EP2001825A1 - Procédé d'obtention industrielle de propène - Google Patents

Procédé d'obtention industrielle de propène

Info

Publication number
EP2001825A1
EP2001825A1 EP07727206A EP07727206A EP2001825A1 EP 2001825 A1 EP2001825 A1 EP 2001825A1 EP 07727206 A EP07727206 A EP 07727206A EP 07727206 A EP07727206 A EP 07727206A EP 2001825 A1 EP2001825 A1 EP 2001825A1
Authority
EP
European Patent Office
Prior art keywords
propene
acid
propane
gas stream
dehydrogenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07727206A
Other languages
German (de)
English (en)
Inventor
Markus Schubert
Ulrich Mueller
Christoph Kiener
Friedhelm Teich
Sven Crone
Falk Simon
Joerg Pastre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to EP07727206A priority Critical patent/EP2001825A1/fr
Publication of EP2001825A1 publication Critical patent/EP2001825A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/31—Pore size distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/402—Further details for adsorption processes and devices using two beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/403—Further details for adsorption processes and devices using three beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/404—Further details for adsorption processes and devices using four beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B01D53/0476—Vacuum pressure swing adsorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

La présente invention concerne un procédé d'obtention industrielle de propène à partir d'un flux de gaz contenant du propène et au moins un autre hydrocarbure, ce procédé consistant (a) à mettre en contact le flux de gaz avec un adsorbant contenant un matériau d'ossature organométallique poreux contenant au moins un composé organique bidenté coordonné à au moins un ion métallique, ledit adsorbant étant chargé de propène, et (b) à libérer le propène de l'adsorbant chargé de propène. L'invention concerne en outre l'utilisation d'un matériau d'ossature organométallique poreux en vue de l'obtention industrielle de propène à partir d'un flux de gaz contenant du propène et au moins un autre hydrocarbure.
EP07727206A 2006-03-29 2007-03-22 Procédé d'obtention industrielle de propène Withdrawn EP2001825A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07727206A EP2001825A1 (fr) 2006-03-29 2007-03-22 Procédé d'obtention industrielle de propène

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06111918 2006-03-29
EP07727206A EP2001825A1 (fr) 2006-03-29 2007-03-22 Procédé d'obtention industrielle de propène
PCT/EP2007/052730 WO2007113118A1 (fr) 2006-03-29 2007-03-22 Procédé d'obtention industrielle de propène

Publications (1)

Publication Number Publication Date
EP2001825A1 true EP2001825A1 (fr) 2008-12-17

Family

ID=38292675

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07727206A Withdrawn EP2001825A1 (fr) 2006-03-29 2007-03-22 Procédé d'obtention industrielle de propène

Country Status (6)

Country Link
EP (1) EP2001825A1 (fr)
KR (1) KR20080114821A (fr)
CN (1) CN101454260A (fr)
BR (1) BRPI0710208A2 (fr)
RU (1) RU2008142555A (fr)
WO (1) WO2007113118A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109746046A (zh) * 2017-11-03 2019-05-14 中国石油化工股份有限公司 一种用于脱氢反应的反应器及其制备方法和应用

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101493529B1 (ko) 2006-04-18 2015-02-13 바스프 에스이 유기금속성 알루미늄 푸마레이트 골격재
ES2402323T3 (es) 2007-05-21 2013-04-30 Basf Se Aminocarboxilatos de aluminio como materiales estructurales organometálicos porosos
EP2318337B1 (fr) * 2008-07-21 2012-06-27 Basf Se Procédé d'obtention industrielle du propène
CN103111262B (zh) * 2013-01-31 2014-11-26 北京大学 一种金属有机骨架多孔材料及其制备方法
CN103193578A (zh) * 2013-04-08 2013-07-10 浙江师范大学 一种利用金属有机骨架材料分离丙烯和丙烷的方法
CN104415737A (zh) * 2013-08-23 2015-03-18 中国科学院大连化学物理研究所 用于甲烷-氮气吸附分离的镁基金属有机骨架材料及制备
CN104772119A (zh) * 2015-03-20 2015-07-15 华南理工大学 一种温敏金属有机骨架材料及其制备方法与应用
CN108126664B (zh) * 2016-12-01 2020-11-24 万华化学集团股份有限公司 一种用于净化烯烃的改性分子筛及利用其去除烯烃中含氧杂质的方法
CN109293467B (zh) 2018-11-09 2021-05-25 浙江大学 一种吸附分离丙烯、丙炔、丙烷和丙二烯的方法
KR102028140B1 (ko) * 2019-03-06 2019-10-02 한국화학연구원 탄화수소 정제를 통한 경질 올레핀 추출 시스템 및 탄화수소 정제를 통한 경질 올레핀 추출 방법
CN113181881B (zh) * 2021-04-29 2023-04-14 郑州大学 一种ZIF-8@Ag配合物核壳结构杂化材料及其制备方法和应用
CN114213754B (zh) * 2021-12-22 2023-04-25 平湖市浙江工业大学新材料研究院 一种MOFs粒子掺杂的复合材料及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI932187A (fi) * 1992-05-29 1993-11-30 Boc Group Inc Foerfarande foer framstaellning av omaettade kolvaeten och separering av desamma fraon maettade kolvaeten
DE102004061238A1 (de) * 2004-12-20 2006-06-22 Basf Ag Adsorptive Anreicherung von Methan in Methan-haltigen Gasgemischen

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2007113118A1 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109746046A (zh) * 2017-11-03 2019-05-14 中国石油化工股份有限公司 一种用于脱氢反应的反应器及其制备方法和应用
CN109746046B (zh) * 2017-11-03 2022-03-29 中国石油化工股份有限公司 一种用于脱氢反应的反应器及其制备方法和应用

Also Published As

Publication number Publication date
WO2007113118A1 (fr) 2007-10-11
RU2008142555A (ru) 2010-05-10
BRPI0710208A2 (pt) 2011-05-24
CN101454260A (zh) 2009-06-10
KR20080114821A (ko) 2008-12-31

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