Classifications

• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F28—HEAT EXCHANGE IN GENERAL
  • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
  • F28F27/00—Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus
  • F28F27/02—Control arrangements or safety devices specially adapted for heat-exchange or heat-transfer apparatus for controlling the distribution of heat-exchange media between different channels
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01M—LUBRICATING OF MACHINES OR ENGINES IN GENERAL; LUBRICATING INTERNAL COMBUSTION ENGINES; CRANKCASE VENTILATING
  • F01M5/00—Heating, cooling, or controlling temperature of lubricant; Lubrication means facilitating engine starting
  • F01M5/005—Controlling temperature of lubricant
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
  • F01M—LUBRICATING OF MACHINES OR ENGINES IN GENERAL; LUBRICATING INTERNAL COMBUSTION ENGINES; CRANKCASE VENTILATING
  • F01M5/00—Heating, cooling, or controlling temperature of lubricant; Lubrication means facilitating engine starting
  • F01M5/005—Controlling temperature of lubricant
  • F01M5/007—Thermostatic control
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F28—HEAT EXCHANGE IN GENERAL
  • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
  • F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
  • F28D9/0031—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other
  • F28D9/0043—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the plates having openings therein for circulation of at least one heat-exchange medium from one conduit to another
  • F28D9/005—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the plates having openings therein for circulation of at least one heat-exchange medium from one conduit to another the plates having openings therein for both heat-exchange media

Definitions

• the invention relates to a heat exchanger for the heat exchange between a first fluid and at least a second fluid, comprising a stack of plates. stampings defining a multiplicity of path elements for the first fluid each located between two adjacent plates of the stack, and connected as a whole to at least one inlet and at least one outlet for the first fluid.
• Such heat exchangers are used in particular for cooling an oil in a motor vehicle, for example a hydraulic and / or cooling and / or lubricating oil.
• the object of the invention is to solve the above problem under satisfactory conditions of cost and size.
• the invention relates in particular to a heat exchanger of the kind defined in the introduction, and provides that it further comprises switching means suitable for establishing at least two configurations for the circulation of the first fluid, namely a first configuration in which all of the Path elements are traversed in parallel between at least one inlet and at least one outlet and a second configuration in which any path for the first fluid between an inlet and an outlet comprises at least two path elements in series.
• the switching means are sensitive to the temperature of the first fluid.
• the switching means are suitable for passing the exchanger from the first configuration to the second configuration in response to an increase in the temperature of the first fluid and vice versa.
• At least two inputs and / or at least two outputs are provided for the first fluid, and the switching means are capable of closing at least one input and / or at least one output in one configuration and releasing them in another configuration.
• bypass means are provided, the activation of which enables the first fluid to not travel through any of said path elements.
• the bypass means are activated by an increase in the pressure of the first fluid.
• the bypass means are activated by a variation in the temperature of the first fluid.
• the bypass means are activated within a determined temperature range and deactivated outside this range.
• the switching means are adapted to change the circulation configuration of the first fluid when crossing a temperature limit included in said range.
• the bypass means include a movable element, under the effect of the temperature and pressure of the first fluid, between a deactivation position in which it closes a bypass passage for the latter and an activation position in which it frees said passage.
• the path elements form at least two sub-assemblies in each of which the path elements are connected together at their two ends so as to be traversed in parallel by the first fluid, said sub-assemblies being mutually connected in parallel in the first configuration and in series in the second configuration.
• the path elements form two sub-assemblies and the heat exchanger has two inlets and two outlets, a first inlet being in connection with a first end of a first subset, the second inlet and a first outlet being in connection with a first end of the second sub-assembly, the second outlet being in connection with the second ends of the two sub-assemblies, and the switching means being suitable for closing the first outlet and for releasing the second inlet and the second outlet in a first configuration and vice versa in the second configuration, the first entry being released in both configurations.
• the path elements form three sub-assemblies and the heat exchanger has two inlets and two outlets, a first inlet being in connection with a first end of a first sub-assembly, the second inlet being in connection with a first end of a second sub-assembly and with a first end of the third ' sub-assembly, a first outlet being in connection with the second end of the third sub-assembly, the second outlet being in connection with the second ends of the first and second sub-assemblies, and the switching means being suitable for releasing the second input and the second output in a first configuration and for closing them in the second configuration, the first input and the first output being released in the two configurations.
• the invention also relates to the use of a heat exchanger as defined for adjusting the temperature of an oil in a motor vehicle.
• Figure 1 is a top view of a heat exchanger according to the invention for adjusting the temperature of the lubricating oil of the heat engine of a motor vehicle, comprising a stack of stamped plates and an auxiliary housing.
• Figures 2 to 5 are sectional views along lines II-II to VV respectively of the stack of the heat exchanger of Figure 1.
• Figure 6 is a perspective view of a variant of the auxiliary housing the heat exchanger.
• Figures 7 to 10 are views in axial section of a bypass device housed in the housing of Figure 6, in different operating positions.
• Figures 11 and 12 are views in axial section of a switching device housed in the housing of Figure 6, in different operating positions.
• FIG. 13 to 15 are schematic representations illustrating switching means usable in a heat exchanger according to the invention.
• FIG. 16 is a graph showing variations in temperature of fluids in a motor vehicle.
• Figure 17 is a top view of another heat exchanger according to the invention.
• FIG. 18 and 19 are perspective views of a variant of the heat exchanger of Figure 17, respectively without and with its auxiliary housing.
• FIG. 20 is a sectional view along line XX-XX of FIG. 17.
• FIG. 21 is a side view of the heat exchanger of FIG. 19.
• FIG 22 is a sectional view along the line XXII-XXII of Figure 21.
• the heat exchanger shown in Figure 1 is intended to be juxtaposed with the engine of a motor vehicle to adjust the temperature of the engine lubricating oil, by heat exchange with an engine coolant.
• the term "top" of the heat exchanger is used here to refer to the face of the latter facing away from the engine, although this face is in reality not necessarily facing upwards.
• the heat exchanger 1 illustrated comprises a stack 2 of stamped sheet metal plates and an auxiliary box 3 adjacent to the lower end of the stack 2 and intended to be attached to the not shown engine of the vehicle.
• the stack 2 comprises a multiplicity of pairs of plates, each pair being formed of two plates 4, 5 having different stamping configurations, the two plates of the same pair delimiting between them a path element 6 for the oil, and two adjacent plates 4, 5 belonging to different pairs delimiting between them a path element 7 for the cooling fluid.
• the plates 4, 5 have the same substantially rectangular outline, elongated in the left-right direction of FIG. 1.
• the plate 4-1 situated at the lower end of the stack 2 is pierced with two openings 10, 11 located near its left edge and two openings 12, 13 located near its right edge, respectively opposite the openings 10.
• the upper end of the stack consists of a plate 4-2 which has no opening and therefore forms a continuous wall of the exchanger. All the intermediate plates between the end plates 4-1 and 4-2, with the exception of a plate 4-3, have openings in alignment with the opening 10, defining a vertical channel 20 -1 below the plate 4-3 and a vertical channel 20-2 above it. All the intermediate plates without exception have openings opposite the openings 12 and 13, defining vertical channels 21 and 22 over the entire height of the stack.
• All the intermediate plates except for a plate 4-4 have openings in alignment with the opening 13, defining a vertical channel 23-1 below the plate 4-4 and a vertical channel 23- 2 above it.
• the plates of the stack delimit twelve path elements 6, namely two path elements between the plates 4-1 and 4-4, four path elements between the plates 4-4 and 4 -3 and four path elements between plates 4-3 and 4-2.
• Appropriate soldering of the edges of the openings of the plates 4, 5 prevents any communication between the channels 20 to 23 and the path elements 7 intended for the coolant.
• tubes extending over part of the height of certain channels, where they are brazed to the edges of the openings prevent any communication of fluid between these channels and the path elements 6 adjacent to the wall of the tubes.
• a tube 31 extends in the channel 21 from the plate 4-1 to the plate 4-3
• a tube 32 extends in the channel 22 between the plate 4-1 and the plate 4-4.
• the openings 10 and 11 constitute inlets for the oil coming from the engine via the housing 3, and the openings 12 and 13 constitute outlets for the oil towards the engine via the housing 3, the openings 11 and 13 can be closed, depending on the oil temperature, by switching means housed in the housing 3.
• the openings 11 and 13 are open.
• the oil then simultaneously enters the channel 20-1 through the opening 10, to reach the path elements 6 located below the plate 4-3, and in the channel 21, through the opening 11, to reach the path elements 6 located above the plate 4-3.
• the fluid then circulates in parallel in all of the path elements 6, from the left to the right of FIGS. 1 to 3, as shown by arrows in FIG. 3.
• the oil having circulated in the path elements located at the above the plate 4-4 then borrows the channel 22 and leaves through the opening 12, while the oil having circulated below the plate 4-4 borrows the channel 23-1 and leaves through the opening 13
• the oil therefore circulates in the exchanger in a single pass, with a reduced pressure drop despite its high viscosity.
• the switching means close the openings 10 and 12.
• the tube 31 leads the oil into the part of the channel 21 located above the plate 4-3, from which it flows from left to right in the path elements located above the plate 4-3. It then borrows channels 22 and 23-2 to reach the path elements located between plates 4-3 and 4-4, where it flows from right to left.
• Through channel 20-1 the oil passes from these latter path elements to those located below the plate 4-4, where they flow from left to right, to reach channel 23-1 and exit by the opening 13 , .. ⁇ (_ (X_ circulation in three passes, illustrated by
• the plate 4-2 has two openings 14, 15 located respectively near the right and left edges thereof, as seen in Figures 1 to 3. All the intermediate plates, excluding the end plate 4 -1, have openings aligned with the openings 14 and 15, defining vertical channels 24, 25 extending over the entire height of the stack. Appropriate armours of edges of the openings prevent any communication of fluid between the channels 24, 25 and the path elements 6 intended for the oil.
• an inlet pipe 34 surrounding the opening 14 and projecting from the upper face of the stack 2 the cooling fluid enters the channel 24, then it flows from right to left in parallel in all of the elements. path 7. It thus reaches the channel 25 and leaves the exchanger by an outlet pipe 35 surrounding the opening 15 and projecting from the upper face of the stack.
• the coolant therefore circulates in one pass, counter-current to the oil in the configuration where the latter circulates in a single pass, and counter-current to two of the three passes when the oil circulates in three passes.
• FIG. 6 represents an auxiliary box 40 intended to form part of a heat exchanger according to the invention, and to be interposed between the stack of plates of the latter and the heat engine of the vehicle.
• the housing 40 has an inlet pipe 41 and an outlet pipe 42 for the engine coolant, which replace the pipes 34 and 35 previously described.
• the openings 14 and 15 are replaced by openings not shown formed in the plate 4-1, which communicate with openings 43, 44 provided on the upper face of the housing.
• the pipes 41 and 42 project in turn on a side face of the housing and do not increase the overall height of the heat exchanger.
• the following description of the housing 40 also applies to the housing 3.
• the housing 40 has an inlet opening and an outlet opening for the oil, located on the underside of the housing and not visible in the figure, and four communication openings 45, 46, 47, 48 communicating respectively with the openings 10, 11, 12 and 13. Passages are provided inside the housing between the inlet opening and the outlet opening, between the inlet opening and the openings 45 and 46, and between openings 47 and 48 and the outlet opening.
• the passage between the inlet opening and the outlet opening can be opened or closed by bypass means 50 housed in the housing.
• the passages connecting the inlet opening to the opening 10 and the opening 12 to the outlet opening can be opened and closed jointly by switching means housed in the housing, and the passages connecting the opening inlet to opening 11 and opening 13 to outlet opening are always open.
• the bypass means and the switching means are described below.
• the bypass device shown in FIGS. 7 to 10 comprises several moving parts inside a cavity 51 elongated along an axis A1, delimited laterally by a tubular sheath 52 and closed at one end by a plug 53. opposite the plug 53, the cavity 51 is extended by an axial channel 54 of smaller diameter which communicates with the oil outlet opening of the housing 40. The cavity 51 also communicates with the oil inlet opening by openings 55 passing through the wall of the sheath 52.
• an expansion capsule formed of a cup 56 filled with a substance with a high coefficient of expansion and a rod guided along the axis Al, which projects from the cup over a length which varies according to the volume of the expandable substance.
• the rod 57 is turned away from the plug 53, and is capped with a cover 58 which extends it axially beyond its free end and which has, in the vicinity of the cup 56, a flange 59 extending radially towards outside to the vicinity of the sheath 52.
• the cavity 51 also contains, beyond the end of the cover 58 turned away from the cup 56, a plug 60 having a flange 61 turned radially outwards .
• the bucket 56 also has a flange 62 facing radially outward.
• a helical spring 63 is compressed between the plug 53 and the flange 62.
• FIG. 7 shows the bypass device 50 at rest, that is to say when the rod 57 is fully retracted at room temperature and there is no oil pressure in the device.
• the spring 66 applies the flange 61 against the flange 65 preventing the passage of oil to the right of the latter along the cavity and isolating the channel 54 from the openings 55.
• the bypass device is therefore closed and the oil circulates in the path elements 6 of one heat exchanger as described above.
• the spring 63 urges the flange 62 so as to apply the end of the cover 58 against the plug 60.
• a rise in the temperature of the oil has the effect of causing the rod 57 to come out of the bucket 56, increasing the distance between the free end of the cover 58, which rests on the plug 60, and the flange 62.
• the force exerted by the spring 63 being greater than that exerted by the spring 66, the latter compresses, once again allowing the plug 60 to release the opening delimited by the flange 65, as shown in FIG. 9.
• the oil is conveyed directly from the inlet to the outlet of the exchanger without passing through the path elements 6.
• the switching device 70 shown in Figures 11 and 12 comprises a body 71 elongated along an axis A2 and pierced with an axial bore which is closed at one end by a plug 72.
• the axial bore is divided in its length in three parts, namely a first part 73 adjacent to the plug 72, a second part 74 of smaller diameter than the part 73, connected to the latter by a radial shoulder 75, and a third part 76 of smaller diameter than the part 74 , connected thereto by a radial shoulder 77.
• an expansion capsule similar to that of the device of FIGS. 7 to 10, comprising a cup 78 and a sliding rod 79.
• the rod 79 is integral with a hollow piston 80 in sealed sliding contact with the wall of the part 73 of the bore and which is provided with an axial appendage 81 extending the rod 79 in the direction of the plug 72.
• Each of the appendages 81, 82 carries in the vicinity of its free end a stop washer 83, 84.
• a helical spring 85 is compressed between the washer 83 and the end of the piston 80 facing the plug 72.
• a helical spring 86 is compressed between this plug and the same end of the piston.
• a helical spring 87 is compressed between the washer 84 and the end of the piston 80 facing away from the plug 72.
• a helical spring 88 surrounding the cup 78 inside the piston 80, is compressed between the wall d end of the latter facing away from the plug, which has a central opening 90 in which the bucket slides, and a flange 89 facing radially outwards from the bucket 78.
• FIG. 11 shows the state of the device at ambient temperature, the rod 79 being retracted.
• the spring 86 urges the piston 80 opposite the plug 72, that is to say towards the bottom of the figure, applying its lower end against the shoulder 75.
• the washer 83 urged upwards by the spring 85, remains at a distance from the plug 72, allowing communication between the bore part 73 and a drilled channel 92 in the cap.
• the washer 84 biased downwards by the spring 87, remains distant from the shoulder 77, allowing communication between the bore parts 74 and 76.
• the oil circulates between the channel 92, connected to the inlet opening 47 and therefore at the outlet opening 12 of the stack 2, and the bore portion 73, connected to the oil outlet of the housing 40.
• the oil circulates in a single pass in the stack 2 as explained previously.
• the bucket 78 slides downward relative to the piston 80, bringing the washer 84, pushed by the spring 87, bearing on the shoulder 77 and interrupting the communication between the parts 74. and 76.
• the spring 87 then raises the piston 80, bringing the washer 83, under the thrust of the spring 85, bearing on the plug 72, also interrupting the communication between the channel 92 and the bore part 73.
• the openings 10 and 12 of the stack 2 are therefore blocked, and the oil circulates in the latter in three passes as described above.
• FIG. 13 and 14 schematically illustrate the switching means in the form of two valves 101, 102, the first being interposed between the oil supply 103 to the heat exchanger and the inlet opening 10 of the stack 2, and the second between the outlet opening 12 and the oil flow 104 from the exchanger.
• the two valves are open and the oil circulates in one pass in the path elements 6.
• the two valves are closed and the oil circulates in three passes.
• Valves 101 and 102 can be solenoid valves controlled as a function of the oil temperature.
• FIG. 15 illustrates a switching device comprising an expansion capsule, the cup 105 of which is fixed and the rod of which carries two valves 107, 108 cooperating respectively with two seats 109, 110 to control access to the inlet and outlet openings 10, 12. Between the valves 107 and 108, the rod 106 is .tightly guided through a wall 111 of the auxiliary housing separating the oil inlet and outlet circuits.
• FIG. 16 shows how the invention makes it possible to optimize the evolution of the temperature of the lubricating oil of the heat engine of a motor vehicle.
• Curves C1, C2 and C3 represent temperature variations from the start of the engine following a prolonged stop, the engine and the associated fluids being at ambient temperature (20 ° C).
• Curve C1 relates to the engine coolant. It comprises a first ascending branch Cl-1 corresponding to the heating of the fluid without passage through the cooling radiator, followed by a horizontal branch Cl-2 corresponding to maintaining the fluid at an optimal temperature, here of the order of 90 ° C, using the cooling radiator.
• Curve C2 represents the evolution of the temperature of the oil obtained using a heat exchanger according to the state of the art.
• a first ascending part C2-1 corresponds to the heating of the oil in the absence of heat exchange with the cooling fluid, at least one of these two fluids not circulating in the exchanger.
• the temperature of the oil increases more slowly than that of the cooling fluid, and later reaches the temperature of the part of curve Cl-2, which it then exceeds to reach an optimal value, here slightly higher than 100 ° C.
• This optimum value is maintained (part of the horizontal curve C2-2) by heat exchange with the cooling fluid, which itself has a lower temperature.
• the means of bypassing the heat exchanger according to the invention make it possible to carry out a heat exchange between the two fluids not only when the oil has reached its optimum temperature but also as long as its temperature is lower than that of the coolant, resulting in rapid initial heating and earlier achievement of the optimum temperature.
• This initial heating phase corresponds to part C3-1 of curve C3, which continues up to the temperature level of the cooling fluid represented by part of curve C1-2.
• the bypass means are activated to interrupt the heat exchange between the two fluids and not to slow down the heating of the oil. As the latter is no longer in contact with a hotter fluid than it, the slope of the curve decreases somewhat (part C3-2).
• the optimal temperature here around 120 ° C, the bypass means are deactivated again to allow the oil to transfer heat to the coolant, its temperature then oscillating around this optimal value (part C3- 3).
• the heat exchanger 120 shown in FIGS. 17 and 20 comprises a stack 121 formed of pairs of stamped plates 122, 123 similar to the pairs of plates 4, 5 previously described.
• the exchanger 120 also comprises inlet and outlet pipes projecting with respect to the same end plate 122-1, turned upwards in FIG. 20.
• An inlet pipe 124 and an outlet pipe 125 for the coolant are located respectively near the left and right edges of the stack, as seen in Figure 17, facing each other in the left-right direction.
• a first oil inlet pipe 126 penetrates into the stack 121 vertically, as seen in FIG.
• a second oil inlet pipe comprises an annular part 128 adjacent to the plate 122-1 and sealingly surrounding the base of the pipe 126, and an inclined tubular part 129.
• a first oil outlet opening 130 extends vertically upward, in Figure 20, from there. plate 122-1, in the vicinity of the right edge of the stack and opposite the tube 126.
• a second oil outlet tube 131 similar to the tube 130, is located near the left edge of the stack.
• the channel 127 outside of tubing 126 connects the path elements 135 to the oil located above 'the plate 122-2 with the tubing 128, 129.
• openings mutually aligned opposite the tubing 130 formed in all the plates except for the plates 122-3 and 123-3, form a channel 137 which makes the tubing 130 communicate with all the elements of path 135.
• the channels 127 and 136 are separated from each other by the tight brazing of the edge of the opening of the plate 122-2 at the end of the tube 126. Openings not shown, arranged opposite of the tubing 131 in the plates situated above the plate 122-2, form a channel which makes the corresponding path elements 135 communicate with the tubing 131.
• Switching means are provided to allow the passage of the oil in the pipes 128, 129 and 130 exclusively at low temperature, and in the pipe 131 exclusively at high temperature, the passage in the pipe 126 being always free.
• the oil simultaneously penetrates through the tubing 126 to reach the lower path elements and the tubing 128, 129 to reach the upper path elements. It flows in parallel, from left to right, through all of the path elements 135 to reach the channel 137 and exit through the tube 130.
• the oil penetrates exclusively through the tube 126 / flows in one first pass from channel 136 to channel 137 via the lower path elements 135, then in a second pass from channel 137 to channel 127 using the upper path elements, to exit through the pipe 131.
• FIG. 18 represents the stack 120 of FIGS. 17 and 20, fitted with pipes 124, 125 for entering and leaving the cooling fluid.
• Tubing 128, 129, 130 and 131 are removed, and tubing 126 is replaced by tubing 140 which only protrudes slightly from plate 122-1.
• Figures 19, 21 and 22 represent the same assembly on which is mounted a switching device 141 for selectively connecting to the previously described channels an oil inlet port 142 and an oil discharge port 143 provided on the switching device for carrying out the circulation configurations in one pass and in two passes.
• the operation of the device 141 is based on the expansion of a substance contained in a capsule formed by a cup 144 and a sliding rod 45.
• the cup 144 is fixed and the exit of the rod 145 pushes a piston 146, against the action of a helical spring 147, so as to close or release different openings, each of which connects one of the orifices 142 and 143 to one of the channels of stack 120.
• the invention is not limited to a heat exchanger allowing circulation of fluid in two passes or in three passes, such as those described. A number of passes greater than three, even or odd, can also be obtained - with appropriate switching means. Whatever the number of passes, the heat exchanger can be provided or no means of diversion. The second fluid can also circulate in several passes.
• the heat exchanger comprises bypass means which are activated within a determined temperature range
• the switching means it is advantageous for the switching means to act at a temperature within this range, so as to avoid a sudden reversal of the direction of circulation of the fluid in the affected path elements.
• the lower limit of the bypass range is for example 90 ° C and the upper limit between 110 and 130 ° C
• the switching temperature can be chosen at any value between 90 and 110 ° C.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Physics & Mathematics (AREA)
• Thermal Sciences (AREA)
• Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
• Cooling, Air Intake And Gas Exhaust, And Fuel Tank Arrangements In Propulsion Units (AREA)

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• 2004
  • 2004-05-18 FR FR0405422A patent/FR2870589B1/fr not_active Expired - Fee Related
• 2005
  • 2005-05-17 EP EP05771168A patent/EP1747418A1/de not_active Withdrawn
  • 2005-05-17 WO PCT/FR2005/001225 patent/WO2005124260A1/fr not_active Application Discontinuation

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