EP1691611A1 - Combinaisons d'agents presentant des proprietes insecticides - Google Patents

Combinaisons d'agents presentant des proprietes insecticides

Info

Publication number
EP1691611A1
EP1691611A1 EP04798022A EP04798022A EP1691611A1 EP 1691611 A1 EP1691611 A1 EP 1691611A1 EP 04798022 A EP04798022 A EP 04798022A EP 04798022 A EP04798022 A EP 04798022A EP 1691611 A1 EP1691611 A1 EP 1691611A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
independently
another
substituents
halogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04798022A
Other languages
German (de)
English (en)
Inventor
Christian Funke
Reiner Fischer
Rüdiger Fischer
Heike Hungenberg
Wolfram Andersch
Wolfgang Thielert
Anton Kraus
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer CropScience AG
Original Assignee
Bayer CropScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102004021565A external-priority patent/DE102004021565A1/de
Application filed by Bayer CropScience AG filed Critical Bayer CropScience AG
Publication of EP1691611A1 publication Critical patent/EP1691611A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles

Definitions

  • the present invention relates to novel active compound combinations comprising known anthranilic amides from one part, and further known insecticidal active substances on the other hand, "there are very good and insects are suitable for controlling animal pests such as.
  • a 1 and A 2 independently of one another represent oxygen or sulfur
  • X 1 represents N or CR 10 .
  • R 1 represents hydrogen or represents in each case optionally mono- or poly-substituted C ⁇ -C 6 - alkyl, C 2 -C 6 -alkenyl, C 2 -C 6 alkynyl or C 3 -C 6 -cycloalkyl, where the substituents independently of one another can be selected from R 6 , halogen, cyarto, nitro, hydroxy, CC 4 -alkoxy, C r C 4 -alkylthio, CC 4 -alkylsulfinyl, CC 4 -alkylsulfonyl, C 2 -C 4 -alkoxycarbonyl, C ⁇ -C -Alkylamino, C 2 -C 8 -dialkylamino, C 3 -C 6 -cycloalkylamino, (-C-C 4 -alkyl) C 3 -C 6 - cycloalkylamino or R 11 , R 2 for hydrogen, CC
  • R 5 and R 8 each independently of one another for hydrogen, halogen or for optionally substituted -Gralkyl, C r C 4 -haloalkyl, R 12 , G, J, -OJ, -OG, -S (O) p -J, - , -S (0) p S (O) p -G - are phenyl wherein the substituents may be independently selected from one to three radicals from W or R 12, C ⁇ -C ⁇ 0 alkyl, C 2 -C 6 - Alkenyl, C 2 -C 6 -alkyl, C r C 4 -alkoxy or C-C -alkythio, each substituent being selected independently of one another by one or more substituents from G, J, R 6 , halogen, cyano, nitro, amino, Hydroxy, C r C 4 alkoxy, CC haloalkoxy, dC ⁇ alkylthio, C r C 4 alkyl
  • J each independently represents an optionally substituted 5- or 6-membered heteroaromatic ring, it being possible for the substituents to be selected independently of one another from one to three W groups or one or more R 12 groups ,
  • R 7 for hydrogen, CC 4 -alkyl, -C-C 4 -haloalkyl, halogen, C ⁇ -C 4 -alkoxy, C ⁇ -C 4 -haloalkoxy, Q- -alkylthio, C r C 4 -alkylsulfmyl, C r C 4 - Alkylsulfonyl, CC 4 -haloalkylthio, CC 4 -haloalkylsulfinyl, C 1 -C 4 -haloalkylsulfonyl, R 9 represents C 1 -C 4 -haloalkyl, C 1 -C -haloalkoxy, C r C 4 -haloalkylsulfinyl or halogen,
  • R 10 represents hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl, halogen, cyano or C r C 4 -haloalkoxy,
  • L each independently represents O, NR 18 or S,
  • R 13 each independently represents hydrogen or represents optionally mono- or polysubstituted -CC 6 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 -AÜ-inyl or C 3 -C 6 cycloal yl , where the substituents can be selected independently of one another from R 6 , halogen, cyano, nitro, hydroxy, Ci-GrAlkoxy, C r C 4 alkylsulfonyl, CC 4 alkylsulfonyl, CC 4 alkyl a ino, -C 8 dialkylamino , C 3 -C6-C!
  • R 14 each independently represents optionally mono- or polysubstituted C 1 -C 20 -alkyl, C 2 - o-alkenyl, C 2 - o-alkynyl or C 3 -C 6 cycloalkyl, the substituents being selected independently of one another can from R 6 , halogen, cyano, nitro, hydroxy, CC 4 -alkoxy, CC 4 -AJj ylsulfinyl, -C-C 4 -alkylsulfonyl, C ⁇ -C -alkylamino, C 2 -C 8 - dialkylamino, C 3 -C 6 -C ⁇ cloalkylamino or (-C-C 4 alkyl) C 3 -C 6 cycloalkylamino or for optionally substituted phenyl,
  • R 16 represents dC 12 alkyl or C r C ⁇ 2 -haloalkyl
  • N (R 16 ) 2 represents a cycle which forms the ring M
  • R 17 each independently represents hydrogen or CC 4 alkyl
  • B (OR 17 ) 2 represents a ring in which the two oxygen atoms are connected via a chain having two to three carbon atoms which are optionally substituted by one or two substituents independently selected from methyl or C 2 -C 6 alkoxycarbonyl
  • R 18 each independently for hydrogen, Ci-C ⁇ -Alkyl or -CC 6 -haloalkyl
  • N (R 13 ) (R 18 ) stands for a cycle which forms the ring M
  • R 19 each independently of one another for hydrogen or for in each case optionally mono- or polysubstituted CC 6 -Alkyl stands, where the substituents can be selected independently of one another from cyano, nitro, hydroxy, -C-C 4 alkoxy, -C
  • M in each case represents an optionally mono- to tetrasubstituted ring which, in addition to the nitrogen atom to which the substituent pair R 13 and R 18 , (R 15 ) 2 or (R 1S ) 2 is linked, has two to six carbon atoms and, if appropriate, additionally another atom stick contains substance, sulfur or oxygen and where the substituents can be selected independently of one another from CrQj-alkyl, halogen, cyano, nitro or -CC 2 alkoxy,
  • W each independently for CC 4 alkyl, C 2 -C 4 alkenyl, C 2 -C 4 alkynyl, C 3 -C 6 cycloalkyl, CC 4 haloalkyl, C 2 -C haloalkenyl, C 2 -C 4 -Haloalkynyl, C 3 -C 6 -halocycloalkyl, halogen, cyano, nitro, CC -alkoxy, -C-C 4 -haloalkoxy, C ⁇ -C 4 -alkylthio, Q-Gr-alkylsulfinyl, C -alkylsulfonyl, C ⁇ -C 4 -Alkylamino, -C 8 -dialkylamino, C 3 -C 6 - ( ⁇ cloall ⁇ ylam-no, (CC ⁇ Alky ⁇ Cs-C ⁇ -cycloalkylarnino, C 2 -C
  • R 5 for hydrogen, CC 6 -Al yl, C r C 6 -haloalkyl, C 2 -C 6 -haloalkenyl, C 2 - C 6 alkaloalkmyl, -C-C -haloalkoxy, CrC 4 -Haloalkylthio or halogen
  • R 8 is hydrogen, CC 6 -alkyl, d-C ⁇ -haloalkyl, C 2 -C 6 -haloalkenyl, C 2 -C 6 -haloalkynyl, CC 4 -haloalkoxy, CC 4 - haloalkylthio , Halogen, C 2 -C 4 alkylcarbonyl, C 2 -C 6 alkoxycarbonyl, C 2 -C 6 alkylarninocarbonyl or C 3 -C 8 dialkylaminocarbonyl, (c) at least one substituent selected from R 6
  • the compounds of the general formula (I) also comprise N-oxides and salts,
  • insecticidal active ingredient from the following groups 2 and 3, selected from A) (thio) phosphates (group 2), preferably (2-1) azinphos-methyl (known from US 2,758,115)
  • Chlo yrifos (known from US 3,244,586)
  • the insecticidal and acaricidal action of the active compound combination according to the invention is substantially higher than the sum of the actions of the individual active compounds. There is an unforeseeable real synergistic effect and not just an addition to the effect.
  • the active compound combinations according to the invention contain at least one active ingredient from group 2 [selected from the compounds (2-1) to (2- 33)] and / or from group 3 [selected from the compounds (3- 1) to (3-10)].
  • the compounds of the formula (T) can be present in different compositions as geometric and / or optical isomers or isomer mixtures, which can optionally be separated in a customary manner. Both the pure isomers and the isomer mixtures, their preparation and use, and agents containing them are the subject of the present invention. For the sake of simplicity, however, the following always refers to compounds of the formula (I), although both the pure compounds and, if appropriate, mixtures with different proportions of isomeric compounds are meant.
  • R 2 represents hydrogen or CC 6 alkyl
  • R 3 represents Ci-Cg-alkyl which is optionally substituted by an R 6 ,
  • R 4 represents C 1 -C 4 -al yl, CC 2 -halogenal yl, C 1 -C 2 -haloalkoxy or halogen,
  • R 5 represents hydrogen, CC 4 alkyl, C 1 -C 2 haloalkyl, CC 2 haloalkoxy or halogen
  • each E 2 is independently O, S, NR 15 , N-OR 15 , NN (R 15 ) 2
  • each L is independent of one another represents O or NR 18
  • R 7 represents CC 4 -haloalkyl or halogen
  • R 9 represents C 1 -C 2 haloalkyl, C 1 -C 2 haloalkoxy, S (O) p C 1 -C 2 haloalkyl or halogen
  • R 15 each independently represents hydrogen or optionally substituted C 1 -C 6 haloalkyl or QC 6 alkyl, where the substituents can be selected independently of one another from cyano, C 1 -C 4 -alkoxy, C 1 -C 4 -haloalkoxy, C r C 4 -alkylthio, C 1 -C 4 alkylsulfinyl, C 1 -C 4 alkylsulfonyl, C r C 4 haloalkylthio, C r C haloalkylsulfinyl or C 1 -C 4 haloalkylsulfonyl
  • R 18 in each case represents hydrogen or C 1 -C 4 alkyl
  • R 19 each independently represents hydrogen or -CC 6 alkyl, p independently represents 0, 1, 2, and at least one active ingredient of group 2 [selected from the compounds (2-1) to (2-33) ] and / or group 3 [selected from compounds (3-1) to (3-10)].
  • halogen represents fluorine, chlorine, bromine and iodine, in particular fluorine, chlorine and bromine.
  • R 2 represents hydrogen or methyl
  • R 3 represents C 1 -C 4 -alkyl (in particular methyl, ethyl, n-, iso-propyl, n-, iso-, sec-, tert-butyl)
  • R 4 represents methyl, trifluoromethyl, trifluorometlioxy, fluorine, chlorine, bromine or iodine,
  • R 5 represents hydrogen, fluorine, chlorine, bromine, iodine, trifluoromethyl or trifluoromethoxy
  • R 7 represents chlorine or bromine
  • R 9 represents trifluoromethyl, chlorine, bromine, difluoromethoxy or trifluoroethoxy, and at least one active ingredient of group 2 [selected from compounds (2-1) to (2-33)] and / or group 3 [selected from the compounds ( 3-1) to (3-10)].
  • Active compound combinations according to the invention which preferably contain the following active compounds of group 2 are preferred: (2-2) chlorpyrifos, (2-31) acephate, (2-32) methamidophos.
  • Active substance combinations according to the invention which preferably contain the following active substances of group 3 are preferred: (3-1) carbaryl, (3-5) mefhiocarb, (3-10) thiodicarb.
  • Active compound combination comprising nr.. Active ingredient combination containing 5e) ⁇ -1-19) and (3-5) methiocarb 42e) ⁇ -1-60) and (3-5) methiocarb
  • Active ingredient combinations which contain compounds of the formula (I) and active ingredients of the formulas (2-1) to (2-23) in which the individual radicals have a combination of the meanings given above as being particularly preferred are very particularly preferred.
  • Saturated or unsaturated hydrocarbon residues such as alkyl or alkenyl can also be used in connection with heteroatoms, e.g. in alkoxy, where possible, be straight-chain or branched.
  • Optionally substituted radicals can be mono- or polysubstituted, and in the case of multiple substitutions the substituents can be the same or different.
  • the active ingredient combinations can also contain other fungicidal, acaricidal or insecticidal active mixing partners.
  • the combinations according to the invention contain active compounds of the formula (I) and the mixing partner of group 2 or group 3 in the preferred and particularly preferred mixing ratios indicated:
  • the mixing ratios are based on weight ratios.
  • the ratio is to be understood as an active ingredient of the formula (_): mixing partner mixing partner preferred particularly preferred mixing ratio mixing ratio (2-1) azinphosmethyl 10: 1 to 1: 10 5: 1 to 1: 5 (2-2) chlorophyros 10: 1 to 1:10 5: 1 to 1: 5 (2-3) diazinon 10: 1 to 1:10 5: 1 to 1: 5 Mixing partner Preferred Particularly preferred mixing ratio Mixing ratio
  • Methiocarb 10 1 to 1:10 5: 1 to 1: 5 Mixing partner Preferred Particularly preferred mixing ratio Mixing ratio (3-6) methomyl 10: 1 to 1:10 5: 1 to 1: 5 (3-7) oxamyl 5: 1 to 1: 100 1: 1 to 1:20 (3-8 ) Pirimicarb 10: 1 to 1:10 5: 1 to 1: 5 (3-9) Propoxur 10: 1 to 1:10 5: 1 to 1: 5 (3-10) Thiodicarb 5: 1 to 1:20 1 : 1 to 1:10
  • the active compound combinations according to the invention are suitable for controlling animal pests, preferably arthropods and nematodes, in particular insects and arachnids, which occur in agriculture, animal health, in forests, in the protection of stored goods and materials and in the hygiene sector. They are effective against normally sensitive and resistant species as well as against all or individual stages of development.
  • the pests mentioned above include: From the order of the Isopoda e.g. Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of the Diplopoda e.g. Blaniulus guttulatus. From the order of the Chilopoda e.g. Geophilus ca ⁇ ophagus, Scutigera spp.
  • Symphyla e.g. Scutigerella immaculata.
  • Thysanura e.g. Lepisma saccharina.
  • Collembola e.g. Onychiurus armatus.
  • Dermaptera e.g. Forficula auricularia.
  • Isoptera e.g. Reticulitermes spp.
  • Phthiraptera e.g. Pediculus humanus co ⁇ oris, Haematopinus spp., Linognathus spp., Trichodectes spp., Damalinia spp.
  • Thysanoptera e.g. Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella accidentalis.
  • From the order of the Heteroptera for example Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triatoma spp.
  • From the order of the Homoptera for example Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphis fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigususpp.
  • Sitophilus spp. Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp., Anthrenus spp., Attagenus spp., Lyctus spp., Meligethes aeneus, Ptinus holpp., Ptinus holpp., Ptinus holpp., Ptinus holpp.
  • Tribolium spp. Tenebrio molitor, Agriotes spp., Conoderus spp., Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus.
  • Hymenoptera e.g. Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of the Diptera e.g.
  • Siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
  • Siphonaptera e.g. Xenopsylla cheopis, Ceratophyllus spp.
  • From the class of the Arachnida e.g. Sco ⁇ io maurus, Latrodectus mactans, Acarus siro, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora, Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalommodes spp., I.
  • Chorioptes spp. Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp.
  • Plant parasitic nematodes include e.g. Pratylenchus spp., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaph.
  • the active substance combinations can be converted into the customary formulations, such as solutions, emulsions, wettable powders, suspensions, powders, dusts, pastes, soluble powders, Granules, suspension emulsion concentrates, active ingredient-impregnated natural and synthetic substances as well as very fine encapsulation in polymeric substances.
  • formulations are made in a known manner, e.g. by mixing the active ingredients with extenders, that is to say liquid solvents and / or solid carriers, optionally using surface-active agents, that is to say emulsifiers and / or dispersing agents and / or foam-generating agents.
  • extenders that is to say liquid solvents and / or solid carriers
  • surface-active agents that is to say emulsifiers and / or dispersing agents and / or foam-generating agents.
  • organic solvents can also be used as auxiliary solvents.
  • auxiliary solvents e.g. organic solvents
  • aromatics such as xylene, toluene, or alkylnaphthalenes
  • chlorinated aromatics and chlorinated aliphatic hydrocarbons such as chlorobenzenes, chlorethylenes or methylene chloride
  • aliphatic hydrocarbons such as cyclohexane or paraffins, e.g.
  • Petroleum fractions mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • alcohols such as butanol or glycol and their ethers and esters
  • ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone
  • strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.
  • Possible solid carriers are: e.g. Ammonium salts and natural rock powders such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders such as highly disperse silica, aluminum oxide and silicates are suitable as solid carriers for granules: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems; as emulsifying and / or foaming agents are possible: e.g.
  • mchtionogerie and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates;
  • Possible dispersants are: e.g. Lignin sulfite liquor and methyl cellulose.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids can be used in the formulations.
  • Other additives can be mineral and vegetable oils.
  • Dyes such as inorganic pigments, for example iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • the formulations generally contain between 0.1 and 95% by weight of active compound, preferably between 0.5 and 90%.
  • the active compound combinations according to the invention can be present in commercially available formulations and in the use forms prepared from these formulations in a mixture with other active compounds, such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • active compounds such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances or herbicides.
  • Insecticides include, for example, phosphoric acid esters, carbamates, carboxylic acid esters, chlorinated hydrocarbons, phenylureas, substances produced by microorganisms, etc.
  • the active compound combinations according to the invention can furthermore be present in their commercially available formulations and in the use forms prepared from these formulations in a mixture with synergists.
  • Synergists are compounds that increase the effectiveness of the active ingredients without the added synergist itself having to be active.
  • the active substance content of the use forms prepared from the commercially available formulations can vary within wide ranges.
  • the active substance concentration of the use forms can be from 0.0000001 to 95% by weight of active substance, preferably between 0.0001 and 1% by weight.
  • the application takes place in a customary manner adapted to the application forms.
  • the active substance combinations When used against hygiene pests and pests of stored products, the active substance combinations are distinguished by an excellent residual action on wood and clay and by a good stability to alkali on limed substrates.
  • the active ingredient combinations according to the invention act not only against plants, hygiene and
  • animal parasites such as shield ticks, leather ticks, space mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, hair lice, featherlings and fleas.
  • ectoparasites animal parasites
  • shield ticks leather ticks, space mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, hair lice, featherlings and fleas.
  • Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp. From the order of the Mallophagida and the subordinates Amblycerina and Ischnocerina e.g.
  • Trimenopon spp. Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
  • Nematocerina and Brachycerina e.g. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota ., Pbilipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp.,
  • Morellia spp. Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp.,
  • Siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
  • Dermacentor spp. Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp.,
  • Raillietia spp. Pneumonyssus spp., Sternostoma spp., Varroa spp.
  • Pterolichus spp. Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp.,
  • the active compound combinations according to the invention are also suitable for controlling arthropods which are used in agricultural animals, such as Cattle, sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, house birds, aquarium fish and so-called experimental animals, such as Infest hamsters, guinea pigs, rats and mice.
  • arthropods By combating these arthropods, deaths and reduced performance (in the case of meat, milk, wool, skins, eggs, honey, etc.) are to be reduced, so that the use of the active compound combinations according to the invention enables more economical and simple animal husbandry.
  • the active compound combinations according to the invention are used in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, drinkers, drenches, granules, pastes, boluses, the feed-through method, suppositories, by parenteral administration, such as by injections (intramuscular, subcutaneous, intravenous, intra- peritoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, diving or bathing (dipping), spraying (spray), pouring on (pour-on and spot-on), washing, powdering and with the help of active ingredients
  • Shaped bodies such as collars, ear tags, tail tags, limb straps, holsters, marking devices, etc.
  • the active substance combinations can be formulated (for example powders, emulsions, flowable agents) which contain the active substances in an amount of 1 to 80% by weight, directly or after 100 to 10,000 - Apply a thinner or use it as a chemical bath. It has also been found that the active compound combinations according to the invention have a high insecticidal action against insects which destroy industrial materials.
  • insects may be mentioned by way of example and without limitation - beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium ca ⁇ ini, Lyctus africanus, Lyctus brunneus, Lyctus brunicanus Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec.
  • non-living materials such as preferably plastics, adhesives, glues, papers and cartons, leather, wood, wood processing products and paints.
  • the material to be protected from insect infestation is very particularly preferably wood and wood processing products.
  • Wood and wood processing products which can be protected by the agent according to the invention or mixtures containing it are to be understood as examples: timber, wooden beams, railway sleepers, bridge parts, jetties, wooden vehicles, boxes, pallets, containers, telephone masts, wooden cladding, wooden windows and doors , Plywood, chipboard, carpentry or wood products that are generally used in house construction or joinery.
  • the active substance combinations can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
  • the formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or fixative, water repellant, optionally siccatives and UV stabilizers and optionally dyes and pigments and further processing aids.
  • the insecticidal compositions or concentrates used to protect wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight.
  • the amount of the agents or concentrates used depends on the type and occurrence of the insects and on the medium. The optimum amount of use can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active compound, based on the material to be protected.
  • the organic chemical solvents used are preferably oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C., preferably above 45 ° C.
  • Corresponding mineral oils or their aromatic fractions or solvent mixtures containing mineral oil, preferably white spirit, petroleum and / or alkylbenzene, are used as such low-volatility, water-insoluble, oily and oily solvents.
  • Mineral oils with a boiling range of 170 to 220 ° C, white spirit with a boiling range of 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatics with a boiling range of 160 to 280 ° C, Te ⁇ entinöl and Like. Used.
  • organic low-volatility oily or oily solvents with an evaporation number above 35 and a flash point above 30 ° C, preferably above 45 ° C can be partially replaced by slightly or medium-volatile organic chemical solvents, with the proviso that the solvent mixture also has an evaporation number 35 and a flash point above 30 ° C, preferably above 45 ° C, and that the mixture is soluble or emulsifiable in this solvent mixture.
  • part of the organic chemical solvent or solvent mixture or an aliphatic polar organic chemical solvent or solvent mixture is replaced.
  • Aliphatic organic chemical solvents containing hydroxyl and / or ester and / or ether groups, such as, for example, glycol ethers, esters or the like, are preferably used.
  • the organic-chemical binders used are the water-thinnable synthetic resins which are known per se and / or which are soluble or dispersible or emulsifiable in the organic chemical solvents used and / or binding drying oils, in particular binders consisting of or containing an acrylate resin, a vinyl resin, e.g. Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydrocarbon resin such as indene-coumarone resin, silicone resin, drying vegetable and / or drying oils and / or physically drying binders based on a natural and / / or synthetic resin used.
  • binders consisting of or containing an acrylate resin, a vinyl resin, e.g. Polyvinyl acetate, polyester resin, polycondensation or polyaddition resin, polyurethane resin, alkyd resin or modified alkyd resin, phenolic resin, hydro
  • the synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In addition, known dyes, pigments, water-repellants, odor correctors and inhibitors or anticorrosive agents and the like can be used.
  • At least one alkyd resin or modified alkyd resin and / or a drying vegetable oil is preferably contained in the agent or in the concentrate as the organic chemical binder.
  • Alkyd resins with an oil content of more than 45% by weight, preferably 50 to 68% by weight, are preferably used according to the invention.
  • All or part of the binder mentioned can be replaced by a fixing agent (mixture) or a plasticizer (mixture). These additives are intended to prevent volatilization of the active ingredients and crystallization or failures. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used).
  • the plasticizers come from the chemical classes of phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate, phosphoric acid esters such as tributyl phosphate, adipic acid esters such as di- (2-ethylhexyl) adipate, stearates such as butyl stearate or amyl stearate, oleates such as butyl oleate, glycerol glycol ether or higher glycerol ether and p-toluenesulfonic acid ester.
  • phthalic acid esters such as dibutyl, dioctyl or benzyl butyl phthalate
  • phosphoric acid esters such as tributyl phosphate
  • adipic acid esters such as di- (2-ethylhexyl) adipate
  • stearates such as butyl stearate or amy
  • Fixing agents are chemically based on polyvinyl alkyl ethers such as e.g. Polyvinyl methyl ether or ketones such as benzophenone, ethylene benzophenone.
  • Water is also particularly suitable as a solvent or diluent, optionally in a mixture with one or more of the above-mentioned organic chemical solvents or diluents, emulsifiers and dispersants.
  • a particularly effective wood protection is achieved through large-scale impregnation processes, e.g. Vacuum, double vacuum or pressure process.
  • the active substance combinations according to the invention can be used to protect objects, in particular ship hulls, sieves, nets, structures, quay systems and signaling systems which come into contact with sea or brackish water.
  • Ledamo ⁇ ha barnacles
  • Balanomo ⁇ ha barnacles
  • Baianus or Pollicipes species increases the frictional resistance of Ships and subsequently leads to a significant increase in operating costs due to increased energy consumption and, moreover, frequent dry dock stays.
  • the active compound combinations according to the invention have an excellent antifouling effect.
  • heavy metals such as in bis (trialkyltin) sulfides, tri-butyltin laurate, tri-n-butyltin chloride, copper (T) oxide, triethyltin chloride, tri - «- butyl (2 -phenyl-4-cWo ⁇ henoxy) -tin, tributyltin oxide, molybdenum disulfide, antimony oxide, polymeric butyl titanate, phenyl (bispyridine) bismuth chloride, tri-M-butyl-zirconium fluoride, manganese ethylene bisthiocarbamate, zir-kdimimethyldistiocarbamate, zistiocarbamate, zistiocarbamate, zistiocarbamate, zistiocarbamate, zistiocarbamate, zistiocarbamate, zistiocarbamate, zistiocarbamate, zisti
  • the ready-to-use antifouling paints can optionally contain other active ingredients, preferably algicides, fungicides, herbicides, molluscicides or other antifouling active ingredients.
  • Suitable combination partners for the antifouling agents according to the invention are preferably: algicides such as 2-tert-butylammoAcyclopropylarnmo-6-memyltWo-l, 3,5-triazm ⁇ dichlorophen,
  • Fungicides such as benzo [ ⁇ ] thiophenecarboxylic acid cyclohexylarnide-S, S-dioxide, dichlofluanid, fluorfolpet,
  • 3-iodo-2-propynyl butyl carbamate, tolyl fluanide and azoles such as azaconazole, cyproconazole, epoxy-conazole, hexaconazole, metconazole, propiconazole and tebuconazole;
  • Molluscicides such as fentin acetate, metaldehyde, methiocarb, niclosamide, thiodicarb and trimethacarb; or conventional antifouling agents such as 4,5-dichloro-2-octyl-4-isothiazolin-3-one, diiodomethylparatrylsulfone, 2- (N, N-dimemylthiocarbamoyltMo) -5-nittothiazyl, potassium, copper, sodium and zinc salts of 2-pyridine thiol-l-oxide, pyridine triphenylborane, tetrabutyldistannoxane, 2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2,4,5,6-tetrachloroisophthalonitrile, tetramethylthiuram disulfide and 2 , 4,6-Trichlo ⁇ henylmaleinimid.
  • the antifouling agents used contain the active compound combinations according to the invention in a concentration of 0.001 to 50% by weight, in particular of 0.01 to 20% by weight.
  • the antifouling agents according to the invention furthermore contain the usual constituents, e.g. in Ungerer, Chem. Ind. 1985, 37, 730-732 and Williams, Antifouling Marine Coatings, Noyes, Park Ridge, 1973.
  • antifouling paints contain in particular binders.
  • binders are polyvinyl chloride in a solvent system, chlorinated rubber in a solvent system, acrylic resins in a solvent system, in particular in an aqueous system, vinyl chloride / vinyl acetate copolymer systems in the form of aqueous dispersions or in the form of organic solvent systems, butadiene / styrene / acrylonitrile rubbers, drying oils, such as linseed oil, resin esters or modified hard resins in combination with tar or bitumen, asphalt and epoxy compounds, small amounts of chlorinated rubber, chlorinated polypropylene and vinyl resins.
  • Paints may also contain inorganic pigments, organic pigments or dyes, which are preferably insoluble in seawater. Paints may also contain materials such as rosin to enable controlled release of the active ingredients. The paints may also contain plasticizers, modifying agents that affect the rheological properties, and other conventional ingredients. The compounds according to the invention or the abovementioned mixtures can also be incorporated into self-polishing antifouling systems.
  • the active ingredient combinations are also suitable for combating animal pests, in particular insects, arachnids and mites, which live in closed rooms, such as apartments, factory halls, offices, vehicle cabins, etc. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include: From the order of the Sco ⁇ ionidea e.g. Buthus occitanus.
  • Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfred- dugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
  • Araneae e.g. Aviculariidae, Araneidae.
  • Opiliones e.g. Pseudosco ⁇ iones chelifer, Pseudosco ⁇ iones cheiridium, Opiliones phalangium.
  • the Opiliones e.g. Pseudosco ⁇ iones chelifer, Pseudosco ⁇ iones cheiridium, Opiliones phalangium.
  • the Isopoda e.g. Oniscus asellus, Porcellio scaber.
  • Diplopoda e.g. Blaniulus guttulatus, Polydesmus spp.
  • Chilopoda e.g. Geophilus spp.
  • From the order of the Zygentoma for example Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
  • From the order of the Blattaria for example Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
  • From the order of the Saltatoria for example Acheta domesticus.
  • From the order of the Dermaptera for example, Forficula auricularia.
  • Tinea cloacella Tinea pellionella, Tineola bisselliella.
  • Ctenocephalides canis Ctenocephalides felis, Pulex irritans,
  • Tunga penetrans Xenopsylla cheopis. From the order of the Hymenoptera e.g. Camponotus herculeanus, Lasius fuliginosus, Lasius niger,
  • Lasius umbratus Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
  • plants and parts of plants can be treated.
  • Plants are understood here to mean all plants and plant populations, such as desired and undesirable wild plants or cultivated plants (including naturally occurring cultivated plants).
  • Cultivated plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights.
  • Plant parts are to be understood to mean all above-ground and underground parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, Fruits and seeds as well as roots, tubers and rhizomes are listed.
  • the plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.
  • the treatment of the plants and parts of plants with the active compounds according to the invention is carried out directly or by acting on their surroundings, living space or storage space using the customary treatment methods, e.g. by dipping, spraying, vaporizing, atomizing, scattering, spreading and, in the case of propagation material, in particular in the case of seeds, furthermore by coating in one or more layers.
  • all plants and their parts can be treated.
  • wild plant species or plant species and their parts obtained by conventional biological breeding methods such as crossing or protoplast fusion
  • transgenic plants and plant cultivars which have been obtained by genetic engineering methods if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated.
  • the term "parts” or “parts of plants” or “plant parts” was explained above.
  • Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.
  • the treatment according to the invention can also cause superadditive (“synergistic") effects.
  • superadditive for example, reduced application rates and / or widening of the spectrum of action and / or an increase in the action of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance , easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products, higher storability and / or workability of the harvested products possible, which go beyond the effects to be expected.
  • the preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which, through the genetic engineering modification, have received genetic material which gives these plants particularly advantageous, valuable properties. gives (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products.
  • transgenic plants are the important cultivated plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, tobacco, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes , Cotton, tobacco and rapeseed are highlighted.
  • the traits that are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and snails by toxins arising in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes Cry ⁇ A (a) , CryIA (b), CryIA (c), CryHA, CryJJIA, CryIDB2, Cry9c Cry2Ab, Cry3Bb and CrylF as well as their combinations) are produced in the plants (hereinafter "Bt plants”).
  • the properties (“traits”) also particularly emphasize the increased defense of plants against fungi, bacteria and viruses by systemic acquired resistance (SAR), systernin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins.
  • the properties (“traits”) which are particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example “PAT” gene), each of which has the desired properties (“traits”).
  • Genes conferring genes can also occur in combinations with one another in the transgenic plants.
  • Bt plants are maize varieties, cotton varieties, soy varieties and potato varieties which are marketed under the trade names YIELD GARD® (eg maize, cotton, soy), KnockOut® (eg Maize), StarLink® (eg maize), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato).
  • herbicide-tolerant plants are maize varieties, cotton varieties and soy varieties which are marketed under the Roundup trade names Ready® (tolerance to glyphosate e.g. corn, cotton, soy), Liberty Link® (tolerance to phosphinotricin, e.g.
  • the herbicide-resistant plants include the varieties marketed under the name Clearf ⁇ eld® (eg maize). Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").
  • the plants listed can be treated according to the invention in a particularly advantageous manner with the compounds of the invention. The preferred ranges given for the mixtures above also apply to the treatment of these plants. Plant treatment with the mixtures specifically listed in this text should be particularly emphasized.
  • Insecticides and acaricides always have a synergistic effect if the effect of the active ingredient combinations is greater than the sum of the effects of the individually applied active ingredients.
  • X means the degree of killing, expressed in% of the untreated control when using the active ingredient A in an application rate of mg / ha or in a concentration of m ppm
  • Y the degree of killing, expressed in% of the untreated control, when using the active ingredient B in a Application rate of ng ha or in a concentration of n ppm
  • E means the degree of destruction, expressed in% of the untreated control, when using the active compounds A and B in application rates of m and ng / ha or in a concentration of m and n ppm
  • the combination is superadditive in its killing, i.e. there is a synergistic effect.
  • the degree of mortality actually observed must be greater than the value for the expected degree of mortality (E) calculated from the above formula.
  • the kill is determined in%. 100% means that all animals have been killed; 0% means that no animals have been killed.
  • Emulsifier 2 parts by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the stated amounts of solvent and emulsifier and the concentrate is diluted to the desired concentration with water containing emulsifier.
  • Cabbage leaves (Brassica oleraceä), which are heavily infested with the green peach aphid (Myzus persicae), are treated by immersing them in the active ingredient preparation of the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne de nouvelles combinaisons d'agents insecticides comprenant des amides d'acide anthranilique (groupe 1) et d'autres agents insecticides sélectionnés parmi le groupe des thio-phosphates (groupe 2) et/ou du groupe des carbamates (groupe 3). Les combinaisons permettent de lutter efficacement contre les parasites animaux notamment les insectes.
EP04798022A 2003-12-04 2004-11-20 Combinaisons d'agents presentant des proprietes insecticides Withdrawn EP1691611A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10356549 2003-12-04
DE102004021565A DE102004021565A1 (de) 2003-12-04 2004-05-03 Wirkstoffkombinationen mit insektiziden Eigenschaften
PCT/EP2004/013197 WO2005053406A1 (fr) 2003-12-04 2004-11-20 Combinaisons d'agents presentant des proprietes insecticides

Publications (1)

Publication Number Publication Date
EP1691611A1 true EP1691611A1 (fr) 2006-08-23

Family

ID=34654844

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04798022A Withdrawn EP1691611A1 (fr) 2003-12-04 2004-11-20 Combinaisons d'agents presentant des proprietes insecticides

Country Status (7)

Country Link
US (2) US20070142327A1 (fr)
EP (1) EP1691611A1 (fr)
KR (1) KR100870171B1 (fr)
AU (1) AU2004294711B2 (fr)
BR (1) BRPI0417322B1 (fr)
CA (1) CA2547989C (fr)
WO (1) WO2005053406A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8921400B2 (en) 2001-08-13 2014-12-30 E I Du Pont De Nemours And Company Arthropodicidal anthranilamides

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4426753A1 (de) * 1994-07-28 1996-02-01 Bayer Ag Mittel zur Bekämpfung von Pflanzenschädlingen
TR200003651T2 (tr) 1998-06-10 2001-06-21 Bayer Aktiengesellschaft Bitki zararlılarının kontrol edilmesi için bileşimler.
MY142967A (en) 2001-08-13 2011-01-31 Du Pont Method for controlling particular insect pests by applying anthranilamide compounds
TW200724033A (en) 2001-09-21 2007-07-01 Du Pont Anthranilamide arthropodicide treatment
DE10228102A1 (de) * 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE10228103A1 (de) * 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
US7247647B2 (en) 2003-01-28 2007-07-24 E. I. Du Pont De Nemours And Company Cyano anthranilamide insecticides
DE10335183A1 (de) * 2003-07-30 2005-02-24 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE10341945A1 (de) * 2003-09-11 2005-04-21 Bayer Cropscience Ag Verwendung von fungiziden Mitteln zur Beizung von Saatgut
DE10347090A1 (de) 2003-10-10 2005-05-04 Bayer Cropscience Ag Synergistische fungizide Wirkstoffkombinationen
DE10347440A1 (de) * 2003-10-13 2005-05-04 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE10353281A1 (de) * 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden und akariziden Eigenschaften
DE102004006075A1 (de) 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102004021564A1 (de) * 2003-11-14 2005-07-07 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
EP1691608B2 (fr) * 2003-12-04 2015-04-08 Bayer CropScience AG Combinaisons d'agents a proprietes insecticides et acaricides
KR100870171B1 (ko) * 2003-12-04 2008-11-24 바이엘 크롭사이언스 아게 살충성을 가지는 활성 물질 배합물
BRPI0406186B1 (pt) * 2003-12-12 2012-10-16 agente para o combate de pragas animais e processo para preparação de composições praguicidas.
DE102004005786A1 (de) * 2004-02-06 2005-08-25 Bayer Cropscience Ag Haloalkylcarboxamide
EA200602033A1 (ru) * 2004-05-10 2007-06-29 Зингента Партисипейшнс Аг Пестицидные смеси
EP1606999A1 (fr) * 2004-06-18 2005-12-21 Bayer CropScience AG Agent pour le traitement des semences de soja
GT200500179AA (es) * 2004-07-01 2008-10-29 Mezclas sinergistas de agentes de antranilamida para el control de plagas de invertebrados
DE102005022147A1 (de) * 2005-04-28 2006-11-02 Bayer Cropscience Ag Wirkstoffkombinationen
GB0516703D0 (en) * 2005-08-15 2005-09-21 Syngenta Participations Ag Novel insecticides
DE102005059470A1 (de) * 2005-12-13 2007-06-14 Bayer Cropscience Ag Insektizide Zusammensetzungen mit verbesserter Wirkung
DE102006031978A1 (de) * 2006-07-11 2008-01-17 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
US20090281157A1 (en) * 2006-07-11 2009-11-12 Bayer Cropscience Ag Active Ingredient Combinations With Insecticidal and Acaricidal Properties
DE102006031976A1 (de) * 2006-07-11 2008-01-17 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
JP5449669B2 (ja) 2006-12-14 2014-03-19 石原産業株式会社 有害生物防除組成物
US20100190645A1 (en) * 2007-02-02 2010-07-29 Anne Suty-Heinze Synergistic fungicidal active compound combinations comprising formononetin
US8683346B2 (en) * 2008-11-17 2014-03-25 Sap Portals Israel Ltd. Client integration of information from a supplemental server into a portal
CN101536698B (zh) * 2009-04-09 2013-07-31 湖北仙隆化工股份有限公司 亚胺硫磷与高效氯氰菊酯的杀虫组合物
EP2582242B1 (fr) 2010-06-18 2016-12-28 Bayer Intellectual Property GmbH Combinaisons d'agents a proprietes insecticides et acaricides
JP6256771B2 (ja) 2012-12-06 2018-01-10 セルジーン クオンティセル リサーチ，インク． ヒストンデメチラーゼ阻害剤
AR120925A1 (es) * 2019-12-31 2022-03-30 Adama Makhteshim Ltd Mezclas insecticidas
AR123313A1 (es) * 2020-08-24 2022-11-16 Adama Makhteshim Ltd Proceso para la preparación de pirazoles sustituidos

Family Cites Families (54)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3364177A (en) * 1966-02-21 1968-01-16 Dow Chemical Co Curing epoxy resins with aminomethylated diphenyl oxides
US4070481A (en) * 1975-09-15 1978-01-24 E. I. Du Pont De Nemours And Company Substituted 2-higher alkyl-3-hydroxy-1,4-naphthoquinone carboxylic acid esters and their use as miticides
US4055661A (en) * 1974-12-11 1977-10-25 E. I. Du Pont De Nemours And Company Miticidal and aphicidal method utilizing 2-higher alkyl-3-hydroxy-1,4-naphthoquinone carboxylic acid esters
FI762480A (fr) 1975-09-15 1977-03-16 Du Pont
US4053634A (en) * 1975-09-15 1977-10-11 E. I. Du Pont De Nemours And Company Miticidal and aphicidal method utilizing 2-higher alkyl-3-hydroxy-1,4-naphthoquinone carboxylic acid esters
IL79360A (en) 1985-07-12 1993-02-21 Ciba Geigy Ag Aleyrodidae-controlling compositions containing n-(4-phenoxy-2,6- diisopropylphenyl) -n)-tert- butylthiourea as active agent
CA1300137C (fr) 1985-12-27 1992-05-05 Hiroshi Hamaguchi Derive oxime du pyrazole, sa production et son utilisation
US5010098A (en) 1987-07-29 1991-04-23 American Cyanamid Company Arylpyrrole insecticidal acaricidal and nematicidal agents and methods for the preparation thereof
DE69217085T2 (de) 1991-11-22 1997-05-28 Uniroyal Chem Co Inc Insekttötende phenylhydrazin-derivate
EP0639572B1 (fr) 1992-04-28 1998-07-29 Yashima Chemical Industry Co., Ltd. 2-(2,6-difluorophenyle)-4-(2-ethoxy-4-tert-butylphenyle)-2-oxazoline
DE4426753A1 (de) * 1994-07-28 1996-02-01 Bayer Ag Mittel zur Bekämpfung von Pflanzenschädlingen
US6828275B2 (en) * 1998-06-23 2004-12-07 Bayer Aktiengesellschaft Synergistic insecticide mixtures
DE19629826A1 (de) * 1996-07-24 1998-01-29 Bayer Ag 1,3-Dimethyl-5-fluor-pyrazol-4-carboxamide
TW533055B (en) * 1997-02-10 2003-05-21 Takeda Chemical Industries Ltd Aqueous suspension of agrochemical
DE19716257A1 (de) * 1997-04-18 1998-10-22 Bayer Ag Fungizide Wirkstoffkombination
DE19953775A1 (de) * 1999-11-09 2001-05-10 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
MY138097A (en) 2000-03-22 2009-04-30 Du Pont Insecticidal anthranilamides
DE10042736A1 (de) * 2000-08-31 2002-03-14 Bayer Ag Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
AU778580B2 (en) * 2000-11-09 2004-12-09 Sumitomo Chemical Company, Limited Ectoparasite control compositions
JP4359433B2 (ja) 2001-05-21 2009-11-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 非芳香族複素環式環を含有するジアミド無脊椎有害動物抑制剤
MY142967A (en) 2001-08-13 2011-01-31 Du Pont Method for controlling particular insect pests by applying anthranilamide compounds
DE60236600D1 (de) 2001-08-13 2010-07-15 Du Pont Substituierte 1h-dihydropyrazole, ihre herstellung und verwendung
AR036872A1 (es) * 2001-08-13 2004-10-13 Du Pont Compuesto de antranilamida, composicion que lo comprende y metodo para controlar una plaga de invertebrados
TWI327566B (en) 2001-08-13 2010-07-21 Du Pont Novel substituted ihydro 3-halo-1h-pyrazole-5-carboxylates,their preparation and use
DK1417176T3 (da) * 2001-08-16 2009-03-23 Du Pont Substituerede anthranilamider til kontrol af hvirvellöse skadegörere
DE10140108A1 (de) * 2001-08-16 2003-03-06 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
TW200724033A (en) 2001-09-21 2007-07-01 Du Pont Anthranilamide arthropodicide treatment
ES2271371T3 (es) 2001-09-21 2007-04-16 E. I. Du Pont De Nemours And Company Antranilamidas artropodicidas.
CN100349890C (zh) 2002-01-22 2007-11-21 纳幕尔杜邦公司 用于防治无脊椎害虫的喹唑啉(二)酮
AU2003210354B9 (en) * 2002-03-01 2008-11-20 Basf Se Fungicidal mixtures based on prothioconazole and a strobilurin derivative
DE10228102A1 (de) * 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE10228104A1 (de) * 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombination
DE10228103A1 (de) * 2002-06-24 2004-01-15 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE10335183A1 (de) * 2003-07-30 2005-02-24 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE10341945A1 (de) * 2003-09-11 2005-04-21 Bayer Cropscience Ag Verwendung von fungiziden Mitteln zur Beizung von Saatgut
DE10347440A1 (de) * 2003-10-13 2005-05-04 Bayer Cropscience Ag Synergistische insektizide Mischungen
DE102004006075A1 (de) * 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102004021564A1 (de) * 2003-11-14 2005-07-07 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
DE10353281A1 (de) * 2003-11-14 2005-06-16 Bayer Cropscience Ag Wirkstoffkombination mit insektiziden und akariziden Eigenschaften
EP1691608B2 (fr) * 2003-12-04 2015-04-08 Bayer CropScience AG Combinaisons d'agents a proprietes insecticides et acaricides
KR100870171B1 (ko) 2003-12-04 2008-11-24 바이엘 크롭사이언스 아게 살충성을 가지는 활성 물질 배합물
BRPI0406186B1 (pt) * 2003-12-12 2012-10-16 agente para o combate de pragas animais e processo para preparação de composições praguicidas.
DE102004001271A1 (de) * 2004-01-08 2005-08-04 Bayer Cropscience Ag Wirkstoffkombinationen mit insektiziden Eigenschaften
EP1719409B1 (fr) 2004-02-24 2012-07-11 Sumitomo Chemical Company, Limited Composition insecticide
EA200602033A1 (ru) 2004-05-10 2007-06-29 Зингента Партисипейшнс Аг Пестицидные смеси
GT200500179AA (es) 2004-07-01 2008-10-29 Mezclas sinergistas de agentes de antranilamida para el control de plagas de invertebrados
MY140912A (en) 2004-07-26 2010-01-29 Du Pont Mixtures of anthranilamide invertebrate pest control agents
DE102004045242A1 (de) * 2004-09-17 2006-03-23 Bayer Cropscience Ag Synergistische fungizide Wirkstoffkombinationen
DE102004049761A1 (de) * 2004-10-12 2006-04-13 Bayer Cropscience Ag Fungizide Wirkstoffkombinationen
DE102004062513A1 (de) * 2004-12-24 2006-07-06 Bayer Cropscience Ag Insektizide auf Basis von Neonicotinoiden und ausgewählten Strobilurinen
DE102004062512A1 (de) * 2004-12-24 2006-07-06 Bayer Cropscience Ag Synergistische Mischungen mit insektizider und fungizider Wirkung
BRPI0607032A2 (pt) 2005-04-08 2009-08-04 Syngenta Participations Ag misturas pesticidas
EP1728430A1 (fr) * 2005-06-04 2006-12-06 Bayer CropScience GmbH Agents herbicides
US20070203025A1 (en) * 2006-02-24 2007-08-30 Udo Bickers Defoliant

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
"INSECTICIDES" *
"The e-Pesticide Manual (Thirteenth Edition) Version 3.0", 2003, BRITISH CROP PROTECTION COUNCIL *
See also references of WO2005053406A1 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8921400B2 (en) 2001-08-13 2014-12-30 E I Du Pont De Nemours And Company Arthropodicidal anthranilamides
US9029365B2 (en) 2001-08-13 2015-05-12 E I Du Pont De Nemours And Company Arthropodicidal anthranilamides

Also Published As

Publication number Publication date
US8865683B2 (en) 2014-10-21
CA2547989A1 (fr) 2005-06-16
BRPI0417322B1 (pt) 2015-11-24
US20070142327A1 (en) 2007-06-21
CA2547989C (fr) 2012-10-09
AU2004294711B2 (en) 2011-05-12
WO2005053406A1 (fr) 2005-06-16
KR100870171B1 (ko) 2008-11-24
US20100249070A1 (en) 2010-09-30
KR20060121262A (ko) 2006-11-28
AU2004294711A1 (en) 2005-06-16
BRPI0417322A (pt) 2007-03-27

Similar Documents

Publication Publication Date Title
EP1686859B1 (fr) Combinaisons d'agents a proprietes insecticides
EP1691608B1 (fr) Combinaisons d'agents a proprietes insecticides et acaricides
EP1686857B1 (fr) Combinaisons d'agents a proprietes insecticides
EP1686858B1 (fr) Combinaisons d'agents a proprietes insecticides et acaricides
EP1553829B1 (fr) Combinaisons de principes actifs a proprietes insecticides et acaricides
EP1699290B2 (fr) Combinaisons d'agents insecticides comprenant des acides anthraniliques et au moins un agent insecticide supplementaire
EP1691611A1 (fr) Combinaisons d'agents presentant des proprietes insecticides
EP1646281A1 (fr) Combinaisons de principes actifs a proprietes insecticides et acaricides
EP1322160A1 (fr) Combinaison de substances actives ayant des proprietes insecticides et acaricides
WO2002037963A1 (fr) Associations de principes actifs aux proprietes insecticides et acaricides
DE10015310A1 (de) Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
WO2002005648A1 (fr) Combinaisons de matieres actives a proprietes insecticides et acaricides
WO2005004604A1 (fr) Combinaisons de principes actifs a proprietes insecticides et acaricides
EP1988778A2 (fr) Combinaisons de principes actifs à propriétés insecticides et acaricides
WO2005065453A1 (fr) Combinaisons de principes actifs a proprietes insecticides et acaricides
DE102004021566A1 (de) Wirkstoffkombinationen mit insektiziden und akariziden Eigenschaften
DE102004021565A1 (de) Wirkstoffkombinationen mit insektiziden Eigenschaften
DE102005041955A1 (de) Wirkstoffkombination mit insektiziden und akariziden Eigenschaften

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20060704

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LU MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20060905

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: A01N 47/22 20060101ALI20081106BHEP

Ipc: A01N 43/56 20060101AFI20081106BHEP

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20090319