EP1848934B1 - Refrigeration circuit with improved liquid/vapour receiver - Google Patents
Refrigeration circuit with improved liquid/vapour receiver Download PDFInfo
- Publication number
- EP1848934B1 EP1848934B1 EP05723391.8A EP05723391A EP1848934B1 EP 1848934 B1 EP1848934 B1 EP 1848934B1 EP 05723391 A EP05723391 A EP 05723391A EP 1848934 B1 EP1848934 B1 EP 1848934B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- receiver
- compressor
- heat exchanger
- heat
- refrigeration circuit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005057 refrigeration Methods 0.000 title claims description 42
- 239000007788 liquid Substances 0.000 title claims description 32
- 239000003507 refrigerant Substances 0.000 claims description 36
- 238000004891 communication Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 4
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 230000006835 compression Effects 0.000 claims description 2
- 238000007906 compression Methods 0.000 claims description 2
- 238000001816 cooling Methods 0.000 description 20
- 239000007789 gas Substances 0.000 description 10
- 239000012071 phase Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 238000007710 freezing Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 235000013361 beverage Nutrition 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B40/00—Subcoolers, desuperheaters or superheaters
- F25B40/02—Subcoolers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/30—Expansion means; Dispositions thereof
- F25B41/39—Dispositions with two or more expansion means arranged in series, i.e. multi-stage expansion, on a refrigerant line leading to the same evaporator
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/008—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B1/00—Compression machines, plants or systems with non-reversible cycle
- F25B1/10—Compression machines, plants or systems with non-reversible cycle with multi-stage compression
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2309/00—Gas cycle refrigeration machines
- F25B2309/06—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
- F25B2309/061—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/05—Compression system with heat exchange between particular parts of the system
- F25B2400/053—Compression system with heat exchange between particular parts of the system between the storage receiver and another part of the system
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/07—Details of compressors or related parts
- F25B2400/075—Details of compressors or related parts with parallel compressors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/13—Economisers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/23—Separators
Definitions
- This invention relates to a refrigeration circuit
- a refrigeration circuit comprising a first compressor device, a heat-rejecting heat exchanger, a first expansion device, a receiver having an upper portion and a lower portion, a second expansion device, and a first evaporator.
- the refrigeration circuit further comprises a flow path between the upper portion of the receiver and a compressor, the pressure side of which is in flow communication with the entrance of the heat-rejecting heat exchanger.
- the refrigeration circuit preferably is of the type designed for CO 2 as a refrigerant, but is not limited thereto.
- the refrigeration circuit is of the two stage expansion type, wherein the refrigerant first is expanded in first stage expansion.
- the first stage expansion provides cooling to complete condensation of the refrigerant in the receiver.
- the section of the refrigeration circuit extending from the receiver to the compressor device is at a substantially lower pressure level than the remaining section of the refrigeration circuit extending from the compressor device to first expansion device.
- EP 0 541 343 A shows a household refrigerator including a refrigerant circuit having a compressor, a condenser receiving refrigerant from the compressor and a phase separator receiving refrigerant from the condenser.
- the portion of the phase separator which contains liquid refrigerant is connected to the inlet of the freezer evaporator, the outlet of which is connected to the compressor. That portion of the phase separator which contains vapour refrigerant is connected to the compressor.
- the fresh food evaporator is connected to the phase separator to receive liquid refrigerant from the phase separator and to return vapor refrigerant to the phase separator.
- a refrigeration circuit for circulating a refrigerant in a predetermined flow direction comprising in flow direction a first compressor device, a heat-rejecting heat exchanger, a first expansion device, a receiver having in its interior an upper portion, being in flow communication with the first expansion device, and a lower portion, a second expansion device being in flow communication with the lower portion of the receiver, and a first evaporator; and comprising a further flow path between the upper portion of the receiver and the suction side of a compressor being part of said first compressor device, the pressure side of which is in flow communication with the entrance of said heat-rejecting heat exchanger; wherein at least one element of the group consisting of the following elements (a) and (b) is provided: (a) a second heat exchanger is arranged in said upper portion of said receiver, the entrance of the second heat exchanger being in flow communication with the exit of said heat-rejecting heat exchanger and the exit of the second heat exchanger being in flow communication with the entrance
- the second heat exchanger arranged in the upper portion of the receiver exchanges heat against the vapour contained in the upper portion of the receiver. Any liquid droplets that may be present in the upper portion of the receiver will be evaporated and entrained into the further flow path.
- the third expansion device and the third heat exchanger arranged in lower portion of the receiver provide sub-cooling the liquid in the lower portion of the receiver.
- Such sub-cooled liquid refrigerant results in more efficient cooling effect by the first evaporator and reduces the formation of refrigerant vapour in the section of the circuit extending from the receiver to the second expansion device.
- All in all the improved receiver provides for a more perfect separation into a gaseous phase of the refrigerant having substantially no content of liquid droplets, and a liquid phase that is sub-cooled and has less tendency to vapour formation.
- the first compressor device may be a single compressor or a parallel group of several compressors.
- the compressor device may be of the type comprising a control of its performance, for example by way of controlling its rotational speed dependent on the pressure level of the compressed gaseous refrigerant to be achieved.
- the compressor associated to the further flow path starting from the upper portion of the receiver may be a further compressor.
- the suction side of such further compressor may be at a higher pressure level than the suction side of the first-mentioned compressor device, or may be a substantially the same pressure level as the first-mentioned compressor device. It is possible to combine the compressor, that is associated to the further flow path, with the first-mentioned compressor device, either by using one and the same compressor for compressing the gaseous refrigerant coming from the second expansion device as well as the gaseous refrigerant coming from the upper portion of the receiver, or by combining the further compressor, that is associated to the further flow path, into a parallel group of compressors forming the first compressor device.
- the refrigeration circuit further comprises a branch circuit, branching off from a location located in a section of said circuit which section extends from said lower portion of said receiver to the entrance of said second expansion device; the branch circuit comprising in flow direction a fourth expansion device, a second evaporator, and a second compressor device; and the branch circuit, at its downstream end, being in flow communication with the suction side of said first compressor device.
- the branch circuit provides low temperature cooling, for example for deep-freezing purposes.
- the second expansion device and the first evaporator provide for medium temperature cooling, for example for keeping food and beverages at a temperature level of 0 to 10°C.
- the refrigeration circuit may comprise one or several second expansion devices/first evaporators, arranged in parallel, and one or several fourth expansion devices/second evaporators, arranged in parallel, if any.
- the refrigerant in the refrigeration circuit may be a one-component refrigerant or a multiple-components refrigerant.
- expansion devices of various constructions and designs may be provided.
- a quite common form of expansion device is an expansion valve.
- the expansion device may be a throttling device or a throttle valve.
- the expansion device depending on its location, the temperature level, and the pressure level, may serve to expand liquid refrigerant to gaseous refrigerant or may expand gaseous refrigerant from a higher pressure level to a lower pressure level.
- This invention further relates to a refrigeration apparatus comprising a refrigeration circuit as disclosed in the present application.
- the refrigeration apparatus of this invention may be provided as a heat pump.
- the technical elements of cooling apparatus and heat pumps are the same.
- the purpose of cooling is the primary purpose, and the related generation of heat is normally a side effect.
- heat pumps the generation of heat is the desired purpose, whereas the related cooling effect of the evaporator(s) is normally considered a less useful side effect.
- This invention also discloses a heat pump having a circuit as disclosed in the present application. Such circuit may be designated a refrigeration circuit because it contains a refrigerant undergoing condensation and evaporation. Some times people prefer to use the term working fluid rather than to use the term refrigerant when describing a heat pump.
- a refrigeration circuit containing CO 2 as a refrigerant may be a circuit operated in transcritical cycle, or may be a circuit operated in subcritical cycle, or may be a circuit operable in transcritical cycle or in subcritical cycle depending on parameters such as environmental temperature and pressure level after the compressor device.
- the refrigeration circuit does not reach a subcritical temperature level at the heat-rejecting heat exchanger, at least in summer time season; the circuit is operated in transcritical cycle.
- the heat-rejecting heat exchanger operates as a gas cooler.
- the heat-rejecting heat exchanger operates as a combined gas cooler and condenser.
- the main functions of the receiver are to permanently keep available a sufficient quantity of liquid refrigerant and to provide a separation between liquid refrigerant and gaseous refrigerant (vapour).
- the condensation of refrigerant by means of flash cooling provided by the first expansion device is a further function.
- the refrigeration apparatus/heat pump of this invention has a number of preferred fields of application. The most important are cooling food and beverages in shops, restaurants or other locations of storage; cooling other temperature-sensitive products such as pharmaceuticals; deep-freezing; cooling buildings of any sort; cooling cars and any other type of vehicles in the broad sense, such as aircrafts, ships, railway cars etc.
- This invention further relates to a refrigeration method.
- the refrigeration method comprises at least one step of the group of steps consisting of (i) operating a heat source in said upper portion of said receiver, (ii) operating a heat sink in said lower portion of said receiver.
- the total refrigeration circuit shown in Fig. 1 comprises a first-described (basic) circuit, a second-described further flow path, and a third-described branch circuit, and some additional elements.
- the basic circuit when beginning with a compressor device 6 and progressing in flow direction of the CO 2 -refrigerant, comprises the following elements:
- the compressor device 6 comprises three parallel compressors and a further compressor 6' to be described in more detail further below.
- the suction sides of the three compressors are supplied by a common supply space.
- the compressor device 6 compresses the supplied gaseous CO 2 to a pressure in the range of 50 to 120 bar, whereby the temperature of the gaseous compressed CO 2 is increased to about 50 to 150°C.
- the pressure of the compressed gaseous CO 2 would typically be in the range of 40 to 70 bar.
- the heat-rejecting heat exchanger removes heat from the CO 2 .
- the CO 2 is typically cooled to 10 to 30°C and condensed in the heat-rejecting heat exchanger 1; in this case heat exchanger 1 works as a combined gas cooler and condenser.
- the CO 2 is typically cooled to a temperature of 25 to 45°C, without condensation of a substantial part of the CO 2 , in the heat-rejecting heat exchanger; in this case it works as a gas cooler.
- the heat exchanger 1 is gas cooled or liquid (water) cooled.
- the vapour or liquid/vapour mixture or liquid CO 2 in subcritical operation is expanded by the expansion valve a provided next to the receiver 3, thereby providing flash gas in an upper portion of the receiver 3.
- the pressure level in the interior of the receiver 3 is 30 to 40 bar.
- a lower portion of the receiver 3 contains liquid CO 2 .
- the receiver 3 also acts as a separator of liquid CO 2 and CO 2 vapour.
- the liquid CO 2 is expanded to typically a temperature of minus 15 to 0°C, resulting in a pressure level of typically 20 to 35 bar.
- the evaporators E2 and E3 next to the expansion valves b and c serve to allow for a complete evaporation of the CO 2 and provide large cool surfaces, from where the cooling proper originates, typically by air moving by the "cool air is heavier than warm air" principle or moving by forced ventilation.
- the compressor device 6 and the receiver 3 are typically mounted in a common metal frame, also supporting the control equipment of the refrigeration apparatus.
- the remaining section of the basic circuit extending from the exit side of the expansion valve a to the suction side of the compressor device 6 is at two substantially lower pressure levels, namely typically 30 to 40 bar in front of the expansion valves b and c and typically 25 to 30 bar in front of the compressor device 6.
- the second-mentioned section of the basic circuit may be designed for such lower pressure levels, i.e. by using tubes having thinner walls, by using less sophisticated connections where CO 2 is flowing, and by using evaporators adapted to the relatively low pressure level.
- the expansion valve e may be dispensed with, and there is just a conduit 12, 15 from the upper portion of the receiver 3 to the further compressor 6'.
- the suction side of such further compressor 6' is at a higher pressure level that the suction side of the compressor device 6.
- the pressure sides of all the compressors 6 and 6' have the same pressure level. Rather than providing the further compressor 6', it is possible to feed from line 15 into one or several of the compressors of the compressor device 6, but at a stage after a first compression stage, so that the flash gas is fed into the compressor device 6 at the right pressure level of the compressors.
- Fig. 1 shows a branch circuit comprising the following: A conduit 8 branches off from the conduit 4 upstream of the expansion valves b and c; a (fourth) expansion valve d; a second evaporator E4; a conduit 9; a second compressor device 10, and a conduit 11 providing fluid flow connection with the suction side of the first compressor device 6.
- the expansion valve d and the second evaporator E4 are designed to provide an expansion of the liquid CO 2 to a lower pressure level than existing at the suction side of the compressor device 6.
- the temperature level reached at the evaporator E4 is lower than the temperature level reached at the evaporators E2 and E3, thereby providing means for deep-freezing or storing at deep-freezing temperature.
- Typical values are 7 to 15 bar and minus 50 to minus 25 °C in the evaporator E4.
- FIG. 1 shows a conduit 13 branching off the conduit 2 (that leads from the first heat exchanger 1 to the first expansion valve a) to a heat exchanger E1, an expansion valve f being provided in such conduit 13.
- a conduit 14 leads from the heat exchanger E1 to the suction side of the further compressor 6'.
- the heat exchanger E1 exchanges heat against the CO 2 flowing through the conduit 2. Since the expansion valve f provides cool gaseous CO 2 , the CO 2 flowing through the conduit 2 is cooled, thereby either assisting in condensation of CO 2 or in sub-cooling of liquid CO 2 .
- Fig. 2 shows a schematically sectional view of the receiver 3 at a larger scale than in Fig. 1 .
- the receiver 3 has in its interior an upper portion 3a and a lower portion 3b.
- a quantity of liquid CO 2 is contained in the receiver 3, filling the interior of the receiver 3 up to a level 22.
- the level 22 may be higher or lower than shown in Fig. 2 .
- the line 2 (providing a fluid flow connection between the exit of the heat exchanger 1 and the expansion valve a, cf. Fig. 1 ) extends into the receiver 3 and is connected to a second heat exchanger 24 arranged in the upper portion 3a of the receiver 3.
- the expansion valve 28 produces flash gas in the upper portion 3a, which as a consequence is at a lower temperature level than the CO 2 flowing through the second heat exchanger 24. Any droplets of liquid CO 2 that may be present in the upper portion 3a, are evaporated. This minimizes the potential for erosion of the expansion valve 34 described in the following paragraph.
- the expansion valve 28 has the same function as the expansion valve a shown in Fig. 1 . The difference is that the conduit 2 does not lead directly to the expansion valve 28, but there is the second heat exchanger 24 upstream of the expansion valve 28. By means of the second heat exchanger 24, the gaseous CO 2 exiting the upper portion 3a contains less condensed CO 2 than without the provision of the second heat exchanger 24.
- the CO 2 By passing through the expansion valve 34 the CO 2 becomes cooler, and the third heat exchanger 32 provides sub-cooling of the liquid CO 2 accumulated in the lower portion 3b of the receiver 3.
- the liquid, sub-cooled CO 2 exits the lower portion 3b via conduit 4, as shown in Fig. 1 .
- the gaseous CO 2 flowing through the third heat exchanger 32 gets a certain overheating which reduces the risk of entrainment of liquid CO 2 into the compressor device 6.
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- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compression-Type Refrigeration Machines With Reversible Cycles (AREA)
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Description
- This invention relates to a refrigeration circuit comprising a first compressor device, a heat-rejecting heat exchanger, a first expansion device, a receiver having an upper portion and a lower portion, a second expansion device, and a first evaporator. The refrigeration circuit further comprises a flow path between the upper portion of the receiver and a compressor, the pressure side of which is in flow communication with the entrance of the heat-rejecting heat exchanger.
- The refrigeration circuit preferably is of the type designed for CO2 as a refrigerant, but is not limited thereto.
- The refrigeration circuit is of the two stage expansion type, wherein the refrigerant first is expanded in first stage expansion. The first stage expansion provides cooling to complete condensation of the refrigerant in the receiver. Furthermore, the section of the refrigeration circuit extending from the receiver to the compressor device is at a substantially lower pressure level than the remaining section of the refrigeration circuit extending from the compressor device to first expansion device.
- It is an object of the invention to provide a refrigeration circuit with an improved receiver.
- It is a further object of the invention to provide a refrigeration circuit with a receiver outputting from its upper portion flash gas having substantially no liquid droplets therein.
- It is a still further object of the invention to provide a refrigeration circuit with a receiver outputting a sub-cooled liquid refrigerant.
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EP 0 541 343 A shows a household refrigerator including a refrigerant circuit having a compressor, a condenser receiving refrigerant from the compressor and a phase separator receiving refrigerant from the condenser. The portion of the phase separator which contains liquid refrigerant is connected to the inlet of the freezer evaporator, the outlet of which is connected to the compressor. That portion of the phase separator which contains vapour refrigerant is connected to the compressor. The fresh food evaporator is connected to the phase separator to receive liquid refrigerant from the phase separator and to return vapor refrigerant to the phase separator. - In accordance with one embodiment of the invention there is provided a refrigeration circuit for circulating a refrigerant in a predetermined flow direction, comprising in flow direction a first compressor device, a heat-rejecting heat exchanger, a first expansion device, a receiver having in its interior an upper portion, being in flow communication with the first expansion device, and a lower portion, a second expansion device being in flow communication with the lower portion of the receiver, and a first evaporator; and comprising a further flow path between the upper portion of the receiver and the suction side of a compressor being part of said first compressor device, the pressure side of which is in flow communication with the entrance of said heat-rejecting heat exchanger; wherein at least one element of the group consisting of the following elements (a) and (b) is provided: (a) a second heat exchanger is arranged in said upper portion of said receiver, the entrance of the second heat exchanger being in flow communication with the exit of said heat-rejecting heat exchanger and the exit of the second heat exchanger being in flow communication with the entrance of said first expansion device, (b) said further flow path comprises a third expansion device and, downstream thereof, a third heat exchanger arranged in said lower portion of said receiver.
- The second heat exchanger arranged in the upper portion of the receiver exchanges heat against the vapour contained in the upper portion of the receiver. Any liquid droplets that may be present in the upper portion of the receiver will be evaporated and entrained into the further flow path.
- The third expansion device and the third heat exchanger arranged in lower portion of the receiver provide sub-cooling the liquid in the lower portion of the receiver. Such sub-cooled liquid refrigerant results in more efficient cooling effect by the first evaporator and reduces the formation of refrigerant vapour in the section of the circuit extending from the receiver to the second expansion device.
- All in all the improved receiver provides for a more perfect separation into a gaseous phase of the refrigerant having substantially no content of liquid droplets, and a liquid phase that is sub-cooled and has less tendency to vapour formation.
- The first compressor device may be a single compressor or a parallel group of several compressors. The compressor device may be of the type comprising a control of its performance, for example by way of controlling its rotational speed dependent on the pressure level of the compressed gaseous refrigerant to be achieved.
- The compressor associated to the further flow path starting from the upper portion of the receiver, may be a further compressor. The suction side of such further compressor may be at a higher pressure level than the suction side of the first-mentioned compressor device, or may be a substantially the same pressure level as the first-mentioned compressor device. It is possible to combine the compressor, that is associated to the further flow path, with the first-mentioned compressor device, either by using one and the same compressor for compressing the gaseous refrigerant coming from the second expansion device as well as the gaseous refrigerant coming from the upper portion of the receiver, or by combining the further compressor, that is associated to the further flow path, into a parallel group of compressors forming the first compressor device.
- In accordance with an embodiment of the invention, the refrigeration circuit further comprises a branch circuit, branching off from a location located in a section of said circuit which section extends from said lower portion of said receiver to the entrance of said second expansion device; the branch circuit comprising in flow direction a fourth expansion device, a second evaporator, and a second compressor device; and the branch circuit, at its downstream end, being in flow communication with the suction side of said first compressor device.
- In such embodiment, the branch circuit provides low temperature cooling, for example for deep-freezing purposes. As compared to such low temperature cooling, the second expansion device and the first evaporator provide for medium temperature cooling, for example for keeping food and beverages at a temperature level of 0 to 10°C.
- The refrigeration circuit may comprise one or several second expansion devices/first evaporators, arranged in parallel, and one or several fourth expansion devices/second evaporators, arranged in parallel, if any.
- The refrigerant in the refrigeration circuit may be a one-component refrigerant or a multiple-components refrigerant.
- In the preceding description, reference has been made to various expansion devices. It should be stressed that expansion devices of various constructions and designs may be provided. A quite common form of expansion device is an expansion valve. The expansion device may be a throttling device or a throttle valve. The expansion device, depending on its location, the temperature level, and the pressure level, may serve to expand liquid refrigerant to gaseous refrigerant or may expand gaseous refrigerant from a higher pressure level to a lower pressure level.
- This invention further relates to a refrigeration apparatus comprising a refrigeration circuit as disclosed in the present application.
- The refrigeration apparatus of this invention may be provided as a heat pump. The technical elements of cooling apparatus and heat pumps are the same. With the cooling apparatus, the purpose of cooling is the primary purpose, and the related generation of heat is normally a side effect. With heat pumps, the generation of heat is the desired purpose, whereas the related cooling effect of the evaporator(s) is normally considered a less useful side effect. This invention also discloses a heat pump having a circuit as disclosed in the present application. Such circuit may be designated a refrigeration circuit because it contains a refrigerant undergoing condensation and evaporation. Some times people prefer to use the term working fluid rather than to use the term refrigerant when describing a heat pump.
- A refrigeration circuit containing CO2 as a refrigerant may be a circuit operated in transcritical cycle, or may be a circuit operated in subcritical cycle, or may be a circuit operable in transcritical cycle or in subcritical cycle depending on parameters such as environmental temperature and pressure level after the compressor device. In typical applications such as cooling temperature sensitive products, deep-freezing, cooling buildings, the refrigeration circuit does not reach a subcritical temperature level at the heat-rejecting heat exchanger, at least in summer time season; the circuit is operated in transcritical cycle. In such a situation the heat-rejecting heat exchanger operates as a gas cooler. In case of a subcritical cycle, the heat-rejecting heat exchanger operates as a combined gas cooler and condenser.
- The main functions of the receiver are to permanently keep available a sufficient quantity of liquid refrigerant and to provide a separation between liquid refrigerant and gaseous refrigerant (vapour). In case of transcritical cycle, the condensation of refrigerant by means of flash cooling provided by the first expansion device is a further function.
- The refrigeration apparatus/heat pump of this invention has a number of preferred fields of application. The most important are cooling food and beverages in shops, restaurants or other locations of storage; cooling other temperature-sensitive products such as pharmaceuticals; deep-freezing; cooling buildings of any sort; cooling cars and any other type of vehicles in the broad sense, such as aircrafts, ships, railway cars etc.
- This invention further relates to a refrigeration method. In an embodiment of the invention the refrigeration method comprises at least one step of the group of steps consisting of (i) operating a heat source in said upper portion of said receiver, (ii) operating a heat sink in said lower portion of said receiver.
- An exemplary embodiment of the invention will be described in the following. The features of such embodiment are preferred features of the refrigeration circuit of this invention:
- Fig. 1
- shows a diagram of a refrigeration circuit for elucidating the basic configuration of such a circuit;
- Fig. 2
- shows a receiver/separator on a larger scale, which may be incorporated in the refrigeration circuit of
Fig. 1 . - The total refrigeration circuit shown in
Fig. 1 comprises a first-described (basic) circuit, a second-described further flow path, and a third-described branch circuit, and some additional elements. - The basic circuit, when beginning with a
compressor device 6 and progressing in flow direction of the CO2-refrigerant, comprises the following elements: -
6 or 6 and 6';compressor device -
conduit 7; - heat-rejecting heat exchanger 1 (gas cooler and/or condenser);
-
conduit 2; - first expansion valve a;
-
receiver 3; -
conduit 4; - two parallel second expansion valves b and c;
- two parallel evaporators E2 and E3;
-
conduit 5 back tocompressor device 6. - The
compressor device 6 comprises three parallel compressors and a further compressor 6' to be described in more detail further below. The suction sides of the three compressors are supplied by a common supply space. Typically, thecompressor device 6 compresses the supplied gaseous CO2 to a pressure in the range of 50 to 120 bar, whereby the temperature of the gaseous compressed CO2 is increased to about 50 to 150°C. In subcritical operation the pressure of the compressed gaseous CO2 would typically be in the range of 40 to 70 bar. - The heat-rejecting heat exchanger removes heat from the CO2. In subcritical operation, the CO2 is typically cooled to 10 to 30°C and condensed in the heat-rejecting
heat exchanger 1; in thiscase heat exchanger 1 works as a combined gas cooler and condenser. In transcritical operation, the CO2 is typically cooled to a temperature of 25 to 45°C, without condensation of a substantial part of the CO2, in the heat-rejecting heat exchanger; in this case it works as a gas cooler. In order to remove heat from the CO2, theheat exchanger 1 is gas cooled or liquid (water) cooled. - The vapour or liquid/vapour mixture or liquid CO2 in subcritical operation, is expanded by the expansion valve a provided next to the
receiver 3, thereby providing flash gas in an upper portion of thereceiver 3. Typically, the pressure level in the interior of thereceiver 3 is 30 to 40 bar. A lower portion of thereceiver 3 contains liquid CO2. Thereceiver 3 also acts as a separator of liquid CO2 and CO2 vapour. - By the expansion valves b and c the liquid CO2 is expanded to typically a temperature of minus 15 to 0°C, resulting in a pressure level of typically 20 to 35 bar. The evaporators E2 and E3 next to the expansion valves b and c serve to allow for a complete evaporation of the CO2 and provide large cool surfaces, from where the cooling proper originates, typically by air moving by the "cool air is heavier than warm air" principle or moving by forced ventilation.
- The
compressor device 6 and thereceiver 3 are typically mounted in a common metal frame, also supporting the control equipment of the refrigeration apparatus. The (first)heat exchanger 1, that is a heat-rejecting heat exchanger, normally stands some distance away from thecompressor device 6 and thereceiver 3 and the expansion valve a, for example outside a building, where it can be cooled best. It is important to note that only the section of the basic circuit extending from the pressure side of thecompressor device 6 to the exit side of the expansion valve a is at the high pressure level of typically 50 to 120 bar. The remaining section of the basic circuit extending from the exit side of the expansion valve a to the suction side of thecompressor device 6 is at two substantially lower pressure levels, namely typically 30 to 40 bar in front of the expansion valves b and c and typically 25 to 30 bar in front of thecompressor device 6. As a consequence, the second-mentioned section of the basic circuit may be designed for such lower pressure levels, i.e. by using tubes having thinner walls, by using less sophisticated connections where CO2 is flowing, and by using evaporators adapted to the relatively low pressure level. - There is a further flow path, starting at an exit side of the upper portion (vapour portion) of the
receiver 3 with aconduit 12 and containing an expansion valve e or throttle valve, and finally leading to the entrance side of thecompressor device 6 via aconduit 11. The expansion valve e serve to reduce the pressure of the gaseous CO2 to the level existing at the suction side of thecompressor device 6. - As an alternative, the expansion valve e may be dispensed with, and there is just a
12, 15 from the upper portion of theconduit receiver 3 to the further compressor 6'. The suction side of such further compressor 6' is at a higher pressure level that the suction side of thecompressor device 6. The pressure sides of all thecompressors 6 and 6' have the same pressure level. Rather than providing the further compressor 6', it is possible to feed fromline 15 into one or several of the compressors of thecompressor device 6, but at a stage after a first compression stage, so that the flash gas is fed into thecompressor device 6 at the right pressure level of the compressors. - Furthermore,
Fig. 1 shows a branch circuit comprising the following: Aconduit 8 branches off from theconduit 4 upstream of the expansion valves b and c; a (fourth) expansion valve d; a second evaporator E4; aconduit 9; asecond compressor device 10, and aconduit 11 providing fluid flow connection with the suction side of thefirst compressor device 6. The expansion valve d and the second evaporator E4 are designed to provide an expansion of the liquid CO2 to a lower pressure level than existing at the suction side of thecompressor device 6. The temperature level reached at the evaporator E4 is lower than the temperature level reached at the evaporators E2 and E3, thereby providing means for deep-freezing or storing at deep-freezing temperature. Typical values are 7 to 15 bar and minus 50 to minus 25 °C in the evaporator E4. - Finally,
Fig. 1 shows aconduit 13 branching off the conduit 2 (that leads from thefirst heat exchanger 1 to the first expansion valve a) to a heat exchanger E1, an expansion valve f being provided insuch conduit 13. Aconduit 14 leads from the heat exchanger E1 to the suction side of the further compressor 6'. The heat exchanger E1 exchanges heat against the CO2 flowing through theconduit 2. Since the expansion valve f provides cool gaseous CO2, the CO2 flowing through theconduit 2 is cooled, thereby either assisting in condensation of CO2 or in sub-cooling of liquid CO2. -
Fig. 2 shows a schematically sectional view of thereceiver 3 at a larger scale than inFig. 1 . Thereceiver 3 has in its interior an upper portion 3a and a lower portion 3b. A quantity of liquid CO2 is contained in thereceiver 3, filling the interior of thereceiver 3 up to alevel 22. Depending on the operational conditions of the refrigeration circuit, thelevel 22 may be higher or lower than shown inFig. 2 . - The line 2 (providing a fluid flow connection between the exit of the
heat exchanger 1 and the expansion valve a, cf.Fig. 1 ) extends into thereceiver 3 and is connected to asecond heat exchanger 24 arranged in the upper portion 3a of thereceiver 3. There is afurther conduit 26, extending outside thereceiver 3 and connecting the downstream end of thesecond heat exchanger 24 to the interior of the upper portion 3a of thereceiver 3, anexpansion valve 28 being provided insuch conduit 26. Theexpansion valve 28 produces flash gas in the upper portion 3a, which as a consequence is at a lower temperature level than the CO2 flowing through thesecond heat exchanger 24. Any droplets of liquid CO2 that may be present in the upper portion 3a, are evaporated. This minimizes the potential for erosion of the expansion valve 34 described in the following paragraph. - The
expansion valve 28 has the same function as the expansion valve a shown inFig. 1 . The difference is that theconduit 2 does not lead directly to theexpansion valve 28, but there is thesecond heat exchanger 24 upstream of theexpansion valve 28. By means of thesecond heat exchanger 24, the gaseous CO2 exiting the upper portion 3a contains less condensed CO2 than without the provision of thesecond heat exchanger 24. - There is a
further conduit 30 leading, outside thereceiver 3, from the upper portion 3a to athird heat exchanger 32 arranged in the lower portion 3b of thereceiver 3, an expansion valve 34 being provided insuch conduit 30. The downstream end of thethird heat exchanger 32 is connected by aconduit 36 to the suction side of thecompressor device 6. In other words, the expansion valve 34 replaces the expansion valve e shown inFig. 1 , and thethird heat exchanger 32 is provided in addition. - By passing through the expansion valve 34 the CO2 becomes cooler, and the
third heat exchanger 32 provides sub-cooling of the liquid CO2 accumulated in the lower portion 3b of thereceiver 3. The liquid, sub-cooled CO2 exits the lower portion 3b viaconduit 4, as shown inFig. 1 . - The gaseous CO2 flowing through the
third heat exchanger 32 gets a certain overheating which reduces the risk of entrainment of liquid CO2 into thecompressor device 6.
Claims (9)
- Refrigeration circuit for circulating a refrigerant in a predetermined flow direction, comprising in flow direction a first compressor device (6), a heat-rejecting heat exchanger (1), a first expansion device (a; 28), a receiver (3) having in its interior an upper vapour portion (3a), being in flow communication with the first expansion device (a; 28), and a lower liquid portion (3b), a second expansion device (b; c; d) being in flow communication with the lower liquid portion (3b) of the receiver (3), and a first evaporator (E2; E3);
a further flow path (12; 30) between the upper vapour portion (3a) of the receiver (3) and the suction side of a compressor being part of said first compressor device (6), the pressure side of which is in flow communication with the entrance of said heat-rejecting heat exchanger (1);
characterized by at least one element of the group consisting of the following elements (a) and (b) is provided:(a) a second heat exchanger (24) is arranged in said upper vapour portion (3a) of said receiver (3), the entrance of the second heat exchanger (24) being in flow communication with the exit of said heat-rejecting heat exchanger (1) and the exit of the second heat exchanger (24) being in flow communication with the entrance of said first expansion device (28),(b) said further flow path (30) comprises a third expansion device (34) and, downstream thereof, a third heat exchanger (32) arranged in said lower liquid portion (3b) of said receiver (3). - Refrigeration circuit according to claim 1, wherein said refrigerant is CO2.
- Refrigeration circuit according to any one of claims 1 to 2, wherein said first compressor device (6) comprises a parallel group of several compressors.
- Refrigeration circuit according to any one of claims 1 to 3, wherein said first compressor device (6) comprises a further compressor (6'), the suction side of the further compressor (6') being at a higher pressure level than the suction side (20) of the first compressor device (6); or
wherein one or several of the compressors of the first compressor device (6) are fed from the further flow path (12;30) at a stage after a first compression stage. - Refrigeration circuit according to any one of claims 1 to 4, further comprising a branch circuit (8; 9; 11), branching off from a location located in a section (4) of said circuit which section extends from said lower liquid portion (3b) of said receiver (3) to the entrance of said second expansion device (b; c); the branch circuit (8; 9; 11) comprising in flow direction a fourth expansion device (d), a second evaporator (E4), and a second compressor device (10); and the branch circuit (8; 9; 11), at its downstream end, being in flow communication with the suction side of said first compressor device (6).
- Refrigeration circuit according to any one of claims 1 to 5, wherein several parallel first evaporators are provided.
- Refrigeration apparatus comprising a refrigeration circuit as specified in any one of claims 1 to 6.
- Refrigeration method, comprising:(a) circulating a refrigerant in a refrigeration circuit comprising, in flow direction, a first compressor device (6), a heat-rejecting heat exchanger (1), a first expansion device (a; 28), a receiver (3) having in its interior an upper vapour portion (3a), being in flow communication with the first expansion device (a; 28), and a lower liquid portion (3b), a second expansion device (b; c; d) being in flow communication with the lower liquid portion (3b) of the receiver (3), and a first evaporator (E2; E3);(b) the refrigeration circuit further comprising a further flow path (12; 30) provided between the upper vapour portion (3a) of the receiver (3) and the suction side of a compressor (6) being part of said first compressor device (6), the pressure side of which is in fluid communication with the entrance of said heat-rejecting heat exchanger (1);(c) said refrigeration method comprising at least one step of the group of steps consisting of(i) operating a heat source (24) in said upper vapour portion (3a) of said receiver (3),(ii) operating a heat sink (32) in said lower liquid portion (3b) of said receiver (3), said heat sink (32) being incorporated in said further flow path (30) having a third expansion device (34) upstream of said heat sink (32).
- Refrigeration method according to claim 8, wherein the refrigerant is CO2.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2005/005411 WO2006091190A1 (en) | 2005-02-18 | 2005-02-18 | Refrigeration circuit with improved liquid/vapour receiver |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1848934A1 EP1848934A1 (en) | 2007-10-31 |
| EP1848934B1 true EP1848934B1 (en) | 2016-09-14 |
Family
ID=34993425
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05723391.8A Expired - Lifetime EP1848934B1 (en) | 2005-02-18 | 2005-02-18 | Refrigeration circuit with improved liquid/vapour receiver |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20090019878A1 (en) |
| EP (1) | EP1848934B1 (en) |
| JP (1) | JP2008530511A (en) |
| CN (1) | CN100590372C (en) |
| AU (1) | AU2005327954A1 (en) |
| MX (1) | MX2007010002A (en) |
| WO (1) | WO2006091190A1 (en) |
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| WO2008019689A2 (en) * | 2006-08-18 | 2008-02-21 | Knudsen Køling A/S | A transcritical refrigeration system with a booster |
| JP4811204B2 (en) * | 2006-09-11 | 2011-11-09 | ダイキン工業株式会社 | Refrigeration equipment |
| JP5196452B2 (en) * | 2007-04-24 | 2013-05-15 | キャリア コーポレイション | Transcritical refrigerant vapor compression system with charge control |
| US8631666B2 (en) | 2008-08-07 | 2014-01-21 | Hill Phoenix, Inc. | Modular CO2 refrigeration system |
| US20120055182A1 (en) | 2008-10-23 | 2012-03-08 | Dube Serge | Co2 refrigeration system |
| CA2724255C (en) * | 2010-09-28 | 2011-09-13 | Serge Dube | Co2 refrigeration system for ice-playing surfaces |
| CH703290A1 (en) * | 2010-09-29 | 2011-12-15 | Erik Vincent Granwehr | Heat pump. |
| DE102011014944B4 (en) * | 2011-03-24 | 2014-08-07 | Airbus Operations Gmbh | Method for operating a cooling system |
| DE102011014943A1 (en) | 2011-03-24 | 2012-09-27 | Airbus Operations Gmbh | Multifunctional refrigerant container and method for operating such a refrigerant container |
| DK177329B1 (en) * | 2011-06-16 | 2013-01-14 | Advansor As | Refrigeration system |
| US9689590B2 (en) | 2012-05-11 | 2017-06-27 | Hill Phoenix, Inc. | CO2 refrigeration system with integrated air conditioning module |
| WO2014179442A1 (en) | 2013-05-03 | 2014-11-06 | Hill Phoenix, Inc. | Systems and methods for pressure control in a co2 refrigeration system |
| US9657969B2 (en) | 2013-12-30 | 2017-05-23 | Rolls-Royce Corporation | Multi-evaporator trans-critical cooling systems |
| JP5865561B1 (en) * | 2014-06-27 | 2016-02-17 | 三菱電機株式会社 | Refrigeration cycle equipment |
| US20170356681A1 (en) * | 2014-12-19 | 2017-12-14 | Carrier Corporation | Refrigeration and heating system |
| CN107036344B (en) | 2016-02-03 | 2021-06-15 | 开利公司 | Refrigerating system, cascade refrigerating system and control method thereof |
| US11125483B2 (en) | 2016-06-21 | 2021-09-21 | Hill Phoenix, Inc. | Refrigeration system with condenser temperature differential setpoint control |
| US11796227B2 (en) | 2018-05-24 | 2023-10-24 | Hill Phoenix, Inc. | Refrigeration system with oil control system |
| US11397032B2 (en) | 2018-06-05 | 2022-07-26 | Hill Phoenix, Inc. | CO2 refrigeration system with magnetic refrigeration system cooling |
| WO2019239587A1 (en) * | 2018-06-15 | 2019-12-19 | 三菱電機株式会社 | Refrigeration cycle device |
| US10663201B2 (en) | 2018-10-23 | 2020-05-26 | Hill Phoenix, Inc. | CO2 refrigeration system with supercritical subcooling control |
| US11209199B2 (en) | 2019-02-07 | 2021-12-28 | Heatcraft Refrigeration Products Llc | Cooling system |
| CN110940119B (en) * | 2019-12-16 | 2021-09-17 | 宁波奥克斯电气股份有限公司 | Refrigerant circulation system and air conditioner under refrigeration mode |
| CN111023362B (en) * | 2019-12-16 | 2021-12-14 | 宁波奥克斯电气股份有限公司 | Refrigerant circulation system and air conditioner in heating mode |
| DK180741B1 (en) * | 2020-04-15 | 2022-02-10 | B Cool As | Method for securing a predetermined temperature in a freezer and in a cold room, and refrigeration system as well as the use of a refrigeration system on board a ship |
| JP7494641B2 (en) * | 2020-08-12 | 2024-06-04 | 株式会社Ihi | Cooling System |
| CN111947355A (en) * | 2020-09-02 | 2020-11-17 | 珠海格力电器股份有限公司 | Purification device and air conditioning unit that separation efficiency is high |
| US12372276B2 (en) | 2021-09-07 | 2025-07-29 | Hill Phoenix, Inc. | Oil management in refrigeration systems |
| US12487017B2 (en) | 2023-06-02 | 2025-12-02 | Hill Phoenix, Inc. | CO2 refrigeration system with supercritical subcooling control |
| CN117073256B (en) * | 2023-08-07 | 2024-06-18 | 同方智慧能源有限责任公司 | Snow field double-temperature-zone refrigerating system |
| CN118324247B (en) * | 2024-02-27 | 2025-09-12 | 北京大学 | Refrigeration and mine water resource utilization system based on transcritical CO2 combined cooling and heating |
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| DE3329661A1 (en) * | 1982-12-14 | 1984-06-14 | VEB Kombinat Luft- und Kältetechnik, DDR 8080 Dresden | Regulation of temperatures, temperature differences or levels in refrigerant circuits |
| NL8303877A (en) * | 1983-11-11 | 1985-06-03 | Grasso Koninkl Maschf | INSTALLATION, SUCH AS COOLING INSTALLATION OR HEAT PUMP. |
| GB8511729D0 (en) * | 1985-05-09 | 1985-06-19 | Svenska Rotor Maskiner Ab | Screw rotor compressor |
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| CN1111689C (en) * | 1997-11-17 | 2003-06-18 | 大金工业株式会社 | Refrigerating apparatus |
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| US7131294B2 (en) * | 2004-01-13 | 2006-11-07 | Tecumseh Products Company | Method and apparatus for control of carbon dioxide gas cooler pressure by use of a capillary tube |
-
2005
- 2005-02-18 AU AU2005327954A patent/AU2005327954A1/en not_active Abandoned
- 2005-02-18 CN CN200580048414A patent/CN100590372C/en not_active Expired - Fee Related
- 2005-02-18 US US11/816,327 patent/US20090019878A1/en not_active Abandoned
- 2005-02-18 WO PCT/US2005/005411 patent/WO2006091190A1/en not_active Ceased
- 2005-02-18 EP EP05723391.8A patent/EP1848934B1/en not_active Expired - Lifetime
- 2005-02-18 JP JP2007556125A patent/JP2008530511A/en not_active Withdrawn
- 2005-02-18 MX MX2007010002A patent/MX2007010002A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008530511A (en) | 2008-08-07 |
| MX2007010002A (en) | 2008-03-19 |
| WO2006091190A1 (en) | 2006-08-31 |
| AU2005327954A1 (en) | 2006-08-31 |
| CN100590372C (en) | 2010-02-17 |
| CN101124441A (en) | 2008-02-13 |
| EP1848934A1 (en) | 2007-10-31 |
| US20090019878A1 (en) | 2009-01-22 |
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