EP2047003B1 - Highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine - Google Patents
Highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine Download PDFInfo
- Publication number
- EP2047003B1 EP2047003B1 EP06796230.8A EP06796230A EP2047003B1 EP 2047003 B1 EP2047003 B1 EP 2047003B1 EP 06796230 A EP06796230 A EP 06796230A EP 2047003 B1 EP2047003 B1 EP 2047003B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- turbine
- max
- blades
- steam
- movable blade
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/14—Form or construction
- F01D5/141—Shape, i.e. outer, aerodynamic form
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/04—Heavy metals
- F05C2201/0433—Iron group; Ferrous alloys, e.g. steel
- F05C2201/0466—Nickel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2220/00—Application
- F05D2220/30—Application in turbines
- F05D2220/31—Application in turbines in steam turbines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/10—Metals, alloys or intermetallic compounds
- F05D2300/13—Refractory metals, i.e. Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, W
- F05D2300/131—Molybdenum
Definitions
- the present invention relates to a highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine, and to a steam turbine, in particular a geothermal impulse turbine, featuring such a movable blade assembly.
- a steam turbine normally comprises a number of successive stages which, in axial-flow turbines, are arranged coaxially with the turbine (machine) axis, so that the steam discharged from one stage flows directly and more or less axially into the next.
- the movable part of each stage comprises a number of blades arranged radially about the shaft and fixed to the shaft by fasteners of various types (inverted-pine-shaped or hammer-headed fasteners); and the ends or tops of the blades are connected to one another by shroud rings fixed to the tops of the blades, for example, by riveting (upsetting) pegs formed on the tops of the blades or formed in one piece with the blades themselves.
- One known application of steam turbines is in geothermal energy generating systems, in which the fluid evolving in the turbine is defined by endogenous natural steam, i.e. steam generated directly in the earth as opposed to steam produced by conventional fossil- or nuclear-fuelled boilers or by heat-recovery boilers as in combination-cycle systems.
- endogenous natural steam i.e. steam generated directly in the earth as opposed to steam produced by conventional fossil- or nuclear-fuelled boilers or by heat-recovery boilers as in combination-cycle systems.
- endogenous steam is characterized, not only by much lower than normal thermodynamic conditions (substantially pressure and temperature), but also by uncontrolled chemistry which depends strongly on the site from which the steam is extracted.
- the steam supplied to the turbine in geothermal systems is normally less than optimum, especially as regards chemical aggression.
- endogenous steam in fact normally contains various substances in various forms which impart aggressive characteristics to it which are totally absent in industrial steam, and which result in the formation of deposits on the steam turbine blades.
- the blades and shroud rings are normally made of martensitic stainless steel, such as AISI 403 or similar, which, being a good compromise between mechanical and erosion resistance characteristics, is widely used in steam turbines, even in geothermal systems.
- FR2809764-A1 discloses a steam turbine having a movable blade assembly wherein the blades have respective free ends that are not mechanically connected to one another.
- US2006/140775-A1 discloses a steam turbine comprising a series of rotor blades made of a nickel alloy having specific compositions so as to maintain a high useful life of the rotor blades, even in case the turbine operates with geothermal vapours containing some aggressive or corrosive agents.
- Number 1 in Figure 1 indicates a substantially known steam turbine, which is therefore only shown schematically. More specifically, turbine 1 is an axial impulse turbine of a geothermal power generating system.
- Turbine 1 substantially comprises a casing 2 having an inlet 3 and an outlet 4 for a stream of endogenous natural steam extracted from the earth.
- Casing 2 houses a stator 5 integral with casing 2; and a rotor 6 connected integrally to a drive shaft 7 extending through casing 2 along a rotation axis A.
- casing 2 houses a number of successive stages 10, each defined by an array 11 of fixed stator blades 12 integral with casing 2 and projecting substantially radially from an inner wall 13 of casing 2, and by an array 14 of movable rotor blades 15 carried by and rotating integrally with shaft 7.
- Figure 2 shows, purely schematically, a stage 10, in particular an impulse stage 10, of turbine 1.
- Stage 10 comprises a movable blade assembly 20 defined by blades 15, which are arranged substantially in a ring about shaft 7 and project radially from shaft 7 towards wall 13 of casing 2.
- blades 15 have a substantially concave profile, and may be of any known type, e.g. cylindrical with a constant section, tapered and/or twisted.
- Each blade 15 is fixed in known manner directly to shaft 7 or, as shown in Figure 2 , to a supporting wheel 21 integral with shaft 7.
- Each blade 15 extends between a fastening end 22, having a connecting portion 23 for connection to shaft 7, and a free end 24 opposite fastening end 22 and terminating with a top portion 25 in no way connected mechanically to the top portions 25 of the other blades 15.
- assembly 20 and, in particular, blades 15 are made of a nickel-based metal alloy (i.e. in which nickel is the predominant component, and which contains roughly over 45% by weight of nickel) with a composition according to claim 1.
- nickel-based metal alloy i.e. in which nickel is the predominant component, and which contains roughly over 45% by weight of nickel
- nickel-based alloys in the Special Metals Corporation INCONEL ® group are particularly indicated, and, in terms of corrosion resistance in geothermal applications, have proved far superior to conventional steel, in particular AISI 403 martensitic steel.
- the INCONEL ® name includes a group of nickel-based alloys which can be age hardened, exhibit good creep resistance up to roughly 700°C, and are highly resistant to corrosion in general and to stress corrosion in particular.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Description
- The present invention relates to a highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine, and to a steam turbine, in particular a geothermal impulse turbine, featuring such a movable blade assembly.
- As is known, in steam turbines, energy is transferred from the steam to the shaft by successively expanding the steam, which, as it expands in the nozzles forming the fixed part of the turbine, increases in speed to convert the thermal energy of the steam to kinetic energy, which is transmitted to the shaft by movable blades fitted to the periphery of the shaft.
- To make the best use of the energy in the steam, a steam turbine normally comprises a number of successive stages which, in axial-flow turbines, are arranged coaxially with the turbine (machine) axis, so that the steam discharged from one stage flows directly and more or less axially into the next.
- The movable part of each stage (movable blades) comprises a number of blades arranged radially about the shaft and fixed to the shaft by fasteners of various types (inverted-pine-shaped or hammer-headed fasteners); and the ends or tops of the blades are connected to one another by shroud rings fixed to the tops of the blades, for example, by riveting (upsetting) pegs formed on the tops of the blades or formed in one piece with the blades themselves.
- One known application of steam turbines is in geothermal energy generating systems, in which the fluid evolving in the turbine is defined by endogenous natural steam, i.e. steam generated directly in the earth as opposed to steam produced by conventional fossil- or nuclear-fuelled boilers or by heat-recovery boilers as in combination-cycle systems.
- Unlike boiler-generated steam, endogenous steam is characterized, not only by much lower than normal thermodynamic conditions (substantially pressure and temperature), but also by uncontrolled chemistry which depends strongly on the site from which the steam is extracted. Unlike other types of systems, in which dedicated systems for processing the condensate used to produce the steam ensure optimum steam characteristics, the steam supplied to the turbine in geothermal systems is normally less than optimum, especially as regards chemical aggression. In addition to noncondensable gases, endogenous steam in fact normally contains various substances in various forms which impart aggressive characteristics to it which are totally absent in industrial steam, and which result in the formation of deposits on the steam turbine blades.
- This applies in particular to the stages in which the steam expanding in the turbine passes from the superheated to the saturated state, and results in severe corrosion/erosion of the blades, and in salt deposits (typically sulphide and chloride), especially beneath the movable blade shroud rings, thus resulting in subdeposit corrosion.
- As a result, the working life of the movable blades, particularly those at the phase-passage turbine stages, is reduced, and operating cost is increased, due to frequent replacement of the blades and stoppage of the system for maintenance work.
- The blades and shroud rings are normally made of martensitic stainless steel, such as AISI 403 or similar, which, being a good compromise between mechanical and erosion resistance characteristics, is widely used in steam turbines, even in geothermal systems.
- Steam turbines with movable blades and shroud rings made of martensitic stainless steel, however, have a poor resistance to corrosion and stress corrosion, particularly in the presence of chloride, as in the case of geothermal system steam turbines, and particularly at the stages where the steam passes from the superheated to the wet state, where the condensation mechanism enriches the concentration of impurities in the steam.
- The problem is further compounded by the formation of deposits of various types (depending on the chemical nature of the endogenous steam evolving in the turbine), which accumulate particularly on the underside of the shroud rings of the movable blades, thus resulting in subdeposit corrosion phenomena.
FR2809764-A1 -
US2006/140775-A1 discloses a steam turbine comprising a series of rotor blades made of a nickel alloy having specific compositions so as to maintain a high useful life of the rotor blades, even in case the turbine operates with geothermal vapours containing some aggressive or corrosive agents. - It is an object of the present invention to provide a highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine, designed to eliminate the aforementioned drawbacks of the known art.
- According to the present invention, there is provided a highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine, as claimed in claim 1.
- A non-limiting embodiment of the invention will be described by way of example with reference to the accompanying drawings, in which:
-
Figure 1 shows a schematic view of a geothermal steam turbine of substantially known configuration; -
Figure 2 shows a schematic partial longitudinal section of one stage of theFigure 1 turbine featuring a movable blade assembly in accordance with the invention; -
Figure 3 shows a partial view of a movable blade assembly in accordance with the invention. - Number 1 in
Figure 1 indicates a substantially known steam turbine, which is therefore only shown schematically. More specifically, turbine 1 is an axial impulse turbine of a geothermal power generating system. - Turbine 1 substantially comprises a
casing 2 having an inlet 3 and an outlet 4 for a stream of endogenous natural steam extracted from the earth. Casing 2 houses astator 5 integral withcasing 2; and a rotor 6 connected integrally to adrive shaft 7 extending throughcasing 2 along a rotation axis A. - As usual,
casing 2 houses a number ofsuccessive stages 10, each defined by anarray 11 offixed stator blades 12 integral withcasing 2 and projecting substantially radially from aninner wall 13 ofcasing 2, and by anarray 14 ofmovable rotor blades 15 carried by and rotating integrally withshaft 7. -
Figure 2 shows, purely schematically, astage 10, in particular animpulse stage 10, of turbine 1. -
Stage 10 comprises amovable blade assembly 20 defined byblades 15, which are arranged substantially in a ring aboutshaft 7 and project radially fromshaft 7 towardswall 13 ofcasing 2. - With reference also to
Figure 3 ,blades 15 have a substantially concave profile, and may be of any known type, e.g. cylindrical with a constant section, tapered and/or twisted. - Each
blade 15 is fixed in known manner directly toshaft 7 or, as shown inFigure 2 , to a supportingwheel 21 integral withshaft 7. Eachblade 15 extends between a fasteningend 22, having a connectingportion 23 for connection toshaft 7, and afree end 24opposite fastening end 22 and terminating with atop portion 25 in no way connected mechanically to thetop portions 25 of theother blades 15. - In other words, no mechanical connection, in particular no shroud ring, is provided connecting the
top portions 25 ofrotor blades 15. Eliminating the shroud ring poses no vibration problems ofblades 15 if they are appropriately shaped and sized and exhibit no resonance phenomena with excitation frequencies. - In accordance with the invention,
assembly 20 and, in particular,blades 15 are made of a nickel-based metal alloy (i.e. in which nickel is the predominant component, and which contains roughly over 45% by weight of nickel) with a composition according to claim 1. - Purely by way of example, nickel-based alloys in the Special Metals Corporation INCONEL® group are particularly indicated, and, in terms of corrosion resistance in geothermal applications, have proved far superior to conventional steel, in particular AISI 403 martensitic steel.
- The INCONEL® name includes a group of nickel-based alloys which can be age hardened, exhibit good creep resistance up to roughly 700°C, and are highly resistant to corrosion in general and to stress corrosion in particular.
- It is understood, however, that similar materials to the alloys in the INCONEL® group may be used in accordance with the invention.
- Examples of materials used to make
blades 15 andassembly 20 in general (main components only) are shown in Table 2.TABLE 2 COMPONENT QUANTITY (% by weight) Nickel 50.00-55.00 Chromium 17.00-21.00 Iron rest Niobium 4.75-5.50 Molybdenum 2.80-3.30 Titanium 0.65-1.15 Aluminium 0.20-0.80 Cobalt 1.00 max. Carbon 0.08 max. Manganese 0.35 max. Silicon 0.35 max. Phosphorous 0.015 max. Sulphur 0.015 max. Boron 0.006 max. Copper 0.30 max. - The advantages of the present invention over known solutions will be clear from the foregoing description
- the movable blade assembly and, specifically, the rotor blades made in accordance with the invention are far more corrosion resistant than blades made of conventional materials;
- the materials used also have better mechanical characteristics, so that, for a given degree of erosion, resistance is improved and, hence, the working life of the component parts increased;
- eliminating the shroud ring (and any other member mechanically connecting the top portions of the blades) eliminates areas in which deposits (defined by substances in the steam) can accumulate on the rotor;
- also eliminated are the gaps, subject to gap corrosion, between the top portions of the blades and the shroud rings;
- deposits defined by substances in the steam are projected radially outwards onto the stator, and accumulate in particular on stator portions directly facing the top portions of the movable blades, so that subsequent deposits only accumulate up to a certain point, beyond which they are removed mechanically by the top portions of the movable blades which act as scraping tools as they rotate;
- the movable blade assembly according to the invention may also be used on steam turbines originally designed for conventional solutions, with only minor alterations to the original fixed parts.
- Clearly, changes may be made to the assembly as described and illustrated herein without, however, departing from the scope of the invention as defined in the accompanying Claims.
Claims (3)
- A highly corrosion-resistant movable blade assembly (20) for a steam turbine, in particular a geothermal impulse turbine, comprising an array (14) of rotor blades (15) carried by a shaft (7) rotating about an axis (A); each blade (15) extending between one end (22) attached to the shaft (7), and a free end (24) terminating with a top portion (25) with no mechanical connection to the top portions (25) of the other blades (15); the assembly being characterized in that the blades (15) are made of a nickel-based metal alloy consisting of:- Nickel: 50,00-55,00 % by weight- Chromium: 17,00-21,00 % w.- Niobium: 4,75-5,50 % w.- Molybdenum: 2,80-3,30 % w.- Titanium: 0,65-1,15 % w.- Aluminium: 0,20-0,80 % w.- Iron: rest- Cobalt: 1,00 max % w.- Carbon: 0,08 max % w.- Manganese: 0,35 max % w.- Silicon: 0,35 max % w.- Phosphorous: 0,015 max % w.- Sulphur: 0,015 max % w.- Boron: 0,006 max % w.- Copper: 0,30 max % w.
- An assembly as claimed in Claim 1, characterized in that the metal alloy is a nickel-based alloy in the INCONEL® group or a similar material.
- A steam turbine (1), in particular a geothermal impulse turbine, comprising a stator (5), and a rotor (6) connected integrally to a shaft (7) rotating about a rotation axis (A); the turbine being characterized in that the rotor (6) comprises a movable blade assembly (20) as claimed in any one of the foregoing Claims.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IT2006/000565 WO2008012842A1 (en) | 2006-07-25 | 2006-07-25 | Highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2047003A1 EP2047003A1 (en) | 2009-04-15 |
EP2047003B1 true EP2047003B1 (en) | 2013-09-04 |
Family
ID=37989174
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06796230.8A Active EP2047003B1 (en) | 2006-07-25 | 2006-07-25 | Highly corrosion-resistant movable blade assembly for a steam turbine, in particular a geothermal impulse turbine |
Country Status (4)
Country | Link |
---|---|
US (1) | US20090324419A1 (en) |
EP (1) | EP2047003B1 (en) |
JP (1) | JP2009544895A (en) |
WO (1) | WO2008012842A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6688598B2 (en) * | 2015-11-11 | 2020-04-28 | 三菱日立パワーシステムズ株式会社 | Austenitic steel and cast austenitic steel using the same |
CN107559049B (en) * | 2017-09-30 | 2023-12-12 | 南京赛达机械制造有限公司 | Efficient turbine blade |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB283505A (en) * | 1927-01-11 | 1929-04-11 | Bbc Brown Boveri & Cie | Improvements in means for draining the low-pressure blading of steam turbines |
BE372479A (en) * | 1929-08-22 | 1930-08-05 | ||
US3619183A (en) * | 1968-03-21 | 1971-11-09 | Int Nickel Co | Nickel-base alloys adaptable for use as steam turbine structural components |
JPH07166803A (en) * | 1993-12-16 | 1995-06-27 | Toshiba Corp | Turbine moving blade and its manufacture |
US7160400B2 (en) * | 1999-03-03 | 2007-01-09 | Daido Tokushuko Kabushiki Kaisha | Low thermal expansion Ni-base superalloy |
JP2001227301A (en) * | 2000-02-15 | 2001-08-24 | Fuji Electric Co Ltd | Steam turbine |
FR2809764B1 (en) * | 2000-05-30 | 2002-11-29 | Framatome Sa | AXIAL TURBINE STAGE |
JP2003082476A (en) * | 2001-06-26 | 2003-03-19 | Toshiba Corp | Corrosion and wear resistant turbine member and manufacturing method |
JP2004124751A (en) * | 2002-09-30 | 2004-04-22 | Toshiba Corp | Moisture separation device for steam turbine |
JP2004169562A (en) * | 2002-11-18 | 2004-06-17 | Toshiba Corp | Steam turbine |
JP4509664B2 (en) * | 2003-07-30 | 2010-07-21 | 株式会社東芝 | Steam turbine power generation equipment |
EP1536026A1 (en) * | 2003-11-27 | 2005-06-01 | Siemens Aktiengesellschaft | High temperature resistant article |
ITMI20042481A1 (en) * | 2004-12-23 | 2005-03-23 | Nuovo Pignone Spa | STEAM TURBINE |
-
2006
- 2006-07-25 JP JP2009521419A patent/JP2009544895A/en active Pending
- 2006-07-25 US US12/374,905 patent/US20090324419A1/en not_active Abandoned
- 2006-07-25 EP EP06796230.8A patent/EP2047003B1/en active Active
- 2006-07-25 WO PCT/IT2006/000565 patent/WO2008012842A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
EP2047003A1 (en) | 2009-04-15 |
US20090324419A1 (en) | 2009-12-31 |
WO2008012842A1 (en) | 2008-01-31 |
JP2009544895A (en) | 2009-12-17 |
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