EP1994185B1 - PROCEDE ET INSTALLATION POUR l'INTEGRATION D'UN HAUT-FOURNEAU ET D'UNE UNITE DE SEPARATION DE GAZ DE L'AIR - Google Patents
PROCEDE ET INSTALLATION POUR l'INTEGRATION D'UN HAUT-FOURNEAU ET D'UNE UNITE DE SEPARATION DE GAZ DE L'AIR Download PDFInfo
- Publication number
- EP1994185B1 EP1994185B1 EP07731629A EP07731629A EP1994185B1 EP 1994185 B1 EP1994185 B1 EP 1994185B1 EP 07731629 A EP07731629 A EP 07731629A EP 07731629 A EP07731629 A EP 07731629A EP 1994185 B1 EP1994185 B1 EP 1994185B1
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- EP
- European Patent Office
- Prior art keywords
- separation unit
- air
- gas separation
- oxygen
- blast furnace
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000000926 separation method Methods 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims abstract description 14
- 239000007789 gas Substances 0.000 claims abstract description 45
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 44
- 239000001301 oxygen Substances 0.000 claims abstract description 44
- 238000009434 installation Methods 0.000 claims description 3
- 239000003570 air Substances 0.000 description 75
- 229910001018 Cast iron Inorganic materials 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000571 coke Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
- F25J3/04969—Retrofitting or revamping of an existing air fractionation unit
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
- F25J3/04551—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production
- F25J3/04557—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production for pig iron or steel making, e.g. blast furnace, Corex
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04593—The air gas consuming unit is also fed by an air stream
- F25J3/046—Completely integrated air feed compression, i.e. common MAC
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04593—The air gas consuming unit is also fed by an air stream
- F25J3/04606—Partially integrated air feed compression, i.e. independent MAC for the air fractionation unit plus additional air feed from the air gas consuming unit
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04781—Pressure changing devices, e.g. for compression, expansion, liquid pumping
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04812—Different modes, i.e. "runs" of operation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04812—Different modes, i.e. "runs" of operation
- F25J3/04824—Stopping of the process, e.g. defrosting or deriming; Back-up procedures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04866—Construction and layout of air fractionation equipments, e.g. valves, machines
- F25J3/04951—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network
- F25J3/04957—Arrangements of multiple air fractionation units or multiple equipments fulfilling the same process step, e.g. multiple trains in a network and inter-connecting equipments upstream of the fractionation unit (s), i.e. at the "front-end"
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/24—Multiple compressors or compressor stages in parallel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
- F25J2230/40—Processes or apparatus involving steps for increasing the pressure of gaseous process streams the fluid being air
Definitions
- the present invention relates to a method of integrating at least one blast furnace and at least one air gas separation unit, wherein blast furnace and at least one blast separation unit are provided.
- air gases are supplied with air by at least n + 1 compressors with n ⁇ 1, and preferably> 1.
- the blast furnace is the most common equipment for producing cast iron mainly composed of iron (from 92 to 95% by weight), carbon (from 3 to 5% by weight), and other elements in small quantities such as silicon, manganese, phosphorus, sulfur, etc.
- This cast iron is then converted into steel in an oxygen converter by injecting oxygen into the cast iron in the liquid state allowing oxidation, especially of carbon.
- the steel obtained will then be refined and put in the desired shade (silicon, manganese etc ...) before being poured into ingots, slabs, blooms, or billets).
- a blast furnace is mainly supplied with iron ore (generally 1.3 to 1.6 tonnes per tonne of cast iron produced) in the form of agglomerates or "pellets" (in English), which are charged by the blast furnace.
- blast furnace coke (between 250 and 500 kg per ton of cast iron) also charged by the top, pulverized coal and injected at the tuyeres, with an injected quantity which can vary between 0 and 250 kg per ton of melting, or any other fuel such as natural gas, fuel oil, coke oven gas, plastics, and air that is still called “wind” for a flow rate that may vary from 800 to 1200 Nm 3 per tonne of cast iron produced enriched or not with oxygen, this enrichment may vary from 0 to 15% by volume, or from 0 to 150 Nm 3 of oxygen per tonne of cast iron produced.
- the gas or gas mixture resulting from the blast furnace is generally recovered and used for its thermal value, either in direct exchange to lower its temperature and to increase that of the gas or the fluid with which it is in heat exchange, either by combustion, by example CO with oxygen to produce additional calories.
- the blast furnace wind enriched or not with oxygen, is injected at the base of the blast furnace at nozzles which are distributed around the circumference of the blast furnace.
- This wind is injected under a pressure that can vary from 1 to 7x10 5 Pa., To overcome the pressure drop in the blast furnace and the pressure existing above the load in the blast furnace.
- the required airflows are very high, ranging from 5000 Nm 3 / hour for very small blast furnaces (for example, blast furnaces that we see in China today) up to 500000 Nm 3 for very big industrial blast furnaces.
- blower or more being dedicated to a blast furnace.
- blast furnaces In a factory producing cast iron and having more than one blast furnace, blast furnaces, at least n + 1 blowers, and sometimes n + 2 blowers, are generally available for continuous blast furnace production. melting when any of these blowers eventually fails (or must be shut down for maintenance or any other cause).
- the redundant blowers also called blower seconds
- blower seconds relative to the number of blast furnaces are generally mounted next to the other blowers in operation, and are in the waiting position, ready to start so as to ensure the continuity of the blower. production of cast iron, even when detecting a pressure and / or air flow on a blower lower than a pre-determined value, below which it is necessary to replace this blower by one of the blowers waiting.
- one or more high capacity oxygen production typically cryogenic separation of air producing an oxygen of industrial purity, that is to say generally greater than 80% vol. preferably greater than 90% by volume, more preferably greater than 95% by volume, and sometimes of purity greater than 99% by volume, as disclosed by FR 2,857,028 .
- the increase in oxygen requirements at a smelter production site may occur, either in the case of increasing the smelting production in existing blast furnaces, or by adding one or more new blast furnaces. at the site, either by increasing the specific oxygen consumption in each blast furnace as a result, for example, of the addition of more fuel such as coal, natural gas, fuel oil, coke oven gas, plastics, etc ... (This addition is usually done at the level of the nozzles).
- This increase can result from the use of oxygen for another technical purpose, such as for example the air enrichment dedicated to the preheating of the stoves.
- the increase in oxygen requirements can lead to the construction of a new oxygen production unit, be it a cryogenic air separation unit, or by so-called VPSA processes.
- the method according to the invention makes it possible to respond to this problem thus posed.
- each blast furnace being powered by at least one of at least one of the n + 1 compressors available, at least one of the compressors which do not feed a blast furnace (hereinafter referred to as the second compressor) is used.
- the second compressor for supplying the air separation unit while, as soon as one of the compressors (hereinafter referred to as the first compressor) feeding a blast furnace produces an air flow rate lower than a predetermined flow rate D min , said first compressor is disconnected from said blast furnace, and the second compressor is connected to said blast furnace and preferably disconnected from the air separation unit.
- the flow rate D min typically corresponds to the minimum flow required for the blast furnace to which it is connected to function properly.
- blowers or compressors are used, when the other blowers (first compressors) are in normal operating condition and normally supply their respective blast furnace, to feed the separation unit with compressed air.
- air gases generally with a small additional compressor so as to increase the pressure of the air supplied to the air gas separation unit to a value of at least about 5x10 5 kPa and / or to supplement the volume of air supplied to the separation unit
- the first compressor having a problem is stopped and replace it by the compressor charged in the meantime to supply compressed air to the air separation unit, this unit being, during this time, put in waiting period, until a (other) second compressor become available (after repair of the first compressor) to supply compressed air to the air separation unit.
- a complementary compressor, dedicated to the air gas separation unit is provided so as to provide at least a portion of the compressed air necessary for this unit and / or the necessary overpressure.
- a compressor is said to be “connected” or “connected” to a blast furnace or an air separation unit when said compressor supplies the blast furnace, respectively the gas separation unit. air in compressed air.
- a compressor is said to be “disconnected” from a blast furnace or air separation unit when it does not supply the blast furnace, respectively the gas separation unit. air in compressed air.
- the characteristics of one or more blowers initially designed to work in operating ranges adapted to the specific pressure and flow requirements for the blast furnace can be adapted to the specific pressure and flow requirements for the blast furnace production unit. 'oxygen.
- Compressed air at a pressure in all cases greater than 2 bar absolute, produced by one of the blowers initially dedicated to a blast furnace, may be sent to the oxygen production unit or the blast furnace.
- the air of this additional blower may then be sent back to the blast furnace, the step of the oxygen production unit being stopped or adapted to a degraded step, compatible with the desired blast furnace step.
- a piping system may be provided for sending compressed air to one or other of the destinations (blast furnace or air separation unit).
- a control system will be used to optimize the adaptation, while the range of operation of the fan or blowers initially in the waiting position will be studied to allow flexibility of adaptation to different possible situations.
- the operation of the unit for separating gases from the air and producing oxygen may be totally stopped if the need for smelting by the blast furnaces requires it and is chosen by the operator as a priority.
- the unit for separating the gases from the air produces oxygen with a purity higher than 90% vol. (Also called impure oxygen) and preferably at a purity higher than 95% by volume of oxygen.
- a complementary compressor dedicated to the air gas separation unit to provide a portion of the air required for the air separation unit (if a large amount of air is necessary, too important for the capacity of a blower).
- this additional compressor can be used to operate the separation unit when the blower (second compressor) will be recovered by a blast furnace. This additional compressor can also be used as a replacement blower in case of two simultaneous failures, in which case the separation unit will be stopped).
- the oxygen produced by the air-gas separation unit may be intended in part for the blast furnaces or partly for other facilities generally present on site such as converters. Thus, some of the oxygen produced by the gas separation unit the air is used in at least one of the converters present at the integration site.
- the air gas separation unit has two modes of operation, a so-called regular operating mode and a so-called degraded operation mode.
- the air separation unit operates in a regular operating mode when it is supplied with air by the second compressor, and in degraded operating mode when the second compressor is connected to a blast furnace, that is, during the waiting period of the air separation unit.
- the unit for separating the gases from the air produces oxygen of purity greater than 90% vol. in regular operation mode and purity less than or equal to 90% in degraded operation mode.
- the air gas separation unit produces oxygen of purity greater than 95% vol. in regular operation mode and less than or equal to 95% in degraded operation mode.
- the air gas separation unit may also generate a first oxygen flow rate in a regular operating mode and a second oxygen flow rate lower than the first flow rate in degraded operation mode.
- the unit for separating the gases from the air can supply oxygen and in particular supply oxygen to the compressed air lines connected to the blast furnace, even during the waiting period.
- the separation unit comprises ducts (18, 19) and valves (7, 8, 13) making it possible to connect the second compressor (16) to at least one of the blast furnace air supply ducts (5, 6) or to the gas separation unit in the air (20), either to both.
- the blast furnaces respectively 1 and 2 are respectively connected to the compressors 3 and 4 via the compressed air supply lines 5 and 6.
- the compressors 3 and 4 are the blowers normally used to feed respectively their blast furnaces.
- This additional compressor 16 is connected by the supply line 19 and the valve 13 to the air separation unit 20, on the one hand, and by the line 18 to the valves 7 and 8, themselves connected respectively to the supply lines 5 and 6.
- the air gas separation unit 20 is connected respectively by the supply lines 21 and 22 to the valves 14 and 15 which respectively supply the lines 6 and 5.
- the replacement compressor 16 supplies via the valve 13 in the open position, the unit for separating the gases from the air which itself delivers its oxygen through the valves respectively 14 and 15 to the lines of blast furnace 6 and 5 so as to enrich this wind with the desired amount of oxygen.
- the valve 13 which was open is then closed or partially closed in the line 19, the detectors 9 and / or 11 simultaneously controlling the opening of the valves 7 and / or 8 (normally closed during the "normal" operating period) so as to be able to supply compressed air to the lines 5 and / or 6 through these valves 7 and 8.
- valves 14 and 15 will be either completely closed (preferential mode) or partially closed if the air separation unit 20 can continue to operate. degraded mode.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Power Engineering (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Manufacture Of Iron (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Blast Furnaces (AREA)
- Separation Of Gases By Adsorption (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Processing Of Stones Or Stones Resemblance Materials (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL07731629T PL1994185T3 (pl) | 2006-03-03 | 2007-02-15 | Sposób i instalacja łączenia wielkiego pieca i jednostki oddzielania gazu powietrznego |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0650762A FR2898134B1 (fr) | 2006-03-03 | 2006-03-03 | Procede d'integration d'un haut-fourneau et d'une unite de separation de gaz de l'air |
PCT/FR2007/050804 WO2007099246A2 (fr) | 2006-03-03 | 2007-02-15 | Procede d'integration d'un haut-fourneau et d'une unite de separation de gaz de l'air |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1994185A2 EP1994185A2 (fr) | 2008-11-26 |
EP1994185B1 true EP1994185B1 (fr) | 2009-12-09 |
Family
ID=37229482
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07731629A Active EP1994185B1 (fr) | 2006-03-03 | 2007-02-15 | PROCEDE ET INSTALLATION POUR l'INTEGRATION D'UN HAUT-FOURNEAU ET D'UNE UNITE DE SEPARATION DE GAZ DE L'AIR |
Country Status (18)
Country | Link |
---|---|
US (2) | US20100230872A1 (pt) |
EP (1) | EP1994185B1 (pt) |
JP (1) | JP2009528448A (pt) |
KR (1) | KR101344102B1 (pt) |
CN (1) | CN101448960B (pt) |
AT (1) | ATE451480T1 (pt) |
AU (1) | AU2007220388B8 (pt) |
BR (1) | BRPI0702906B1 (pt) |
CA (1) | CA2644535C (pt) |
DE (1) | DE602007003698D1 (pt) |
EA (1) | EA013661B1 (pt) |
FR (1) | FR2898134B1 (pt) |
MX (1) | MX2008011089A (pt) |
MY (1) | MY156426A (pt) |
PL (1) | PL1994185T3 (pt) |
UA (1) | UA91589C2 (pt) |
WO (1) | WO2007099246A2 (pt) |
ZA (1) | ZA200807151B (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2969175B1 (fr) | 2010-12-21 | 2013-01-04 | Air Liquide | Procede d'operation d'une installation de haut fourneau avec recyclage de gaz de gueulard |
AT510565B1 (de) * | 2011-06-21 | 2012-05-15 | Siemens Vai Metals Tech Gmbh | Vorrichtung zur regelung von prozessgasen in einer anlage zur herstellung von direkt reduzierten metallerzen |
CN103194553B (zh) * | 2013-04-07 | 2014-11-05 | 昆明理工大学 | 一种基于最小二乘支持向量机的高炉氧气使用量控制方法 |
JP6341148B2 (ja) * | 2015-07-06 | 2018-06-13 | Jfeスチール株式会社 | 圧縮空気の回収装置および圧縮空気の運用方法 |
HUE057873T2 (hu) | 2017-07-03 | 2022-06-28 | Air Liquide | Eljárás vas- vagy acélmû mûködtetésére |
EP3734206B1 (en) * | 2017-12-26 | 2024-02-07 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | System and method for supplying backup product in air separation device |
Family Cites Families (22)
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US3143412A (en) * | 1960-11-28 | 1964-08-04 | Dravo Corp | Method of enriching the oxygen content of air supplied to blast furnaces |
JPS5547313A (en) * | 1978-09-27 | 1980-04-03 | Nippon Kokan Kk <Nkk> | Manufacturing and supplying apparatus for oxygen gas |
JPS59212676A (ja) * | 1983-05-17 | 1984-12-01 | 株式会社神戸製鋼所 | 空気分離装置における減量運転方法 |
JPS61139609A (ja) * | 1984-12-13 | 1986-06-26 | Kawasaki Steel Corp | 工業炉の酸素富化方法 |
JPS63166916A (ja) * | 1986-12-27 | 1988-07-11 | Nkk Corp | 酸素高炉ガスの利用方法 |
FR2677667A1 (fr) | 1991-06-12 | 1992-12-18 | Grenier Maurice | Procede d'alimentation d'un haut-fourneau en air enrichi en oxygene, et installation de reduction de minerai de fer correspondante. |
FR2680114B1 (fr) * | 1991-08-07 | 1994-08-05 | Lair Liquide | Procede et installation de distillation d'air, et application a l'alimentation en gaz d'une acierie. |
GB9208647D0 (en) * | 1992-04-22 | 1992-06-10 | Boc Group Plc | Air separation |
JP3496233B2 (ja) * | 1993-04-26 | 2004-02-09 | Jfeスチール株式会社 | 高炉酸素富化送風の酸素混合装置 |
FR2712383B1 (fr) * | 1993-11-12 | 1995-12-22 | Air Liquide | Installation combinée d'une unité de production de métal et d'une unité de séparation de l'air. |
EP0793069A1 (en) * | 1996-03-01 | 1997-09-03 | Air Products And Chemicals, Inc. | Dual purity oxygen generator with reboiler compressor |
GB9609099D0 (en) * | 1996-05-01 | 1996-07-03 | Boc Group Plc | Oxygen steelmaking |
FR2753638B1 (fr) * | 1996-09-25 | 1998-10-30 | Procede pour l'alimentation d'une unite consommatrice d'un gaz | |
US5855648A (en) * | 1997-06-05 | 1999-01-05 | Praxair Technology, Inc. | Solid electrolyte system for use with furnaces |
FR2765889B1 (fr) * | 1997-07-08 | 1999-08-13 | Air Liquide | Procede et installation d'alimentation d'un haut fourneau |
FR2774308B1 (fr) | 1998-02-05 | 2000-03-03 | Air Liquide | Procede et installation combines de production d'air comprime et d'au moins un gaz de l'air |
JP2001131616A (ja) * | 1999-11-11 | 2001-05-15 | Nkk Corp | 高炉の操業方法及び焼結炉の操業方法 |
US6745573B2 (en) * | 2001-03-23 | 2004-06-08 | American Air Liquide, Inc. | Integrated air separation and power generation process |
JP4699643B2 (ja) * | 2001-06-26 | 2011-06-15 | 大陽日酸株式会社 | 空気液化分離方法及び装置 |
US6568207B1 (en) * | 2002-01-18 | 2003-05-27 | L'air Liquide-Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Integrated process and installation for the separation of air fed by compressed air from several compressors |
FR2866900B1 (fr) * | 2004-02-27 | 2006-05-26 | Air Liquide | Procede de renovation d'une installation combinee d'un haut fourneau et d'une unite de separation de gaz de l'air |
FR2857028A1 (fr) * | 2004-09-09 | 2005-01-07 | Air Liquide | Procede de renovation d'un haut-fourneau |
-
2006
- 2006-03-03 FR FR0650762A patent/FR2898134B1/fr not_active Expired - Fee Related
-
2007
- 2007-02-15 CN CN2007800074893A patent/CN101448960B/zh active Active
- 2007-02-15 PL PL07731629T patent/PL1994185T3/pl unknown
- 2007-02-15 WO PCT/FR2007/050804 patent/WO2007099246A2/fr active Application Filing
- 2007-02-15 MY MYPI20083270A patent/MY156426A/en unknown
- 2007-02-15 US US12/281,172 patent/US20100230872A1/en not_active Abandoned
- 2007-02-15 MX MX2008011089A patent/MX2008011089A/es active IP Right Grant
- 2007-02-15 AU AU2007220388A patent/AU2007220388B8/en not_active Ceased
- 2007-02-15 UA UAA200810847A patent/UA91589C2/ru unknown
- 2007-02-15 DE DE602007003698T patent/DE602007003698D1/de active Active
- 2007-02-15 AT AT07731629T patent/ATE451480T1/de active
- 2007-02-15 CA CA2644535A patent/CA2644535C/fr active Active
- 2007-02-15 JP JP2008556825A patent/JP2009528448A/ja active Pending
- 2007-02-15 BR BRPI0702906-3A patent/BRPI0702906B1/pt active IP Right Grant
- 2007-02-15 EP EP07731629A patent/EP1994185B1/fr active Active
- 2007-02-15 EA EA200870311A patent/EA013661B1/ru not_active IP Right Cessation
-
2008
- 2008-08-19 ZA ZA200807151A patent/ZA200807151B/xx unknown
- 2008-09-02 KR KR1020087021461A patent/KR101344102B1/ko active IP Right Grant
-
2012
- 2012-07-19 US US13/553,740 patent/US8702837B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
BRPI0702906A2 (pt) | 2011-03-22 |
US20120280436A1 (en) | 2012-11-08 |
CN101448960B (zh) | 2011-05-11 |
US20100230872A1 (en) | 2010-09-16 |
EA200870311A1 (ru) | 2009-02-27 |
AU2007220388B8 (en) | 2011-01-20 |
CA2644535C (fr) | 2014-06-03 |
CN101448960A (zh) | 2009-06-03 |
WO2007099246A3 (fr) | 2009-01-29 |
UA91589C2 (ru) | 2010-08-10 |
PL1994185T3 (pl) | 2010-05-31 |
AU2007220388A1 (en) | 2007-09-07 |
CA2644535A1 (fr) | 2007-09-07 |
JP2009528448A (ja) | 2009-08-06 |
WO2007099246A2 (fr) | 2007-09-07 |
FR2898134A1 (fr) | 2007-09-07 |
MX2008011089A (es) | 2008-09-05 |
MY156426A (en) | 2016-02-26 |
AU2007220388B2 (en) | 2010-09-16 |
ZA200807151B (en) | 2009-06-24 |
US8702837B2 (en) | 2014-04-22 |
EA013661B1 (ru) | 2010-06-30 |
ATE451480T1 (de) | 2009-12-15 |
KR101344102B1 (ko) | 2013-12-20 |
BRPI0702906B1 (pt) | 2014-06-10 |
KR20080106418A (ko) | 2008-12-05 |
FR2898134B1 (fr) | 2008-04-11 |
EP1994185A2 (fr) | 2008-11-26 |
DE602007003698D1 (de) | 2010-01-21 |
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