EP1679268B1 - Bouchon non remplissable avec deux dispositifs d'inviolabilité - Google Patents

Bouchon non remplissable avec deux dispositifs d'inviolabilité Download PDF

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Publication number
EP1679268B1
EP1679268B1 EP20050380267 EP05380267A EP1679268B1 EP 1679268 B1 EP1679268 B1 EP 1679268B1 EP 20050380267 EP20050380267 EP 20050380267 EP 05380267 A EP05380267 A EP 05380267A EP 1679268 B1 EP1679268 B1 EP 1679268B1
Authority
EP
European Patent Office
Prior art keywords
stopper
external
closing element
laminar covering
covering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP20050380267
Other languages
German (de)
English (en)
Other versions
EP1679268A1 (fr
Inventor
Eduardo Martin Lopez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Plastivit SA
Original Assignee
Plastivit SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plastivit SA filed Critical Plastivit SA
Priority to PL05380267T priority Critical patent/PL1679268T3/pl
Publication of EP1679268A1 publication Critical patent/EP1679268A1/fr
Application granted granted Critical
Publication of EP1679268B1 publication Critical patent/EP1679268B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/32—Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
    • B65D41/34—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
    • B65D41/3404—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with ratchet-and-pawl mechanism between the container and the closure skirt or the tamper element
    • B65D41/3409—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with ratchet-and-pawl mechanism between the container and the closure skirt or the tamper element the tamper element being integrally connected to the closure by means of bridges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D49/00—Arrangements or devices for preventing refilling of containers
    • B65D49/02—One-way valves
    • B65D49/04—Weighted valves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/32—Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
    • B65D41/34—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
    • B65D41/3423—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with flexible tabs, or elements rotated from a non-engaging to an engaging position, formed on the tamper element or in the closure skirt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/32—Caps or cap-like covers with lines of weakness, tearing-strips, tags, or like opening or removal devices, e.g. to facilitate formation of pouring openings
    • B65D41/34—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt
    • B65D41/3423—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with flexible tabs, or elements rotated from a non-engaging to an engaging position, formed on the tamper element or in the closure skirt
    • B65D41/3428—Threaded or like caps or cap-like covers provided with tamper elements formed in, or attached to, the closure skirt with flexible tabs, or elements rotated from a non-engaging to an engaging position, formed on the tamper element or in the closure skirt the tamper element being integrally connected to the closure by means of bridges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00—Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/62—Secondary protective cap-like outer covers for closure members
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2401/00—Tamper-indicating means
    • B65D2401/55—Tamper-indicating means based on a change or a contrast in colour

Definitions

  • the present invention relates to a non refillable stopper, in particular of the type used for expensive alcoholic beverages, having security features which are far superior to those of currently known non refillable stoppers.
  • non refillable stoppers for alcoholic beverages is precisely that they cannot easily be manipulated in order to refill the container with beverages of inferior quality.
  • This illegal action is traditionally fairly widespread, particularly in specific countries, and causes significant harm to bottlers of the original beverages.
  • the inventors of the present non refillable stopper have set the objective of very significantly increasing the security features of the stopper so as to provide a non refillable stopper having very simple features but which, after the opening thereof, simultaneously and clearly exhibits two highly visible signs which demonstrate the initial opening thereof.
  • the inventors have demonstrated that, although the effect of a visual indicator may sometimes be unnoticed after manipulation, the production of a double security device with two highly visible indicators on the exterior of the stopper make it virtually impossible to miss said manipulation.
  • the non refillable stopper basically comprises what is known as a special tubular closing element which is connected externally to the bottle neck and has a special structure both at its upper edge and at its lower edge, and is also combined with an external laminar covering provided with a skirt, preferably made of a metal, which covers what is known as the cap of the stopper and is rotationally engaged therewith, having special design features which will be described in detail hereinafter such that respective mutual displacements of the ends of the special tubular closing element and of the external metal covering of the cap and its skirt are produced when the stopper is unscrewed and the cap therefore separated from the body to allow the subsequent egress of the liquid.
  • the non refillable stopper conventionally comprises an internal closure valve 1 which is combined with what is known as the washer 2 which is the part resting on the upper edge of the bottle neck 3 and is fitted by means of an internal wing 4 in the interior portion of the actual bottle for the purposes of sealing and retention.
  • Said washer 2 which receives the lower plate of the valve 1 in its upper region by means of a small flange 5 further comprises a cylindrical projection 6 intended to receive the upper body 7, equipped with an external thread, on which the cap 8 is engaged, the upper portion 9 of which abuts against the upper face 10 of the internal portion of said body 7.
  • An external laminar covering 11 is fitted externally to the entire cap 8 and special tubular closing element 17, and has numerous recesses 12 which mate with grooves 13 in the external cylindrical portion of the closure, causing it to be rotationally engaged.
  • the closure 8 comprises downwardly directed projecting radial fins 14 which combine with a recessed zone 15 of the external laminar covering 11 and cause the axial connection between said external covering 11 and the closure 8.
  • the special tubular closing element 17 is shown in greater detail in Fig. 5 , which illustrates large lateral windows such as 21, 21', 22, 22', each of which has a T-shaped expanse such as 23 and 24 for adaptable retention on the bottle neck, joined, to its openings by central arms, for example 25 and 26. Lower openings such as 28 and 28' impart greater flexibility to the special tubular closing element 17.
  • the external laminar covering 11, as indicated, is also fitted to the external portion of the special tubular closing element 17 in such a way that the lower edge of the lateral wall of said metal covering 11 externally surrounds an upper projecting flange 16 of the special tubular closing element 17, which has a similar flange 18 in the lower portion, with the feature that the upper flange 16 remains slightly compressed, in other words deflected inwards and making contact with the internal portion of lateral wall of the covering laminar part 11 and the flange 18 also remains slightly compressed or deflected, and also makes contact with the corresponding internal portion of the skirt 19 connected to the metal covering 11 by means of fracturable bridges (not shown) and which, beneath the flange 16, has a zone 20 which is smoothly recessed from the bottle neck and joined to the upper portion 11 by known easy-break bridges.
  • the security edges 16 and 18 of said special tubular closing element 17 are concealed when the bottle is closed, as shown in Fig. 1 , but, as the bottle stopper is opened, the first phase of which is shown in Fig. 3 , after the short vertical displacement until the zone 20 abuts against the lower edge of the projection 16, the lower flange 18 will be revealed and, owing to the earlier deflection which it has received, will tend to move outwards and occupy a greater diameter than the skirt 19, so that said skirt cannot subsequently be reintroduced to cover said security flange 18 again.
  • the flange 16 in view of its compressed state and after having passed beyond the lateral wall of the covering 11 in its ascending movement, will issue outwards and occupy the position shown in Fig. 3 , so that the external diameter effectively occupied by said flange 16 will be slightly greater than the lower edge of the lateral wall of the covering 11 so that, in the subsequent closed position of the bottle, the position occupied by the various elements is that shown in Fig. 3 , which shows clearly that the external security flanges 16 and 18 will remain visible and cannot be concealed again by the skirt or the upper metal covering since the diameters which they now occupy, which are somewhat greater than said covering, do not allow the subsequent concealment thereof.
  • the colouring thereof may be very visible and different from the remainder of the stopper so as to make the opening more clearly identifiable.
  • the present invention enables an additional effect of security against external manipulation to be achieved, as shown in Fig. 9,10 and 11 .
  • the existence of the T-shaped expanses such as those indicated by reference numerals 23 and 24 in Fig. 5 enables a penetration effect to be achieved with the step of the neck 3, producing an outward fold which permanently deforms the skirt 19 of the lower portion of the external laminar cover II.
  • FIG. 9 to 11 also show the connection by means of corresponding ribs and recesses between the bottle neck and the tubular closing element 17, the projections 29, 29', etc. of the bottle neck which are combined with ribs 30, 30', etc. of the tubular closing element 17 being illustrated.
  • T-shaped fins such as 23 and 24 shown in Fig. 5
  • the disposition of the T-shaped fins is illustrated in greater detail in said figure showing the possible disposition of easy-break connecting bridges at the edges, such as those indicated by reference numerals 31 and 32, which will improve the driving thereof into bottles of inferior quality, in other words lesser precision of the flange and possibly smaller width of the drive-in step.
  • the arrangement of the non refillable stopper according to the present invention provides, in a very simple and practical manner, a double device for security against manipulation of the stopper which will not be salvageable for possible manipulators of the bottle attempting to refill the bottle at a later stage.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)

Claims (10)

  1. Bouchon non rechargeable pour bouteilles de boisson, du type comprenant une rondelle intérieure (2) couplée au col de bouteille (3) et portant une vanne de fermeture mobile (1), la rondelle (2) comportant également une partie cylindrique saillante (6) pour recevoir un corps supérieur (7), équipé d'un filetage extérieur pour visser une capsule (8), et ladite rondelle (2) possédant une partie tubulaire inférieure qui est couplée à la partie extérieure du col de bouteille, avec un revêtement stratifié extérieur (11) qui recouvre extérieurement ladite capsule (8) et l'ensemble de corps tubulaire relié à l'extérieur du col (3), ledit revêtement stratifié extérieur (11) comportant une partie supérieure et une jupe (19) reliée à ladite partie supérieure par des ponts fracturables, caractérisé en ce qu'un élément de fermeture tubulaire particulier (17) formant un corps tubulaire est relié à la partie supérieure du col de bouteille (3) et entoure celle-ci, et est recouvert par ledit revêtement stratifié extérieur (11), ledit élément de fermeture tubulaire particulier (17) comportant un flasque saillant supérieur (16) et un flasque saillant inférieur (18), respectivement, qui sont pressés vers l'intérieur par l'action dudit revêtement stratifié extérieur (11), ledit élément de fermeture tubulaire particulier (17) et ledit revêtement stratifié extérieur (11) étant configurés de telle sorte que, durant le dévissage vers le haut initial du bouchon, avant la rupture desdits ponts fracturables, ladite jupe (19) se déplace vers le haut avec ledit revêtement stratifié extérieur (11) et révèle ledit flasque saillant inférieur (18), et, après la rupture desdits ponts fracturables, ladite partie supérieure du revêtement stratifié extérieur (11) continue à se déplacer vers le haut et révèle ledit flasque saillant supérieur (16), lesdits flasques (16, 18), du fait de leur disposition comprimée, faisant par conséquent saillie élastiquement vers l'extérieur lorsqu'ils sont libérés par ledit revêtement stratifié extérieur (11), empêchant ledit revêtement stratifié extérieur (11) de redescendre, étant visibles de façon permanente afin de mettre en évidence l'ouverture précédente du bouchon de bouteille.
  2. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 1, caractérisé en ce que ladite partie supérieure du revêtement stratifié extérieur (11) comporte des moyens (12) de liaison radiale à ladite capsule (8), de telle sorte que, lorsque l'on fait tourner la partie supérieure du bouchon, ledit revêtement stratifié extérieur (11) et ladite capsule (8) tournent simultanément.
  3. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 2, caractérisé en ce que lesdits moyens de liaison radiale sont constitués par une série de cavités (12) qui s'accouplent avec des rainures (13) réalisées dans ladite capsule (8).
  4. Bouchon non rechargeable pour bouteilles de boisson selon les revendications précédentes, caractérisé en ce que ladite capsule (8) comporte des ergots radiaux saillants dirigés vers le bas (14) qui se combinent avec un renfoncement (15) de ladite partie supérieure du revêtement stratifié extérieur (11) de façon à relier axialement ladite capsule (8) audit revêtement stratifié extérieur (11).
  5. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 1, caractérisé en ce que le bord supérieur de ladite jupe (19) du revêtement stratifié extérieur (11) comporte une zone (20) qui est légèrement en retrait par rapport au col de bouteille, et réunie à ladite partie supérieure du revêtement stratifié extérieur (11) par des ponts pouvant être fracturés.
  6. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 1, caractérisé en ce que, entre le bord supérieur de ladite zone en retrait (20) de la jupe (19) et ledit flasque supérieur (16) de l'élément de fermeture tubulaire particulier (17), est disposée une séparation qui est plus grande que la hauteur dudit flasque inférieur (18) de l'élément de fermeture tubulaire particulier (17), de telle sorte que ledit flasque inférieur (18) soit complètement exposé avant que ladite zone en retrait (20) ne bute contre la partie inférieure dudit flasque supérieur (16) de l'élément de fermeture tubulaire particulier (17).
  7. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 1, caractérisé en ce que les diamètres extérieurs desdits flasques supérieur (16) et inférieur (18) de l'élément de fermeture tubulaire particulier (17) dans la position relâchée, ou, en d'autres termes, lorsqu'ils sont relâchés, sont légèrement plus grands que les parties opposées dudit revêtement stratifié extérieur (11), de telle sorte que, lorsqu'ils sont relâchés et après le déplacement vertical ascendant dudit revêtement stratifié extérieur (11), lesdits flasques (16, 18) ne puissent pas être cachés par une nouvelle descente dudit revêtement stratifié extérieur (11).
  8. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 1, caractérisé en ce que ledit élément de fermeture tubulaire particulier (17) comporte de grandes ouvertures latérales (21, 21', 22, 22') dont chacune est munie d'une surface de maintien en forme de T (23, 24) susceptible d'être entraînée par son bord supérieur dans le flasque inférieur du col de bouteille dans le cas d'une tentative d'extraction axiale du bouchon, provoquant le pliage vers l'extérieur desdites surfaces de maintien (23, 24), marquant et/ou détruisant ledit revêtement stratifié extérieur (11), et mettant ainsi en évidence la manipulation.
  9. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 8, caractérisé en ce que chacune desdites surfaces de maintien en forme de T (23, 24) est reliée au corps dudit élément de fermeture tubulaire (17) par ses bords latéraux à l'aide de ponts faciles à rompre (31, 32), améliorant ainsi l'entraînement de celui-ci dans des bouteilles de qualité inférieure.
  10. Bouchon non rechargeable pour bouteilles de boisson selon la revendication 1, caractérisé en ce que ledit élément de fermeture tubulaire particulier (17) est muni de nervures (30, 30') qui se combinent à des saillies (29, 29') du col de bouteille pour relier entre eux ledit élément de fermeture tubulaire particulier (17) et ledit col de bouteille.
EP20050380267 2004-12-24 2005-12-16 Bouchon non remplissable avec deux dispositifs d'inviolabilité Active EP1679268B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL05380267T PL1679268T3 (pl) 2004-12-24 2005-12-16 Korek niepozwalający na ponowne napełnianie z urządzeniem podwójnie zabezpieczającym

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES200403078A ES2229959B1 (es) 2004-12-24 2004-12-24 Tapon irrellenable con doble dispositivo de seguridad.

Publications (2)

Publication Number Publication Date
EP1679268A1 EP1679268A1 (fr) 2006-07-12
EP1679268B1 true EP1679268B1 (fr) 2009-10-14

Family

ID=34610391

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20050380267 Active EP1679268B1 (fr) 2004-12-24 2005-12-16 Bouchon non remplissable avec deux dispositifs d'inviolabilité

Country Status (11)

Country Link
EP (1) EP1679268B1 (fr)
CN (1) CN1792733A (fr)
AR (1) AR052820A1 (fr)
AT (1) ATE445547T1 (fr)
BR (1) BRPI0505629A (fr)
CO (1) CO5710200A1 (fr)
DE (1) DE602005017114D1 (fr)
ES (2) ES2229959B1 (fr)
MX (1) MXPA05014146A (fr)
PL (1) PL1679268T3 (fr)
RU (1) RU2377170C2 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101112923B (zh) * 2006-07-27 2010-09-29 珠海经济特区龙狮瓶盖有限公司 一种防伪瓶盖
WO2008121086A1 (fr) * 2007-03-30 2008-10-09 Teko Aluminyum Sanayi Anonim Sirketi Capsule de sécurité pour bouteille, à double anneau de sécurité
RU2008140398A (ru) * 2008-10-14 2010-04-20 Андрей Борисович Прозуменщиков (RU) Укупорочное устройство (варианты)
CN102211687B (zh) * 2010-04-09 2013-01-09 海普制盖股份有限公司 下旋顶防伪瓶盖
EA020845B1 (ru) * 2012-06-13 2015-02-27 Дмитрий Иванович ПАХОМОВ Укупорочное устройство
ES2575791T3 (es) * 2013-02-21 2016-07-01 Bericap Kapak Sanayi Anonim Sirketi Sistema de cierre de manipulación evidente para botellas
TR201914840A2 (tr) * 2019-09-30 2021-04-21 Bericap Kapak San A S Yeni̇den dolumu engelleyi̇ci̇ parçaya hai̇z kurcalama karşiti kapak mekani̇zmasi

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4572387A (en) * 1985-03-01 1986-02-25 Sunbeam Plastics Corporation Screw-type safety cap
CO4480049A1 (es) * 1995-01-30 1997-07-09 Grupo Stevi S A De C V Tapa inviolable e irrellenable con sobretapa
IT1301982B1 (it) * 1998-07-31 2000-07-20 Guala Closures Spa Dispositivo di chiusura con sigillo per contenitori di liquidi.
BR0116959B1 (pt) * 2001-04-04 2010-12-28 fechamento de garrafa com válvula sem retorno.
JP2003261155A (ja) * 2002-03-04 2003-09-16 Alcoa Closure Systems Japan Ltd 合成樹脂製キャップ
GB2390086A (en) * 2002-06-10 2003-12-31 Montgomery Daniel & Son Ltd Tamper evident anti-refill closure

Also Published As

Publication number Publication date
ATE445547T1 (de) 2009-10-15
CN1792733A (zh) 2006-06-28
DE602005017114D1 (de) 2009-11-26
EP1679268A1 (fr) 2006-07-12
PL1679268T3 (pl) 2010-03-31
ES2229959A1 (es) 2005-04-16
RU2005141807A (ru) 2007-07-20
CO5710200A1 (es) 2006-12-29
AR052820A1 (es) 2007-04-04
ES2229959B1 (es) 2006-02-16
RU2377170C2 (ru) 2009-12-27
BRPI0505629A (pt) 2006-09-19
ES2334363T3 (es) 2010-03-09
MXPA05014146A (es) 2006-06-23

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