EP1929230B1 - Heat exchanger - Google Patents

Heat exchanger Download PDF

Info

Publication number
EP1929230B1
EP1929230B1 EP06805897A EP06805897A EP1929230B1 EP 1929230 B1 EP1929230 B1 EP 1929230B1 EP 06805897 A EP06805897 A EP 06805897A EP 06805897 A EP06805897 A EP 06805897A EP 1929230 B1 EP1929230 B1 EP 1929230B1
Authority
EP
European Patent Office
Prior art keywords
section
cooling
heat exchanger
pipe
coupling element
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP06805897A
Other languages
German (de)
French (fr)
Other versions
EP1929230A1 (en
Inventor
Giuseppe Belmonte
Gennaro Calabritto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eni SpA
Original Assignee
Eni SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eni SpA filed Critical Eni SpA
Publication of EP1929230A1 publication Critical patent/EP1929230A1/en
Application granted granted Critical
Publication of EP1929230B1 publication Critical patent/EP1929230B1/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/86Other features combined with waste-heat boilers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • F28D7/0083Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids with units having particular arrangement relative to a supplementary heat exchange medium, e.g. with interleaved units or with adjacent units arranged in common flow of supplementary heat exchange medium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/02Header boxes; End plates
    • F28F9/0229Double end plates; Single end plates with hollow spaces
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F9/00Casings; Header boxes; Auxiliary supports for elements; Auxiliary members within casings
    • F28F9/26Arrangements for connecting different sections of heat-exchange elements, e.g. of radiators
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1884Heat exchange between at least two process streams with one stream being synthesis gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861Heat exchange between at least two process streams
    • C10J2300/1892Heat exchange between at least two process streams with one stream being water/steam
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0075Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for syngas or cracked gas cooling systems
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/04Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being spirally coiled
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/10Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
    • F28D7/106Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically consisting of two coaxial conduits or modules of two coaxial conduits

Definitions

  • the present invention relates to a heat exchanger.
  • the present invention relates to a heat exchanger for the rapid cooling of high temperature gas.
  • the present invention relates to a heat exchanger for the cooling of synthesis gas (syngas) coming from the catalytic partial oxidation of light hydrocarbons, for example methane, known as Catalytic Partial Oxidation (CPO).
  • synthesis gas syngas
  • CPO Catalytic Partial Oxidation
  • the rapid cooling of syngas at the outlet of the reaction unit is a necessity not to be neglected, as if this gas is maintained at those temperatures, even for short periods of time, it can give undesired by-products, such as alcohols or olefins (substantially ethylene and propylene) or even regenerate the starting methane.
  • Systems for rapidly cooling a gas which is at a high temperature are mentioned in literature, for example in the patents US 2,896,927 and US 4,377,132 or in "Syngas Cooler Systems for Gasification Plants", an ALSTOM brochure.
  • Some methods and relevant equipment include the direct cooling of gas by means of water (quenching). This solution however has the drawback of having to separate the cooled syngas from the aqueous vapour formed.
  • the object of the present invention relates to a device for the effective and rapid indirect cooling of syngas in applications in which the thermal recovery of the sensible heat of the gas is not required, for engineering simplicity or for economical reasons. For example in the production of hydrogen in medium- small-scale systems.
  • the Applicants have therefore found a heat exchanger, particularly suitable for the rapid cooling of gases which are at a temperature higher than 500°C, for example between 750 and 1100°C, and which allows to avoid any contact between the hot gas and the cooling liquid, normally water.
  • the object of the present invention therefore relates to a heat exchanger for the rapid cooling of a gas at high temperature, leaving a reaction unit/device, which comprises a coupling element to the reaction unit/device, a gas cooling and transportation pipe and a covering shell, in which:
  • the coupling element is axially crossed by the pass-through duct, connected to the reaction device, for example a CPO reactor for the production of syngas at a temperature ranging from 500 to 1100°C.
  • the external pipe which covers the first section of the transportation pipe of the hot gas is connected, at one end, to one or more specific feeding ducts of the cooling liquid, which pass through the coupling element.
  • the coupling element moreover, is independently cooled by means of a duct which feeds the cooling liquid in correspondence with its axis. Said fluid is discharged from the element, after following a spiral path from the inside outwards, by means of an opening connected to the side surface of the element itself.
  • the cooling fluid circulating inside the coupling element (for independent cooling) can be discharged inside the volume contained in the shell of the exchanger.
  • the other end of the second pipe which covers the first section, is free and ends with the curved section, substantially in a semicircle, so that the cooling liquid can debouch freely, but in the opposite direction, into the closed space of the shell, after flowing in the jacket between the two pipes.
  • baffles orthogonal to the axis, which also act as a support for both sections of the gas transportation pipe.
  • the second section of the transportation and cooling pipe is substantially continuous to the first one, without interruption, and develops in a spiral.
  • the spirals preferably envelop, without touching it, the first section of the covered pipe. It is possible however for the spirals to develop downstream of the first section.
  • the other end of the transportation pipe i.e. the end of the spiral section, is connected to an opening present on the shell for the discharge of the cooled gas outside the heat exchanger, object of the present invention.
  • the shell has a substantially cylindrical form with the diameter of the base substantially identical to that of the coupling element and larger than the diameter of the spirals.
  • the shell includes in its inner space the pipe system of the first and second section.
  • the space of the shell is filled with the cooling fluid, which is discharged by the exchanger through a proper discharge opening.
  • the circulating liquid destined for the cooling of the coupling element, also converges into the shell space.
  • the total liquid is discharged from the exchanger, object of the present invention, through the proper opening situated on the shell.
  • the pipe system of the first and second section is completely immersed in the cooling liquid.
  • the heat exchanger object of the present invention, comprises the coupling element A, the pipe system for the gas transportation and cooling B and the shell C.
  • the coupling element A also includes the ducts 1 and 2 for the feeding of the cooling fluid (water), which converge into the coaxial duct 7, and the cooling duct 4, for the independent cooling of the coupling element, which feeds the water to the center of the spiral 4', from which it exits through 5.
  • the cooling fluid water
  • the gas transportation and cooling pipe system B comprises the first pipe section 6, the coaxial pipe which jackets it 7 and the second section of the spiral pipe 8.
  • the first section of the pipe 6 includes, in turn, the first end 3, coinciding with the axial pass-through duct of the element A, and the second curvilinear end 3'.
  • the coaxial pipe 7 jackets the first section starting from the end 3 until the curved end 3'. At this end (3') the coaxial pipe is not closed, to allow the water to be discharged inside the shell, as will be described further on.
  • the shell C includes the discharge opening 9 of the cooled gas, the discharge opening 10 of the water and the supporting baffles 11 of the two sections of the gas transportation pipe.
  • the hot gas 12 leaving the reaction unit is introduced into the heat exchanger by means of the pass-through duct 3 of the coupling element A.
  • the gas flows into the first section 6 of the cooling and transportation pipe B and subsequently into the second section 8, to be then discharged at a low temperature through the discharge opening of the gas 9.
  • the gas flows through the first section 6, it undergoes a first rapid cooling by means of the water, fed through 1 and 2, which circulates inside the annular hollow space between the pipes 6 and 7, up to the end 3'.
  • the water flows freely in the closed space of the shell, filling it, it further cools the gas flowing through the section 8 of the cooling pipe and is discharged from the opening 10.
  • the latter is cooled by means of the specific system consisting of the duct 4, which feeds water to the system 4' developping in a spiral, and of the discharge duct 5.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Power Steering Mechanism (AREA)
  • Compression-Type Refrigeration Machines With Reversible Cycles (AREA)

Abstract

Heat exchanger for cooling a high temperature gas leaving a reaction unit/device, comprising a coupling element to the reaction unit/device (A), a gas transportation and cooling pipe (B) and a covering shell (C).

Description

  • The present invention relates to a heat exchanger.
  • More specifically, the present invention relates to a heat exchanger for the rapid cooling of high temperature gas.
  • Even more specifically, the present invention relates to a heat exchanger for the cooling of synthesis gas (syngas) coming from the catalytic partial oxidation of light hydrocarbons, for example methane, known as Catalytic Partial Oxidation (CPO).
  • It is known that the reparation of syngas, a gaseous blend containing H2 and CO in various proportions, can be effected by the catalytic partial oxidation of natural gas, methane or gaseous/liquid hydrocarbon mixtures, from refinery or petrochemical facilities, in fixed bed tubular reactors which can operate, depending on the catalyst used, at a pressure ranging from 1 to 150 atm and temperatures higher than 500°C, which, in some cases, can reach and exceed 1,000°C.
  • The rapid cooling of syngas at the outlet of the reaction unit is a necessity not to be neglected, as if this gas is maintained at those temperatures, even for short periods of time, it can give undesired by-products, such as alcohols or olefins (substantially ethylene and propylene) or even regenerate the starting methane. Systems for rapidly cooling a gas which is at a high temperature, are mentioned in literature, for example in the patents US 2,896,927 and US 4,377,132 or in "Syngas Cooler Systems for Gasification Plants", an ALSTOM brochure. Some methods and relevant equipment include the direct cooling of gas by means of water (quenching). This solution however has the drawback of having to separate the cooled syngas from the aqueous vapour formed.
  • Other industrial systems consist of equipment for indirect cooling, which allow the recovery of heat contained in syngas, for the production of high pressure steam, see eg. US 3,788,281 .
  • The object of the present invention relates to a device for the effective and rapid indirect cooling of syngas in applications in which the thermal recovery of the sensible heat of the gas is not required, for engineering simplicity or for economical reasons. For example in the production of hydrogen in medium- small-scale systems.
  • The Applicants have therefore found a heat exchanger, particularly suitable for the rapid cooling of gases which are at a temperature higher than 500°C, for example between 750 and 1100°C, and which allows to avoid any contact between the hot gas and the cooling liquid, normally water.
  • The object of the present invention therefore relates to a heat exchanger for the rapid cooling of a gas at high temperature, leaving a reaction unit/device, which comprises a coupling element to the reaction unit/device, a gas cooling and transportation pipe and a covering shell, in which:
    1. a) the coupling element, substantially cylindrical, is situated between the reaction unit and the shell of the exchanger, it is internally cooled by means of a cooling fluid, normally water, and is axially connected, by means of a pass-through duct, to the feeding line of the hot gas coming from the reaction unit;
    2. b) the transportation and cooling pipe of the hot gas is fixed to the base of the coupling element, connected to the reaction unit, at the pass-through duct, said hot gas transportation and cooling pipe consisting of two sections:
      • the first section, substantially linear, is inserted in a coaxial position in a second pipe having a larger diameter which covers it, so as to form an annular hollow space in which the cooling fluid, generally water, flows, an end of said first section forming the pass-through duct of the coupling element;
      • the second section, fixed in a continuous manner to the first section, at the other end, substantially curved in a semicircle, spirally envelopes, without touching it, at least part of said first jacketed section;
    3. c) the covering shell is substantially cylindrical, closed at one end and open at the other end, it is connected to said coupling element, and comprises at least the openings for discharging the cooling liquid and the cooled gas.
  • According to the present invention, the coupling element is axially crossed by the pass-through duct, connected to the reaction device, for example a CPO reactor for the production of syngas at a temperature ranging from 500 to 1100°C.
  • The external pipe which covers the first section of the transportation pipe of the hot gas is connected, at one end, to one or more specific feeding ducts of the cooling liquid, which pass through the coupling element. The coupling element, moreover, is independently cooled by means of a duct which feeds the cooling liquid in correspondence with its axis. Said fluid is discharged from the element, after following a spiral path from the inside outwards, by means of an opening connected to the side surface of the element itself.
  • In an alternative embodiment of the present invention, the cooling fluid circulating inside the coupling element (for independent cooling) can be discharged inside the volume contained in the shell of the exchanger.
  • The other end of the second pipe, which covers the first section, is free and ends with the curved section, substantially in a semicircle, so that the cooling liquid can debouch freely, but in the opposite direction, into the closed space of the shell, after flowing in the jacket between the two pipes.
  • The path of the liquid inside the shell volume is guided by baffles, orthogonal to the axis, which also act as a support for both sections of the gas transportation pipe.
  • The second section of the transportation and cooling pipe is substantially continuous to the first one, without interruption, and develops in a spiral. In order to save space, the spirals preferably envelop, without touching it, the first section of the covered pipe. It is possible however for the spirals to develop downstream of the first section.
  • The other end of the transportation pipe, i.e. the end of the spiral section, is connected to an opening present on the shell for the discharge of the cooled gas outside the heat exchanger, object of the present invention.
  • The shell has a substantially cylindrical form with the diameter of the base substantially identical to that of the coupling element and larger than the diameter of the spirals. In this way, the shell includes in its inner space the pipe system of the first and second section. The space of the shell is filled with the cooling fluid, which is discharged by the exchanger through a proper discharge opening. In an alternative embodiment of the present invention, the circulating liquid, destined for the cooling of the coupling element, also converges into the shell space. The total liquid is discharged from the exchanger, object of the present invention, through the proper opening situated on the shell. In any case, whether operating with the first or second alternative embodiment, the pipe system of the first and second section is completely immersed in the cooling liquid.
  • The heat exchanger object of the present invention can be better understood by referring to the schemes of the enclosed figures which represent an illustrative but nonlimiting, embodiment, and wherein:
    • Figure 1 represents a longitudinal, flat sectional view of the overall exchanger;
    • Figure 2 represents a front flat view of the scheme ofFigure 1, produced according to the section ZZ.
  • With reference to the figures, the heat exchanger, object of the present invention, comprises the coupling element A, the pipe system for the gas transportation and cooling B and the shell C.
  • The coupling element A also includes the ducts 1 and 2 for the feeding of the cooling fluid (water), which converge into the coaxial duct 7, and the cooling duct 4, for the independent cooling of the coupling element, which feeds the water to the center of the spiral 4', from which it exits through 5.
  • The gas transportation and cooling pipe system B comprises the first pipe section 6, the coaxial pipe which jackets it 7 and the second section of the spiral pipe 8. The first section of the pipe 6 includes, in turn, the first end 3, coinciding with the axial pass-through duct of the element A, and the second curvilinear end 3'. The coaxial pipe 7 jackets the first section starting from the end 3 until the curved end 3'. At this end (3') the coaxial pipe is not closed, to allow the water to be discharged inside the shell, as will be described further on.
  • The shell C includes the discharge opening 9 of the cooled gas, the discharge opening 10 of the water and the supporting baffles 11 of the two sections of the gas transportation pipe.
  • The operation of the heat exchanger, object of the present invention, will appear evident on the basis of the drawings and what is described above. In particular, the hot gas 12, leaving the reaction unit (not shown), is introduced into the heat exchanger by means of the pass-through duct 3 of the coupling element A. The gas flows into the first section 6 of the cooling and transportation pipe B and subsequently into the second section 8, to be then discharged at a low temperature through the discharge opening of the gas 9. As the gas flows through the first section 6, it undergoes a first rapid cooling by means of the water, fed through 1 and 2, which circulates inside the annular hollow space between the pipes 6 and 7, up to the end 3'. Here, the water flows freely in the closed space of the shell, filling it, it further cools the gas flowing through the section 8 of the cooling pipe and is discharged from the opening 10.
  • During operation, in order to prevent overheating of the coupling element, the latter is cooled by means of the specific system consisting of the duct 4, which feeds water to the system 4' developping in a spiral, and of the discharge duct 5.

Claims (8)

  1. A heat exchanger for the rapid cooling of a gas at high temperature, leaving a reaction unit/device, which comprises a coupling element to the reaction unit/device (A), a gas cooling and transportation pipe (B) and a covering shell (C), in which:
    a) the coupling element (A), substantially cylindrical, is situated between the reaction unit and the exchanger shell (C), it is internally cooled by means of a cooling fluid, normally water, and is axially connected, by means of a pass-through duct (3), to the feeding line of the hot gas (12) coming from the reaction unit;
    b) the hot gas transportation and cooling pipe (B) is fixed to the base of the coupling element (A), connected to the reaction unit, at the pass-through duct (3), said hot gas transportation and cooling pipe consisting of two sections:
    - the first section (6), substantially linear, is inserted in a coaxial position into a second pipe (7) having a larger diameter which jackets it, so as to form an annular hollow space in which the cooling fluid, normally water, flows, an end (3) of said first section forming the pass-through duct of the coupling element;
    - the second section (8), fixed in a continuous manner to the first section (6), at the other end (3'), substantially curved in a semicircle, spirally envelopes, without touching it, at least part of said first covered section (6);
    c) the covering shell (C) is substantially cylindrical, closed at one end and open at the other end, connected to said coupling element and comprises at least the openings for discharging the cooling liquid (10) and the cooled gas (9).
  2. The heat exchanger according to claim 1, wherein the external pipe (7) which jackets the first section (6) of the transportation tube (B) of the hot gas is connected, at one end, to one or more specific feeding ducts of the cooling liquid (1, 2), which cross the coupling element (A).
  3. The heat exchanger according to claim 1 or 2, wherein the coupling element (A) comprises an independent duct (4) which feeds the cooling liquid in correspondence with its axis, said cooling fluid being discharged by means of an opening (5) connected to the side surface of the element itself, after following a spiral path (4') from the inside outwards.
  4. The heat exchanger according to any of the previous claims, wherein the other end of the second pipe (7) which covers the first section (6) is free and ends with a curvilinear section, so that the cooling liquid can debouch freely, in the opposite direction, into the hollow space of the shell, after flowing in the jacket between the two pipes.
  5. The heat exchanger according to any of the previous claims, wherein the second section (8) of the cooling and transportation pipe is essentially continuous to the first section, without interruptions, and develops in a spiral.
  6. The heat exchanger according to any of the previous claims, wherein the other end of the transportation pipe, i.e. the end of the spiral section, is connected to an opening (9) on the cover for discharging the cooled gas outside the heat exchanger.
  7. The heat exchanger according to any,of the previous claims, wherein the shell (C) has a substantially cylindrical form, with the base diameter substantially identical to that of the coupling element and larger than the diameter of the spirals.
  8. The heat exchanger according to any of the previous claims, wherein the shell (C) contains in its inner space the pipe system of the first and second section, said space being filled by the cooling liquid which is discharged from the exchanger through the proper discharge opening (10).
EP06805897A 2005-09-30 2006-09-26 Heat exchanger Active EP1929230B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT001834A ITMI20051834A1 (en) 2005-09-30 2005-09-30 HEAT EXCHANGER
PCT/EP2006/009376 WO2007039199A1 (en) 2005-09-30 2006-09-26 Heat exchanger

Publications (2)

Publication Number Publication Date
EP1929230A1 EP1929230A1 (en) 2008-06-11
EP1929230B1 true EP1929230B1 (en) 2010-12-01

Family

ID=36097257

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06805897A Active EP1929230B1 (en) 2005-09-30 2006-09-26 Heat exchanger

Country Status (15)

Country Link
US (1) US20080202734A1 (en)
EP (1) EP1929230B1 (en)
CN (1) CN101278165B (en)
AP (1) AP2747A (en)
AT (1) ATE490445T1 (en)
BR (1) BRPI0616773B1 (en)
CA (1) CA2622847C (en)
DE (1) DE602006018633D1 (en)
DK (1) DK1929230T3 (en)
EA (1) EA011836B1 (en)
IT (1) ITMI20051834A1 (en)
MA (1) MA30001B1 (en)
NO (1) NO339343B1 (en)
UA (1) UA90736C2 (en)
WO (1) WO2007039199A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016029093A1 (en) * 2014-08-22 2016-02-25 Simple Approach Systems, Inc. Apparatus, system, and method for converting varied source industry waste into energy
CN106679467B (en) * 2017-02-28 2019-04-05 郑州大学 Shell-and-tube heat exchanger with external bobbin carriage
CN106855367B (en) * 2017-02-28 2024-01-26 郑州大学 Shell-and-tube heat exchanger with distributed inlets and outlets
US11662127B2 (en) * 2020-09-04 2023-05-30 Intellihot, Inc. Electric heating and cooling system

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2578059A (en) * 1945-05-29 1951-12-11 Graham Mfg Co Inc Heat interchanger
DE1918171B2 (en) * 1969-04-10 1972-01-05 GAS COOLER FOR COOLING NITROGEN GAS OR SYNTHESIS GAS
CH508806A (en) * 1969-11-19 1971-06-15 Escher Wyss Ag Process for dissipating waste heat from the working fluid of a thermal power plant and thermal power plant for carrying out the method
US3921708A (en) * 1970-10-07 1975-11-25 Ygnis Sa Heat exchanger and method of operation thereof
NL7204070A (en) * 1972-03-27 1973-10-01
CA1055479A (en) * 1975-08-27 1979-05-29 James W. Barr (Jr.) Descaling of heat exchanger
US4256176A (en) * 1978-04-10 1981-03-17 Aerco International, Inc. Heat-reclaiming system
US4377132A (en) * 1981-02-12 1983-03-22 Texaco Development Corp. Synthesis gas cooler and waste heat boiler
FR2514879B1 (en) * 1981-10-16 1986-07-18 Creusot Loire HEAT EXCHANGER FOR DUST-FILLED GAS
DE3709339C1 (en) * 1987-03-21 1988-07-21 Steinmueller Gmbh L & C Gas-liquid heat exchanger
DE3931685A1 (en) * 1989-09-22 1991-04-04 Borsig Babcock Ag HEAT EXCHANGER FOR COOLING REACTION GAS
US5379832A (en) * 1992-02-18 1995-01-10 Aqua Systems, Inc. Shell and coil heat exchanger
US5487423A (en) * 1993-02-16 1996-01-30 Piscine Service Anjou Sa Heat exchanger
DE4407594A1 (en) * 1994-03-08 1995-09-14 Borsig Babcock Ag Heat exchanger for cooling hot reaction gas
TW445366B (en) * 1998-05-15 2001-07-11 Noboru Maruyama Assembly body of heat exchange coils
US6293335B1 (en) * 1999-06-24 2001-09-25 Aquacal, Inc. Method and apparatus for optimizing heat transfer in a tube and shell heat exchanger
CN2445276Y (en) * 2000-10-18 2001-08-29 郑宝佳 Totally-enclosed heat storage type spiral heat exchanger
CN2511932Y (en) * 2001-12-18 2002-09-18 大连保税区科利德化工科技开发有限公司 Purified condenser for high purity ammonia

Also Published As

Publication number Publication date
BRPI0616773A2 (en) 2013-01-01
ATE490445T1 (en) 2010-12-15
UA90736C2 (en) 2010-05-25
ITMI20051834A1 (en) 2007-04-01
US20080202734A1 (en) 2008-08-28
EA011836B1 (en) 2009-06-30
WO2007039199A1 (en) 2007-04-12
DK1929230T3 (en) 2011-03-21
CA2622847C (en) 2014-07-08
CA2622847A1 (en) 2007-04-12
MA30001B1 (en) 2008-12-01
NO339343B1 (en) 2016-11-28
CN101278165A (en) 2008-10-01
EP1929230A1 (en) 2008-06-11
DE602006018633D1 (en) 2011-01-13
NO20081431L (en) 2008-06-13
AP2008004435A0 (en) 2008-04-30
AP2747A (en) 2013-09-30
EA200800649A1 (en) 2008-10-30
BRPI0616773B1 (en) 2018-10-23
CN101278165B (en) 2010-05-19

Similar Documents

Publication Publication Date Title
RU2234975C2 (en) Radial-flow through reactor and method for processing of liquid reactant flow
KR101826589B1 (en) Multi-Stage Multi-Tube Shell-and-Tube Reactor
EP1929230B1 (en) Heat exchanger
US7500999B2 (en) Catalytic reactor
US20020085970A1 (en) Shell and tube reactor
US20020000066A1 (en) Reactor for producing hydrogen from hydrocarbon fuels
NZ215292A (en) The process and apparatus for producing the gas containing hydrogen and carbon oxides by steam reforming of hydrocarbons
BR0207108B1 (en) heat exchanger reactor and chiller assembly.
RU2331628C2 (en) Method of catalytic oxidation in vapour phase implemented in multiple-tubular reactor
JP5600460B2 (en) Hydrogen production apparatus and fuel cell system
JP2787773B2 (en) Apparatus and method suitable for producing hydrogen
EP3271062B1 (en) Boiling water reactor
WO2002053491A2 (en) Shell and tube reactor
EP1756506B1 (en) Apparatus for cooling a hot gas
KR20140043248A (en) Spiral heat exchanger for hydrodesulfurizer feedstock
JP7349604B2 (en) hydrogen generator
Astanovskii et al. Reactor for catalytic processes under optimal temperature conditions
JP5538025B2 (en) Hydrogen production apparatus and fuel cell system
KR20220093652A (en) Heat exchange system for effluent discharged from multiple devices
GB2161596A (en) Reactor for exothermic gas reactions
JP2013100294A (en) Process for production of propylene oxide

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20080312

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 602006018633

Country of ref document: DE

Date of ref document: 20110113

Kind code of ref document: P

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20101201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

LTIE Lt: invalidation of european patent or patent extension

Effective date: 20101201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110301

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110302

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110312

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110401

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110401

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20110902

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602006018633

Country of ref document: DE

Effective date: 20110902

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110930

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20110926

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110926

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110930

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110926

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110926

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101201

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230706

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20230925

Year of fee payment: 18

Ref country code: DK

Payment date: 20230927

Year of fee payment: 18

Ref country code: DE

Payment date: 20230927

Year of fee payment: 18