EP2066451A1 - Electrostatic spraying arrangement - Google Patents
Electrostatic spraying arrangementInfo
- Publication number
- EP2066451A1 EP2066451A1 EP07818465A EP07818465A EP2066451A1 EP 2066451 A1 EP2066451 A1 EP 2066451A1 EP 07818465 A EP07818465 A EP 07818465A EP 07818465 A EP07818465 A EP 07818465A EP 2066451 A1 EP2066451 A1 EP 2066451A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- atomizer
- transformer
- arrangement
- assembly
- high voltage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007590 electrostatic spraying Methods 0.000 title abstract 2
- 239000011248 coating agent Substances 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 238000009413 insulation Methods 0.000 claims abstract description 11
- 230000005540 biological transmission Effects 0.000 claims description 21
- 230000003287 optical effect Effects 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 8
- 230000008054 signal transmission Effects 0.000 claims description 7
- 238000007600 charging Methods 0.000 claims description 6
- 239000006199 nebulizer Substances 0.000 claims description 5
- 230000002457 bidirectional effect Effects 0.000 claims description 3
- 238000009503 electrostatic coating Methods 0.000 claims description 3
- 238000002955 isolation Methods 0.000 claims description 3
- 230000033001 locomotion Effects 0.000 claims description 3
- 238000007667 floating Methods 0.000 claims description 2
- 238000012806 monitoring device Methods 0.000 claims 1
- 238000012544 monitoring process Methods 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000000034 method Methods 0.000 description 9
- 238000000926 separation method Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 210000000245 forearm Anatomy 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 230000001939 inductive effect Effects 0.000 description 3
- 230000007480 spreading Effects 0.000 description 3
- 210000000707 wrist Anatomy 0.000 description 3
- DTCAGAIFZCHZFO-UHFFFAOYSA-N 2-(ethylamino)-1-(3-fluorophenyl)propan-1-one Chemical compound CCNC(C)C(=O)C1=CC=CC(F)=C1 DTCAGAIFZCHZFO-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 238000007786 electrostatic charging Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000005405 multipole Effects 0.000 description 1
- 230000006855 networking Effects 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000005236 sound signal Effects 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
- B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
- B05B5/053—Arrangements for supplying power, e.g. charging power
- B05B5/0531—Power generators
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
- B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
- B05B5/053—Arrangements for supplying power, e.g. charging power
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
- B05B5/08—Plant for applying liquids or other fluent materials to objects
- B05B5/10—Arrangements for supplying power, e.g. charging power
Definitions
- the invention relates to an atomizer arrangement for a coating machine for series-wise electrostatic coating of workpieces such as motor vehicle bodies or parts thereof.
- the atomizer arrangement can consist in particular of an electrostatic atomizer and the forearm (arm 2) of a coating robot exist where the atomizer is arranged on the usual wrist.
- Electrostatic atomizers are known.
- rotary atomizers in addition to a turbine (ie a pneumatic or hydraulic drive) or an electric motor for driving the atomising bell, they contain various components such as e.g. Valves, valve terminals, bus connection modules for fieldbus systems, valve controllers, drive control loops and other controllers of all kinds, inductive, optical and / or capacitive sensors, high voltage generators, etc.
- atomizers working with direct charging of the coating material, usually the entire atomizer is placed under high voltage so that the coating material is charged by an electrode device containing all the electrically conductive parts such as atomizer, paint tube, fittings, etc., with which it comes into contact.
- an electrode device containing all the electrically conductive parts such as atomizer, paint tube, fittings, etc., with which it comes into contact.
- external charging of the coating material with external electrodes is also possible.
- An electrostatic rotary atomizer which contains an electric motor controlled by a safety transformer is known from WO 2005/110613. Further information NEN via electrostatic atomizers and their components can be found for example in EP 0 219 409, EP 1 245 291, EP 1 293 308 and EP 1 394 757.
- EP 1 232 799 describes an air atomizer with easily separable and interconnectable components, at the separation points correspondingly easily detachable and connectable electrical line connections are required. Instead of plug contacts used for this purpose, the line connections in this air atomizer from inductive couplers with two flat coils, in particular Topfkernbauweise, which should be so small that virtually no structural changes of instead connectable by plug separable parts of the atomizer are required.
- An electrostatic sprayer includes various components that are to be supplied with electrical power and / or receive and / or transmit electrical signals.
- All actuators and sensors and other electronic components of the atomizer require electrical supply, and all the actuators provided there require signals coming from the outside, while all sensors and other electronic components deliver, for example, diagnostic data and other signals to the outside, in particular also actual values from externally controlled parameters the atomizer.
- the aim of the invention is in particular an expedient and trouble-free supply of components of a high-voltage nebulizer arrangement with electrical power at potential separation between an external supply line arrangement and the consumers of the nebulizer.
- the invention is based on the recognition that a transformer arrangement provided at least partly in the atomizer or in an adjacent moving member of the coating machine, namely in the front of a coating robot or possibly outside the coating machine, as for example for supplying and controlling an electric drive motor of the atomizer per se can already be present, useful for dining other components of the atomizer can be used.
- the transformer can bring about galvanic isolation between the line arrangement provided for the power supply of the atomizer arrangement and consumers located in the atomizer or possibly in the robot arm, which are at high voltage. This separation is best carried out with an isolating transformer which has a sufficient insulation gap or other insulation device between see the primary and secondary circuits has.
- different components require different supply voltages.
- a frequency controlled drive of the atomizer requires different voltages and frequencies than a consumer requiring only a constant DC voltage (eg, 24V).
- the invention makes it possible to easily transmit signals transmitted or received by sensors, actuators, controls and / or other electrical components of the atomizer assembly into or out of the atomizer assembly, although in operation these components are at high voltage.
- This problem is solved by transmitting the signals with galvanic isolation.
- the galvanic separation can be realized in different ways, in particular by preferably digital information or data transmission via optical waveguides or radio links or as sound signals or else by amplitude or frequency modulation of e.g. from a transformer arrangement with high-voltage insulation in the high voltage range of the atomizer arrangement led supply voltages.
- FIG. 1 shows an atomizer arrangement with a transformer arrangement according to the invention
- Fig. 2 is a schematic representation of a preferred embodiment of the transformer arrangement
- FIG. 3 shows the basic diagram of a signal transmission via optical waveguide; and Fig. 4 shows the schematic diagram of a signal transmission over a radio link.
- the components of an electrostatic rotary atomizing arrangement which are at high voltage potential during operation, namely the actual atomizer or an arrangement of the atomizer, a wrist and the forearm of a high-voltage coating robot.
- the forearm can be made in a conventional manner of insulating material. With the exception of the primary circuits of the transformer arrangement described below, all of the components considered in region 1 can be at the high-voltage potential.
- this area 1 leads a two- or multi-pole external supply line arrangement 2, which, as shown, the parallel primary coils of the three in a conventional manner as isolating transformer with high-voltage insulation paths (for more than 100 or 150 kV) formed transformers Tl, T2 and T3 feeds.
- a two- or multi-pole external supply line arrangement 2 which, as shown, the parallel primary coils of the three in a conventional manner as isolating transformer with high-voltage insulation paths (for more than 100 or 150 kV) formed transformers Tl, T2 and T3 feeds.
- the AC voltage of the line arrangement 2 feeds the primary coil of the first transformer Tl via a converter 3 with voltage pulses which feed on the secondary side the frequency-controlled drive 4 of an electric motor M located in the high voltage area 1, which instead of the one in FIG Rotary atomizers otherwise conventional air turbine is provided for driving the atomizer and can be located in the atomizer itself or in other cases outside eg in or on the forearm of the robot.
- the motor M for example, the above-mentioned WO 2005/110613 Al correspond. Accordingly, the AC voltage generated on the secondary side of the transformer Tl can be converted into an optionally controlled variable DC voltage of, for example 40 V, which can be superimposed on an AC voltage with the speed control or - control of the motor controllable frequency.
- This DC voltage can then be converted into an AC voltage supplying the motor M with a frequency corresponding to the superimposed frequency.
- the speed can be controlled, for example, in a known manner by changing the synchronizing frequency and wherein the power supply can also be separated from, for example, a digital speed control.
- the electric motor M could also be provided a pneumatic or hydraulic drive for the Zestäuberglocke.
- an electric motor it may be appropriate to dimension it so that it can be easily replaced in existing atomizers with their conventional air turbine.
- the secondary coil of the second transformer T2 is used to supply power to the components, including actuators 6, sensors 7 and electronic elements of the atomizer, which are located in the high-voltage region 1.
- the AC voltage generated by the transformer T2 can be converted by a converter 5 into a DC supply voltage.
- Typical examples of the components indicated only schematically in FIGS. 6 and 7 are actuators such as control and drive circuits for valves and flow, speed and other control circuits as well as sensors for the switching position of valves, speed, flow rate, temperature, pressure of the valve loading Stratification material, etc.
- the actuators considered here may include, for example, other electrical or other motors such as metering pump drive.
- the power supply of the sensors and actuators in other embodiments, one could also be used in the motor control, e.g. the drive 4 generated DC voltage can be used.
- the drive 4 generated DC voltage can be used.
- electric batteries for the power supply of individual sensors and / or actuators in a manner known per se or possibly also other separate power sources such as fuel cells.
- the power supply of the components of the atomizer by a for other purposes such as in particular an electric drive motor anyway existing transformer arrangement has the advantage that the power consumption is reduced to a minimum.
- the secondary coil of the third transformer T3 feeds a converter 9, which generates the high voltage required for the electrostatic charging of the coating material from the input AC voltage or supplies a high voltage generator, not shown, of the atomizer.
- the high voltage is applied to the internal or external electrode arrangements (not shown) customary for electrostatic atomizers for direct or external charging of the coating material.
- the transformer arrangement can supply all of the application-related components present on a robot, for example, with the electrical power they require in each case.
- the transformer assembly By mounting relatively heavy standard constructions for the transformer assembly as separate components in the atomizer or in the robotic arm of, for example, a paint robot, they could affect its motion dynamics. It may therefore be more appropriate to structurally integrate the transformer or a transformer coil into the body of the robot arm so that it serves as a supporting element of the robot arm and effects or at least contributes to its necessary rigidity. As a result, the transformer does not significantly increase the overall weight of the atomizer assembly, including the robotic arm.
- FIG. 2 A possible realization thereof is shown schematically in Fig. 2, in which a pivotally mounted robot arm 10 can be seen, is mounted at one (left) end via a wrist of the indicated at 11 atomizer, while at its opposite end the usual axis housing 12 is located with the manual axis motors required for the atomizer movements.
- the housing 12 may be low or grounded.
- the outer housing of the robot arm 10 is formed or supported on its inner side by a transformer coil 14 adapted to the geometric shape of the robot arm, which thus effects the required mechanical strength of the robot arm 10.
- the robot arm 10 including the secondary coil in this example, can Transformer coil 14 are at high voltage potential.
- control and sensor signals to and from the actuators and sensors located in the high-voltage region 1 must be carried out galvanically isolated in order to preclude influences due to the high voltage.
- possibilities of optical transmission or a radio link are considered below, which may also be useful independently of the power supply with a transformer described above.
- an electrical / optical transducer assembly 20 which generates, e.g. digital sensor signals in optical
- the optical sensor and control signals are bidirectionally via an optical fiber array LWL between the transducer assembly 20 and an exceptional half of the high voltage region located external transducer assembly 21 transmitted.
- the transducer assembly 21 can convert the optical signals back into electrical, eg digital signals.
- the optical transmission is known to be potential-free.
- the signal conversion at the respective end of the fiber optic cable forming the optical waveguide arrangement from optical into electrical signals or vice versa can be carried out with commercially available components. Both individual signals can be transmitted as well as complex bus signals, which allows the use of known fieldbus systems and their components.
- the data in and out of the high-voltage area 1 can also be transmitted via a radio link, as shown in FIG. 4.
- a radio link 25 between a located in the high voltage range 1 transducer assembly 26, which converts the aforementioned sensor or control signals into radio signals, and an external transducer assembly 27, which converts the radio signals back into electrical signals.
- Commercially available systems can be used which establish radio links, for example via Bluetooth or with the wireless networks known as WLAN. This is especially the transmission of large amounts of data possible.
- WLAN wireless networks
- the signal transmission over a radio link is known also potential free.
- the signal conversion at the respective end of the radio link 25 into electrical signals or radio signals can be carried out in a conventional manner with conventional transmitting or receiving components.
- individual signals can be transmitted as well as complex bus signals, so that the use of known fieldbus systems and their components is possible.
- the signal transmission By radio is bidirectional, ie on the considered transmission medium signals are transmitted in both directions.
- Bluetooth is a well-known industry standard according to IEEE 802.15.1 for the wireless radio networking of devices over a relatively short distance up to about 100 m.
- the networked devices can transmit in the ISM band (Industrial, Scientific and Medical Band) between 2.402 GHz and 2.480 GHz.
- ISM band International, Scientific and Medical Band
- a frequency hopping method is used, in which the frequency band is divided into a plurality (79) of frequency stages, for example, in the 1 MHz distance, which changes up to 1600 times a second become.
- At the lower and upper end there is a respective frequency band as a guard band to adjacent frequency ranges.
- EDR Enhanced Data Rate
- WLAN Wireless Local Area Network
- IEEE 802.11 which can be operated in infrastructure mode or in ad hoc mode.
- infrastructure mode the individual network nodes are coordinated by a base station, which makes it easy to connect to wired networks; in ad hoc mode, there is no station especially excellent, but all are equal.
- Ad hoc networks can be set up quickly and easily. For WLAN also methods for increasing the security of data transmission are known.
- the known as frequency spreading known method are used in which a narrow-band signal is converted into a broadband signal.
- the transmission energy which was previously concentrated in a small frequency range, is distributed over a wider frequency range.
- a resulting advantage is greater robustness over narrowband interference.
- frequency spreading in digital technology is used to determine the spectral density of the
- the method can be carried out in different ways.
- DSSS Direct Sequence Spread Spectrum
- the user data is linked with a code by means of an exclusive OR (XOR) and then modulated to the bandwidth.
- XOR exclusive OR
- This method is generally used in combination with the CDMA technique and can be used in particular for WLAN according to the standard IEEE 802.11 and the mobile radio standard UMTS.
- Frequency hopping based frequency spreading techniques divide the available bandwidth among many smaller bandwidth channels in terms of frequency division multiplexing. This method can i.a. be used with Bluetooth.
- the optical waveguide arrangement LWL or the radio link 25 it is expedient to electronically monitor the described signal transmission via the optical waveguide arrangement LWL or the radio link 25 with a system to which a security software program belongs that monitors the transmission path and the transmitted information checked for plausibility.
- a security software program belongs that monitors the transmission path and the transmitted information checked for plausibility.
- One possibility for example, is to transmit the given data packet, eg frequency-modulated several times, eg five times during information data transmission and to check on the other side whether at least two identical data packets arrive, ie the radio or other transmission path is in order.
- safety-related components of the atomizer assembly and / or the transmission path can be switched off in order to protect objects and persons.
- the operating personnel can be informed about the detected condition.
- the following monitors can be constantly active: control of the optical transmission path or the radio connection; Plausibility of the transmission information (protocols); as well as shutdown function of the entire system in case of error and informing the operating personnel.
- Another possibility for the floating transfer of control signals to the high-voltage region of a nebulizer arrangement is to superimpose the input voltage of the above-described transformer arrangement components containing control information, which are filtered out again on the secondary side and used as control signals for components located in the high-voltage region can.
- the superimposed components may, for example, be an optionally digital frequency or amplitude modulation of the input voltage.
- the rotational speed of the possibly electric drive motor of the atomizer can also be controlled and / or regulated in the closed loop.
- sensor signals from the atomizer arrangement can also be transmitted to a low or earth potential area in or outside the coating machine.
- Arranged atomizer assembly to arrange outside the painting robot, e.g. even in a cupboard outside the paint booth. This could be useful, for example, to avoid explosion protection problems.
- the then required high-voltage insulation between the transformer and the atomizer can be realized in a manner known to those skilled in the art within leading to the painting robot or atomizer line arrangement.
Landscapes
- Electrostatic Spraying Apparatus (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Developing Agents For Electrophotography (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Spray Control Apparatus (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07818465T PL2066451T3 (en) | 2006-09-27 | 2007-09-26 | Electrostatic spraying arrangement |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200610045631 DE102006045631A1 (en) | 2006-09-27 | 2006-09-27 | Sprayer arrangement for coating machine for series-wise electrostatic coating of workpiece, e.g. motor vehicle body or parts, has transformer arrangement that has high voltage-isolation device between primary and secondary circuits |
DE102007004819A DE102007004819A1 (en) | 2007-01-31 | 2007-01-31 | Sprayer arrangement for coating machine for series-wise electrostatic coating of workpiece, e.g. motor vehicle body or parts, has transformer arrangement that has high voltage-isolation device between primary and secondary circuits |
PCT/EP2007/008382 WO2008037456A1 (en) | 2006-09-27 | 2007-09-26 | Electrostatic spraying arrangement |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2066451A1 true EP2066451A1 (en) | 2009-06-10 |
EP2066451B1 EP2066451B1 (en) | 2011-05-11 |
Family
ID=38705032
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07818465A Active EP2066451B1 (en) | 2006-09-27 | 2007-09-26 | Electrostatic spraying arrangement |
Country Status (11)
Country | Link |
---|---|
US (1) | US8485125B2 (en) |
EP (1) | EP2066451B1 (en) |
JP (1) | JP5312331B2 (en) |
KR (1) | KR101452349B1 (en) |
AT (1) | ATE508804T1 (en) |
BR (1) | BRPI0717421B1 (en) |
CA (1) | CA2663245C (en) |
MX (1) | MX2009002988A (en) |
PL (1) | PL2066451T3 (en) |
RU (1) | RU2441709C2 (en) |
WO (1) | WO2008037456A1 (en) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4347372B2 (en) * | 2007-08-10 | 2009-10-21 | トヨタ自動車株式会社 | Electrostatic coating equipment |
SE531271C2 (en) * | 2008-04-22 | 2009-02-10 | Conjet Ab | Vattenbilningsaggregat |
DE102008045553A1 (en) * | 2008-09-03 | 2010-03-04 | Dürr Systems GmbH | Painting device and associated method |
US9641216B2 (en) * | 2009-04-07 | 2017-05-02 | Battelle Energy Alliance, Llc | Monitoring devices and systems for monitoring frequency hopping wireless communications, and related methods |
DE102009051877A1 (en) | 2009-11-04 | 2011-05-05 | Dürr Systems GmbH | Coating process and coating system with dynamic adjustment of the atomizer speed and the high voltage |
US10479262B2 (en) * | 2013-03-14 | 2019-11-19 | International Research Institute iRI | Systems and methods for replicating vehicular illumination |
US20180130867A1 (en) * | 2016-11-09 | 2018-05-10 | Analog Devices Global | Magnetic isolators for increased voltage operations and related methods |
US10286564B2 (en) | 2017-05-01 | 2019-05-14 | Lincoln Global, Inc. | System for locally generating electricity on a robotic device |
US11181588B2 (en) * | 2018-08-13 | 2021-11-23 | Carlisle Fluid Technologies, Inc. | Systems and methods for detection and configuration of spray system components |
US11044022B2 (en) * | 2018-08-29 | 2021-06-22 | Analog Devices Global Unlimited Company | Back-to-back isolation circuit |
US11450469B2 (en) | 2019-08-28 | 2022-09-20 | Analog Devices Global Unlimited Company | Insulation jacket for top coil of an isolated transformer |
US11387316B2 (en) | 2019-12-02 | 2022-07-12 | Analog Devices International Unlimited Company | Monolithic back-to-back isolation elements with floating top plate |
DE102021101027A1 (en) * | 2021-01-19 | 2022-07-21 | Dürr Systems Ag | Coating device, in particular painting robot |
DE102021101026B4 (en) * | 2021-01-19 | 2022-11-03 | Dürr Systems Ag | Coating device with a transmission device for the wireless transmission of energy and/or data |
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-
2007
- 2007-09-26 MX MX2009002988A patent/MX2009002988A/en active IP Right Grant
- 2007-09-26 EP EP07818465A patent/EP2066451B1/en active Active
- 2007-09-26 KR KR1020097005460A patent/KR101452349B1/en active IP Right Grant
- 2007-09-26 CA CA2663245A patent/CA2663245C/en active Active
- 2007-09-26 JP JP2009529600A patent/JP5312331B2/en active Active
- 2007-09-26 AT AT07818465T patent/ATE508804T1/en active
- 2007-09-26 WO PCT/EP2007/008382 patent/WO2008037456A1/en active Application Filing
- 2007-09-26 BR BRPI0717421A patent/BRPI0717421B1/en active IP Right Grant
- 2007-09-26 RU RU2009115657/05A patent/RU2441709C2/en active
- 2007-09-26 US US12/442,161 patent/US8485125B2/en active Active
- 2007-09-26 PL PL07818465T patent/PL2066451T3/en unknown
Non-Patent Citations (1)
Title |
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See references of WO2008037456A1 * |
Also Published As
Publication number | Publication date |
---|---|
MX2009002988A (en) | 2009-04-01 |
CA2663245C (en) | 2015-12-08 |
RU2009115657A (en) | 2010-11-10 |
JP5312331B2 (en) | 2013-10-09 |
EP2066451B1 (en) | 2011-05-11 |
ATE508804T1 (en) | 2011-05-15 |
BRPI0717421B1 (en) | 2020-01-28 |
US20100147215A1 (en) | 2010-06-17 |
KR20090057020A (en) | 2009-06-03 |
RU2441709C2 (en) | 2012-02-10 |
KR101452349B1 (en) | 2014-10-21 |
JP2010504850A (en) | 2010-02-18 |
PL2066451T3 (en) | 2011-10-31 |
WO2008037456A1 (en) | 2008-04-03 |
BRPI0717421A2 (en) | 2013-11-26 |
US8485125B2 (en) | 2013-07-16 |
CA2663245A1 (en) | 2008-04-03 |
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