EP2012397B1 - Spark plug and method for its production - Google Patents
Spark plug and method for its production Download PDFInfo
- Publication number
- EP2012397B1 EP2012397B1 EP08012086.8A EP08012086A EP2012397B1 EP 2012397 B1 EP2012397 B1 EP 2012397B1 EP 08012086 A EP08012086 A EP 08012086A EP 2012397 B1 EP2012397 B1 EP 2012397B1
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- EP
- European Patent Office
- Prior art keywords
- molded part
- ground electrode
- intermediate piece
- welded
- noble
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
- 229910045601 alloy Inorganic materials 0.000 claims description 27
- 239000000956 alloy Substances 0.000 claims description 27
- 238000003466 welding Methods 0.000 claims description 26
- 239000002131 composite material Substances 0.000 claims description 24
- 229910000510 noble metal Inorganic materials 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 16
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 15
- 229910052759 nickel Inorganic materials 0.000 claims description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052741 iridium Inorganic materials 0.000 claims description 9
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 229910052703 rhodium Inorganic materials 0.000 claims description 7
- 239000010948 rhodium Substances 0.000 claims description 7
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 7
- 229910052763 palladium Inorganic materials 0.000 claims description 6
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 238000010894 electron beam technology Methods 0.000 claims description 4
- 239000012212 insulator Substances 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 4
- 229910052702 rhenium Inorganic materials 0.000 claims description 4
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 4
- 229910052707 ruthenium Inorganic materials 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 229910052727 yttrium Inorganic materials 0.000 claims description 4
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052762 osmium Inorganic materials 0.000 claims description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 2
- 230000003014 reinforcing effect Effects 0.000 claims description 2
- 238000000465 moulding Methods 0.000 description 23
- 229910001260 Pt alloy Inorganic materials 0.000 description 16
- 229910000575 Ir alloy Inorganic materials 0.000 description 14
- 239000011265 semifinished product Substances 0.000 description 12
- 239000010970 precious metal Substances 0.000 description 9
- 230000008646 thermal stress Effects 0.000 description 7
- 238000005275 alloying Methods 0.000 description 6
- 229910001055 inconels 600 Inorganic materials 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- DDQZSLVVXJOWDT-UHFFFAOYSA-N iridium nickel Chemical compound [Ni].[Ir] DDQZSLVVXJOWDT-UHFFFAOYSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- SXRIPRHXGZHSNU-UHFFFAOYSA-N iridium rhodium Chemical compound [Rh].[Ir] SXRIPRHXGZHSNU-UHFFFAOYSA-N 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 229910000923 precious metal alloy Inorganic materials 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T13/00—Sparking plugs
- H01T13/20—Sparking plugs characterised by features of the electrodes or insulation
- H01T13/32—Sparking plugs characterised by features of the electrodes or insulation characterised by features of the earthed electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T21/00—Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs
- H01T21/02—Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs of sparking plugs
Definitions
- the invention relates to a spark plug with the features specified in the preamble of claim 1 and of a method with the features specified in the preamble of claim 4.
- a spark plug which has a cylindrical center electrode made of copper with a jacket made of a highly heat-resistant nickel alloy. To increase the life of the center electrode is reinforced with a tip of a precious metal material.
- the EP 1 517 418 A2 discloses alloys of more than 50% by weight of iridium with at least one further metal or metal oxide from the group consisting of platinum, rhodium, nickel, tungsten, palladium, ruthenium, rhenium, aluminum, aluminum oxide, yttrium and yttrium oxide.
- the iridium alloy tip is butt welded to the forward end of the base center electrode.
- connection zone By subjecting the connection zone to a laser beam which is passed around the electrode, an alloy is formed in the connection zone, which consists of components of the non-noble center electrode and the electrode tip of the iridium alloy.
- the alloy zone is intended to mitigate thermal stresses resulting from the different thermal expansion coefficients of the iridium alloy and the copper.
- the coefficient of thermal expansion is between about 6 x 10 -6 K -1 and 7 x 10 -6 K -1 for platinum alloys between 9 x 10 -6 K -1 and 11 x 10 -6 K -1 .
- the coefficient of thermal expansion is 16 ⁇ 10 -6 K -1 , for nickel-based alloys between 10.5 ⁇ 10 -6 K -1 and 14.5 ⁇ 10 -6 K -1 .
- the ground electrode of the known spark plug is formed as usual from a flat wire with a rectangular cross-section and consists of a highly heat-resistant nickel-based alloy. It is reinforced with a molding of a platinum alloy with more than 50 wt .-% platinum and with at least one metal from the group iridium, rhodium, nickel, tungsten, palladium, ruthenium and rhenium. As a molding reveals the EP 1 517 418 A2 a blank, which is welded with a laser on the base ground electrode. It is disadvantageous that the non-noble ground electrode has a substantially different shape and arrangement than the center electrode of the spark plug.
- connection zone between the molded part formed from the platinum alloy and the base ground electrode, which projects beyond the molded part from the platinum alloy, is much worse to achieve with a laser beam than the connecting zone between the center electrode and its tip consisting of the iridium alloy.
- an alloying zone covering the entire cross section of the platinum alloy molding, which is formed from the platinum alloy and the nickel-based alloy, is difficult or impossible to achieve.
- this causes the bonding zone between the platinum alloy molding member and the ground electrode to be stressed by thermal stresses more than the bonding zone between the center electrode and its electrode tip formed from an iridium alloy.
- cracking is observed in the junction zone between the ground electrode and the platinum alloy molding, which can lead to premature termination of the spark plug life, until the platinum alloy is removed.
- EP 1 416 599 A2 to provide a 0.2 mm iridium alloy wafer with 40% by weight nickel between the base non-noble electrode and the precious metal alloy molding, which in this case is an iridium alloy or a platinum alloy.
- This disc is first welded by resistance welding to the base ground electrode, which according to the disclosure of EP 1 416 599 A2 as well as the center electrode consists of Inconel 600. Thereafter, a molded article of the iridium or platinum alloy, which is cylindrical and at its one end has a larger diameter flange, welded to this flange by resistance welding on the already welded to the ground electrode disc made of iridium nickel. Thereafter, a laser beam is applied to the connection zone to improve the weld joint.
- the iridium-40% nickel iridium washer provided between the non-noble ground electrode and the iridium or platinum alloy mold achieves thermal stresses in the junction zone between the Inconel 600 and the IrNi40 disk, as well as the thermal stresses between the IrNi40 and the molding of the nobler iridium or platinum alloy are lower than the thermal stresses between Inconel 600 and the iridium or platinum alloy molding without inserting the IrNi40 disk.
- IrNi40 has a linear thermal expansion coefficient that is between that of the ground electrode and that of the iridium or platinum alloy molding.
- the EP 1 376 791 A1 discloses between the non-noble ground electrode and the noble molding, with which the ground electrode is to be equipped, an intermediate piece - in particular of a noble metal alloy - provide, the linear expansion coefficient of which neither matches the ground electrode with that of the noble molding, but intervenes.
- a spark plug with the features specified in the preamble of claim 1 discloses the JP 2005-203110 A , Thereafter, it is known, a prefabricated rivet-shaped Composite part, which consists of a precious metal molding and an intermediate piece, which consists of the same base metal material as the ground electrode to weld butt to the ground electrode.
- the ground electrode is provided with a blind hole, in which a precious metal molded part is inserted and welded to the ground electrode.
- EP1341282 discloses the preamble of claims 1 and 4.
- the present invention has for its object to provide a way how the life of a generic spark plug can be extended.
- nickel-based alloys particularly, z. Inconel materials, in particular Inconel 600.
- Other well-suited alloys are nickel-based alloys containing 1.5 to 2.5% by weight of silicon, 1.5 to 3% by weight of aluminum, up to 0.5% by weight of manganese and 0.05 to 0.2 wt .-% of titanium in combination with 0.1 to 0.3 wt .-% zirconium and the remainder of nickel, wherein the zirconium may be wholly or partially replaced by the double mass hafnium
- Another suitable nickel-base alloy contains 1.5 to 2.5% by weight of silicon, 1.5 to 3% by weight of aluminum, up to 0.5% by weight of manganese and 0.005 to 0.2% by weight. Yttrium in combination with 0.05 to 0.3 wt .-% lanthanum and the balance nickel.
- platinum, iridium and their base alloys are particularly suitable platinum, iridium and their base alloys.
- platinum-based alloys are mainly iridium, rhodium, ruthenium, palladium, tungsten, nickel and osmium as alloying components into consideration.
- iridium-based alloys are mainly platinum, rhodium, palladium, rhenium and chromium as alloying components into consideration.
- Particularly suitable are iridium-rhodium alloys, in particular iridium with 10 wt .-% rhodium.
- the noble metal materials for the molding may contain small amounts of oxides of one or more of the elements zirconium, yttrium, hafnium, cerium, titanium, magnesium, barium and lanthanum, taken together preferably 0.05 to 1 wt .-%.
- the intermediate piece or a composite part formed from the non-precious intermediate piece and the noble molded part can be connected to the ground electrode in different ways. One possibility is to provide a continuous hole in the base ground electrode and to insert the composite part formed from the shaped part and the intermediate piece into the through hole in such a way that the intermediate piece can be welded thereto at the side facing away from the center electrode of the ground electrode.
- the precious metal-containing molded part should terminate flush with the center electrode facing surface of the ground electrode.
- claim 4 is a method for reinforcing a ground electrode for a spark plug having the features of claim 1.
- the noble metal-containing molded part, with which the ground electrode is to be reinforced welded to an intermediate piece of a material whose thermal expansion coefficient does not deviate from the thermal expansion coefficient of the base ground electrode.
- the composite part formed from the molded part and the intermediate piece is then inserted into the through hole of the ground electrode so that the molded part is flush with the surface of the ground electrode facing the center electrode, and is welded to the base ground electrode.
- the welded connection takes place on the center electrode opposite side of the ground electrode, and preferably by laser welding.
- the ground electrode usually consists of a profile wire with a rectangular profile, from which a straight section is separated and welded to the body of the spark plug. Only then is the ground electrode bent towards the center electrode.
- the composite part, with which the ground electrode is to be reinforced, is preferably welded to the ground electrode as long as the ground electrode is not yet bent towards the center electrode, but is still straight. This considerably facilitates the welding of the composite part to the ground electrode.
- the molded part and the intermediate piece are first provisionally connected to each other and then welded by means of a laser.
- Preliminary bonding can be accomplished by butting them together by electrical resistance welding.
- Another possibility is to butt the molded part and the intermediate piece by cold welding, for. B. by friction welding or by compression with simultaneous increase in diameter by upsetting. Electrical resistance welding and cold welding are known per se as a method of making bimetallic contact rivets.
- a composite part is formed by provisionally connecting the molded part to the intermediate piece, its connecting zone can be processed by laser welding in such a way that an alloy zone is formed which extends over the entire cross section of the composite part.
- the composite part is expediently rotated about its own longitudinal axis, while its connection zone is located in the area of action of the laser beam and is hit all around by the laser beam.
- the molded part and the intermediate piece can be cut off from a wire-shaped semifinished product and then joined together. But it is also possible to provisionally connect two wire-shaped semi-finished products at their ends first and then cut them from the respective semifinished product and to weld additionally with a laser. Finally, it is possible, a cut off from the semi-finished, consisting mainly of precious metal molding provisionally with the end of a base wire-shaped semifinished product to connect and only then to separate the composite part of non-precious semi-finished product. The latter approach is preferred.
- FIG. 1 shows a spark plug with a spark plug body 1 made of a highly heat-resistant alloy, for. B. of a nickel-based alloy.
- a ceramic insulator 2 is disposed, in which a center electrode 3 is embedded, which may be made of copper and is reinforced with a noble metal tip 5, which is welded to the front end of the center electrode 3 to form a connection zone 7, in which a Alloy of the constituents of the materials for the center electrode 3 and the noble metal tip 5 is present.
- a ground electrode 4 is welded, which usually consists of a nickel alloy.
- the ground electrode 4 is formed from a profile wire having a rectangular cross-section and formed as a roof electrode, that is, it is bent at right angles, so that its bent portion of the noble metal tip 5 of the center electrode 3 is opposite.
- the ground electrode 4 is reinforced with a predominantly made of precious metal molded part 6, which is welded to a base 9, which serves as an intermediate piece between the ground electrode 4 and the predominantly made of precious metal molding 6, which forms a the entire cross section of the base 9 detecting connecting zone 8 is welded to the base 9.
- In the connection zone 8 is an alloy of the constituents of the materials from which the intermediate piece 9 (the base) and the molded part 6 exist.
- the noble metal tip 5 and the molded part 6 formed of noble metal face each other at a predetermined distance.
- a molded part 6 is welded by electrical resistance welding.
- the molded part 6 is a section of a predominantly made of precious metal wire-shaped semifinished product whose diameter is slightly smaller than that of the semifinished product 10.
- the connection zone 8 between them with a laser processed, which is led around the connection zone 8.
- the composite of the semifinished product 10 and the molded part 6 can be rotated about its longitudinal axis 11, wherein the laser remains stationary directed to the connection zone 8.
- connection zone 8 which consists of the constituents of the materials of the wire sections involved and extends over the entire cross section of the molded part 6 and the intermediate piece 9.
- a composite part 12 which consists of the molded part 6, the connection zone 8 and an intermediate piece 9 of the semifinished product 10, separated from the semifinished product 10 and welded to the ground electrode 4.
- FIG. 2a shows a way to arm the ground electrode 4, namely by means of a composite part 12, the intermediate piece 9 is provided with a head 9a, which may be formed by upsetting.
- a composite part 12 is inserted from behind into a through hole 14 of the ground electrode 4 and welded to it at the side facing away from the center electrode 3 of the ground electrode 4, where the head 9a abuts against the ground electrode 4.
- the welding can be done by laser welding alone.
- the molded part 6 is flush with the surface of the ground electrode 4.
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Spark Plugs (AREA)
Description
Die Erfindung geht von einer Zündkerze mit den im Oberbegriff des Anspruchs 1 angegebenen Merkmalen und von einem Verfahren mit den im Oberbegriff des Anspruchs 4 angegebenen Merkmalen aus.The invention relates to a spark plug with the features specified in the preamble of
Aus der
Die Masseelektrode der bekannten Zündkerze ist wie üblich aus einem Flachdraht mit rechteckigem Querschnitt gebildet und besteht aus einer hochwärmebeständigen Nickelbasislegierung. Sie ist mit einem Formteil aus einer Platinlegierung mit mehr als 50 Gew.-% Platin und mit wenigstens einem Metall aus der Gruppe Iridium, Rhodium, Nickel, Wolfram, Palladium, Ruthenium und Rhenium armiert. Als Formteil offenbart die
Um dem zu begegnen, offenbart die
Durch die zwischen der unedlen Masseelektrode und dem Formteil aus der Iridium- oder Platinlegierung vorgesehene Scheibe aus Iridium mit 40 % Nickel wird erreicht, dass die Wärmespannungen in der Verbindungszone zwischen dem Inconel 600 und der Scheibe aus IrNi40 sowie die Wärmespannungen zwischen der Scheibe aus IrNi40 und dem Formteil aus der edleren Iridium- oder Platinlegierung geringer sind als es die Wärmespannungen zwischen Inconel 600 und dem Formteil aus der Iridium- oder Platinlegierung ohne Einfügen der Scheibe aus IrNi40 wären. Der Grund dafür liegt darin, dass IrNi40 einen linearen thermischen Ausdehnungskoeffizienten hat, der zwischen dem der Masseelektrode und dem des Formteils aus der Iridium- oder Platinlegierung liegt.The iridium-40% nickel iridium washer provided between the non-noble ground electrode and the iridium or platinum alloy mold achieves thermal stresses in the junction zone between the Inconel 600 and the IrNi40 disk, as well as the thermal stresses between the IrNi40 and the molding of the nobler iridium or platinum alloy are lower than the thermal stresses between Inconel 600 and the iridium or platinum alloy molding without inserting the IrNi40 disk. The reason for this is that IrNi40 has a linear thermal expansion coefficient that is between that of the ground electrode and that of the iridium or platinum alloy molding.
Es bleibt jedoch der Nachteil, dass es sowohl beim Aufschweißen der dünnen Scheibe aus IrNi40 auf das Inconel 600 als auch beim Aufschweißen des Formteils aus der edleren Iridium- oder Platinlegierung auf die dünne Scheibe aus IrNi40 schwierig oder unmöglich ist, eine sich über den gesamten Querschnitt des Formteils erstreckende Legierungszone zu erhalten. Die Legierungszone erfasst vielmehr, wie Figur 6 der
Die
Eine Zündkerze mit den im Oberbegriff des Anspruchs 1 angegebenen Merkmalen offenbart die
In der
Diese Aufgabe wird gelöst durch eine Zündkerze mit den im Anspruch 1 angegebenen Merkmalen und durch ein Verfahren zu ihrer Herstellung mit den im Anspruch 4 angegebenen Merkmalen. Vorteilhafte Weiterbildungen der Erfindung sind Gegenstand der Unteransprüche.This object is achieved by a spark plug having the features specified in
Bei einer erfindungsgemäßen Zündkerze hat das Zwischenstück einen thermischen Ausdehnungskoeffizienten, der nicht von dem thermischen Ausdehnungskoeffizienten der unedlen Masseelektrode abweicht. Am besten besteht das Zwischenstück aus demselben Werkstoff wie die unedle Masseelektrode. Das aus dem Formteil und dem Zwischenstück gebildete Verbundteil steckt so in einem durchgehenden Loch der Masseelektrode, dass es bündig mit der der Mittelelektrode zugewandten Oberfläche der Masseelektrode abschließt. Das hat wesentliche Vorteile:
- Das Zwischenstück passt bestmöglich zum Material der Masseelektrode, was für das Verschweißen des Zwischenstücks mit der Masseelektrode optimal ist.
- In der Verbindungszone zwischen der Masseelektrode und dem Zwischenstück treten keine Wärmespannungen auf. Deshalb ist ein Ablösen des Zwischenstückes von der Masseelektrode selbst dann nicht zu befürchten, wenn sich die Schweißzone nicht auf den gesamten Querschnitt des Zwischenstücks erstreckt, sondern nur auf den Randbereich.
- Das Formteil aus einem Edelmetall oder aus einer Edelmetalllegierung kann auf das Zwischenstück geschweißt werden, bevor das Zwischenstück mit der unedlen Masseelektrode verschweißt wird. Einschränkungen, wie sie beim Aufschweißen des Zwischenstücks auf die Masseelektrode auftreten würden, treten nicht auf, wenn das Formteil und das Zwischenstück miteinander verschweißt werden, bevor das Zwischenstück mit der Masseelektrode verschweißt wird, vielmehr ist die Verbindungszone zwischen dem Formteil und dem Zwischenstück von allen Seiten her bestens zugänglich, so dass eine sich über den gesamten Querschnitt erstreckende Legierungszone aus dem Werkstoff des Formteils und aus dem Werkstoff des Zwischenstücks gebildet werden kann. In der Legierungszone gibt es einen stetigen Übergang vom niedrigeren Wärmeausdehnungskoeffizienten des Edelmetallwerkstoffs zum höheren Wärmeausdehnungskoeffizienten des unedlen Werkstoffs des Zwischenstückes. Zusammengenommen setzen diese beiden Maßnahmen das Risiko einer Rissbildung in der Legierungszone drastisch herab.
- Durch das Aufbringen des Edelmetall-Formteils auf das unedle Zwischenstück als Sockel kann der Spannungsbedarf für die Erzeugung der Zündfunken herabgesetzt werden. Das führt in weiterer Folge in Verbindung mit dem Einbetten des Edelmetallformteils in die unedle Masseelektrode, so dass das Formteil bündig mit der Oberfläche der unedlen Masseelektrode abschließt, zu einem geringeren Abbrand, zu einer erhöhten Lebensdauer und auch zu verbesserten Kaltstarteigenschaften, weil bei verschmutzten Zündkerzen der parasitäre Anteil beim Spannungsanstieg infolge des geringeren Spannungsbedarfes herabgesetzt wird.
- The adapter fits best possible to the material of the ground electrode, which is optimal for welding the intermediate piece with the ground electrode.
- In the connection zone between the ground electrode and the intermediate piece, no thermal stresses occur. Therefore, a detachment of the intermediate piece from the ground electrode is not to be feared even if the welding zone does not extend to the entire cross section of the intermediate piece, but only to the edge region.
- The molded article made of a noble metal or a noble metal alloy can be welded onto the intermediate piece before the intermediate piece is welded to the base ground electrode. Restrictions, such as when welding of the intermediate piece on the ground electrode, do not occur when the molded part and the intermediate piece are welded together before the intermediate piece is welded to the ground electrode, but the connection zone between the molding and the intermediate piece is easily accessible from all sides, so that an alloying zone extending over the entire cross-section can be formed from the material of the molded part and from the material of the intermediate piece. In the alloying zone there is a steady transition from the lower coefficient of thermal expansion of the noble metal material to the higher coefficient of thermal expansion of the base non-precious material. Taken together, these two measures drastically reduce the risk of cracking in the alloy zone.
- By applying the precious metal molding on the base base as a base, the voltage requirement for the generation of the spark can be reduced. This leads in consequence in connection with the embedding of the noble metal molded part in the non-noble ground electrode, so that the molded part flush with the surface of the base ground electrode, to a lower burnup, increased life and also to improved cold start, because with soiled spark plugs parasitic component is reduced in the voltage increase due to the lower voltage requirement.
Als Werkstoff für die unedle Masseelektrode und auch für das Zwischenstück eignen sich hochwärmebeständige Nickelbasislegierungen besonders, z. B. Inconelwerkstoffe, insbesondere Inconel 600. Andere gut geeignete Legierungen sind Nickelbasislegierungen, welche 1,5 bis 2,5 Gew.-% Silizium, 1,5 bis 3 Gew.-% Aluminium, bis zu 0,5 Gew.-% Mangan und 0,05 bis 0,2 Gew.-% Titan in Kombination mit 0,1 bis 0,3 Gew.-% Zirkon enthalten und zum Rest aus Nickel bestehen, wobei das Zirkon ganz oder teilweise durch die doppelte Masse Hafnium ersetzt sein kann. Eine andere gut geeignete Nickelbasislegierung enthält 1,5 bis 2,5 Gew.-% Silizium, 1,5 bis 3 Gew.-% Aluminium, bis zu 0,5 Gew.-% Mangan und 0,005 bis 0,2 Gew.-% Yttrium in Kombination mit 0,05 bis 0,3 Gew.-% Lanthan und als Rest Nickel.As a material for the non-noble ground electrode and also for the intermediate piece are highly heat-resistant nickel-based alloys particularly, z. Inconel materials, in particular Inconel 600. Other well-suited alloys are nickel-based alloys containing 1.5 to 2.5% by weight of silicon, 1.5 to 3% by weight of aluminum, up to 0.5% by weight of manganese and 0.05 to 0.2 wt .-% of titanium in combination with 0.1 to 0.3 wt .-% zirconium and the remainder of nickel, wherein the zirconium may be wholly or partially replaced by the double mass hafnium , Another suitable nickel-base alloy contains 1.5 to 2.5% by weight of silicon, 1.5 to 3% by weight of aluminum, up to 0.5% by weight of manganese and 0.005 to 0.2% by weight. Yttrium in combination with 0.05 to 0.3 wt .-% lanthanum and the balance nickel.
Als Edelmetallwerkstoffe für das Formteil eignen sich besonders Platin, Iridium und deren Basislegierungen. Für Platinbasislegierungen kommen vor allem Iridium, Rhodium, Ruthenium, Palladium, Wolfram, Nickel und Osmium als Legierungsbestandteile in Betracht. Für Iridiumbasislegierungen kommen vor allem Platin, Rhodium, Palladium, Rhenium und Chrom als Legierungsbestandteile in Betracht. Besonders geeignet sind Iridium-Rhodiumlegierungen, insbesondere Iridium mit 10 Gew.-% Rhodium. Darüber hinaus können die Edelmetallwerkstoffe für das Formteil noch geringe Mengen Oxide eines oder mehrerer der Elemente Zirkon, Yttrium, Hafnium, Cer, Titan, Magnesium, Barium und Lanthan enthalten, zusammengenommen vorzugsweise 0,05 bis 1 Gew.-%. Das Zwischenstück bzw. ein aus dem unedlen Zwischenstück und dem edlen Formteil gebildetes Verbundteil kann auf unterschiedliche Weise mit der Masseelektrode verbunden werden. Eine Möglichkeit besteht darin, in der unedlen Masseelektrode ein durchgehendes Loch vorzusehen und das aus dem Formteil und dem Zwischenstück gebildete Verbundteil so in die durchgehende Bohrung einzusetzen, dass das Zwischenstück an der der Mittelelektrode abgewandten Seite der Masseelektrode mit dieser verschweißt werden kann. Das kann dadurch erleichtert werden, dass das Verbundteil nach Art eines Nietes mit einem Kopf versehen ist, welcher sich an dem Zwischenstück befindet und an der Masseelektrode anschlägt, wenn das Verbundteil in das Loch der Masseelektrode gesteckt wird. Das edelmetallhaltige Formteil soll bündig mit der der Mittelelektrode zugewandten Oberfläche der Masseelektrode abschließen.As noble metal materials for the molding are particularly suitable platinum, iridium and their base alloys. For platinum-based alloys are mainly iridium, rhodium, ruthenium, palladium, tungsten, nickel and osmium as alloying components into consideration. For iridium-based alloys are mainly platinum, rhodium, palladium, rhenium and chromium as alloying components into consideration. Particularly suitable are iridium-rhodium alloys, in particular iridium with 10 wt .-% rhodium. In addition, the noble metal materials for the molding may contain small amounts of oxides of one or more of the elements zirconium, yttrium, hafnium, cerium, titanium, magnesium, barium and lanthanum, taken together preferably 0.05 to 1 wt .-%. The intermediate piece or a composite part formed from the non-precious intermediate piece and the noble molded part can be connected to the ground electrode in different ways. One possibility is to provide a continuous hole in the base ground electrode and to insert the composite part formed from the shaped part and the intermediate piece into the through hole in such a way that the intermediate piece can be welded thereto at the side facing away from the center electrode of the ground electrode. This can be facilitated by providing the composite part with a head in the manner of a rivet, which is located at the intermediate piece and abuts against the ground electrode when the composite part is inserted into the hole of the ground electrode. The precious metal-containing molded part should terminate flush with the center electrode facing surface of the ground electrode.
Gegenstand des Anspruchs 4 ist ein Verfahren zum Armieren einer Masseelektrode für eine Zündkerze mit den Merkmalen des Anspruchs 1.The subject matter of
Beim Herstellen einer solchen Zündkerze wird das edelmetallhaltige Formteil, mit welchem die Masseelektrode armiert werden soll, auf ein Zwischenstück aus einem Werkstoff geschweißt, dessen thermischer Ausdehnungskoeffizient nicht vom thermischen Ausdehnungskoeffizienten der unedlen Masseelektrode abweicht. Das aus dem Formteil und dem Zwischenstück gebildete Verbundteil wird anschließend so in das durchgehende Loch der Masseelektrode gesteckt, dass das Formteil mit der der Mittelelektrode zugewandten Oberfläche der Masseelektrode bündig abschließt, und wird mit der unedlen Masseelektrode verschweißt. Die Schweißverbindung erfolgt auf der der Mittelelektrode abgewandten Seite der Masseelektrode und zwar am besten durch Laserschweißen.When producing such a spark plug, the noble metal-containing molded part, with which the ground electrode is to be reinforced, welded to an intermediate piece of a material whose thermal expansion coefficient does not deviate from the thermal expansion coefficient of the base ground electrode. The composite part formed from the molded part and the intermediate piece is then inserted into the through hole of the ground electrode so that the molded part is flush with the surface of the ground electrode facing the center electrode, and is welded to the base ground electrode. The welded connection takes place on the center electrode opposite side of the ground electrode, and preferably by laser welding.
Die Masseelektrode besteht üblicherweise aus einem Profildraht mit einem Rechteckprofil, von welchem ein gerader Abschnitt abgetrennt und mit dem Körper der Zündkerze verschweißt wird. Erst danach wird die Masseelektrode zur Mittelelektrode hin gebogen. Das Verbundteil, mit welchem die Masseelektrode armiert werden soll, wird mit der Masseelektrode vorzugsweise verschweißt, solange wie die Masseelektrode noch nicht zur Mittelelektrode hin gebogen ist, sondern noch gerade verläuft. Das erleichtert das Verschweißen des Verbundteils mit der Masseelektrode beträchtlich.The ground electrode usually consists of a profile wire with a rectangular profile, from which a straight section is separated and welded to the body of the spark plug. Only then is the ground electrode bent towards the center electrode. The composite part, with which the ground electrode is to be reinforced, is preferably welded to the ground electrode as long as the ground electrode is not yet bent towards the center electrode, but is still straight. This considerably facilitates the welding of the composite part to the ground electrode.
Vorzugsweise werden das Formteil und das Zwischenstück zunächst vorläufig miteinander verbunden und anschließend mittels eines Lasers verschweißt. Das vorläufige Verbinden kann dadurch geschehen, dass sie durch elektrisches Widerstandsschweißen stumpf miteinander verschweißt werden. Eine andere Möglichkeit besteht darin, das Formteil und das Zwischenstück durch Kaltverschweißen stumpf miteinander zu verbinden, z. B. durch Reibschweißen oder durch Zusammenpressen unter gleichzeitiger Durchmesservergrößerung durch Stauchen. Das elektrische Widerstandsschweißen und das Kaltverschweißen sind als Verfahren zum Herstellen von Bimetallkontaktnieten an sich bekannt.Preferably, the molded part and the intermediate piece are first provisionally connected to each other and then welded by means of a laser. Preliminary bonding can be accomplished by butting them together by electrical resistance welding. Another possibility is to butt the molded part and the intermediate piece by cold welding, for. B. by friction welding or by compression with simultaneous increase in diameter by upsetting. Electrical resistance welding and cold welding are known per se as a method of making bimetallic contact rivets.
Ist durch vorläufiges Verbinden des Formteils mit dem Zwischenstück ein Verbundteil gebildet, kann deren Verbindungszone durch Laserschweißen so bearbeitet werden, dass sich eine Legierungszone ausbildet, welche sich über den gesamten Querschnitt des Verbundteils erstreckt. Dazu wird das Verbundteil zweckmäßigerweise um seine eigene Längsachse gedreht, während sich seine Verbindungszone im Einwirkungsbereich des Laserstrahls befindet und rundum vom Laserstrahl getroffen wird.If a composite part is formed by provisionally connecting the molded part to the intermediate piece, its connecting zone can be processed by laser welding in such a way that an alloy zone is formed which extends over the entire cross section of the composite part. For this purpose, the composite part is expediently rotated about its own longitudinal axis, while its connection zone is located in the area of action of the laser beam and is hit all around by the laser beam.
Das Formteil und das Zwischenstück können von einem drahtförmigen Halbzeug abgeschnitten und dann miteinander verbunden werden. Es ist aber auch möglich, zwei drahtförmige Halbzeuge zunächst an ihren Enden vorläufig miteinander zu verbinden und sie erst dann vom jeweiligen Halbzeug abzuschneiden und ergänzend mit einem Laser zu verschweißen. Schließlich ist es möglich, ein vom Halbzeug abgeschnittenes, überwiegend aus Edelmetall bestehendes Formteil vorläufig mit dem Ende eines unedlen drahtförmigen Halbzeugs zu verbinden und erst danach das Verbundteil vom unedlen Halbzeug zu trennen. Die zuletzt genannte Vorgehensweise wird bevorzugt.The molded part and the intermediate piece can be cut off from a wire-shaped semifinished product and then joined together. But it is also possible to provisionally connect two wire-shaped semi-finished products at their ends first and then cut them from the respective semifinished product and to weld additionally with a laser. Finally, it is possible, a cut off from the semi-finished, consisting mainly of precious metal molding provisionally with the end of a base wire-shaped semifinished product to connect and only then to separate the composite part of non-precious semi-finished product. The latter approach is preferred.
Anstelle des Laserschweißens kann auch ein Elektronenstrahlschweißen stattfinden.Instead of laser welding and electron beam welding can take place.
Der weiteren Erläuterung der Erfindung dienen die beigefügten Zeichnungen. Darin zeigen
-
die Spitze einer nicht erfindungsgemäßen Zündkerze in einer Schrägansicht,Figur 1 -
verschiedene Schritte beim Armieren einer Masseelektrode einer Zündkerze undFigur 2 -
Figur 2a ein Beispiel der Armierung einer Masseelektrode.
-
FIG. 1 the tip of a spark plug not according to the invention in an oblique view, -
FIG. 2 various steps in arming a ground electrode of a spark plug and -
FIG. 2a an example of the reinforcement of a ground electrode.
Gleiche oder einander entsprechende Teile sind in den Beispielen mit übereinstimmenden Bezugszahlen bezeichnet.Like or corresponding parts are designated in the examples with corresponding reference numerals.
Auf den vorderen Rand des Körpers 1 ist eine Masseelektrode 4 geschweißt, welche üblicherweise aus einer Nickellegierung besteht. Die Masselelektrode 4 ist aus einem Profildraht mit rechteckigem Querschnitt gebildet und als Dachelektrode ausgebildet, d. h., sie ist rechtwinklig umgebogen, so dass ihr umgebogener Abschnitt der Edelmetallspitze 5 der Mittelelektrode 3 gegenüberliegt. Die Masseelektrode 4 ist mit einem überwiegend aus Edelmetall bestehenden Formteil 6 armiert, welches auf einen Sockel 9 geschweißt ist, der als Zwischenstück zwischen der Masseelektrode 4 und dem überwiegend aus Edelmetall bestehenden Formteil 6 dient, welches unter Ausbildung einer den ganzen Querschnitt des Sockels 9 erfassenden Verbindungszone 8 mit dem Sockel 9 verschweißt ist. In der Verbindungszone 8 liegt eine Legierung aus den Bestandteilen der Werkstoffe vor, aus welchen das Zwischenstück 9 (der Sockel) und das Formteil 6 bestehen. Die Edelmetallspitze 5 und das aus Edelmetall gebildete Formteil 6 liegen einander in vorbestimmtem Abstand gegenüber.On the front edge of the
Zum Armieren der Masseelektrode 4 geht man vorzugsweise so vor, wie es in
- 1.1.
- Körper der ZündkerzeBody of the spark plug
- 2.Second
- Isolatorinsulator
- 3.Third
- Mittelelektrodecenter electrode
- 4.4th
- Masseelektrodeground electrode
- 5.5th
- Edelmetallspitzenoble metal tip
- 6.6th
- Formteilmolding
- 7.7th
- Verbindungszoneconnecting zone
- 8.8th.
- Verbindungszoneconnecting zone
- 9.9th
- Zwischenstück, als Sockel ausgebildetAdapter, designed as a base
- 9a.9a.
- Kopfhead
- 10.10th
- HalbzeugWorkpiece
- 11.11th
- Längsachselongitudinal axis
- 12.12th
- Verbundteilcomposite part
- 14.14th
- durchgehendes Lochthrough hole
Claims (10)
- Spark plug- having a body (1) made of a non-noble metal material in which an insulator (2) is arranged,- having a central electrode (3) arranged in the insulator (2),- having a ground electrode (4) that proceeds from the body (1) and to which is welded a molded part (6) that faces the central electrode (3) and the mass of which primarily consists of one or a plurality of noble metals, and,- having an intermediate piece (9) that is provided between the molded part (6) and the ground electrode (4) and that is welded to the molded part (6) and to the ground electrode (4),wherein a composite part (12) formed from the molded part (6) and the intermediate piece (9) is inserted in a hole (14) of the non-noble ground electrode (4) and passes through the ground electrode (4), and
wherein the intermediate piece (9) is welded to the ground electrode (4) at the side thereof that faces away from the central electrode (3),
characterized in that the intermediate piece (9) consists of the same material as the non-noble ground electrode (4), and,
in that the molded part (6) closes in a flush manner with the surface of the ground electrode (4) facing the central electrode (3). - The spark plug according to claim 1, characterized in that the molded part (6) consists of platinum
or of a platinum-based alloy that contains one or a plurality of the components iridium, rhodium, ruthenium, palladium, tungsten, nickel, and osmium,
or consists of iridium
or of an iridium-based alloy that contains one or a plurality of the following components: rhodium, platinum, nickel, chromium, palladium, rhenium. - The spark plug according to any of the foregoing claims, characterized in that the molded part contains an oxide of one or a plurality of the elements zirconium, yttrium, hafnium, cerium, titanium, magnesium, barium, lanthanum.
- The method for reinforcing a ground electrode (4) of a spark plug according to any of the foregoing claims having a molded part (6), the mass of which primarily consists of one or a plurality of noble metals, in that the molded part (6) is welded onto an intermediate piece (9),
wherein a through-hole (14) is provided in the non-noble ground electrode (4), wherein the composite part (12) formed from the molded part (6) and the intermediate piece (9) is inserted into the through-hole (14), and,
wherein the intermediate piece (9) is welded to the non-noble ground electrode (4) at the side thereof that faces away from the central electrode (3), characterized in that the intermediate piece (9) consists of the same material as the non-noble ground electrode (4), and,
in that the composite part (12) formed from the molded part (6) and the intermediate piece (9) is inserted into the through-hole (14) such that the composite part (12) closes in a flush manner with the surface of the ground electrode (4) facing the central electrode (3). - The method in accordance with claim 4, characterized in that the molded part (6) and the intermediate piece (9) are first temporarily connected to one another and then are welded to one another using a laser or electron beam welding.
- The method in accordance with claim 5, characterized in that the molded part (6) and the intermediate piece (9) are rotated about their common center longitudinal axis (11) and during this are welded with the laser.
- The method in accordance with claim 5 or 6, characterized in that the molded part (6) and the intermediate piece (9) are temporarily connected to one another using resistance welding or using cold welding.
- The method in accordance with any one of claims 4 through 7, characterized in that wire segments are used as molded part (6) and as intermediate piece (9).
- The method in accordance with claim 8, characterized in that the molded part (6) and a wire from which the intermediate piece (9) is formed are temporarily butt welded to one another,
a composite part (12) formed thereby is separated from the wire supply and then the connection zone (8) between the molded part (6) and the wire for forming an alloy extending across the entire cross-section is additionally welded with a laser or using electron beam welding. - The method in accordance with claim 8, characterized in that the molded part (6) and a wire from which the intermediate piece (9) is formed are temporarily butt welded to one another, then the connection zone (8) between the molded part (6) and the wire for forming an alloy extending across the entire cross-section is additionally welded with a laser or using electron beam welding and then a composite part (12) formed thereby is separated from the wire supply.
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US9368943B2 (en) | 2013-03-12 | 2016-06-14 | Federal-Mogul Ignition Company | Spark plug having multi-layer sparking component attached to ground electrode |
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JP2004186152A (en) * | 2002-11-22 | 2004-07-02 | Ngk Spark Plug Co Ltd | Sparking plug and manufacturing method thereof |
JP2005203110A (en) * | 2004-01-13 | 2005-07-28 | Ngk Spark Plug Co Ltd | Manufacturing method of spark plug, and spark plug |
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JP2877035B2 (en) | 1995-06-15 | 1999-03-31 | 株式会社デンソー | Spark plug for internal combustion engine |
JP3361479B2 (en) | 1999-04-30 | 2003-01-07 | 日本特殊陶業株式会社 | Manufacturing method of spark plug |
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DE60302012T2 (en) | 2002-06-21 | 2006-07-13 | NGK Spark Plug Co., Ltd., Nagoya | Spark plug and its manufacturing process |
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DE10252736B4 (en) * | 2002-11-13 | 2004-09-23 | Robert Bosch Gmbh | spark plug |
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