheet comprising said security tape respects the upper limits of the ash levels inscribed in said specifications.
  • an advantage of the invention relates for example to the authentication of a security document by analyzing the signal of the magnetic response.
  • sowing that is to say in the fibrous suspension mixture before it is dewatered
  • soft magnetic fibers makes it possible, in a reproducible manner, to homogeneously distribute said magnetic soft fibers .
  • the introduction of said magnetic soft fibers in strip according to the prior art that is to say in a round shape by localized supply ducts or by laminar flow over a flat table, induced a certain variability in the concentration of said magnetic soft fibers, but also in the width of said magnetic soft fiber band.
  • the invention makes it possible to reproducibly obtain a homogeneous distribution of said magnetic soft fibers.
  • concentration of magnetic soft fibers and the width of said introduced security tape the number of "signatures" or possible magnetic signals is multiplied.
  • said paper security tape comprises at least two security elements chosen from those mentioned above.
  • said paper security tape comprises between 0.1 and 1% by dry weight of magnetic fibers, in particular with soft magnetism, with respect to the total amount of fibers, and preferably between 0 , 2 and 0.6%.
  • said paper security tape comprises a plurality of small boards divided according to a surface density of between 4000 and 25000 boards / m 2 , preferably between 5000 and 20000 boards / m 2 and more preferably between 11000 and 18,000 boards / m 2 .
  • said security tape comprises a series of parallel safety wires, and more particularly the succession of inter-wire spaces and / or the series of different widths of said safety wires constitute a code, in particular barcode type.
  • said paper security tape comprises a magnetic magnet anti-theft wire.
  • This type of antitheft security wire can be very sharp and therefore difficult to incorporate into a security sheet, it happens in particular that said antitheft wire, when introduced according to the prior art that is to say directly in a fibrous substrate, is not completely covered with fibers.
  • the incorporation of such an antitheft security wire according to the The present invention consists in the manufacture of a fibrous sheet in which several anti-theft security threads are introduced, said security sheet thus obtained then being cut into ribbons comprising at least one anti-theft thread. These ribbons are then introduced into said fibrous substrate.
  • the areas of said security tape which may have fibrous covering defects are covered by the fibrous material of said fibrous substrate, and thus a security sheet is obtained comprising at least one anti-theft security thread and free of covering defects.
  • said security tape comprises at least one electronic device.
  • said electronic device is a radio frequency identification device, more commonly referred to as an RFID device, and in particular an electronic chip and / or an antenna which can notably be printed on said paper security tape.
  • said paper security tape comprises at least one chemically or biochemical chemical tampering and / or authentication and / or identification reagent reacting in a colored manner, with at least one agent respectively of falsification and / or authentication and / or identification.
  • a paper security tape comprising a chemical or biochemical tampering reagent that reacts in a colored manner with at least one tampering agent can in particular be located on a zone of inscription of the variable information liable to be falsified.
  • this zone includes the areas intended for registration in figures and letters of the amount of the said check or the name of the recipient of the check.
  • said paper security tape comprises a chemical or biochemical authentication reagent reacting in a colored manner with at least one authentication agent, additional security of the security sheet containing said paper security tape is obtained, the reaction of authentication being in fact located on the area where said paper security tape has been incorporated.
  • Another advantage of the above particular case is to be able to use at least one anti-tampering reagent in documents intended to receive a surface treatment, in particular to promote the adhesion of the ink during the personalization of said documents.
  • the reagents of this type are generally not used because they are reagents incompatible with the mixtures of colloidal dispersions of polymers.
  • This particular case has the additional advantage of allowing the use of tampering reagents which react with certain adhesives, and in particular those used on adhesive-coated sheets, in particular for visas to be pasted on passports or for safety films stuck on some security documents.
  • the fact of incorporating said reagents into said paper security tape makes it possible to isolate the reagents and thus prevent any premature reaction between said reagents and said adhesives, especially contained on said adhesive-coated sheets, without preventing the reaction with them. reagents used in attempts to falsify said security documents containing said adhesive sheets.
  • said fibrous substrate comprises at least one chemically or biochemical chemical tampering and / or authentication and / or identification reagent reacting in a colored manner, with at least one agent respectively of falsification and / or or authentication and / or identification.
  • said paper security tape and said fibrous substrate each comprise at least one chemically or biochemical chemical tampering and / or authentication and / or identification reagent reacting in a colored manner, with at least one respectively tampering agent and / or authentication and / or identification.
  • Said chemical or biochemical infalsification and / or authentication and / or identification reagents are preferably different and can in particular react with one and the same agent or with two different agents.
  • said security tape and said fibrous substrate of the security sheet each comprise at least one chemical or biochemical reagent for tampering and / or for authentication and / or identification, these reagents being chemically incompatible.
  • chemically incompatible means that the reactants can react together because they are in contact with each other or because they involve chemical reactions, with the falsification or authentication and / or identification agents, which are incompatible with each other. .
  • the use of a single fibrous substrate sometimes prevents the combination of some of said chemical or biochemical infalsification and / or authentication and / or identification reagents which, inserted into a common substrate react together (incompatible reagents).
  • said chemical or biochemical reagents for tampering and / or authentication and / or identification may be compatible but give rise to incompatible reactions during the attempt to falsify or to the authentication or identification of said security document that make said document is not damaged during its forgery or that the authentication reaction does not give the expected result.
  • the use of at least one ribbon according to the invention therefore has the particular advantage of allowing the use of at least two incompatible reagents or reactions.
  • said security tape comprises perforations in a pattern or a code.
  • said pattern or code is observable, or observable only in transmitted or observable light in both transmitted light and reflected light. If said security tape has an invisible fluorescent print, said pattern can also be visible only under UV illumination.
  • said perforation pattern comprises at least one alphanumeric character or an ideogram.
  • said paper security tape comprises perforations in a pattern and further comprises a chemical reagent or biochemical for tampering and / or authentication and / or identification reacting in a colored manner.
  • said chemical or biochemical reagent reacts with the falsification and / or authentication and / or identification agent according to a reaction that gives a particular coloration to said paper security tape.
  • Said pattern made by perforation then becomes visible by contrast between the coloring of said paper security tape and that of said fibrous substrate.
  • said security tape is calendered. This calendering is carried out in particular to minimize the extra thickness created by the introduction of said paper security tape.
  • said security tape is free of a surface coating, in particular free of a pigmented layer.
  • the good affinity between said fibrous substrate and said security tape is thus favored.
  • said security tape comprises a water-activatable adhesive agent, for example a polyvinyl alcohol (PVA), in particularly partially hydrolysed.
  • PVA polyvinyl alcohol
  • said paper security tape has a wet strength (REH) with respect to traction greater than 30%, in particular so as not to cause problems when introduced into said security sheet.
  • the resistance in the wet state in tension is measured by dividing the value of the wet tensile strength measured according to the NF Q 03.056 standard by the dry tensile strength measured according to the NF EN ISO 1924 standard.
  • wet state may in particular be provided in a conventional manner by the addition of a wet strength agent, for example such as a polyamine-amide-epichlorohydrin resin (PAAE), a formaldehyde melamine resin, etc.
  • PAAE polyamine-amide-epichlorohydrin resin
  • formaldehyde melamine resin etc.
  • an additional wet strength may be obtained by adding a portion of the REH agent (s) in surfactant baths of a fibrous sheet, for example for the manufacture of the fibrous web. security.
  • said security tape is comprised in mass or in window in said fibrous substrate.
  • the ribbon may appear only on one side of the sheet in a window or appear on each face of the sheet in a through window.
  • said fibrous substrate has a fibrous monolayer, in particular a single-ply, or several fibrous layers, in particular multijet.
  • said fibrous substrate comprises two fibrous layers, in particular a bijet structure.
  • said security tape and at least one of the layers of said fibrous substrate have different colors. This achieves a higher security due to the presence of two fibrous layers of different colors in the same security sheet.
  • said substrate of the security sheet and the security tape are of different colors and each comprise a filigree pattern.
  • the security of said security document is thus improved because of the presence of two watermarks of different coloration to be counteracted, in particular because the use of transparent inks, commonly used to counterfeit watermarks, does not make it possible to create such color effects.
  • this security allows rapid authentication of said security document, the coloring of said watermarks being easily observable in transmitted light.
  • said fibrous substrate comprises at least two paper safety ribbons as described above.
  • said security sheet comprises two security tapes, it is then possible that they respectively contain two different reagents giving, by reaction with a single developer, two different localized colors. It is also possible that said security tapes react specifically to two different agents to give, in a localized manner, two different colors or not.
  • the invention also relates to a process for the papermaking of said security sheet described above wherein said fibrous material-based security tape is introduced at a wet end into said fibrous substrate. Said substrate - ribbon assembly thus obtained is then pressed and dried.
  • said security tape is introduced in wet part, in bulk or in window in said fibrous substrate.
  • known methods can be used to introduce plastic security threads of the prior art.
  • the ribbon may have any of the features detailed above, or any combination thereof.
  • the method uses a paper machine which is equipped with at least one round shape, and said security tape is introduced into the shaped tank of said round shape, before or shortly after the start dewatering the composition forming said fibrous substrate of the sheet.
  • the method uses a paper machine which is equipped with at least one flat table, and said paper security tape is introduced above said flat table, during the dewatering of the paper. composition forming said substrate of the sheet.
  • said fibrous substrate comprises at least two jets
  • said safety tape is introduced before wet assembly of two successive jets, that is to say, according to the method paper maker, before drying the safety tape assembly - fibrous jets from the substrate.
  • said paper security tape as described above is incorporated by laminating between two fibrous layers of said fibrous substrate of said security sheet.
  • said paper security tape may appear in the window, especially if at least one of said layers comprises perforations or areas devoid of material.
  • the invention also relates to the paper security tape as described above.
  • the invention also relates to a security document comprising a security sheet as described above.
  • This document can be manufactured by cutting, binding, binding, rolling, gluing and / or laminating this security sheet.
  • More particularly said security document is a means of payment, such as a bank note, a check or a restaurant ticket, an identity document such as an identity card or a visa or a passport or a permit. driving, a lottery ticket, a ticket or an entrance ticket to cultural or sports events.
  • the invention also relates to an article to be authenticated comprising said security sheet as described or obtained previously, said article being chosen from a security label, a packaging, in particular a packaging for the drugs or for food or for perfumes or for electronic parts or for spare parts, a sheet used in the medical or hospital field, including a paper used to make sterilization packaging, and still a paper art.
  • the invention also relates to a method of authenticating a security sheet comprising a security tape which comprises at least one chemical or biochemical reagent for tampering and / or authentication and / or identification reacting in a colored manner with at least one falsification and / or authentication and / or identification agent respectively, as well as perforations according to a pattern or a code.
  • a security tape which comprises at least one chemical or biochemical reagent for tampering and / or authentication and / or identification reacting in a colored manner with at least one falsification and / or authentication and / or identification agent respectively, as well as perforations according to a pattern or a code.
  • said chemical or biochemical reagent tampering or authentication and / or unreacted identification
  • said pattern or said perforated code is invisible.
  • the said method is therefore characterized in that the reaction between said tampering and / or authentication and / or identification reagent, and an agent for falsification and / or authentication and / or identification, respectively, gives a coloring said paper security tape making said perforations, in particular said pattern or said perforated code, observable on said security tape.
  • the invention also relates to a security sheet comprising a fibrous substrate in which is incorporated, at least partially, a security tape, preferably comprising at least one security element, extending between two edges.
  • a security tape preferably comprising at least one security element, extending between two edges.
  • said fibrous substrate, said security tape being made of paper and having a watermark.
  • the ribbon may have one or more of the above features.
  • the invention also relates to a security sheet comprising a fibrous substrate in which is incorporated, at least partially, a security tape, preferably comprising at least one security element, and extending between two edges of said fibrous substrate, said security tape being made of paper and having a different color than at least one layer of said fibrous substrate.
  • a security tape preferably comprising at least one security element, and extending between two edges of said fibrous substrate, said security tape being made of paper and having a different color than at least one layer of said fibrous substrate.
  • different color is meant a color difference visible to the naked eye.
  • the ribbon may have one or more of the above features.
  • a security sheet comprising a paper security tape comprising as security element boards with a fluorescent invisible printing and incorporated into a filigree fibrous substrate.
  • a sheet of paper is made on a flat-table paper machine.
  • the boards printed with a fluorescent ink are added to the aqueous suspension of refined cellulose fibers of the order of 30 ° SR, the fibrous mat containing these boards is sown and dried.
  • Said sheet obtained once dried has a basis weight of 45 g / m 2 .
  • said security tapes are introduced in the round shape into the round shape of the tank.
  • a security sheet is obtained according to the invention shown in front on the figure 2 and according to a cut in the thickness on the figure 3 .
  • the tape is not coated with the MOWILITH adhesive, all other steps being performed.
  • a security sheet comprising a paper security tape comprising, as a security element, soft magnetism fibers embedded in a fibrous substrate.
  • a sheet is made on a flat-bed paper machine according to the traditional method, that is to say by draining, pressing and then drying an aqueous suspension of refined cellulose fibers at 32 ° SR.
  • Said soft magnetic security fibers are fibers of an alloy of nickel and iron called Supermalloy ® . These fibers have a diameter of 10 ⁇ m and an average length of 3 mm and are introduced as a mixture into the fibrous suspension at a level of 0.7% by weight relative to the fibrous composition in the leading vat, that is to say say before the formation of said sheet.
  • a sheet of a grammage of 35 g / m 2 is obtained which is then calendered, coated with adhesive, for example by gravure on both sides with MOWILITH DC adhesive at a rate of 5 g / m 2 per side, then cut into ribbons 3.5 cm wide.
  • the ribbons may be reeled.
  • the security sheet is made on a flat-bed paper machine by mass-introducing said security strips into the fibrous composition forming the substrate.
  • the security tapes are introduced during dewatering, between the fibrous mat forming and the dough roll located on the forming table, and the sheet is then pressed. After drying, the security sheet thus obtained has a basis weight of 100 g / m 2 .
  • the homogeneous distribution of magnetic fibers in the ribbon and the regular width of said security tape make it possible to authenticate and / or identify said security sheet reliably.
  • the coating with the adhesive is not carried out, all the other steps being reproduced elsewhere.
  • the removal of the adhesive is carried out by gluing press.
  • the fibrous substrate of the sheet is formed in which said security strips, at the mark and in the window, are introduced, according to the method of introducing security threads onto a round-shaped paper machine described in FIG. patent application EP 059 056 .
  • the resulting security sheet thus comprises an iridescent coating appearing according to dashed lines because of the window introduction of said security tape.
  • the adhesive is deposited on the layer of pigments.
  • a security sheet comprising a white natural color fibrous substrate comprising a watermark and a yellow paper security tape comprising a watermark.
  • Said ribbon and said substrate form a security sheet such that the two filigree patterns complement each other.
  • a paper of yellow color and watermarked in a pattern representing a hair is made from an aqueous suspension of cellulose fibers refined at 40 ° SR comprising a yellow dye.
  • the surfacing and coating free sheet thus obtained weighs 70 g / m 2 , it is then calendered, coated by gravure printing of MOWILITH DC on both sides at a rate of 5 g / m 2 per side, then cut into strips of 5 cm wide.
  • Such a security tape is shown on the figure 4b .
  • the fibrous substrate of the sheet is formed from an aqueous suspension of refined cellulose fibers of the order of 38 ° SR and a filigree pattern is formed according to a face completing the filigree hair of the ribbon. ; said security strips are introduced into the mass of the substrate forming the mark so that the watermarks of the ribbon and the substrate complement each other to form a face.
  • said security tapes are introduced during the dewatering of the fibrous suspension on the round shape, in the form tank. After pressing and drying, a sheet is obtained whose weight is 80 g / m 2 .
  • the resulting security sheet therefore has a two-color watermark visible in transmitted light, such as that shown on the figure 4 .
  • the tape is not coated with adhesive, because it is not the strong adhesion of the ribbon in the substrate is sought.
  • This example implements aspects of the invention independent of the presence of adhesive on the ribbon.
  • a security sheet comprising a fibrous substrate comprising an authentication chemical reagent reacting in a colored manner to an external authentication agent which may be present in a pen.
  • authentication and a security paper tape which itself comprises an authentication chemical reagent reacting in a colored manner to the authentication agent present in said pen.
  • a sheet of the overlay type is formed on a flat-table machine from an aqueous suspension of refined cellulose fibers, of the order of 30 ° SR, and a paranitrophenol composition is introduced by surfacing the sheet in the press. gluer.
  • This sheet of paper has a grammage of 30 g / m 2 and therefore includes paranitrophenol as an authentication chemical reagent that can react on its entire surface in a colored manner with soda (sodium hydroxide) weakly concentrated, the soda being the external authentication agent contained in the pen. Paranitrophenol is colorless and yellow in the presence of weakly concentrated sodium hydroxide.
  • the coating-free sheet thus obtained is then calendered and then cut into strips of 2 cm wide.
  • the substrate of the sheet is made on a round paper machine from an aqueous suspension of cellulosic fibers comprising another authentication chemical reagent also reacting in a colored manner with weakly concentrated sodium hydroxide.
  • This reagent is a colored indicator for check derived from xanthene, it is colorless and takes a blue color in the presence of weakly concentrated soda, which is the authentication agent contained in said pen.
  • Said security tapes obtained previously are introduced in bulk during the formation of said substrate, according to a common method of mass introduction of security threads on a round-shaped paper machine as described in Example 4.
  • the resulting security sheet has a basis weight of 80 g / m 2 .
  • This sheet is authenticatable with an increased level of security. Indeed, by using on said sheet an authentication pen containing weakly concentrated sodium hydroxide, a first blue color appears on the areas where there is no paper security tape and a second green color on the areas above said paper security tape, said green color resulting from mixing the yellow and blue colors respectively of said paper security tape and said fibrous substrate.
  • the paper security tape 1 shown on the figure 1 has a width of 1.5 cm and is secured by boards 4 about 3 mm printed with an invisible ink fluorescent so that they are visible only under UV illumination.
  • the distribution of said boards 4 in said paper security tape 1 is homogeneous and their observation under UV illumination shows a band whose edges are relatively regular.
  • An object of the invention 3 is represented on the figure 2 , it consists of a security sheet 2 of dimensions 6 x 12 cm comprising in its mass a security paper tape 1 secured by said boards 4 and shown on the figure 1 .
  • This security paper tape 1 is introduced at a distance of 2 cm from the edge of the security sheet 2.
  • Said boards 4 being invisible fluorescent, they are invisible if observed in transmitted and / or reflected light.
  • said boards 4 can be seen arranged in a strip corresponding to said paper security strip 1, of homogeneous distribution and with relatively regular edges.
  • a section according to (AA ') of the figure 2 is represented on the figure 3 .
  • This cut in the thickness of said security sheet 3 object of the invention reveals said paper security tape 1 comprising said boards 4 and contained in the mass of the security sheet 2.
  • FIG. 4 Another object of the invention 3 is represented on the figure 4 . It comprises a fibrous substrate 2 of dimensions 6 ⁇ 12 cm, watermarked and whose watermark represents a face 5a as represented frontally on the figure 4a as well as a paper security tape 1 of 5 cm wide, yellow in color and watermarked, the watermark of which represents a hair 5b as shown in FIG. figure 4b .
  • Said security sheet 3 comprising said security paper tape 1 at a distance of 4 cm from its edge is represented on the figure 4 it contains a watermark representing a head composed of a yellow hair 5b and a face 5a in shades of gray.
  • An object of the invention 3 is represented on the figure 5 it comprises a security sheet 2 of dimensions 6 ⁇ 12 cm and in the mass of which is incorporated a paper security tape 1 of 2 cm wide and which comprises perforations 6 with a diameter of 2 mm, as well as a manganese sulfate which will act as an undyed tampering reagent. Said perforations 6 form the word "FALSIFIE”. During normal use of said object of the invention 3, said paper security tape 1 and said perforations 6 are not observable either in transmitted light or in reflected light.
  • the same object of the invention 3 having been the object of an attempt of falsification by soaking in a bath of sodium hypochlorite, and commonly used for the falsification of manual writing, is represented on the figure 5 .
  • the manganese salt contained in said paper security tape 1 reacted with the sodium hypochlorite bath to give a brown coloring product.
  • Said perforations 6 thus become observable and show in negative the word "FALSIFIE" signifying the attempt to falsify said object of the invention 3.
  • the security tape can be detected in various ways after incorporation into the security sheet.
  • the ribbon can be detected by direct observation of the security sheet, to the naked eye in reflected light or transmitted light. Differences in hue, appearance, and / or opacity between the ribbon and the fibrous substrate may determine the presence of the ribbon.
  • the security tape by the presence of the adhesive, for example a heat-sealing varnish, which can be observed in the form of bubbles by observation by scanning electron microscope (SEM).
  • SEM scanning electron microscope

Landscapes

  • Paper (AREA)
  • Credit Cards Or The Like (AREA)
  • Laminated Bodies (AREA)
  • Adhesive Tapes (AREA)

Description

L'invention se rapporte au domaine des documents de sécurité. Elle concerne une feuille de sécurité comprenant un ruban de sécurité ainsi que le procédé de fabrication de la feuille de sécurité. Elle concerne aussi le ruban de sécurité lui-même.The invention relates to the field of security documents. It relates to a security sheet comprising a security tape and the method of manufacturing the security sheet. It also concerns the security tape itself.

Les documents de sécurité sont produits à partir de matériaux notamment fibreux et peuvent notamment être des billets de banque, des cartes d'identité, des passeports, des permis de conduire, des visas, des chèques, des bons de valeurs, des titres de transport ou des tickets d'entrée à une manifestation culturelle ou sportive.Security documents are produced from particularly fibrous materials and may include banknotes, identity cards, passports, driving licenses, visas, checks, vouchers, tickets or admission tickets to a cultural or sports event.

Lors de la fabrication d'une feuille de sécurité destinée à la réalisation d'un document de sécurité comprenant des éléments de sécurité en bande, il y a principalement deux modes d'obtention de bandes contenant lesdits éléments de sécurité : soit on introduit de petits éléments de sécurité, par exemple tels que des planchettes qui sont des éléments en plastique et/ou en papier, plats et de format relativement petit, ou tels que des fibres colorées ou luminescentes, soit on introduit un ruban fin couramment appelé « fil de sécurité ». Ce ruban est généralement en matière plastique et il comprend des éléments de sécurité, par exemple luminescents.In the manufacture of a security sheet for the production of a security document comprising security elements in tape, there are mainly two modes of obtaining strips containing said security elements: either one introduces small security elements, for example such as boards which are plastic and / or paper elements, flat and of relatively small size, or such as colored or luminescent fibers, or a fine ribbon commonly called "security thread" is introduced ". This ribbon is generally made of plastic and comprises security elements, for example luminescent.

L'introduction en bande d'éléments de sécurité de format relativement petit tels que des fibres ou des planchettes peut notamment se faire, si la machine à papier est une machine à table plate, par flux laminaire d'un jet contenant une suspension desdits éléments de sécurité au-dessus d'une feuille de papier en formation qui sera ensuite pressée puis séchée selon le procédé papetier courant. Ce mode d'introduction est décrit par exemple dans la demande de brevet EP 1 253 241 .The introduction into strips of security elements of relatively small size such as fibers or boards may in particular be done, if the paper machine is a flat-table machine, by laminar flow of a jet containing a suspension of said elements. security over a sheet of paper in formation which will then be pressed and dried according to the current papermaking process. This method of introduction is described for example in the patent application EP 1 253 241 .

Dans le cas d'une machine à papier équipée d'une forme ronde, l'introduction en bande desdits éléments de sécurité peut notamment se faire par des conduits d'alimentation placés le long de la laize et débouchant dans la cuve de forme à proximité de la forme ronde, avant le début de l'égouttage de la suspension fibreuse sur la toile de la forme ronde. Après égouttage, on obtient une feuille de sécurité qui est ensuite pressée puis séchée selon le procédé papetier courant.In the case of a paper machine equipped with a round shape, the introduction in strip of said security elements can in particular be done by supply ducts placed along the width and opening into the shape tank nearby. from round form, before the beginning of draining of a fibrous suspension on a fabric of a round form. After draining, a security sheet is obtained which is then pressed and then dried according to the current papermaking process.

Le principal inconvénient relatif audit premier mode d'obtention d'une bande contenant des éléments de sécurité est la dispersion irrégulière desdits éléments de sécurité. En raison du mode d'introduction des éléments, il est en effet difficile d'obtenir une bande dont les bords soient réguliers et à l'intérieur de laquelle la répartition des éléments de sécurité soit relativement homogène, dans la largeur (x) et dans la longueur (y) mais aussi dans l'épaisseur (z) de ladite feuille de sécurité.The main drawback relating to said first method of obtaining a band containing security elements is the irregular dispersion of said security elements. Due to the introduction of the elements, it is difficult to obtain a band whose edges are regular and within which the distribution of the elements of security is relatively homogeneous, in the width (x) and in the length (y) but also in the thickness (z) of said security sheet.

Ces variations de largeur de bande et de distribution spatiale (x,y,z) des éléments de sécurité peuvent notamment être gênantes en cas de reconnaissance et/ou d'authentification et/ou d'identification basée sur la distribution spatiale (x,y,z) desdits éléments de sécurité dans ledit document de sécurité. En effet, du fait d'une trop grande variabilité, l'utilisation de la position ou de la largeur de ladite bande, ou encore de la distribution spatiale desdits éléments de sécurité, à des fins de reconnaissance et/ou d'authentification et/ou d'identification, peut notamment être impossible à mettre en oeuvre.These variations of bandwidth and spatial distribution (x, y, z) of the security elements can be particularly troublesome in the case of recognition and / or authentication and / or identification based on the spatial distribution (x, y , z) said security elements in said security document. Indeed, because of too great variability, the use of the position or the width of said band, or the spatial distribution of said security elements, for purposes of recognition and / or authentication and / or or identification, may in particular be impossible to implement.

Les termes « reconnaissance », « authentification » et « identification » sont définis ici de la manière suivante : « reconnaissance » s'applique lorsqu'un document ou un élément d'un document est comparé à une référence afin de déterminer l'authenticité dudit document ou dudit élément, « authentification » correspond au fait qu'on détermine si le document est authentique ou s'il a été falsifié ou contrefait, et « identification » correspond à la vérification de l'identité du propriétaire d'un document donné.The terms "recognition", "authentication" and "identification" are defined here as follows: "recognition" applies when a document or element of a document is compared to a reference to determine the authenticity of that document document or element, "authentication" means determining whether the document is authentic or whether it has been falsified or counterfeited, and "identification" is the verification of the identity of the owner of a given document.

On rencontre notamment le type de problème mentionné ci-dessus dans le cas d'une authentification d'éléments de sécurité de façon automatique à l'aide d'un dispositif non portatif basée sur le signal spécifique d'un ou de plusieurs élément(s) de sécurité. En effet, certains desdits éléments de sécurité sont recouverts d'une couche de fibres et/ou de charges minérales trop épaisse pour permettre la détection correcte de leurs signaux spécifiques par ledit dispositif d'authentification automatique. Ainsi, pour un signal ayant une intensité donnée, il faut introduire une plus grande quantité d'éléments de sécurité afin de compenser la perte d'intensité du signal.In particular, the type of problem mentioned above is encountered in the case of authentication of security elements automatically using a non-portable device based on the specific signal of one or more elements (s). ) of security. Indeed, some of said security elements are covered with a layer of fibers and / or mineral charges too thick to allow the correct detection of their specific signals by said automatic authentication device. Thus, for a signal having a given intensity, it is necessary to introduce a larger quantity of security elements in order to compensate for the loss of signal intensity.

Selon ledit second mode d'obtention d'une bande contenant des éléments de sécurité, lesdits fils de sécurité introduits ont en général une largeur inférieure à 10 mm, une épaisseur comprise entre 12 et 45 µm et sont, dans la plupart des cas, constitués de rubans de matériaux plastiques, notamment à base de polyester.According to said second method for obtaining a strip containing security elements, said introduced security threads generally have a width of less than 10 mm, a thickness of between 12 and 45 μm and are, in most cases, made up of ribbons of plastic materials, in particular based on polyester.

Lesdits fils de sécurité sont notamment sécurisés par des motifs visibles ou non, en positif et/ou en négatif, des dispositifs optiquement variables et en particulier des hologrammes, de la luminescence et en particulier de la fluorescence, du magnétisme, de la conduction électrique ou encore de la thermochromie.Said security son are in particular secured by visible or non-visible patterns, in positive and / or negative, optically variable devices and in particular holograms, luminescence and in particular fluorescence, magnetism, electrical conduction or still thermochromic.

Lesdits fils de sécurité sont incorporés à l'intérieur du substrat fibreux constituant ladite feuille de sécurité soit « en masse », c'est-à-dire totalement recouverts de matière fibreuse, soit « en fenêtre », ledit fil de sécurité étant alors situé à la surface de ladite feuille de sécurité et en masse dans cette dernière, par exemple d'une façon alternée. En particulier, les fenêtres ainsi décrites peuvent être traversantes ou non, selon que ledit fil de sécurité apparaît respectivement sur deux ou sur une seule face de ladite feuille de sécurité.Said security threads are incorporated inside the fibrous substrate constituting said security sheet is "en masse", that is to say completely covered with fibrous material, or "window", said security thread being then located on the surface of said security sheet and en masse in the latter, for example in an alternating manner. In particular, the windows thus described may or may not be through, depending on whether said security thread appears respectively on two or on one side of said security sheet.

L'introduction desdits fils de sécurité en masse peut notamment être réalisée dans un seul jet, sur une machine à papier à table plate ou à forme ronde. Dans le cas d'une forme ronde, le fil est introduit dans la cuve de forme avant ou peu après le début de l'égouttage de la suspension fibreuse sur la toile. La position dudit fil de sécurité dans l'épaisseur de la feuille de sécurité finale est notamment déterminée par le lieu et l'inclinaison d'introduction dudit fil de sécurité. Le jet ainsi obtenu peut alors être marié à l'état humide, c'est-à-dire avant séchage, avec d'autres jets dont les compositions fibreuses peuvent être identiques ou différentes et qui peuvent être formés sur des machines à papier à table plate ou à forme ronde.The introduction of said security son en masse can in particular be carried out in a single jet, on a paper machine flat or round table. In the case of a round shape, the wire is introduced into the shaped tank before or shortly after the beginning of the draining of the fibrous suspension on the fabric. The position of said security thread in the thickness of the final security sheet is determined in particular by the place and the insertion inclination of said security thread. The jet thus obtained can then be married in the wet state, that is to say before drying, with other jets whose fibrous compositions can be identical or different and which can be formed on paper machines at the table flat or round.

Une autre façon d'introduire lesdits fils de sécurité en masse est de les incorporer entre deux jets successifs produits sur une table plate et/ou une forme ronde, avant le « mariage » desdits jets successifs par pressage à l'état humide. Lesdits jets peuvent eux-même être mariés à d'autres jets dont les compositions peuvent être identiques ou différentes et qui peuvent être formés sur une table plate ou une forme ronde, avant ou après l'introduction desdits fils de sécurité. Après leur mariage, les deux jets successifs comprenant lesdits fils de sécurité sont éventuellement mariés aux autres jets et ensuite séchés selon le procédé papetier courant permettant d'obtenir une feuille de sécurité.Another way of introducing said security son en masse is to incorporate them between two successive jets produced on a flat table and / or a round shape, before the "marriage" of said successive jets by wet pressing. Said jets can themselves be married to other jets whose compositions may be identical or different and which can be formed on a flat table or a round shape, before or after the introduction of said security son. After their marriage, the two successive streams comprising said security son are eventually married to the other jets and then dried according to the current papermaking process to obtain a security sheet.

L'introduction d'un fil de sécurité en fenêtre dans un seul jet est par exemple décrite dans les demandes de brevet EP 059 056 pour une machine à papier à forme ronde et EP 0 609 252 pour une machine à papier à table plate. L'introduction en fenêtre entre deux jets d'un matériau fibreux multijet est quant à elle décrite dans la demande de brevet EP 229 645 .The introduction of a window security thread in a single jet is for example described in the patent applications EP 059 056 for a paper machine with round shape and EP 0 609 252 for a flat-table paper machine. The window introduction between two jets of a multijet fibrous material is described in the patent application. EP 229 645 .

Afin d'améliorer leur adhésion dans le substrat fibreux, lesdits fils de sécurité peuvent notamment être enduits d'un adhésif, par exemple de produits thermoscellants encore appelés produits réactivables à chaud.In order to improve their adhesion in the fibrous substrate, said security threads may in particular be coated with an adhesive, for example heat-sealing products also called hot-reactive products.

L'introduction desdits fils de sécurité peut notamment engendrer un mauvais recouvrement desdits fil de sécurité se caractérisant, lorsqu'ils sont introduits en masse, par un manque de matière au-dessus desdits fils de sécurité et, lorsqu'ils sont introduits en fenêtre, par des pontages insuffisants. On désigne par pontage le recouvrement fibreux d'un fil de sécurité introduit en fenêtre dans les zones entre les fenêtres, c'est-à-dire aux endroits où le fil est contenu dans la masse de ladite feuille de sécurité. Ces manques de matière fibreuse sur ledit fil de sécurité sont couramment désignés par l'expression « effet de sparkling ». Ils sont d'autant plus prononcés que ladite feuille de sécurité dans laquelle lesdits fils de sécurité sont introduits est de faible grammage.The introduction of said security threads may in particular lead to a poor overlap of said security threads characterized, when they are introduced en masse, by a lack of material above said security threads and, when they are introduced in a window, by insufficient bridging. By bridging is meant the fibrous covering of a security thread introduced in the windows in the zones between the windows, that is to say at the places where the thread is contained in the mass of said security sheet. These lacks of fibrous material on said security thread are commonly referred to as "sparkling effect". They are all the more pronounced that said security sheet in which said security threads are introduced is of low grammage.

Cet effet de sparkling se traduit en particulier par des défauts visuels sur ladite feuille de sécurité et par une fragilisation de ladite feuille de sécurité, constituant ainsi un inconvénient des feuilles de sécurité de l'art antérieur contenant lesdits fils de sécurité.This sparkling effect is reflected in particular by visual defects on said security sheet and by embrittlement of said security sheet, thus constituting a drawback of the prior art security sheets containing said security threads.

En outre, l'incorporation en masse ou en fenêtre de fils de sécurité dont la largeur dépasse environ 1,5 cm est difficile car elle occasionne des ruptures de la feuille fibreuse au niveau de la « partie humide » de la machine à papier, c'est-à-dire avant séchage de la feuille de papier. De plus, plus les ruptures de la feuille interviennent en amont sur la machine à papier, plus elles sont gênantes, d'une part car le parcours pour amener la feuille jusqu'à l'enroulage est plus long, et d'autre part car ce parcours est plus difficile à réaliser, du fait de la moindre siccité et donc de la plus grande fragilité de la feuille. Une rupture de la feuille en partie humide sera donc plus gênante qu'une rupture en sécherie dans la mesure où elle demandera des temps de nettoyages, de redémarrage et de mise au bon de la production plus importants.In addition, the incorporation in mass or window safety son whose width exceeds about 1.5 cm is difficult because it causes breakage of the fibrous sheet at the "wet end" of the paper machine, c that is, before drying the paper sheet. In addition, the more the breaks in the sheet occur upstream on the paper machine, the more they are annoying, on the one hand because the path to bring the sheet up to winding is longer, and secondly because this course is more difficult to achieve, because of the less dry and therefore the greater fragility of the leaf. A rupture of the leaf in wet part will be more troublesome than a break in drying because it will require cleaning times, restart and put to good production more important.

Ces ruptures peuvent notamment provenir des défauts de recouvrement desdits fils de sécurité ou de leurs pontages insuffisants énoncés précédemment. En effet, plus lesdits fils de sécurité sont larges, plus lesdits défauts sont prononcés. Il en découle une plus grande fragilisation de la feuille, en particulier le long des bandes d'introduction desdits fils de sécurité, et par conséquent une plus grande fréquence des ruptures de la feuille.These failures can in particular be caused by defects in the coverage of said security threads or their insufficient bridging as previously stated. Indeed, the more said security son are wide, the more said defects are pronounced. This results in greater embrittlement of the sheet, in particular along the insertion strips of said safety threads, and consequently a greater frequency of breaks in the sheet.

De plus, les adhésifs, par exemple des enduits thermoscellants, qui peuvent être ajoutés auxdits fils de sécurité ne développent leurs propriétés adhésives qu'après séchage de ladite feuille de papier contenant lesdits fils de sécurité, et les matériaux plastiques constitutifs desdits fils de sécurité étant hydrophobes, lesdits fils de sécurité de l'art antérieur ne développent aucune liaison avec le substrat fibreux de ladite feuille de sécurité lors de l'égouttage et du pressage qui ont lieu en partie humide, c'est-à-dire, avant séchage de la feuille. Par conséquent, l'introduction desdits fils de sécurité fragilise ladite feuille de sécurité le long de la bande d'introduction, les propriétés d'adhésion dudit fil de sécurité enduit d'un adhésif, par exemple d'un produit thermoscellant, n'étant développées que lors du séchage.In addition, the adhesives, for example heat-sealing coatings, which can be added to said security threads develop their adhesive properties only after drying of said paper sheet containing said security threads, and the plastic materials constituting said security threads being hydrophobic, said security son of the art prior art do not develop any bond with the fibrous substrate of said security sheet during dewatering and pressing which take place in wet part, that is to say, before drying of the sheet. Consequently, the introduction of said security threads weakens said security sheet along the introduction strip, the adhesion properties of said security thread coated with an adhesive, for example a heat-sealing product, not being developed only during drying.

De plus, si lesdits fils de sécurité sont trop larges, leur imperméabilité gêne l'égouttage de l'eau contenue dans les fibres situées au-dessus des fils et empêche ainsi la consolidation du matelas fibreux, ce qui occasionne notamment des ruptures de la feuille de papier en partie humide, lors de la production de feuilles de sécurité contenant lesdits fils de sécurité. Lorsque la largeur desdits fils de sécurité dépasse environ 1,5 cm, le matelas fibreux n'est plus assez solide et engendre un trop grand nombre de ruptures de la feuille de papier pour permettre une machinabilité correcte de la machine à papier.In addition, if said security threads are too wide, their impermeability impedes the drainage of the water contained in the fibers located above the son and thus prevents the consolidation of the fibrous mat, which causes in particular breakage of the sheet partially wet paper during the production of security sheets containing said security threads. When the width of said security son exceeds about 1.5 cm, the fibrous mat is no longer strong enough and causes too many breaks of the paper sheet to allow a correct machinability of the paper machine.

Du fait des problèmes techniques exposés dans les paragraphes précédents, lesdits fils de sécurité ont notamment pour inconvénient leur largeur limitée.Because of the technical problems described in the preceding paragraphs, said security threads have the particular disadvantage of their limited width.

Les matériaux dont lesdits fils de sécurité sont composés sont généralement des films plastiques qui sont éventuellement métallisés puis éventuellement recouverts de vernis.The materials of which said security threads are composed are generally plastic films which are optionally metallized and then possibly coated with varnish.

Un autre inconvénient desdits fils de sécurité est qu'on ne peut les combiner qu'avec des particules très fines et, en particulier, par impression et/ou métallisation. A titre d'exemple, l'incorporation d'éléments de sécurité plats et de format relativement petit, tels que des planchettes, est impossible du fait des matériaux dont lesdits fils de sécurité sont constitués.Another disadvantage of said security threads is that they can be combined only with very fine particles and, in particular, by printing and / or metallization. For example, the incorporation of flat security elements and relatively small size, such as boards, is impossible because of the materials of which said security son are constituted.

La demande de brevet européen EP 0 557 157 de la Demanderesse décrit la fabrication d'une feuille de sécurité présentant des signes monochromes ou polychromes visibles en lumière transmise. La feuille de sécurité est fabriquée à partir d'au moins deux jets fibreux et d'une bande comportant des marques monochromes ou polychromes, introduite entre les deux jets fibreux. La bande ainsi introduite comporte avantageusement des fibres de cellulose et un produit liant soluble et/ou fusible de sorte que ledit produit puisse se disperser lors de l'incorporation de la bande entre les deux jets de manière à ce que la bande disparaisse au sein de la feuille et à ce que les marques imprimées se trouvent intimement liées à la feuille. La bande ainsi obtenue est complètement déstructurée au sein de la feuille de sécurité.The European patent application EP 0 557 157 of the Applicant describes the manufacture of a security sheet having monochrome or polychrome signs visible in transmitted light. The security sheet is manufactured from at least two fibrous jets and a strip having monochrome or polychrome marks introduced between the two fibrous jets. The strip thus introduced advantageously comprises cellulose fibers and a soluble and / or fusible binder product so that said product can be dispersed during the incorporation of the strip between the two jets so that the band disappears within sheet and that the printed marks are intimately linked to the sheet. The band thus obtained is completely destructured within the security sheet.

La demande FR 2 847 915 décrit l'incorporation, dans un papier sécurisé, d'un ruban réalisé en un tissu différent d'un papier.Requirement FR 2 847 915 discloses the incorporation, into a secure paper, of a ribbon made of a different tissue from a paper.

La demande de brevet français FR 2 679 934 de la Demanderesse décrit un système d'authentification d'un papier de sécurité à l'aide d'un premier réactif chimique présent sur le papier de sécurité, d'une composition d'authentification comprenant un second réactif chimique formant un produit coloré avec le premier réactif chimique et d'une composition d'effacement du produit coloré. La réaction chimique se produisant lors de l'authentification entre le second réactif et le premier réactif chimique engendre uniquement une coloration de la zone où se produit la réaction.The French patent application FR 2 679 934 of the Applicant describes a system for authenticating a security paper using a first chemical reagent present on the security paper, an authentication composition comprising a second chemical reagent forming a colored product with the first chemical reagent and an erasing composition of the colored product. The chemical reaction occurring during the authentication between the second reagent and the first chemical reagent only produces a coloration of the zone where the reaction occurs.

La demande internationale WO 2006/095033 concerne une bande de sécurité comportant un ruban d'un support cellulosique formé de fibres végétales. La cohésion et l'intégration du ruban dans le substrat de la bande sont assurées par la création de liaisons chimiques entre les fibres végétales contenues dans le ruban et dans le substrat, notamment des liaisons hydrogène, mais ne permettent pas au ruban de garder son intégrité et sa cohésion au sein du substrat de la bande, notamment lorsque la bande est placée dans un milieu humide, en cas de tentative de récupération de la bande par un contre facteur, par exemple.International demand WO 2006/095033 relates to a safety band comprising a ribbon of a cellulosic support formed of vegetable fibers. The cohesion and the integration of the ribbon in the substrate of the strip are ensured by the creation of chemical bonds between the vegetable fibers contained in the ribbon and in the substrate, in particular hydrogen bonds, but do not allow the ribbon to maintain its integrity. and its cohesion within the substrate of the strip, especially when the strip is placed in a wet environment, in case of an attempt to recover the strip by a counter factor, for example.

L'invention vise à perfectionner encore les feuilles de sécurité.The invention aims to further improve the security sheets.

L'invention concerne à cet effet une feuille de sécurité comprenant un substrat fibreux dans lequel est incorporé, au moins partiellement, un ruban s'étendant entre deux bords dudit substrat fibreux, ledit ruban de sécurité étant en papier.The invention relates for this purpose to a security sheet comprising a fibrous substrate in which is incorporated, at least partially, a ribbon extending between two edges of said fibrous substrate, said security tape being made of paper.

Le ruban de sécurité comporte, dans un exemple préféré de mise en oeuvre de l'invention, au moins un adhésif, par exemple au moins un agent thermoscellant.The security tape comprises, in a preferred embodiment of the invention, at least one adhesive, for example at least one heat-sealing agent.

Le ruban comporte également, dans un exemple préféré de mise en oeuvre de l'invention, au moins un élément de sécurité.The ribbon also comprises, in a preferred embodiment of the invention, at least one security element.

De préférence, le ruban s'étend entre deux bords opposés de ladite feuille de sécurité.Preferably, the ribbon extends between two opposite edges of said security sheet.

Le terme « substrat » désigne une feuille fibreuse pouvant notamment comprendre une ou plusieurs couches fibreuses. En particulier, on utilisera le terme « jets » pour désigner des couches produites en continu sur une même machine à papier puis associées à l'état humide.The term "substrate" denotes a fibrous sheet that may especially comprise one or more fibrous layers. In particular, the term "jets" will be used to denote layers produced continuously on the same paper machine and then associated with the wet state.

L'invention peut permettre de fournir une feuille de sécurité avec des éléments de sécurité disposés en bande selon une répartition spatiale (x,y,z) relativement homogène.The invention can make it possible to provide a security sheet with security elements arranged in a band with a relatively homogeneous spatial distribution (x, y, z).

L'adhésif ci-dessus permet d'optimiser l'adhésion du ruban de sécurité dans la feuille de sécuritéThe above adhesive optimizes the adhesion of the security tape in the security sheet

L'adhésif peut par exemple être un enduit thermoscellant, par exemple un vernis thermoscellant, un agent réticulable aux ultraviolets (UV), un adhésif à irradier, un adhésif sensible à la pression (PSA), un vernis avec une base solvant, du type polyester par exemple, un adhésif en phase aqueuse, etc...The adhesive may for example be a heat-sealing coating, for example a heat-sealing varnish, an ultraviolet (UV) cross-linkable agent, an adhesive to be irradiated, a pressure-sensitive adhesive (PSA), a varnish with a solvent base, of the type polyester for example, an adhesive in the aqueous phase, etc.

Comme adhésif en phase aqueuse, on peut notamment citer les marques suivantes : le Mowilith DC (dispersion aqueuse d'acétate de vinyle homopolymère avec des particules de taille allant de 0,3 µm à 2 µm et de température de transition vitreuse Tg de 38°C environ, et de teneur à sec en matières solides entre 55 et 57 %) et le Vinamul 3265 de la société CELANESE ; le DH9004, le DH9017, le DH9044 et le DL5001 de la société COLLANO ; le Primal NW1845, le Primal LC40, le Primal P308M et le Primal EP6000 de la société ROHM & HAAS ; le 006SDW078-2 de la société BASF.As adhesive in the aqueous phase, mention may be made especially of the following marks: Mowilith DC (aqueous dispersion of vinyl acetate homopolymer with particles of size ranging from 0.3 μm to 2 μm and glass transition temperature T g of 38 About C °, and solids dry content between 55 and 57%) and Vinamul 3265 from the company CELANESE; DH9004, DH9017, DH9044 and DL5001 from the company COLLANO; Primal NW1845, Primal LC40, Primal P308M and Primal EP6000 from ROHM &HAAS; the 006SDW078-2 from BASF.

L'adhésif peut avantageusement être un adhésif à base d'acétate de polyvinyle comme le Mowilith DC.The adhesive may advantageously be an adhesive based on polyvinyl acetate such as Mowilith DC.

La Demanderesse a pu constaté que parmi les adhésifs cités précédemment, le Vinamul 3265, le Mowilith DC, le Collano DL5001, le Primal NW1845 et le Primal P308M présentent de très bons résultats au test de froissage à sec, c'est-à-dire que la porosité du papier n'est pas excessivement affectée par le froissage.The Applicant has found that among the adhesives mentioned above, Vinamul 3265, Mowilith DC, Collano DL5001, Primal NW1845 and Primal P308M have very good results in the dry crumple test, that is to say that the porosity of the paper is not excessively affected by wrinkling.

De plus, le Vinamul 3265 et le Mowilith DC présentent également de très bons résultats au test de froissage humide.Le Mowilith DC présente de très bons résultats au test de lavage.In addition, Vinamul 3265 and Mowilith DC also perform very well in the wet crumple test. Mowilith DC has very good results in the wash test.

Aussi, le Mowilith DC procure de très bons résultats en terme de pouvoir d'adhésion, mais l'invention n'est pas limitée à un adhésif particulier.Also, Mowilith DC provides very good results in terms of adhesiveness, but the invention is not limited to a particular adhesive.

Selon un exemple de mise en oeuvre de l'invention, l'adhésif n'est pas présent sous forme de fibres, ni sous forme particulaire.According to an exemplary implementation of the invention, the adhesive is not present in the form of fibers or in particulate form.

L'incorporation de l'adhésif au ruban de sécurité peut se faire par enduction.The incorporation of the adhesive into the security tape can be done by coating.

L'enduction peut être réalisée au moins partiellement à coeur, c'est-à-dire atteindre en profondeur, voire en totalité le ruban de sécurité, ou en surface.The coating can be carried out at least partially at the core, that is to say reach in depth, or even in totality the security tape, or at the surface.

De préférence, l'enduction est réalisée sur le support servant à la fabrication du ruban avant découpage de ce support. En variante, l'enduction peut être réalisée pendant la fabrication du support servant à la fabrication du ruban de sécurité.Preferably, the coating is performed on the support used for the manufacture of the tape before cutting the support. Alternatively, the coating can be performed during the manufacture of the support for the manufacture of the security tape.

L'enduction peut être réalisée sur une seule face du support ou sur les deux faces du support. L'adhésif peut couvrir entièrement la face sur laquelle il est déposé.The coating can be performed on one side of the support or on both sides of the support. The adhesive can completely cover the face on which it is deposited.

L'incorporation de l'adhésif au ruban de sécurité peut également se faire par imprégnation, en plongeant le ruban ou le support servant à le fabriquer dans un bain.The incorporation of the adhesive tape security can also be done by impregnation, by dipping the tape or the support for making it in a bath.

Le ruban de sécurité conserve sa propre cohésion après introduction dans le substrat fibreux. Aussi, la structure du ruban de sécurité peut être observable après son introduction dans le substrat fibreux dans certaines conditions, par exemple en coupe ou par vision en réflexion ou en transmission. Ainsi, il peut être possible d'observer le ruban de sécurité grâce à des écarts de propriétés optiques, par exemple des différences de contraste, de teinte, de saturation, de clarté, d'opacité, qui rendent visible une frontière entre le ruban et le substrat ou caractérisent la présence du ruban.The safety tape retains its own cohesion after introduction into the fibrous substrate. Also, the structure of the security tape may be observable after its introduction into the fibrous substrate under certain conditions, for example in section or by vision in reflection or transmission. Thus, it may be possible to observe the security tape due to differences in optical properties, for example differences in contrast, hue, saturation, clarity, opacity, which make visible a border between the ribbon and the substrate or characterize the presence of the ribbon.

Afin de détecter la présence de l'adhésif dans une feuille de sécurité selon un exemple de mise en oeuvre de l'invention, il est possible d'observer l'adhésif, par exemple le vernis thermoscellant, sous la forme de bulles, par exemple à l'aide d'un microscope électronique à balayage (MEB).In order to detect the presence of the adhesive in a security sheet according to an exemplary embodiment of the invention, it is possible to observe the adhesive, for example the heat-sealing varnish, in the form of bubbles, for example using a scanning electron microscope (SEM).

Le ruban de sécurité peut être observable par topographie dans la feuille.The security tape may be observable by topography in the sheet.

Le ruban de sécurité peut être observable par transparence dans la feuille, notamment à l'oeil nu.The security tape can be observed by transparency in the sheet, in particular with the naked eye.

Le ruban de sécurité peut comprendre au moins un élément de sécurité sur l'une de ses faces, voire sur chacune de ses faces. Le ruban de sécurité peut comporter des éléments de sécurité différents sur chaque face.The security tape may comprise at least one security element on one of its faces, or even on each of its faces. The security tape may have different security features on each side.

Le ruban de sécurité peut présenter des bords de forme irrégulière, par exemple ayant la forme de lignes brisées ou ondulées, de créneaux, de zigzag, entre autres. Les bords du ruban de sécurité peuvent avoir les mêmes formes ou des formes différentes, régulières ou irrégulières.The security tape may have irregularly shaped edges, for example in the form of broken or wavy lines, crenellations, zigzag, among others. The edges of the security tape may have the same shapes or different shapes, regular or irregular.

Le ruban de sécurité peut être transparent ou translucide ou bien encore opaque, par exemple d'un aspect foncé, notamment plus sombre que le substrat. Il peut être introduit ou non en fenêtre dans le substrat fibreux. L'introduction en fenêtre peut notamment permettre d'obtenir différentes variations d'opacité lorsque le ruban de sécurité est opaque. Le ruban de sécurité peut éventuellement être combiné à une bande de matière thermoplastique et/ou métallique, par exemple de PET, contrecollée ou laminée à chaud au ruban avant son introduction dans le substrat fibreux.The security tape may be transparent or translucent or even opaque, for example a dark appearance, especially darker than the substrate. It can be introduced or not into the fibrous substrate window. The introduction in window can in particular make it possible to obtain different variations of opacity when the security tape is opaque. The security tape can optionally be combined with a strip of thermoplastic material and / or metal, for example PET, laminated or hot rolled to the ribbon before its introduction into the fibrous substrate.

Le ruban de sécurité peut encore présenter différentes caractéristiques perceptibles par exemple à la vue ou au toucher.The security tape can still have different characteristics perceptible for example to the sight or touch.

Le ruban de sécurité peut par exemple être embossé, permettant ainsi de créer un effet particulier, par exemple un effet tactile ou de relief en surface, le ruban pouvant apparaître partiellement sur la surface du substrat fibreux.The security tape may for example be embossed, thus creating a particular effect, for example a touch or surface relief, the ribbon may appear partially on the surface of the fibrous substrate.

Le ruban de sécurité peut être enduit d'un polymère thermoplastique puis éventuellement embossé à la suite de cette enduction.The security tape may be coated with a thermoplastic polymer and optionally embossed as a result of this coating.

Le ruban de sécurité peut être imprimé avec des gouttes de vernis, de résine ou d'encre thermogonflante, entre autres.The security tape can be printed with drops of varnish, resin or thermo-inking ink, among others.

Lorsque le ruban comporte des impressions, cela peut par exemple permettre d'obtenir des effets optiques variables.When the ribbon comprises impressions, this may for example allow to obtain variable optical effects.

Le ruban de sécurité peut comporter une encre thermogonflante permettant de créer au moins un relief, cette encre étant activée avant introduction du ruban dans le substrat fibreux. L'activation avant incorporation permet de réduire le risque de déstructuration de la feuille lors du gonflement de l'encre.The security tape may comprise a heat-reflecting ink for creating at least one relief, this ink being activated before introduction of the ribbon in the fibrous substrate. Activation before incorporation reduces the risk of destructuring the sheet during swelling of the ink.

Le ruban de sécurité peut comporter des particules, par exemple détectables à l'oeil nu ou au toucher, introduites en masse dans le ruban de sécurité, par exemple sous forme de billes, par exemple des billes d'une matière synthétique, par exemple le polyuréthane, ou minérale, par exemple le verre, de dimension par exemple inférieure à 300 µm, ou par dépôt par sérigraphie ou héliogravure, par exemple sous forme de billes, par exemple de dimension inférieure à 100 µm.The security tape may comprise particles, for example detectable with the naked eye or with the touch, introduced in mass in the security tape, for example in the form of balls, for example balls of a synthetic material, for example the polyurethane, or mineral, for example glass, of dimension for example less than 300 microns, or by deposition by screen printing or gravure, for example in the form of beads, for example less than 100 microns in size.

Le ruban de sécurité peut comporter une bande textile, par exemple tricotée, intégrée au ruban ou contrecollée au ruban.The security tape may comprise a textile band, for example knitted, integrated ribbon or laminated tape.

Le ruban de sécurité peut comporter une impression en relief, par exemple sérigraphiée.The security tape may include an embossed print, for example screen printed.

Le ruban de sécurité peut présenter au toucher un aspect gras, rugueux, lisse, soyeux, doux, entre autres.The safety tape may have a greasy, rough, smooth, silky, soft look, among other things.

Le ruban de sécurité peut notamment comporter des dépôts de polymères, notamment sous forme de billes, par exemple des billes de polyuréthane (PU), des billes de verre, des polyamides 6 ou 12, des pigments styrène-acrylique, des cires ou billes de polypropylène (PP), du polyéthylène (PE), du chlorure de polyvinyle (PVC), des polymères à base de méthacrylate de méthyle, le ruban étant par exemple introduit en fenêtre.The security tape may in particular comprise polymer deposits, in particular in the form of beads, for example polyurethane (PU) beads, glass, polyamides 6 or 12, styrene-acrylic pigments, polypropylene (PP) waxes or beads, polyethylene (PE), polyvinyl chloride (PVC), methyl methacrylate-based polymers, the ribbon being for example introduced in window.

Afin d'obtenir ledit ruban de sécurité, on peut fabriquer d'abord une feuille fibreuse, de préférence de faible grammage, par exemple entre environ 15 et 90 g/m2, selon un procédé papetier courant, c'est-à-dire par exemple par égouttage d'une suspension de fibres comprenant éventuellement des charges et des additifs classiques en papeterie, les éventuels éléments de sécurité spécifiques, pressage du matelas fibreux obtenu puis séchage. Cette feuille est ensuite éventuellement calandrée ce qui permet en particulier de réduire son épaisseur, puis on la coupe pour former des rubans qui sont alors enroulés en bobines.In order to obtain said security tape, it is possible to first manufacture a fibrous sheet, preferably of light weight, for example between about 15 and 90 g / m 2 , according to a current papermaking process, that is to say for example by draining a suspension of fibers optionally comprising conventional fillers and additives in stationery, the possible specific safety elements, pressing of the fibrous mat obtained and drying. This sheet is then optionally calendered which allows in particular to reduce its thickness, and then cut to form ribbons which are then wound into coils.

L'ajout de l'adhésif au ruban de sécurité peut notamment se faire par un procédé d'enduction, par exemple un couchage, ou par des procédés issus des techniques d'impression d'une base papier après sa fabrication, par exemple le couchage à lame d'air, l'héliogravure, la sérigraphie, le couchage à rideau, la flexographie, entre autres.The addition of the adhesive to the security tape may in particular be done by a coating process, for example a coating, or by processes resulting from printing techniques of a paper base after its manufacture, for example coating air-blast, rotogravure, screen printing, curtain coating, flexography, among others.

De préférence, on utilise un procédé d'héliogravure.Preferably, a photogravure process is used.

En variante, l'enduction du ruban de sécurité peut se faire lors de la fabrication de la feuille fibreuse, par exemple par une enduction de surface sur presse encolleuse ou par imprégnation.Alternatively, the coating of the security tape can be done during the manufacture of the fibrous sheet, for example by surface coating on sizing press or impregnation.

L'enduction de l'adhésif, par exemple sur une feuille fibreuse servant à la fabrication du ruban, peut se faire par exemple à raison de 2 à 15 g/m2 par face, de préférence entre 3 et 8 g/m2 par face.The coating of the adhesive, for example on a fibrous sheet used for the manufacture of the ribbon, can be carried out for example at a rate of 2 to 15 g / m 2 per side, preferably between 3 and 8 g / m 2 per face.

La température de scellage peut varier entre 70 et 135 °C, par exemple, selon l'adhésif employé, et le scellage peut avoir lieu lors du séchage de la feuille de sécurité.The sealing temperature can vary between 70 and 135 ° C, for example, depending on the adhesive used, and sealing can take place during drying of the security sheet.

Dans un exemple de mise en oeuvre de l'invention, on enduit une feuille fibreuse de 20 g/m2 ayant subi un traitement de résistance à l'état humide (REH), avec un adhésif en phase aqueuse à raison de 5 g/m2 par face, à l'aide, d'un procédé par héliogravure par exemple. On obtient ainsi un compromis satisfaisant entre pouvoir d'adhésion et quantité de matière enduite.In an exemplary embodiment of the invention, a 20 g / m 2 wet-strength fibrous sheet (REH) is coated with an adhesive in the aqueous phase at a rate of 5 g / m 2. m 2 per side, using, for example, a photogravure process. This gives a satisfactory compromise between adhesion power and amount of coated material.

L'introduction desdits rubans de sécurité au sein dudit substrat fibreux peut notamment se faire selon les modes d'introduction des fils de sécurité en plastique de l'art antérieur tels que décrits précédemment ou par contrecollage desdits rubans de sécurité entre deux feuilles ou couches fibreuses qui constituent alors la base dudit substrat fibreux.The introduction of said security ribbons within said fibrous substrate can in particular be done according to the introduction modes of the plastic security threads of the art. prior as described above or by laminating said security tapes between two sheets or fibrous layers which then constitute the base of said fibrous substrate.

Ladite feuille de sécurité proposée par la Demanderesse comprend au moins un ruban de sécurité en papier pouvant être plus large que lesdits fils de sécurité de l'art antérieur sans pour autant présenter des défauts de recouvrement fibreux ou des pontages insuffisants tels que décrits précédemment. Ceci résulte en particulier de la perméabilité desdits rubans de sécurité en papier qui favorise l'égouttage, ainsi que de la bonne affinité entre les fibres dudit ruban de sécurité en papier et la matière fibreuse dudit substrat.Said security sheet proposed by the Applicant comprises at least one paper security tape which may be wider than said security threads of the prior art without presenting fibrous overlap defects or insufficient bridging as described above. This results in particular from the permeability of said paper security ribbons which promotes drainage, as well as the good affinity between the fibers of said paper security tape and the fibrous material of said substrate.

De plus, lesdits rubans de sécurité peuvent être incorporés dans ledit substrat fibreux sans entraîner une augmentation de la fréquence des ruptures de la feuille, et ceci notamment en raison de la composition préférentielle desdits rubans de sécurité en papier. En effet, lesdits rubans de sécurité comprennent de préférence des matériaux fibreux hydrophiles, notamment tels que des fibres cellulosiques ou des fibres synthétiques ou éventuellement des fibres minérales traitées par ensimage, de manière à développer avec ledit substrat fibreux des liaisons permettant de réduire sa fragilisation due en particulier à l'introduction d'un élément dans ladite base fibreuse. L'ensimage est une enduction des fibres qui permet notamment de les rendre hydrophiles.In addition, said security tapes can be incorporated in said fibrous substrate without causing an increase in the frequency of breakage of the sheet, and this in particular because of the preferred composition of said paper security tapes. Indeed, said security tapes preferably comprise hydrophilic fibrous materials, in particular such as cellulosic fibers or synthetic fibers or optionally mineral fibers treated by sizing, so as to develop with said fibrous substrate bonds making it possible to reduce its embrittlement due to in particular to the introduction of an element into said fibrous base. The size is a fiber coating that allows in particular to make them hydrophilic.

On peut obtenir par conséquent une bonne cohésion de ladite feuille de sécurité et donc à la fois une bonne machinabilité en partie humide et la possibilité d'introduire des éléments de sécurité selon des bandes relativement larges.It is therefore possible to obtain a good cohesion of said security sheet and therefore both a good machinability in the wet part and the possibility of introducing security elements in relatively wide bands.

Par rapport à l'art antérieur consistant en l'introduction de petits éléments de sécurité en bande, par flux laminaire au-dessus d'une feuille de sécurité en formation sur une table plate ou par au moins une alimentation localisée lors de la formation d'une feuille de sécurité dans une cuve de forme, la présente invention peut permettre d'obtenir si on le souhaite lesdits éléments selon une bande dont les limites sont nettes et à l'intérieur de laquelle la répartition des éléments de sécurité est homogène.Compared to the prior art consisting of the introduction of small band security elements, by laminar flow over a safety sheet forming on a flat table or by at least one localized supply during the formation of A security sheet in a shaped tank, the present invention can achieve if desired said elements in a band whose boundaries are clear and within which the distribution of security elements is homogeneous.

De plus, du fait du mode d'incorporation dudit ruban de sécurité dans ledit substrat fibreux, le positionnement desdits éléments de sécurité dudit ruban de sécurité en papier dans l'épaisseur de ladite feuille de sécurité est amélioré. On résout ainsi les problèmes présentés ci-avant qui surviennent notamment lors de certaines authentifications basées sur la distribution spatiale (x,y,z) desdits éléments de sécurité.In addition, because of the mode of incorporation of said security tape in said fibrous substrate, the positioning of said security elements of said paper security tape in the thickness of said security sheet is improved. This solves the problems presented above which arise in particular for certain authentications based on the spatial distribution (x, y, z) of said security elements.

Selon un exemple de mise en oeuvre de l'invention, ledit substrat comprend, en plus dudit ruban de sécurité, au moins un élément de sécurité, en particulier choisi parmi les traceurs, notamment nanométriques, les fibres de sécurité notamment métalliques, magnétiques (à magnétisme doux et/ou dur), ou absorbantes ou excitables dans l'ultraviolet (UV), le visible ou l'infrarouge (IR) et en particulier le proche infrarouge (NIR), les éléments de sécurité plats et de format relativement petit tels que les planchettes, les pigments ou agglomérats de pigments notamment absorbants ou excitables sous illumination Laser ou dans l'ultraviolet (UV), le visible ou l'infrarouge (IR), en particulier le proche infrarouge (NIR), et les fils de sécurité (en général à base plastiques, notamment de polyester) comprenant notamment un revêtement au moins partiel, métallique, métallisé, iridescent ou magnétique (à magnétisme doux et/ou dur), ledit revêtement pouvant notamment comporter des motifs en positif ou en négatif et lesdits motifs pouvant notamment être obtenus par démétallisation, les réactifs chimiques ou biochimiques d'infalsification et/ou d'authentification et/ou d'identification pouvant notamment réagir avec au moins un agent respectivement de falsification et/ou d'authentification et/ou d'identification, et les éléments optiquement variables notamment des hologrammes, des cristaux liquides, des pigments iridescents ou des structures à effet miroir, en particulier des couches diélectriques, et leurs combinaisons.According to an exemplary embodiment of the invention, said substrate comprises, in addition to said security tape, at least one security element, in particular chosen from tracers, in particular nanoscale, security fibers, in particular metallic, magnetic (to soft and / or hard magnetism), or absorbent or excitable in the ultraviolet (UV), the visible or the infrared (IR) and in particular the near infrared (NIR), the flat and relatively small security elements such as that the boards, the pigments or agglomerates of pigments in particular absorbing or excitable under Laser illumination or in the ultraviolet (UV), the visible or the infrared (IR), in particular the near infrared (NIR), and the security threads (Generally based on plastics, in particular of polyester) comprising in particular an at least partial coating, metallic, metallized, iridescent or magnetic (with soft magnetism and / or hard), said coating being able in particular c have positive or negative motives and said patterns may in particular be obtained by demetallization, the chemical or biochemical infadification and / or authentication and / or identification reagents may in particular react with at least one agent respectively of falsification and and / or authentication and / or identification, and optically variable elements including holograms, liquid crystals, iridescent pigments or mirror effect structures, in particular dielectric layers, and combinations thereof.

Ledit substrat fibreux peut en particulier comporter des éléments de sécurité visibles à l'oeil nu mais il peut aussi comprendre des traceurs qui se présentent sous forme de matière active, de particules ou de fibres, capables de générer un signal spécifique lorsque ces traceurs sont soumis à une excitation optronique, électrique, magnétique ou électromagnétique. Ces « traceurs » constituent une substance identifiable grâce à une propriété distinctive et utilisée pour marquer un élément (un document de sécurité dans le cas présent) et assurer son suivi, le suivi de son évolution ou permettre sa reconnaissance, son authentification ou son identification.Said fibrous substrate may in particular comprise security elements visible to the naked eye, but it may also comprise tracers which are in the form of active material, particles or fibers, capable of generating a specific signal when these tracers are subject to to optronic, electrical, magnetic or electromagnetic excitation. These "tracers" constitute an identifiable substance through a distinctive property and used to mark an element (a security document in this case) and ensure its follow-up, the follow-up of its evolution or allow its recognition, authentication or identification.

Les structures diélectriques à effet miroir sont constituées d'une alternance de couches de haut et de bas indice, par exemple respectivement du dioxyde d'Hafnium et du dioxyde de Silice, et peuvent notamment être obtenues par gravure ionique.The dielectric structures with a mirror effect consist of an alternation of high and low index layers, for example respectively of Hafnium dioxide and of silica, and may in particular be obtained by ion etching.

Le ruban de sécurité en papier peut être à base de fibres cellulosiques (en particulier de fibres de coton) et/ou de fibres organiques naturelles autres que cellulosiques et/ou de fibres synthétiques, par exemple telles que des fibres de polyester ou de polyamide, et/ou éventuellement de fibres minérales, par exemple telles que des fibres de verre. Le ruban de sécurité peut ne pas comporter de fibres d'alcool polyvinylique (PVA).The paper security tape may be based on cellulosic fibers (in particular cotton fibers) and / or natural organic fibers other than cellulosic and / or synthetic fibers, for example such as polyester or polyester fibers. polyamide, and / or optionally mineral fibers, for example such as glass fibers. The safety tape may not include polyvinyl alcohol (PVA) fibers.

De préférence, lesdites fibres sont hydrophiles, notamment de manière à développer des liaisons chimiques, principalement hydrogène, avec ledit substrat fibreux.Preferably, said fibers are hydrophilic, in particular so as to develop chemical bonds, mainly hydrogen, with said fibrous substrate.

De préférence, ledit ruban de sécurité comprend en poids au moins 50 % de fibres cellulosiques.Preferably, said security tape comprises by weight at least 50% of cellulosic fibers.

Selon l'invention, le substrat fibreux est à base de fibres telles que décrites ci-dessus pour le ruban.According to the invention, the fibrous substrate is based on fibers as described above for the ribbon.

Selon un cas particulier de l'invention, le substrat fibreux et ledit ruban de sécurité sont à base des mêmes fibres, c'est à dire que leur composition en fibres est la même en nature et de préférence en mêmes proportions, ceci permet une bonne affinité entre les deux composants et peut, de plus, être un moyen d'authentification supplémentaire.According to a particular case of the invention, the fibrous substrate and said security tape are based on the same fibers, that is to say that their fiber composition is the same in nature and preferably in the same proportions, this allows good affinity between the two components and may, in addition, be an additional means of authentication.

Selon un cas particulier de l'invention, ledit ruban de sécurité a une largeur comprise entre 2 et 60 mm, de préférence entre 4 et 30 mm et plus préférentiellement entre 10 et 20 mm.According to a particular case of the invention, said security tape has a width of between 2 and 60 mm, preferably between 4 and 30 mm and more preferably between 10 and 20 mm.

En particulier, ledit ruban de sécurité peut comprendre des perforations, notamment afin de favoriser l'égouttage lors de la fabrication de ladite feuille de sécurité.In particular, said security tape may comprise perforations, in particular to promote drainage during the manufacture of said security sheet.

Selon un autre exemple de mise en oeuvre de l'invention, ledit ruban de sécurité a une épaisseur comprise entre 20 et 120 µm, de préférence entre 30 et 80 µm, et plus préférentiellement entre 45 et 55 µm.According to another example of implementation of the invention, said security tape has a thickness of between 20 and 120 microns, preferably between 30 and 80 microns, and more preferably between 45 and 55 microns.

Selon un autre cas particulier de l'invention, ledit ruban de sécurité comprend au moins un motif filigrané.According to another particular case of the invention, said security tape comprises at least one filigree pattern.

Selon un cas particulier de l'invention, ledit substrat fibreux comprend au moins un motif filigrané.According to a particular case of the invention, said fibrous substrate comprises at least one filigree pattern.

Selon un cas particulier de l'invention, ledit substrat fibreux et ledit ruban de sécurité comprennent chacun au moins un motif filigrané, lesdits motifs se complétant par superposition et/ou association.According to a particular case of the invention, said fibrous substrate and said safety tape each comprise at least one filigree pattern, said patterns being complemented by superposition and / or association.

En particulier, lesdits motifs filigranés peuvent se superposer de manière à obtenir un effet de moirage. Un tel effet fait apparaître un motif notamment produit par le rapprochement de lignes lors de la superposition de deux motifs à structure périodique et en particulier tramés.In particular, said filigree patterns may be superimposed so as to obtain a moire effect. Such an effect reveals a particular pattern produced by the approximation of lines during the superposition of two patterns of periodic structure and in particular screened.

Le ruban de sécurité peut comporter un filigrane et éventuellement des perforations autour de ce filigrane.The security tape may include a watermark and possibly perforations around this watermark.

Le ruban de sécurité peut encore être coloré, notamment avoir une couleur différente de celle du substrat.The security tape can still be colored, in particular having a different color from that of the substrate.

Pour un papetier producteur de documents filigranés, un autre avantage de l'invention dans le cas d'un ruban comportant un filigrane, est l'utilisation de ses outils et procédés de fabrication de feuille habituels. Il produit par exemple un stock de papiers filigranés, colorés ou non, qu'il découpe et stocke en rubans. Le moment voulu, ces rubans seront alors introduits lors de la production de feuilles de sécurité, ce qui permettra au papetier de travailler avec une « toile veline », c'est-à-dire non embossée. En effet l'embossage de la toile de fabrication qui permet la formation de filigranes sur les feuilles de sécurité de l'art antérieur a notamment pour inconvénient de nécessiter plusieurs jours de travail. Ainsi, l'incorporation de filigranes disposés sur des rubans de sécurité en papier permet de gagner en souplesse au niveau du planning de fabrication.For a papermaker producing watermarked documents, another advantage of the invention in the case of a ribbon having a watermark, is the use of its usual sheet making tools and processes. For example, it produces a stock of filigree papers, colored or not, which it cuts and stores in ribbons. At the desired moment, these ribbons will then be introduced during the production of security sheets, which will allow the paper manufacturer to work with a "veline canvas", that is to say, not embossed. Indeed the embossing of the fabric that allows the formation of watermarks on the security sheets of the prior art has the disadvantage of requiring several days of work. Thus, the incorporation of watermarks arranged on paper security ribbons makes it possible to gain flexibility in the planning of manufacture.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend au moins un élément de sécurité choisi parmi les traceurs, notamment nanométriques, les fibres de sécurité notamment métalliques, magnétiques (à magnétisme doux et/ou dur), ou absorbantes ou excitables dans l'ultraviolet (UV), le visible ou l'infrarouge (IR) et en particulier le proche infrarouge (NIR), les éléments de sécurité plats et de format relativement petit tels que les planchettes, les pigments ou agglomérats de pigments notamment absorbants ou excitables sous illumination Laser ou dans l'ultraviolet (UV), le visible ou l'infrarouge (IR), en particulier le proche infrarouge (NIR), et les fils de sécurité (à base plastiques, notamment de polyester) comprenant notamment un revêtement au moins partiel, métallique, métallisé, iridescent ou magnétique (à magnétisme doux et/ou dur), ledit revêtement pouvant notamment comporter des motifs en positif ou en négatif et lesdits motifs pouvant notamment être obtenus par démétallisation, les réactifs chimiques ou biochimiques d'infalsification et/ou d'authentification et/ou d'identification pouvant notamment réagir avec au moins un agent respectivement de falsification et/ou d'authentification et/ou d'identification, et les éléments optiquement variables notamment des hologrammes, des cristaux liquides, des pigments iridescents ou des structures à effet miroir, en particulier diélectriques, et leurs combinaisons.According to a particular case of the invention, said paper security tape comprises at least one security element chosen from tracers, in particular nanoscale, security fibers, especially metallic, magnetic (with soft magnetism and / or hard), or absorbing or excitable in the ultraviolet (UV), the visible or the infrared (IR) and in particular the near infrared (NIR), the flat and relatively small security elements such as boards, pigments or pigment agglomerates particularly absorbent or excitable under laser illumination or in the ultraviolet (UV), visible or infrared (IR), in particular the near infrared (NIR), and security son (based on plastics, especially polyester) comprising in particular an at least partial coating, metallic, metallized, iridescent or magnetic (with soft and / or hard magnetism), said coating being able to include, in particular, positive or negative patterns, and In particular, the units that may be obtained by demetallization, the chemical or biochemical infadification and / or authentication and / or identification reagents may in particular react with at least one falsification and / or authentication agent and / or identification, and optically variable elements including holograms, liquid crystals, iridescent pigments or mirror effect structures, particularly dielectric, and combinations thereof.

L'incorporation de traceurs dans un document de sécurité par le biais d'un ruban de sécurité en papier est localisée, ce qui permet notamment de créer une zone, éventuellement invisible à l'oeil nu, de reconnaissance et/ou d'authentification dudit document de sécurité. La reconnaissance et/ou l'authentification dudit document peut notamment être basée sur l'intensité et/ou le type du signal généré par les traceurs, considérés individuellement ou non, sur la densité des traceurs, ou encore sur leur distribution spatiale dans une zone prédéfinie ou non du document. En particulier, des traceurs répartis de manière aléatoire peuvent former une signature unique et ainsi être utilisés à des fins d'identification.The incorporation of tracers in a security document by means of a security paper tape is located, which allows in particular to create an area, possibly invisible to the naked eye, recognition and / or authentication of said security document. The recognition and / or authentication of said document may in particular be based on the intensity and / or the type of the signal generated by the tracers, considered individually or not, on the density of the tracers, or on their spatial distribution in a zone. predefined or not of the document. In particular, randomly distributed tracers can form a unique signature and thus be used for identification purposes.

En particulier, l'introduction dans une feuille de sécurité des pigments ou agglomérats de pigments absorbants dans l'infrarouge ou dans le proche infrarouge tels que précédemment cités, peut être utilisée afin de rendre ladite feuille authentifiable, comme décrit dans la demande de brevet WO 2005/034049 . Cette même demande préconise plus particulièrement l'utilisation de kaolin et de talc en mélange, produits qui sont d'usage courant dans le domaine papetier, dans une feuille de sécurité à zone dite de répartition variable et notamment filigranée. L'utilisation de ces composés permet en particulier une authentification de ladite feuille de sécurité par spectroscopie infrarouge, en particulier proche infrarouge, et une meilleure lecture optique des filigranes code-barre. Cependant, la quantité minimum de ces composés à introduire dans ladite feuille pour permettre une lecture optique et/ou une authentification correcte peut être trop importante par rapport aux quantités maximales de cendres définies dans certains cahiers des charges. La présente invention permet donc de résoudre le problème précédent, par exemple en fournissant une feuille de sécurité comportant un ruban de sécurité filigrané à base de matière fibreuse et d'un mélange de kaolin et de talc en proportion suffisante pour favoriser l'authentification par spectroscopie infrarouge dudit document ou la lecture optique dudit filigrane. En effet, le taux de kaolin et de talc sera particulièrement élevé, mais seulement dans la zone contenant ledit ruban de sécurité, de manière à ce que ladite feuille de sécurité comprenant ledit ruban de sécurité respecte les limites supérieures des taux de cendres inscrites dans lesdits cahiers des charges.In particular, the introduction into a security sheet of pigments or agglomerates of absorbent pigments in the infrared or in the near infrared as mentioned above, can be used to make said sheet authenticatable, as described in the patent application. WO 2005/034049 . This same application recommends more particularly the use of kaolin and talc mixed, products that are common in the paper industry, in a security sheet area called variable distribution and especially watermarked. The use of these compounds makes it possible, in particular, to authenticate said security sheet by infrared spectroscopy, in particular near-infrared spectroscopy, and better optical reading of bar-coded watermarks. However, the minimum amount of these compounds to be introduced into said sheet to allow optical reading and / or correct authentication may be too great compared to the maximum ash quantities defined in certain specifications. The present invention thus makes it possible to solve the above problem, for example by providing a security sheet comprising a filigree security tape made of fibrous material and a mixture of kaolin and talc in a proportion sufficient to promote spectroscopic authentication. infrared of said document or optical reading of said watermark. Indeed, the kaolin and talc content will be particularly high, but only in the zone containing said security tape, so that said security sheet comprising said security tape respects the upper limits of the ash levels inscribed in said specifications.

Dans le cas particulier d'un ruban de sécurité selon l'invention comprenant des fibres magnétiques, un avantage de l'invention concerne par exemple l'authentification d'un document de sécurité par analyse du signal de la réponse magnétique. En particulier, l'introduction en semis, c'est-à-dire en mélange dans la suspension fibreuse avant son égouttage, de fibres à magnétisme doux dites fibres « soft magnétiques » permet d'obtenir, de façon reproductible, une répartition homogène desdites fibres soft magnétiques. En revanche, l'introduction desdites fibres soft magnétiques en bande selon l'art antérieur, c'est-à-dire dans une forme ronde par des conduits d'alimentation localisés ou par flux laminaire au-dessus d'une table plate, induit une certaine variabilité de la concentration desdites fibres soft magnétiques, mais aussi de la largeur de ladite bande de fibres soft magnétiques. En utilisant un ruban de sécurité en papier fabriqué par découpe d'une feuille comprenant des fibres soft magnétiques introduites en semis, l'invention permet d'obtenir de façon reproductible une répartition homogène desdites fibres soft magnétiques. Ainsi, en faisant varier la concentration en fibres soft magnétiques et la largeur dudit ruban de sécurité introduit, on multiplie le nombre de « signatures » ou signaux magnétiques possibles.In the particular case of a security tape according to the invention comprising magnetic fibers, an advantage of the invention relates for example to the authentication of a security document by analyzing the signal of the magnetic response. In particular, the introduction into sowing, that is to say in the fibrous suspension mixture before it is dewatered, of soft magnetism fibers called "soft magnetic" fibers makes it possible, in a reproducible manner, to homogeneously distribute said magnetic soft fibers . On the other hand, the introduction of said magnetic soft fibers in strip according to the prior art, that is to say in a round shape by localized supply ducts or by laminar flow over a flat table, induced a certain variability in the concentration of said magnetic soft fibers, but also in the width of said magnetic soft fiber band. By using a paper security tape made by cutting a sheet comprising magnetic soft fibers introduced in seedling, the invention makes it possible to reproducibly obtain a homogeneous distribution of said magnetic soft fibers. Thus, by varying the concentration of magnetic soft fibers and the width of said introduced security tape, the number of "signatures" or possible magnetic signals is multiplied.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend au moins deux éléments de sécurité choisis parmi ceux cités précédemment.According to a particular case of the invention, said paper security tape comprises at least two security elements chosen from those mentioned above.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend entre 0,1 et 1% en poids sec de fibres magnétiques, en particulier à magnétisme doux, par rapport à la quantité totale de fibres, et de préférence entre 0,2 et 0,6 %.According to a particular case of the invention, said paper security tape comprises between 0.1 and 1% by dry weight of magnetic fibers, in particular with soft magnetism, with respect to the total amount of fibers, and preferably between 0 , 2 and 0.6%.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend une pluralité de planchettes réparties selon une densité surfacique comprise entre 4000 et 25000 planchettes/m2, de préférence entre 5000 et 20000 planchettes/m2 et plus préférentiellement entre 11000 et 18000 planchettes/m2.According to a particular case of the invention, said paper security tape comprises a plurality of small boards divided according to a surface density of between 4000 and 25000 boards / m 2 , preferably between 5000 and 20000 boards / m 2 and more preferably between 11000 and 18,000 boards / m 2 .

Selon un cas particulier de l'invention, ledit ruban de sécurité comprend une série de fils de sécurité parallèles, et plus particulièrement la succession des espaces inter-fils et/ou la série des différentes largeurs desdits fils de sécurité constituent un code, en particulier de type code-barre.According to a particular case of the invention, said security tape comprises a series of parallel safety wires, and more particularly the succession of inter-wire spaces and / or the series of different widths of said safety wires constitute a code, in particular barcode type.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend un fil antivol à magnétisme doux.According to a particular case of the invention, said paper security tape comprises a magnetic magnet anti-theft wire.

Ce type de fil de sécurité antivol peut être très coupant et donc difficilement incorporable à une feuille de sécurité, il arrive en particulier que ledit fil antivol, lorsqu'il est introduit selon l'art antérieur c'est-à-dire directement dans un substrat fibreux, ne soit pas totalement recouvert de fibres. L'incorporation d'un tel fil de sécurité antivol selon la présente invention consiste en la fabrication d'une feuille fibreuse dans laquelle on introduit plusieurs fils de sécurité antivol, ladite feuille de sécurité ainsi obtenue étant ensuite découpée en rubans comprenant au moins un fil antivol. Ces rubans sont ensuite introduits dans ledit substrat fibreux. Ainsi, les zones dudit ruban de sécurité pouvant présenter des défauts de recouvrement fibreux sont recouvertes par la matière fibreuse dudit substrat fibreux, et on obtient ainsi une feuille de sécurité comprenant au moins un fil de sécurité antivol et exempte de défauts de recouvrement.This type of antitheft security wire can be very sharp and therefore difficult to incorporate into a security sheet, it happens in particular that said antitheft wire, when introduced according to the prior art that is to say directly in a fibrous substrate, is not completely covered with fibers. The incorporation of such an antitheft security wire according to the The present invention consists in the manufacture of a fibrous sheet in which several anti-theft security threads are introduced, said security sheet thus obtained then being cut into ribbons comprising at least one anti-theft thread. These ribbons are then introduced into said fibrous substrate. Thus, the areas of said security tape which may have fibrous covering defects are covered by the fibrous material of said fibrous substrate, and thus a security sheet is obtained comprising at least one anti-theft security thread and free of covering defects.

Selon un cas particulier de l'invention, ledit ruban de sécurité comprend au moins un dispositif électronique. De préférence, ledit dispositif électronique est un dispositif d'identification par fréquences radio, plus couramment appelé dispositif RFID, et en particulier une puce électronique et/ou une antenne qui peut notamment être imprimée sur ledit ruban de sécurité en papier.According to a particular case of the invention, said security tape comprises at least one electronic device. Preferably, said electronic device is a radio frequency identification device, more commonly referred to as an RFID device, and in particular an electronic chip and / or an antenna which can notably be printed on said paper security tape.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend au moins un réactif chimique ou biochimique d'infalsification et/ou d'authentification et/ou d'identification réagissant de manière colorée, à au moins un agent respectivement de falsification et/ou d'authentification et/ou d'identification.According to a particular case of the invention, said paper security tape comprises at least one chemically or biochemical chemical tampering and / or authentication and / or identification reagent reacting in a colored manner, with at least one agent respectively of falsification and / or authentication and / or identification.

En particulier, un ruban de sécurité en papier comprenant un réactif chimique ou biochimique d'infalsification réagissant de manière colorée à au moins un agent de falsification peut notamment être situé sur une zone d'inscription des mentions variables susceptible d'être falsifiée. A titre d'exemple : sur un chèque, cette zone comprend notamment les zones destinées à l'inscription en chiffres et en lettres du montant dudit chèque ou du nom du destinataire du chèque.In particular, a paper security tape comprising a chemical or biochemical tampering reagent that reacts in a colored manner with at least one tampering agent can in particular be located on a zone of inscription of the variable information liable to be falsified. For example: on a check, this zone includes the areas intended for registration in figures and letters of the amount of the said check or the name of the recipient of the check.

Si ledit ruban de sécurité en papier comprend un réactif chimique ou biochimique d'authentification réagissant de manière colorée à au moins un agent d'authentification, on obtient une sécurisation supplémentaire de la feuille de sécurité contenant ledit ruban de sécurité en papier, la réaction d'authentification étant en effet localisée sur la zone où ledit ruban de sécurité en papier a été incorporé.If said paper security tape comprises a chemical or biochemical authentication reagent reacting in a colored manner with at least one authentication agent, additional security of the security sheet containing said paper security tape is obtained, the reaction of authentication being in fact located on the area where said paper security tape has been incorporated.

Un autre avantage du cas particulier précédent est de pouvoir utiliser au moins un réactif d'infalsification dans des documents destinés à recevoir un traitement de surface, notamment pour favoriser l'adhésion de l'encre lors de la personnalisation desdits documents. En effet, les réactifs de ce type ne sont généralement pas utilisés car ce sont des réactifs incompatibles avec les mélanges de dispersions colloïdales de polymèresAnother advantage of the above particular case is to be able to use at least one anti-tampering reagent in documents intended to receive a surface treatment, in particular to promote the adhesion of the ink during the personalization of said documents. Indeed, the reagents of this type are generally not used because they are reagents incompatible with the mixtures of colloidal dispersions of polymers.

(latex) couramment utilisés dans la composition desdits traitements de surface des papiers, à titre d'exemple on peut citer le latex du polymère styrène-butadiène commercialisé sous le nom Latexia 301 par la société Ciba. Dans la mesure où le ruban est introduit en masse, l'invention permet donc d'incorporer lesdits réactifs dans ledit ruban de sécurité en papier et d'appliquer au moins l'un desdits traitements de surface audit substrat fibreux sans rencontrer ce type de problème.(Latex) commonly used in the composition of said surface treatments of papers, by way of example, mention may be made of the latex of the styrene-butadiene polymer sold under the name Latexia 301 by the company Ciba. Insofar as the ribbon is introduced in bulk, the invention therefore makes it possible to incorporate said reagents in said paper security tape and to apply at least one of said surface treatments to said fibrous substrate without encountering this type of problem. .

Ce cas particulier a pour autre avantage de permettre l'utilisation de réactifs d'infalsification qui réagissent avec certains adhésifs, et notamment ceux utilisés sur des feuilles adhésivées, en particulier pour des Visas à coller sur les passeports ou pour les films de sécurité collés sur certains documents de sécurité. En effet, le fait d'incorporer lesdits réactifs dans ledit ruban de sécurité en papier permet d'isoler les réactifs et d'empêcher ainsi toute réaction prématurée entre lesdits réactifs et lesdits adhésifs notamment contenus sur lesdites feuilles adhésivées, sans empêcher la réaction avec les réactifs utilisés lors de tentatives de falsification desdits documents de sécurité contenant lesdites feuilles adhésivées.This particular case has the additional advantage of allowing the use of tampering reagents which react with certain adhesives, and in particular those used on adhesive-coated sheets, in particular for visas to be pasted on passports or for safety films stuck on some security documents. Indeed, the fact of incorporating said reagents into said paper security tape makes it possible to isolate the reagents and thus prevent any premature reaction between said reagents and said adhesives, especially contained on said adhesive-coated sheets, without preventing the reaction with them. reagents used in attempts to falsify said security documents containing said adhesive sheets.

De plus, dans le domaine desdits documents de sécurité, on requiert parfois un niveau de blancheur élevé qui peut être incompatible avec l'utilisation de certains desdits réactifs chimiques ou biochimiques d'infalsification et/ou d'authentification et/ou d'identification. L'incorporation dudit ruban de sécurité en papier permet alors d'introduire ces réactifs dans certaines zones d'un document tout en préservant la blancheur globale dudit document.In addition, in the field of said security documents, a high level of whiteness is sometimes required which may be incompatible with the use of some of said chemical or biochemical infalsification and / or authentication and / or identification reagents. The incorporation of said paper security tape then makes it possible to introduce these reagents into certain areas of a document while preserving the overall whiteness of said document.

Selon un cas particulier de l'invention, ledit substrat fibreux comprend au moins un réactif chimique ou biochimique d'infalsification et/ou d'authentification et/ou d'identification réagissant de manière colorée, à au moins un agent respectivement de falsification et/ou d'authentification et/ou d'identification.According to a particular case of the invention, said fibrous substrate comprises at least one chemically or biochemical chemical tampering and / or authentication and / or identification reagent reacting in a colored manner, with at least one agent respectively of falsification and / or or authentication and / or identification.

En particulier ledit ruban de sécurité en papier et ledit substrat fibreux comprennent chacun au moins un réactif chimique ou biochimique d'infalsification et/ou d'authentification et/ou d'identification réagissant de manière colorée, avec au moins un agent respectivement de falsification et/ou d'authentification et/ou d'identification. Lesdits réactifs chimiques ou biochimiques d'infalsification et/ou d'authentification et/ou d'identification sont de préférence différents et peuvent notamment réagir avec un seul et même agent ou avec deux agents différents.In particular, said paper security tape and said fibrous substrate each comprise at least one chemically or biochemical chemical tampering and / or authentication and / or identification reagent reacting in a colored manner, with at least one respectively tampering agent and / or authentication and / or identification. Said chemical or biochemical infalsification and / or authentication and / or identification reagents are preferably different and can in particular react with one and the same agent or with two different agents.

Selon un cas particulier de l'invention, ledit ruban de sécurité et ledit substrat fibreux de la feuille de sécurité comprennent chacun au moins un réactif chimique ou biochimique d'infalsification et/ou d'authentification et/ou d'identification, ces réactifs étant chimiquement incompatibles. On entend par « chimiquement incompatibles » que les réactifs peuvent réagir ensemble du fait qu'ils sont en contact ou qu'ils mettent enjeu des réactions chimiques, avec les agents de falsification ou d'authentification et/ou d'identification, qui sont incompatibles.According to a particular case of the invention, said security tape and said fibrous substrate of the security sheet each comprise at least one chemical or biochemical reagent for tampering and / or for authentication and / or identification, these reagents being chemically incompatible. The term "chemically incompatible" means that the reactants can react together because they are in contact with each other or because they involve chemical reactions, with the falsification or authentication and / or identification agents, which are incompatible with each other. .

En effet, dans l'art antérieur l'utilisation d'un seul substrat fibreux empêche parfois la combinaison de certains desdits réactifs chimiques ou biochimiques d'infalsification et/ou d'authentification et/ou d'identification qui, insérés dans un substrat commun, réagissent ensemble (réactifs incompatibles). De plus, lesdits réactifs chimiques ou biochimiques d'infalsification et/ou d'authentification et/ou d'identification peuvent être compatibles mais donner lieu à des réactions incompatibles lors de la tentative de falsification ou de l'authentification ou de l'identification dudit document de sécurité qui font que ledit document n'est pas endommagé lors de sa falsification ou que la réaction d'authentification ne donne pas le résultat escompté. L'utilisation d'au moins un ruban selon l'invention a donc notamment pour avantage de permettre la mise en oeuvre d'au moins deux réactifs ou réactions incompatibles.Indeed, in the prior art the use of a single fibrous substrate sometimes prevents the combination of some of said chemical or biochemical infalsification and / or authentication and / or identification reagents which, inserted into a common substrate react together (incompatible reagents). In addition, said chemical or biochemical reagents for tampering and / or authentication and / or identification may be compatible but give rise to incompatible reactions during the attempt to falsify or to the authentication or identification of said security document that make said document is not damaged during its forgery or that the authentication reaction does not give the expected result. The use of at least one ribbon according to the invention therefore has the particular advantage of allowing the use of at least two incompatible reagents or reactions.

Selon un cas particulier de l'invention, ledit ruban de sécurité comprend des perforations selon un motif ou un code. En fonction des différences d'opacité et de couleur entre ledit substrat et ledit ruban de sécurité, ledit motif ou code est observable, ou observable seulement en lumière transmise ou observable à la fois en lumière transmise et en lumière réfléchie. Si ledit ruban de sécurité possède une impression invisible fluorescente, ledit motif peut aussi être visible seulement sous illumination UV.According to a particular case of the invention, said security tape comprises perforations in a pattern or a code. Depending on the differences in opacity and color between said substrate and said security tape, said pattern or code is observable, or observable only in transmitted or observable light in both transmitted light and reflected light. If said security tape has an invisible fluorescent print, said pattern can also be visible only under UV illumination.

En particulier, ledit motif réalisé par perforation comprend au moins un caractère alphanumérique ou un idéogramme.In particular, said perforation pattern comprises at least one alphanumeric character or an ideogram.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier comprend des perforations selon un motif et comprend de plus un réactif chimique ou biochimique d'infalsification et/ou d'authentification et/ou d'identification réagissant de manière colorée. Lors d'une tentative de falsification et/ou lors de l'authentification et/ou d'identification dudit document, ledit réactif chimique ou biochimique réagit avec l'agent de falsification et/ou d'authentification et/ou d'identification selon une réaction qui donne une coloration particulière audit ruban de sécurité en papier. Ledit motif réalisé par perforation devient alors visible par contraste entre la coloration dudit ruban de sécurité en papier et celle dudit substrat fibreux.According to a particular case of the invention, said paper security tape comprises perforations in a pattern and further comprises a chemical reagent or biochemical for tampering and / or authentication and / or identification reacting in a colored manner. During an attempt to falsify and / or during the authentication and / or identification of said document, said chemical or biochemical reagent reacts with the falsification and / or authentication and / or identification agent according to a reaction that gives a particular coloration to said paper security tape. Said pattern made by perforation then becomes visible by contrast between the coloring of said paper security tape and that of said fibrous substrate.

Selon un cas particulier de l'invention, ledit ruban de sécurité est calandré. On réalise ce calandrage notamment afin de minimiser la surépaisseur créée par l'introduction dudit ruban de sécurité en papier.According to a particular case of the invention, said security tape is calendered. This calendering is carried out in particular to minimize the extra thickness created by the introduction of said paper security tape.

Selon un cas particulier de l'invention, ledit ruban de sécurité est exempt d'un revêtement de surface, en particulier exempt d'une couche pigmentée. La bonne affinité entre ledit substrat fibreux et ledit ruban de sécurité est ainsi favorisée.According to a particular case of the invention, said security tape is free of a surface coating, in particular free of a pigmented layer. The good affinity between said fibrous substrate and said security tape is thus favored.

Selon un autre cas particulier de l'invention et notamment pour accroître l'affinité entre ledit substrat fibreux et ledit ruban de sécurité, ledit ruban de sécurité comprend un agent adhésif activable à l'eau, par exemple un alcool polyvinylique (PVA), en particulier partiellement hydrolysé.According to another particular case of the invention and in particular to increase the affinity between said fibrous substrate and said safety tape, said security tape comprises a water-activatable adhesive agent, for example a polyvinyl alcohol (PVA), in particularly partially hydrolysed.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier présente une résistance à l'état humide (REH) par rapport à la traction supérieure à 30%, notamment afin de ne pas occasionner de problèmes lors de son introduction dans ladite feuille de sécurité. La résistance à l'état humide en traction est mesurée en divisant la valeur de la résistance humide à la traction mesurée selon la norme NF Q 03.056 par la résistance sèche à la traction mesurée selon la norme NF EN ISO 1924. Cette résistance à l'état humide peut notamment être apportée de manière conventionnelle par l'ajout d'un agent de résistance à l'état humide, par exemple tel qu'une résine polyamine-amide-épichlorhydrine (PAAE), une résine mélamine formol, etc...According to a particular case of the invention, said paper security tape has a wet strength (REH) with respect to traction greater than 30%, in particular so as not to cause problems when introduced into said security sheet. The resistance in the wet state in tension is measured by dividing the value of the wet tensile strength measured according to the NF Q 03.056 standard by the dry tensile strength measured according to the NF EN ISO 1924 standard. wet state may in particular be provided in a conventional manner by the addition of a wet strength agent, for example such as a polyamine-amide-epichlorohydrin resin (PAAE), a formaldehyde melamine resin, etc.

En variante, un complément de résistance à l'état humide (REH) peut être obtenu en ajoutant une partie du ou des agent(s) REH dans des bains de surfaçage d'une feuille fibreuse, servant par exemple à la fabrication du ruban de sécurité.Alternatively, an additional wet strength (REH) may be obtained by adding a portion of the REH agent (s) in surfactant baths of a fibrous sheet, for example for the manufacture of the fibrous web. security.

Selon un cas particulier de l'invention, ledit ruban de sécurité est compris en masse ou en fenêtre dans ledit substrat fibreux. Le ruban peut n'apparaître que sur une face de la feuille dans une fenêtre ou apparaître sur chaque face de la feuille dans une fenêtre traversante.According to a particular case of the invention, said security tape is comprised in mass or in window in said fibrous substrate. The ribbon may appear only on one side of the sheet in a window or appear on each face of the sheet in a through window.

Selon un cas particulier de l'invention, ledit substrat fibreux possède une monocouche fibreuse, en particulier monojet, ou plusieurs couches fibreuses, en particulier multijet. De préférence, ledit substrat fibreux comporte deux couches fibreuses, en particulier une structure bijet.According to a particular case of the invention, said fibrous substrate has a fibrous monolayer, in particular a single-ply, or several fibrous layers, in particular multijet. Preferably, said fibrous substrate comprises two fibrous layers, in particular a bijet structure.

Selon un cas particulier de l'invention, ledit ruban de sécurité et au moins l'une des couches dudit substrat fibreux ont des couleurs différentes. On atteint ainsi une sécurisation plus élevée due à la présence de deux couches fibreuses de couleurs différentes dans une même feuille de sécurité.According to a particular case of the invention, said security tape and at least one of the layers of said fibrous substrate have different colors. This achieves a higher security due to the presence of two fibrous layers of different colors in the same security sheet.

En particulier et de manière à accroître la sécurisation du document de sécurité qui comprendra une feuille de sécurité selon l'invention, ledit substrat de la feuille de sécurité et le ruban de sécurité sont de couleurs différentes et comprennent chacun un motif filigrané. La sécurisation dudit document de sécurité est ainsi améliorée du fait de la présence de deux filigranes de coloration différente à contretyper, notamment car l'utilisation d'encres transparentisantes, couramment employées pour contrefaire les filigranes, ne permet pas de créer de tels effets de couleur. De plus, cette sécurisation permet une authentification rapide dudit document de sécurité, la coloration desdits filigranes étant en effet aisément observable en lumière transmise.In particular and in order to increase the security of the security document which will comprise a security sheet according to the invention, said substrate of the security sheet and the security tape are of different colors and each comprise a filigree pattern. The security of said security document is thus improved because of the presence of two watermarks of different coloration to be counteracted, in particular because the use of transparent inks, commonly used to counterfeit watermarks, does not make it possible to create such color effects. . In addition, this security allows rapid authentication of said security document, the coloring of said watermarks being easily observable in transmitted light.

Selon un cas particulier de l'invention, ledit substrat fibreux comprend au moins deux rubans de sécurité en papier tels que décrits précédemment.According to a particular case of the invention, said fibrous substrate comprises at least two paper safety ribbons as described above.

En particulier, si ladite feuille de sécurité comprend deux rubans de sécurité, il est alors possible qu'ils contiennent respectivement deux réactifs différents donnant, par réaction avec un unique agent révélateur, deux couleurs localisées différentes. Il est en outre possible que lesdits rubans de sécurité réagissent spécifiquement à deux agents différents pour donner, de façon localisée, deux couleurs différentes ou non.In particular, if said security sheet comprises two security tapes, it is then possible that they respectively contain two different reagents giving, by reaction with a single developer, two different localized colors. It is also possible that said security tapes react specifically to two different agents to give, in a localized manner, two different colors or not.

L'invention concerne aussi un procédé de fabrication par voie papetière de ladite feuille de sécurité décrite précédemment selon lequel ledit ruban de sécurité à base de matière fibreuse est introduit en partie humide dans ledit substrat fibreux. Ledit ensemble substrat - ruban ainsi obtenu est ensuite pressé puis séché.The invention also relates to a process for the papermaking of said security sheet described above wherein said fibrous material-based security tape is introduced at a wet end into said fibrous substrate. Said substrate - ribbon assembly thus obtained is then pressed and dried.

Selon un cas particulier de l'invention, ledit ruban de sécurité est introduit en partie humide, en masse ou en fenêtre dans ledit substrat fibreux. A cet effet, on peut utiliser des procédés connus pour introduire des fils de sécurité en plastiques de l'art antérieur. Le ruban peut présenter l'une quelconque des caractéristiques détaillées ci-dessus, ou toute combinaison de celles-ci.According to a particular case of the invention, said security tape is introduced in wet part, in bulk or in window in said fibrous substrate. For this purpose, known methods can be used to introduce plastic security threads of the prior art. The ribbon may have any of the features detailed above, or any combination thereof.

Selon un cas particulier de l'invention, le procédé utilise une machine à papier qui est équipée d'au moins une forme ronde, et ledit ruban de sécurité est introduit dans la cuve de forme de ladite forme ronde, avant ou peu après le début de l'égouttage de la composition formant ledit substrat fibreux de la feuille.According to a particular case of the invention, the method uses a paper machine which is equipped with at least one round shape, and said security tape is introduced into the shaped tank of said round shape, before or shortly after the start dewatering the composition forming said fibrous substrate of the sheet.

Selon un cas particulier de l'invention, le procédé utilise une machine à papier qui est équipée d'au moins une table plate, et ledit ruban de sécurité en papier est introduit au-dessus de ladite table plate, pendant l'égouttage de la composition formant ledit substrat de la feuille.According to a particular case of the invention, the method uses a paper machine which is equipped with at least one flat table, and said paper security tape is introduced above said flat table, during the dewatering of the paper. composition forming said substrate of the sheet.

Selon un cas particulier de l'invention, ledit substrat fibreux comprend au moins deux jets, et ledit ruban de sécurité est introduit avant l'assemblage à l'état humide de deux jets successifs, c'est-à-dire, selon le procédé papetier courant, avant séchage de l'ensemble ruban de sécurité - jets fibreux du substrat.According to a particular case of the invention, said fibrous substrate comprises at least two jets, and said safety tape is introduced before wet assembly of two successive jets, that is to say, according to the method paper maker, before drying the safety tape assembly - fibrous jets from the substrate.

Selon un cas particulier de l'invention, ledit ruban de sécurité en papier tel que décrit précédemment est incorporé par contrecollage entre deux couches fibreuses dudit substrat fibreux de ladite feuille de sécurité.According to a particular case of the invention, said paper security tape as described above is incorporated by laminating between two fibrous layers of said fibrous substrate of said security sheet.

En particulier, ledit ruban de sécurité en papier peut apparaître en fenêtre, notamment si au moins l'une desdites couches comprend des perforations ou des zones dépourvues de matière.In particular, said paper security tape may appear in the window, especially if at least one of said layers comprises perforations or areas devoid of material.

L'invention concerne aussi le ruban de sécurité en papier tel que décrit précédemment.The invention also relates to the paper security tape as described above.

L'invention concerne aussi un document de sécurité comprenant une feuille de sécurité telle que décrite précédemment.The invention also relates to a security document comprising a security sheet as described above.

Ce document peut être fabriqué par découpe, association, reliure, laminage, collage et/ou contrecollage de cette feuille de sécurité.This document can be manufactured by cutting, binding, binding, rolling, gluing and / or laminating this security sheet.

Plus particulièrement ledit document de sécurité est un moyen de paiement, tel qu'un billet de banque, un chèque ou un ticket restaurant, un document d'identité tel qu'une carte d'identité ou un visa ou un passeport ou un permis de conduire, un ticket de loterie, un titre de transport ou encore un ticket d'entrée à des manifestations culturelles ou sportives.More particularly said security document is a means of payment, such as a bank note, a check or a restaurant ticket, an identity document such as an identity card or a visa or a passport or a permit. driving, a lottery ticket, a ticket or an entrance ticket to cultural or sports events.

L'invention concerne aussi un article à authentifier comprenant ladite feuille de sécurité telle que décrite ou obtenue précédemment, ledit article étant choisi parmi une étiquette de sécurité, un emballage, notamment un emballage pour les médicaments ou pour des aliments ou pour des parfums ou pour des pièces électroniques ou pour des pièces détachées, une feuille utilisée dans le domaine médical ou hospitalier, notamment un papier utilisé pour faire des emballages de stérilisation, et encore un papier d'art.The invention also relates to an article to be authenticated comprising said security sheet as described or obtained previously, said article being chosen from a security label, a packaging, in particular a packaging for the drugs or for food or for perfumes or for electronic parts or for spare parts, a sheet used in the medical or hospital field, including a paper used to make sterilization packaging, and still a paper art.

L'invention concerne aussi un procédé d'authentification d'une feuille de sécurité comprenant un ruban de sécurité qui comprend au moins un réactif chimique ou biochimique d'infalsification et/ou d'authentification et/ou d'identification réagissant de manière colorée avec au moins un agent respectivement de falsification et/ou d'authentification et/ou d'identification, ainsi que des perforations selon un motif ou un code. En absence ou avant application dudit agent de falsification ou d'authentification, ledit réactif chimique ou biochimique d'infalsification ou d'authentification et/ou d'identification n'ayant pas réagi, ledit motif ou ledit code perforé est invisible. Lorsque ladite feuille de sécurité est mise en présence d'un agent de falsification ou d'authentification et/ou d'identification, la réaction entre ledit réactif et ledit agent produit une coloration dudit ruban de sécurité qui rend lisible ledit motif ou ledit code perforé.The invention also relates to a method of authenticating a security sheet comprising a security tape which comprises at least one chemical or biochemical reagent for tampering and / or authentication and / or identification reacting in a colored manner with at least one falsification and / or authentication and / or identification agent respectively, as well as perforations according to a pattern or a code. In the absence or before application of said falsification or authentication agent, said chemical or biochemical reagent tampering or authentication and / or unreacted identification, said pattern or said perforated code is invisible. When said security sheet is placed in the presence of a falsification or authentication and / or identification agent, the reaction between said reagent and said agent produces a coloration of said security tape which renders said pattern or said perforated code readable .

Le dit procédé se caractérise donc en ce que la réaction entre ledit réactif d'infalsification et/ou d'authentification et/ou d'identification, et un agent respectivement de falsification et/ou d'authentification et/ou d'identification donne une coloration audit ruban de sécurité en papier rendant observables lesdites perforations, en particulier ledit motif ou ledit code perforé, sur ledit ruban de sécurité.The said method is therefore characterized in that the reaction between said tampering and / or authentication and / or identification reagent, and an agent for falsification and / or authentication and / or identification, respectively, gives a coloring said paper security tape making said perforations, in particular said pattern or said perforated code, observable on said security tape.

Selon un autre de ces aspects, l'invention concerne également une feuille de sécurité comprenant un substrat fibreux dans lequel est incorporé, au moins partiellement, un ruban de sécurité, comprenant de préférence au moins un élément de sécurité, s'étendant entre deux bords dudit substrat fibreux, ledit ruban de sécurité étant en papier et comportant un filigrane. Le ruban peut présenter une ou plusieurs des caractéristiques ci-dessus.According to another of these aspects, the invention also relates to a security sheet comprising a fibrous substrate in which is incorporated, at least partially, a security tape, preferably comprising at least one security element, extending between two edges. said fibrous substrate, said security tape being made of paper and having a watermark. The ribbon may have one or more of the above features.

Selon encore un autre de ces aspects, l'invention concerne également une feuille de sécurité comprenant un substrat fibreux dans lequel est incorporé, au moins partiellement, un ruban de .sécurité, comprenant de préférence au moins un élément de sécurité, et s'étendant entre deux bords dudit substrat fibreux, ledit ruban de sécurité étant en papier et présentant une couleur différente d'au moins une couche dudit substrat fibreux. Par « couleur différente », il faut comprendre un écart de couleur visible à l'oeil nu. Le ruban peut présenter une ou plusieurs des caractéristiques ci-dessus.According to yet another of these aspects, the invention also relates to a security sheet comprising a fibrous substrate in which is incorporated, at least partially, a security tape, preferably comprising at least one security element, and extending between two edges of said fibrous substrate, said security tape being made of paper and having a different color than at least one layer of said fibrous substrate. By "different color" is meant a color difference visible to the naked eye. The ribbon may have one or more of the above features.

L'invention sera mieux comprise à la lecture des exemples non limitatifs et des figures qui suivent.The invention will be better understood on reading the non-limiting examples and the figures which follow.

EXEMPLES PROPOSESPROPOSED EXAMPLES Exemple 1Example 1

On considère la réalisation, sur une machine à papier à forme ronde, d'une feuille de sécurité comprenant un ruban de sécurité en papier comprenant comme élément de sécurité des planchettes comportant une impression invisible fluorescente et incorporé dans un substrat fibreux filigrané.Considering the realization, on a paper machine with round shape, a security sheet comprising a paper security tape comprising as security element boards with a fluorescent invisible printing and incorporated into a filigree fibrous substrate.

Fabrication des rubans de sécurité selon l'invention :Manufacture of security tapes according to the invention:

On fabrique une feuille de papier sur une machine à papier à table plate. On ajoute les planchettes imprimées avec une encre fluorescente à la suspension aqueuse de fibres de cellulose raffinées de l'ordre de 30°SR, on presse le matelas fibreux contenant ces planchettes en semis et on le sèche. Ladite feuille obtenue une fois séchée, a un grammage de 45 g/m2.A sheet of paper is made on a flat-table paper machine. The boards printed with a fluorescent ink are added to the aqueous suspension of refined cellulose fibers of the order of 30 ° SR, the fibrous mat containing these boards is sown and dried. Said sheet obtained once dried has a basis weight of 45 g / m 2 .

On obtient ainsi une feuille comprenant des planchettes invisibles fluorescentes en semis, réparties de façon homogène dans l'espace, qui est alors calandrée, enduite par héliogravure sur la totalité de ses deux faces d'adhésif MOWILITH DC à raison de 5 g/m2 par face, puis découpée en rubans de 1,5 cm de large, lesdits rubans étant représentés sur la figure 1. On bobine les rubans.This gives a sheet comprising invisible fluorescent seed boards, distributed homogeneously in space, which is then calendered, coated by gravure on all of its two faces of adhesive MOWILITH DC at a rate of 5 g / m 2 per side, then cut into 1.5 cm wide ribbons, said ribbons being represented on the figure 1 . We reel the ribbons.

Fabrication de la feuille de sécurité comprenant un ruban en papier selon l'invention.Manufacture of the security sheet comprising a paper ribbon according to the invention.

Lors de la fabrication dudit substrat filigrané fibreux sur la forme ronde, on introduit en masse lesdits rubans de sécurité dans la cuve de forme de la forme ronde.During the manufacture of said fibrous filigreed substrate on the round shape, said security tapes are introduced in the round shape into the round shape of the tank.

Après égouttage, pressage puis séchage de l'ensemble substrat - ruban, on obtient une feuille de sécurité selon l'invention représentée de face sur la figure 2 et selon une coupe dans l'épaisseur sur la figure 3.After draining, pressing and then drying the substrate-ribbon assembly, a security sheet is obtained according to the invention shown in front on the figure 2 and according to a cut in the thickness on the figure 3 .

Dans une variante où l'on ne recherche pas l'adhésion du ruban, le ruban n'est pas enduit avec l'adhésif MOWILITH, toutes les autres étapes étant par ailleurs effectuées.In a variant where adhesion of the tape is not desired, the tape is not coated with the MOWILITH adhesive, all other steps being performed.

Exemple 2Example 2

On considère la réalisation d'une feuille de sécurité comprenant un ruban de sécurité en papier comprenant comme élément de sécurité des fibres à magnétisme doux, incorporé en masse dans un substrat fibreux.It is considered the production of a security sheet comprising a paper security tape comprising, as a security element, soft magnetism fibers embedded in a fibrous substrate.

Fabrication des rubans de sécurité selon l'invention :Manufacture of security tapes according to the invention:

On fabrique une feuille sur une machine à papier à table plate selon la méthode traditionnelle, c'est-à-dire par égouttage, pressage puis séchage d'une suspension aqueuse de fibres de cellulose raffinées à 32°SR. Lesdites fibres de sécurité à magnétisme doux sont des fibres d'un alliage de Nickel et de fer appelé Supermalloy®. Ces fibres ont un diamètre de 10 µm et une longueur moyenne de 3 mm et sont introduites en mélange dans la suspension fibreuse à hauteur de 0,7 % en masse par rapport à la composition fibreuse dans le cuvier de tête, c'est-à-dire avant la formation de ladite feuille.A sheet is made on a flat-bed paper machine according to the traditional method, that is to say by draining, pressing and then drying an aqueous suspension of refined cellulose fibers at 32 ° SR. Said soft magnetic security fibers are fibers of an alloy of nickel and iron called Supermalloy ® . These fibers have a diameter of 10 μm and an average length of 3 mm and are introduced as a mixture into the fibrous suspension at a level of 0.7% by weight relative to the fibrous composition in the leading vat, that is to say say before the formation of said sheet.

On obtient une feuille d'un grammage de 35 g/m2 qui est ensuite calandrée, enduite d'adhésif, par exemple par héliogravure sur ses deux faces avec l'adhésif MOWILITH DC à raison de 5 g/m2 par face, puis découpée en rubans de 3,5 cm de large. On bobine éventuellement les rubans.A sheet of a grammage of 35 g / m 2 is obtained which is then calendered, coated with adhesive, for example by gravure on both sides with MOWILITH DC adhesive at a rate of 5 g / m 2 per side, then cut into ribbons 3.5 cm wide. The ribbons may be reeled.

On obtient ainsi des rubans de sécurité comprenant des fibres à magnétisme doux dont la répartition spatiale est homogène.This produces safety ribbons comprising soft magnetism fibers whose spatial distribution is homogeneous.

Fabrication de la feuille de sécurité comprenant un ruban en papier selon l'invention.Manufacture of the security sheet comprising a paper ribbon according to the invention.

On fabrique sur une machine à papier à table plate la feuille de sécurité en introduisant en masse lesdits rubans de sécurité dans la composition fibreuse formant le substrat. Les rubans de sécurité sont introduits lors de l'égouttage, entre le matelas fibreux en formation et le rouleau égoutteur situé sur la table de formation, et la feuille est ensuite pressée. Après séchage, la feuille de sécurité ainsi obtenue a un grammage de 100 g/m2.The security sheet is made on a flat-bed paper machine by mass-introducing said security strips into the fibrous composition forming the substrate. The security tapes are introduced during dewatering, between the fibrous mat forming and the dough roll located on the forming table, and the sheet is then pressed. After drying, the security sheet thus obtained has a basis weight of 100 g / m 2 .

En utilisant un détecteur magnétique adéquat, la répartition homogène en fibres magnétiques dans le ruban et la largeur régulière dudit ruban de sécurité permettent d'authentifier et/ou d'identifier ladite feuille de sécurité de façon fiable.By using a suitable magnetic detector, the homogeneous distribution of magnetic fibers in the ribbon and the regular width of said security tape make it possible to authenticate and / or identify said security sheet reliably.

Dans une variante ou l'adhésion du ruban n'est pas recherchée, l'enduction avec l'adhésif n'est pas effectuée, toutes les autres étapes étant reproduites par ailleurs.In a variant where the adhesion of the ribbon is not desired, the coating with the adhesive is not carried out, all the other steps being reproduced elsewhere.

Dans une autre variante, la dépose de l'adhésif s'effectue par presse encolleuse.In another variant, the removal of the adhesive is carried out by gluing press.

Exemple 3Example 3

On considère la réalisation, sur une machine à papier à table plate, d'une feuille de sécurité comprenant un ruban de sécurité ayant comme élément de sécurité une couche iridescente, incorporé en fenêtre dans le substrat fibreux de la feuille.It is considered the realization, on a flat-table paper machine, of a security sheet comprising a security tape having as security element an iridescent layer, incorporated into the fibrous fibrous substrate of the sheet.

Fabrication des rubans de sécurité selon l'invention :Manufacture of security tapes according to the invention:

Par voie papetière sur table plate on fabrique une feuille de papier à base de fibres de cellulose raffinées à 25°SR. La feuille ainsi obtenue est calandrée puis recouverte, par impression héliogravure, de pigments iridescents mica-titane bleu/rose Iriodin® de la société Merck. La composition contenant les pigments peut contenir également l'adhésif, en tant que co-liant, par exemple l'adhésif MOWILITH DC. Cette feuille qui pèse 55 g/m2 est ensuite découpée en rubans de 5 mm de large.By paper-making on a flat table is made a paper sheet based on refined cellulose fibers at 25 ° SR. The sheet thus obtained is calendered and then covered, by gravure printing, iridescent pigments blue-pink mica-titanium Iriodin® Merck. The composition containing the pigments may also contain the adhesive, as a co-binder, for example MOWILITH DC adhesive. This sheet which weighs 55 g / m 2 is then cut into ribbons 5 mm wide.

Fabrication de la feuille de sécurité comprenant un ruban en papier selon l'invention.Manufacture of the security sheet comprising a paper ribbon according to the invention.

Sur une forme ronde on forme le substrat fibreux de la feuille dans lequel on introduit lesdits rubans de sécurité, au repère et en fenêtre, selon le procédé d'introduction en fenêtre de fils de sécurité sur une machine à papier à forme ronde décrit dans la demande de brevet EP 059 056 .On a round shape, the fibrous substrate of the sheet is formed in which said security strips, at the mark and in the window, are introduced, according to the method of introducing security threads onto a round-shaped paper machine described in FIG. patent application EP 059 056 .

La feuille de sécurité résultante comprend donc un couchage iridescent apparaissant selon des pointillés du fait de l'introduction en fenêtre dudit ruban de sécurité.The resulting security sheet thus comprises an iridescent coating appearing according to dashed lines because of the window introduction of said security tape.

Dans une variante, l'adhésif est déposé sur la couche de pigments.In a variant, the adhesive is deposited on the layer of pigments.

Exemple 4Example 4

On considère la réalisation, sur une machine à papier à forme ronde, d'une feuille de sécurité comprenant un substrat fibreux de couleur naturelle blanche comprenant un filigrane et d'un ruban de sécurité en papier jaune comprenant un filigrane. Ledit ruban et ledit substrat forment une feuille de sécurité telle que les deux motifs filigranés se complètent.Considering the realization, on a round paper machine, of a security sheet comprising a white natural color fibrous substrate comprising a watermark and a yellow paper security tape comprising a watermark. Said ribbon and said substrate form a security sheet such that the two filigree patterns complement each other.

Fabrication des rubans de sécurité selon l'invention.Manufacture of security tapes according to the invention.

Sur une forme ronde, on fabrique à partir d'une suspension aqueuse de fibres de cellulose raffinées à 40°SR comprenant un colorant jaune, une feuille de papier de coloration jaune et filigranée selon un motif représentant une chevelure. La feuille exempte de surfaçage et de couchage ainsi obtenue pèse 70 g/m2, elle est ensuite calandrée, enduite par héliogravure de MOWILITH DC sur ses deux faces à raison de 5 g/m2 par face, puis découpée en rubans de 5 cm de large. Un tel ruban de sécurité est représenté sur la figure 4b.On a round shape, a paper of yellow color and watermarked in a pattern representing a hair is made from an aqueous suspension of cellulose fibers refined at 40 ° SR comprising a yellow dye. The surfacing and coating free sheet thus obtained weighs 70 g / m 2 , it is then calendered, coated by gravure printing of MOWILITH DC on both sides at a rate of 5 g / m 2 per side, then cut into strips of 5 cm wide. Such a security tape is shown on the figure 4b .

Fabrication de la feuille de sécurité comprenant un ruban en papier selon l'invention.Manufacture of the security sheet comprising a paper ribbon according to the invention.

Sur une machine à forme ronde, on forme le substrat fibreux de la feuille à partir d'une suspension aqueuse de fibres de cellulose raffinées de l'ordre de 38°SR et on forme un motif filigrané selon un visage complétant la chevelure filigranée du ruban ; lesdits rubans de sécurité sont introduits dans la masse du substrat en formation au repère de manière à ce que les filigranes du ruban et du substrat se complètent pour former un visage. Selon le procédé d'introduction dans la masse de fils de sécurité sur une machine à papier à forme ronde, lesdits rubans de sécurité sont introduits lors de l'égouttage de la suspension fibreuse sur la forme ronde, dans la cuve de forme. Après pressage puis séchage, on obtient une feuille dont le grammage est de 80 g/m2.On a round machine, the fibrous substrate of the sheet is formed from an aqueous suspension of refined cellulose fibers of the order of 38 ° SR and a filigree pattern is formed according to a face completing the filigree hair of the ribbon. ; said security strips are introduced into the mass of the substrate forming the mark so that the watermarks of the ribbon and the substrate complement each other to form a face. According to the method of introduction into the mass of security threads on a round-shaped paper machine, said security tapes are introduced during the dewatering of the fibrous suspension on the round shape, in the form tank. After pressing and drying, a sheet is obtained whose weight is 80 g / m 2 .

La feuille de sécurité résultante comporte donc un filigrane bicolore visible en lumière transmise, tel que celui représenté sur la figure 4.The resulting security sheet therefore has a two-color watermark visible in transmitted light, such as that shown on the figure 4 .

Exemple 5Example 5

Dans cet exemple, le ruban n'est pas enduit d'adhésif, car ce n'est pas la forte adhésion du ruban dans le substrat qui est recherchée. Cet exemple met en oeuvre des aspects de l'invention indépendants de la présence d'adhésif sur le ruban.In this example, the tape is not coated with adhesive, because it is not the strong adhesion of the ribbon in the substrate is sought. This example implements aspects of the invention independent of the presence of adhesive on the ribbon.

On considère la réalisation, sur une machine à papier à forme ronde, d'une feuille de sécurité comprenant un substrat fibreux comprenant un réactif chimique d'authentification réagissant de manière colorée à un agent d'authentification externe qui peut être présent dans un stylo d'authentification et un ruban de sécurité en papier qui comprend lui-même un réactif chimique d'authentification réagissant de manière colorée à l'agent d'authentification présent dans ledit stylo.Considering the realization, on a round paper machine, of a security sheet comprising a fibrous substrate comprising an authentication chemical reagent reacting in a colored manner to an external authentication agent which may be present in a pen. authentication and a security paper tape which itself comprises an authentication chemical reagent reacting in a colored manner to the authentication agent present in said pen.

Fabrication des rubans de sécurité selon l'invention :Manufacture of security tapes according to the invention:

On forme sur une machine à table plate une feuille de type overlay à partir d'une suspension aqueuse de fibres de cellulose raffinées, de l'ordre de 30 °SR, et on introduit une composition de paranitrophénol par un surfaçage de la feuille en presse encolleuse. Cette feuille de papier a un grammage de 30 g/m2 et comprend donc du paranitrophénol comme réactif chimique d'authentification qui pourra réagir sur toute sa surface de manière colorée avec de la soude (hydroxide de sodium) faiblement concentrée, la soude étant l'agent d'authentification externe contenu dans le stylo. Le paranitrophénol, est incolore et prend une coloration jaune en présence de soude faiblement concentrée. La feuille exempte de couchage ainsi obtenue est ensuite calandrée puis découpée en rubans de 2 cm de large.A sheet of the overlay type is formed on a flat-table machine from an aqueous suspension of refined cellulose fibers, of the order of 30 ° SR, and a paranitrophenol composition is introduced by surfacing the sheet in the press. gluer. This sheet of paper has a grammage of 30 g / m 2 and therefore includes paranitrophenol as an authentication chemical reagent that can react on its entire surface in a colored manner with soda (sodium hydroxide) weakly concentrated, the soda being the external authentication agent contained in the pen. Paranitrophenol is colorless and yellow in the presence of weakly concentrated sodium hydroxide. The coating-free sheet thus obtained is then calendered and then cut into strips of 2 cm wide.

Fabrication de la feuille de sécurité comprenant un ruban en papier selon l'invention.Manufacture of the security sheet comprising a paper ribbon according to the invention.

On fabrique sur une machine à papier à forme ronde, le substrat de la feuille à partir d'une suspension aqueuse de fibres cellulosiques comportant un autre réactif chimique d'authentification réagissant aussi de manière colorée avec de la soude faiblement concentrée. Ce réactif est un indicateur coloré pour chèque dérivé du xanthène, il est incolore et prend une coloration bleue en présence de soude faiblement concentrée, qui est l'agent d'authentification contenu dans ledit stylo.The substrate of the sheet is made on a round paper machine from an aqueous suspension of cellulosic fibers comprising another authentication chemical reagent also reacting in a colored manner with weakly concentrated sodium hydroxide. This reagent is a colored indicator for check derived from xanthene, it is colorless and takes a blue color in the presence of weakly concentrated soda, which is the authentication agent contained in said pen.

Lesdits rubans de sécurité obtenus précédemment sont introduits en masse lors de la formation dudit substrat, selon un procédé courant d'introduction en masse de fils de sécurité sur une machine à papier à forme ronde tel que décrit dans l'exemple 4.Said security tapes obtained previously are introduced in bulk during the formation of said substrate, according to a common method of mass introduction of security threads on a round-shaped paper machine as described in Example 4.

La feuille de sécurité résultante a un grammage de 80g/m2.The resulting security sheet has a basis weight of 80 g / m 2 .

Cette feuille est authentifiable avec un niveau de sécurité accru. En effet, en utilisant sur ladite feuille un stylo d'authentification contenant de la soude faiblement concentrée, on fait apparaître une première couleur bleue sur les zones où il n'y a pas ledit ruban de sécurité en papier puis une seconde couleur verte sur les zones situées au-dessus dudit ruban de sécurité en papier, ladite couleur verte résultant du mélange des couleurs jaune et bleue, respectivement dudit ruban de sécurité en papier et dudit substrat fibreux.This sheet is authenticatable with an increased level of security. Indeed, by using on said sheet an authentication pen containing weakly concentrated sodium hydroxide, a first blue color appears on the areas where there is no paper security tape and a second green color on the areas above said paper security tape, said green color resulting from mixing the yellow and blue colors respectively of said paper security tape and said fibrous substrate.

DESCRIPTIONDESCRIPTION DES FIGURESFIGURES

  • La figure 1 représente une vue de face sous illumination UV d'un ruban de sécurité 1 comprenant des planchettes 4 imprimées avec une encre invisible fluorescente.The figure 1 represents a front view under UV illumination of a security tape 1 comprising boards 4 printed with an invisible fluorescent ink.
  • La figure 2 représente une vue de face sous illumination UV d'une feuille de sécurité 2 contenant ledit ruban de sécurité 1 de la figure 1.The figure 2 represents a front view under UV illumination of a security sheet 2 containing said security tape 1 of the figure 1 .
  • La figure 3 représente une coupe dans l'épaisseur selon (AA') de la feuille de sécurité 3 objet de l'invention représentée de face sur la figure 2.The figure 3 represents a section in the thickness according to (AA ') of the security sheet 3 which is the subject of the invention represented frontally on the figure 2 .
  • La figure 4 représente, selon une vue de face, un objet de l'invention 3 comprenant une feuille de sécurité filigranée 2 représentée de face sur la figure 4a dans laquelle est incorporé un ruban de sécurité en papier filigrané 1 représenté de face sur la figure 4b.The figure 4 represents, according to a front view, an object of the invention 3 comprising a watermark security sheet 2 represented frontally on the figure 4a in which is incorporated a watermark paper security tape 1 shown front on the figure 4b .
  • La figure 5 représente une vue de face d'une feuille de sécurité 3 objet de l'invention dans laquelle est incorporé un ruban de sécurité en papier 1 perforé selon un texte et qui comprend un réactif d'infalsification réagissant de manière colorée aux agents de falsification.The figure 5 is a front view of a security sheet 3 object of the invention in which is incorporated a paper security tape 1 perforated according to a text and which comprises an infalsification reagent reacting in a colored manner to the falsification agents.
  • La figure 6 représente une image par transparence d'une feuille de sécurité selon l'invention, comportant un ruban de sécurité.The figure 6 represents a transparency image of a security sheet according to the invention, comprising a security tape.
  • La figure 7 représente une image par topographie d'une feuille de sécurité selon l'invention, comportant un ruban de sécurité.The figure 7 represents a topographic image of a security sheet according to the invention, comprising a security tape.

Le ruban de sécurité en papier 1 représentée sur la figure 1 a une largeur de 1,5 cm et il est sécurisé par des planchettes 4 d'environ 3 mm imprimées avec une encre invisible fluorescente de sorte qu'elles soient visibles seulement sous une illumination UV. La répartition desdites planchettes 4 dans ledit ruban de sécurité en papier 1 est homogène et leur observation sous illumination UV fait apparaître une bande dont les bords sont relativement réguliers.The paper security tape 1 shown on the figure 1 has a width of 1.5 cm and is secured by boards 4 about 3 mm printed with an invisible ink fluorescent so that they are visible only under UV illumination. The distribution of said boards 4 in said paper security tape 1 is homogeneous and their observation under UV illumination shows a band whose edges are relatively regular.

Un objet de l'invention 3 est représenté sur la figure 2, il est constitué d'une feuille de sécurité 2 de dimensions 6 x 12 cm comprenant dans sa masse un ruban de sécurité en papier 1 sécurisé par lesdites planchettes 4 et représenté sur la figure 1. Ce ruban de sécurité en papier 1 est introduit à une distance de 2 cm par rapport au bord de la feuille de sécurité 2. Lesdites planchettes 4 étant invisibles fluorescentes, elles sont invisibles si on les observe en lumière transmise et/ou réfléchie. En revanche, sous illumination UV, on aperçoit lesdites planchettes 4 disposées selon une bande correspondant audit ruban de sécurité en papier 1, de répartition homogène et aux bords relativement réguliers.An object of the invention 3 is represented on the figure 2 , it consists of a security sheet 2 of dimensions 6 x 12 cm comprising in its mass a security paper tape 1 secured by said boards 4 and shown on the figure 1 . This security paper tape 1 is introduced at a distance of 2 cm from the edge of the security sheet 2. Said boards 4 being invisible fluorescent, they are invisible if observed in transmitted and / or reflected light. On the other hand, under UV illumination, said boards 4 can be seen arranged in a strip corresponding to said paper security strip 1, of homogeneous distribution and with relatively regular edges.

Une coupe selon (AA') de la figure 2 est représentée sur la figure 3. Cette coupe dans l'épaisseur de ladite feuille de sécurité 3 objet de l'invention fait apparaître ledit ruban de sécurité en papier 1 comprenant lesdites planchettes 4 et contenu dans la masse de la feuille de sécurité 2.A section according to (AA ') of the figure 2 is represented on the figure 3 . This cut in the thickness of said security sheet 3 object of the invention reveals said paper security tape 1 comprising said boards 4 and contained in the mass of the security sheet 2.

Un autre objet de l'invention 3 est représenté sur la figure 4. Il comprend un substrat fibreux 2 de dimensions 6 x 12 cm, filigrané et dont le filigrane représente un visage 5a tel que représenté de face sur la figure 4a, ainsi qu'un ruban de sécurité en papier 1 de 5 cm de large, de coloration jaune et filigrané, dont le filigrane représente une chevelure 5b telle que représentée sur la figure 4b. Ladite feuille de sécurité 3 comprenant ledit ruban de sécurité en papier 1 à une distance de 4 cm de son bord est représentée sur la figure 4, elle contient un filigrane 5 représentant une tête composée d'une chevelure 5b jaune et d'un visage 5a en nuances de gris.Another object of the invention 3 is represented on the figure 4 . It comprises a fibrous substrate 2 of dimensions 6 × 12 cm, watermarked and whose watermark represents a face 5a as represented frontally on the figure 4a as well as a paper security tape 1 of 5 cm wide, yellow in color and watermarked, the watermark of which represents a hair 5b as shown in FIG. figure 4b . Said security sheet 3 comprising said security paper tape 1 at a distance of 4 cm from its edge is represented on the figure 4 it contains a watermark representing a head composed of a yellow hair 5b and a face 5a in shades of gray.

Un objet de l'invention 3 est représenté sur la figure 5, il comprend une feuille de sécurité 2 de dimensions 6 x 12 cm et dans la masse de laquelle est incorporé un ruban de sécurité en papier 1 de 2 cm de large et qui comprend des perforations 6 d'un diamètre de 2 mm, ainsi qu'un sulfate de manganèse qui agira en tant que réactif d'infalsification non coloré. Lesdites perforations 6 forment le mot « FALSIFIE ». Lors de l'utilisation normale dudit objet de l'invention 3, ledit ruban de sécurité en papier 1 et lesdites perforations 6 ne sont pas observables ni en lumière transmise ni en lumière réfléchie. En revanche, le même objet de l'invention 3 ayant fait l'objet d'une tentative de falsification par trempage dans un bain d'hypochlorite de sodium, et couramment utilisé pour la falsification des écritures manuelles, est représenté sur la figure 5. Le sel de manganèse contenu dans ledit ruban de sécurité en papier 1 a réagi avec le bain d'hypochlorite de sodium pour donner un produit de coloration brune. Lesdites perforations 6 deviennent donc observables et font apparaître en négatif le mot « FALSIFIE » signifiant la tentative de falsification dudit objet de l'invention 3.An object of the invention 3 is represented on the figure 5 it comprises a security sheet 2 of dimensions 6 × 12 cm and in the mass of which is incorporated a paper security tape 1 of 2 cm wide and which comprises perforations 6 with a diameter of 2 mm, as well as a manganese sulfate which will act as an undyed tampering reagent. Said perforations 6 form the word "FALSIFIE". During normal use of said object of the invention 3, said paper security tape 1 and said perforations 6 are not observable either in transmitted light or in reflected light. On the other hand, the same object of the invention 3 having been the object of an attempt of falsification by soaking in a bath of sodium hypochlorite, and commonly used for the falsification of manual writing, is represented on the figure 5 . The manganese salt contained in said paper security tape 1 reacted with the sodium hypochlorite bath to give a brown coloring product. Said perforations 6 thus become observable and show in negative the word "FALSIFIE" signifying the attempt to falsify said object of the invention 3.

Il est possible de détecter de diverses façons le ruban de sécurité après incorporation à la feuille de sécurité.The security tape can be detected in various ways after incorporation into the security sheet.

Par exemple, le ruban peut être détecté par observation directe de la feuille de sécurité, à l'oeil nu en lumière réfléchie ou en lumière transmise. Des différences de teinte, d'épair et/ou d'opacité entre le ruban et le substrat fibreux peuvent permettre de déterminer la présence du ruban.For example, the ribbon can be detected by direct observation of the security sheet, to the naked eye in reflected light or transmitted light. Differences in hue, appearance, and / or opacity between the ribbon and the fibrous substrate may determine the presence of the ribbon.

En variante, il est possible d'obtenir une image de la feuille de sécurité par topographie ou par transparence afin d'observer par exemple l'épair et la topographie du papier. Par exemple, on peut remarquer la présence du ruban de sécurité, notamment par différences de contraste, sur les figures 6 et 7, qui sont respectivement des images de la feuille de sécurité par transparence et par topographie.As a variant, it is possible to obtain an image of the security sheet by topography or by transparency in order to observe, for example, the epair and the topography of the paper. For example, one can notice the presence of the security tape, in particular by differences of contrast, on the Figures 6 and 7 , which are respectively images of the security sheet by transparency and by topography.

De plus, il est encore possible de repérer la présence du ruban de sécurité par la présence de l'adhésif, par exemple un vernis thermoscellant, qui peut être observé sous la forme de bulles par observation au microscope électronique à balayage (MEB).In addition, it is still possible to identify the presence of the security tape by the presence of the adhesive, for example a heat-sealing varnish, which can be observed in the form of bubbles by observation by scanning electron microscope (SEM).

L'expression « comportant un » est synonyme de comportant « au moins un ».The phrase "having one" is synonymous with having "at least one".

Claims (15)

  1. Security sheet comprising a fibrous substrate into which is incorporated, at least partially, a security tape comprising at least one security element and extending continuously between two edges of said fibrous substrate;
    security sheet characterized by the fact that said security tape is made of paper and comprises an adhesive.
  2. Security sheet according to claim 1, characterized in that the security tape comprises a watermark.
  3. Security sheet according to claim 1 or 2, characterized in that the security tape has a different color from at least one layer of said fibrous substrate.
  4. Security sheet according to at least one of the preceding claims, characterized in that said security tape is based on cellulosic fibers, in particular cotton fibers, and/or natural organic fibers other than cellulosic fibers and/or synthetic fibers and/or eventually mineral fibers.
  5. Security sheet according to at least one of the preceding claims, characterized in that said security tape in paper is based on hydrophilic fibers.
  6. Security sheet according to at least one of claims 4 or 5, characterized in that said security tape in paper comprises at least 50% of cellulosic fibers.
  7. Security sheet according to at least one of the preceding claims, characterized in that said fibrous substrate and said paper security tape are based on the same types of fibers, in particular if appropriate in the same proportions in the case of two or more sorts of fibers.
  8. Security sheet according to at least one of the preceding claims, characterized in that said security tape has a width between 2 and 60 mm, preferably between 4 and 30 mm, and more preferably between 10 and 20 mm.
  9. Security sheet according to at least one of the preceding claims, characterized in that said security tape has a thickness between 20 and 120 µm, preferably between 30 and 80 µm, and more preferably between 45 and 55 µm.
  10. Security sheet according to at least one of the preceding claims, characterized in that said fibrous substrate and said paper security tape each comprise at least one watermark pattern and in that said patterns are complementary to one another by superimposition and/or combination, the security tape having preferably a different color from that of the substrate.
    The security sheet as claimed in claim 54, wherein said fibrous substrate is based on cellulosic fibers and/or natural organic fibers other than cellulosic fibers and/or synthetic fibers and/or mineral fibers.
  11. Security sheet according to any one of the preceding claims, the adhesive comprising polyvinyl acetate.
  12. Security sheet according to any one of the preceding claims, the tape comprising between 2 and 15 g/m2 of the adhesive, better between 3 and 8 g/m2.
  13. Security sheet according to at least one of the preceding claims, characterized in that the adhesive comprises a water-activable adhesive agent that is a polyvinyl alcohol, preferably partially hydrolyzed.
  14. Security sheet according to at least one of the preceding claims, characterized in that the adhesive comprises a heat sealing agent.
  15. Method for fabricating a security sheet, comprising a fibrous substrate and a security tape in paper, as claimed in one of the preceding claims, characterized in that the security sheet is formed by a papermaking process which comprises the following steps :
    - in the wet end of the papermaking process, said paper security tape is inserted into said fibrous substrate in formation,
    - the substrate-tape combination thereby obtained is pressed,
    - the assembly is then dried.
EP07858556.9A 2006-10-12 2007-10-11 Security film comprising a fibrous substrate Revoked EP2082097B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL07858556T PL2082097T3 (en) 2006-10-12 2007-10-11 Security film comprising a fibrous substrate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0608949A FR2907136B1 (en) 2006-10-12 2006-10-12 SECURITY TAPE, SHEET AND SECURITY DOCUMENT COMPRISING IT AND METHOD OF INCORPORATING IT
PCT/FR2007/052126 WO2008043965A2 (en) 2006-10-12 2007-10-11 Security film comprising a fibrous substrate

Publications (2)

Publication Number Publication Date
EP2082097A2 EP2082097A2 (en) 2009-07-29
EP2082097B1 true EP2082097B1 (en) 2015-08-26

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EP07858556.9A Revoked EP2082097B1 (en) 2006-10-12 2007-10-11 Security film comprising a fibrous substrate

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US (1) US8376409B2 (en)
EP (1) EP2082097B1 (en)
BR (1) BRPI0719827B1 (en)
CA (1) CA2672752A1 (en)
ES (1) ES2553888T3 (en)
FR (1) FR2907136B1 (en)
PL (1) PL2082097T3 (en)
WO (1) WO2008043965A2 (en)

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FR2907136B1 (en) 2010-01-15
BRPI0719827B1 (en) 2019-01-22
CA2672752A1 (en) 2008-04-17
ES2553888T3 (en) 2015-12-14
PL2082097T3 (en) 2016-01-29
WO2008043965A2 (en) 2008-04-17
US20100071609A1 (en) 2010-03-25
FR2907136A1 (en) 2008-04-18
US8376409B2 (en) 2013-02-19
WO2008043965A3 (en) 2008-05-29
BRPI0719827A2 (en) 2014-05-06
EP2082097A2 (en) 2009-07-29

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