EP1741494B1 - Process for making a hose, especially a shower hose, with several layers - Google Patents
Process for making a hose, especially a shower hose, with several layers Download PDFInfo
- Publication number
- EP1741494B1 EP1741494B1 EP05014638A EP05014638A EP1741494B1 EP 1741494 B1 EP1741494 B1 EP 1741494B1 EP 05014638 A EP05014638 A EP 05014638A EP 05014638 A EP05014638 A EP 05014638A EP 1741494 B1 EP1741494 B1 EP 1741494B1
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- EP
- European Patent Office
- Prior art keywords
- hose
- particles
- mechanical action
- process according
- inner tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L11/00—Hoses, i.e. flexible pipes
- F16L11/04—Hoses, i.e. flexible pipes made of rubber or flexible plastics
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
Definitions
- the invention relates to a method for producing a hose, in particular a multi-layer shower hose, a device for producing the hose and a hose.
- a shower hose which has several layers.
- the one layer is formed by a so-called inner tube, while an outer layer is formed by a so-called outer tube.
- a coloring is provided between the inner tube and the outer tube.
- the coloring is caused by a color powder, for example with metal pigments or particles.
- the particles are filled in an intermediate region between the inner tube and the outer tube.
- the inner tube is pulled from above through a funnel in which the color pigments are arranged.
- an annular nozzle is arranged, which applies the outer tube.
- the annular nozzle is arranged to the funnel so that small amounts of the color pigments penetrate during the application of the outer tube in the space between the inner tube and the outer tube. The application of the color pigments to the surface of the inner tube and the extrusion of the outer tube takes place in a sense in one step.
- a shower hose can be made quickly with the method described in the document, the result is not always satisfactory for aesthetic reasons.
- the coloring of the shower hose is often very grainy, even if very small diameter color pigments are used.
- the invention has for its object to provide a method, an apparatus for producing a hose and a hose in which the coloring is carried out by color pigments or particles, which are applied in powder form to the inner tube, the coloring should be as fine-grained and uniform smooth.
- the inventive method according to claim 1 differs from that of the document DE 195 11 216 C2 known manufacturing process essentially by the fact that the tube is manufactured in three steps.
- the inventive method is basically by the additional step in which by brushing, rolling, cloth or the like is mechanically acted on the particles adhering to the inner tube particles, consuming.
- the result of this manufacturing process justifies this additional expense.
- the coloring of the shower hose is finer and smoother, even when comparatively large particles are used.
- the method according to the invention it is possible, for example, to use larger particles than in the method as it is known from the document DE 195 11 216 C2 the case is. Since larger particles z. T. easier to handle and are cheaper to buy, the disadvantages are offset by the additional cost of the method according to the invention.
- Another advantage of larger particles is that the surfaces made with these larger particles shine more than the surfaces made with smaller particles.
- the particles could be made of aluminum-coated foil.
- the other aesthetic impression namely the more uniform, smoother and finer-grained coloring of the shower hose is directly linked to the mechanical action on the particles adhering to the inner hose.
- the often used for coloring particles often have the form of microscopic platelets. If these particles are applied by the method disclosed in the cited document, these platelets are filled randomly between the inner tube and the outer tube.
- the tiles are aligned in all possible directions. In part, they are perpendicular to the surface of the Inner tube, in part, they lie parallel to the surface of the inner tube. In between, any angular position of the plates to the inner tube is possible. Due to the mechanical action on the particles adhering to the inner tube, these particles are aligned. The particles are then substantially parallel to the surface of the inner tube. This results in the overall more uniform, smoother and finer-grained impression of the shower hose produced by the production method according to the invention.
- the surface of the inner tube can be heated with a heater prior to the application of the particles.
- the surface can be heated to a typical for the material of the inner tube temperature at which the surface of the tube is viscous or plastically deformable.
- an adhesive or the like is applied to the surface of the inner tube before the application of the particles. With an adhesive, however, there may be the risk that it will clump after the application of the particles, in particular during the mechanical action.
- the inner tube for applying the particles is drawn through a bath with the particles. It is also possible that the particles are sprayed or inflated onto the surface of the inner tube.
- the mechanical action on the particles adhering to the inner tube takes place.
- the mechanical action can be done for example by a pressure medium, for example by compressed air.
- the inner tube with the particles adhering to it can from the pressure medium be streamed.
- the particles can be acted upon by brushes, rollers, cloths or the like.
- the hose can be acted on as often as desired mechanically.
- a mechanical action is always recommended in particular when the inner tube provided with the particles has made contact with another object, for example a deflection roller.
- depressions are pressed into the surface of the inner tube with one or more punches.
- a device according to the invention for producing a hose, in particular a shower hose, with which preferably the aforementioned method can be carried out comprises a container for a bath of particles, through which an inner hose can be pulled.
- the container has an inlet opening and an outlet opening from the then provided with the particle inner tube can exit.
- the container can rotate and / or be vibrated by a vibrator.
- the container may be a slanted cylinder which is traversed longitudinally by the inner tube.
- the device according to the invention has means for the mechanical action on the particles adhering to the inner tube.
- the means for the mechanical action on the adhering to the inner tube particles may include nozzles for a pressure medium, in particular compressed air, which are directed to the inner tube, so that the pressure medium can flow to the inner tube.
- the device according to the invention may alternatively or additionally comprise further means for mechanical action. These may include brushes, rollers, cloths or the like, for example.
- the means for mechanical action may be at least partially made of textiles, leather, foam, soft plastic materials, elastomers, bristles or the like.
- the mechanical action can z. B. be a polishing.
- a mechanical action means for example, it is possible for a mechanical action means to be a spiral brush through which the inner tube is pulled.
- a spiral brush can be set in rotation about its longitudinal axis by means of a drive, whereby the surface of the inner tube and thus of the particles adhering to the inner tube are acted upon tangentially as well as longitudinally while the inner tube is pulled through.
- the nozzles can be arranged in a device according to the invention in the transport direction of the provided with the particles inner tube behind the rotating brush.
- the means for mechanical action are arranged in a housing.
- the housing may have an inlet opening and an outlet opening for the particle-coated tube.
- the inlet opening of the housing is preferably indirectly connected to the outlet opening of the container.
- the connection can be made for example by a cuff.
- a filter may be used, via which a pressure compensation can be made, which is necessary because of the force acting on the inner tube pressure medium. Through the filter, the pressure medium can escape, while possibly entrained by the pressure medium particles adhere to the filter and can be supplied for further use.
- the filter is for this purpose preferably arranged above the container for the particle bath, so that the retained particles can fall into the container.
- the device according to the invention may comprise a container which is funnel-shaped at least in one section.
- a tip of the funnel is preferably directed against the transport direction of the hose and at the top of the inlet opening of the container is provided for the hose.
- a tube produced by the method according to the invention, but also another tube with an inner layer and an outer layer, can be designed in such a way that recesses are provided in an outer surface of the inner layer. These depressions may be impressions, which have been caused for example by one or more stamp.
- the recesses may preferably be arranged regularly and form a pattern.
- the depressions may in particular be circular, annular, drop-shaped, linear, arrow-shaped, cross-shaped, square, rectangular, symbol-like and / or formed as letters or numerals.
- An inventive tube but also another tube may preferably be extruded so that it is a non-circular, z. B. a star-shaped, angular or oval, Cross section has.
- Such a tube may be provided, for example, as an inner tube or as a tube forming the inner layer of a multi-layered tube, wherein the outer layer may have a circular outer edge in cross-section.
- Inventive device has an outer housing 11 with a housing bottom 11a.
- the inner tube to be processed can be introduced via an inlet opening 11b.
- the finished hose can then be led out of the housing.
- a plurality of guide rollers 12 a, 12 b, 12 c are arranged, via which the processing inner tube or the coated inner tube is performed.
- FIGS. 2 to 4 In the transport direction to the inlet opening 11 b is then in the FIGS. 2 to 4 arranged main body of the device according to the invention shown.
- This main part has four to the housing bottom 11 a vertically arranged struts on which the remaining parts of the main part are substantially fixed.
- the tip of a funnel 4 is inserted with play.
- the hopper 14 itself is fixed to a plate 28a which has vibration-permissive elements attached to the housing bottom 11a.
- a vibrator 28 is arranged, which can set the plate 28 a and the funnel 14 in vibration.
- annular brush (not shown) is inserted in the opening 13 at the top of the funnel 14.
- a cuff 15 which is also connected to a slidable on the struts 26 slide 17 via a flange 16.
- the carriage 17 has an adjoining the flange 16 and the sleeve 15 through hole.
- the holding member 18 also has a partially conical through hole, which extends the through hole in the movable carriage 17.
- a lower end of a rotatable cage 29, 30, 31 is inserted, which is formed from a lower ring 29 an upper ring 31 and the two rings 29 and 31 connecting struts 30.
- the lower ring 29 protrudes with a circumferential collar into the upper end of the through hole of the holding part 18 and is sealed relative to the holding part 18.
- the holding part 18 can likewise be movable on the struts 26 in order to enable a change of a filter element 19 arranged in the cage 28, 30, 31.
- the cage 29, 30, 31 receives the filter element 19.
- This filter element 19 is impermeable to particles, but allows air or other gases to pass through.
- the filter element 19 has a substantially circular cross-section, however, the side wall of the filter element 19 is preferably folded several times, so that there is an approximately star-shaped cross-sectional shape of the filter element 19.
- a pipe socket 33 is arranged, which is attached at one end to the upper ring 31 and extends into the region of the lower ring 29. However, a small gap remains between the lower end of the pipe socket 33 and the inner diameter of the lower ring 29.
- the through hole of the bearing neck 35 widens conically at its upper end.
- a complementarily shaped cone 22 is used, wherein between the cone 22 and the conical extension of the through bore of the bearing stub 35 an annular gap remains, which is connected to a compressed air connection (not shown) and forms an annular nozzle.
- the cone 22 has a central through-hole, which continues the through-bore of the bearing neck 35 from its tapered region.
- an electric motor 25 is fixed, whose shaft passes through a hole in the end plate and can drive a drive ring 33 via a belt 24, which is fixedly connected to the sleeve 20.
- the sleeve 20 and all the parts fixedly connected thereto such as the cage 29, 30, 31, the filter element 29, the pipe socket 33 and the spiral brush 32 arranged in the pipe socket, can be driven, the sleeve 20, the cage 29, 30, 31, the filter element 19, the holding part 18, the carriage 17 and the end plate 27, moreover, together form an inner housing, to which reference is also made in the claims.
- the so-called inner tube is guided via the inlet opening 11b in the housing bottom 11a of the outer housing 11 into the tip 13 of the funnel 14. Before that is the surface of the inner tube (Bzz. 1, Fig. 5 ) Was heated by means of a heater so far that the surface is plastically deformable.
- the particles are filled, with which the tube to be produced is then colored.
- the carriage 17 can be moved downwards, whereby the particles can be filled into the funnel 14 from above through the passage opening of the carriage 17 and the sleeve 16.
- the heated inner tube 1 takes in the funnel 14 with its outer surface on the particles and leads them on its way up with it.
- the inner tube 1 with the adhering particles is guided through the sleeve 15, through the carriage 17 to the holding part 18. From the holding part 18, the inner tube is guided further upwards through the bearing neck 35 by the rotating spiral brush 32.
- the inner tube with the adhering particles, from the compressed air emerging from the annular nozzle is irradiated.
- the surface with the adhering particles undergoes a two-stage mechanical aftertreatment.
- the rotating spiral brush 32 on the surface with the adhering particles.
- the particles are thereby aligned relative to the surface of the inner tube. If necessary, too much applied particles are removed.
- the compressed air exerted on the inner tube with the adhering particles is acted upon in the annular nozzle by the compressed air emerging from the annular nozzle. Loose or loose particles adhering to the surface of the inner tube are blown away by the compressed air and conveyed against the transport direction of the hose down.
- the compressed air carries the particles down with them.
- the particles are accelerated downwardly by the compressed air to be fed to the hopper 14 so that they are available for further processing. So that no excessively high overpressure arises within the device 1, the supplied compressed air must be removed from the interior of the outer housing 11. The purpose of the remaining between the pipe socket 33 and the lower ring 29 gap. The compressed air can be deflected at this gap by about 180 ° upwards, with the entrained particles continue to fly down due to their inertia. The compressed air then comes to the overpressure side of the filter element 19 and is pressed by the filter element 19. Any particles still entrained are held in the filter 19.
- a means of the device according to the Fig. 1 to 4 provided with particles inner tube 1 is then provided with an outer layer 3, the so-called outer tube 3. Between this outer tube 3 and the inner tube 1, the particles 2 are arranged in a further, middle layer, as in Fig. 5 is shown.
- the inner tube 1 may have a fabric insert to increase the compressive strength.
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Herstellen eines Schlauches, insbesondere eines Brauseschlauchs aus mehreren Schichten, eine Vorrichtung zum Herstellen des Schlauchs und einen Schlauch.The invention relates to a method for producing a hose, in particular a multi-layer shower hose, a device for producing the hose and a hose.
Aus der Druckschrift mit der Veröffentlichungsnummer
Zur Herstellung eines derartigen Schlauchs wird der Innenschlauch von oben durch einen Trichter gezogen, in welchem die Farbpigmente angeordnet sind. Unterhalb des Trichters ist eine Ringdüse angeordnet, welche den Außenschlauch aufträgt. Dabei ist die Ringdüse zu dem Trichter so angeordnet, dass geringfügige Mengen der Farbpigmente während des Auftragens des Außenschlauchs in den Zwischenraum zwischen dem Innenschlauch und dem Außenschlauch eindringen. Das Auftragen der Farbpigmente auf die Oberfläche des Innenschlauchs und das Aufextrudieren des Außenschlauchs erfolgt gewissermaßen in einem Arbeitsschritt.To produce such a tube, the inner tube is pulled from above through a funnel in which the color pigments are arranged. Below the funnel an annular nozzle is arranged, which applies the outer tube. In this case, the annular nozzle is arranged to the funnel so that small amounts of the color pigments penetrate during the application of the outer tube in the space between the inner tube and the outer tube. The application of the color pigments to the surface of the inner tube and the extrusion of the outer tube takes place in a sense in one step.
Zwar kann mit dem in der Druckschrift beschriebenen Verfahren ein Brauseschlauch schnell hergestellt werden, das Ergebnis ist aus ästhetischen Gründen jedoch nicht immer befriedigend. So wirkt die Einfärbung des Brauseschlauchs oft sehr grobkörnig, auch wenn Farbpigmente mit sehr kleinem Durchmesser verwendet werden.Although a shower hose can be made quickly with the method described in the document, the result is not always satisfactory for aesthetic reasons. For example, the coloring of the shower hose is often very grainy, even if very small diameter color pigments are used.
Gewünscht wird jedoch häufig eine Einfärbung die möglichst feinkörnig und gleichmäßig erscheint. Mit dem in der Druckschrift beschriebenen Herstellungsverfahren und der dort angedeuteten Vorrichtung zur Herstellung eines solchen Brauseschlauchs ist eine feinkörnige und möglichst gleichmäßige glatte Einfärbung nicht herstellbar.However, often desired is a coloring which appears as fine-grained and uniform. With the manufacturing method described in the document and the device indicated therein for producing such a shower hose, a fine-grained and as uniform as possible smooth coloring can not be produced.
Hier setzt die vorliegende Erfindung an.This is where the present invention begins.
Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren, eine Vorrichtung zur Herstellung eines Schlauchs und einen Schlauch vorzuschlagen, bei dem die Einfärbung durch Farbpigmente beziehungsweise Partikel erfolgt, die pulverförmig auf den Innenschlauch aufgetragen werden, wobei die Einfärbung möglichst feinkörnig und gleichmäßig glatt sein soll.The invention has for its object to provide a method, an apparatus for producing a hose and a hose in which the coloring is carried out by color pigments or particles, which are applied in powder form to the inner tube, the coloring should be as fine-grained and uniform smooth.
Diese Aufgabe wird durch das erfindungsgemäße Verfahren nach Anspruch 1, durch eine erfindungsgemäße Vorrichtung nach Anspruch 11 und durch einen Schlauch nach Anspruch 24 gelöst.This object is achieved by the inventive method according to
Das erfindungsgemäße Verfahren nach Anspruch 1 unterscheidet sich von dem aus der Druckschrift
Das erfindungsgemäße Verfahren ist im Grunde durch den zusätzlichen Schritt, in dem durch Bürsten, Rollen, Lappen oder dergleichen mechanisch auf die an dem Innenschlauch anhaftenden Partikel eingewirkt wird, aufwändiger. Das Ergebnis dieses Herstellungsverfahrens rechtfertigt jedoch diesen zusätzlichen Aufwand. Die Einfärbung des Brauseschlauchs ist feinkörniger und gleichmäßiger glatt, selbst wenn vergleichsweise große Partikel verwendet werden. Durch das erfindungsgemäße Verfahren ist es beispielsweise möglich, größere Partikel zu verwenden als bei dem Verfahren, wie es aus der Druckschrift
Die Partikel könne aus einer aluminiumbedampften Folie hergestellt sein.The particles could be made of aluminum-coated foil.
Der andere ästhetische Eindruck, nämlich die gleichmäßigere, glattere und feinkörnigere Einfärbung des Brauseschlauchs ist unmittelbar mit der mechanischen Einwirkung auf die an dem Innenschlauch anhaftenden Partikel verknüpft. Die zum Einfärben oft verwendeten Partikel haben oft die Form von mikroskopisch kleinen Plättchen. Werden diese Partikel nach dem in der genannten Druckschrift offenbarten Verfahren aufgebracht, sind diese Plättchen ungeordnet zwischen dem Innenschlauch und dem Außenschlauch eingefüllt. Die Plättchen sind in alle möglichen Richtungen ausgerichtet. Zum Teil stehen sie senkrecht zu der Oberfläche des Innenschlauchs, zum Teil liegen sie parallel an der Oberfläche des Innenschlauchs an. Dazwischen ist jede beliebige Winkelstellung der Plättchen zum Innenschlauch möglich. Durch das mechanische Einwirken auf die an dem Innenschlauch anhaftenden Partikel werden diese Partikel ausgerichtet. Die Partikel liegen dann im Wesentlichen parallel zur Oberfläche des Innenschlauchs. Dadurch entsteht der insgesamt gleichmäßigere, glattere und feinkörnigere Eindruck des nach dem erfindungsgemäßen Herstellungsverfahren hergestellten Brauseschlauchs.The other aesthetic impression, namely the more uniform, smoother and finer-grained coloring of the shower hose is directly linked to the mechanical action on the particles adhering to the inner hose. The often used for coloring particles often have the form of microscopic platelets. If these particles are applied by the method disclosed in the cited document, these platelets are filled randomly between the inner tube and the outer tube. The tiles are aligned in all possible directions. In part, they are perpendicular to the surface of the Inner tube, in part, they lie parallel to the surface of the inner tube. In between, any angular position of the plates to the inner tube is possible. Due to the mechanical action on the particles adhering to the inner tube, these particles are aligned. The particles are then substantially parallel to the surface of the inner tube. This results in the overall more uniform, smoother and finer-grained impression of the shower hose produced by the production method according to the invention.
Bei einem erfindungsgemäßen Verfahren kann vor dem Auftragen der Partikel die Oberfläche des Innenschlauchs mit einer Heizung aufgeheizt werden. Die Oberfläche kann dabei auf eine für das Material des Innenschlauchs typische Temperatur erhitzt werden, bei welcher die Oberfläche des Schlauchs viskos oder plastisch verformbar wird. Ebenso ist es möglich, dass auf die Oberfläche des Innenschlauchs vor dem Auftragen der Partikel ein Klebstoff oder ähnlichem aufgetragen wird. Bei einem Klebstoff kann jedoch die Gefahr bestehen, dass dieser nach dem Auftrag der Partikel, insbesondere während des mechanischen Einwirkens, verklumpt.In a method according to the invention, the surface of the inner tube can be heated with a heater prior to the application of the particles. The surface can be heated to a typical for the material of the inner tube temperature at which the surface of the tube is viscous or plastically deformable. It is also possible that an adhesive or the like is applied to the surface of the inner tube before the application of the particles. With an adhesive, however, there may be the risk that it will clump after the application of the particles, in particular during the mechanical action.
Vorzugsweise wird der Innenschlauch zum Auftragen der Partikel durch ein Bad mit den Partikeln gezogen. Ebenso ist es möglich, dass die Partikel auf die Oberfläche des Innenschlauchs aufgesprüht beziehungsweise aufgeblasen werden.Preferably, the inner tube for applying the particles is drawn through a bath with the particles. It is also possible that the particles are sprayed or inflated onto the surface of the inner tube.
Nach dem Auftragen der Partikel findet das mechanische Einwirken auf die an dem Innenschlauch anhaftenden Partikel statt. Das mechanische Einwirken kann beispielsweise durch ein Druckmedium zum Beispiel durch Druckluft erfolgen. Der Innenschlauch mit den daran anhaftenden Partikeln kann dazu von dem Druckmedium angeströmt werden. Alternativ oder zusätzlich kann durch Bürsten, Rollen, Lappen oder dergleichen auf die Partikel eingewirkt werden.After the particles have been applied, the mechanical action on the particles adhering to the inner tube takes place. The mechanical action can be done for example by a pressure medium, for example by compressed air. The inner tube with the particles adhering to it can from the pressure medium be streamed. Alternatively or additionally, the particles can be acted upon by brushes, rollers, cloths or the like.
Durch die mechanische Einwirkung können z. B. nicht unmittelbar an dem Innenschlauch anhaftende Partikel zum Teil entfernt werden. Damit ist es möglich, den Verbrauch der Partikel pro Längeneinheit des Schlauches zu reduzieren.Due to the mechanical action z. B. not directly on the inner tube adhering particles are partially removed. This makes it possible to reduce the consumption of the particles per unit length of the hose.
Auf den Schlauch kann im Grunde beliebig oft mechanisch eingewirkt werden. Ein mechanisches Einwirken ist insbesondere immer dann empfehlenswert, wenn der mit den Partikeln versehene Innenschlauch Kontakt mit einem anderen Gegenstand, zum Beispiel einer Umlenkrolle hatte.Basically, the hose can be acted on as often as desired mechanically. A mechanical action is always recommended in particular when the inner tube provided with the particles has made contact with another object, for example a deflection roller.
Gemäß der Erfindung ist es möglich, dass nach dem Erhitzen der Oberfläche des Innenschlauchs und vor oder nach dem Auftragen der Partikel, insbesondere vor oder nach dem mechanischen Einwirken, mit einem oder mehreren Stempeln Vertiefungen in die Oberfläche des Innenschlauchs eingedrückt werden.According to the invention, it is possible that after heating the surface of the inner tube and before or after the application of the particles, in particular before or after the mechanical action, depressions are pressed into the surface of the inner tube with one or more punches.
Eine erfindungsgemäße Vorrichtung zum Herstellen eines Schlauches, insbesondere eines Brauseschlauchs, mit der vorzugsweise das vorgenannte Verfahren durchgeführt werden kann, umfasst einen Behälter für ein Bad aus Partikeln, durch welches ein Innenschlauch gezogen werden kann. Der Behälter hat dazu eine Eintrittsöffnung und eine Austrittsöffnung aus dem dann der mit dem Partikel versehene Innenschlauch austreten kann. Der Behälter kann rotieren und/oder durch einen Vibrator in Schwingungen versetzt werden. Bei dem Behälter kann es sich um einen schräg stehenden Zylinder handeln, der von dem Innenschlauch in Längsrichtung durchlaufen wird. Zusätzlich weist die erfindungsgemäße Vorrichtung Mittel zum mechanischen Einwirken auf die an dem Innenschlauch anhaftenden Partikel auf. Die Mittel zur mechanischen Einwirkung auf die an dem Innenschlauch anhaftenden Partikel können Düsen für ein Druckmedium, insbesondere Druckluft umfassen, welche auf den Innenschlauch gerichtet sind, so dass das Druckmedium den Innenschlauch anströmen kann. Die erfindungsgemäße Vorrichtung kann alternativ oder zusätzlich weitere Mittel zur mechanischen Einwirkung umfassen. Diese können beispielsweise Bürsten, Rollen, Lappen oder dergleichen umfassen. Die Mittel zur mechanischen Einwirkung können zumindest teilweise aus Textilien, Leder, Schaumstoff, weichen Kunststoffmaterialien, Elastomeren, Borsten oder Ähnlichem hergestellt sein. Das mechanische Einwirken kann z. B. ein Polieren sein.A device according to the invention for producing a hose, in particular a shower hose, with which preferably the aforementioned method can be carried out, comprises a container for a bath of particles, through which an inner hose can be pulled. The container has an inlet opening and an outlet opening from the then provided with the particle inner tube can exit. The container can rotate and / or be vibrated by a vibrator. The container may be a slanted cylinder which is traversed longitudinally by the inner tube. In addition, the device according to the invention has means for the mechanical action on the particles adhering to the inner tube. The means for the mechanical action on the adhering to the inner tube particles may include nozzles for a pressure medium, in particular compressed air, which are directed to the inner tube, so that the pressure medium can flow to the inner tube. The device according to the invention may alternatively or additionally comprise further means for mechanical action. These may include brushes, rollers, cloths or the like, for example. The means for mechanical action may be at least partially made of textiles, leather, foam, soft plastic materials, elastomers, bristles or the like. The mechanical action can z. B. be a polishing.
Es ist beispielsweise möglich, dass ein Mittel zur mechanischen Einwirkung eine Spiralbürste ist, durch welche der Innenschlauch gezogen wird. Eine solche Spiralbürste kann mittels eines Antriebs um ihre Längsachse in Rotation versetzt werden, wodurch bei gleichzeitigem Durchziehen des Innenschlauchs sowohl tangential als auch in Längsrichtung auf die Oberfläche des Innenschlauchs und somit auf die an dem Innenschlauch anhaftenden Partikel eingewirkt wird.For example, it is possible for a mechanical action means to be a spiral brush through which the inner tube is pulled. Such a spiral brush can be set in rotation about its longitudinal axis by means of a drive, whereby the surface of the inner tube and thus of the particles adhering to the inner tube are acted upon tangentially as well as longitudinally while the inner tube is pulled through.
Die Düsen können bei einer erfindungsgemäßen Vorrichtung in Transportrichtung des mit den Partikeln versehenen Innenschlauchs hinter der rotierenden Bürste angeordnet sein.The nozzles can be arranged in a device according to the invention in the transport direction of the provided with the particles inner tube behind the rotating brush.
Vorzugsweise sind die Mittel zur mechanischen Einwirkung in einem Gehäuse angeordnet. Das Gehäuse kann eine Eintrittsöffnung und eine Austrittsöffnung für den mit den Partikeln beschichteten Schlauch haben. Die Eintrittsöffnung des Gehäuses ist vorzugsweise mittelbar mit der Austrittsöffnung des Behälters verbunden. Die Verbindung kann beispielsweise durch eine Manschette hergestellt sein. In eine Wand des Gehäuses kann ein Filter eingesetzt sein, über den ein Druckausgleich hergestellt werden kann, der wegen des auf den Innenschlauch einwirkenden Druckmediums notwendig ist. Durch das Filter kann das Druckmedium entweichen, während die eventuell von dem Druckmedium mitgeführten Partikel in dem Filter haften bleiben und einer weiteren Verwendung zugeführt werden können. Der Filter ist dazu vorzugsweise oberhalb des Behälters für das Partikelbad angeordnet, so dass die zurückgehaltenen Partikel in den Behälter fallen können.Preferably, the means for mechanical action are arranged in a housing. The housing may have an inlet opening and an outlet opening for the particle-coated tube. The inlet opening of the housing is preferably indirectly connected to the outlet opening of the container. The connection can be made for example by a cuff. In a wall of the housing, a filter may be used, via which a pressure compensation can be made, which is necessary because of the force acting on the inner tube pressure medium. Through the filter, the pressure medium can escape, while possibly entrained by the pressure medium particles adhere to the filter and can be supplied for further use. The filter is for this purpose preferably arranged above the container for the particle bath, so that the retained particles can fall into the container.
Die erfindungsgemäße Vorrichtung kann einen Behälter aufweisen, der zumindest in einem Abschnitt trichterförmig ausgebildet ist. Eine Spitze des Trichters ist dabei vorzugsweise gegen die Transportrichtung des Schlauchs gerichtet und an der Spitze ist die Eintrittsöffnung des Behälters für den Schlauch vorgesehen.
Ein nach dem erfindungsgemäßen Verfahren hergestellter Schlauch aber auch ein anderer Schlauch mit einer inneren Schicht und einer äußeren Schicht kann so ausgestaltet sein, dass in einer äußeren Oberfläche der inneren Schicht Vertiefungen vorgesehen sind. Diese Vertiefungen können Einprägungen sein, die beispielsweise durch einen oder mehrere Stempel hervorgerufen worden sind. Die Vertiefungen können vorzugsweise regelmäßig angeordnet sein und ein Muster bilden. Die Vertiefungen können insbesondere kreisförmig, ringförmig, tropfenförmig, linienförmig, pfeilförmig, kreuzförmig, quadratisch, rechteckig, symbolartig und/oder als Buchstaben bzw. Ziffern ausgebildet sein.The device according to the invention may comprise a container which is funnel-shaped at least in one section. A tip of the funnel is preferably directed against the transport direction of the hose and at the top of the inlet opening of the container is provided for the hose.
A tube produced by the method according to the invention, but also another tube with an inner layer and an outer layer, can be designed in such a way that recesses are provided in an outer surface of the inner layer. These depressions may be impressions, which have been caused for example by one or more stamp. The recesses may preferably be arranged regularly and form a pattern. The depressions may in particular be circular, annular, drop-shaped, linear, arrow-shaped, cross-shaped, square, rectangular, symbol-like and / or formed as letters or numerals.
Ein erfindungsgemäßer Schlauch aber auch ein anderer Schlauch kann vorzugsweise so extrudiert sein, dass er einen nicht-kreisförmigen, z. B. einen sternförmigen, eckigen oder ovalen, Querschnitt hat. Ein derartiger Schlauch kann beispielsweise als Innenschlauch bzw. als einen die innere Schicht eines mehrschichtigen Schlauchs bildender Schlauch vorgesehen sein, wobei die äußere Schicht im Querschnitt einen kreisförmigen äußeren Rand haben kann.An inventive tube but also another tube may preferably be extruded so that it is a non-circular, z. B. a star-shaped, angular or oval, Cross section has. Such a tube may be provided, for example, as an inner tube or as a tube forming the inner layer of a multi-layered tube, wherein the outer layer may have a circular outer edge in cross-section.
Eine erfindungsgemäße Vorrichtung zum Herstellen eines erfindungsgemäßen Schlauchs und ein erfindungsgemäßer Schlauch sind anhand der Zeichnung näher erläutert. Es zeigen
- Fig. 1
- eine Frontansicht der erfindungsgemäßen Vorrichtung mit abgenommener Frontwand,
- Fig. 2
- eine perspektivische Darstellung eines Hauptteils der erfindungsgemäßen Vorrichtung,
- Fig. 3
- eine Rückansicht des Hauptteils gemäß
Fig. 2 , - Fig. 4
- einen Schnitt durch den Hauptteil der Vorrichtung gemäß der Linie IV. in
Fig. 3 und - Fig. 5
- einen Schnitt durch einen erfindungsgemäßen Schlauch.
- Fig. 1
- a front view of the device according to the invention with removed front wall,
- Fig. 2
- a perspective view of a main part of the device according to the invention,
- Fig. 3
- a rear view of the main part according to
Fig. 2 . - Fig. 4
- a section through the main part of the device according to the line IV. In
Fig. 3 and - Fig. 5
- a section through a hose according to the invention.
Erfindungsgemäße Vorrichtung gemäß den
Auf der Außenseite des Gehäuses und innerhalb des Gehäuses sind mehrere Umlenkrollen 12a, 12 b, 12c angeordnet, über welche der zu verarbeitende Innenschlauch bzw. der beschichtete Innenschlauch geführt wird.On the outside of the housing and within the housing a plurality of
In Transportrichtung an die Eintrittsöffnung 11 b anschließend ist der in den
In die Eintrittsöffnung 11 b in dem Gehäuseboden 11 a ist die Spitze eines Trichters 4 mit Spiel eingesetzt. Der Trichter 14 selbst ist an einer Platte 28a befestigt, die über Schwingungen erlaubende Elemente an dem Gehäuseboden 11a befestigt ist. Auf der Oberseite der Platte 28a ist ein Vibrator 28 angeordnet, welcher die Platte 28a und den Trichter 14 in Schwingungen versetzen kann.In the inlet opening 11 b in the housing bottom 11 a, the tip of a
In der Öffnung 13 an der Spitze des Trichters 14 ist eine ringförmige Bürste (nicht dargestellt) eingesetzt.In the
An dem weiten Ende des Trichters 14 schließt sich - in
An den fahrbaren Schlitten schließt sich oberhalb, ebenfalls auf den Streben 26 ruhend, ein Halteteil 18 verfahrbar an. Das Halteteil 18 hat ebenfalls eine zum Teil konische Durchgangsbohrung, die die Durchgangsbohrung in dem verfahrbaren Schlitten 17 verlängert.At the mobile carriage closes above, also resting on the
In das obere Ende dieser Durchgangsbohrung des Halteteils 18 ist ein unteres Endes eines drehbaren Käfigs 29, 30, 31 eingesetzt, der aus einem unteren Ring 29 einem oberen Ring 31 und die beiden Ringe 29 und 31 verbindenden Streben 30 gebildet wird. Der untere Ring 29 ragt mit einem umlaufenden Bund in das obere Ende der Durchgangsbohrung des Halteteils 18 hinein und ist gegenüber dem Halteteil 18 abgedichtet. Das Halteteil 18 kann in einer Ausführung ebenfalls auf den Streben 26 verfahrbar sein, um einen Wechsel eines in dem Käfig 28, 30, 31 angeordneten Filterelements 19 zu ermöglichen.In the upper end of this through hole of the holding
Der Käfig 29, 30, 31 nimmt das Filterelement 19 auf. Dieses Filterelement 19 ist für Partikel undurchdringlich, lässt jedoch Luft oder andere Gase hindurchtreten. Das Filterelement 19 hat einen im Wesentlichen kreisförmigen Querschnitt, die Seitenwand des Filterelements 19 ist jedoch vorzugsweise mehrfach gefaltet, so dass sich eine in etwa sternförmige Querschnittsform des Filterelements 19 ergibt.The
Innerhalb des Filterelements 19 ist ein Rohrstutzen 33 angeordnet, der mit einem Ende an dem oberen Ring 31 befestigt ist und bis in den Bereich des unteren Rings 29 erstreckt. Zwischen dem unteren Ende des Rohrstutzens 33 und dem Innendurchmesser des unteren Rings 29 verbleibt dabei jedoch ein geringer Spalt.Within the
Der obere Ring 31 ist mit einer Hülse 20 fest verbunden, die Hülse 20 ist über zwei Kugellager 34 an einem Lagerstutzen 35 drehbar gelagert. Der Lagerstutzen 35 ist in einer Öffnung einer Abschlussplatte 27 angebracht, die an den oberen Enden der Streben 26 befestigt ist. Der Lagerstutzen 35 weist eine mit mehreren Absätzen versehenen und sich in einen mittleren Bereich verjüngende Durchgangsbohrung auf. Das untere Ende des Lagerstutzens 35 reicht bis an den oberen Ring 31 heran.The
Die Durchgangsbohrung des Lagerstutzens 35 erweitert sich an ihrem oberen Ende konisch. In diese konische Erweiterung ist ein komplementär geformter Konus 22 eingesetzt wobei zwischen dem Konus 22 und der konischen Erweiterung der Durchgangsbohrung des Lagerstutzens 35 ein Ringspalt verbleibt, welcher mit einem Druckluftanschluss (nicht dargestellt) verbunden ist und eine Ringdüse bildet. Der Konus 22 weißt eine zentrale Durchgangsbohrung auf, welche die Durchgangsbohrung des Lagerstutzens 35 ab ihrem verjüngten Bereich fortsetzt.The through hole of the bearing
Auf der Oberseite der Abschlussplatte 27 ist ein Elektromotor 25 befestigt, dessen Welle eine Bohrung in der Abschlussplatte durchgreift und über einen Riemen 24 einen Antriebsring 33 antreiben kann, der fest mit der Hülse 20 verbunden ist. Über den Elektromotor 25 kann somit die Hülse 20 und alle damit fest verbundenen Teile wie dem Käfig 29, 30, 31, dem Filterelement 29, dem Rohrstutzen 33 und in dem Rohrstutzen angeordneten Spiralbürste 32 angetrieben werden die Hülse 20, der Käfig 29, 30, 31, das Filterelement 19, das Halteteil 18, der Schlitten 17 und die Abschlussplatte 27 bilden im Übrigen zusammen ein inneres Gehäuse, auf welches auch in den Ansprüchen Bezug genommen ist.On the top of the
Der so genannte Innenschlauch wird über die Eintrittsöffnung 11b im Gehäuseboden 11a des äußeren Gehäuses 11 in die Spitze 13 des Trichters 14 geführt. Davor ist die Oberfläche des Innenschlauchs (Bzz. 1,
In dem Trichter 14 sind die Partikel eingefüllt, mit welchen der herzustellende Schlauch dann eingefärbt ist. Zum Einfüllen der Partikel kann der Schlitten 17 nach unten gefahren werden, wodurch von oben durch die Durchtrittsöffnung des Schlittens 17 und die Manschette 16 hindurch die Partikel in den Trichter 14 eingefüllt werden können.In the
Der aufgeheizte Innenschlauch 1 nimmt in dem Trichter 14 mit seiner äußeren Oberfläche die Partikel an und führt diese auf seinem Weg nach oben mit sich. Der Innenschlauch 1 mit den anhaftenden Partikeln wird durch die Manschette 15, durch den Schlitten 17 zu dem Halteteil 18 geführt. Von dem Halteteil 18 wird der lnnenschlauch durch die rotierende Spiralbürste 32 weiter nach oben durch den Lagerstutzen 35 hindurchgeführt. Insbesondere im mittleren sich verjüngenden Bereich des Lagerstutzens 35 wird der Innenschlauch mit den anhaftenden Partikeln, von der aus der Ringdüse austretenden Druckluft, angestrahlt.The heated
Mit den anhaftenden Partikeln tritt aus dem Konus über eine Austrittsöffnung 23 aus und wird von dort der Umlenkrolle 12b zugeführt.With the adhering particles emerges from the cone via an
Nach dem Aufbringen der Partikel vibrierenden Trichter 14 erfährt die Oberfläche mit den anhaftenden Partikeln eine zweistufige mechanische Nachbehandlung. So wird zum einen durch die rotierende Spiralbürste 32 auf die Oberfläche mit den anhaftenden Partikeln eingewirkt. Die Partikel werden dadurch relativ zur Oberfläche des Innenschlauchs ausgerichtet. Gegebenenfalls zuviel aufgetragene Partikel werden entfernt. Zum anderen wird in der Ringdüse durch die aus der Ringdüse austretende Druckluft auf den Innenschlauch mit den anhaftenden Partikeln eingewirkt. Lose oder zu lose an der Oberfläche des Innenschlauchs anhaftende Partikel werden durch die Druckluft weggeblasen und gegen die Transportrichtung des Schlauchs nach unten befördert. Die Druckluft führt die Partikel nach unten mit.After applying the
Die Partikel werden durch die Druckluft nach unten beschleunigt, um dem Trichter 14 zugeführt zu werden, so dass sie einer weiteren Verarbeitung zur Verfügung stehen. Damit innerhalb der Vorrichtung 1 kein zu hoher Überdruck entsteht, muss die zugeführte Druckluft aus dem Inneren des äußeren Gehäuses 11 abgeführt werden. Dazu dient der zwischen dem Rohrstutzen 33 und dem unteren Ring 29 verbleibende Spalt. Die Druckluft kann an diesem Spalt um ca. 180° nach oben umgelenkt werden, wobei die mitgeführten Partikel auf Grund ihrer Massenträgheit weiter nach unten fliegen. Die Druckluft kommt dann auf die Überdruckseite des Filterelements 19 und wird durch das Filterelement 19 gedrückt. Eventuell noch mitgeführte Partikel werden in dem Filter 19 festgehalten.The particles are accelerated downwardly by the compressed air to be fed to the
Ein mittels der Vorrichtung gemäß der
Claims (30)
- Process for producing a hose, in particular a shower hose, from a plurality of layers (1, 3), comprising the following steps:- firstly, particles are applied to an outer surface of an inner hose (1), which forms an inner layer (1) of the shower hose,- mechanical action is then exerted on the particles (2) which adhere to the inner hose,- an outer layer (3) is then applied,characterized
in that mechanical action is exerted on the particles by brushes (32), rollers, tabs or the like. - Process according to Claim 1, characterized in that the surface of the inner hose (1) is heated by a heater before the particles are applied.
- Process according to Claim 1, characterized in that an adhesive, lacquer or similar is applied to the surface of the inner hose (1) before the particles are applied.
- Process according to Claim 1 or 2, characterized in that the surface is heated to a temperature which is typical for the material of the inner hose (1).
- Process according to one of Claims 1 to 4, characterized in that the particles are applied by drawing the inner hose (1) through a bath containing the particles.
- Process according to one of Claims 1 to 5, characterized in that mechanical action is exerted on the particles by a pressure medium, for example compressed air.
- Process according to one of Claims 1 to 6, characterized in that some of the particles which do not adhere directly to the inner hose (1) are removed by the mechanical action.
- Process according to one of Claims 1 to 7, characterized in that the particles (2) are oriented or smoothed by the mechanical action.
- Process according to one of Claims 1 to 8, characterized in that depressions are impressed in the surface of the inner hose by one or more punches after the surface of the inner hose (1) has been heated and before or after the application of the particles.
- Device (10) for producing a hose, in particular a shower hose, in particular for carrying out a process according to one of Claims 1 to 9,- having a container (14) for a bath of particles,- wherein the container (14) has an inlet opening (13) for an inner hose and an outlet opening for the inner hose (1) provided with the particles,wherein
the device (10) has means for exerting mechanical action on the particles which adhere to the inner hose (1),
characterized
in that the means for exerting mechanical action comprise brushes (32), rollers, tabs and/or the like. - Device according to Claim 10, characterized in that the means for exerting mechanical action comprise nozzles for a pressure medium, in particular compressed air.
- Device according to Claim 11, characterized in that the means for exerting mechanical action are produced in part from textiles, leather, foam material, soft plastic materials, elastomers, bristles or similar.
- Device according to one of Claims 10 to 12, characterized in that one means for exerting mechanical action is a helical brush (32), which can be rotated about its longitudinal axis by means of a drive.
- Device according to Claim 13, characterized in that the nozzles are arranged downstream from the rotatable brush (32) in the direction in which the inner hose (1) provided with the particles is transported.
- Device according to one of Claims 10 to 14, characterized in that the means for exerting mechanical action are arranged in a housing (20, 29, 30, 31, 19, 18, 17).
- Device according to Claim 15, characterized in that the housing (20, 29, 30, 31, 19, 18, 17) has an inlet opening and an outlet opening for the hose coated with the particles.
- Device according to Claim 16, characterized in that the inlet opening of the housing (20, 29, 30, 31, 19, 18, 17) is connected at least indirectly to the outlet opening of the container (14).
- Device according to one of Claims 15 to 17, characterized in that a filter (19) is inserted into a wall of the housing (20, 29, 30, 31, 19, 18, 17).
- Device according to one of Claims 10 to 18, characterized in that the container (14) is coupled to a vibrator (28).
- Device according to one of Claims 10 to 19, characterized in that the container (14) has a funnel-shaped design at least in one portion, and a tip of the funnel points counter to the direction in which the hose is transported.
- Device according to one of Claims 10 to 20, characterized in that the device (10) comprises a heating means for heating up the hose.
- Hose, in particular shower hose, produced by the process according to one of Claims 1 to 9, wherein particles are arranged between an inner layer (1) and an outer layer (3) of the hose, characterized in that the particles have a platelet-like form, and the platelet-like particles are arranged substantially parallel to the outer surface of the inner layer.
- Hose, in particular shower hose, e.g. according to Claim 22, having an inner layer and an outer layer, characterized in that depressions are provided in an outer surface of the inner layer.
- Hose according to Claim 23, characterized in that the depressions are punched formations.
- Hose according to Claim 23 or 24, characterized in that the depressions have a regular arrangement.
- Hose according to one of Claims 23 to 25, characterized in that the depressions have a circular, annular, drop-shaped, linear, arrow-shaped, cross-shaped, square or rectangular form and/or are in the form of letters and/or numerals.
- Hose, in particular shower hose, e.g. according to one of Claims 22 to 26, characterized in that the hose has a non-circular cross section.
- Hose according to Claim 27, characterized in that the hose has a star-shaped cross section.
- Hose according to Claim 28, characterized in that the hose has an oval or angular cross section.
- Hose, in particular shower hose, according to one of Claims 22 to 25, characterized in that the inner and/or outer layer (1, 3) is formed by a hose according to one of Claims 27 to 29.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES05014638T ES2361356T3 (en) | 2005-07-06 | 2005-07-06 | PROCEDURE FOR THE MANUFACTURE OF A FLEXIBLE TUBE, IN PARTICULAR OF A FLEXIBLE SHOWER TUBE OF VARIOUS LAYERS. |
AT05014638T ATE494078T1 (en) | 2005-07-06 | 2005-07-06 | METHOD FOR PRODUCING A HOSE, IN PARTICULAR A SHOWER HOSE FROM MULTIPLE LAYERS |
DE502005010802T DE502005010802D1 (en) | 2005-07-06 | 2005-07-06 | Method for producing a hose, in particular a multi-layer shower hose |
EP05014638A EP1741494B1 (en) | 2005-07-06 | 2005-07-06 | Process for making a hose, especially a shower hose, with several layers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05014638A EP1741494B1 (en) | 2005-07-06 | 2005-07-06 | Process for making a hose, especially a shower hose, with several layers |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1741494A1 EP1741494A1 (en) | 2007-01-10 |
EP1741494B1 true EP1741494B1 (en) | 2011-01-05 |
Family
ID=35414783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05014638A Not-in-force EP1741494B1 (en) | 2005-07-06 | 2005-07-06 | Process for making a hose, especially a shower hose, with several layers |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1741494B1 (en) |
AT (1) | ATE494078T1 (en) |
DE (1) | DE502005010802D1 (en) |
ES (1) | ES2361356T3 (en) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3508946A (en) * | 1964-04-09 | 1970-04-28 | Dow Corning | Pipe coated with epoxy resin composition cured with extra-coordinate silicon complex and process for coating said pipe |
DE19511216C2 (en) * | 1995-03-27 | 2002-07-25 | Hansgrohe Ag | Double-walled hose, in particular shower hose, and process for its production |
-
2005
- 2005-07-06 ES ES05014638T patent/ES2361356T3/en active Active
- 2005-07-06 EP EP05014638A patent/EP1741494B1/en not_active Not-in-force
- 2005-07-06 AT AT05014638T patent/ATE494078T1/en active
- 2005-07-06 DE DE502005010802T patent/DE502005010802D1/en active Active
Also Published As
Publication number | Publication date |
---|---|
ES2361356T3 (en) | 2011-06-16 |
DE502005010802D1 (en) | 2011-02-17 |
ATE494078T1 (en) | 2011-01-15 |
EP1741494A1 (en) | 2007-01-10 |
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