Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
  • D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
  • D21F11/14—Making cellulose wadding, filter or blotting paper
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B31—MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
  • B31F—MECHANICAL WORKING OR DEFORMATION OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
  • B31F1/00—Mechanical deformation without removing material, e.g. in combination with laminating
  • B31F1/12—Crêping
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
  • D21H27/002—Tissue paper; Absorbent paper
  • D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
  • D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness
  • D21H27/007—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness relating to absorbency, e.g. amount or rate of water absorption, optionally in combination with other parameters relating to physical or mechanical properties
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
  • D21H11/14—Secondary fibres
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
  • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
  • D21H21/18—Reinforcing agents
  • D21H21/20—Wet strength agents
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
  • D21H27/002—Tissue paper; Absorbent paper
  • D21H27/004—Tissue paper; Absorbent paper characterised by specific parameters
  • D21H27/005—Tissue paper; Absorbent paper characterised by specific parameters relating to physical or mechanical properties, e.g. tensile strength, stretch, softness

Definitions

• the present invention relates generally to wet-pressed absorbent sheet and more particularly to wet-pressed, fabric creped sheet peeled from a Yankee dryer.
• the sheet exhibits elevated absorbency and MD stretch as well as an MD bending length especially suitable for automatic towel dispensers.
• Fabric creping has been employed in connection with papermaking processes which include mechanical or compactive dewatering of the paper web as a means to influence product properties. See United States Patent Nos. 4,689,119 and 4,551,199 to Weldon; 4,849,054 and 4,834,838 to Klowak; and 6,287,426 to Edwards et al. Operation of fabric creping processes has been hampered by the difficulty of effectively transferring a web of high or intermediate consistency to a dryer. Note also United States Patent No. 6,350,349 to Hermans et al. which discloses wet transfer of a web from a rotating transfer surface to a fabric.
• Sheet Material Dispenser with Perforation Sensor and Method United States Patent No. 6,766,977 to Denen et al. which discloses a paper dispenser releasing individual sheets of paper in response to movement (once the dispenser detects movement, it releases paper and activates a perforation sensor to stop advancement of the roll of paper after a set number of rotations); Waste Minimizing Paper Dispenser, United States Patent No. 6,793, 170 to Denen et al.
• wet pressed/fabric creped towel with a unique combination of properties suitable for automatic dispensers can be produced without dry creping provided the wet-press manufacturing process is suitably controlled.
• the present invention thus provides economical feedstock for automatic dispensers which readily incorporates recycle fiber and which may be produced at higher line speeds and with lower energy costs than throughdried products.
• a manufacturing method for fabric-creped sheet which includes peeling, rather than creping the product from a Yankee dryer.
• the product has more MD stretch than uncreped throughdried products (discussed below) and more stiffness or MD bending length than dry-creped products for dispensing reliability.
• a method of making a fabric-creped absorbent cellulosic sheet with improved dispensing characteristics comprising: a) compactively dewatering a papermaking furnish to form a nascent web; b) applying the dewatered web to a translating transfer surface moving at a first speed; c) fabric-creping the web from the transfer surface at a consistency of from about 30 to about 60 percent utilizing a patterned creping fabric, the creping step occurring under pressure in a fabric creping nip defined between the transfer surface and the creping fabric wherein the fabric is traveling at a second speed slower than the speed of said transfer surface, the fabric pattern, nip parameters, velocity delta and web consistency being selected such that the web is creped from the transfer surface and transferred to the creping fabric; d) adhering the web to a drying cylinder with a resinous adhesive coating composition; e) drying the web on the drying cylinder; and f) peeling the web from the drying cylinder.
• the furnish, creping fabric and creping adhesive are selected and the velocity delta, nip parameters and web consistency, caliper and basis weight are controlled such that the MD bending length of the dried web is at least about 3.5 cm.
• the MD bending length of the dried web is from about 3.5 cm to about 5 cm. and more preferably the MD bending length of the dried web is from about 3.75 cm to about 4.5 cm.
• the process is suitably operated at a fabric crepe of from about 3.5% to about 30%; typically operated at a fabric crepe of from about 5% to about 15%.
• the dried web generally exhibits a WAR value of less than about 35 seconds; typically, the dried web exhibits a WAR value of less than about 30 or less than about 25 seconds such as a WAR value of from about 10 to about 20 seconds.
• the papermaking furnish typically comprises a wet strength resin as well as a dry strength resin.
• the papermaking furnish comprises a wet strength resin and as a dry strength resin carboxymethyl cellulose and/or polyacrylamide, with the proviso that the wet strength resin add-on rate is less than about 20 lbs per ton of papermaking fiber.
• a creping adhesive is also used.
• the resinous adhesive coating composition is employed at an add-on rate of less than about 40 mg/m of drier surface, such as less than about 35 mg/m 2 or less than about 25 mg/m 2 , or less than about 20 mg/m . Less than about 10 mg/m is readily achieved if so desired.
• the creping adhesive add-on rate is calculated by dividing the rate of application of adhesive (mg/min) by surface area of the drying cylinder passing under the spray applicator boom (m 2 /min).
• the resinous adhesive composition most preferably consists essentially of a polyvinyl alcohol resin and a polyamide-epichlorohydrin resin wherein the weight ratio of polyvinyl alcohol resin to polyamide-epichlorohydrin resin is from about 2 to about 4.
• Consisting essentially of it is meant that the adhesive composition contains less than 5% by weight modifier and more preferably less than about 2% by weight modifier.
• the furnish is predominantly SW pulp such as predominantly Douglas fir pulp.
• the furnish comprises recycle pulp.
• the papermaking fiber in the furnish may be at least 25%, 40% or 50% by weight Douglas Fir fiber and/or at least 25%, 40% or 50% by weight recycle fiber.
• a suitable composition includes, for example, pulp which is at least 25% by weight Douglas fir fiber and at least 25% by weight recycle fiber. Li some cases more than 50% recycle fiber may be used, such as up to 75% by weight fiber recycle fiber or 100% by weight fiber of recycle fiber.
• the process further comprises on-line calendering the web with a calender stack prior to winding the web on a roll, wherein the calender stack is synchronized with the reel prior to loading the calender stack.
• a calender loading of anywhere from 10-35 pli is suitable.
• the web is tensioned between the drying cylinder and the calender stack with a spreader bar or bow roll.
• the web also may be tensioned between the calender stack and the reel with an interposed spreader bar or roll.
• a method of making a fabric- creped absorbent cellulosic sheet with improved dispensing characteristics comprising: a) compactively dewatering a papermaking furnish to form a nascent web; b) applying the dewatered web to a translating transfer surface moving at a first speed; c) fabric-creping the web from the transfer surface at a consistency of from about 30 to about 60 percent utilizing a patterned creping fabric, the creping step occurring under pressure in a fabric creping nip defined between the transfer surface and the creping fabric wherein the fabric is traveling at a second speed slower than the speed of said transfer surface, the fabric pattern, nip parameters, velocity delta and web consistency being selected such that the web is creped from the transfer surface and transferred to the creping fabric; wherein the fabric crepe is from about 2% to about 15%; d) adhering the web to a drying cylinder with a resinous adhesive coating composition; e) drying the web on the drying cylinder; and f
• a method of making a fabric- creped absorbent cellulosic sheet with improved dispensing characteristics comprising: a) compactively dewatering a papermaking furnish to form a nascent web; b) applying the dewatered web to a translating transfer surface moving at a first speed; c) fabric-creping the web from the transfer surface at a consistency of from about 30 to about 60 percent utilizing a patterned creping fabric, the creping step occurring under pressure in a fabric creping nip defined between the transfer surface and the creping fabric wherein the fabric is traveling at a second speed slower than the speed of said transfer surface, the fabric pattern, nip parameters, velocity delta and web consistency being selected such that the web is creped from the transfer surface and transferred to the creping fabric; wherein the fabric crepe is from about 2 to about 15%; d) adhering the web to a drying cylinder with a resinous adhesive coating composition; e) drying the web on the drying cylinder; and
• Still another aspect of the invention is a method of making a fabric-creped absorbent cellulosic sheet with improved dispensing characteristics comprising: a) compactively dewatering a papermaking furnish to form a nascent web; b) applying the dewatered web to a translating transfer surface moving at a first speed; c) fabric-creping the web from the transfer surface at a consistency of from about 30 to about 60 percent utilizing a patterned creping fabric, the creping step occurring under pressure in a fabric creping nip defined between the transfer surface and the creping fabric wherein the fabric is traveling at a second speed slower than the speed of said transfer surface, the fabric pattern, nip parameters, velocity delta and web consistency being selected such that the web is creped from the transfer surface and transferred to the creping fabric; d) adhering the web to a drying cylinder with a resinous adhesive coating composition; e) drying the web on the drying cylinder; f) peeling the web from the drying cylinder; and g) stabilizing
• the process may also include stabilizing the web over an open draw utilizing at least one additional air foil or at least two additional air foils to stabilize the web.
• the web is formed having an apparently random distribution of fiber orientation and creped such that the fiber is redistributed on the creping fabric with a different distribution of fiber orientation corresponding to that of the creping fabric.
• the product has no crepe bars which are due to dry creping and the product is supplied to consumers from an automatic dispenser in the form of a single-ply towel. Because the sheet had not been dry-creped, it has very low dusting as will be seen in the examples which follow.
• the sheet of the invention contains from about 8-16 lbs/ton of PAE wet strength resin and from about 2-6 lbs per ton of carboxymethyl cellulose dry strength resin.
• 1 to 11 lbs. of polyacrylamide dry strength resin may be included. Less than about 17.5 lbs/ton of wet strength resin is preferred for higher absorbency.
• FIGS 1-5 are photomicrographs of TAD sheets suitable for automatic towel dispensers
• Figures 6-15 are photomicrographs of fabric-creped sheet of the invention suitable for automatic towel dispensers
• Figure 16 is a schematic diagram of a first papermachine suitable for practicing the process of the present invention.
• Figure 17 is a schematic diagram of a second papermachine suitable for producing the present invention.
• Figures 18 and 19 are schematic diagrams illustrating the use of air foils in connection with the present invention.
• Figures 20 and 21 are photomicrographs of uncreped TAD sheet
• Figures 22 and 23 are photomicrographs of fabric-creped, peeled sheet of the invention.
• Figures 24 and 25 are graphs comparing tensile properties of uncreped TAD sheet and the fabric creped, peeled sheet of the invention.
• test specimens are prepared under standard TAPPI conditions, that is, conditioned in an atmosphere of 23° ⁇ 1.0 0 C (73.4° ⁇ 1.8 0 F) at 50% relative humidity for at least about 2 hours.
• Basis weight refers to the weight of a 3000 square foot ream of product. Consistency refers to percent solids of a nascent web, for example, calculated on a bone dry basis. "Air dry” means including residual moisture, by convention up to about 10 percent moisture for pulp and up to about 6% for paper. A nascent web having 50 percent water and 50 percent bone dry pulp has a consistency of 50 percent.
• cellulosic cellulosic sheet
• papermaking fibers include virgin pulps or recycle (secondary) cellulosic fibers or fiber mixes comprising cellulosic fibers.
• Fibers suitable for making the webs of this invention include: nonwood fibers, such as cotton fibers or cotton derivatives, abaca, kenaf, sabai grass, flax, esparto grass, straw, jute hemp, bagasse, milkweed floss fibers, and pineapple leaf fibers; and wood fibers such as those obtained from deciduous and coniferous trees, including softwood fibers, such as northern and southern softwood kraft fibers; hardwood fibers, such as eucalyptus, maple, birch, aspen, or the like.
• Papermaking fibers can be liberated from their source material by any one of a number of chemical pulping processes familiar to one experienced in the art including sulfate, sulfite, polysulfide, soda pulping, etc.
• the pulp can be bleached if desired by chemical means including the use of chlorine, chlorine dioxide, oxygen, alkaline peroxide and so forth.
• the products of the present invention may comprise a blend of conventional fibers (whether derived from virgin pulp or recycle sources) and high coarseness lignin-rich tubular fibers, such as bleached chemical thermomechanical pulp (BCTMP).
• BCTMP bleached chemical thermomechanical pulp
• "Furnish” and like terminology refers to aqueous compositions including papermaking fibers, optionally wet strength resins, debonders and the like for making paper products.
• furnishes consist predominantly (more than 50% by weight of fiber) of softwood (SW) fiber such as Douglas fir.
• SW softwood
• SSWK Southern Softwood Kraft
• recycle fiber which is typically predominantly hardwood (HW) fiber is used.
• Recycle fiber is in many cases 80% hardwood fiber.
• compactively dewatering the web or furnish refers to mechanical dewatering by wet pressing on a dewatering felt, for example, in some embodiments by use of mechanical pressure applied continuously over the web surface as in a nip between a press roll and a press shoe wherein the web is in contact with a papermaking felt.
• the terminology "compactively dewatering" is used to distinguish processes wherein the initial dewatering of the web is carried out largely by thermal means as is the case, for example, in United States Patent No. 4,529,480 to Trokhan and United States Patent No. 5,607,551 to Farrington et al. noted above.
• Compactively dewatering a web thus refers, for example, to removing water from a nascent web having a consistency of less than 30 percent or so by application of pressure thereto and/or increasing the consistency of the web by about 15 percent or more by application of pressure thereto; that is, for example, increasing the consistency of the web from 30 percent to 45 percent.
• Creping fabric and like terminology refers to a fabric or belt which bears a pattern suitable for practicing the process of the present invention and preferably is permeable enough such that the web may be dried while it is held in the creping fabric, hi cases where the web is transferred to another fabric or surface (other than the creping fabric) for drying, the creping fabric may have lower permeability.
• "Fabric side” and like terminology refers to the side of the web which is in contact with the creping fabric.
• Dryer side or “Yankee side” is the side of the web in contact with the drying cylinder, typically opposite the fabric side of the web.
• Fpm refers to feet per minute.
• a “like” web produced by “like” means refers to a web made from substantially identical equipment in substantially the same way; that is with substantially the same overall crepe, fabric crepe, nip parameters and so forth.
• MD machine direction
• CD cross-machine direction
• Nip parameters include, without limitation, nip pressure, nip width, backing roll hardness, fabric approach angle, fabric takeaway angle, uniformity, nip penetration and velocity delta between surfaces of the nip.
• Nip width means the MD length over which the nip surfaces are in contact.
• On line and like terminology refers to a process step performed without removing the web from the papermachine in which the web is produced. A web is drawn or calendered on line when it is drawn or calendered without being severed prior to wind-up.
• a translating transfer surface refers to the surface from which the web is creped into the creping fabric.
• the translating transfer surface may be the surface of a rotating drum as described hereafter, or may be the surface of a continuous smooth moving belt or another moving fabric which may have surface texture and so forth.
• the translating transfer surface needs to support the web and facilitate the high solids creping as will be appreciated from the discussion which follows.
• suction is not required in a fabric creping step, so accordingly when we refer to fabric creping as being "under pressure" we are referring to loading of the receptor fabric against the transfer surface although suction assist can be employed at the expense of further complication of the system so long as the amount of suction is not sufficient to interfere with rearrangement or redistribution of the fiber.
• Calipers and or bulk reported herein may be measured at 8 or 16 sheet calipers as specified.
• the sheets are stacked and the caliper measurement taken about the central portion of the stack.
• the test samples are conditioned in an atmosphere of 23° ⁇ 1.0°C (73.4° ⁇ 1.8 0 F) at 50% relative humidity for at least about 2 hours and then measured with a Thwing- Albert Model 89-11- JR or Progage Electronic Thickness Tester with 2-in (50.8-mm) diameter anvils, 539 ⁇ 10 grams dead weight load, and 0.231 in./sec descent rate.
• each sheet of product to be tested must have the same number of plies as the product as sold.
• eight sheets are selected and stacked together.
• napkins are unfolded prior to stacking.
• each sheet to be tested must have the same number of plies as produced off the winder.
• basesheet testing off of the papermachine reel single plies must be used. Sheets are stacked together aligned in the MD. On custom embossed or printed product, try to avoid taking measurements in these areas if at all possible. Bulk may also be expressed in units of volume/weight by dividing caliper by basis weight.
• MD bending length (cm) is determined in accordance with ASTM test method D 1388-96, cantilever option. Reported bending lengths refer to MD bending lengths unless a CD bending length is expressly specified.
• the MD bending length test was performed with a Cantilever Bending Tester available from Research Dimensions, 1720 Oakridge Road, Neenah, Wisconsin, 54956 which is substantially the apparatus shown in the ASTM test method, item 6.
• the instrument is placed on a level stable surface, horizontal position being confirmed by a built in leveling bubble.
• the bend angle indicator is set at 41.5° below the level of the sample table. This is accomplished by setting the knife edge appropriately.
• the sample is cut with a one inch JD strip cutter available from Thwing- Albert Instrument
• Samples are cut 1 inch x 8 inch machine direction specimens. Samples are conditioned at 23 °C ⁇ 1°C (73.4 0 F ⁇ 1.8°F) at 50% relative humidity for at least two hours. For machine direction specimens the longer dimension is parallel to the machine direction. The specimens should be flat, free of wrinkles, bends or tears. The Yankee side of the specimens is also labeled. The specimen is placed on the horizontal platform of the tester aligning the edge of the specimen with the right hand edge. The movable slide is placed on the specimen, being careful not to change its initial position. The right edge of the sample and the movable slide should be set at the right edge of the horizontal platform.
• the movable slide is displaced to the right in a smooth, slow manner at approximately 5 inch/minute until the specimen touches the knife edge.
• the overhang length is recorded to the nearest 0.1 cm. This is done by reading the left edge of the movable slide.
• Three specimens are preferably run with the Yankee side up and three specimens are preferably run with the Yankee side down on the horizontal platform.
• the MD bending length is reported as the average overhang length in centimeters divided by two to account for bending axis location. Bending length refers to MD bending length unless specified otherwise.
• the simple absorbency tester is a particularly useful apparatus for measuring the hydrophilicity and absorbency properties of a sample of tissue, napkins, or towel.
• a sample of tissue, napkins, or towel 2.0 inches in diameter is mounted between a top flat plastic cover and a bottom grooved sample plate.
• the tissue, napkin, or towel sample disc is held in place by a 1/8 inch wide circumference flange area.
• the sample is not compressed by the holder.
• De-ionized water at 73 °F is introduced to the sample at the center of the bottom sample plate through a 1 mm. diameter conduit. This water is at a hydrostatic head of minus 5 mm.
• Flow is initiated by a pulse introduced at the start of the measurement by the instrument mechanism. Water is thus imbibed by the tissue, napkin, or towel sample from this central entrance point radially outward by capillary action. When the rate of water imbibation decreases below 0.005 gm water per 5 seconds, the test is terminated. The amount of water removed from the reservoir and absorbed by the sample is weighed and reported as grams of water per square meter of sample or grams of water per gram of sheet. In practice, an M/K Systems Inc. Gravimetric Absorbency Testing System is used. This is a commercial system obtainable from M/K Systems Inc., 12 Garden Street, Danvers, Mass., 01923.
• WAC or water absorbent capacity is actually determined by the instrument itself.
• WAC is defined as the point where the weight versus time graph has a "zero" slope, i.e., the sample has stopped absorbing.
• the termination criteria for a test are expressed in maximum change in water weight absorbed over a fixed time period. This is basically an estimate of zero slope on the weight versus time graph.
• the program uses a change of 0.005g over a 5 second time interval as termination criteria; unless "Slow SAT" is specified in which case the cut off criteria is 1 mg in 20 seconds.
• Water absorbency rate or WAR is measured in seconds and is the time it takes for a sample to absorb a 0.1 gram droplet of water disposed on its surface by way of an automated syringe.
• the test specimens are preferably conditioned at 23° C ⁇ 1° C (73.4 ⁇ 1.8 0 F) at 50 % relative humidity.
• 4 3x3 inch test specimens are prepared. Each specimen is placed in a sample holder such that a high intensity lamp is directed toward the specimen. 0.1 ml of water is deposited on the specimen surface and a stop watch is started. When the water is absorbed, as indicated by lack of further reflection of light from the drop, the stopwatch is stopped and the time recorded to the nearest 0.1 seconds. The procedure is repeated for each specimen and the results averaged for the sample.
• WAR is measured in accordance with TAPPI method T-432 cm-99.
• Dry tensile strengths (MD and CD), stretch, ratios thereof, modulus, break modulus, stress and strain are measured with a standard Instron test device or other suitable elongation tensile tester which may be configured in various ways, typically using 3 or 1 inch wide strips of tissue or towel, conditioned in an atmosphere of 23° ⁇ 1°C (73.4° ⁇ I 0 F) at 50% relative humidity for 2 hours. The tensile test is run at a crosshead speed of 2 in/min. Tensile strength is sometimes referred to simply as "tensile”.
• GM Break Modulus is expressed in grams/3 inches/ %strain. % strain is dimensionless and units need not be specified. Tensile values refer to break values unless otherwise indicated. Tensile strengths are reported in g/3" at break. GM Break Modulus is thus:
• Tensile ratios are simply ratios of the values determined by way of the foregoing methods. Unless otherwise specified, a tensile property is a dry sheet property.
• the wet tensile of the tissue of the present invention is measured using a three-inch wide strip of tissue that is folded into a loop, clamped in a special fixture termed a Finch Cup, then immersed in a water.
• the Finch Cup which is available from the Thwing- Albert Instrument Company of Philadelphia, Pa., is mounted onto a tensile tester equipped with a 2.0 pound load cell with the flange of the Finch Cup clamped by the tester's lower jaw and the ends of tissue loop clamped into the upper jaw of the tensile tester.
• the sample is immersed in water that has been adjusted to a pH of 7.0 ⁇ 0.1 and the tensile is tested after a 5 second immersion time. Values are divided by two, as appropriate, to account for the loop.
• Fabric crepe ratio is an expression of the speed differential between the creping fabric and the forming wire and typically calculated as the ratio of the web speed immediately before fabric creping and the web speed immediately following fabric creping, the forming wire and transfer surface being typically, but not necessarily, operated at the same speed:
• Fabric crepe can also be expressed as a percentage calculated as:
• a web creped from a transfer cylinder with a surface speed of 750 fpm to a fabric with a velocity of 500 fpm has a fabric crepe ratio of 1.5 and a fabric crepe of 50%.
• the total crepe ratio is calculated as the ratio of the forming wire speed to the reel speed and a % total crepe is:
• Total Crepe % [Total Crepe Ratio - l]x 100%
• a process with a forming wire speed of 2000 fpm and a reel speed of 1000 fpm has a line or total crepe ratio of 2 and a total crepe of 100%.
• PLI or pli means pounds force per linear inch.
• Pusey and Jones (P&J) hardness is measured in accordance with ASTM D 531, and refers to the indentation number (standard specimen and conditions).
• Velocity delta means a difference in linear speed
• a creping adhesive is optionally used to secure the web to the transfer cylinder and is used to adhere the fabric creped web to the Yankee before it is peeled as is hereinafter described.
• the adhesive is preferably a hygroscopic, re-wettable, substantially non- crosslinking adhesive.
• preferred adhesives are those which include poly( vinyl alcohol) of the general class described in United States Patent No. 4,528,316 to Soerens et al.
• Other suitable adhesives are disclosed in co-pending United States Provisional Patent Application Serial No. 60/372,255, filed April 12, 2002, entitled “Improved Creping Adhesive Modifier and Process for Producing Paper Products" (Attorney Docket No. 2394).
• the disclosures of the '316 patent and the'255 application are incorporated herein by reference.
• Suitable adhesives are optionally provided with modifiers and so forth. It is preferred to use crosslinker and/or modifier sparingly or not at all in the adhesive.
• Creping adhesives may comprise a thermosetting or non-thermosetting resin, a film- forming semi-crystalline polymer and optionally an inorganic cross-linking agent as well as modifiers.
• the creping adhesive of the present invention may also include other components, including, but not limited to, hydrocarbons oils, surfactants, or plasticizers.
• Creping modifiers which may be used in limited amounts include a quaternary ammonium complex comprising at least one non-cyclic amide.
• the quaternary ammonium complex may also contain one or several nitrogen atoms (or other atoms) that are capable of reacting with alkylating or quaternizing agents.
• These alkylating or quaternizing agents may contain zero, one, two, three or four non-cyclic amide containing groups.
• An amide containing group is represented by the following formula structure:
• R 7 and Rg are non-cyclic molecular chains of organic or inorganic atoms.
• Preferred non-cyclic bis-amide quaternary ammonium complexes can be of the formula:
• R 1 and R 2 can be long chain non-cyclic saturated or unsaturated aliphatic groups
• R 3 and R 4 can be long chain non-cyclic saturated or unsaturated aliphatic groups, a halogen, a hydroxide, an alkoxylated fatty acid, an alkoxylated fatty alcohol, a polyethylene oxide group, or an organic alcohol group
• R 5 and R 6 can be long chain non-cyclic saturated or unsaturated aliphatic groups.
• the modifier is optionally present in the creping adhesive in an amount of from about 0.05% to about 25%, more preferably from about 0.25% to about 10%, and most preferably from about 0.5% to about 5% based on the total solids of the creping adhesive composition.
• Modifiers include those obtainable from Goldschmidt Corporation of Essen/Germany or Process Application Corporation based in Washington Crossing, PA.
• Appropriate creping modifiers from Goldschmidt Corporation include, but are not limited to, VARISOFT ® 222LM, VARISOFT ® 222, VARISOFT ® 110, VARISOFT ® 222LT, VARISOFT ® 110 DEG, and VARISOFT ® 238.
• Appropriate creping modifiers from Process Application Corporation include, but are not limited to, PALSOFT 580 FDA or PALSOFT 580C.
• creping modifiers for use in the present invention include, but are not limited to, those compounds as described in WO/01/85109, which is incorporated herein by reference in its entirety.
• Creping adhesives for use in connection with to the present invention may include any suitable thermosetting or non-thermosetting resin.
• Resins according to the present invention are preferably chosen from thermosetting and non-thermosetting polyamide resins or glyoxylated polyacrylamide resins.
• Polyamides for use in the present invention can be branched or unbranched, saturated or unsaturated.
• Polyamide resins for use in the present invention may include polyaminoamide- epichlorohydrin (PAE) resins of the same general type employed as wet strength resins.
• PAE resins are described, for example, in "Wet-Strength Resins and Their Applications," Ch. 2, H. Epsy entitled Alkaline-Curing Polymeric Amine-Epichlorohydrin Resins, which is incorporated herein by reference in its entirety.
• Preferred PAE resins for use according to the present invention include a water-soluble polymeric reaction product of an epihalohydrin, preferably epichlorohydrin, and a water-soluble polyamide having secondary amine groups derived from a polyalkylene polyamine and a saturated aliphatic dibasic carboxylic acid containing from about 3 to about 10 carbon atoms.
• non-thermosetting cationic polyamide resins can be found in United States Patent No. 5,338,807, issued to Espy et al. and incorporated herein by reference.
• the non-thermosetting resin may be synthesized by directly reacting the polyamides of a dicarboxylic acid and methyl bis(3-aminopropyl)amine in an aqueous solution, with epichlorohydrin.
• the carboxylic acids can include saturated and unsaturated dicarboxylic acids having from about 2 to 12 carbon atoms, including for example, oxalic, malonic, succinic, glutaric, adipic, pilemic, suberic, azelaic, sebacic, maleic, itaconic, phthalic, and terephthalic acids. Adipic and glutaric acids are preferred, with adipic acid being the most preferred.
• the esters of the aliphatic dicarboxylic acids and aromatic dicarboxylic acids, such as the phathalic acid, may be used, as well as combinations of such dicarboxylic acids or esters.
• the polyamide resin may be based on DETA (diethylene triamine) instead of a generalized polyamine.
• DETA diethylene triamine
• Two examples of structures of such a polyamide resin are given below. Structure 1 shows two types of end groups: a di-acid and a mono-acid based group:
• Structure 2 shows a polymer with one end-group based on a di-acid group and the other end- group based on a nitrogen group:
• the polyamide resin has a viscosity of from about 80 to about 800 centipoise and a total solids of from about 5% to about 40%.
• the polyamide resin is present in the creping adhesive according to the present invention in an amount of from about 0% to about 99.5%.
• the polyamide resin is present in the creping adhesive in an amount of from about 20% to about 80%.
• the polyamide resin is present in the creping adhesive in an amount of from about 40% to about 60% based on the total solids of the creping adhesive composition.
• Polyamide resins for use according to the present invention can be obtained from Ondeo-Nalco Corporation, based in Naperville, Illinois, and Hercules Corporation, based in Wilmington, Delaware.
• Creping adhesive resins for use according to the present invention from Ondeo-Nalco Corporation include, but are not limited to, CREPECCEL ® 675NT, CREPECCEL ® 675P and CREPECCEL ® 690HA.
• Appropriate creping adhesive resins available from Hercules Corporation include, but are not limited to, HERCULES 82-176, HERCULES 1145, Unisoft 805 and CREPETROL A-6115.
• Other polyamide resins for use according to the present invention include, for example, those described in United States Patent Nos. 5,961,782 and 6,133,405, both of which are incorporated herein by reference.
• the creping adhesive also includes a film-forming semi-crystalline polymer.
• FiIm- forming semi-crystalline polymers for use in the present invention can be selected from, for example, heinicellulose, carboxymethyl cellulose, and most preferably includes polyvinyl alcohol (PVOH).
• Polyvinyl alcohols used in the creping adhesive can have an average molecular weight of about 13,000 to about 124,000 daltons. According to one embodiment, the polyvinyl alcohols have a degree of hydrolysis of from about 80% to about 99.9%. According to another embodiment, polyvinyl alcohols have a degree of hydrolysis of from about 85% to about 95%. hi yet another embodiment, polyvinyl alcohols have a degrees of hydrolysis of from about 86% to about 90%.
• polyvinyl alcohols preferably have a viscosity, measured at 20 degree centigrade using a 4% aqueous solution, of from about 2 to about 100 centipoise. According to another embodiment, polyvinyl alcohols have a viscosity of from about 10 to about 70 centipoise. In yet another embodiment, polyvinyl alcohols have a viscosity of from about 20 to about 50 centipoise.
• the polyvinyl alcohol is present in the creping adhesive in an amount of from about 10% to 90% or 20% to about 80% or more, hi some embodiments, the polyvinyl alcohol is present in the creping adhesive in an amount of from about 40% to about 60%, by weight, based on the total solids of the creping adhesive composition.
• Polyvinyl alcohols for use according to the present invention include those obtainable from Monsanto Chemical Co. and Celanese Chemical. Appropriate polyvinyl alcohols from Monsanto Chemical Co. include Gelvatols, including, but not limited to, GELVATOL 1-90, GELVATOL 3-60, GELVATOL 20-30, GELVATOL 1-30, GELVATOL 20-90, and GELVATOL 20-60. Regarding the Gelvatols, the first number indicates the percentage residual polyvinyl acetate and the next series of digits when multiplied by 1,000 gives the number corresponding to the average molecular weight.
• the creping adhesive may also comprise one or more inorganic cross-linking salts or agents.
• Such additives are believed best used sparingly or not at all in connection with the present invention.
• a non-exhaustive list of multivalent metal ions includes calcium, barium, titanium, chromium, manganese, iron, cobalt, nickel, zinc, molybdenium, tin, antimony, niobium, vanadium, tungsten, selenium, and zirconium. Mixtures of metal ions can be used.
• Preferred anions include acetate, formate, hydroxide, carbonate, chloride, bromide, iodide, sulfate, tartrate, and phosphate.
• zirconium salt for use according to one embodiment of the present invention can be chosen from one or more zirconium compounds having a valence of plus four, such as ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate, and sodium zirconium tartrate.
• Appropriate zirconium compounds include, for example, those described in United States Patent No. 6,207,011, which is incorporated herein by reference.
• the inorganic cross-linking salt can be present in the creping adhesive in an amount of from about 0% to about 30%. In another embodiment, the inorganic cross-linking agent can be present in the creping adhesive in an amount of from about 1% to about 20%. In yet another embodiment, the inorganic cross-linking salt can be present in the creping adhesive in an amount of from about 1% to about 10% by weight based on the total solids of the creping adhesive composition.
• Zirconium compounds for use according to the present invention include those obtainable from EKA Chemicals Co. (previously Hopton Industries) and Magnesium Elektron, Inc. Appropriate commercial zirconium compounds from EKA Chemicals Co. are AZCOTE 5800M and KZCOTE 5000 and from Magnesium Elektron, Inc. are AZC or KZC.
• the creping adhesive can include any other components, including, but not limited to, organic cross-linkers, hydrocarbon oils, surfactants, amphoterics, humectants, plasticizers, or other surface treatment agents.
• organic cross-linkers includes glyoxal, maleic anhydride, bismaleimide, bis acrylamide, and epihalohydrin.
• the organic cross-linkers can be cyclic or non-cyclic compounds.
• Plastizers for use in the present invention can include propylene glycol, diethylene glycol, Methylene glycol, dipropylene glycol, and glycerol.
• the creping adhesive may be applied as a single composition or may be applied in its component parts. More particularly, the polyamide resin may be applied separately from the polyvinyl alcohol (PVOH) and the modifier.
• PVOH polyvinyl alcohol
• a normal coating package is applied at a total coating rate (add on as calculated above) of 54 mg/m 2 with 32 mg/m 2 of PVOH (Celvol 523)/ 11.3 mg/m 2 of PAE (Hercules 1145) and 10.5 mg/m 2 of modifier (Hercules 4609VF).
• a preferred coating for the peeling process of the invention is applied at a rate of 20 mg/m 2 with 14.52 mg/m 2 of PVOH (Celvol 523)/ 5.10 mg/m 2 of PAE (Hercules 1145) and 0.38 mg/m 2 of modifier (Hercules 4609VF).
• an absorbent paper web is made by dispersing papermaking fibers into aqueous furnish (slurry) and depositing the aqueous furnish onto the forming wire of a papermaking machine.
• Any suitable forming scheme might be used.
• an extensive but non-exhaustive list in addition to Fourdrinier formers includes a crescent former, a C-wrap twin wire former, an S-wrap twin wire former, or a suction breast roll former.
• the forming fabric can be any suitable foraminous member including single layer fabrics, double layer fabrics, triple layer fabrics, photopolymer fabrics, and the like.
• Non-exhaustive background art in the forming fabric area includes United States Patent Nos.
• Foam-forming of the aqueous furnish on a forming wire or fabric may be employed as a means for controlling the permeability or void volume of the sheet upon fabric-creping. Foam-forming techniques are disclosed in United States Patent No. 4,543,156 and Canadian Patent No. 2,053,505, the disclosures of which are incorporated herein by reference.
• the foamed fiber furnish is made up from an aqueous slurry of fibers mixed with a foamed liquid carrier just prior to its introduction to the headbox.
• the pulp slurry supplied to the system has a consistency in the range of from about 0.5 to about 7 weight percent fibers, preferably in the range of from about 2.5 to about 4.5 weight percent.
• the pulp slurry is added to a foamed liquid comprising water, air and surfactant containing 50 to 80 percent air by volume forming a foamed fiber furnish having a consistency in the range of from about 0.1 to about 3 weight percent fiber by simple mixing from natural turbulence and mixing inherent in the process elements.
• the addition of the pulp as a low consistency slurry results in excess foamed liquid recovered from the forming wires.
• the excess foamed liquid is discharged from the system and may be used elsewhere or treated for recovery of surfactant therefrom.
• the furnish may contain chemical additives to alter the physical properties of the paper produced. These chemistries are well understood by the skilled artisan and may be used in any known combination. Such additives may be surface modifiers, softeners, debonders, strength aids, latexes, opacifiers, optical brighteners, dyes, pigments, sizing agents, barrier chemicals, retention aids, insolubilizers, organic or inorganic crosslinkers, or combinations thereof; said chemicals optionally comprising polyols, starches, PPG esters, PEG esters, phospholipids, surfactants, polyamines, HMCP (Hydrophobically Modified Cationic Polymers), HMAP (Hydrophobically Modified Anionic Polymers) or the like.
• additives may be surface modifiers, softeners, debonders, strength aids, latexes, opacifiers, optical brighteners, dyes, pigments, sizing agents, barrier chemicals, retention aids, insolubilizers, organic
• the pulp can be mixed with strength adjusting agents such as wet strength agents, dry strength agents and debonders/softeners and so forth. Suitable wet strength agents are known to the skilled artisan.
• strength adjusting agents such as wet strength agents, dry strength agents and debonders/softeners and so forth.
• Suitable wet strength agents are known to the skilled artisan.
• a comprehensive but non-exhaustive list of useful strength aids include urea- formaldehyde resins, melamine formaldehyde resins, glyoxylated polyacrylamide resins, polyamide-epichlorohydrin resins and the like.
• Thermosetting polyacrylamides are produced by reacting acrylamide with diallyl dimethyl ammonium chloride (DADMAC) to produce a cationic polyacrylamide copolymer which is ultimately reacted with glyoxal to produce a cationic cross-linking wet strength resin, glyoxylated polyacrylamide.
• DMDMAC diallyl dimethyl ammonium chloride
• a cationic polyacrylamide copolymer which is ultimately reacted with glyoxal to produce a cationic cross-linking wet strength resin, glyoxylated polyacrylamide.
• acrylamide/-DADMAC/glyoxal can be used to produce cross-linking resins, which are useful as wet strength agents.
• dialdehydes can be substituted for glyoxal to produce thermosetting wet strength characteristics.
• polyamide-epichlorohydrin wet strength resins an example of which is sold under the trade names Kymene 557LX and Kymene 557H by Hercules Incorporated of Wilmington, Delaware and Amres® from Georgia-Pacific Resins, Inc. These resins and the process for making the resins are described in United States Patent No. 3,700,623 and United States Patent No. 3,772,076 each of which is incorporated herein by reference in its entirety.
• Suitable temporary wet strength agents may likewise be included, particularly in special applications where disposable towel with permanent wet strength resin is to be avoided.
• a comprehensive but non-exhaustive list of useful temporary wet strength agents includes aliphatic and aromatic aldehydes including glyoxal, malonic dialdehyde, succinic dialdehyde, glutaraldehyde and dialdehyde starches, as well as substituted or reacted starches, disaccharides, polysaccharides, chitosan, or other reacted polymeric reaction products of monomers or polymers having aldehyde groups, and optionally, nitrogen groups.
• Representative nitrogen containing polymers which can suitably be reacted with the aldehyde containing monomers or polymers, includes vinyl-amides, acrylamides and related nitrogen containing polymers. These polymers impart a positive charge to the aldehyde containing reaction product, hi addition, other commercially available temporary wet strength agents such as PAREZ 745, manufactured by Bayer, can be used, along with those disclosed, for example, in United States Patent No. 4,605,702.
• the temporary wet strength resin may be any one of a variety of water-soluble organic polymers comprising aldehydic units and cationic units used to increase dry and wet tensile strength of a paper product. Such resins are described in United States Patent Nos. 4,675,394; 5,240,562; 5,138,002; 5,085,736; 4,981,557; 5,008,344; 4,603,176; 4,983,748; 4,866,151; 4,804,769 and 5,217,576. Modified starches sold under the trademarks CO-BOND® 1000 and CO-BOND® 1000 Plus, by National Starch and Chemical Company of Bridgewater, NJ. may be used.
• the cationic aldehydic water soluble polymer can be prepared by preheating an aqueous slurry of approximately 5% solids maintained at a temperature of approximately 240 degrees Fahrenheit and a pH of about 2.7 for approximately 3.5 minutes. Finally, the slurry can be quenched and diluted by adding water to produce a mixture of approximately 1.0% solids at less than about 130 degrees Fahrenheit.
• Chemical Company are sold under the trademarks CO-BOND® 1600 and CO-BOND® 2300. These starches are supplied, as aqueous colloidal dispersions and do not require preheating prior to use.
• Temporary wet strength agents such as glyoxylated polyacrylamide can be used.
• Temporary wet strength agents such glyoxylated polyacrylamide resins are produced by reacting acrylamide with diallyl dimethyl ammonium chloride (DADMAC) to produce a cationic polyacrylamide copolymer which is ultimately reacted with glyoxal to produce a cationic cross-linking temporary or semi- permanent wet strength resin, glyoxylated polyacrylamide.
• DADMAC diallyl dimethyl ammonium chloride
• Resins of this type are commercially available under the trade name of PAREZ 631NC, by Bayer Industries. Different mole ratios of acrylamide/DADMAC/glyoxal can be used to produce cross-linking resins, which are useful as wet strength agents. Furthermore, other dialdehydes can be substituted for glyoxal to produce wet strength characteristics.
• Suitable dry strength agents include starch, guar gum, polyacrylamides, carboxymethyl cellulose and the like. Of particular utility is carboxymethyl cellulose, an example of which is sold under the trade name Hercules CMC, by Hercules Incorporated of Wilmington, Delaware.
• the pulp may contain from about 0 to about 15 lb/ton of dry strength agent.
• the pulp may contain from about 1 to about 5 lbs/ton of dry strength agent.
• Suitable debonders are likewise known to the skilled artisan. Debonders or softeners may also be incorporated into the pulp or sprayed upon the web after its formation.
• the present invention may also be used with softener materials including but not limited to the class of amido amine salts derived from partially acid neutralized amines. Such materials are disclosed in United States Patent No. 4,720,383. Evans, Chemistry and Industi ⁇ , 5 July 1969, pp. 893-903; Egan, J.Am. Oil Chemist's Soc. Vol. 55 (1978), pp. 118-121; and Trivedi et al., J.Am.Oil Chemist's Soc, June 1981, pp. 754-756, incorporated by reference in their entirety, indicate that softeners are often available commercially only as complex mixtures rather than as single compounds. While the following discussion will focus on the predominant species, it should be understood that commercially available mixtures would generally be used in practice.
• Quasoft 202- JR is a suitable softener material, which may be derived by alkylating a condensation product of oleic acid and diethylenetriamine. Synthesis conditions using a deficiency of alleviation agent (e.g., diethyl sulfate) and only one alkylating step, followed by pH adjustment to protonate the non-ethylated species, result in a mixture consisting of cationic ethylated and cationic non-ethylated species. A minor proportion (e.g., about 10%) of the resulting amido amine cyclize to imidazoline compounds.
• alleviation agent e.g., diethyl sulfate
• the compositions as a whole are pH-sensitive. Therefore, in the practice of the present invention with this class of chemicals, the pH in the head box should be approximately 6 to 8, more preferably 6 to 7 and most preferably 6.5 to 7.
• Quaternary ammonium compounds such as dialkyl dimethyl quaternary ammonium salts are also suitable particularly when the alkyl groups contain from about 10 to 24 carbon atoms. These compounds have the advantage of being relatively insensitive to pH.
• Biodegradable softeners can be utilized. Representative biodegradable cationic softeners/debonders are disclosed in United States Patent Nos. 5,312,522; 5,415,737;
• the compounds are biodegradable diesters of quaternary ammonia compounds, quaternized amine-esters, and biodegradable vegetable oil based esters functional with quaternary ammonium chloride and diester dierucyldimethyl ammonium chloride and are representative biodegradable softeners.
• a particularly preferred debonder composition includes a quaternary amine component as well as a nonionic surfactant.
• the nascent web is typically dewatered on a papermaking felt.
• Any suitable felt may be used.
• felts can have double-layer base weaves, triple-layer base weaves, or laminated base weaves.
• Preferred felts are those having the laminated base weave design.
• a wet-press-felt which may be particularly useful with the present invention is Vector 3 made by Voith Fabric. Background art in the press felt area includes United States Patent Nos. 5,657,797; 5,368,696; 4,973,512; 5,023,132; 5,225,269; 5,182,164; 5,372,876; and 5,618,612.
• a differential pressing felt as is disclosed in United States Patent No. 4,533,437 to Curran et al. may likewise be utilized.
• Suitable creping or textured fabrics include single layer or multi-layer, or composite preferably open meshed structures. Fabric construction per se_ is of less importance than the topography of the creping surface in the creping nip as discussed in more detail below. Long MD knuckles with slightly lowered CD knuckles are greatly preferred for some products.
• Fabrics may have at least one of the following characteristics: (1) on the side of the creping fabric that is in contact with the wet web (the "top” side), the number of machine direction (MD) strands per inch (mesh) is from 10 to 200 and the number of cross-direction (CD) strands per inch (count) is also from 10 to 200; (2) the strand diameter is typically smaller than 0.050 inch; (3) on the top side, the distance between the highest point of the MD knuckles and the highest point on the CD knuckles is from about 0.001 to about 0.02 or 0.03 inch; (4) in between these two levels there can be knuckles formed either by MD or CD strands that give the topography a three dimensional hill/valley appearance which is imparted to the sheet; (5) the fabric may be oriented in any suitable way so as to achieve the desired effect on processing and on properties in the product; the long warp knuckles may be on the top side to increase MD ridges in the product, or the long shute k
• One preferred fabric is a WO 13 Albany International multilayer fabric.
• Such fabrics are formed from monofilament polymeric fibers having diameters typically ranging from about 0.25 mm to about 1 mm.
• Such fabrics are formed from monofilament polymeric fibers having diameters typically ranging from about 10 mm to about 100 mm.
• This fabric may be used to produce an absorbent cellulosic sheet having variable local basis weight comprising a papermaking fiber reticulum provided with (i) a plurality of cross-machine direction (CD) extending, fiber-enriched pileated regions of relatively high local basis weight interconnected by (ii) a plurality of elongated densified regions of compressed papermaking fibers, the elongated densified regions having relatively low local basis weight and are generally oriented along the machine direction (MD) of the sheet.
• the elongated densified regions are further characterized by an MD/CD aspect ratio of at least 1.5.
• the MD/CD aspect ratios of the densified regions are greater than 2 or greater than 3; generally between about 2 and 10.
• the fiber-enriched, pileated regions have fiber orientation bias along the CD of the sheet and the densified regions of relatively low basis weight extend in the machine direction and also have fiber orientation bias along the CD of the sheet.
• This product is further described in copending application United States Application Serial No. 60/808,863, entitled “Fabric Creped Absorbent Sheet with Variable Local Basis Weight", filed May 26, 2006, (Attorney Docket No. 20179; GP-06- 11), the disclosure of which is incorporated herein in its entirety by reference.
• the creping fabric may be of the class described in United States Patent No. 5,607,551 to Farrington et al, Cols. 7-8 thereof, as well as the fabrics described in United States Patent No. 4,239,065 to Trokhan and United States Patent No. 3,974,025 to Ayers.
• Such fabrics may have about 20 to about 60 meshes per inch and are formed from monofilament polymeric fibers having diameters typically ranging from about 0.008 to about 0.025 inches. Both warp and weft monofilaments may, but need not necessarily be of the same diameter.
• the filaments are so woven and complimentarily serpentinely configured in at least the Z-direction (the thickness of the fabric) to provide a first grouping or array of coplanar top-surface-plane crossovers of both sets of filaments; and a predetermined second grouping or array of sub-top-surface crossovers.
• the arrays are interspersed so that portions of the top-surface-plane crossovers define an array of wicker-basket-like cavities in the top surface of the fabric, which cavities are disposed in staggered relation in both the machine direction (MD) and the cross-machine direction (CD), and so that each cavity spans at least one sub-top-surface crossover.
• the cavities are discretely perimetrically enclosed in the plan view by a picket-like-lineament comprising portions of a plurality of the top-surface plane crossovers.
• the loop of fabric may comprise heat set monofilaments of thermoplastic material; the top surfaces of the coplanar top-surface-plane crossovers may be monoplanar flat surfaces.
• Specific embodiments of the invention include satin weaves as well as hybrid weaves of three or greater sheds, and mesh counts of from about 10 X 10 to about 120 X 120 filaments per inch (4 X 4 to about 47 X 47 per centimeter). Although the preferred range of mesh counts is from about 18 by 16 to about 55 by 48 filaments per inch (9 X 8 to about 22 X
• a dryer fabric may be used as the creping fabric if so desired. Suitable fabrics are described in United States Patent Nos. 5,449,026 (woven style) and 5,690,149 (stacked MD tape yarn style) to Lee as well as United States Patent No.
• the nascent web may be conditioned with suction boxes and a steam shroud until it reaches a solids content suitable for transferring to a dewatering felt.
• the nascent web may be transferred with suction assistance to the felt.
• suction assist is unnecessary as the nascent web is formed between the forming fabric and the felt.
• Figures 1 through 15 the fabric creped, peeled product of the present invention resembles uncreped throughdried sheet.
• Figures 1 through 5 photomicrographs of a through dried product; in this respect Figure 1 is a photomicrograph (10X) of the top side of the sheet; Figure 2 is a photomicrograph (10X) of the back side of the sheet; Figure 3 is a photomicrograph (25X) of the top side of the sheet; and Figure 4 is a photomicrograph (25X) of the back of the side of the through dried sheet.
• Figure 5 is a cross-sectional view (cut along the machine direction, 62.5X) which shows that the sheet is substantially without crepe bars inasmuch as this throughdried sheet has not been dry-creped.
• Figures 6 through 10 are photomicrographs of a fabric creped sheet which was creped at a 7% fabric crepe and peeled from a Yankee dryer.
• Figure 6 is a top side view (10X) of the sheet, while Figure 7 is a back side view (10X) of the sheet;
• Figure 8 is a top side view (25X) of the sheet while Figure 9 is a back side view (25X) of the sheet;
• Figure 10 is a cross sectional view along the machine direction of the sheet at a magnification of 62.5X.
• the sheet has a good distribution of fiber and that the sheet is substantially without crepe bars of the type which occur when a product is dry-creped from a Yankee cylinder. It is further noted with respect to Figures 6 through 10 that the back side of the sheet bears the pattern of the creping fabric used to produce the sheet. Thus, if so desired, the sheet may be made more or less "sided". Alternatively, the sheet may be calendered to reduce sidedness as noted above.
• Figures 11 through 15 show another fabric creped sheet prepared in accordance with the present invention wherein the sheet was creped with a 5% fabric crepe, thereafter applied to Yankee dryer with a PAE/polyvinyl alcohol adhesive and peeled therefrom.
• Figure 11 is a top side view of the sheet at a magnification of 10X
• Figure 12 is a photomicrograph of the back side of the sheet at a magnification of 10X
• Figure 13 is a view of the top side of the sheet at a magnification of 25X
• Figure 14 is a photomicrograph of the back side of the sheet at a magnification of 25X
• Figure 15 is a cross-sectional view, along the machine direction at a magnification of 62, 5X.
• the fabric creped sheet has a good distribution of fiber and there is a substantial absence of crepe bars.
• the fabric creped sheet has a structure which is somewhat undulatory in the machine direction allowing for stretch as will be appreciated from the examples hereinafter provided.
• a preferred method of initiating the inventive process is to start with a furnish that includes a polyacrylamide (i.e., Parez) at 1-11 lbs/ton along with a PAE resin at about 11 lbs/ton and operate the Yankee in a dry, blade-crepe mode with PVOH creping adhesive, creping the web from the cylinder for half an hour to forty- five minutes or so while an adhesive coating builds up on the Yankee. Thereafter, the acrylamide is no longer used in the furnish and carboxymethyl cellulose is used instead at 2-6 lbs/ton of fiber while the web is peeled from the Yankee as described below.
• start-up may be accomplished without using any dry strength agent.
• Figure 16 is a schematic diagram of a papermachine 40 having a conventional twin wire forming section 42, a felt run 44, a shoe press section 46 a creping fabric 48 and a Yankee dryer 50 suitable for practicing the present invention.
• Forming section 42 includes a pair of forming fabrics 52, 54 supported by a plurality of rolls 56, 58, 60, 62, 64, 66 and a forming roll 68.
• a headbox 70 provides papermaking furnish issuing therefrom as a jet in the machine direction to a nip 72 between forming roll 68 and roll 56 and the fabrics.
• the furnish forms a nascent web 74 which is dewatered on the fabrics with the assistance of suction, for example, by way of suction box 76.
• the nascent web is advanced to a papermaking felt 78 which is supported by a plurality of rolls 80, 82, 84, 85 and the felt is in contact with a shoe press roll 86.
• the web is of low consistency as it is transferred to the felt. Transfer may be assisted by suction; for example roll 80 may be a suction roll if so desired or a pickup or suction shoe as is known in the art.
• Transfer roll 90 may be a heated roll if so desired.
• roll 86 could be a conventional suction pressure roll.
• roll 84 is a suction roll effective to remove water from the felt prior to the felt entering the shoe press nip since water from the furnish will be pressed into the felt in the shoe press nip.
• using a suction roll at 84 is typically desirable to ensure the web remains in contact with the felt during the direction change as one of skill in the art will appreciate from the diagram.
• Web 74 is wet-pressed on the felt in nip 88 with the assistance of pressure shoe 92.
• the web is thus compactively dewatered at 88, typically by increasing the consistency by 15 or more points at this stage of the process.
• the configuration shown at 88 is generally termed a shoe press; in connection with the present invention, cylinder 90 is operative as a transfer cylinder which operates to convey web 74 at high speed, typically 1000 fpm-6000 fpm, to the creping fabric.
• Cylinder 90 has a smooth surface 94 which may be provided with adhesive and/or release agents if needed. Web 74 is adhered to transfer surface 94 of cylinder 90 which is rotating at a high angular velocity as the web continues to advance in the machine-direction indicated by arrows 96. On the cylinder, web 74 has a generally random apparent distribution of fiber.
• Direction 96 is referred to as the machine-direction (MD) of the web as well as that of papermachine 40; whereas the cross-machine-direction (CD) is the direction in the plane of the web perpendicular to the MD.
• MD machine-direction
• CD cross-machine-direction
• Web 74 enters nip 88 typically at consistencies of 10-25 percent or so and is dewatered and dried to consistencies of from about 35 to about 70 by the time it is transferred to creping fabric 48 as shown in the diagram.
• Fabric 48 is supported on a plurality of rolls 98, 100, 102 and a press nip roll 104 and forms a fabric crepe nip 106 with transfer cylinder 90 as shown.
• the creping fabric defines a creping nip over the distance (nip width) in which creping fabric 48 is adapted to contact roll 90; that is, applies significant pressure to the web against the transfer cylinder.
• backing (or creping) roll 100 may be provided with a soft deformable surface which will increase the width of the creping nip and increase the fabric creping angle between the fabric and the sheet and the point of contact or a shoe press roll could be used as roll 100 to increase effective contact with the web in high impact fabric creping nip 106 where web 74 is transferred to fabric 48 and advanced in the machine- direction.
• Creping nip 106 generally extends over a fabric creping nip width or distance of anywhere from about 1/8" to about 2", typically 1 A" to 2". For a creping fabric with 32 CD strands per inch, web 74 thus will encounter anywhere from about 4 to 64 weft filaments in the nip.
• nip pressure in nip 106 that is, the loading between backing roll 100 and transfer roll 90 is suitably 20-200, preferably 40-70 pounds per linear inch (PLI).
• nip 112 occurs at a web consistency of generally from about 25 or 30 to about 70 percent. At these consistencies, it is difficult to adhere the web to surface 114 of cylinder 110 firmly enough to remove the web from the fabric thoroughly. This aspect of the process is important, particularly when it is desired to use a high velocity drying hood.
• Papermachine 40 is a three fabric loop machine having a forming section 42 generally referred to in the art as a crescent former.
• Forming section 42 includes a forming wire 52 supported by a plurality of rolls such as rolls 62, 65.
• the forming section also includes a forming roll 68 which supports paper making felt 78 such that web 74 is formed directly on felt 78.
• Felt run 44 extends to a shoe press section 46 wherein the moist web is deposited on a transfer roll 90 as described above. Thereafter web 74 is creped onto fabric 48 in fabric crepe nip 106 between rolls 90, 100 before being deposited on Yankee dryer in another press nip 112.
• Suction is optionally applied by suction box 75 as the web is held in fabric.
• Headbox 70 and press shoe 92 operate as noted above in connection with Figure 16.
• the system includes a suction turning roll 84, in some embodiments; however, the three loop system may be configured in a variety of ways wherein a turning roll is not necessary.
• Any suitable line arrangement may be used downstream of Yankee dryer 50 between the Yankee dryer and take up reel 120.
• One preferred layout is shown schematically in
• FIGS 18 and 19 There is shown a Yankee cylinder 110 upon which the sheet is dried and in proximity therewith a first foil 160 which has a rounded edge 162 adjacent the Yankee dryer. The rounded edge of the foil is in close proximity with the surface of cylinder 110.
• any open draw is provided with some form of stabilizing airfoil and there are provided tensioners so as to prevent wrinkling of the sheet.
• Second and third airfoils 164, 168 stabilize the web over open draw along the production line. Thereafter a spreader bar or bow roll 166 may be used to apply tension to the web in order to prevent wrinkling as the web progresses to an optional calender stack 172.
• Stack 172 may be used to calender the web especially if it is desired to reduce sidedness. While any suitable calender load may be employed, it is preferred that the calender load be between about 15 and about 25 pli.
• calender stack 172 Between calender stack 172 and reel 120 there is provided a Measurex® control instrument 180 to measure consistency and basis weight in order to provide data for feedback control of the papermachine. Fourth and fifth airfoils 174, 178 stabilize the web on either side of the Measurex® instrument. Another spreader bar or bow roll 176 is provided in front of reel 120 in order to tension the web.
• calender stack 172 be synchronized with reel 120 prior to loading the calender stack. After loading, reel 120 can be speeded up to be slightly faster than calendar stack 172 (3-10 fpm faster) to promote good winding.
• the present invention makes it possible to employ elevated levels of recycled fiber in the towel without compromising product quality. Also, a reduced add-on rate of Yankee coatings was preferred when running 100% recycled fiber. The addition of recycled fiber also made it possible to reduce the use of dry strength resin.
• the amount of fabric crepe is greater than the amount of fabric crepe; the furnish blend which should consist of suitable fiber; the wet end additive package which may include cationic and anionic dry and wet strength resins, preferably including carboxymethyl cellulose; preferably, steam pressures are reduced for manufacture of the inventive product from about 115 psi to about 70 psi and the adhesive coating package for the Yankee is reduced by 50 or 70 percent with respect to dry creped products. So also, the modifier level in the creping adhesive is reduced substantially.
• the sheet moisture as it is taken from the Yankee dryer is higher when peeled in accordance with the present invention than in a dry crepe process where the moisture may be 2 percent or less. Typically, the sheet moisture in the inventive process is anywhere from about 3 to 5 percent.
• a foil with a rounded front edge enhances the sheet's stability when peeling from the Yankee dryer; whereas a bow or spreader bar helps eliminate or reduce wrinkling of the sheet prior to the calender stack.
• the calender stack is synchronized with the reel speed prior to loading the calender stack. After the calender stack has been loaded the reel speed may be increased to get a good roll structure. Further modifications to the above examples will be readily apparent to those of skill in the art. For example, if one wanted to increase stiffness, additional starch could be added to the product.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Paper (AREA)
• Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

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• 2006
  • 2006-06-13 EP EP06773075.4A patent/EP1907625B1/de active Active
  • 2006-06-13 WO PCT/US2006/023037 patent/WO2007001837A2/en active Search and Examination
  • 2006-06-13 CA CA2612663A patent/CA2612663C/en active Active

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