EP1710294A1 - Verfahren zur Verbesserung der Stabilität oder der Kompatibilität von Tensiden - Google Patents

Verfahren zur Verbesserung der Stabilität oder der Kompatibilität von Tensiden Download PDF

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Publication number
EP1710294A1
EP1710294A1 EP06111831A EP06111831A EP1710294A1 EP 1710294 A1 EP1710294 A1 EP 1710294A1 EP 06111831 A EP06111831 A EP 06111831A EP 06111831 A EP06111831 A EP 06111831A EP 1710294 A1 EP1710294 A1 EP 1710294A1
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Prior art keywords
detergent
soluble
oil
compatibility
acid
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French (fr)
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EP1710294B1 (de
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Peter John Dowding
Christopher John Adams
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Infineum International Ltd
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Infineum International Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M177/00Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/02Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic oxygen-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/08Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/24Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027Neutral salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/028Overbased salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/122Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms monocarboxylic
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/144Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • C10M2207/262Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
    • CCHEMISTRY; METALLURGY
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088Neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/089Overbased salts
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions

Definitions

  • the present invention relates to a method of improving the stability of a detergent in a lubricating oil composition, or a method of improving the compatibility of a detergent with other additives in a lubricating oil composition, such as friction modifiers, other detergents, metal rust inhibitors, viscosity index improvers, corrosion inhibitors, oxidation inhibitors and anti-wear agents.
  • the invention relates to a method of improving the compatibility of a detergent with friction modifiers or other detergents present in a lubricating oil composition.
  • a method of improving the stability of a detergent in a lubricating oil composition or a method of improving the compatibility of a detergent with another additive in a lubricating oil composition including the step of reacting the detergent with a water-soluble ⁇ , ⁇ -unsaturated carbonyl compound.
  • the water-soluble ⁇ , ⁇ -unsaturated carbonyl compound is preferably selected from maleic anhydride, itaconic anhydride, citriconic anhydride, alkyl maleic anhydride, cycloalkyl maleic anhydride, acrylic acid and methacrylic acid.
  • the water-soluble ⁇ , ⁇ -unsaturated carbonyl compound is preferably maleic anhydride.
  • the detergent is reacted with from about 0.5 to about 10, preferably from about 1 to about 6, more preferably from about 2 to about 5 wt. %, e.g., 2 to 4 wt. %, of the water-soluble ⁇ , ⁇ -unsaturated carbonyl compound, based on the weight of detergent.
  • the reaction can be carried out at temperatures of from about 30°C to about 200°C, preferably from about 60°C to about 150°C, more preferably from about 80°C to about 120°C, for about 0.5 hours to about 8 hours.
  • additives found in lubricating oil compositions are metal rust inhibitors, viscosity index improvers, corrosion inhibitors, oxidation inhibitors, antifoaming agents, anti-wear agents and pour point depressants. Some are discussed in further detail below.
  • a dithiophosphoric acid may be made by reacting mixtures of primary and secondary alcohols.
  • multiple dithiophosphoric acids can be prepared where the hydrocarbyl groups on one are entirely secondary in character and the hydrocarbyl groups on the others are entirely primary in character.
  • any basic or neutral zinc compound could be used but the oxides, hydroxides and carbonates are most generally employed.
  • Commercial additives frequently contain an excess of zinc due to the use of an excess of the basic zinc compound in the neutralization reaction.
  • the preferred zinc dihydrocarbyl dithiophosphates are oil soluble salts of dihydrocarbyl dithiophosphoric acids and may be represented by the following formula: wherein R and R' may be the same or different hydrocarbyl radicals containing from 1 to 18, preferably 2 to 12, carbon atoms and including radicals such as alkyl, alkenyl, aryl, arylalkyl, alkaryl and cycloaliphatic radicals. Particularly preferred as R and R' groups are alkyl groups of 2 to 8 carbon atoms.
  • Typical oil soluble aromatic amines having at least two aromatic groups attached directly to one amine nitrogen contain from 6 to 16 carbon atoms.
  • the amines may contain more than two aromatic groups.
  • Compounds having a total of at least three aromatic groups in which two aromatic groups are linked by a covalent bond or by an atom or group (e.g., an oxygen or sulphur atom, or a -CO-, -SO 2 - or alkylene group) and two are directly attached to one amine nitrogen also considered aromatic amines having at least two aromatic groups attached directly to the nitrogen.
  • a viscosity index improver dispersant functions both as a viscosity index improver and as a dispersant.
  • examples of viscosity index improver dispersants include reaction products of amines, for example polyamines, with a hydrocarbyl-substituted mono -or dicarboxylic acid in which the hydrocarbyl substituent comprises a chain of sufficient length to impart viscosity index improving properties to the compounds.
  • additives which maintains the stability of the viscosity of the blend may be necessary to include an additive which maintains the stability of the viscosity of the blend.
  • polar group-containing additives achieve a suitably low viscosity in the pre-blending stage it has been observed that some compositions increase in viscosity when stored for prolonged periods.
  • Additives which are effective in controlling this viscosity increase include the long chain hydrocarbons functionalized by reaction with mono- or dicarboxylic acids or anhydrides which are used in the preparation of the ashless dispersants as hereinbefore disclosed.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
EP06111831A 2005-04-06 2006-03-28 Verfahren zur Verbesserung der Stabilität oder der Kompatibilität von Tensiden Active EP1710294B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06111831A EP1710294B1 (de) 2005-04-06 2006-03-28 Verfahren zur Verbesserung der Stabilität oder der Kompatibilität von Tensiden

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Application Number Priority Date Filing Date Title
EP05252141 2005-04-06
EP06111831A EP1710294B1 (de) 2005-04-06 2006-03-28 Verfahren zur Verbesserung der Stabilität oder der Kompatibilität von Tensiden

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EP1710294B1 EP1710294B1 (de) 2013-03-06

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008128657A2 (en) 2007-04-24 2008-10-30 Infineum International Limited A method of improving the compatibility of an overbased detergent with other additives in lubricating oil composition
GB2474987A (en) * 2006-11-22 2011-05-04 Afton Chemical Corp Lubricant compositions
EP3144372A1 (de) * 2015-09-16 2017-03-22 Infineum International Limited Additivkonzentrate zur formulierung von schmierölzusammensetzungen
EP3192858A1 (de) 2016-01-15 2017-07-19 Infineum International Limited Verwendung einer schmierölzusammensetzung
EP3222700A1 (de) * 2016-03-22 2017-09-27 Infineum International Limited Additivkonzentrate
EP3222698A1 (de) * 2016-03-22 2017-09-27 Infineum International Limited Additivkonzentrate
EP3222699A1 (de) * 2016-03-22 2017-09-27 Infineum International Limited Additivkonzentrate

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0041851A2 (de) * 1980-06-09 1981-12-16 Exxon Research And Engineering Company Schmiermittelzusammensetzung mit stabilisiertem Metalldetergenzzusatz und mit einer reibungsreduzierenden Esterkomponente
EP0271262A1 (de) 1986-11-29 1988-06-15 Bp Chemicals (Additives) Limited Erdalkalimetallalkylphenolate, ihre geschwefelten Derivate, ihre Herstellung und ihre Verwendung
US4867890A (en) 1979-08-13 1989-09-19 Terence Colclough Lubricating oil compositions containing ashless dispersant, zinc dihydrocarbyldithiophosphate, metal detergent and a copper compound
US4981603A (en) * 1988-09-30 1991-01-01 Amoco Corporation Blending method for improved compatibility of dispersants and basic magnesium detergents in DI packages
EP0761648A2 (de) 1995-08-23 1997-03-12 Chevron Chemical Company Herstellung von Phenat-Stearat mit hohen Basenzahlen und geringer feiner Sedimentenformung
WO2001074751A2 (en) 2000-04-03 2001-10-11 The Lubrizol Corporation Lubricating oil compositions containing saligenin derivatives
EP0902827B1 (de) 1996-05-31 2003-11-19 Infineum USA L.P. Überbasische metallenthaltende detergens
US20040029747A1 (en) * 2002-08-06 2004-02-12 Jacob Emert Modified detergents and lubricating oil compositions containing same
EP1452581A2 (de) 2003-02-27 2004-09-01 Chevron Oronite Technology B.V. Verfahren zur Verbesserung der Elastomerverträglichkeit

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4867890A (en) 1979-08-13 1989-09-19 Terence Colclough Lubricating oil compositions containing ashless dispersant, zinc dihydrocarbyldithiophosphate, metal detergent and a copper compound
EP0041851A2 (de) * 1980-06-09 1981-12-16 Exxon Research And Engineering Company Schmiermittelzusammensetzung mit stabilisiertem Metalldetergenzzusatz und mit einer reibungsreduzierenden Esterkomponente
EP0271262A1 (de) 1986-11-29 1988-06-15 Bp Chemicals (Additives) Limited Erdalkalimetallalkylphenolate, ihre geschwefelten Derivate, ihre Herstellung und ihre Verwendung
EP0273588A1 (de) 1986-11-29 1988-07-06 Bp Chemicals (Additives) Limited Geschwefelt Erdalkalimetallalkylphenolate, ihre Herstellung und ihre Verwendung
US4981603A (en) * 1988-09-30 1991-01-01 Amoco Corporation Blending method for improved compatibility of dispersants and basic magnesium detergents in DI packages
EP0761648A2 (de) 1995-08-23 1997-03-12 Chevron Chemical Company Herstellung von Phenat-Stearat mit hohen Basenzahlen und geringer feiner Sedimentenformung
EP0902827B1 (de) 1996-05-31 2003-11-19 Infineum USA L.P. Überbasische metallenthaltende detergens
WO2001074751A2 (en) 2000-04-03 2001-10-11 The Lubrizol Corporation Lubricating oil compositions containing saligenin derivatives
US20040029747A1 (en) * 2002-08-06 2004-02-12 Jacob Emert Modified detergents and lubricating oil compositions containing same
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GB2474987A (en) * 2006-11-22 2011-05-04 Afton Chemical Corp Lubricant compositions
GB2474987B (en) * 2006-11-22 2011-07-13 Afton Chemical Corp Lubricant compositions
WO2008128657A2 (en) 2007-04-24 2008-10-30 Infineum International Limited A method of improving the compatibility of an overbased detergent with other additives in lubricating oil composition
WO2008128657A3 (en) * 2007-04-24 2008-12-11 Infineum Int Ltd A method of improving the compatibility of an overbased detergent with other additives in lubricating oil composition
US8703673B2 (en) 2007-04-24 2014-04-22 Infineum International Limited Method of improving the compatibility of an overbased detergent with other additives in a lubricating oil composition
KR20170033245A (ko) * 2015-09-16 2017-03-24 인피늄 인터내셔날 리미티드 윤활유 조성물의 제형화를 위한 첨가제 농축물
EP3144372A1 (de) * 2015-09-16 2017-03-22 Infineum International Limited Additivkonzentrate zur formulierung von schmierölzusammensetzungen
EP3192858A1 (de) 2016-01-15 2017-07-19 Infineum International Limited Verwendung einer schmierölzusammensetzung
EP3222700A1 (de) * 2016-03-22 2017-09-27 Infineum International Limited Additivkonzentrate
EP3222698A1 (de) * 2016-03-22 2017-09-27 Infineum International Limited Additivkonzentrate
EP3222699A1 (de) * 2016-03-22 2017-09-27 Infineum International Limited Additivkonzentrate
US10781392B2 (en) 2016-03-22 2020-09-22 Infineum International Limited Additive concentrates
US11292980B2 (en) 2016-03-22 2022-04-05 Infineum International Ltd Additive concentrates
US11299690B2 (en) 2016-03-22 2022-04-12 Infineum International Ltd. Additive concentrates

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