EP2077949A2 - Manufacturing process to produce litho sheet - Google Patents
Manufacturing process to produce litho sheetInfo
- Publication number
- EP2077949A2 EP2077949A2 EP07759824A EP07759824A EP2077949A2 EP 2077949 A2 EP2077949 A2 EP 2077949A2 EP 07759824 A EP07759824 A EP 07759824A EP 07759824 A EP07759824 A EP 07759824A EP 2077949 A2 EP2077949 A2 EP 2077949A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- less
- equal
- alloy
- current
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N1/00—Printing plates or foils; Materials therefor
- B41N1/04—Printing plates or foils; Materials therefor metallic
- B41N1/08—Printing plates or foils; Materials therefor metallic for lithographic printing
- B41N1/083—Printing plates or foils; Materials therefor metallic for lithographic printing made of aluminium or aluminium alloys or having such surface layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/03—Chemical or electrical pretreatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/03—Chemical or electrical pretreatment
- B41N3/034—Chemical or electrical pretreatment characterised by the electrochemical treatment of the aluminum support, e.g. anodisation, electro-graining; Sealing of the anodised layer; Treatment of the anodic layer with inorganic compounds; Colouring of the anodic layer
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
Definitions
- This invention in one embodiment relates to an Al alloy and yet in another
- Lithographic sheet manufacturing typically includes a
- electrograining roughening
- a finished printing plate formed of lithographic sheet is inserted into the
- Al-materials for offset printing plates must exhibit sufficiently high fatigue strength or reversed bending fatigue strength
- the present invention provides an alloy suitable for
- the aluminum alloy includes:
- the aluminum alloy includes:
- a lithographic sheet including a electrolytic pre-etching step.
- method for producing a lithographic sheet includes:
- peaks may be obtained from a thyristor power supply which conducts in either one or
- Figure 1 shows the sinusoidal wave form of current used in the prior art
- Figures 2a-2c represent micrographs of a lithographic sheet surface formed
- Figures 3a-3c represent micrographs of a lithographic sheet surface formed
- Figures 4a-4c represent micrographs of a lithographic sheet surface formed
- Figures 5a-5c represent micrographs of a lithographic sheet surface formed
- Lithographic sheet is used in printing
- aluminum alloy means aluminum alloy
- the alloy of the present invention includes:
- the Mg content may range from 0.31 wt % to about
- the Si content may range from about 0.05 wt % to about
- the Si content may range from about 0.8 wt % to
- Si in solution may alter the reactivity of the lithographic sheet during
- Low pitting density may be have a surface characterized
- plateaus that may be detected by
- S negative skewness
- the Si content is too great, too few pits may form during electro-graining, in which the
- excess pitting may be
- a surfacing having at least two pits with a diameter greater than 10 ⁇ m
- the Fe content may range from about 0.25 wt % to
- the Fe content may range from about
- Mg present ranging from 0.31 wt % to approximately
- mixtures further including additives selected from the group including but not limited to
- the Mg content may range from 0.31 wt
- Mg is one element in the alloy that may provide for
- electrograining acids such as HNO 3 or HCl.
- the temi increased mechanical strength means that a
- present invention and work hardened to H 18, may have an ultimate tensile strength
- inventive aluminum alloy has a higher ultimate
- the H 18 designation means that the material was cold rolled at a temperature not
- a hard material denotes a Brinell hardness greater than about 50.
- Zn may be present in less than or equal to about 0.03
- the Zn content may range from 0.01 wt % to 0.03 wt %.
- Zn is advantageous for electro-graining in nitric acid.
- Zn is electrochemically anodic with respect to aluminum and functions as
- the initiator for pit formation during electrograining.
- Ti may be present in less than or equal to about 0.03
- micrographs do not include isolated pits having a diameter greater than about 10 ⁇ m in
- Grain refiner such as TiB 2 , may or may not be present. Ti combined with
- Mn is present in less than about 0.25 wt %, preferably
- Mn may have a strengthening effect.
- Mn may be present within a range of about 0.01 wt % to about 0.25 wt %. In one embodiment, Mn may be present from about 0.05 wt % to about 0.25 wt % to
- Cu may be present in up to about 0.04 %, and in one embodiment of the
- present invention is limited to about 0.007 wt % or less.
- the alloy includes about 0.8 wt % to about 0.12 wt %
- the lithographic sheet forming process begins with providing a direct cast
- titanium boride may be employed as a grain refiner.
- the ingot is scalped in a machining
- the pre-heat step prepares the ingot for hot rolling and provides for a
- the pre-heat step is
- heat time may range from 2-20 hours depending on the heat up cycle of the furnace.
- the ingot is then hot rolled to a thickness ranging from about 7.5 mm to
- the hot rolling apparatus may be single stand or multi-stand hot mill.
- the strip is then coiled, in which the coiling temperature is
- the sheet may experience surface defects including but not limited to
- the strip is cold rolled
- the annealing atmosphere may or may not be an inert atmosphere.
- the strip is then cold rolled to a final gauge, i.e. ranging from about 0.1 mm to about 0.5
- the aluminum strip is then treated with an electrolytic pre- etching or
- an electrolytic pre-etching step including a
- coating may be an aluminum oxide having a thickness of about 100 nm or less, and in yet
- another embodiment may be a thickness ranging from about 1 nm to about 30 nm. It is
- the electrolytic pre-etching step includes passing the
- the mineral acid bath may include any one of the minerals acid bath (electrolyte)
- mineral acid is in a concentration of about 5% to about 35%, and yet in an even further
- the mineral acid bath may be about 15% to about 25%. In one embodiment,
- the mineral acid includes sulfuric, phosphoric, or sulfuric-phosphoric mixtures.
- the aluminum content of the electrolyte should be kept below about 15 g/1
- the mineral acid wherein higher levels may decrease conductivity.
- the mineral acid is sodium tartrate
- bath includes phosphoric acid ranging from about 10% to about 30%, and in yet another
- embodiment approximately 20% phosphoric acid, and containing about 2 g/1 to about 15
- the temperature of the mineral acid bath is the temperature of the mineral acid bath
- acid bath may include chromic, boric, and tartaric acids and combinations thereof.
- Figure 1 shows the non-sinusoidal wave form 10 of the current generated
- a thyristor power supply which is used during pre-etching when practicing this
- the operating frequency of the thyristor power supply is at least several
- form 10 here disclosed can be generated by a thyristor power supply where the
- conduction angle is selected for the exact current density applied to the aluminum sheet.
- the peak voltage ranges from about 35 to about 60 volts.
- the thyristor power supply maintains a constant peak voltage. Degreasing
- Peak current is related to peak voltage.
- cathodic and anodic current the current having a non-sinusoidal wave form 10
- the aluminum strip may be roughened by
- electrograining and may be treated by similar processes used to provide lithographic sheet and plates. Suitable electrograining response may be achieved with the alloy and
- the present alloy and processing method provides a lithographic sheet
- form 10 which can be asymmetrical or symmetrical and has a constant peak voltage.
- Table 1 below shows the composition of an alloy within the scope of the
- Lithographic sheets were formed using the alloy representative of the
- the comparison sheet formed from AA 1050 was
- Figures 2a-2c represent micrographs of electrogram roughened lithographic
- Figures 3a-3c represent micrographs of a comparative example of an
- Figures 4a-4c represent micrographs of a comparative example of an
- AA 1050 similar to AA 1050, which included about 0.2 wt % Mg and about 0.07 wt % Mn.
- alloy composition including 0.090 wt % Si, 0.34 wt % Fe, 0.004 wt % Cu, 0.07 1 wt %
- the alloy was composed of .096
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78782606P | 2006-03-31 | 2006-03-31 | |
PCT/US2007/065635 WO2007115167A2 (en) | 2006-03-31 | 2007-03-30 | Manufacturing process to produce litho sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2077949A2 true EP2077949A2 (en) | 2009-07-15 |
EP2077949B1 EP2077949B1 (en) | 2015-09-30 |
Family
ID=38190587
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07759824.1A Revoked EP2077949B1 (en) | 2006-03-31 | 2007-03-30 | Manufacturing process to produce litho sheet |
Country Status (6)
Country | Link |
---|---|
US (1) | US20080035488A1 (en) |
EP (1) | EP2077949B1 (en) |
KR (1) | KR101152169B1 (en) |
CN (1) | CN101484322A (en) |
BR (1) | BRPI0709691A2 (en) |
WO (1) | WO2007115167A2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012059362A1 (en) | 2010-11-04 | 2012-05-10 | Novelis Inc. | Aluminium lithographic sheet |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101152169B1 (en) | 2006-03-31 | 2012-06-15 | 알코아 인코포레이티드 | Manufacturing process to produce litho sheet |
EP2998126A1 (en) * | 2006-07-21 | 2016-03-23 | Hydro Aluminium Rolled Products GmbH | Process for manufacturing a suport for lithographic printing plates |
ES2407655T5 (en) * | 2007-11-30 | 2023-02-23 | Speira Gmbh | Aluminum strip for supports for lithographic printing plates and their production |
US20110039121A1 (en) * | 2007-11-30 | 2011-02-17 | Hydro Aluminium Deutschland Gmbh | Aluminum strip for lithographic printing plate carriers and the production thereof |
WO2009144108A1 (en) * | 2008-05-28 | 2009-12-03 | Novelis Inc. | Composite aluminium lithographic sheet |
ES2587024T3 (en) * | 2008-11-21 | 2016-10-20 | Hydro Aluminium Rolled Products Gmbh | Aluminum band for lithographic printing plate supports with high alternating flexural strength |
WO2010127903A1 (en) | 2009-05-08 | 2010-11-11 | Novelis Inc. | Aluminium lithographic sheet |
NO2499272T3 (en) * | 2009-11-13 | 2018-01-13 | ||
EP2495106B1 (en) | 2011-03-02 | 2015-05-13 | Hydro Aluminium Rolled Products GmbH | Aluminium band for lithographic printing plate carriers with water-based coatings |
KR102150366B1 (en) | 2020-03-20 | 2020-09-01 | 주식회사 창신 | Spuit type cosmetic comtaimers |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59227494A (en) * | 1983-06-09 | 1984-12-20 | Fuji Photo Film Co Ltd | Manufacture of support for lithographic plate |
JPS6021298A (en) * | 1983-07-18 | 1985-02-02 | Fuji Photo Film Co Ltd | Preparation of support for planographic printing plate |
JPS61146598A (en) * | 1984-12-20 | 1986-07-04 | Furukawa Alum Co Ltd | Supporter for lithographic printing plate and its manufacture |
JPS61274993A (en) | 1985-05-31 | 1986-12-05 | Nippon Light Metal Co Ltd | Aluminum alloy support for offset printing |
JPS62230946A (en) * | 1986-04-01 | 1987-10-09 | Furukawa Alum Co Ltd | Aluminum alloy support for planographic printing plate |
JPH07100837B2 (en) | 1986-11-20 | 1995-11-01 | スカイアルミニウム株式会社 | Aluminum alloy for wrought and its manufacturing method |
US4721552A (en) | 1987-04-27 | 1988-01-26 | Polychrome Corporation | Two-step method for electrolytically graining lithographic metal plates |
DE3714059C3 (en) | 1987-04-28 | 1995-12-07 | Vaw Ver Aluminium Werke Ag | Material in ribbon or plate form and process for its production and its use as a support for planographic printing forms |
IT1238055B (en) * | 1989-03-01 | 1993-06-26 | LAYERED MATERIAL FOR SLIDING BEARING ELEMENTS WITH ANTI-FRICTION LAYER FOR ALUMINUM-BASED BEARINGS. | |
GB9112211D0 (en) * | 1991-06-06 | 1991-07-24 | Alcan Int Ltd | Treating a1 sheet |
JP3647461B2 (en) * | 1994-12-19 | 2005-05-11 | アルキャン・インターナショナル・リミテッド | Cleaning of processed aluminum products |
DE69726760T2 (en) * | 1996-06-17 | 2004-09-23 | Alcan International Ltd., Montreal | TREATMENT OF ALUMINUM WORKPIECES |
JP3580462B2 (en) | 1996-07-05 | 2004-10-20 | 富士写真フイルム株式会社 | Method for producing aluminum support for lithographic printing plate |
US6596150B2 (en) * | 1998-05-28 | 2003-07-22 | Fuji Photo Film Co., Ltd. | Production method for an aluminum support for a lithographic printing plate |
DE29924474U1 (en) * | 1999-07-02 | 2003-08-28 | Hydro Aluminium Deutschland | litho |
JP4056682B2 (en) | 2000-07-11 | 2008-03-05 | 富士フイルム株式会社 | Support for lithographic printing plate |
EP1188580B1 (en) | 2000-09-14 | 2008-08-13 | FUJIFILM Corporation | Aluminum support for planographic printing plate, process for its production, and planographic printing master place |
ES2259311T3 (en) * | 2000-12-11 | 2006-10-01 | Novelis, Inc. | ALUMINUM ALLOY FOR LITHOGRAPHIC IRON. |
JP2003048379A (en) * | 2001-05-30 | 2003-02-18 | Fuji Photo Film Co Ltd | Support for lithographic printing plate and original plate for lithographic printing plate |
GB0117683D0 (en) * | 2001-07-20 | 2001-09-12 | Alcan Int Ltd | Aluminium alloy sheet with roughened surface |
GB2379669B (en) * | 2001-09-12 | 2005-02-16 | Alcan Int Ltd | Al alloy for lithographic sheet |
DE60329343D1 (en) * | 2002-02-26 | 2009-11-05 | Fujifilm Corp | Aluminum support for a planographic printing plate and process for its production, and a presensitized printing plate using the same |
JP4070587B2 (en) * | 2002-12-02 | 2008-04-02 | 富士フイルム株式会社 | Planographic printing plate precursor |
JP4105042B2 (en) * | 2003-06-12 | 2008-06-18 | 三菱アルミニウム株式会社 | Aluminum alloy material for lithographic printing plate and method for producing the same |
JP2005305690A (en) * | 2004-04-19 | 2005-11-04 | Konica Minolta Medical & Graphic Inc | Printing plate material, printing method of printing plate material and offset press |
CN101203629B (en) | 2005-05-19 | 2012-01-18 | 海德鲁铝业德国有限责任公司 | Conditioning of a litho strip |
KR101152169B1 (en) | 2006-03-31 | 2012-06-15 | 알코아 인코포레이티드 | Manufacturing process to produce litho sheet |
-
2007
- 2007-03-30 KR KR1020087026631A patent/KR101152169B1/en active IP Right Grant
- 2007-03-30 BR BRPI0709691-7A patent/BRPI0709691A2/en not_active Application Discontinuation
- 2007-03-30 CN CNA2007800113309A patent/CN101484322A/en active Pending
- 2007-03-30 EP EP07759824.1A patent/EP2077949B1/en not_active Revoked
- 2007-03-30 WO PCT/US2007/065635 patent/WO2007115167A2/en active Application Filing
- 2007-03-30 US US11/694,116 patent/US20080035488A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2007115167A2 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012059362A1 (en) | 2010-11-04 | 2012-05-10 | Novelis Inc. | Aluminium lithographic sheet |
Also Published As
Publication number | Publication date |
---|---|
KR20080109058A (en) | 2008-12-16 |
EP2077949B1 (en) | 2015-09-30 |
US20080035488A1 (en) | 2008-02-14 |
WO2007115167A3 (en) | 2008-11-13 |
CN101484322A (en) | 2009-07-15 |
KR101152169B1 (en) | 2012-06-15 |
BRPI0709691A2 (en) | 2011-07-19 |
WO2007115167A2 (en) | 2007-10-11 |
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