EP1880620A2 - Thermal protection fabric - Google Patents

Thermal protection fabric Download PDF

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Publication number
EP1880620A2
EP1880620A2 EP07112602A EP07112602A EP1880620A2 EP 1880620 A2 EP1880620 A2 EP 1880620A2 EP 07112602 A EP07112602 A EP 07112602A EP 07112602 A EP07112602 A EP 07112602A EP 1880620 A2 EP1880620 A2 EP 1880620A2
Authority
EP
European Patent Office
Prior art keywords
fabric
aramid
fibers
layer
thermal protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP07112602A
Other languages
German (de)
French (fr)
Other versions
EP1880620A3 (en
Inventor
Miguel Lanuza Inés
Francisco Casas Sanz
Eva Latorre Guallar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tejidos Estambril SA
Original Assignee
Tejidos Estambril SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tejidos Estambril SA filed Critical Tejidos Estambril SA
Publication of EP1880620A2 publication Critical patent/EP1880620A2/en
Publication of EP1880620A3 publication Critical patent/EP1880620A3/en
Withdrawn legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08Heat resistant; Fire retardant
    • A41D31/085Heat resistant; Fire retardant using layered materials
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A41D31/102Waterproof and breathable
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/12Hygroscopic; Water retaining
    • A41D31/125Moisture handling or wicking function through layered materials
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/26Electrically protective, e.g. preventing static electricity or electric shock
    • A41D31/265Electrically protective, e.g. preventing static electricity or electric shock using layered materials
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00Double or multi-ply fabrics not otherwise provided for
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/01Surface features
    • D10B2403/011Dissimilar front and back faces
    • D10B2403/0114Dissimilar front and back faces with one or more yarns appearing predominantly on one face, e.g. plated or paralleled yarns

Definitions

  • the present invention relates to a technical fabric for thermal protection and comfort.
  • the fabric of the invention is formed of an outer layer and an inner layer that is near or in contact with the user, both layers comprising different types of fibers. Said layers are spaced apart by an air layer.
  • Thermal protection fabrics are known formed of fiber thread layers that can be of different nature according to the properties desired to provide to the fabric concerned.
  • the present invention provides a fiber technical fabric for thermal protection that allows to overcome the disadvantages of the fabrics which for the same purpose have been used so far, further providing other additional advantages, as it will be seen hereinafter.
  • the invention provides a thermal protection fabric formed of two fiber layers: a high thermal protection, low moisture absorption (lower than 10%) outer layer, and a high absorption, fire-resistant inner layer.
  • the outer layer and the inner layer are formed of respective weft and warp threads, and they are conveniently spaced apart by an air layer.
  • the outer layer of the fabric according to the invention is made out of stable fiber threads.
  • These outer layer fibers can be selected from meta-aramid, para-aramid, polyamideimide, modacrylic fibers and mixtures thereof.
  • the inner layer of the fabric is made out of fibers selected from fire-resistant viscose, treated cotton or polybenzimidazole or mixtures with meta-aramid, para-aramid, polyamideimide and modacrylic.
  • the fabric of the invention can be made out of fibers forming staple fiber threads.
  • the fabric can be double shed fabric.
  • Other variants of the described fabric can be plated knitted fabric.
  • At least one of the layers of the fabric includes carbon fibers. At least one of the layers of the fabric could also include metal fibers to provide the fabric with antistatic properties. Both said carbon fibers and said metal fibers would be included in small proportions.
  • a fabric as the one of the invention a highly effective garment is obtained as for thermal protection and with a great sweat absorption power due to the composition of the inner layer (the one in contact with the skin) promoting the passage of sweat to the fabric providing a greater comfort since the skin is dried. This comfort is promoted by the use of staple (non multifilament) fibers further obtaining a more aesthetic visual appearance.
  • a good moisture transference is further obtained due to the composition of the outer layer of the fabric which prevents the fabric from being impregnated and, therefore, with the water remaining in the surface and thus easily evaporated.
  • the fabric of the invention is a high air permeability and low water steam resistance fabric.
  • thermal protection fabric according to the invention.
  • the fabric comprises an outer layer 1 and an inner layer 2.
  • This inner layer 2 is the one in contact or in the proximity of the user's skin. Both layers 1, 2 are formed of fiber threads 6 forming the weft 4 and the warp 5 of the fabric.
  • the fiber composition of the outer layer 1 is different from the fiber composition of the inner layer 2.
  • the outer layer 1 and the inner layer 2 are spaced apart by an intermediate air layer 3.
  • the outer layer 1 of the fabric that is herein described according to the invention has high thermal protection and low moisture absorption (lower than 10%) features.
  • the outer layer 1 of the fabric can be made out of stable fiber threads selected from meta-aramid, para-aramid, polyamideimide, modacrylic fibers and mixtures thereof.
  • the inner layer 2 is a high absorption, fire-resistant layer.
  • This inner layer 2 of the fabric can be made out of staple fiber threads selected from viscose, treated cotton or polybenzimidazole or mixtures of meta-aramid, para-aramid, polyamideimide and modacrylic.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

It comprises two layers of stable fiber thread: a high thermal protection, low absorption outer layer (1), and a high absorption, fire-resistant inner layer (2). Both layers (1, 2) are arranged spaced apart by an air layer (3). The outer layer (1) may be made out of meta-aramid, para-aramid, polyamideimide, modacrylic and mixtures thereof; and the inner layer (2) may be made out of fire-resistant viscose, treated cotton or polybenzimidazole or mixtures with meta-aramid, para-aramid, polyamideimide and modacrylic. The fabric may be knitted fabric or double cloth fabric.

Description

    Field of the invention
  • The present invention relates to a technical fabric for thermal protection and comfort. The fabric of the invention is formed of an outer layer and an inner layer that is near or in contact with the user, both layers comprising different types of fibers. Said layers are spaced apart by an air layer.
  • BACKGROUND ART
  • Thermal protection fabrics are known formed of fiber thread layers that can be of different nature according to the properties desired to provide to the fabric concerned.
  • Although theoretically, in general, in order to obtain a good fire protection non combustible materials must be used, this is not easy in the event they are fabrics for garments. Other difficulties further exist in the use of certain materials in thermal protection clothing such as obtaining suitable steam permeability and water impermeability values. Certain synthetic fibers, such as para-aramid (e.g. Kevlar®, Twaron®, Technora®), meta-aramid (e.g. Nomex®, Conex®) or polybenzimidazole (PBI®), allow good results to be obtained.
  • One example of the use of such materials for making technical protection fabrics is the international application WO01/64985 , which describes a fabric with an outer layer having Nomex® threads and an inner layer having Kevlar® threads. In one embodiment, both layers are interlaced by warp Nomex® threads.
  • Although prior art solutions can be effective in certain applications, they are not completely effective in providing a protection and comfort combined action. On the other hand, the use of Nomex® fibers for the outer layer does not promote user sweating as these fibers have a low moisture absorption (absorption index of the order of 5.5%). In addition, the use of Kevlar® fibers in the inner layer does not provide appropriate protection and comfort.
  • SUMMARY OF THE INVENTION
  • The present invention provides a fiber technical fabric for thermal protection that allows to overcome the disadvantages of the fabrics which for the same purpose have been used so far, further providing other additional advantages, as it will be seen hereinafter.
  • Particularly, the invention provides a thermal protection fabric formed of two fiber layers: a high thermal protection, low moisture absorption (lower than 10%) outer layer, and a high absorption, fire-resistant inner layer. The outer layer and the inner layer are formed of respective weft and warp threads, and they are conveniently spaced apart by an air layer.
  • Particularly, the outer layer of the fabric according to the invention is made out of stable fiber threads. These outer layer fibers can be selected from meta-aramid, para-aramid, polyamideimide, modacrylic fibers and mixtures thereof.
  • On the other hand, the inner layer of the fabric is made out of fibers selected from fire-resistant viscose, treated cotton or polybenzimidazole or mixtures with meta-aramid, para-aramid, polyamideimide and modacrylic.
  • The fabric of the invention can be made out of fibers forming staple fiber threads. The fabric can be double shed fabric. Other variants of the described fabric can be plated knitted fabric.
  • It is envisaged that at least one of the layers of the fabric includes carbon fibers. At least one of the layers of the fabric could also include metal fibers to provide the fabric with antistatic properties. Both said carbon fibers and said metal fibers would be included in small proportions.
  • With a fabric as the one of the invention a highly effective garment is obtained as for thermal protection and with a great sweat absorption power due to the composition of the inner layer (the one in contact with the skin) promoting the passage of sweat to the fabric providing a greater comfort since the skin is dried. This comfort is promoted by the use of staple (non multifilament) fibers further obtaining a more aesthetic visual appearance. A good moisture transference is further obtained due to the composition of the outer layer of the fabric which prevents the fabric from being impregnated and, therefore, with the water remaining in the surface and thus easily evaporated. The fabric of the invention is a high air permeability and low water steam resistance fabric.
  • Other objects, advantages and features of the thermal protection fabric of the invention will be clear from the description of the invention of a preferred embodiment. This description is given by way of a non limiting example and it is depicted in the appended drawings.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • In said drawings,
    • Figure 1 is a diagrammatic view showing one embodiment of a double cloth fabric according to the invention; and
    • Figure 2 is a diagrammatic view showing one embodiment of a knitted fabric according to the invention.
    DETAILED DESCRIPTION OF ONE PREFERRED EMBODIMENT
  • Several exemplary embodiments of a thermal protection fabric according to the invention are described hereinbelow.
  • As it can be seen from figure 1 of the drawings herein enclosed, the fabric comprises an outer layer 1 and an inner layer 2. This inner layer 2 is the one in contact or in the proximity of the user's skin. Both layers 1, 2 are formed of fiber threads 6 forming the weft 4 and the warp 5 of the fabric. The fiber composition of the outer layer 1 is different from the fiber composition of the inner layer 2.
  • As it can be seen, the outer layer 1 and the inner layer 2 are spaced apart by an intermediate air layer 3.
  • The outer layer 1 of the fabric that is herein described according to the invention has high thermal protection and low moisture absorption (lower than 10%) features. The outer layer 1 of the fabric can be made out of stable fiber threads selected from meta-aramid, para-aramid, polyamideimide, modacrylic fibers and mixtures thereof.
  • On the other hand, the inner layer 2 is a high absorption, fire-resistant layer. This inner layer 2 of the fabric can be made out of staple fiber threads selected from viscose, treated cotton or polybenzimidazole or mixtures of meta-aramid, para-aramid, polyamideimide and modacrylic.
  • The configuration of the fabric with the weft 6 and warp 4 thread 5, forming a double joined cloth (figure 1) or knitted (figure 2) fabric according to the invention, respectively, is shown in figure 1.
  • While the present invention has been described in the specification and it has been depicted in the appended drawings with reference to one preferred embodiment thereof, different changes can be made in the thermal protection fabric of the invention without departing from the scope of protection defined in the following claims.

Claims (9)

  1. - Thermal protection fabric comprising an outer layer (1) and an inner layer (2) of fibers, characterized in that the outer layer (1) is a high thermal protection, low absorption layer, the inner layer (2) being made out of high absorption, fire-resistant fibers.
  2. - Fabric as claimed in claim 1, characterized in that the outer layer (1) is made out of one or more of fibers selected from meta-aramid, para-aramid, polyamideimide, modacrylic and mixtures thereof.
  3. - Fabric as claimed in claim 1, characterized in that the inner layer (2) is made out of fibers selected from fire-resistant viscose, treated cotton or polybenzimidazole or mixtures of meta-aramid, para-aramid, polyamideimide and modacrylic
  4. - Fabric as claimed in any of the preceding claims, characterized in that said fibers form stable fiber threads.
  5. - Fabric as claimed in any of the preceding claims, characterized in that said fabric is a plated knitted fabric.
  6. - Fabric as claimed in any of the preceding claims, characterized in that this fabric is a double cloth fabric.
  7. - Fabric as claimed in any of the preceding claims, characterized in that both layers (1, 2) are spaced apart by an air layer (3).
  8. - Fabric as claimed in any of the preceding claims, characterized in that at least one of the layers includes carbon fibers.
  9. - Fabric as claimed in any of the preceding claims, characterized in that at least one of the layers includes metal fibers.
EP07112602A 2006-07-18 2007-07-17 Thermal protection fabric Withdrawn EP1880620A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200601973A ES2327883B1 (en) 2006-07-18 2006-07-18 THERMAL PROTECTION FABRIC.

Publications (2)

Publication Number Publication Date
EP1880620A2 true EP1880620A2 (en) 2008-01-23
EP1880620A3 EP1880620A3 (en) 2008-11-26

Family

ID=38544341

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07112602A Withdrawn EP1880620A3 (en) 2006-07-18 2007-07-17 Thermal protection fabric

Country Status (2)

Country Link
EP (1) EP1880620A3 (en)
ES (1) ES2327883B1 (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITNA20090039A1 (en) * 2009-06-15 2010-12-16 Vito Graniglia BREATHABLE AND ANTISTATIC FABRIC FOR CLOTHING, SPORTSWEAR, PROTECTION AND SAFETY EQUIPMENT, ACCESSORIES THAT GO DIRECTLY TO THE HUMAN PERSON
WO2011033145A1 (en) * 2009-09-18 2011-03-24 Tag Innovación, S. A. Double cloth fabric
CN102150962A (en) * 2010-12-08 2011-08-17 吴江市合欣转移印花有限公司 Anti-static thermal insulation fabric
GB2478854A (en) * 2010-03-19 2011-09-21 Toray Textiles Europ Ltd Fabric for personal protection garments
WO2011143076A3 (en) * 2010-05-10 2012-01-19 Milliken & Company Flame resistant textile materials
EP2610376A3 (en) * 2011-12-30 2013-12-18 IBENA Textilwerke GmbH Tissue combination
CN104372497A (en) * 2014-11-25 2015-02-25 吴松山 Indigo blue jean fabric
CN104389100A (en) * 2014-11-29 2015-03-04 滁州惠智科技服务有限公司 Fluorescent sunscreen fabric production method
FR3030583A1 (en) * 2014-12-23 2016-06-24 Europrotect France Sa TEXTILE FOR THE MANUFACTURE OF PROTECTIVE CLOTHING AGAINST FIRE
BE1024793B1 (en) * 2017-05-09 2018-06-28 Utexbel Nv MULTI-LAYER TISSUE MATERIAL SUITABLE FOR MANUFACTURING PROTECTIVE CLOTHING FOR WELDERS
GB2559772A (en) * 2017-02-17 2018-08-22 Arville Textiles Ltd Fire resistant textile
WO2020168437A1 (en) * 2019-02-22 2020-08-27 Jess Black Inc. Fire-resistant double-faced fabric of knitted construction
WO2022110012A1 (en) * 2020-11-27 2022-06-02 贝嘉制衣(绍兴)有限公司 Shirt fabric

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001064985A2 (en) 2000-03-02 2001-09-07 Marcanada Inc. Outer shell fabric for fire protective garments for firefighters and for workers exposed to risk of flash fire or electric arc
WO2004037027A1 (en) 2002-10-21 2004-05-06 E.I. Du Pont De Nemours And Company Multilayered, breathable textile fabric
US20060046022A1 (en) 2004-08-27 2006-03-02 Yves Bader Thermally-resistant composite fabric sheet
DE60216801T2 (en) 2001-11-07 2007-11-08 Kermel COMPLEX LAYER MATERIAL FOR PROTECTIVE CLOTHING, ESPECIALLY FOR FIREPROOF CLOTHING

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5691040A (en) * 1995-12-18 1997-11-25 Marcanada Inc. Liner for firefighter garment made of a laminate of a woven fabric and a non-woven material
FR2781341B1 (en) * 1998-07-23 2000-10-20 Dollfus Mieg Et Compagnie Dmc TEXTILE COMPLEX FOR THE PRODUCTION OF THERMAL PROTECTIVE CLOTHING
DE20214118U1 (en) * 2002-09-12 2002-11-14 Theodolf Fritsche GmbH & Co., 95233 Helmbrechts Protective clothing
CA2611804A1 (en) * 2004-06-14 2005-12-22 De Ball Inc. Fire insulating barrier material for a firefighter protective garment

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001064985A2 (en) 2000-03-02 2001-09-07 Marcanada Inc. Outer shell fabric for fire protective garments for firefighters and for workers exposed to risk of flash fire or electric arc
DE60216801T2 (en) 2001-11-07 2007-11-08 Kermel COMPLEX LAYER MATERIAL FOR PROTECTIVE CLOTHING, ESPECIALLY FOR FIREPROOF CLOTHING
WO2004037027A1 (en) 2002-10-21 2004-05-06 E.I. Du Pont De Nemours And Company Multilayered, breathable textile fabric
DE10248999B3 (en) 2002-10-21 2004-05-06 Theodolf Fritsche Gmbh & Co. Multi-layer, breathable textile fabric
US20060046022A1 (en) 2004-08-27 2006-03-02 Yves Bader Thermally-resistant composite fabric sheet

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITNA20090039A1 (en) * 2009-06-15 2010-12-16 Vito Graniglia BREATHABLE AND ANTISTATIC FABRIC FOR CLOTHING, SPORTSWEAR, PROTECTION AND SAFETY EQUIPMENT, ACCESSORIES THAT GO DIRECTLY TO THE HUMAN PERSON
WO2011033145A1 (en) * 2009-09-18 2011-03-24 Tag Innovación, S. A. Double cloth fabric
GB2478854A (en) * 2010-03-19 2011-09-21 Toray Textiles Europ Ltd Fabric for personal protection garments
WO2011114108A3 (en) * 2010-03-19 2011-11-10 Toray Textiles Europe Limited Fire resistant fabric for high visibility protection garments
GB2478854B (en) * 2010-03-19 2012-11-21 Toray Textiles Europ Ltd Fabric for personal protection garments
WO2011143076A3 (en) * 2010-05-10 2012-01-19 Milliken & Company Flame resistant textile materials
RU2531462C2 (en) * 2010-05-10 2014-10-20 Милликен Энд Компани Flame-proof textile materials
CN102150962A (en) * 2010-12-08 2011-08-17 吴江市合欣转移印花有限公司 Anti-static thermal insulation fabric
EP2610376A3 (en) * 2011-12-30 2013-12-18 IBENA Textilwerke GmbH Tissue combination
CN104372497A (en) * 2014-11-25 2015-02-25 吴松山 Indigo blue jean fabric
CN104389100A (en) * 2014-11-29 2015-03-04 滁州惠智科技服务有限公司 Fluorescent sunscreen fabric production method
CN105951266A (en) * 2014-11-29 2016-09-21 耿云花 Fluorescent sunproof fabric
CN104389100B (en) * 2014-11-29 2016-11-30 海宁市弘翔纺织科技有限公司 A kind of production method of fluorescence sunscreen fabric
CN105951266B (en) * 2014-11-29 2019-04-30 宁波侨泰兴纺织有限公司 A kind of fluorescence sunscreen fabric
FR3030583A1 (en) * 2014-12-23 2016-06-24 Europrotect France Sa TEXTILE FOR THE MANUFACTURE OF PROTECTIVE CLOTHING AGAINST FIRE
WO2016102873A1 (en) * 2014-12-23 2016-06-30 Europrotect France Sa Fabric for manufacturing garments for fire protection
GB2559772A (en) * 2017-02-17 2018-08-22 Arville Textiles Ltd Fire resistant textile
BE1024793B1 (en) * 2017-05-09 2018-06-28 Utexbel Nv MULTI-LAYER TISSUE MATERIAL SUITABLE FOR MANUFACTURING PROTECTIVE CLOTHING FOR WELDERS
WO2020168437A1 (en) * 2019-02-22 2020-08-27 Jess Black Inc. Fire-resistant double-faced fabric of knitted construction
US11905630B2 (en) 2019-02-22 2024-02-20 Jess Black Inc. Fire-resistant double-faced fabric of knitted construction
WO2022110012A1 (en) * 2020-11-27 2022-06-02 贝嘉制衣(绍兴)有限公司 Shirt fabric

Also Published As

Publication number Publication date
ES2327883A1 (en) 2009-11-04
EP1880620A3 (en) 2008-11-26
ES2327883B1 (en) 2010-09-06

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